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ISSN 1862-5258<br />

Basics<br />

Can additives make plastics<br />

biodegradable? | 41<br />

Jan / Feb<br />

<strong>01</strong> | 2<strong>01</strong>7<br />

Highlights<br />

Automotive | 10<br />

Foam | 32<br />

BENELUX-Special<br />

bioplastics MAGAZINE Vol. 12<br />

... is read in 92 countries


Editorial<br />

dear<br />

readers<br />

I hope you all had a good start to the new year. And, even as I write these lines, our readers<br />

in China are holding their own New Year’s celebrations as they enter the “Year of<br />

the Fire Rooster”.<br />

The new year also marks the start of a new series in bioplastics MAGAZINE. In<br />

each issue, we will devote attention to a different part of the world, in order to<br />

explore how well the concept of bioplastics is known and understood in the various<br />

regions and countries around the globe. To that end, articles will be solicited<br />

for each edition from companies, researchers and other stakeholders from the<br />

region in focus in that issue. In addition, we have devised a simple survey, which<br />

we ourselves will conduct among members of the local population to assess the<br />

prevailing attitudes towards and general perception of bioplastics. This first issue<br />

starts with the BENELUX countries. Other areas to follow this year are Germany/<br />

Austria/Switzerland, China, Scandinavia, North America and Italy/France. More<br />

areas, such as UK, New Zealand/Australia, Spain/Portugal, Poland and the Baltic<br />

States, Thailand and so on to follow later.<br />

The other highlight topics of this issue include Bioplastic Foams and Bioplastics in<br />

Automotive Applications. In the Basics section, we once again examine the general<br />

question of “Can additives make conventional plastics biodegradable?”<br />

I’d also like to draw your attention to our two conferences this year. In early<br />

May, our bio!PAC event will take place for the second time. As the World’s biggest<br />

trade fair on packaging – interpack 2<strong>01</strong>7 – will be hosted in Düsseldorf, Germany,<br />

we decided to organize bio!PAC this time in the same way as we did the Bioplastics Business<br />

Breakfast @K. See pp 8-9 for details. End of September, Stuttgart, Germany will again be the<br />

place to be for all involved in Automotive Applications. The Call for Papers for the second<br />

edition of bio!CAR is already open (see p. 17).<br />

EcoComunicazione.it<br />

www.novamont.com<br />

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QUALITY OUR TOP PRIORITY<br />

Using the MATER-BI trademark licence<br />

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These are designed to ensure that films<br />

are converted under ideal conditions<br />

and that articles produced in MATER-BI<br />

meet a l essential requirements. To date<br />

over 1000 products have been tested.<br />

THE GUARANTEE<br />

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USED FOR ALL TYPES<br />

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theoriginal_R8_bioplasticmagazine_flagEBC_11.12-2<strong>01</strong>6_210x297_ese.indd 1 18/<strong>01</strong>/17 11:19<br />

r8_03.2<strong>01</strong>6<br />

bioplastics MAGAZINE Vol. 12<br />

ISSN 1862-5258<br />

Basics<br />

Can additives make plastics<br />

biodegradable? | 40<br />

Highlights<br />

Automotive | 10<br />

Foam | 32<br />

BENELUX-Special<br />

Jan / Feb<br />

<strong>01</strong> | 2<strong>01</strong>7<br />

... is read in 92 countries<br />

Until then, please enjoy reading this latest issue of bioplastics MAGAZINE.<br />

Sincerely yours<br />

Michael Thielen<br />

The BENELUX Union is a politico-economic union of three neighbouring<br />

states in western Europe: Belgium, the Netherlands, and Luxembourg.<br />

The name Benelux is formed from joining the first two or three<br />

letters of each country‘s name – Belgium Netherlands Luxembourg<br />

– and was first used to name the customs agreement that initiated<br />

the union (signed in 1944). It is now used more generally to refer to the<br />

geographic, economic and cultural grouping of the three countries.<br />

In 1951, these countries joined West Germany, France, and Italy to form<br />

the European Coal and Steel Community, a<br />

predecessor of the European Economic Community (EEC) and<br />

today‘s European Union (EU). (Source: Wikipedia)


Content<br />

Imprint<br />

Events<br />

8 bio!PAC<br />

Automotive<br />

10 Biobased engineering plastic for Mazda’s<br />

Roadstar RF<br />

11 Panels for trucks and buses<br />

12 Responsible Sourcing of Biomaterials for<br />

Epichlorohydrin<br />

14 Biobased materials – The future for the<br />

automotive industry<br />

16 New ABS reinforced with natural fibers<br />

18 New automotive applications for bio-PA<br />

Report<br />

22 25 years of biodegradable testing<br />

39 Bioplastics Survey<br />

From Science and Research<br />

28 How prawn shopping bags could save the<br />

planet<br />

30 Chitosan-based polymer developed to<br />

patch wounds<br />

Book Review<br />

29 Book Review<br />

Foam<br />

32 Starch based particle foam for<br />

biodegradable packaging<br />

33 The biodegradable foam market in China<br />

34 PLA based particle foam<br />

36 New compostable particle foam<br />

Brand Owners<br />

38 Brand Owners Perspective<br />

<strong>01</strong>|2<strong>01</strong>7<br />

Jan / Feb<br />

Basics<br />

40 Can additives make plastics<br />

biodegradable?<br />

Ten Years Ago<br />

41 “Advancing Bioplastics from Down<br />

Under” (Foam 2007)<br />

3 Editorial<br />

5 News<br />

20 Material News<br />

26 Application News<br />

42 Glossary<br />

46 Suppliers Guide<br />

49 Event Calendar<br />

50 Companies in this issue<br />

Publisher / Editorial<br />

Dr. Michael Thielen (MT)<br />

Karen Laird (KL)<br />

Samuel Brangenberg (SB)<br />

Head Office<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach, Germany<br />

phone: +49 (0)2161 6884469<br />

fax: +49 (0)2161 6884468<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Media Adviser<br />

Samsales (German language)<br />

phone: +49(0)2161-6884467<br />

fax: +49(0)2161 6884468<br />

s.brangenberg@samsales.de<br />

Chris Shaw (English language)<br />

Chris Shaw Media Ltd<br />

Media Sales Representative<br />

phone: +44 (0) 1270 522130<br />

mobile: +44 (0) 7983 967471<br />

and Michael Thielen (see head office)<br />

Layout/Production<br />

Kerstin Neumeister<br />

Print<br />

Poligrāfijas grupa Mūkusala Ltd.<br />

1004 Riga, Latvia<br />

bioplastics MAGAZINE is printed on<br />

chlorine-free FSC certified paper.<br />

Print run: 3,400 copies<br />

bioplastics magazine<br />

ISSN 1862-5258<br />

bM is published 6 times a year.<br />

This publication is sent to qualified<br />

subscribers (149 Euro for 6 issues).<br />

bioplastics MAGAZINE is read in<br />

92 countries.<br />

Every effort is made to verify all<br />

Information published, but Polymedia<br />

Publisher cannot accept responsibility<br />

for any errors or omissions or for any<br />

losses that may arise as a result. No<br />

items may be reproduced, copied or<br />

stored in any form, including electronic<br />

format, without the prior consent of the<br />

publisher. Opinions expressed in articies<br />

do not necessarily reflect those of<br />

Polymedia Publisher.<br />

All articles appearing in bioplastics<br />

MAGAZINE, or on the website<br />

www.bioplasticsmagazine.com are<br />

strictly covered by copyright.<br />

bioplastics MAGAZINE welcomes contributions<br />

for publication. Submissions are<br />

accepted on the basis of full assignment<br />

of copyright to Polymedia Publisher<br />

GmbH unless otherwise agreed in advance<br />

and in writing. We reserve the right<br />

to edit items for reasons of space, clarity<br />

or legality. Please contact the editorial<br />

office via mt@bioplasticsmagazine.com.<br />

The fact that product names may not be<br />

identified in our editorial as trade marks<br />

is not an indication that such names are<br />

not registered trade marks.<br />

bioplastics MAGAZINE tries to use British<br />

spelling. However, in articles based on<br />

information from the USA, American<br />

spelling may also be used.<br />

Envelopes<br />

A part of this print run is mailed to the<br />

readers wrapped in BoPLA envelopes<br />

sponsored by Taghleef Industries, S.p.A.<br />

Maropack GmbH & Co. KG, and SFV<br />

Verpackungen<br />

Cover<br />

Fotolia: Fisher Photostudio<br />

Follow us on twitter:<br />

http://twitter.com/bioplasticsmag<br />

Like us on Facebook:<br />

https://www.facebook.com/bioplasticsmagazine


daily upated news at<br />

www.bioplasticsmagazine.com<br />

News<br />

MHG’s updated corporate<br />

identity back into “Danimer“<br />

Meredian Holdings Group Inc., “MHG”, a leading biopolymer<br />

manufacturer, announced in late December that it will do<br />

business as Danimer Scientific, effective immediately. MHG’s<br />

updated corporate identity is a visual salute to their solid,<br />

steadfast origins as a biotechnology company committed to<br />

sustainability and the development of innovative bioplastic<br />

products that do not contribute to global pollution.<br />

Danimer Scientific was originally formed in 2004 and provided<br />

sustainable polymer solutions by developing compostable and<br />

biodegradable plastic alternatives. Following many years of<br />

successful R & D, relationship building, and B-to-B launches<br />

of bioplastic products for use in consumer and business<br />

applications, the Company has decided to reenergize and<br />

emphasize the original corporate identity.<br />

”The adoption of our founding name and logo marks a<br />

significant milestone as we dedicate ourselves to future<br />

product innovation and the development of global-scale<br />

solutions to plastic pollution,” stated CEO Stephen Croskrey.<br />

“The renewal of our corporate identity signals an exciting<br />

time for the company as we intensify our dedication to<br />

the development of dynamic biopolymer solutions, like<br />

our completely biodegradable PHA plastic for widespread<br />

commercial use.”<br />

In 2007, the founders of Danimer Scientific acquired the<br />

intellectual property from Procter & Gamble, “P&G”, for<br />

NodaxTM PHA. Nodax PHA was created by the distinguished<br />

Dr. Isao Noda while at P&G and he is now a Member of<br />

the Board of Directors at Danimer Scientific. Nodax PHA<br />

possesses a full spectrum of physical properties that have<br />

been proven capable of replacing many short-term use<br />

petroleum-based plastics, for both performance and price.<br />

Danimer Scientific’s Nodax PHA received OK Marine<br />

Biodegradable certification from Vinçotte International, the<br />

first such validation awarded to a biopolymer. The exciting<br />

biopolymer also has a total of six Vinçotte certifications<br />

and statements of aerobic and anaerobic compostability<br />

and biodegradability in soil, fresh water, salt water, and<br />

industrial and home compost.<br />

Danimer Scientific currently operates two facilities with<br />

well over 200,000 square feet of state-of-the-art laboratory<br />

and manufacturing/testing space. Recently, the Company<br />

announced the appointment of their new Chief Executive<br />

Officer, Stephen Croskrey, who is pioneering the Company’s<br />

planned eightfold expansion of the current PHA biorefinery. MT<br />

www.danimerscientific.com<br />

JV to produce biosuccinic<br />

acid in China<br />

With an eye to gaining a strong foothold in the world’s<br />

largest succinic acid market, Canada’s BioAmber Inc.<br />

and South Korean-based CJ CheilJedang Corporation<br />

(CJCJ) have announced that they have signed a nonbinding<br />

letter of intent, under which the two companies<br />

will establish a Chinese joint venture.<br />

The goal: to competitively produce bio-succinic acid<br />

in China and rapidly penetrate the Asian market. The<br />

new facility would produce up to 36,000 tonnes of biosuccinic<br />

acid annually and commercialize the output in<br />

Asia to accelerate sales growth.<br />

In the announcement, the companies state that<br />

this can be achieved rapidly, cost effectively and with<br />

limited capital investment by retrofitting an existing<br />

CJCJ fermentation facility with BioAmber’s succinic<br />

acid technology. CJCJ would incur all capital costs<br />

required to retrofit their fermentation facility, including<br />

the capital needed during plant commissioning and<br />

startup, and production would begin in Q1 2<strong>01</strong>8.<br />

If market demand were to subsequently exceed<br />

production capacity, the joint venture could expand<br />

production through debottlenecking and/or additional<br />

investment. The partners would also have a mutual<br />

right-of-first-refusal to retrofit additional CJCJ<br />

fermentation facilities globally.<br />

The joint venture could offer BioAmber a quick route<br />

to the Chinese and broader Asian market, as well as<br />

serve as a blueprint for the build-out of additional<br />

bio-succinic acid production with very limited capital<br />

investment, noted Jean-Francois Huc, BioAmber’s<br />

CEO. For CJCJ, it would provide an opportunity to utilize<br />

their existing fermentation assets more effectively: “In<br />

order to competitively supply the growing market for<br />

bio-succinic acid in Asia,” explained Dr. Hang Duk Roh,<br />

Head of CJ CheilJedang BIO.<br />

CJCJ would own 65% of the JV and BioAmber would<br />

own 35%. The JV would pay BioAmber a technology<br />

royalty for having access to BioAmber’s proven biosuccinic<br />

acid technology, and would pay CJCJ a tolling<br />

fee for producing bio-succinic acid on behalf of the JV.<br />

Both partners would be entitled to a share of the profits<br />

equal to their respective equity ownership positions.<br />

Huc emphasized that the company would remain<br />

focused on ramping up operations at the Sarnia site<br />

and building a second plant in North America. However:<br />

“This JV is an opportunity for BioAmber to accelerate<br />

the deployment of its bio-succinic acid technology on a<br />

global scale without capital investment,” he said.<br />

Fabrice Orecchioni, BioAmber’s COO, added: “CJCJ<br />

has visited our Sarnia facility and we have visited their<br />

intended plant in China. Both partners are confident<br />

that the China plant can be reconfigured to quickly<br />

produce bio-succinic acid, for a fraction of what it cost<br />

us to build our Sarnia facility.” KL<br />

www.bio-amber.com<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 5


News<br />

daily upated news at<br />

www.bioplasticsmagazine.com<br />

Avantium announced acquisition of Liquid Light<br />

In early January, Avantium (Amsterdam, The Netherlands), a leading chemical technology company and a forerunner in<br />

renewable chemistry, announced it had acquired Liquid Light Inc. (Monmouth Junction, New Jersey, USA), a company spun<br />

out from Princeton University in 2008 that has developed and patented low-energy electrochemistry technologies to convert<br />

CO 2<br />

into major chemicals. Their patent portfolio includes filings on producing multiple chemical building blocks used in large<br />

existing markets, including oxalic acid, glycolic acid, ethylene glycol, propylene, isopropanol, methyl-methacrylate and acetic<br />

acid for the production of polymers, coatings and cosmetics.<br />

The development of electrochemistry has the potential to use CO 2<br />

as a feedstock for the sustainable production of chemicals<br />

and materials, and is seen as a ’game-changer’ for the chemical industry. The technology behind the process is simple: Take<br />

CO 2<br />

and mix it in a water-filled chamber with an electrode and a catalyst. The ensuing chemical reaction converts CO 2<br />

into a<br />

new molecule, methanol, which can be used as a fuel, an industrial solvent or a starting material for the manufacture of other<br />

chemicals. By adjusting the design of their catalyst, Liquid Light can produce a range of commercially important multi-carbon<br />

chemicals. Additionally, by using ‘co-feedstocks’ along with CO 2<br />

, a plant built with Liquid Light’s technology may produce<br />

multiple products simultaneously.<br />

Tom van Aken, Chief Executive Officer of Avantium, said: “The acquisition of Liquid Light is an important step in our strategy<br />

to create and commercialize breakthrough technologies in renewable chemistry. It will extend our capabilities beyond catalytic<br />

conversion of biomass. This acquisition will enable the development of a powerful technology platform on the basis of carbon<br />

dioxide feedstock, meaning it turns waste into valuable products such as chemicals and plastics.”<br />

The technology and patent portfolio of Liquid Light will be integrated into Avantium’s Renewable Chemistry business unit and<br />

its existing R&D program in electrochemistry. The combination of Liquid Light’s expertise in electrochemistry with Avantium’s<br />

expertise in catalysis and process engineering will be the basis of an unrivaled technology platform to develop novel production<br />

technologies for converting CO 2<br />

to chemicals and materials.<br />

The integration of the Liquid Light assets into Avantium is complete and effective immediately. Financial details of the<br />

transaction were not disclosed. KL/MT<br />

www.avantium.com<br />

Solegear acquires Lindar Bioplastic Division<br />

The Canada-based producer of plant-based plastics announced end of last year that it was acquiring 100 % of LINDAR<br />

Corporation’s bioplastic division for CAD$ 845,000, comprising 4,225,000 common shares of the Company at a deemed price<br />

of $0.20 per share.<br />

Lindar is a leading manufacturer of plastic thermoformed food packaging, trays and products for industrial OEM industries.<br />

Located in Baxter, Minnesota (USA), the company has been producing thermoformed packaging since 1993 and is a leader in<br />

packaging innovations, including single-serve and tamper evident food packaging.<br />

“Lindar was one of the early innovators to embrace the important role packaging design can play in ensuring food safety. By<br />

combining Lindar’s thermoformed packaging know-how with Solegear’s commitment to engineering plant-based materials<br />

with no BPAs or phthalates, this acquisition positions Solegear with the people, infrastructure, products and pricing to further<br />

scale our business at a faster rate.”<br />

For Lindar, the acquisition by Solegear will make it possible to create scale and engage more customers about what is<br />

possible with plant-based packaging. “Something that is much easier to achieve with Solegear than on our own,” said Tom<br />

Haglin, President of Lindar. “As Lindar’s bioplastic division becomes part of the Solegear family, Lindar will be able to capitalize<br />

on this business association by introducing new and expanded products with greater capabilities.”<br />

The purchased assets generated over CAD$1.3 million in revenue in 2<strong>01</strong>5.<br />

Revenues generated from the purchased assets are expected to be accretive to Solegear during the current fiscal year.<br />

Issuance of the Shares to LINDAR is conditional upon execution of the Outsourcing Agreement, and completion of the Asset<br />

Purchase remains subject to TSX Venture Exchange approval. The Shares will be issued from treasury and subject to a 24<br />

-month hold period from the signing date of the Outsourcing Agreement. MT<br />

www.solegear.ca<br />

6 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


News<br />

Global biodegradable market to show strong<br />

growth through 2021<br />

The bioplastics market continues to show healthy growth. Analysts from technology research company Technavio have now<br />

separately examined the biodegradable plastics market. According to their latest report, the global biodegradable polymers<br />

market can look forward to growth at a CAGR of 21.1 % over the next five years.<br />

The research study covers the present scenario and growth prospects of the global biodegradable polymers market for 2<strong>01</strong>7-<br />

2021. The study considers revenue generated from the sale of biodegradable polymers market across various geographies to<br />

determine the market size.<br />

By application, this market is segmented into food packaging, foam packaging, biodegradable bags, agriculture, and other<br />

segments. Biodegradable polymers find utility in these areas as they are great in reducing carbon footprint and providing<br />

enhanced sustainability on account of the entire process being cyclic. The global market was valued at USD 2,040.2 million in<br />

2<strong>01</strong>6 and is forecast to reach USD 5,324.4 million by 2021.<br />

Region wise, Western Europe is the market leader in the global biodegradable polymers market with a share of over<br />

41 % (2<strong>01</strong>6 figures). The high levels of consumer awareness and maturity in the region make way for easy adoption of new<br />

technologies and products, which is the main reason behind the segment’s dominance. The key products available in the<br />

Western European market are compostable biobased waste bags and loose-fill packaging materials. North America and ROW<br />

(Rest of World) follow Western Europe.<br />

Technavio analysts point to the following three factors that they say are contributing to the growth of biodegradable polymers:<br />

Eco-friendly packaging leading to enhanced customer appeal<br />

Consumers have shown a clear preference towards sustainable options for plastic bags and food packaging. The preference<br />

for sustainability in these product categories is pushing vendors to adopt greener technologies and strategies for branding and<br />

gaining a larger consumer base. Therefore, the increasing acceptance of sustainable packaging and green products among<br />

consumers is directly driving the biodegradable polymers market.<br />

Government emphasis on efficient plastic waste management<br />

Management of plastic waste is a top priority for most governments as mass consumption of products with short lifespans is<br />

increasing, leading to accumulation of an enormous amount of non-degradable waste. This waste takes up valuable real estate<br />

space and often ends up in landfills or dumping grounds that have grave environmental impacts. To curb this, governments<br />

across the globe are aiding in and pushing for the adoption of biodegradable polymers through various initiatives and reforms,<br />

thus bringing in a steady demand for these products.<br />

Emergence of biobased and renewable raw materials<br />

“The global biodegradable polymers market is driven by the emergence of renewable resources, biomass, and biobased<br />

raw materials such as starch and vegetable crop derivatives. In 2<strong>01</strong>5, biobased plastics accounted for more than 80 % of the<br />

global biodegradable polymers market. The use of bioplastics in numerous applications such as packaging and retail goods<br />

has greatly aided market growth,” says Swapnil Tejveer Sharma, one of the lead analysts at Technavio for plastics, polymers,<br />

and elastomers research. KL/MT<br />

www.technavio.com<br />

Apologies<br />

We sincerely apologize for not mentioning the authors of the article on the<br />

“Fair Mouse” in the recent new issue of bioplastics MAGAZINE. MT<br />

The authors are<br />

Jacek Leciński, Andrea Siebert-Raths<br />

Daniela Jahn and Jessica Rutz<br />

Institute for Bioplastics and Biocomposites<br />

University of Applied Sciences and Arts<br />

Hannover, Germany<br />

You can read the article online on pp 24<br />

at https://issuu.com/bioplastics/docs/bioplasticsmagazine_1606_<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 7


Events<br />

bioplastics MAGAZINE presents:<br />

The second bio!PAC conference on biobased packaging in Düsseldorf, Germany,<br />

organised by bioplastics MAGAZINE together with Green Serendipity is the<br />

must-attend conference for everyone interested in packaging made from renewable<br />

resources. The conference offers high class presentations from top<br />

individuals from raw material and packaging providers as well as from brand<br />

owners already using biobased packaging. The unique event also offers excellent<br />

networking opportunities. Free access to interpack is also included.<br />

Please find below the preliminary programme. Find more details and register<br />

at the conference website. www.bio-pac.info<br />

bio PAC<br />

biobased packaging<br />

conference<br />

4-5-6 may 2<strong>01</strong>5<br />

messe düsseldorf<br />

Preliminary Programme - bio!PAC: Conference on Biobased Packaging<br />

Other than the first edition in 2<strong>01</strong>5 in Amsterdam, this year bio!PAC will be organized within the framework of interpack, the<br />

World‘s biggest trade fair on packaging in Düsseldorf, Germany. And bio!PAC will be organized in the same way as the recent<br />

Bioplastics Business Breakfast @K 2<strong>01</strong>6.<br />

On three mornings during the show from May 4 - 6, bioplastics MAGAZINE in cooperation with Green Serendipity will host<br />

a bio!PAC Business Breakfast: From 8:00 am to 12:30 pm the delegates get the chance to listen to and discuss high-class<br />

presentations and benefit from a unique networking opportunity. The trade fair interpack opens at 10 am. Register soon to<br />

reserve your seat. Admission starts at EUR 299.00. The conference fee includes a free day-ticket for interpack as well as free<br />

public transportation in the greater Düsseldorf area (except taxi).<br />

The programme is divided into three highlight topics:<br />

• 04 May 2<strong>01</strong>7: Biobased packaging materials & possibilities<br />

• 05 May 2<strong>01</strong>7: Innovations & inspiration by brand owners<br />

• 06 May 2<strong>01</strong>7: Biobased packaging & the Bio-Economy<br />

The preliminary programme below will constantly be amended and updated on the website.<br />

Martin Bussmann, BASF<br />

Patrick Gerritsen, Bio4Pack<br />

Andy Sweetman, Futamura<br />

Emanuela Bardi, Taghleef Industrie<br />

Mariagiovanna Vetere, NatureWorks (t.b.c.)<br />

Hein van den Reek, Billerudkorsnas/Fiberform<br />

Stefan Corbus, Kuraray EVAL Europe<br />

Floris Buijzen, Corbion<br />

Marco Brons, Cumapol<br />

Remy Jongboom, Biotec<br />

Martin Clemesha, Braskem<br />

Ryuichiro Sugimoto, PTT/MCC<br />

Thijs Rodenburg, Rodenburg<br />

Jasper Gabrielse, Seepje<br />

Paul Masselink, O‘Right<br />

Marcea van Doorn, Bunzl<br />

Claudio Gemmiti, Coffee Company<br />

Hasso von Progrell, European Bioplastics (t.b.c.)<br />

Michael Carus, nova-Institute<br />

Florian Graichen, Scion<br />

Sam Deconinck, OWS (t.b.c.)<br />

Erwin Vink, Holland Bioplastics<br />

Jan-Govert van Gilst, NNRGY<br />

Green Serendipity, Caroli Buitenhuis<br />

Compostable food and transport packaging<br />

Biobased and biodegradable laminate structures<br />

State of the art Biolaminate solutions to replace conventional plastics in flexible packaging<br />

BoPLA flexible film applications in food and non-food packaging (t.b.c.)<br />

The latest INGEO packaging applications and developments (t.b.c.)<br />

Formable Paper & Pulp challenge conventional packaging<br />

Plantic Sheet: biobased, biodegradable and barrier solution for sustainable packaging<br />

PLA packaging applications and innovations<br />

Sustainable polyesters such as bio-PET<br />

Bio back to basics<br />

Packaging opportunities with Green PE (t.b.c.)<br />

Biobased and biodegradable PBS for packaging applications<br />

Development of sustainable flexible packaging based on 2 nd generation feedstock<br />

Bumpy road in search for the right sustainable packaging<br />

Tree in a bottle (t.b.c.)<br />

Connecting the sustainable dots<br />

Purpod 100 using biodegradable materials and own waste streams (t.b.c.)<br />

Facts and Myths on biobased plastics packaging(t.b.c.)<br />

biobased packaging and the bio-economy<br />

Biobased packaging - the New Zealand perspective (t.b.c.)<br />

End of life options for biobased packaging<br />

Creation of better conditions for Compostable Packaging<br />

Innovative packaging solutions with locally sourced elephantsgras<br />

Futurelook on biobased and circular packaging<br />

(subject to changes, visit www.bio-pac.info for updates)<br />

8 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


io PAC<br />

organized by bioplastics MAGAZINE<br />

biobased packaging<br />

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04-05-06 may 2<strong>01</strong>7<br />

messe düsseldorf<br />

Packaging is necessary for:<br />

» protection during transport and storage<br />

» prevention of product losses<br />

» increasing shelf life<br />

» sharing product information and marketing<br />

BUT:<br />

Packaging does not necessarily need to be made from petroleum<br />

based plastics. Most packaging have a short life and therefore<br />

give rise to<br />

large quantities of waste. Accordingly, it is vital to use the most<br />

suitable<br />

raw materials and implement good ‘end-of-life’ solutions.<br />

Biobased materials have a key role to play in this respect.<br />

Gold Sponsor<br />

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» is packaging made from mother nature‘s gifts.<br />

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» can help to reduce the depletion of finite fossil resources and<br />

CO 2<br />

emissions<br />

» can offer environmental benefits in the end-of-life phase<br />

» offers incredible opportunities<br />

www.bio-pac.info<br />

Early Bird Discount<br />

in cooperation with<br />

Save 15% on regular prices<br />

before February 28, 2<strong>01</strong>7<br />

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supported by<br />

Media Partner


Automotive Materials<br />

Biobased engineering plastic<br />

for Mazda’s Roadstar RF<br />

DURABIO, developed by Mitsubishi Chemical Corporation<br />

(MCC), is a biobased engineering plastic made from plantderived<br />

isosorbide. It features excellent performance, offering<br />

higher resistance to impact, heat, and weather than conventional<br />

engineering plastics. Additional benefits include ease of<br />

coloring – Durabio can be simply mixed with pigment to create<br />

glossy, highly reflective, and rich hue surfaces – as well its hardness,<br />

enhancing durability and scratch resistance. These advantages<br />

eliminate the need for a coating process, thereby reducing<br />

emissions of volatile organic compounds (VOCs) from paints.<br />

MCC and Mazda jointly developed a new grade of Durabio that can<br />

be used for exterior design parts without coating. The new grade has<br />

been used for interior and exterior design parts of Mazda’s CX-9,<br />

Axela, and Demio since 2<strong>01</strong>5, when it was first adopted for<br />

the Roadstar launched in the same year. The Roadstar<br />

RF is the fifth model to use Durabio, and the new grade<br />

will be adopted for more models.<br />

Example of adoption:<br />

Roadstar (top),<br />

Axela (bottom)<br />

Photos by Mazda<br />

MCC will accelerate research and development of<br />

Durabio, with the goal of expanding applications for<br />

automobile interior design parts, of course, but also<br />

expansion of its use in exterior design parts, contributing<br />

to environment-friendly automobile production. MT<br />

www.mcpp-europe.com<br />

Focus: ++ Bio-based Building Blocks & Platform Chemicals ++ Oleochemistry ++ Innovation Award ++ Start-ups ++<br />

HIGHLIGHTS OF THE WORLDWIDE BIOECONOMY<br />

• Policy and Markets<br />

• Standardisation, Labelling and Certifications<br />

• Innovation Award “Bio-based Material of the Year 2<strong>01</strong>7”<br />

• Bio-based Building Blocks and Platform Chemicals<br />

• Oleochemicals and Bio-based Polymers<br />

• Start-Ups<br />

Organiser<br />

News<br />

Start-ups are invited to apply<br />

for the exciting Start-up<br />

Session!<br />

The 10 th International Conference on Bio-based Materials is aimed at<br />

providing international major players from the bio-based building blocks,<br />

polymers and industrial biotechnology industries with an opportunity<br />

to present and discuss their latest developments and strategies. The<br />

conference builds on successful previous conferences: 300 participants<br />

and 30 exhibitors mainly from industry are expected.<br />

www.nova-institute.eu<br />

Contact<br />

Dominik Vogt<br />

Conference Manager<br />

+49 (0)2233 4814-49<br />

dominik.vogt@nova-institut.de<br />

Find more information at:<br />

www.bio-based-conference.com<br />

10 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


Automotive<br />

Panels for trucks and buses<br />

New biodegradable and flame-retardant panels for trucks and buses<br />

from wastes from the paper industry<br />

AIMPLAS (Valencia, Spain), the Plastics Technology<br />

Centre, has finished the European project BRIGIT<br />

after 48 months of research. In the project, 15 partners<br />

including the University of Cantabria and the Spanish<br />

company Green Source S.A. Thanks to these researches, it<br />

has been obtained a new generation of fire resistant panels<br />

for trucks and buses manufactured from biopolymers from<br />

by-products from the cellulose paste manufacturing for the<br />

paper industry.<br />

The project BRIGIT (EU Seventh Framework Programme)<br />

began in August 2<strong>01</strong>2. During its performance, different<br />

subjects have been tackled, from the obtaining of<br />

biopolymers, their formulation and modification to improve<br />

the fire behaviour to the processing of the resulting<br />

biocomposites for panel manufacturing, which were<br />

installed inside trucks and buses from Solaris and Fiat.<br />

Moreover, the economic and environmental viability of the<br />

new products has been validated.<br />

High added value for the wastes from the<br />

cellulose manufacturing<br />

In order to get these innovative panels, the partners of<br />

the project developed a new process to obtain bioplastics, in<br />

particular PHB (polyhydroxybutyrate) and PBS (polybutylene<br />

succinate), more ecologic than the existing ones. They are<br />

obtained from by-products from the cellulose production.<br />

As the main project researcher, Miguel Ángel Valera, says<br />

“the use of by-products from the cellulose manufacturing<br />

process as source of sugars needed to carry out the<br />

fermentation process of the microorganisms producing PHB<br />

and succinate acid, it allows an integration of the processes<br />

needed to obtain the biopolymers used in BRIGIT, therefore<br />

we get a saving in manufacturing costs.”<br />

More recyclable and eco-friendly vehicles<br />

By means of compounding techniques, AIMPLAS mixed<br />

and modified both biopolymers to obtain a biocomposite with<br />

strict requirements. Firstly, it is a processable material by<br />

means of extrusion, with the mechanical and fire resistance<br />

that the transports industry demands, but with the advantage<br />

of being fully biodegradable and also compostable after its<br />

grinding, in contrast with the thermosetting resins currently<br />

used.<br />

Secondly, by means of continuous compression moulding<br />

the multilayer panels formed by biocomposite sheets and<br />

natural fibres (replacing the usual glass fibre) and a light<br />

cork core inside have been manufactured. In addition to<br />

be installed inside trucks and buses as columns and side<br />

panels, these 3D panels could be also used in trains, ships,<br />

vans and other means of transport of goods and people. MT<br />

www.aimplas.net<br />

Solaris Urbino<br />

Magnetic<br />

for Plastics<br />

www.plasticker.com<br />

• International Trade<br />

in Raw Materials, Machinery & Products Free of Charge.<br />

• Daily News<br />

from the Industrial Sector and the Plastics Markets.<br />

• Current Market Prices<br />

for Plastics.<br />

• Buyer’s Guide<br />

for Plastics & Additives, Machinery & Equipment, Subcontractors<br />

and Services.<br />

• Job Market<br />

for Specialists and Executive Staff in the Plastics Industry.<br />

Up-to-date • Fast • Professional<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 11


Automotive Materials<br />

The ABT plant has been operating since 2<strong>01</strong>2 with a capacity of 100,000 tonnes per year.<br />

Biobased materials derived from plant residues are<br />

opening up exciting opportunities for environmentally-responsible<br />

products. As trendsetters like biobased<br />

epichlorohydrin (ECH), bio-succinic acid and lignin continue<br />

to offer more sustainable alternatives for traditional chemicals,<br />

it is increasingly important that the materials are<br />

sourced responsibly.<br />

Epicerol ® is an ECH based on 100 % renewable glycerine,<br />

a by-product from the transformation of vegetable oils.<br />

Manufactured by Advanced Biochemical Thailand Co., Ltd.<br />

(ABT) using an innovative process developed by Solvay, the<br />

drop-in was developed and commercialised because of<br />

demand for a truly sustainable ECH.<br />

A comparative Life Cycle Analysis (LCA) benchmarked<br />

Epicerol against state-of-the-art propylene-based<br />

processes from cradle-to-gate. It showed that incorporating<br />

one tonne of Epicerol can reduce a product’s carbon footprint<br />

by 2.56 tonnes CO 2<br />

equivalent, which corresponds to a<br />

61 % reduction of the Global Warming Potential (the sum<br />

of GHG emissions and biogenic CO 2<br />

capture). Epicerol also<br />

benefits from a 57 % reduction of non-renewable energy<br />

consumption.<br />

The technology reduces the volume of chlorinated byproducts<br />

from production by over 80 %, while another<br />

distinctive technology enables brine recycling and drastically<br />

reduces liquid effluents.<br />

Epicerol has recently received awards for its environmental<br />

profile. The Institution of Chemical Engineers (IChemE) and<br />

the JEC Company have both commended it, in 2<strong>01</strong>6 and<br />

2<strong>01</strong>5 respectively.<br />

Because the glycerine for the process is a by-product from<br />

biodiesel and oleochemicals production, it brings added<br />

value to a material which might otherwise go to waste and<br />

contributes by supporting smallholders. To this end, ABT<br />

works with the Roundtable on Sustainable Biomaterials<br />

(RSB) to manage the impact of its raw materials.<br />

In 2<strong>01</strong>5, ABT became the first biobased chemical operator<br />

in Asia to obtain certification from RSB. To further show its<br />

commitment, ABT joined UN agencies and influential NGOs<br />

in becoming a full member of RSB as well. Members are<br />

experts in rural development, food security, environmental<br />

conservation and industry.<br />

ABT sources it vegetable glycerine from suppliers which<br />

are certified and have a number of their own sustainability<br />

measures in place throughout the value chain. These<br />

include mills that fuel boilers with waste and generate<br />

electricity from captured methane.<br />

Epicerol continues to demonstrate its value as a<br />

commercially-proven drop-in. As with traditional ECH, it is<br />

a chemical used for a wide range of industries, including<br />

the production of epoxy resins for coatings, advanced<br />

composite materials and electronic components. It is also<br />

used in the production of lens monomers for eyewear and<br />

synthetic rubbers for the automotive and printing sectors.<br />

Supplied in industrial quantities to major producers<br />

worldwide, Epicerol continues to be demonstrated as the<br />

most sustainable ECH in terms of carbon footprint and<br />

process environmental performance.<br />

www.solvay.com<br />

12 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


Automotive<br />

Responsible sourcing<br />

of biomaterials for<br />

epichlorohydrin<br />

By:<br />

Thibaud Caulier<br />

Epicerol Business Manager<br />

Solvay Epicerol<br />

Brussels, Belgium<br />

Biobased ECH is used for a wide range of industries.<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 13


Automotive Materials<br />

Biobased materials – The future<br />

In December 2009, aiming to develop its expertise into a<br />

sustainable competitive advantage and thus to contribute<br />

to the profitability of the company and enhance customer<br />

satisfaction, Renault established a cross-functional<br />

field dedicated to expertise. One of the strategic areas of<br />

expertise identified was “Polymers, Characterization &<br />

Processes of Transformation”, led by Dr. Liraut.<br />

Renault’s Polymer materials strategy is focused on<br />

providing sustainable mobility for all.<br />

As illustrated in Fig. 1, this strategy is built on 4 axes:<br />

• increase customer value<br />

• improve durability<br />

• reduce costs<br />

• reduce environmental footprint<br />

Biobased materials are one pillar to support this<br />

strategy.<br />

Customer Value<br />

• Decorations (metal, painting, grains)<br />

• Skin TPO, Slush, Leather<br />

• Thermal Comfort<br />

• Light atmosphere<br />

Durability<br />

• Anti scratch<br />

• Anti durst<br />

• UV protection<br />

Reduction of environmental footprint<br />

Since 2005, Renault has been committed to reducing the<br />

environmental impact of its vehicles throughout their lifecycle,<br />

from one generation to the next. In order to ensure<br />

and monitor compliance with this commitment, Renault has<br />

measured the environmental impact of its vehicles throughout<br />

their life-cycle, from the extraction of the raw materials needed<br />

for manufacturing to their end of life, since 2004. Life-cycle<br />

analyses (LCA) are carried out in compliance with international<br />

standards on LCA (ISO 14040 and 14044).<br />

Cost<br />

• Alliance Specifications<br />

• Panel of Materials<br />

• Local Integration<br />

Fig 1: strategy built on 4 axes<br />

Environmental Footprint<br />

• Weight reduction<br />

• Recycled materials<br />

• Biobased materials<br />

• Recycling in existing fields<br />

The results of the life-cycle assessments show that usephase<br />

vehicle emissions account for more than 80 % of the<br />

CO 2<br />

and for most atmospheric pollutants emitted over the life<br />

cycle of an ICE vehicle.<br />

By curbing emissions during the use phase, therefore,<br />

Renault can significantly reduce the environmental footprint of<br />

its vehicles. Improving vehicle fuel efficiency is a crucial part<br />

of this.<br />

A potent lever for better fuel economy is weight reduction.<br />

For example, calculations have shown that reducing vehicle<br />

weight by 10kg cuts CO 2<br />

emissions by 1g/km.<br />

Use of PE+natural fibers<br />

New Megane’s dashboard insert in NAFilean -<br />

APM by the end of 2<strong>01</strong>6<br />

1.270 kg saving<br />

with an additional<br />

cost of € 2.50<br />

per saved kg<br />

The choice of materials impacts directly on vehicle weight.<br />

To reduce weight, all families of materials must be taken<br />

into account: steels with high elasticity; light alloys, such as<br />

aluminum; composites; and plastics.<br />

Renault has taken steps to address this concern, starting in<br />

2<strong>01</strong>6 with the use of PE filled with natural fibers (PE-NF) instead<br />

of talc or glass fibers, in semi-structural parts requiring a high<br />

rigidity, low impact resistance and a good thermal resistance.<br />

The use of PE-NF yields a weight saving of between 6 % and 20 %,<br />

thanks to a reduction of the thicknesses of the parts.<br />

In the new Megane, the use of Nafilean , a natural fiber<br />

composite produced by APM - Automotive Performance<br />

Materials (PE-Hemp 20 %), for a dashboard insert has enabled<br />

a weight reduction of 1.27 kg at an additional cost of 2.5 € per<br />

saved kg.<br />

Studies of other natural fibers, such as Miscanthus or<br />

Woodforce, are still in progress.<br />

The use of these specific biobased materials is also considered<br />

in the light of the end of life perspective. Their recycling process<br />

is taken into account.<br />

14 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


Automotive<br />

for the automotive industry?<br />

Improvement of durability<br />

As an example of a biobased material application to<br />

improve durability, Renault has adopted PA 6.10 and 10.10 for<br />

several under-the-hood parts, such as for the pipes of fuel<br />

supply system or brake system. These Bio-PA grades offer<br />

a good balance between technical and economic benefits, as<br />

well as very good chemical resistance, particularly in a fuel<br />

environment.<br />

Use of PA11, then PA 6.10 or PA 10.10<br />

• Technical and economic interest<br />

• Very good chemical resistance<br />

Under-the-hood parts<br />

Fuel pipe of<br />

fuel supply system<br />

or brake system<br />

Reduction of cost<br />

A good example to illustrate how using a biobased<br />

material can also lead to cost savings is Renault’s use of<br />

Mitsubishi Chemical Corporation’s DURABIO . Durabio is<br />

a biobased engineering plastic made from plant-derived<br />

isosorbide. It combines an excellent performance - offering<br />

a better compromise between resistance to impact, heat,<br />

and light ageing than conventional engineering plastics -<br />

with additional benefits, including high reflective surfaces,<br />

hardness, enhanced durability and scratch resistance.<br />

Renault has adopted MCC’s Durabio biobased engineering<br />

plastic for the outer mask of the speedometer-tachometer<br />

combo in the new generation of its Clio cars. It was introduced<br />

on June 6, 2<strong>01</strong>6.<br />

Using Durabio means that no coating process is required,<br />

which represents a cost saving of 0.40 € per part.<br />

This marks the first use of Durabio by a European automaker<br />

(MCC’s press release, August 2 nd , 2<strong>01</strong>6)<br />

Increase of customer value<br />

Renault is striving to enhance the perceived quality of its<br />

new vehicles, was another factor driving the carmaker’s<br />

research into the use of biobased material. Renault is<br />

currently looking closely at biobased materials that could<br />

provide a aesthetics effect and / or an innovative touch<br />

and feel.<br />

For Renault, the use of biobased materials is closely<br />

linked to its polymers strategy. In this context, the<br />

company is not interested in drop-In biobased solutions<br />

to replace conventional plastics. New materials must<br />

provide additional benefits according to the main axes of<br />

the polymers strategy: durability, customer value, cost,<br />

and environment.<br />

The materials engineering department and<br />

biomaterials specialist need to follow up new innovative<br />

development of biobased material. To that end, the<br />

materials engineering department at Renault joined the<br />

Industry and Agro-resource (IAR) Cluster in November<br />

2<strong>01</strong>6, which promotes exchanges and project launches.<br />

The IAR Cluster enables the development and testing<br />

of new technologies and products, based on a renewable<br />

approach. It therefore fosters the emergence of new<br />

markets and boosts companies’ competitiveness in the<br />

area of agro-resources.<br />

Under investigation<br />

• Specific aspect and touch feeling<br />

• Acoustic / thermal comfort<br />

Natural fibres, wood<br />

painting<br />

relatd products of other industries<br />

Use of DURABIO - Mitsubishi Chemical<br />

instead of ABS or ABS-PC + painting<br />

• Avoid the need of painting for durability<br />

• Very good micro scratch & impact resistance<br />

New Clio’s outer-mask<br />

Cost savings: 0.40 € per part<br />

Better high gloss surface<br />

Ecological design<br />

visible by customer<br />

By:<br />

Alexia Delsalle-Roma<br />

Biomaterials Specialist - Materials Innovation Leader<br />

Renault Group<br />

Guyancourt, France<br />

www.renault.com<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 15


Automotive Materials<br />

New ABS reinforced with<br />

natural fibres<br />

ELIX ABS-NF, an innovative material development from<br />

ELIX Polymers, is a wood-fibre reinforced ABS that was<br />

created as part of the company’s strategy to move towards<br />

a more sustainable product portfolio. Elix Polymers<br />

is a leading manufacturer of ABS (Acrylonitrile-Butadiene-<br />

Styrene) resins and derivatives in Europe, headquartered in<br />

Tarragona, Spain<br />

Suitable for injection moulding applications, Elix ABS-NF<br />

offers excellent flowability, making fast and efficient mould<br />

filling possible. Even very thin walls can be produced easily.<br />

Moreover, fibre degradation levels are very low, despite shear<br />

heating.<br />

The selected wood fibre is a certified 100 % biobased<br />

product, non-seasonal and a by-product from an industrial<br />

process with consistent quality performance from batch-tobatch.<br />

Because the new material is based on ABS, it has generated<br />

a great deal of interest, especially from the automotive<br />

industry as, until now, polypropylene (PP) has been the most<br />

commonly used resin reinforced with natural fibres. The<br />

target applications for Elix ABS-NF are visible interior parts<br />

and semi-structural interior parts.<br />

For visible parts, the wood-like appearance offers interesting<br />

options, while when coloured, the material opens up new<br />

design possibilities with different surface textures. Possible<br />

applications are door trim panels and audio speaker covers.<br />

OEMs are looking at surface finishes of this kind especially<br />

for new electric cars; Elix Polymers is already working closely<br />

with the design departments of several automotive OEMs.<br />

For semi-structural parts, such as the center console<br />

carrier, ABS-NF can replace the glass-reinforced ABS that<br />

is currently used by some OEMs for these applications.<br />

ABS-NF’s improved stiffness means that the mechanical<br />

properties of the two materials are very similar. However,<br />

Elix’s ABS-NF boasts a density of only 1.12 g/cm³ , compared<br />

to 1.15 for conventional glass-fibre reinforced ABS, which<br />

translates to a 3 % weight reduction when opting for the new<br />

material. ABS-NF is more easily recycled than ABS-GF, yet<br />

retains its properties better than glass-filled ABS after several<br />

processing cycles, thanks to the lower fibre size reduction.<br />

Compared to other polymers reinforced with natural fibres<br />

Elix ABS-NF has a high heat stability Vicat B50 with over<br />

100 °C and a much better surface quality. Furthermore, the<br />

emissions are very low according to test results VDA 278 VOC<br />

= 2 / FOG = 45 μg/g (ppm), which meets the stringent OEM<br />

requirements.<br />

Having successfully caught the interest of the main<br />

automotive OEM’s with the new ABS-NF, Elix says that<br />

already,several tests are now running at interior Tier1<br />

suppliers and institutes for bioplastics. Driven by consumer<br />

demand for more sustainable products and the desire to<br />

reduce dependency on fossil resources, many other sectors<br />

have also expressed interest in this product, including the<br />

furniture industry, consumer goods, toys and the white goods<br />

industry.<br />

Elix Polymers was awarded the Frost&Sullivan new product<br />

innovation award for Automotive natural fibre composites for<br />

the development of this innovative product. The development<br />

of Elix ABS-NF was facilitated by the European Economic Area<br />

(EEA) and Norway Grants which is the first time in the industry<br />

where a company was supported by a European Grant towards<br />

developing sustainable ABS materials and composites.<br />

Through this, Elix Polymers has not only positioned itself<br />

as a leading supplier of eco-friendly ABS materials, but has<br />

also extended its commitment to develop an environmentally<br />

sustainable product portfolio. Elix Polymers holds a superior<br />

position in sustainability by ensuring an 8.8 % reduction in<br />

energy intensity and 2.56 % reduction in carbon footprint in<br />

manufacturing processes, both from 2<strong>01</strong>4 to 2<strong>01</strong>5. MT<br />

www.elix-polymers.com<br />

16 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


Automotive<br />

bio CAR<br />

organized by bioplastics MAGAZINE<br />

CALL FOR PAPERS<br />

NOW OPEN<br />

biobased materials for<br />

automotive applications<br />

conference<br />

September 2<strong>01</strong>7<br />

Stuttgart<br />

» The amount of plastics in modern cars is constantly increasing.<br />

» Plastics and composites help achieving light-weighting targets.<br />

» Plastics offer enormous design opportunities.<br />

» Plastics are important for the touch-and-feel and the safety of cars.<br />

ANZEIGE<br />

BUT:<br />

consumers, suppliers in the automotive industry and OEMs are more and more looking for biobased<br />

alternatives to petroleum based materials.<br />

That‘s why bioplastics MAGAZINE is organizing this new conference on biobased materials for<br />

the automotive industry.<br />

co-orgnized by<br />

in cooperation with<br />

www.bio-car.info<br />

supported by<br />

Media Partner


Automotive Materials<br />

By:<br />

Erico Spini<br />

Marketing and Application Development Director Europe<br />

Radici Group Performance Plastics<br />

Chignlo d’Isola (BG), Italy<br />

New automotive<br />

applications<br />

for bio-PA<br />

Air brake pipes and tank breather hose<br />

made of biobased PA 6.10<br />

Fig 1: Extruded air pipe made of Radilon D<br />

40EP25ZW 333 BK for the pneumatic braking system<br />

of a truck (photo: RadiciGroup)<br />

Fig 2: Extruded heat and media-resistant car tank<br />

breather hose (blue) made of partially biobased<br />

PA6.10, in assembled state (photo: RadiciGroup)<br />

A more comprehensive version of this article was<br />

previously published in KUNSTSTOFFE 8/2<strong>01</strong>6<br />

and can be found here<br />

http://tinyurl.com/naturally-effective<br />

In numerous areas of application, materials based on renewable<br />

resources can already replace plastics based on fossil raw materials<br />

and thus contribute to the more sustainable handling of<br />

resources. RadiciGroup Performance Plastics (Chignolo d’Isola,<br />

Italy), has commercialized a range of partially biobased PA 6.10<br />

types that are suitable for a wide variety of applications in many<br />

areas of industry. The examples selected here are an air brake<br />

pipe for trucks (Fig. 1) and a tank breather hose for passenger<br />

cars (Fig. 2) from Fiat Chrysler Automobile (FCA), (Orbassano, Italy).<br />

Both applications pose particularly high demands on material<br />

testing and approval procedures.<br />

Polyamide from renewable raw materials<br />

PA 6.10 is a partly biobased Polyamide made of petroleum based<br />

hexamethylene diamine and around 64 % biobased sebacic acid.<br />

Sebacic acid is obtained from the beans of the castor oil plant<br />

which is cultivated above all in India and China. Since it grows<br />

primarily on dry soil, it does not compete for the production of<br />

foodstuffs.<br />

Properties<br />

PA6.10 is a semi-crystalline polymer, available as both an<br />

injection molding grade and an extrusion grade. Furthermore,<br />

fillers, stabilizers and additives can be incorporated to finetune<br />

specific properties for a particular application. Among its<br />

outstanding characteristics are low water absorption, high heat<br />

resistance, very good chemical resistance and good mechanical<br />

properties. The water absorption of test bars according to ISO 62 on<br />

exposure to a standard climate (23 °C, 50 % relative humidity) and<br />

on immersion in water is shown in Figure 3. The water absorption<br />

on immersion is around a third of the value obtained with PA6<br />

and PA6.6. At 50 % relative humidity, the moisture absorption is<br />

somewhere between the values for PA6.6 and PA12. The biobased<br />

PA6.10 is thus suitable for most applications that call for good<br />

dimensional stability in moist environments.<br />

The melt and heat deflection temperature (HDT B) are in the<br />

range of PA6, but significantly higher than PA11 and PA12 (Fig.4).<br />

This is particularly important if the material is to be used as a<br />

substitute for PA11 and PA12, for example for applications in which<br />

the temperatures exceed those tolerated by PA12, as is the case with<br />

many diesel fuel lines in new cars. Furthermore, the polymer has<br />

very good chemical resistance (also in the presence of salts such<br />

as zinc chloride and calcium chloride), high hydrolysis resistance<br />

and, compared with PA6 and PA6.6, undergoes smaller changes in<br />

the mechanical properties after the absorption of moisture.<br />

18 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


Automotive<br />

Pneumatic brake lines<br />

For pneumatic brake systems air pipes, RadiciGroup has<br />

developed the extrusion grade Radilon D 40EP25ZW 333 BK<br />

(Fig. 1). The material has particularly high flexibility in order to<br />

facilitate installation of the pipes, which, especially with trucks,<br />

can reach a considerable length. Furthermore, it is heat-stabilized,<br />

which means that components made from it can be exposed to<br />

high temperatures even over a prolonged period.<br />

Based on the burst pressure curve up to a temperature of<br />

125 °C, the material is suitable according to ISO 7628 for lines at a<br />

nominal pressure of up to 10 bar and up to 12.5 bar. Figure 5 shows<br />

the burst pressure after the contact with media that trigger stress<br />

cracking, and after aging in artificial light. The corrosive solution<br />

is made up of 50 % water, copper chloride, sodium chloride,<br />

potassium chloride and zinc chloride. For aging in artificial light,<br />

the pipe was irradiated with xenon lamps for 750 h at 65°C. In this<br />

case, too, the burst pressure must be at least 80 % of the original<br />

value.<br />

Tank breather hoses<br />

As part of a joint project with FCA, RadiciGroup has developed<br />

a material that has similar properties to the material described<br />

above. At the request of the customer, the material is colored<br />

blue and is used for the production of tank breather hoses for<br />

cars (Fig. 2). Such parts are conventionally made of an impactmodified<br />

PA12 incorporating a plasticizer.<br />

During development of the material, particular attention was<br />

placed on the ease of processing via extrusion. Here, low part<br />

tolerances are essential. The corrugated tubes must, especially<br />

in the corrugated areas, comply with strict measuring tolerances<br />

as too thin areas in the wall can lead to failure of the component<br />

during operation.<br />

The part was subjected to a number of tests to determine its<br />

suitability for practical application. The component passed for<br />

example a pressure test at 2.5 bar before and after thermal aging<br />

at 90 °C for 168 h. The specimen also successfully passed the<br />

cold impact strength test using a free falling dart (2 kg weight,<br />

diameter of the hemispherical ended portion of the dart:10 mm)<br />

when dropped from a height of 400 mm and 500 mm after storage<br />

at -40 °C for 4 h. These tests were performed both on fresh new<br />

parts and on others that had been aged in hot air at 90 °C for<br />

168 h. Furthermore, a pull-off test was carried out on the hose<br />

and/ or connections both when new and after aging in fuel vapors<br />

at 60 °C over a period of 168 h. Subsequently, the specimen was<br />

bent by 180 °C in a radius corresponding to five times the outer<br />

diameter of the hose. After this, there was no visible damage, not<br />

even at the fixing points for the connections.<br />

Conclusions<br />

The example of PA6.10 shows that engineering plastics based to<br />

a large extent on renewable raw materials can replace materials<br />

of fossil origin even in technical parts. Specific formulations<br />

geared to the respective application help to meet or even exceed<br />

the requirements for the approval of critical components such as<br />

pneumatic brake pipes and tank breather hoses. Potential new<br />

applications are currently emerging through the demand for<br />

ever higher operating temperatures. Because of its high thermal<br />

resistance compared with materials used until now, additional<br />

possible applications in vehicle fuel systems could thus emerge<br />

for PA6.10.<br />

%<br />

10<br />

9<br />

8<br />

7<br />

6<br />

5<br />

4<br />

3<br />

2<br />

1<br />

0<br />

PA6 PA 6.6 PA6.12 PA6.10 PA12 PA11 PPA<br />

Moisture Absorption<br />

Water Absorption<br />

Fig. 3: PA6.10 has, at 50% relative humidity, a much lower<br />

water absorption than PA6 and PA6.6 and is approximately<br />

the same as PA12 following water immersion<br />

(source: RadiciGroup)<br />

°C<br />

300<br />

250<br />

200<br />

150<br />

100<br />

50<br />

0<br />

PA6 PA 6.6 PA6.12 PA6.10 PA12 PA11<br />

HDT B value (at 0,45 MPa)<br />

Melting temperature<br />

Fig. 4: With PA6.10, the heat deflection temperature and<br />

melt temperature are in the range of PA6 and significantly<br />

higher than PA11 and PA12 (source: RadiciGroup)<br />

bar<br />

80<br />

70<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

0<br />

60<br />

Burst pressure after stress cracking<br />

Minimum 40 bar<br />

for tubes with nominal<br />

pressure of 12.5 bar<br />

Minimum 32 bar<br />

for tubes with nominal<br />

pressure of 10.0 bar<br />

69<br />

Burst pressure after aging in artificial light<br />

Fig. 5: Burst pressure after exposure to media that trigger<br />

stress cracking, and after aging in artificial light (source:<br />

RadiciGroup)<br />

www.radicigroup.com<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 19


Material-News<br />

New biodegradable plastic<br />

for horticultural applications<br />

Green Dot Bioplastics (Cottonwood Falls, Kansas, USA) has developed a new biodegradable biocomposite for horticultural<br />

applications made from reclaimed biobased feedstocks.<br />

What is more symbolic of sustainability than nurturing a healthy garden? Greenhouses and gardeners can now lessen the<br />

environmental impact of plastic pots with a new high-performing biodegradable plastic from Green Dot Bioplastics.<br />

Made from 80 % reclaimed and 80 % biobased material, Terratek ® BD2114 from Green Dot Bioplastics is a renewable and<br />

biodegradable alternative to traditional plastic pots. Reclaimed plant fibers serve as a visual reminder that this planter will safely<br />

return to nature once its useful life has ended. Biodegradation rates will vary according to environment and part size.<br />

Using biodegradable plantable pots made with Terratek BD2114 can reduce greenhouse water consumption by more than 80 %.<br />

Current compostable planters are most often made from paper, peat or cardboard. These absorbent materials allow water to quickly<br />

evaporate from potting soil, requiring growers to water plants more often. Terratek BD2114 does not absorb water, retaining moisture<br />

in the potting soil.<br />

Plantable pots made with Terratek BD2114 also provide advantages for retailers. The biocomposite plastic is more durable and has<br />

a longer shelf life compared to traditional biodegradable pots. The plastic can be easily colored to enhance product differentiation.<br />

Green Dot Bioplastics CEO, Mark Remmert explained, “Our new Terratek biodegradable biocomposite offers unique functional and<br />

aesthetic attributes with a lighter environmental footprint compared to horticulture containers currently in use.”<br />

Terratek BD2114 from Green Dot is an ideal material to make plantable pots or tree and shrub containers more sustainable. The<br />

company can provide custom formulations of biobased and biodegradable materials to fit all types of horticultural applications. MT<br />

www.GreenDotBioplastics.com<br />

AVALON Industries takes over all biobased<br />

chemistry activities from AVA-CO2<br />

AVALON Industries AG, the new entity of Swiss-based company AVA-CO2 Schweiz AG, announced in mid-December it is<br />

taking over all biobased chemistry activities from AVA-CO2 with immediate effect.<br />

In response to rapid application developments relating to biobased chemical 5-Hydroxymethylfurfural (5-HMF) and following<br />

increased 5-HMF demand from value chain partners, Avalon Industries was created to take advantage of new market<br />

opportunities and to prepare for future large-scale production in order to meet the huge demand of the rapidly growing market<br />

for biobased chemicals – specifically in the areas of bioplastics as well as biobased resins and adhesives. A subsidiary of AVA-<br />

CO2, Avalon Industries is taking over all operational activities from AVA-CO2 and will focus on the global implementation of<br />

the Hydrothermal Processing (HTP) technology for the industrial-scale production of 5-HMF. This technology was successfully<br />

developed and patented by AVA-CO2 over the last seven years.<br />

AVA Biochem BSL AG, the operator of the ‘Biochem-1’ production plant in Muttenz, Switzerland, becomes an Avalon Industries<br />

subsidiary and will continue to focus on 5-HMF production for the fine chemicals market. With this Avalon Industries is now<br />

taking control of the existing 5-HMF production capacity, as well as the expertise and know-how related to the proprietary HTP<br />

technology. In this constellation, Avalon Industries is fully equipped for the future successful, commercial, industrial-scale<br />

implementation of 5-HMF production.<br />

“We are excited about this new development, which brings us closer towards the large-scale commercialisation of 5-HMF<br />

and its downstream applications such as 2,5-Furandicarboxylic acid (FDCA), Polyethylene Furanoate (PEF) as well as non-toxic,<br />

biobased resins and adhesives,” a spokesperson of Avalon mentioned in a press release. MT<br />

www.avalon-industries.com<br />

20 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


Material-News<br />

Material-News<br />

CO 2<br />

Cyanobacteria<br />

technology now<br />

suitable for PLA<br />

Photanol (Amsterdam, The Netherlands) is a<br />

platform renewable chemicals company that utilises<br />

proprietary engineered cyanobacteria to process carbon<br />

dioxide and sunlight into valuable chemical products.<br />

Photanol’s technology and patents are based on the<br />

genetic modification of cyanobacteria to produce a<br />

broad range of biochemicals. These bacteria are natural<br />

photosynthesizers, drawing energy from abundant and<br />

free sunlight on one hand, and carbon from abundant and<br />

problematic CO 2<br />

on the other.<br />

Biobased chemicals have faced challenges in continued<br />

penetration of the global market, relating to low fossil<br />

fuel prices, land/food discussions and major supply<br />

chain constraints. Cyanobacteria offer a much simpler,<br />

renewable pathway for chemical production and have<br />

the potential to emerge as the sustainable production<br />

platform for next-generation clean chemicals.<br />

Already suitable to produce over 15 chemical<br />

compounds, Photanol has now developed a pathway<br />

to produce Lactic Acid using their CO 2<br />

cyanobacteria<br />

photosynthesis technology which makes it possible to<br />

produce PLA bioplastics with many intrinsic advantages<br />

over feed stocks that are currently in use.<br />

Firstly, Photanol doesn’t require the use of arable land<br />

as the photobioreactor can be placed on waste land or<br />

deserts and is therefore non food-competing. The only<br />

thing needed is sufficient sunlight. Secondly, it absorbs<br />

CO 2<br />

which will not only provide an ecological benefit, it<br />

also creates potential value in terms of carbon credits. In<br />

addition, there will be no feedstock volatility and Photanol’s<br />

technology will be cost competitive with today’s feedstock.<br />

Having finalised the pilot stage, Photanol is preparing the<br />

construction and operation of a 20 tonnes Photobioreactor<br />

Demonstration Plant. Photanol is currently in discussion<br />

with parties in the biochemical and bioplastics industry<br />

and welcomes other value chain parties to join the<br />

Photanol consortium. MT<br />

www.photanol.com<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 21


Report<br />

By:<br />

Sam Deconinck, Marketing & Sales Manager<br />

Bruno De Wilde, Lab Manager<br />

OWS<br />

Gent, Belgium<br />

25 years of<br />

bioplastics<br />

degradation<br />

testing<br />

A journey<br />

Inside (early days)<br />

OWS (Organic Waste Systems) is one of the world’s leading<br />

experts in biodegradability, compostability and ecotoxicity<br />

testing of different types of materials, including<br />

bioplastics. The Belgium-based company, with some 80<br />

employees and various laboratories, is housed in a beautifully<br />

restored building in the old harbour of Gent. The journey<br />

started in 1990 - right around the time when the first modern<br />

bioplastics entered the market.<br />

Slow but steady start<br />

Novon Polymers, Procter & Gamble and Novamont were<br />

OWS’s very first customers. Testing was performed at two<br />

laboratories compliant with the principles of Good Laboratory<br />

Practice (GLP), one at the head office in Gent, Belgium, the<br />

other located in Dayton, Ohio in the United States.<br />

As a result, OWS became one of the pioneers of the<br />

bioplastics industry. The company’s intensive participation in a<br />

number of standardization organizations, both at the national<br />

(ASTM and DIN) and international (CEN and ISO) level, led<br />

to the co-development over the past 25 years of several test<br />

methods and standard specifications on biodegradability<br />

and compostability. This resulted, among other things, in<br />

the publication of ISO 14855 and ISO 16929: test methods to<br />

determine the biodegradation and disintegration respectively<br />

under industrial composting conditions.<br />

Outside (today)<br />

Even though no specific standard specification on industrial<br />

compostability had yet been finalized at the time, Vinçotte,<br />

the Belgium-based certification institute, had already<br />

certified the first compostable material in 1995 under their<br />

OK Compost certification program. Two years later, European<br />

Bioplastics (then IBAW) and DIN CERTCO jointly introduced<br />

the Seedling logo. The Biodegradable Plastics Institute<br />

(BPI), the US counterpart of Vinçotte and DIN CERTCO,<br />

introduced its logo in 1999. Certification bureaus in Japan,<br />

Australia, Korea, Canada, etc. soon followed suit; OWS has<br />

been recognized by all certification bureaus worldwide now<br />

for many years.<br />

Early on, the focus was mainly on niche markets for which<br />

biodegradability and/or compostability was an asset, such as<br />

biowaste collection bags. This would rapidly change with the<br />

introduction of EN 13432.<br />

Significant growth<br />

It had taken several years and a substantial amount of<br />

time and the combined efforts of a number of parties, but in<br />

22 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


Report<br />

February 20<strong>01</strong>, the European standard EN 13432 on industrial<br />

compostability was published. The US equivalents ASTM<br />

D6400 and ASTM D6868 were introduced in, respectively,<br />

1999 and 2003. This resulted in a significant growth of the<br />

bioplastics industry, which ultimately led to OWS’s decision to<br />

concentrate its knowhow at a single site. The company closed<br />

down the laboratory in the US, invested in the laboratory<br />

in Gent and switched from GLP compliance to ISO 17025<br />

accreditation.<br />

With the expansion of the industry came also the next<br />

step in the market development. Biodegradable and<br />

compostable materials were now also being used for organic<br />

food packaging, matching the image of organic farming.<br />

Shortly after, bioplastics producers also began to target fast<br />

food restaurants, festivals, sport events, etc. as potential<br />

customers.<br />

At the same time, simple products like bags and single<br />

layer packaging were further optimized, resulting in more<br />

complex structures. Compostable materials started being<br />

used for pizza boxes, frozen food packaging and yoghurt<br />

cups; today, all kinds of short-life packaging are produced<br />

from compostable materials. Yet this also served to raise<br />

new issues. While EN 13432 perfectly prescribes what<br />

compostability entails, it no longer provided answers to<br />

questions such as: Do blends of already certified components<br />

need to undergo full testing? What to do with multi-layered<br />

structures? And what about inks, additives and adhesives?<br />

As a result, certification committees were introduced during<br />

which experts, including OWS, discuss how these new<br />

complex products needed to be tested to comply with EN<br />

13432. These are the so-called by-laws.<br />

Today, OWS has a team of 16 people working exclusively on<br />

biodegradability, compostability and ecotoxicity testing.<br />

Biodegradation in other environments<br />

However, in addition to compostability tests, OWS<br />

performed other kinds of tests as well. One of the first<br />

applications tackled by the industry was mulching films.<br />

A test method to quantify soil biodegradation had been<br />

developed in 1996 at ASTM level (ASTM D5988). Although it<br />

subsequently took until 2003 for the international equivalent,<br />

ISO 17556, to be published, the first certificates for soil<br />

biodegradable products were granted in 2000 by Vinçotte<br />

under their OK Biodegradable Soil certification program.<br />

Today, DIN CERTCO also has a similar certification scheme<br />

and accompanying certificate and logo.<br />

Similarly, certification schemes were also developed<br />

for materials and products that are home compostable or<br />

biodegradable in fresh water (for example, wet tissues and<br />

wrappers of dishwasher tablets). In recent years, however,<br />

marine degradation has received the most attention. Even<br />

though the only available test method (ASTM D7081) has been<br />

withdrawn, companies continue to work on developments in<br />

this field.<br />

What to expect in the next years<br />

Short-life packaging and consumer goods will further drive<br />

the compostable plastic industry in the coming years. Coffee<br />

capsules, for instance, are a very hot product nowadays and<br />

OWS has tested several tens of different coffee capsules from<br />

different companies in the past two to three years. Other<br />

products generating interest include multi-layered stand-<br />

Taking a test reactor out of the incubator<br />

Investigating the content of a composting bin<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 23


Report<br />

up pouches, fruit stickers and agricultural products used for<br />

tree and root protection.<br />

Legislation is another very important driver. In March<br />

2<strong>01</strong>6, France introduced national legislation requiring home<br />

compostability for all single use plastic bags (< 50µm). Food<br />

service ware has since been included in this legislation, and<br />

is required to be home compostable as of 2020. As a result,<br />

OWS has seen an exponential growth in home compostability<br />

testing requests, specifically for the French market.<br />

Also, at the European level, discussions are ongoing to<br />

incorporate specific requirements on soil biodegradation<br />

in the updated Soil Fertilizer Regulation. For instance, all<br />

major producers of controlled-release fertilizer coatings<br />

must therefore start investing in the development of soil<br />

biodegradable coatings. Today, OWS has already started<br />

working for some of the largest producers of controlledrelease<br />

coatings in the world, and is in contact with several<br />

other producers as well.<br />

“A compostable picnic”<br />

Anaerobic digestion plant<br />

Things are also changing in the US. Transparent certification<br />

schemes and by-laws have been in place in Europe for many<br />

years, but are unknown in the US. At the end of 2<strong>01</strong>6, BPI<br />

established a Standards and Procedures Committee, with as<br />

first priority: the development of a certification scheme and<br />

set of by-laws. OWS is a member of this committee.<br />

Shift to “AD-able” plastics?<br />

Compostable products and their end-of-life characteristics<br />

perfectly match the European (bio)waste management scene.<br />

For many years, source-separated biowaste has been treated<br />

via industrial composting. EN 13432 compliant products<br />

can be processed by these systems and do not hinder the<br />

composting process. Furthermore, the separate collection of<br />

municipal biowaste is also expected to develop further.<br />

However, there is a clear shift in Europe from industrial<br />

composting to anaerobic digestion when it comes to the<br />

biological treatment of organic household waste. Anaerobic<br />

digestion is a form of organic recycling, just like industrial<br />

composting. Yet, with the production of biogas, which can be<br />

converted to electricity, it is also a form of energy recycling.<br />

As a result, more and more industrial composting plants<br />

are looking at the possibility of expanding their capacity<br />

with an anaerobic digestion plant, both in Europe and in the<br />

US, where they seem to switch directly from landfilling to<br />

anaerobic digestion.<br />

While industrial composting is a fairly simple and robust<br />

treatment, anaerobic digestion is complex and has several<br />

varying parameters which can influence the conditions (wet<br />

vs. dry, mesophilic vs. thermophilic temperature, one stage<br />

vs. two stages, etc.). For instance, OWS’s patented DRANCO<br />

technology is a dry, thermophilic one stage process. As a<br />

result, not all compostable plastics (bio)degrade under these<br />

conditions. This could be a problem. Therefore, as part of the<br />

European FP7 project Open-Bio (see link below), OWS codeveloped<br />

a test method and standard specification for so<br />

called “AD-able” plastics. A representative test method has<br />

been defined, and criteria have been set. Both documents<br />

have been transferred to CEN, and, once validated, could add<br />

an extra driver to this already rapidly growing industry.<br />

www.ows.be<br />

www.biobasedeconomy.eu/research/open-bio<br />

24 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


ioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 25


Application News<br />

The world’s first biocomposite car<br />

Students from Netherlands-based Eindhoven University of<br />

technology have built a 4-seat electric car weighing a slender<br />

300 kg – made from a flax sandwich material with a PLA core.<br />

It is the first time a car body structure has been made from a<br />

biocomposite.<br />

As reducing vehicle weight took over as a priority in the<br />

design and production of new cars, carmakers have increasingly<br />

resorted to the use of light materials, such as aluminium and<br />

carbon-fiber composites, for the body chassis structural parts.<br />

The TU/ecomotive team of students responsible for the design<br />

of the car called Lina, however, chose a different solution. Using<br />

sandwich panels comprised of flax-based composite with a PLA<br />

honeycomb core for Lina’s chassis, they have shown that biobased<br />

materials can deliver the required strength, without the<br />

weight, needed for an energy-efficient, light-weight, modern-day<br />

connected urban minicar.<br />

They call their approach, characterized by their drive to<br />

consume the least possible about of energy during production<br />

through the use of sustainable materials, “reduction during<br />

production”. Efficient and practical, Lina offers a sustainable<br />

choice, from cradle to grave.<br />

A redesigned battery pack from Nova will make swapping<br />

batteries easy and convenient, while paving the way for new<br />

battery technologies. In response to the recent car sharing trend,<br />

the latest NFC technology has also been incorporated into Lina:<br />

users gain access to the car using a smartphone or a card with<br />

an NFC chip. The car will recognize the user by the unique NFC<br />

code, and activate his or her personal user settings, such as<br />

playlists, frequent destinations or telephone contacts.<br />

Visualisation by DD COM (www.ddcom.nl)<br />

The next step is to put Lina through her paces out on the street. To that end, the car will undergo an inspection at the RDW<br />

Netherlands Vehicle Authority to receive a licence number, which will enable the car to be driven on the public roads. Lina will<br />

be presented some time before the summer of 2<strong>01</strong>7. KL<br />

www.tuecomotive.nl<br />

Toothbrush handle from PLA compound<br />

The latest toothbrush handles made by Morbach, Germanybased<br />

SWAK Experience UG are produced from a biobased<br />

plastic developed by the Junior Research Group at the<br />

Institute for Bioplastics and Biocomposites of the University<br />

of Applied Sciences and Arts Hanover, Germany. Here, a team<br />

of scientists have successfully modified a PLA-based plastic,<br />

such that it is now suitable for daily use in dental care.<br />

The handle is produced mainly from renewably-sourced<br />

materials from GMO-free feedstocks, thus meeting all the<br />

requirements of SWAK, the manufacturer of the toothbrush<br />

and a company that aims, wherever possible, to provide their<br />

customers with sustainable options to promote oral health.<br />

For better handling, the injection moulded handle is slightly<br />

angled, similar to the dental instruments used by dentists.<br />

While the handle is intended to last as long as possible,<br />

the brush heads must be regularly changed. These are<br />

made from the wood of the toothbrush tree, also called<br />

Miswak (Salvadora persica), which has been used in the Arab<br />

world for centuries to clean teath. Miswak wood is a natural<br />

source of fluoride and other minerals that are beneficial to<br />

dental health.<br />

The scientists of the Junior Research Group are working<br />

in close consultation with company of SWAK to optimize the<br />

handle material and the production process. The goal is to<br />

increase the biobased content of the material of the handle,<br />

as well as to explore the use of natural fibres. MT<br />

www.fng.ifbb-hannover.de | www.swak.de<br />

26 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


Application News<br />

Shellfish chemistry to create<br />

new biodegradable adhesive<br />

Compostable black<br />

lids for hot drinks<br />

A new type of adhesive that combines the bonding chemistry of<br />

shellfish with a bio-based polymer has been shown to perform as well as<br />

commercially available products and can be easily degraded, representing<br />

a potential non-toxic alternative.<br />

“Adhesives releasing toxins including carcinogenic formaldehyde are<br />

almost everywhere in our homes and offices. The plywood in our walls,<br />

the chairs we sit on, and the carpet beneath our feet are all off-gassing<br />

reactive chemicals” said Jonathan Wilker, a professor of chemistry and<br />

materials engineering at Purdue University (West Lafayette, Indiana,<br />

USA). “Most of these glues are also permanent, preventing disassembly<br />

and recycling of electronics, furniture and automobiles. In order to<br />

develop the next generation of advanced adhesives we have turned to<br />

biology for inspiration.”<br />

Mussels extend hair-like fibers that attach to surfaces using plaques<br />

of adhesive. Proteins in the glue contain the amino acid DOPA, which<br />

harbors the chemistry needed to facilitate the cross-linking of protein<br />

molecules, providing strength and adhesion. Purdue researchers have<br />

now combined this bonding chemistry of mussel proteins with PLA The<br />

adhesive was created by harnessing the chemistry of compounds called<br />

catechols, contained in DOPA.<br />

“We found the adhesive bonding to be appreciable and comparable to<br />

several petroleum-based commercial glues,” Wilker said.<br />

“Results presented (in a research paper published online Jan. 4 in<br />

the journal Macromolecules) show that a promising new adhesive system<br />

can be derived from a renewable resource, display high-strength bonding,<br />

and easily degrade in a controlled fashion,” Wilker said. “Particularly<br />

unique was the ability to debond this adhesive under mild conditions.”<br />

“The detrimental health and environmental effects of synthetic glues<br />

are becoming more of a concern, with alternatives being developed,”<br />

Wilker said. “Renewable, nontoxic, and removable adhesives are thus in<br />

great demand to decrease our exposure to pollutants as well as waste in<br />

landfills.” A YouTube video is available at https://youtu.be/v4cdfWPCi8o.<br />

The researchers tested the adhesive by measuring the force needed<br />

to pull apart metal and plastic plates bonded together, finding that it<br />

compared favorably with various commercial products. Unlike synthetic<br />

glues, however, the adhesive can be easily degraded in water. MT<br />

Vegware, headquartered in Edinburgh,<br />

Scotland, is a manufacturer and visionary<br />

brand, and the only completely compostable<br />

packaging company operating globally. End of<br />

last year Vegware launched compostable black<br />

lids for hot cups.<br />

“We made the lids to meet demands of the<br />

artisan coffee market and contract caterers<br />

for a black lid that looks great, but doesn’t<br />

compromise on eco credentials, Our customers<br />

have been asking for compostable black lids<br />

for years – we’re delighted to launch them.”<br />

Vegware’s Sales Director, Teresa Suter, says.<br />

Sleek and stylish, the matte-finish lids can<br />

withstand heat up to 85°C. Made from plantbased<br />

CPLA (crystallised PLA), the black lids<br />

are certified compostable and 67 % lower in<br />

embodied carbon than conventional plastic lids.<br />

The new black lids are available in two<br />

sizes to fit 8 – 20oz cups. Like all of Vegware’s<br />

packaging, they’re designed to be recycled with<br />

food waste. MT<br />

www.vegware.com<br />

Purdue graduate student Heather Siebert tests the adhesive.<br />

(Purdue University photo/Erin Easterling)<br />

www.purdue.edu<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 27


From Materials Science and Research<br />

How prawn shopping bags<br />

could save the planet<br />

Bioengineers at The University<br />

of Nottingham (UK) are trialling<br />

how to use shrimp shells<br />

to make biodegradable shopping bags,<br />

as a green alternative to oil-based plastic,<br />

and as a new food packaging material<br />

to extend product shelf life.The new material<br />

for these affordable eco-friendly bags is being optimised<br />

for Egyptian conditions, as effective waste management<br />

is one of the country’s biggest challenges.<br />

An expert in testing the properties of materials, Dr Nicola<br />

Everitt from the Faculty of Engineering at Nottingham, is<br />

leading the research together with academics at Nile<br />

University in Egypt.<br />

“Non-degradable plastic packaging is causing<br />

environmental and public health problems in Egypt,<br />

including contamination of water supplies which<br />

particularly affects living conditions of the poor,” explains<br />

Dr Everitt.<br />

Turning the problem into the solution<br />

This new project aims to turn shrimp shells, which are a<br />

part of the country’s waste problem into part of the solution.<br />

Dr Everitt said: “Use of a degradable biopolymer made of<br />

prawn shells for carrier bags would lead to lower carbon<br />

emissions (…). It could also make exports more acceptable<br />

to a foreign market within a 10-15-year time frame. All<br />

priorities at a national level in Egypt.”<br />

Degradable nanocomposite material<br />

The research is being undertaken to produce an<br />

innovative biopolymer nanocomposite material which is<br />

degradable, affordable and suitable for shopping bags and<br />

food packaging.<br />

Chitosan is a man-made polymer derived from the organic<br />

compound chitin, which is extracted from shrimp shells,<br />

first using acid (to remove the calcium carbonate backbone<br />

of the crustacean shell) and then alkali (to produce the long<br />

molecular chains which make up the biopolymer). The dried<br />

chitosan flakes can then be dissolved into solution and<br />

polymer film made by conventional processing techniques.<br />

Chitosan was chosen<br />

because it is a promising<br />

biodegradable polymer<br />

already used in pharmaceutical<br />

packaging due to its antimicrobial,<br />

antibacterial and biocompatible<br />

properties. The second strand of the<br />

project is to develop an active polymer film that<br />

absorbs oxygen.<br />

Enhancing food shelf life and cutting food waste<br />

This future generation food packaging could have the<br />

ability to enhance food shelf life with high efficiency and<br />

low energy consumption, making a positive impact on food<br />

wastage in many countries. If successful, Dr Everitt plans<br />

to approach UK packaging manufacturers with the product.<br />

Additionally, the research aims to identify a production<br />

route by which these degradable biopolymer materials for<br />

shopping bags and food packaging could be manufactured.<br />

Acknowledgement<br />

The project is sponsored by the Newton Fund and the<br />

Newton-Mosharafa Fund grant and is one of 13 Newtonfunded<br />

collaborations for The University of Nottingham. MT<br />

www.nottingham.ac.uk<br />

Chitosan film made from shrimp shell in the early developmental<br />

phase (picture courtesy of University of Nottingham)<br />

28 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


Book Review<br />

Keratin-based<br />

Biomaterials<br />

and<br />

Bioproducts<br />

Soy-based<br />

Bioplastics<br />

One of the most economical and practical approaches<br />

to develop bioproducts including bioplastics is to<br />

use abundant low-cost agricultural byproducts and<br />

coproducts. Residues left after harvesting food crops, byproducts<br />

generated during production of biofuels, and<br />

conversion of animals and plants into food are some of the<br />

readily available raw materials suitable for development of<br />

bioproducts.<br />

Keratins are unique biopolymers that have distinct<br />

structure, properties and applications. Keratins are the<br />

major constituents in hairs, feathers, claws, hooves<br />

and other parts in humans and animals. Unlike many<br />

body parts, keratins are dispensable and are removed<br />

periodically. Examples include hairs and nails. Although<br />

keratins have unique functionality and structure, there are<br />

limited industrial uses of keratin. Keratin is<br />

being used commercially<br />

in cosmetics and some<br />

medicines. However,<br />

substantial amounts of<br />

keratinaceous materials<br />

are being disposed as waste<br />

in landfills.<br />

This book presents the<br />

structure and properties of<br />

keratin and their possible<br />

applications. Information<br />

in this book will be useful<br />

to researchers in academia<br />

and industry working on<br />

bioproducts and also on tissue<br />

engineering and drug delivery.<br />

Brief information on the products developed has also<br />

been included. Researchers, students, agriculturists,<br />

and farmers will be able to understand the potential of<br />

developing various keratin-based bioproducts.<br />

You can buy the books<br />

through us:<br />

http://tinyurl.com/bm2<strong>01</strong>7<strong>01</strong><br />

Soy and its coproducts are rapidly emerging as one of<br />

the most prominent sustainable plastics of the 21 st<br />

century. The relative abundance of soy and its functional<br />

and thermoplastic properties, low cost, and biodegradable<br />

characteristics have made it a material of great<br />

interest for widespread use in the plastics industry. As most<br />

of the functional properties of the final products are directly<br />

related to the physico-chemical properties of the raw material,<br />

a detailed knowledge of the inherent characteristics<br />

of soy-based materials is essential for understanding and<br />

manipulating their properties for better end-user applications.<br />

This book summarises in a most comprehensive<br />

manner the recent technical research accomplishments<br />

in the area of soy-based bioplastics. The prime aim and<br />

focus of this book is to<br />

present recent advances<br />

in the processing and<br />

applications of soybased<br />

biopolymers as<br />

potential bioplastics.<br />

It reflects recent<br />

theoretical advances and<br />

experimental results,<br />

and opens new avenues<br />

for researchers as well<br />

as readers working in<br />

the field of plastics and<br />

sustainable materials.<br />

The different topics<br />

covered in this book<br />

include: structural<br />

analysis of soy-based materials; soy/biopolymer blends;<br />

films, fibres, foams, and composites; and different<br />

advanced applications. In addition, several critical issues<br />

and suggestions for future work are comprehensively<br />

discussed in the hope that the book will provide a deep<br />

insight into the state of the art of soy-based bioplastics.<br />

The book is unique, with contributions from leading<br />

experts in the bioplastics research area, and is a useful<br />

reference for scientists, academics, research scholars, and<br />

technologists.<br />

www.smithersrapra.com<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 29


From Materials Science and Research<br />

Chitosan-based polymer<br />

developed to patch wounds<br />

Remember Shrilk, anyone? The chitosan bioplastic<br />

made from natural insect cuticle, such as that found<br />

in the rigid exoskeleton of a housefly or grasshopper,<br />

first developed in 2<strong>01</strong>1 by a team of researchers from the<br />

Wyss Institute at Harvard? Well, they’ve done it again, but<br />

this time it’s an innovative, chitosan-based wound closure<br />

technique.<br />

Moving on from bioplastic, Wyss Institute Founding<br />

Director Donald Ingber and Javier Fernandez have devoted<br />

efforts to extending chitosan’s usefulness into the clinical<br />

realm. “What’s good for the environment is also good<br />

for us,” said Javier Fernandez, who first developed a<br />

chitosan bioplastic called ‘Shrilk’ with Ingber back in 2<strong>01</strong>4<br />

(see bM 03/2<strong>01</strong>4).<br />

The researchers recently unveiled a new study in the<br />

journal Tissue Engineering that demonstrates biodegradable<br />

chitosan bioplastics can be used to bond bodily tissues to<br />

repair wounds or even to hold implanted medical devices in<br />

place. As chitosan is already approved for clinical use and<br />

it has antimicrobial properties, the approach could one day<br />

be utilized to immediately seal tissue tears or other serious<br />

injuries, preventing infection from setting in before a patient<br />

can be moved to a hospital for more in-depth care.<br />

“This work really spans the entire mission of the Wyss,<br />

as we have developed a biomaterial that could be used in<br />

sustainable consumer products and packaging or, as we<br />

now show, be adapted for clinical uses,” said Fernandez, the<br />

first author on the new study, who is a former Wyss Institute<br />

Postdoctoral Fellow and is currently an Assistant Professor<br />

at Singapore University of Technology and Design. “The<br />

material is non-toxic and biodegradable, leaving behind no<br />

trace once it has served its purpose.”<br />

To adapt chitosan to seal wounds and surgical incisions,<br />

Ingber and Fernandez searched for a way to quickly and<br />

tightly bond chitosan materials to living tissues. They<br />

zeroed in on transglutaminase (TG), a naturally occurring<br />

enzyme found in the body – where it keeps skin strong and<br />

strengthens blood clots – that has also been adopted to<br />

bond proteins together during commercial food processing.<br />

“As we started thinking about going in vivo, we faced<br />

the challenge of how to adhere chitosan to living tissues,”<br />

said senor author Ingber, M.D., Ph.D. “We explored using<br />

different formulations of transglutaminase to bond various<br />

forms of chitosan materials, including sheets, foams and<br />

sprays, to many different types of tissues.”<br />

A sheet of chitosan may be applied with a transglutaminase<br />

powder to patch wounds, as the team demonstrated using<br />

an ex vivo porcine intestine with a large hole in it. A pressure<br />

test revealed that the chitosan patch was even stronger<br />

than the native intestinal tissue.<br />

For the spray, a stream of liquid chitosan and liquid<br />

transglutaminase combine during application to quickly<br />

bond chitosan to tissue and close wounds. The team used<br />

this approach to seal a porcine lung that had sustained a<br />

puncture wound while it was cyclically insufflated with air<br />

to mimic inspiration and expiration. The spray application<br />

could also be useful for covering large areas of vulnerable<br />

tissue, like might be found on someone whose skin had<br />

sustained serious burns.<br />

To treat even larger and more traumatic wounds like those<br />

that might occur on the battlefield or during a motor vehicle<br />

accident, Ingber and Fernandez formulated a chitosan foam<br />

that could potentially be used to fill and seal larger wound<br />

cavities until a patient can be transported to a hospital for<br />

surgical intervention.<br />

The team’s findings also suggest that their approach<br />

could be tailored to bond inorganic surfaces – which make<br />

up crucial components of many different kinds of biomedical<br />

implants and microfluidic devices – to tissue or chitosan.<br />

“Right now our approach is very general, but we could<br />

theoretically take this concept and adapt it into almost any<br />

form imaginable for a broad number of possible uses,” said<br />

Fernandez.<br />

Looking ahead, the team hopes to develop an array of<br />

specific applications through collaboration with clinical<br />

partners.<br />

Additional co-authors on the study include Wyss Institute<br />

researchers Suneil Seetharam, Christopher Ding, and<br />

Edward Doherty. KL<br />

In this image of chitosan foam bonded to a one-centimeter-long<br />

defect in explanted porcine muscle, the foam is so well adhered to<br />

the muscle that it is notably difficult to distinguish the transition<br />

between chitosan foam and native tissue. (photo: Wyss Institute at<br />

Harvard University)<br />

www.wyss.harvard.edu<br />

30 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


ioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 31


Foam<br />

Starch based particle foam for<br />

biodegradable packaging<br />

Thanks to a new processing technique, foamable particles<br />

that are based on renewable resources can be processed<br />

into individual molded parts, e. g. for utilization<br />

as packaging material. Subsequent to use, the foam parts<br />

are compostable.<br />

Due to their product properties – light-weight, insulating,<br />

form-fitting – particle foams can be utilized, among<br />

other areas, in the automotive, logistics, and packaging<br />

sectors. Conventional foams, made of – for example – EPS<br />

(expanded polystyrene) or EPP (expanded polypropylene), are<br />

based on fossil source materials and are manufactured in<br />

molding machines with the help of steam and the effects of<br />

temperature and pressure. Jointly with the project partners<br />

Loick Biowertstoff and Storopack Deutschland as well as<br />

the Institute for Food and Environmental Research (ILU),<br />

Fraunhofer UMSICHT has developed an alternative that<br />

consists primarily of vegetable starch and water. Additional<br />

additives can supplement the formulation.<br />

“Our task was to manufacture starch particles that are as<br />

sustainable and biodegradable as possible that correspond<br />

to conventional, petro-chemically based particles in their<br />

properties’ profile,” explained Stephan Kabasci, Head of the<br />

Department Biobased Plastics at Fraunhofer UMSICHT. With<br />

an eye on the existing packaging market, the pricing also<br />

had to be taken into consideration in the selection of the<br />

components of the formulation.<br />

Temperature-controlled slab press<br />

In multiple series of tests with the novel starch particles,<br />

different foaming processes were tested. In direct comparison,<br />

a temperature-controlled slab press provided for the best<br />

results. For this, the starch particles are filled into a forming<br />

tool and fixated between two slabs for a specified time under<br />

pressure. So-called injection compression molds and/or<br />

die tools that feature a punch protruding into the negative<br />

mold are being utilized. This allows for a direct build-up of<br />

pressure in the direction of the particles located in the mold.<br />

For the expansion effect of the material, the pressure is a<br />

decisive factor in addition to the correct temperature-control<br />

that effects the formation of steam.<br />

Then the distance between the two slabs is being increased<br />

and the cooling off of the die tool is being initiated. This<br />

cooling-down process is carried out under counter-pressure<br />

so that the starch particles can expand, however not beyond<br />

the desired geometry of the molded part. “This way, we<br />

can manufacture compact molded parts with a closed and<br />

flat surface,” said Kabasci. Through water pressure and<br />

contact pressure, multiple molded parts can be glued to one<br />

another and additional geometries can be realized through<br />

cutting. Areas of use are, for example, edge protection for<br />

the transport of goods that are sensitive to shock, productprotecting<br />

spacers in packaging, or the replacement of<br />

polystyrene-based floral arrangement foams.<br />

www.umsicht.fraunhofer.de<br />

Molded foam parts glued together with water.<br />

Bisected molded foam part made of starch particles.<br />

fill conclude press expand remove<br />

(Photos and graph by Fraunhofer UMSICHT<br />

32 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


Foam<br />

The biodegradable foam<br />

market in China<br />

By:<br />

John Leung<br />

Consultant, Biosolutions<br />

Hongkong<br />

(source:Fotolia)<br />

Although biodegradable plastics first appeared on the<br />

market over 15 years ago, these plastics still only<br />

have a share of less than 1 % of the total plastics<br />

market. The reality is that the cost of some biodegradable<br />

plastics is more than double that of conventional plastics,<br />

while their general performance is 20 % lower than comparable<br />

plastics. Despite strong governmental support in<br />

some countries, the major market for biodegradable plastics<br />

is limited to bio-waste collection bags for food waste<br />

and garden waste. At the end of life, these bags can be<br />

industrially composted or processed via anaerobic digestion,<br />

to produce biogas and organic fertilizer. Biodegradable<br />

plastics are also used for nursery pots used to transplant<br />

seedlings, as clearing non-degradable plastic containers<br />

from the soil after harvest is very expensive and the complete<br />

removal of these containers is impossible. From the<br />

above, it can be concluded that, if biodegradable plastics<br />

are to break through, applications should be found which<br />

are cost competitive with existing products and can provide<br />

better performance.<br />

One such application is a biodegradable foam cup to replace<br />

existing LDPE-coated paper cups. The market price of a<br />

13 oz. (385 ml) paper cup with LDPE lamination is RMB 0.2<br />

(EUR 0.027) a piece. Made from biodegradable foam, the<br />

weight of this same 13 oz. cup can be reduced to 5 g, and the<br />

cost to RMB 0.16 (EUR 0,02) a piece - but with the following<br />

comparative advantages.<br />

Plastic foam is an excellent insulation material; cups<br />

containing hot liquids made from plastic foam are therefore<br />

far more comfortable for customers to hold. In addition, hot<br />

beverages can be kept hot – and ice cream for example can be<br />

kept cold - for a much longer time.<br />

The PLA-based foam referred to in the above application is<br />

biodegradable according to the European standard EN13432<br />

and has a biobased content that is higher than 80 %.<br />

In the past, the Chinese government has supported<br />

biodegradable mulch film projects in the provinces of Yunnan<br />

and Xinguang. The provinces of Hainan and Jinlin have special<br />

legislation in place for the application of biodegradable<br />

shopping bags. A rubbish classification system has been<br />

initiated in every city in China and at least five cities have already<br />

launched trial scale anaerobic digestion lines. Those five cities<br />

are Beijing, Shanghai, Shenzhen, Guangzhou and Wuhan.<br />

Although China today accounts for less than 1 % of the global<br />

consumption of biodegradable products, its strong economic<br />

growth, huge population and clear government ambition make<br />

it the biggest potential market for biodegradable products.<br />

China’s Legal and Reforms Committee have watched the<br />

biodegradable market for more than 10 years. They are highly<br />

interested in the biodegradable foam technology presented<br />

and expect to replace PS foam trays in supermarkets and<br />

single use serviceware.<br />

Guizhou Province will be enacting laws that make the use<br />

of biodegradable foam for serviceware compulsory in tourist<br />

regions. Since Guizhou Province is one of the poorest areas in<br />

China, the China Poverty Relief Fund will fund 100 % of cost of<br />

a model factory in Guizhou. lt will provide over 150 permanent<br />

job positions.<br />

Due to the different political system, legislation processes<br />

can be very fast in China.<br />

Biodegradable foam products are expected to enter the<br />

market in the course of 2<strong>01</strong>7.<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 33


Foam<br />

PLA based particle foam<br />

The first CO 2<br />

neutral foam in the world with Cradle to Cradle certification.<br />

Synbra Technology is currently finalising the certification of<br />

the world’s first particle foam to receive a Carbon Neutrality<br />

verification in compliance with the PAS 2060 standard.<br />

BioFoam ® is a fully biobased particle foam made from<br />

renewable resources (PLA based). Already starting up in 2006,<br />

Synbra Technology invented, developed and patented this<br />

unique material. Through its converting companies, Synbra<br />

Group wants to become the leading supplier of sustainable and<br />

biodegradable particle foam.<br />

Synbra Group companies, such as IsoBouw, Synprodo,<br />

Plastimar and Styropack, are already using the BioFoam<br />

material in series production for the white goods sector, ice<br />

cream packaging and the pharmaceutical sector, amongst<br />

others. Besides its own production facilities, Synbra is setting<br />

up a network of pioneering partner companies in the USA, the<br />

UK, Italy and is seeking coverage in other strategic markets.<br />

The existing distribution and production network already offers<br />

BioFoam moulded products as a valuable and sustainable<br />

addition to the existing range of particle foam products.<br />

About PLA & BioFoam:<br />

Based on renewable resources, BioFoam is extremely<br />

environmentally friendly. After use BioFoam can be either reformed<br />

into a new foam product or recycled into solid PLA.<br />

Besides that it’s got the unique possibility to be fully composted.<br />

Since 2009 BioFoam is a C2CCM (Silver) certified foam – the<br />

first foam to obtain this certification. It is already used in many<br />

applications and has become a driver for product innovation<br />

within many industries (see also the cases below). Some recent<br />

applications are Alabastine (Akzo Nobel) trays for tubes (DIY<br />

market), Zandonella ice-cream box (Germany), Greeny icecream<br />

box (Italy), Cryostore (cold chain boxes), IsoBouw (Deco-<br />

Bio) and Termokomfort (BioFoam pearls).<br />

BioFoam and LCA – Life Cycle Analysis<br />

The peer reviewed BioFoam LCA was originally prepared<br />

by Akzo Nobel Sustainable Development in October 2<strong>01</strong>0.<br />

It was updated by thinkstep AG in September 2<strong>01</strong>6 (see<br />

Table 1). Through the use of biomass, short-cycle CO 2<br />

is used<br />

for the growth of plants, and this contributes to the reduction<br />

of the greenhouse effect, which constitutes in itself again a<br />

compensation for a part of the emissions further in the chain.<br />

This production chain includes transport, fermenting lactic<br />

acid and lactide production and PLA polymerisation, where<br />

electricity, gas and oil are used. The entire chain is, therefore,<br />

still not Carbon Neutral. It is exactly known how much emission<br />

takes place, and in which manufacturing step it takes place. This<br />

applies to CO 2<br />

emission, but also for other emission sources,<br />

which are important for a Life-Cycle-Analysis<br />

In the development process, Synbra Technology has always<br />

aimed at the most sustainable solutions possible. And with a high<br />

interest from both large retail chains and producers, Synbra has<br />

put extra effort into making BioFoam CO 2<br />

neutral. Please note<br />

for sake of clarity, it is not emission neutral. But the emissions<br />

related to CO 2<br />

emissions of gas are compensated annually with<br />

CO 2<br />

certificates and in this way the emissions related to the<br />

BioFoam productions becomes neutral. The emissions related<br />

to CO 2<br />

emissions remaining in the value chain and which does<br />

not fall under their direct influence, Synbra compensates for the<br />

full 100 %. The certificates are available in different quality levels.<br />

Synbra has chosen the highest level: Gold Standard certificates.<br />

Electricity used is derived from hydropower.<br />

Environmentally friendly and CO 2<br />

-neutral<br />

During composting, biodegradable blends of fossil and<br />

biobased plastics on the market, still may release fossil CO 2<br />

,<br />

this is not the case for BioFoam, which is fully biobased. It was<br />

the first foam to be awarded the Cradle to Cradle CM certificate<br />

and has also received a material health certificate from EPEA -<br />

Hamburg, Germany certifying that BioFoam is free from any<br />

CMR (carcinogenic, mutagenic and reprotoxic) substance.<br />

Unlike any other particle foam on the market, only CO 2<br />

(taken<br />

from the atmosphere) is used as a blowing agent. No VOC’s are<br />

emitted during production. BioFoam is a certified food-approved<br />

Application example: white goods buffer.<br />

Application example: colorFabb 3D printing reel<br />

34 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


Foam<br />

Buss Laboratory Kneader MX 30-22<br />

Foam<br />

By:<br />

Jan Noordegraaf - Synbra Technology, Etten Leur, The Netherlands<br />

Peter de Bruijn - Synprodo, Wijchen,The Netherlands<br />

Anette Priess Gade - Styropack, Glejbjerg, Denmark<br />

material. Without addition of a flame retardant it meets the<br />

Euro class E fire standard.<br />

New product developments<br />

In December 2<strong>01</strong>6 BioFoam E-PLA has been approved<br />

as a material that can be used in the entire range of a large<br />

furniture retail chain and has also been approved as filler<br />

protection in furniture products. In January 2<strong>01</strong>7 it was<br />

approved as a buffer protection material by several white<br />

goods producers.<br />

ColorFabb, Venlo, The Netherlands, Europe’s leading<br />

and most innovative 3D wire printing producer has chosen<br />

to introduce BioFoam reels instead of the much heavier<br />

polycarbonate injection moulded reels. This reduced the reel<br />

weight by 80 %, saving weight in internet shipping. In addition<br />

after its use the reel can be composted or brought back to a<br />

distribution hub for regrinding and re-extrusion into 3D wire.<br />

Synbra is working actively on further breakthrough<br />

developments in substrates, fish boxes and leisure<br />

applications.<br />

www.biofoam.nl | www.synbra-technology.nl<br />

www.synprodo.nl | www.styropack.dk<br />

indicator<br />

Non-Renewable<br />

Energy Use, MJ<br />

Renewable Energy<br />

Use MJ<br />

Carbon Footprint, kg<br />

CO 2<br />

-Equiv.<br />

Acidification,kg SO 2<br />

-<br />

Equiv.<br />

Photochemical<br />

Oxidant Formation,<br />

kg Ethene-Equiv.<br />

Eutrophication, kg<br />

Phosphate-Equiv.<br />

1 kg of moulded<br />

BioFoam<br />

1 kg of moulded<br />

BioFoam<br />

(compensated)<br />

35.6 35.6<br />

56.8 56.8<br />

1.74 0.00<br />

0.0337 0.0337<br />

0.00262 0.00262<br />

0.<strong>01</strong>07 0.<strong>01</strong>07<br />

Table 1: The CO 2<br />

offsetting is not included in the GABI LCA<br />

i-report. In the Technical Specification “ISO/TS 14067:2<strong>01</strong>3<br />

Greenhouse gases -- Carbon footprint of products<br />

-- Requirements and guidelines for quantification and<br />

communication” it is stated that “The CFP (Carbon Footprint)<br />

and the partial CFP shall not include offsetting.” (chapters<br />

3.1.1.4. and 6.3.4.1.). Also for example in the PCR (Product<br />

Category Rules) of the German EPD system (IBU) it is specified<br />

that “IBU does not allow CO 2<br />

certificates to be included in<br />

the quantification of the global warming potential.” (chapter<br />

5.5.8, see attachment p.17). Based on these methodological<br />

guidance documents thinkstep does not recommend to include<br />

the offsetting into the calculations but to communicate it in<br />

a qualitative way to show your commitment. The table below<br />

summarises this in a transpararent way.<br />

Buss Kneader Technology<br />

Leading Compounding Technology<br />

for heat and shear sensitive plastics<br />

For more than 60 years Buss Kneader technology<br />

has been the benchmark for continuous preparation<br />

of heat and shear sensitive compounds –<br />

a respectable track record that predestines this<br />

technology for processing biopolymers such<br />

as PLA and PHA.<br />

> Uniform and controlled shear mixing<br />

> Extremely low temperature profile<br />

> Precise temperature control<br />

> High filler loadings<br />

Buss AG<br />

Switzerland<br />

www.busscorp.com<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 35


Foam<br />

New<br />

compostable<br />

particle foam<br />

BASF presents ecovio ® EA with high<br />

bio-based content for packaging<br />

solutions<br />

During K-fair 2<strong>01</strong>6, BASF launched its new innovative expandable<br />

ecovio ® EA particle foam. This product is predominantly<br />

biobased (>70 %) and, like all of the grades<br />

under the ecovio brand, it supports the biological cycle through<br />

its certified compostability.<br />

ecovio EA is a patented product made out of BASF’s<br />

biodegradable polyester ecoflex ® type and Polylactic acid (PLA).<br />

It is the first expandable, closed cell particle foam developed<br />

as a drop-in solution for Expandable Polystyrene (EPS) and<br />

Expanded Polypropylene (EPP) customers. By utilizing an<br />

innovative continuous process, the ecovio polymer is charged<br />

with the blowing agent pentane to produce expandable beads.<br />

These expandable ecovio EA beads are shipped globally using<br />

a standard EPS octabin packaging. Under ambient storage<br />

conditions, these beads have a shelf-life of more than 6 months<br />

without any quality impairment.<br />

BASF<br />

Convertors OEM‘s<br />

End of life<br />

steam<br />

steam<br />

Expandable beads<br />

Foam beads<br />

Shape molded parts<br />

Compostable<br />

Drop-in processing solution for EPS customers<br />

The major advantage of this product is that the convertors can<br />

use their existing machineries to process ecovio EA.<br />

ecovio EA enables trouble-free pre-expansion of the beads<br />

on conventional EPS pre-expanders. The foam density can be<br />

adjusted by simply tuning the steaming time and temperature.<br />

The minimum density of 23 g/l can be achieved in a one-step<br />

and above 16 g/l in a two-step expansion. It also expands at<br />

least three times faster than EPS, which leads to significantly<br />

lower steam consumption and faster production cycle times. The<br />

subsequent shape moulding can also be done using EPS or EPP<br />

machines. The innovative blend recipe with modified ecoflex acts<br />

as an in-situ hot melt adhesive which facilitates superior bead<br />

fusion of shape moulded parts and leads to good surface quality.<br />

In some cases, the mould needs to be adapted/modified to<br />

process ecovio EA foam beads due to different shrinkage than<br />

EPS and EPP. The major requirement of the mould is to provide a<br />

sufficient number of filling injectors as to achieve good filling and<br />

evenly distributed steam holes add to a perfect part appearance<br />

and performance. By doing so, high quality ecovio foam products<br />

can be produced continuously on standard commercial machines.<br />

36 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


Foam<br />

By:<br />

Bangaru Sampath<br />

Global Technical Marketing Manager<br />

BASF SE<br />

Ludwigshafen, Germany<br />

Biobased content between 60% and 80%<br />

The major benefits for the convertors/moulders<br />

include<br />

• Utilization of their existing machineries (no major<br />

investment needed)<br />

• Low transportation cost due to shipment and storage of<br />

high density beads (density 700 g/l)<br />

• Foaming to all desired density ranges whenever required<br />

• Full flexibility in terms of density and complex dimension<br />

of shape moulded parts<br />

• Less energy consumption during foam processing<br />

Performance and applications<br />

ecovio EA foam offers better thermal and chemical<br />

resistance in comparison to EPS and its outstanding<br />

mechanical properties boast very good energy absorption<br />

and resilience even when subjected to multiple, heavy<br />

impacts. These excellent properties make it particularly<br />

suitable for transport packaging for heavy, high-value or<br />

delicate goods (e.g. washing machines, television screens)<br />

where a high level of impact resistance and robustness is<br />

vital. The foam application can also be extended for its use in<br />

the food packaging sector due to its good thermal insulation<br />

performance. For example, to maintain the cooling chain at<br />

all times for temperature-sensitive goods such as packaged<br />

vegetables, fruit, meat, frozen goods or even drugs. This<br />

effectively prevents the goods from being spoiled. Soon, a<br />

new ecovio EA food contact grade will be launched and this<br />

will extend the range of applications to all of the areas in<br />

which foam is in direct contact with processed food.<br />

End of life<br />

ecovio EA is highly durable under normal environmental<br />

conditions but degrades very quickly within five weeks under<br />

industrial composting conditions. Prior to composting, the<br />

foam material may also be recycled to alternate plastic<br />

products (e.g. with injection moulding technology) in<br />

customised recycling processes. The high biobased content<br />

and the certified compostability make ecovio EA particularly<br />

attractive wherever a fossil packaging solution no longer<br />

meets customers’ requirements for a biobased and<br />

biodegradable packaging solution. Due to its high biobased<br />

content the CO 2<br />

footprint is much lower as compared to<br />

completely fossil based foam products.<br />

www.ecovio.com<br />

Physical properties of ecovio EA for packaging<br />

Properties Test standard Unit Test result Test result<br />

Density DIN EN ISO 845 kg/m 3 25 30<br />

Thermal conductivity<br />

Compressive stress<br />

at 10°C<br />

at 35°C<br />

at 60°C<br />

at 10 % strain<br />

at 25 % strain<br />

at 50 % strain<br />

DIN EN 12667<br />

ISO 844<br />

mW/(m·K)<br />

kPa<br />

32 - 33<br />

36 - 37<br />

40 - 41<br />

95<br />

127<br />

180<br />

32 - 33<br />

36 - 37<br />

41 - 42<br />

Specific cushioning<br />

factor, C*<br />

ISO 4651 2.7 2.7<br />

Bending strength DIN EN 12089 kPa 210 - 230 250 - 270<br />

Tensile strength DIN EN ISO 1798 kPa 224 258<br />

Elongation at break DIN EN ISO 1798 % 10 8.5<br />

Short term<br />

resistance to heat<br />

deformation<br />

°C 100 100<br />

124<br />

161<br />

227<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 37


Brand Owner<br />

Brand-Owner’s perspective<br />

on bioplastics and how to<br />

unleash its full potential<br />

“As the world’s leading supplier of carton packaging,<br />

we believe using renewable resources, when managed<br />

responsibly, is a more sustainable source of raw materials.<br />

A renewable resource is a resource that can replenish<br />

itself naturally over time and, therefore, be used again.<br />

Our ambition is to achieve fully renewable packaging using<br />

100% renewable materials – helping us to ensure a supply of<br />

packaging material that both protects the food they contain,<br />

as well as the resources they were sourced from.<br />

By introducing biobased polymers made from sugar cane<br />

we are taking an important step towards sustainable sourcing<br />

in our packaging. Today the source is Brazilian sugar cane,<br />

the only commercially available, fully traceable source for<br />

renewable polyethylene (PE). It is important for us to source<br />

renewable materials for packaging by focusing on three key<br />

areas: traceability, certification and recyclability.<br />

We started from a strong foundation with a package that is made<br />

from over 70% paperboard, which is made from wood. Adding to<br />

that, we have introduced the first biobased caps in our sector,<br />

MARIO ABREU, VP ENVIRONMENT, TETRA PAK<br />

and now leading the way with the use of certified biobased<br />

plastic coatings and biobased adhesive layers which brings<br />

us closer to our long term ambition by taking the biobased<br />

content of a package to over 80%. And we will continue to<br />

innovate and look for ways to incorporate more renewable<br />

materials into our packages towards our ambition for fully<br />

renewable packaging.”<br />

www.tetrapak.com<br />

38 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


Report<br />

Bioplastics Survey<br />

By:<br />

Michael Thielen<br />

As you may have noticed, we have started a new series<br />

“Special focus on certain geographical areas”. ‘As part<br />

of this new series we will also focus on the attitudes towards<br />

and general perception of bioplastics across the world.<br />

With the help of a simple survey, we want to try to explore<br />

how well the concept of bioplastics is known and understood<br />

throughout the various countries.<br />

We have kicked off with a report on a visit to a shopping<br />

center in the Netherlands, where we conducted our survey<br />

among a (non-representative) sample of normal people.<br />

Of those we interviewed, 63 % were male and 37 % were<br />

female. About 23 % were aged between 20 and 40, while<br />

77 % were between the ages of 40 and 60. This represents<br />

the average distribution of people browsing this particular<br />

shopping center on this Saturday morning.<br />

When asked whether they knew what bioplastics were,<br />

around one third responded with yes (and went on to back<br />

this up by correctly defining these as materials of biobased<br />

origin and/or with biodegradable features). The other 67 %<br />

all indicated that they were interested in learning about<br />

what bioplastics were. We briefly explained that conventional<br />

plastics were made from oil, a scarce and depletable resource …<br />

that burning petroleum-based products would affect climate …<br />

that biobased plastics can be made from renewable resources<br />

or waste streams, such as corn, sugar beet, sugar cane<br />

or e.g. waste starch from the potato industry … and that<br />

biodegradable/compostable plastics (whether biobased or<br />

otherwise) can offer significant benefits, depending on the<br />

application.<br />

After this brief explanation, almost all of those interviewed<br />

expressed the opinion that bioplastics were beneficial for the<br />

environment and for the climate, or at least “less bad”, as one<br />

young man was at pains to point out.<br />

Asked whether they would buy products made of bioplastics,<br />

if they should happen to see them on display at the store, 93%<br />

confirmed that they would. Yet “only” 73 % reported that they<br />

would be willing to pay more for such products, with most<br />

responding: “a little more, yes”, or “but not twice as much”…<br />

In sum, not many consumers know about or are aware<br />

of bioplastics and their potential. However, the results<br />

of this survey reveal that given the knowledge and the<br />

chance, consumers – at least those we interviewed- would<br />

opt for products using bioplastics and even be willing to<br />

pay a small premium. This indicates an obvious need for<br />

comprehensive end consumer education. Consumer behavior<br />

can make a significant impact on the ways products affect the<br />

environment. Educating consumers about bioplastics offers<br />

a huge opportunity to promote these materials and to effect<br />

positive changes in the shopping choices people make.<br />

Please note that this was not a representative survey. Our survey did not ask<br />

about factors such as educational background, family status, urban or rural<br />

residency, etc. but was merely conducted in order to gain a first, rough idea.<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 39


10<br />

Years ago<br />

From Science & Research<br />

Controlled (soil) biodegradation<br />

Published in<br />

bioplastics MAGAZINE<br />

In Jan 2<strong>01</strong>7, Kate Parker (Zealafoam) says:<br />

“The ten years since first introducing our PLA foaming<br />

technology have been an exciting and busy period for the<br />

Biopolymer Network Limited (BPN) team from New Zealand.<br />

Over that time BPN has continued working on their patented<br />

process for making Zealafoam ® , a PLA based alternative to<br />

expanded polystyrene (EPS), which uses CO 2<br />

as a green blowing<br />

agent to produce low density particle PLA foam. Advances<br />

have been made in base material with work focussed<br />

on optimisation of PLA grades, blends and additives<br />

(bM <strong>01</strong>/13). Cost-effective biomass fillers have shown<br />

excellent results in producing novel foams. A focus on<br />

commercialisation has led to a multitude of industry<br />

trials worldwide (bM <strong>01</strong>/11) allowing us to prove our<br />

technology on a range of existing foaming and moulding<br />

machines. This has enabled us to address issues around<br />

commercial production. It has also led to foams of lower density<br />

with moulded products under 20 g/l being achieved. Applications<br />

today include products ranging from loose bead (used in furniture<br />

and loose fill packaging), to fish boxes and cycle helmets. The next<br />

stages for the research team include leveraging this technology for<br />

other product lines including foamed cups and thin, lightweight<br />

labelling film (bM <strong>01</strong>/16).”<br />

Advancing Bioplastics from Down-Under:<br />

CO 2 production in bioplastic-additive degradation trials<br />

mmol CO 2<br />

8.00<br />

7.00<br />

6.00<br />

5.00<br />

4.00<br />

3.00<br />

2.00<br />

1.00<br />

0.00<br />

Fig 1<br />

Impact Resistance (kJ/m 2 )<br />

4.5<br />

4.0<br />

3.5<br />

3.0<br />

2.5<br />

2.0<br />

1.5<br />

1.0<br />

0.5<br />

0.0<br />

PLA<br />

Fig 2<br />

Bioplastic with<br />

various additives<br />

Bioplastic only<br />

www.scionresearch.com<br />

PLA 1<br />

PLA 2<br />

New Developments in Environmentally Intelligent<br />

Bioplastic Additives & Compounds<br />

Advancing Bioplastics from Down-Under:<br />

Time (days)<br />

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17<br />

Impact strength PLA compounds<br />

Article contributed by<br />

Dr. Alan Fernyhough, Unit Manager of the Bioplastics<br />

Engineering Group, Scion, Rotorua, New Zealand<br />

PLA 3<br />

Scion, based in Rotorua, New Zealand, is a research organisation<br />

with approx. 390 employees firmly focused on a biomaterials<br />

future and has been working with bioplastics for about<br />

10 years.<br />

Scion recognised at an early stage that bioplastics represented<br />

a huge opportunity for New Zealand, with its traditional<br />

strengths in all aspects of the agriculture, horticulture, and<br />

forestry industries’ value chains. Each year large volumes of a<br />

wide range of biomasses are processed for an increasing range<br />

of end uses in New Zealand. Such resources, and the residues<br />

from the harvesting and downstream processing, represent valuable<br />

sources of fibres, fillers, polymers and functional chemical<br />

additives for use in industrial biopolymer products, such as<br />

bioplastics.<br />

The core focus of Scion has been on additives and compounding<br />

formulations for enhanced performance in commercial bioplastics.<br />

One of the early areas of research was the compatibilised<br />

combination of wood and other natural fibres with a range<br />

of commercial bioplastics such as MaterBi, Solanyl, Biopol<br />

(PHA), PLA and others. Scion then developed a novel technology<br />

for wood-fibre (as opposed to wood flour) pellet manufacture for<br />

bioplastics compounding and moulding- showing markedly superior<br />

performance to wood flour and to agri-fibre reinforced bioplastics.<br />

A database of properties and formulations for a wide<br />

range of biobased additives, fillers/fibres, compatibilisers etc<br />

was established with data on mechanical properties, processability,<br />

water and biodegradation responses, durability/weathering<br />

(UV/humidity) and other properties such as flame retardancy.<br />

Now the database comprises in excess of 300 formulations<br />

with such data, using major commercial bioplastics, variously<br />

compounded with novel (biobased) additives, or combinations of<br />

additives, sourced primarily from readily available biomasses.<br />

With moulders and compounders Scion is developing several<br />

applications in New Zealand, ranging from controllably degradable<br />

plant pots, erosion control products, underground temporary<br />

fixtures, office furniture and stationery products. The<br />

knowhow in enhancing bioplastics performance, together with<br />

an ability to control the degradation (accelerate or decelerate)<br />

profiles of commercial bioplastics, in soil and aqueous media, is<br />

now being applied to such product developments. Most interest<br />

has been for injection moulding, but there is increasing interest<br />

in extrusions and thermoforming. Examples of some of Scion’s<br />

developments are:<br />

Controlled Degradation Compounds<br />

The biodegradation of PLA and other bioplastics in soil<br />

media can be controlled by (biobased) additive technologies,<br />

while maintaining processability and mechanical integrity. For<br />

example Figure 1 shows examples of different biodegradation<br />

profiles, in soil, of PLA compounds with the addition of biomass<br />

additive systems, selected from the database.<br />

High Impact PLA<br />

Another outcome from Scions screening work has been<br />

clues to improving the impact resistance of brittle bioplastics,<br />

such as PLA. While it is relatively straightforward to improve<br />

stiffness and strength in PLA, for example by compatibilised<br />

addition of natural fibres or fillers, it is less easy to improve<br />

impact strength at the same time. However, researchers at<br />

Scion have identified some approaches which can do this.<br />

Figure 2 shows example data on impact strength for some<br />

injection moulded PLA formulations.<br />

Visualising Biopolymers in Natural Fibres<br />

A unique approach to ‘track’ biopolymers in moulded compounds<br />

has been developed by Dr Grigsby and Armin Thumm.<br />

Natural fibres differ from glass and carbon fibres in that they<br />

are permeable, and have cell walls and hollow centres of<br />

various dimensions (lumen). Confocal microscopy has been<br />

applied (Figure 3) to visualise differences in interfacial behaviours,<br />

at a fibre cell wall level. Use of selected flow modifiers,<br />

and/or certain processing conditions can lead to lower<br />

instances of voids between the biopolymer and fibre, and, can<br />

promote (or reduce) lumen filling. The implications of such<br />

differences on properties are being evaluated.<br />

New Functional Additives for Bioplastics<br />

Scion continues to screen biomass streams for functional<br />

Biofoam Developments<br />

Work on biofoams has focused on a new PLA foaming technology<br />

which uses carbon dioxide as blowing agent. Dr Witt<br />

has led this work and developed novel routes to the manufacture<br />

of very low density moulded blocks (~20g/l; Figure 4). Scion<br />

also works with a major foam moulder in New Zealand to<br />

further develop their bioplastic foaming technology for packaging<br />

products. Much of this is undertaken within Biopolymer<br />

Network Ltd, a JV between Scion and two other NZ research<br />

institutes, AgResearch and Crop & Food Research.<br />

About Scion<br />

Scion was established in 1947 as the New Zealand Forest<br />

Research Institute. From its forestry science roots, the government-owned<br />

Institute branched out into other areas of<br />

research: exploring the potential of trees, and other plants,<br />

crops and biomass residues to produce new bio-based materials.<br />

To mark this shift in emphasis, the organisation changed<br />

its trading name to “Scion”, which refers to a piece of plant<br />

material that is grafted onto an established rootstock. This<br />

new name symbolises the growth of research towards a future<br />

world where bio-based materials are required to replace<br />

non-renewable synthetics.<br />

This article could only give a condensed and incomplete<br />

overview of Scions activities. In future issues bioplastics MAG-<br />

AZINE will address one or the other activity in more detail.<br />

Fig 3 all pictures: Scion<br />

Fig 4<br />

additives of potential use in bioplastics. Scion has developed<br />

34 bioplastics MAGAZINE [<strong>01</strong>/07] Vol. 2<br />

extractions, fractionations and derivatisations of such extracts<br />

and has developed novel ways of using them. For example,<br />

they can be used as components in high performance<br />

adhesive formulations and as functional additives for bioplastic<br />

compounds.<br />

bioplastics MAGAZINE [<strong>01</strong>/07] Vol. 2 35<br />

tinyurl.com/foam2007<br />

40 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


Basics<br />

Can additives make plastics<br />

biodegradable?<br />

By:<br />

Constance Ißbrücker<br />

European Bioplastics<br />

Berlin Germany<br />

Biodegradability is an inherent property of a material<br />

or product resulting from the action of naturally<br />

occurring microorganisms, such as bacteria, fungi,<br />

and algae. The process produces water, carbon dioxide,<br />

and biomass. No additives are needed and no fragments<br />

remain in the environment. In the case of industrial<br />

composting, the requirements are clearly defined in internationally<br />

agreed standards such as EN13432, or ISO<br />

18606. For biodegradation in other environments other<br />

standards can and should regulate the framework conditions<br />

and pass/fail criteria.<br />

So-called oxo-degradable plastics are commonly<br />

fossil-based, non-biodegradable polyolefins or<br />

polyesters (e.g. PE or PET) supplemented with salts<br />

of transition metals. These additives are supposed<br />

to enable the biodegradation of apparently nonbiodegradable<br />

plastics. However, to date no reproducible<br />

study could provide satisfactory evidence for this, for<br />

example by measuring a significant amount of carbon<br />

dioxide evolvement, which is the standard indicator of<br />

and verification method for biodegradation. Publications<br />

in support of oxo-degradable plastics have claimed<br />

about 60% biodegradation in two years, leaving the fate<br />

of the remaining 40% up to speculation. Apart from the<br />

comparatively long time span (EN 13432 requires 90%<br />

disintegration in 12 weeks and biodegradation of 90%<br />

within six months), there are serious implications: It is<br />

assumed that oxo-degradable materials only disintegrate<br />

and finally visibly disappear under the influence of light<br />

(UV radiation) and oxygen. If no real biodegradation takes<br />

place simultaneously and subsequently, the process of<br />

disintegration results in the formation of invisible plastic<br />

fragments, contributing to the ubiquitous environmental<br />

and health hazard of microplastics in the environment.<br />

Another group of plastic materials supplemented with<br />

additives that are supposed to support biodegradation<br />

are so-called enzyme-mediated plastics. Naturally<br />

occurring biodegradation relies on enzymatic reactions<br />

initiated by naturally present organisms. The producers of<br />

enzyme-mediated plastics intend to emulate the process<br />

of biodegradation by adding enzymes to conventional<br />

polyolefins. So far no independent study or publication<br />

shows any positive results for such materials with regard<br />

to biodegradation, even though most of the producing<br />

companies are claiming that their plastics are 100%<br />

biodegradable or even compliant with accepted composting<br />

standards. These claims are often made not on the basis of<br />

conversion to carbon dioxide, but instead on the basis of mass<br />

loss, which is no scientific proof of biodegradation taking place.<br />

It is important to clearly differentiate between different<br />

concepts in this context: Enzyme-mediated plastics should not<br />

be confused with recent promising research efforts focussing<br />

on a kind of enzymatic recycling. In the latter case waste of<br />

conventional plastics (e.g. PET or PU) waste are depolymerised<br />

through tailor-made enzymes. The obtained monomers then<br />

can function as raw material for the production of bioplastics<br />

such as PHA, which is biodegradable in numerous environments<br />

without the use of any supporting additives.<br />

www.european-bioplastics.org<br />

Home Compostable*<br />

Mailing Film<br />

* According to OK Compost Home and NF T51-800 (11-2<strong>01</strong>5)<br />

NEW<br />

Bio4Pack GmbH • PO Box 5007 • D-48419 Rheine • Germany<br />

T +49 (0) 5975 955 94 57 • www.bio4pack.com<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 41


Basics<br />

Glossary 4.2 last update issue 02/2<strong>01</strong>6<br />

In bioplastics MAGAZINE again and again<br />

the same expressions appear that some of our readers<br />

might not (yet) be familiar with. This glossary shall help<br />

with these terms and shall help avoid repeated explanations<br />

such as PLA (Polylactide) in various articles.<br />

Bioplastics (as defined by European Bioplastics<br />

e.V.) is a term used to define two different<br />

kinds of plastics:<br />

a. Plastics based on → renewable resources<br />

(the focus is the origin of the raw material<br />

used). These can be biodegradable or not.<br />

b. → Biodegradable and → compostable<br />

plastics according to EN13432 or similar<br />

standards (the focus is the compostability of<br />

the final product; biodegradable and compostable<br />

plastics can be based on renewable<br />

(biobased) and/or non-renewable (fossil) resources).<br />

Bioplastics may be<br />

- based on renewable resources and biodegradable;<br />

- based on renewable resources but not be<br />

biodegradable; and<br />

- based on fossil resources and biodegradable.<br />

1 st Generation feedstock | Carbohydrate rich<br />

plants such as corn or sugar cane that can<br />

also be used as food or animal feed are called<br />

food crops or 1 st generation feedstock. Bred<br />

my mankind over centuries for highest energy<br />

efficiency, currently, 1 st generation feedstock<br />

is the most efficient feedstock for the production<br />

of bioplastics as it requires the least<br />

amount of land to grow and produce the highest<br />

yields. [bM 04/09]<br />

2 nd Generation feedstock | refers to feedstock<br />

not suitable for food or feed. It can be either<br />

non-food crops (e.g. cellulose) or waste materials<br />

from 1 st generation feedstock (e.g.<br />

waste vegetable oil). [bM 06/11]<br />

3 rd Generation feedstock | This term currently<br />

relates to biomass from algae, which – having<br />

a higher growth yield than 1 st and 2 nd generation<br />

feedstock – were given their own category.<br />

It also relates to bioplastics from waste<br />

streams such as CO 2<br />

or methane [bM 02/16]<br />

Aerobic digestion | Aerobic means in the<br />

presence of oxygen. In →composting, which is<br />

an aerobic process, →microorganisms access<br />

the present oxygen from the surrounding atmosphere.<br />

They metabolize the organic material<br />

to energy, CO 2<br />

, water and cell biomass,<br />

whereby part of the energy of the organic material<br />

is released as heat. [bM 03/07, bM 02/09]<br />

Since this Glossary will not be printed<br />

in each issue you can download a pdf version<br />

from our website (bit.ly/OunBB0)<br />

bioplastics MAGAZINE is grateful to European Bioplastics for the permission to use parts of their Glossary.<br />

Version 4.0 was revised using EuBP’s latest version (Jan 2<strong>01</strong>5).<br />

[*: bM ... refers to more comprehensive article previously published in bioplastics MAGAZINE)<br />

Anaerobic digestion | In anaerobic digestion,<br />

organic matter is degraded by a microbial<br />

population in the absence of oxygen<br />

and producing methane and carbon dioxide<br />

(= →biogas) and a solid residue that can be<br />

composted in a subsequent step without<br />

practically releasing any heat. The biogas can<br />

be treated in a Combined Heat and Power<br />

Plant (CHP), producing electricity and heat, or<br />

can be upgraded to bio-methane [14] [bM 06/09]<br />

Amorphous | non-crystalline, glassy with unordered<br />

lattice<br />

Amylopectin | Polymeric branched starch<br />

molecule with very high molecular weight<br />

(biopolymer, monomer is →Glucose) [bM 05/09]<br />

Amylose | Polymeric non-branched starch<br />

molecule with high molecular weight (biopolymer,<br />

monomer is →Glucose) [bM 05/09]<br />

Biobased | The term biobased describes the<br />

part of a material or product that is stemming<br />

from →biomass. When making a biobasedclaim,<br />

the unit (→biobased carbon content,<br />

→biobased mass content), a percentage and<br />

the measuring method should be clearly stated [1]<br />

Biobased carbon | carbon contained in or<br />

stemming from →biomass. A material or<br />

product made of fossil and →renewable resources<br />

contains fossil and →biobased carbon.<br />

The biobased carbon content is measured via<br />

the 14 C method (radio carbon dating method)<br />

that adheres to the technical specifications as<br />

described in [1,4,5,6].<br />

Biobased labels | The fact that (and to<br />

what percentage) a product or a material is<br />

→biobased can be indicated by respective<br />

labels. Ideally, meaningful labels should be<br />

based on harmonised standards and a corresponding<br />

certification process by independent<br />

third party institutions. For the property<br />

biobased such labels are in place by certifiers<br />

→DIN CERTCO and →Vinçotte who both base<br />

their certifications on the technical specification<br />

as described in [4,5]<br />

A certification and corresponding label depicting<br />

the biobased mass content was developed<br />

by the French Association Chimie du Végétal<br />

[ACDV].<br />

Biobased mass content | describes the<br />

amount of biobased mass contained in a material<br />

or product. This method is complementary<br />

to the 14 C method, and furthermore, takes<br />

other chemical elements besides the biobased<br />

carbon into account, such as oxygen, nitrogen<br />

and hydrogen. A measuring method has<br />

been developed and tested by the Association<br />

Chimie du Végétal (ACDV) [1]<br />

Biobased plastic | A plastic in which constitutional<br />

units are totally or partly from →<br />

biomass [3]. If this claim is used, a percentage<br />

should always be given to which extent<br />

the product/material is → biobased [1]<br />

[bM <strong>01</strong>/07, bM 03/10]<br />

Biodegradable Plastics | Biodegradable Plastics<br />

are plastics that are completely assimilated<br />

by the → microorganisms present a defined<br />

environment as food for their energy. The<br />

carbon of the plastic must completely be converted<br />

into CO 2<br />

during the microbial process.<br />

The process of biodegradation depends on<br />

the environmental conditions, which influence<br />

it (e.g. location, temperature, humidity) and<br />

on the material or application itself. Consequently,<br />

the process and its outcome can vary<br />

considerably. Biodegradability is linked to the<br />

structure of the polymer chain; it does not depend<br />

on the origin of the raw materials.<br />

There is currently no single, overarching standard<br />

to back up claims about biodegradability.<br />

One standard for example is ISO or in Europe:<br />

EN 14995 Plastics- Evaluation of compostability<br />

- Test scheme and specifications<br />

[bM 02/06, bM <strong>01</strong>/07]<br />

Biogas | → Anaerobic digestion<br />

Biomass | Material of biological origin excluding<br />

material embedded in geological formations<br />

and material transformed to fossilised<br />

material. This includes organic material, e.g.<br />

trees, crops, grasses, tree litter, algae and<br />

waste of biological origin, e.g. manure [1, 2]<br />

Biorefinery | the co-production of a spectrum<br />

of bio-based products (food, feed, materials,<br />

chemicals including monomers or building<br />

blocks for bioplastics) and energy (fuels, power,<br />

heat) from biomass.[bM 02/13]<br />

Blend | Mixture of plastics, polymer alloy of at<br />

least two microscopically dispersed and molecularly<br />

distributed base polymers<br />

Bisphenol-A (BPA) | Monomer used to produce<br />

different polymers. BPA is said to cause<br />

health problems, due to the fact that is behaves<br />

like a hormone. Therefore it is banned<br />

for use in children’s products in many countries.<br />

BPI | Biodegradable Products Institute, a notfor-profit<br />

association. Through their innovative<br />

compostable label program, BPI educates<br />

manufacturers, legislators and consumers<br />

about the importance of scientifically based<br />

standards for compostable materials which<br />

biodegrade in large composting facilities.<br />

Carbon footprint | (CFPs resp. PCFs – Product<br />

Carbon Footprint): Sum of →greenhouse<br />

gas emissions and removals in a product system,<br />

expressed as CO 2<br />

equivalent, and based<br />

on a →life cycle assessment. The CO 2<br />

equivalent<br />

of a specific amount of a greenhouse gas<br />

is calculated as the mass of a given greenhouse<br />

gas multiplied by its →global warmingpotential<br />

[1,2,15]<br />

42 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


Basics<br />

Carbon neutral, CO 2<br />

neutral | describes a<br />

product or process that has a negligible impact<br />

on total atmospheric CO 2<br />

levels. For<br />

example, carbon neutrality means that any<br />

CO 2<br />

released when a plant decomposes or<br />

is burnt is offset by an equal amount of CO 2<br />

absorbed by the plant through photosynthesis<br />

when it is growing.<br />

Carbon neutrality can also be achieved<br />

through buying sufficient carbon credits to<br />

make up the difference. The latter option is<br />

not allowed when communicating → LCAs<br />

or carbon footprints regarding a material or<br />

product [1, 2].<br />

Carbon-neutral claims are tricky as products<br />

will not in most cases reach carbon neutrality<br />

if their complete life cycle is taken into consideration<br />

(including the end-of life).<br />

If an assessment of a material, however, is<br />

conducted (cradle to gate), carbon neutrality<br />

might be a valid claim in a B2B context. In this<br />

case, the unit assessed in the complete life<br />

cycle has to be clarified [1]<br />

Cascade use | of →renewable resources means<br />

to first use the →biomass to produce biobased<br />

industrial products and afterwards – due to<br />

their favourable energy balance – use them<br />

for energy generation (e.g. from a biobased<br />

plastic product to →biogas production). The<br />

feedstock is used efficiently and value generation<br />

increases decisively.<br />

Catalyst | substance that enables and accelerates<br />

a chemical reaction<br />

Cellophane | Clear film on the basis of →cellulose<br />

[bM <strong>01</strong>/10]<br />

Cellulose | Cellulose is the principal component<br />

of cell walls in all higher forms of plant<br />

life, at varying percentages. It is therefore the<br />

most common organic compound and also<br />

the most common polysaccharide (multisugar)<br />

[11]. Cellulose is a polymeric molecule<br />

with very high molecular weight (monomer is<br />

→Glucose), industrial production from wood<br />

or cotton, to manufacture paper, plastics and<br />

fibres [bM <strong>01</strong>/10]<br />

Cellulose ester | Cellulose esters occur by<br />

the esterification of cellulose with organic<br />

acids. The most important cellulose esters<br />

from a technical point of view are cellulose<br />

acetate (CA with acetic acid), cellulose propionate<br />

(CP with propionic acid) and cellulose<br />

butyrate (CB with butanoic acid). Mixed polymerisates,<br />

such as cellulose acetate propionate<br />

(CAP) can also be formed. One of the most<br />

well-known applications of cellulose aceto<br />

butyrate (CAB) is the moulded handle on the<br />

Swiss army knife [11]<br />

Cellulose acetate CA | → Cellulose ester<br />

CEN | Comité Européen de Normalisation<br />

(European organisation for standardization)<br />

Certification | is a process in which materials/products<br />

undergo a string of (laboratory)<br />

tests in order to verify that the fulfil certain<br />

requirements. Sound certification systems<br />

should be based on (ideally harmonised) European<br />

standards or technical specifications<br />

(e.g. by →CEN, USDA, ASTM, etc.) and be<br />

performed by independent third party laboratories.<br />

Successful certification guarantees<br />

a high product safety - also on this basis interconnected<br />

labels can be awarded that help<br />

the consumer to make an informed decision.<br />

Compost | A soil conditioning material of decomposing<br />

organic matter which provides nutrients<br />

and enhances soil structure.<br />

[bM 06/08, 02/09]<br />

Compostable Plastics | Plastics that are<br />

→ biodegradable under →composting conditions:<br />

specified humidity, temperature,<br />

→ microorganisms and timeframe. In order<br />

to make accurate and specific claims about<br />

compostability, the location (home, → industrial)<br />

and timeframe need to be specified [1].<br />

Several national and international standards<br />

exist for clearer definitions, for example EN<br />

14995 Plastics - Evaluation of compostability -<br />

Test scheme and specifications. [bM 02/06, bM <strong>01</strong>/07]<br />

Composting | is the controlled →aerobic, or<br />

oxygen-requiring, decomposition of organic<br />

materials by →microorganisms, under controlled<br />

conditions. It reduces the volume and<br />

mass of the raw materials while transforming<br />

them into CO 2<br />

, water and a valuable soil conditioner<br />

– compost.<br />

When talking about composting of bioplastics,<br />

foremost →industrial composting in a<br />

managed composting facility is meant (criteria<br />

defined in EN 13432).<br />

The main difference between industrial and<br />

home composting is, that in industrial composting<br />

facilities temperatures are much<br />

higher and kept stable, whereas in the composting<br />

pile temperatures are usually lower,<br />

and less constant as depending on factors<br />

such as weather conditions. Home composting<br />

is a way slower-paced process than<br />

industrial composting. Also a comparatively<br />

smaller volume of waste is involved. [bM 03/07]<br />

Compound | plastic mixture from different<br />

raw materials (polymer and additives) [bM 04/10)<br />

Copolymer | Plastic composed of different<br />

monomers.<br />

Cradle-to-Gate | Describes the system<br />

boundaries of an environmental →Life Cycle<br />

Assessment (LCA) which covers all activities<br />

from the cradle (i.e., the extraction of raw materials,<br />

agricultural activities and forestry) up<br />

to the factory gate<br />

Cradle-to-Cradle | (sometimes abbreviated<br />

as C2C): Is an expression which communicates<br />

the concept of a closed-cycle economy,<br />

in which waste is used as raw material<br />

(‘waste equals food’). Cradle-to-Cradle is not<br />

a term that is typically used in →LCA studies.<br />

Cradle-to-Grave | Describes the system<br />

boundaries of a full →Life Cycle Assessment<br />

from manufacture (cradle) to use phase and<br />

disposal phase (grave).<br />

Crystalline | Plastic with regularly arranged<br />

molecules in a lattice structure<br />

Density | Quotient from mass and volume of<br />

a material, also referred to as specific weight<br />

DIN | Deutsches Institut für Normung (German<br />

organisation for standardization)<br />

DIN-CERTCO | independant certifying organisation<br />

for the assessment on the conformity<br />

of bioplastics<br />

Dispersing | fine distribution of non-miscible<br />

liquids into a homogeneous, stable mixture<br />

Drop-In bioplastics | chemically indentical<br />

to conventional petroleum based plastics,<br />

but made from renewable resources. Examples<br />

are bio-PE made from bio-ethanol (from<br />

e.g. sugar cane) or partly biobased PET; the<br />

monoethylene glykol made from bio-ethanol<br />

(from e.g. sugar cane). Developments to<br />

make terephthalic acid from renewable resources<br />

are under way. Other examples are<br />

polyamides (partly biobased e.g. PA 4.10 or PA<br />

6.10 or fully biobased like PA 5.10 or PA10.10)<br />

EN 13432 | European standard for the assessment<br />

of the → compostability of plastic<br />

packaging products<br />

Energy recovery | recovery and exploitation<br />

of the energy potential in (plastic) waste for<br />

the production of electricity or heat in waste<br />

incineration pants (waste-to-energy)<br />

Environmental claim | A statement, symbol<br />

or graphic that indicates one or more environmental<br />

aspect(s) of a product, a component,<br />

packaging or a service. [16]<br />

Enzymes | proteins that catalyze chemical<br />

reactions<br />

Enzyme-mediated plastics | are no →bioplastics.<br />

Instead, a conventional non-biodegradable<br />

plastic (e.g. fossil-based PE) is enriched<br />

with small amounts of an organic additive.<br />

Microorganisms are supposed to consume<br />

these additives and the degradation process<br />

should then expand to the non-biodegradable<br />

PE and thus make the material degrade. After<br />

some time the plastic is supposed to visually<br />

disappear and to be completely converted to<br />

carbon dioxide and water. This is a theoretical<br />

concept which has not been backed up by<br />

any verifiable proof so far. Producers promote<br />

enzyme-mediated plastics as a solution to littering.<br />

As no proof for the degradation process<br />

has been provided, environmental beneficial<br />

effects are highly questionable.<br />

Ethylene | colour- and odourless gas, made<br />

e.g. from, Naphtha (petroleum) by cracking or<br />

from bio-ethanol by dehydration, monomer of<br />

the polymer polyethylene (PE)<br />

European Bioplastics e.V. | The industry association<br />

representing the interests of Europe’s<br />

thriving bioplastics’ industry. Founded<br />

in Germany in 1993 as IBAW, European<br />

Bioplastics today represents the interests<br />

of about 50 member companies throughout<br />

the European Union and worldwide. With<br />

members from the agricultural feedstock,<br />

chemical and plastics industries, as well as<br />

industrial users and recycling companies, European<br />

Bioplastics serves as both a contact<br />

platform and catalyst for advancing the aims<br />

of the growing bioplastics industry.<br />

Extrusion | process used to create plastic<br />

profiles (or sheet) of a fixed cross-section<br />

consisting of mixing, melting, homogenising<br />

and shaping of the plastic.<br />

FDCA | 2,5-furandicarboxylic acid, an intermediate<br />

chemical produced from 5-HMF.<br />

The dicarboxylic acid can be used to make →<br />

PEF = polyethylene furanoate, a polyester that<br />

could be a 100% biobased alternative to PET.<br />

Fermentation | Biochemical reactions controlled<br />

by → microorganisms or → enyzmes (e.g.<br />

the transformation of sugar into lactic acid).<br />

FSC | Forest Stewardship Council. FSC is an<br />

independent, non-governmental, not-forprofit<br />

organization established to promote the<br />

responsible and sustainable management of<br />

the world’s forests.<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 43


Basics<br />

Gelatine | Translucent brittle solid substance,<br />

colorless or slightly yellow, nearly tasteless<br />

and odorless, extracted from the collagen inside<br />

animals‘ connective tissue.<br />

Genetically modified organism (GMO) | Organisms,<br />

such as plants and animals, whose<br />

genetic material (DNA) has been altered<br />

are called genetically modified organisms<br />

(GMOs). Food and feed which contain or<br />

consist of such GMOs, or are produced from<br />

GMOs, are called genetically modified (GM)<br />

food or feed [1]. If GM crops are used in bioplastics<br />

production, the multiple-stage processing<br />

and the high heat used to create the<br />

polymer removes all traces of genetic material.<br />

This means that the final bioplastics product<br />

contains no genetic traces. The resulting<br />

bioplastics is therefore well suited to use in<br />

food packaging as it contains no genetically<br />

modified material and cannot interact with<br />

the contents.<br />

Global Warming | Global warming is the rise<br />

in the average temperature of Earth’s atmosphere<br />

and oceans since the late 19th century<br />

and its projected continuation [8]. Global<br />

warming is said to be accelerated by → green<br />

house gases.<br />

Glucose | Monosaccharide (or simple sugar).<br />

G. is the most important carbohydrate (sugar)<br />

in biology. G. is formed by photosynthesis or<br />

hydrolyse of many carbohydrates e. g. starch.<br />

Greenhouse gas GHG | Gaseous constituent<br />

of the atmosphere, both natural and anthropogenic,<br />

that absorbs and emits radiation at<br />

specific wavelengths within the spectrum of<br />

infrared radiation emitted by the earth’s surface,<br />

the atmosphere, and clouds [1, 9]<br />

Greenwashing | The act of misleading consumers<br />

regarding the environmental practices<br />

of a company, or the environmental benefits<br />

of a product or service [1, 10]<br />

Granulate, granules | small plastic particles<br />

(3-4 millimetres), a form in which plastic is<br />

sold and fed into machines, easy to handle<br />

and dose.<br />

HMF (5-HMF) | 5-hydroxymethylfurfural is an<br />

organic compound derived from sugar dehydration.<br />

It is a platform chemical, a building<br />

block for 20 performance polymers and over<br />

175 different chemical substances. The molecule<br />

consists of a furan ring which contains<br />

both aldehyde and alcohol functional groups.<br />

5-HMF has applications in many different<br />

industries such as bioplastics, packaging,<br />

pharmaceuticals, adhesives and chemicals.<br />

One of the most promising routes is 2,5<br />

furandicarboxylic acid (FDCA), produced as an<br />

intermediate when 5-HMF is oxidised. FDCA<br />

is used to produce PEF, which can substitute<br />

terephthalic acid in polyester, especially polyethylene<br />

terephthalate (PET). [bM 03/14, 02/16]<br />

Home composting | →composting [bM 06/08]<br />

Humus | In agriculture, humus is often used<br />

simply to mean mature →compost, or natural<br />

compost extracted from a forest or other<br />

spontaneous source for use to amend soil.<br />

Hydrophilic | Property: water-friendly, soluble<br />

in water or other polar solvents (e.g. used<br />

in conjunction with a plastic which is not water<br />

resistant and weather proof or that absorbs<br />

water such as Polyamide (PA).<br />

Hydrophobic | Property: water-resistant, not<br />

soluble in water (e.g. a plastic which is water<br />

resistant and weather proof, or that does not<br />

absorb any water such as Polyethylene (PE)<br />

or Polypropylene (PP).<br />

Industrial composting | is an established<br />

process with commonly agreed upon requirements<br />

(e.g. temperature, timeframe) for transforming<br />

biodegradable waste into stable, sanitised<br />

products to be used in agriculture. The<br />

criteria for industrial compostability of packaging<br />

have been defined in the EN 13432. Materials<br />

and products complying with this standard<br />

can be certified and subsequently labelled<br />

accordingly [1,7] [bM 06/08, 02/09]<br />

ISO | International Organization for Standardization<br />

JBPA | Japan Bioplastics Association<br />

Land use | The surface required to grow sufficient<br />

feedstock (land use) for today’s bioplastic<br />

production is less than 0.<strong>01</strong> percent of the<br />

global agricultural area of 5 billion hectares.<br />

It is not yet foreseeable to what extent an increased<br />

use of food residues, non-food crops<br />

or cellulosic biomass (see also →1 st /2 nd /3 rd<br />

generation feedstock) in bioplastics production<br />

might lead to an even further reduced<br />

land use in the future [bM 04/09, <strong>01</strong>/14]<br />

LCA | is the compilation and evaluation of the<br />

input, output and the potential environmental<br />

impact of a product system throughout its life<br />

cycle [17]. It is sometimes also referred to as<br />

life cycle analysis, ecobalance or cradle-tograve<br />

analysis. [bM <strong>01</strong>/09]<br />

Littering | is the (illegal) act of leaving waste<br />

such as cigarette butts, paper, tins, bottles,<br />

cups, plates, cutlery or bags lying in an open<br />

or public place.<br />

Marine litter | Following the European Commission’s<br />

definition, “marine litter consists of<br />

items that have been deliberately discarded,<br />

unintentionally lost, or transported by winds<br />

and rivers, into the sea and on beaches. It<br />

mainly consists of plastics, wood, metals,<br />

glass, rubber, clothing and paper”. Marine<br />

debris originates from a variety of sources.<br />

Shipping and fishing activities are the predominant<br />

sea-based, ineffectively managed<br />

landfills as well as public littering the main<br />

land-based sources. Marine litter can pose a<br />

threat to living organisms, especially due to<br />

ingestion or entanglement.<br />

Currently, there is no international standard<br />

available, which appropriately describes the<br />

biodegradation of plastics in the marine environment.<br />

However, a number of standardisation<br />

projects are in progress at ISO and ASTM<br />

level. Furthermore, the European project<br />

OPEN BIO addresses the marine biodegradation<br />

of biobased products.[bM 02/16]<br />

Mass balance | describes the relationship between<br />

input and output of a specific substance<br />

within a system in which the output from the<br />

system cannot exceed the input into the system.<br />

First attempts were made by plastic raw material<br />

producers to claim their products renewable<br />

(plastics) based on a certain input<br />

of biomass in a huge and complex chemical<br />

plant, then mathematically allocating this<br />

biomass input to the produced plastic.<br />

These approaches are at least controversially<br />

disputed [bM 04/14, 05/14, <strong>01</strong>/15]<br />

Microorganism | Living organisms of microscopic<br />

size, such as bacteria, funghi or yeast.<br />

Molecule | group of at least two atoms held<br />

together by covalent chemical bonds.<br />

Monomer | molecules that are linked by polymerization<br />

to form chains of molecules and<br />

then plastics<br />

Mulch film | Foil to cover bottom of farmland<br />

Organic recycling | means the treatment of<br />

separately collected organic waste by anaerobic<br />

digestion and/or composting.<br />

Oxo-degradable / Oxo-fragmentable | materials<br />

and products that do not biodegrade!<br />

The underlying technology of oxo-degradability<br />

or oxo-fragmentation is based on special additives,<br />

which, if incorporated into standard<br />

resins, are purported to accelerate the fragmentation<br />

of products made thereof. Oxodegradable<br />

or oxo-fragmentable materials do<br />

not meet accepted industry standards on compostability<br />

such as EN 13432. [bM <strong>01</strong>/09, 05/09]<br />

PBAT | Polybutylene adipate terephthalate, is<br />

an aliphatic-aromatic copolyester that has the<br />

properties of conventional polyethylene but is<br />

fully biodegradable under industrial composting.<br />

PBAT is made from fossil petroleum with<br />

first attempts being made to produce it partly<br />

from renewable resources [bM 06/09]<br />

PBS | Polybutylene succinate, a 100% biodegradable<br />

polymer, made from (e.g. bio-BDO)<br />

and succinic acid, which can also be produced<br />

biobased [bM 03/12].<br />

PC | Polycarbonate, thermoplastic polyester,<br />

petroleum based and not degradable, used<br />

for e.g. baby bottles or CDs. Criticized for its<br />

BPA (→ Bisphenol-A) content.<br />

PCL | Polycaprolactone, a synthetic (fossil<br />

based), biodegradable bioplastic, e.g. used as<br />

a blend component.<br />

PE | Polyethylene, thermoplastic polymerised<br />

from ethylene. Can be made from renewable<br />

resources (sugar cane via bio-ethanol) [bM 05/10]<br />

PEF | polyethylene furanoate, a polyester<br />

made from monoethylene glycol (MEG) and<br />

→FDCA (2,5-furandicarboxylic acid , an intermediate<br />

chemical produced from 5-HMF). It<br />

can be a 100% biobased alternative for PET.<br />

PEF also has improved product characteristics,<br />

such as better structural strength and<br />

improved barrier behaviour, which will allow<br />

for the use of PEF bottles in additional applications.<br />

[bM 03/11, 04/12]<br />

PET | Polyethylenterephthalate, transparent<br />

polyester used for bottles and film. The<br />

polyester is made from monoethylene glycol<br />

(MEG), that can be renewably sourced from<br />

bio-ethanol (sugar cane) and (until now fossil)<br />

terephthalic acid [bM 04/14]<br />

PGA | Polyglycolic acid or Polyglycolide is a biodegradable,<br />

thermoplastic polymer and the<br />

simplest linear, aliphatic polyester. Besides<br />

ist use in the biomedical field, PGA has been<br />

introduced as a barrier resin [bM 03/09]<br />

PHA | Polyhydroxyalkanoates (PHA) or the<br />

polyhydroxy fatty acids, are a family of biodegradable<br />

polyesters. As in many mammals,<br />

including humans, that hold energy reserves<br />

in the form of body fat there are also bacteria<br />

that hold intracellular reserves in for of<br />

of polyhydroxy alkanoates. Here the microorganisms<br />

store a particularly high level of<br />

44 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


Basics<br />

energy reserves (up to 80% of their own body<br />

weight) for when their sources of nutrition become<br />

scarce. By farming this type of bacteria,<br />

and feeding them on sugar or starch (mostly<br />

from maize), or at times on plant oils or other<br />

nutrients rich in carbonates, it is possible to<br />

obtain PHA‘s on an industrial scale [11]. The<br />

most common types of PHA are PHB (Polyhydroxybutyrate,<br />

PHBV and PHBH. Depending<br />

on the bacteria and their food, PHAs with<br />

different mechanical properties, from rubbery<br />

soft trough stiff and hard as ABS, can be produced.<br />

Some PHSs are even biodegradable in<br />

soil or in a marine environment<br />

PLA | Polylactide or Polylactic Acid (PLA), a<br />

biodegradable, thermoplastic, linear aliphatic<br />

polyester based on lactic acid, a natural acid,<br />

is mainly produced by fermentation of sugar<br />

or starch with the help of micro-organisms.<br />

Lactic acid comes in two isomer forms, i.e. as<br />

laevorotatory D(-)lactic acid and as dextrorotary<br />

L(+)lactic acid.<br />

Modified PLA types can be produced by the<br />

use of the right additives or by certain combinations<br />

of L- and D- lactides (stereocomplexing),<br />

which then have the required rigidity for<br />

use at higher temperatures [13] [bM <strong>01</strong>/09, <strong>01</strong>/12]<br />

Plastics | Materials with large molecular<br />

chains of natural or fossil raw materials, produced<br />

by chemical or biochemical reactions.<br />

PPC | Polypropylene Carbonate, a bioplastic<br />

made by copolymerizing CO 2<br />

with propylene<br />

oxide (PO) [bM 04/12]<br />

PTT | Polytrimethylterephthalate (PTT), partially<br />

biobased polyester, is similarly to PET<br />

produced using terephthalic acid or dimethyl<br />

terephthalate and a diol. In this case it is a<br />

biobased 1,3 propanediol, also known as bio-<br />

PDO [bM <strong>01</strong>/13]<br />

Renewable Resources | agricultural raw materials,<br />

which are not used as food or feed,<br />

but as raw material for industrial products<br />

or to generate energy. The use of renewable<br />

resources by industry saves fossil resources<br />

and reduces the amount of → greenhouse gas<br />

emissions. Biobased plastics are predominantly<br />

made of annual crops such as corn,<br />

cereals and sugar beets or perennial cultures<br />

such as cassava and sugar cane.<br />

Resource efficiency | Use of limited natural<br />

resources in a sustainable way while minimising<br />

impacts on the environment. A resource<br />

efficient economy creates more output<br />

or value with lesser input.<br />

Seedling Logo | The compostability label or<br />

logo Seedling is connected to the standard<br />

EN 13432/EN 14995 and a certification process<br />

managed by the independent institutions<br />

→DIN CERTCO and → Vinçotte. Bioplastics<br />

products carrying the Seedling fulfil the<br />

criteria laid down in the EN 13432 regarding<br />

industrial compostability. [bM <strong>01</strong>/06, 02/10]<br />

Saccharins or carbohydrates | Saccharins or<br />

carbohydrates are name for the sugar-family.<br />

Saccharins are monomer or polymer sugar<br />

units. For example, there are known mono-,<br />

di- and polysaccharose. → glucose is a monosaccarin.<br />

They are important for the diet and<br />

produced biology in plants.<br />

Semi-finished products | plastic in form of<br />

sheet, film, rods or the like to be further processed<br />

into finshed products<br />

Sorbitol | Sugar alcohol, obtained by reduction<br />

of glucose changing the aldehyde group<br />

to an additional hydroxyl group. S. is used as<br />

a plasticiser for bioplastics based on starch.<br />

Starch | Natural polymer (carbohydrate)<br />

consisting of → amylose and → amylopectin,<br />

gained from maize, potatoes, wheat, tapioca<br />

etc. When glucose is connected to polymerchains<br />

in definite way the result (product) is<br />

called starch. Each molecule is based on 300<br />

-12000-glucose units. Depending on the connection,<br />

there are two types → amylose and →<br />

amylopectin known. [bM 05/09]<br />

Starch derivatives | Starch derivatives are<br />

based on the chemical structure of → starch.<br />

The chemical structure can be changed by<br />

introducing new functional groups without<br />

changing the → starch polymer. The product<br />

has different chemical qualities. Mostly the<br />

hydrophilic character is not the same.<br />

Starch-ester | One characteristic of every<br />

starch-chain is a free hydroxyl group. When<br />

every hydroxyl group is connected with an<br />

acid one product is starch-ester with different<br />

chemical properties.<br />

Starch propionate and starch butyrate |<br />

Starch propionate and starch butyrate can be<br />

synthesised by treating the → starch with propane<br />

or butanic acid. The product structure<br />

is still based on → starch. Every based → glucose<br />

fragment is connected with a propionate<br />

or butyrate ester group. The product is more<br />

hydrophobic than → starch.<br />

Sustainable | An attempt to provide the best<br />

outcomes for the human and natural environments<br />

both now and into the indefinite future.<br />

One famous definition of sustainability is the<br />

one created by the Brundtland Commission,<br />

led by the former Norwegian Prime Minister<br />

G. H. Brundtland. The Brundtland Commission<br />

defined sustainable development as<br />

development that ‘meets the needs of the<br />

present without compromising the ability of<br />

future generations to meet their own needs.’<br />

Sustainability relates to the continuity of economic,<br />

social, institutional and environmental<br />

aspects of human society, as well as the nonhuman<br />

environment).<br />

Sustainable sourcing | of renewable feedstock<br />

for biobased plastics is a prerequisite<br />

for more sustainable products. Impacts such<br />

as the deforestation of protected habitats<br />

or social and environmental damage arising<br />

from poor agricultural practices must<br />

be avoided. Corresponding certification<br />

schemes, such as ISCC PLUS, WLC or Bon-<br />

Sucro, are an appropriate tool to ensure the<br />

sustainable sourcing of biomass for all applications<br />

around the globe.<br />

Sustainability | as defined by European Bioplastics,<br />

has three dimensions: economic, social<br />

and environmental. This has been known<br />

as “the triple bottom line of sustainability”.<br />

This means that sustainable development involves<br />

the simultaneous pursuit of economic<br />

prosperity, environmental protection and social<br />

equity. In other words, businesses have<br />

to expand their responsibility to include these<br />

environmental and social dimensions. Sustainability<br />

is about making products useful to<br />

markets and, at the same time, having societal<br />

benefits and lower environmental impact<br />

than the alternatives currently available. It also<br />

implies a commitment to continuous improvement<br />

that should result in a further reduction<br />

of the environmental footprint of today’s products,<br />

processes and raw materials used.<br />

Thermoplastics | Plastics which soften or<br />

melt when heated and solidify when cooled<br />

(solid at room temperature).<br />

Thermoplastic Starch | (TPS) → starch that<br />

was modified (cooked, complexed) to make it<br />

a plastic resin<br />

Thermoset | Plastics (resins) which do not<br />

soften or melt when heated. Examples are<br />

epoxy resins or unsaturated polyester resins.<br />

Vinçotte | independant certifying organisation<br />

for the assessment on the conformity of bioplastics<br />

WPC | Wood Plastic Composite. Composite<br />

materials made of wood fiber/flour and plastics<br />

(mostly polypropylene).<br />

Yard Waste | Grass clippings, leaves, trimmings,<br />

garden residue.<br />

References:<br />

[1] Environmental Communication Guide,<br />

European Bioplastics, Berlin, Germany,<br />

2<strong>01</strong>2<br />

[2] ISO 14067. Carbon footprint of products -<br />

Requirements and guidelines for quantification<br />

and communication<br />

[3] CEN TR 15932, Plastics - Recommendation<br />

for terminology and characterisation<br />

of biopolymers and bioplastics, 2<strong>01</strong>0<br />

[4] CEN/TS 16137, Plastics - Determination<br />

of bio-based carbon content, 2<strong>01</strong>1<br />

[5] ASTM D6866, Standard Test Methods for<br />

Determining the Biobased Content of<br />

Solid, Liquid, and Gaseous Samples Using<br />

Radiocarbon Analysis<br />

[6] SPI: Understanding Biobased Carbon<br />

Content, 2<strong>01</strong>2<br />

[7] EN 13432, Requirements for packaging<br />

recoverable through composting and biodegradation.<br />

Test scheme and evaluation<br />

criteria for the final acceptance of packaging,<br />

2000<br />

[8] Wikipedia<br />

[9] ISO 14064 Greenhouse gases -- Part 1:<br />

Specification with guidance..., 2006<br />

[10] Terrachoice, 2<strong>01</strong>0, www.terrachoice.com<br />

[11] Thielen, M.: Bioplastics: Basics. Applications.<br />

Markets, Polymedia Publisher,<br />

2<strong>01</strong>2<br />

[12] Lörcks, J.: Biokunststoffe, Broschüre der<br />

FNR, 2005<br />

[13] de Vos, S.: Improving heat-resistance of<br />

PLA using poly(D-lactide),<br />

bioplastics MAGAZINE, Vol. 3, <strong>Issue</strong> 02/2008<br />

[14] de Wilde, B.: Anaerobic Digestion, bioplastics<br />

MAGAZINE, Vol 4., <strong>Issue</strong> 06/2009<br />

[15] ISO 14067 onb Corbon Footprint of<br />

Products<br />

[16] ISO 14021 on Self-declared Environmental<br />

claims<br />

[17] ISO 14044 on Life Cycle Assessment<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 45


Suppliers Guide<br />

1. Raw Materials<br />

AGRANA Starch<br />

Bioplastics<br />

Conrathstraße 7<br />

A-3950 Gmuend, Austria<br />

technical.starch@agrana.com<br />

www.agrana.com<br />

Jincheng, Lin‘an, Hangzhou,<br />

Zhejiang 311300, P.R. China<br />

China contact: Grace Jin<br />

mobile: 0086 135 7578 9843<br />

Grace@xinfupharm.comEurope<br />

contact(Belgium): Susan Zhang<br />

mobile: 0032 478 991619<br />

zxh0612@hotmail.com<br />

www.xinfupharm.com<br />

1.1 bio based monomers<br />

Kingfa Sci. & Tech. Co., Ltd.<br />

No.33 Kefeng Rd, Sc. City, Guangzhou<br />

Hi-Tech Ind. Development Zone,<br />

Guangdong, P.R. China. 510663<br />

Tel: +86 (0)20 6622 1696<br />

info@ecopond.com.cn<br />

www.ecopond.com.cn<br />

FLEX-162 Biodeg. Blown Film Resin!<br />

Bio-873 4-Star Inj. Bio-Based Resin!<br />

Simply contact:<br />

Tel.: +49 2161 6884467<br />

suppguide@bioplasticsmagazine.com<br />

Stay permanently listed in the<br />

Suppliers Guide with your company<br />

logo and contact information.<br />

For only 6,– EUR per mm, per issue you<br />

can be present among top suppliers in<br />

the field of bioplastics.<br />

For Example:<br />

Showa Denko Europe GmbH<br />

Konrad-Zuse-Platz 4<br />

81829 Munich, Germany<br />

Tel.: +49 89 93996226<br />

www.showa-denko.com<br />

support@sde.de<br />

PTT MCC Biochem Co., Ltd.<br />

info@pttmcc.com / www.pttmcc.com<br />

Tel: +66(0) 2 140-3563<br />

MCPP Germany GmbH<br />

+49 (0) 152-<strong>01</strong>8 920 51<br />

frank.steinbrecher@mcpp-europe.com<br />

MCPP France SAS<br />

+33 (0) 6 07 22 25 32<br />

fabien.resweber@mcpp-europe.com<br />

Corbion Purac<br />

Arkelsedijk 46, P.O. Box 21<br />

4200 AA Gorinchem -<br />

The Netherlands<br />

Tel.: +31 (0)183 695 695<br />

Fax: +31 (0)183 695 604<br />

www.corbion.com/bioplastics<br />

bioplastics@corbion.com<br />

62 136 Lestrem, France<br />

Tel.: + 33 (0) 3 21 63 36 00<br />

www.roquette-performance-plastics.com<br />

1.2 compounds<br />

FKuR Kunststoff GmbH<br />

Siemensring 79<br />

D - 47 877 Willich<br />

Tel. +49 2154 9251-0<br />

Tel.: +49 2154 9251-51<br />

sales@fkur.com<br />

www.fkur.com<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

39 mm<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach<br />

Germany<br />

Tel. +49 2161 664864<br />

Fax +49 2161 631045<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

DuPont de Nemours International S.A.<br />

2 chemin du Pavillon<br />

1218 - Le Grand Saconnex<br />

Switzerland<br />

Tel.: +41 22 171 51 11<br />

Fax: +41 22 580 22 45<br />

www.renewable.dupont.com<br />

www.plastics.dupont.com<br />

API S.p.A.<br />

Via Dante Alighieri, 27<br />

36065 Mussolente (VI), Italy<br />

Telephone +39 0424 579711<br />

www.apiplastic.com<br />

www.apinatbio.com<br />

Green Dot Bioplastics<br />

226 Broadway | PO Box #142<br />

Cottonwood Falls, KS 66845, USA<br />

Tel.: +1 620-273-8919<br />

info@greendotholdings.com<br />

www.greendotpure.com<br />

Sample Charge:<br />

39mm x 6,00 €<br />

= 234,00 € per entry/per issue<br />

Sample Charge for one year:<br />

6 issues x 234,00 EUR = 1,404.00 €<br />

The entry in our Suppliers Guide is<br />

bookable for one year (6 issues) and<br />

extends automatically if it’s not canceled<br />

three month before expiry.<br />

Tel: +86 351-8689356<br />

Fax: +86 351-8689718<br />

www.ecoworld.jinhuigroup.com<br />

ecoworldsales@jinhuigroup.com<br />

BIO-FED<br />

Branch of AKRO-PLASTIC GmbH<br />

BioCampus Cologne<br />

Nattermannallee 1<br />

50829 Cologne, Germany<br />

Tel.: +49 221 88 88 94-00<br />

info@bio-fed.com<br />

www.bio-fed.com<br />

NUREL Engineering Polymers<br />

Ctra. Barcelona, km 329<br />

50<strong>01</strong>6 Zaragoza, Spain<br />

Tel: +34 976 465 579<br />

inzea@samca.com<br />

www.inzea-biopolymers.com<br />

www.facebook.com<br />

www.issuu.com<br />

www.twitter.com<br />

www.youtube.com<br />

Xinjiang Blue Ridge Tunhe<br />

Polyester Co., Ltd.<br />

No. 316, South Beijing Rd. Changji,<br />

Xinjiang, 831100, P.R.China<br />

Tel.: +86 994 2713175<br />

Mob: +86 13905253382<br />

lilong_tunhe@163.com<br />

www.lanshantunhe.com<br />

PBAT & PBS resin supplier<br />

Global Biopolymers Co.,Ltd.<br />

Bioplastics compounds<br />

(PLA+starch;PLA+rubber)<br />

194 Lardproa80 yak 14<br />

Wangthonglang, Bangkok<br />

Thailand 10310<br />

info@globalbiopolymers.com<br />

www.globalbiopolymers.com<br />

Tel +66 81 9150446<br />

PolyOne<br />

Avenue Melville Wilson, 2<br />

Zoning de la Fagne<br />

5330 Assesse<br />

Belgium<br />

Tel.: + 32 83 660 211<br />

www.polyone.com<br />

46 bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12


Suppliers Guide<br />

1.6 masterbatches<br />

Tecnaro GmbH<br />

Bustadt 40<br />

D-74360 Ilsfeld. Germany<br />

Tel: +49 (0)7062/97687-0<br />

www.tecnaro.de<br />

1.3 PLA<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

GRANCH BIOPACK CO., LTD<br />

Huanggang, Hubei, China<br />

Tel: +86-(0)713-4253230<br />

Robin.li@salesgh.com<br />

http://xsguancheng.en.alibaba.com<br />

Molds, Change Parts and Turnkey<br />

Solutions for the PET/Bioplastic<br />

Container Industry<br />

284 Pinebush Road<br />

Cambridge Ontario<br />

Canada N1T 1Z6<br />

Tel. +1 519 624 9720<br />

Fax +1 519 624 9721<br />

info@hallink.com<br />

www.hallink.com<br />

JIANGSU SUPLA BIOPLASTICS CO., LTD.<br />

Tel: +86 527 88278888<br />

WeChat: supla-168<br />

supla@supla-bioplastics.cn<br />

www.supla-bioplastics.cn<br />

Zhejiang Hisun Biomaterials Co.,Ltd.<br />

No.97 Waisha Rd, Jiaojiang District,<br />

Taizhou City, Zhejiang Province, China<br />

Tel: +86-576-88827723<br />

pla@hisunpharm.com<br />

www.hisunplas.com<br />

PolyOne<br />

Avenue Melville Wilson, 2<br />

Zoning de la Fagne<br />

5330 Assesse<br />

Belgium<br />

Tel.: + 32 83 660 211<br />

www.polyone.com<br />

2. Additives/Secondary raw materials<br />

Minima Technology Co., Ltd.<br />

Esmy Huang, COO<br />

No.33. Yichang E. Rd., Taipin City,<br />

Taichung County<br />

411, Taiwan (R.O.C.)<br />

Tel. +886(4)2277 6888<br />

Fax +883(4)2277 6989<br />

Mobil +886(0)982-829988<br />

esmy@minima-tech.com<br />

Skype esmy325<br />

www.minima.com<br />

6.2 Laboratory Equipment<br />

MODA: Biodegradability Analyzer<br />

SAIDA FDS INC.<br />

143-10 Isshiki, Yaizu,<br />

Shizuoka,Japan<br />

Tel:+81-54-624-6260<br />

Info2@moda.vg<br />

www.saidagroup.jp<br />

7. Plant engineering<br />

1.4 starch-based bioplastics<br />

BIOTEC<br />

Biologische Naturverpackungen<br />

Werner-Heisenberg-Strasse 32<br />

46446 Emmerich/Germany<br />

Tel.: +49 (0) 2822 – 92510<br />

info@biotec.de<br />

www.biotec.de<br />

Grabio Greentech Corporation<br />

Tel: +886-3-598-6496<br />

No. 91, Guangfu N. Rd., Hsinchu<br />

Industrial Park,Hukou Township,<br />

Hsinchu County 30351, Taiwan<br />

sales@grabio.com.tw<br />

www.grabio.com.tw<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

3. Semi finished products<br />

3.1 films<br />

Infiana Germany GmbH & Co. KG<br />

Zweibrückenstraße 15-25<br />

913<strong>01</strong> Forchheim<br />

Tel. +49-9191 81-0<br />

Fax +49-9191 81-212<br />

www.infiana.com<br />

4. Bioplastics products<br />

Natur-Tec ® - Northern Technologies<br />

42<strong>01</strong> Woodland Road<br />

Circle Pines, MN 55<strong>01</strong>4 USA<br />

Tel. +1 763.404.8700<br />

Fax +1 763.225.6645<br />

info@natur-tec.com<br />

www.natur-tec.com<br />

NOVAMONT S.p.A.<br />

Via Fauser , 8<br />

28100 Novara - ITALIA<br />

Fax +39.0321.699.6<strong>01</strong><br />

Tel. +39.0321.699.611<br />

www.novamont.com<br />

EREMA Engineering Recycling<br />

Maschinen und Anlagen GmbH<br />

Unterfeldstrasse 3<br />

4052 Ansfelden, AUSTRIA<br />

Phone: +43 (0) 732 / 3190-0<br />

Fax: +43 (0) 732 / 3190-23<br />

erema@erema.at<br />

www.erema.at<br />

Uhde Inventa-Fischer GmbH<br />

Holzhauser Strasse 157–159<br />

D-13509 Berlin<br />

Tel. +49 30 43 567 5<br />

Fax +49 30 43 567 699<br />

sales.de@uhde-inventa-fischer.com<br />

Uhde Inventa-Fischer AG<br />

Via Innovativa 31, CH-7<strong>01</strong>3 Domat/Ems<br />

Tel. +41 81 632 63 11<br />

Fax +41 81 632 74 03<br />

sales.ch@uhde-inventa-fischer.com<br />

www.uhde-inventa-fischer.com<br />

1.5 PHA<br />

TianAn Biopolymer<br />

No. 68 Dagang 6th Rd,<br />

Beilun, Ningbo, China, 315800<br />

Tel. +86-57 48 68 62 50 2<br />

Fax +86-57 48 68 77 98 0<br />

enquiry@tianan-enmat.com<br />

www.tianan-enmat.com<br />

Bio4Pack GmbH<br />

D-48419 Rheine, Germany<br />

Tel.: +49 (0) 5975 955 94 57<br />

info@bio4pack.com<br />

www.bio4pack.com<br />

President Packaging Ind., Corp.<br />

PLA Paper Hot Cup manufacture<br />

In Taiwan, www.ppi.com.tw<br />

Tel.: +886-6-570-4066 ext.5531<br />

Fax: +886-6-570-4077<br />

sales@ppi.com.tw<br />

6. Equipment<br />

6.1 Machinery & Molds<br />

9. Services<br />

Osterfelder Str. 3<br />

46047 Oberhausen<br />

Tel.: +49 (0)208 8598 1227<br />

Fax: +49 (0)208 8598 1424<br />

thomas.wodke@umsicht.fhg.de<br />

www.umsicht.fraunhofer.de<br />

Metabolix, Inc.<br />

Bio-based and biodegradable resins<br />

and performance additives<br />

21 Erie Street<br />

Cambridge, MA 02139, USA<br />

US +1-617-583-1700<br />

DE +49 (0) 221 / 88 88 94 00<br />

www.metabolix.com<br />

info@metabolix.com<br />

BeoPlast Besgen GmbH<br />

Bioplastics injection moulding<br />

Industriestraße 64<br />

D-40764 Langenfeld, Germany<br />

Tel. +49 2173 84840-0<br />

info@beoplast.de<br />

www.beoplast.de<br />

Buss AG<br />

Hohenrainstrasse 10<br />

4133 Pratteln / Switzerland<br />

Tel.: +41 61 825 66 00<br />

Fax: +41 61 825 68 58<br />

info@busscorp.com<br />

www.busscorp.com<br />

Institut für Kunststofftechnik<br />

Universität Stuttgart<br />

Böblinger Straße 70<br />

7<strong>01</strong>99 Stuttgart<br />

Tel +49 711/685-62814<br />

Linda.Goebel@ikt.uni-stuttgart.de<br />

www.ikt.uni-stuttgart.de<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 47


Suppliers Guide<br />

www.pu-magazine.com<br />

K2<strong>01</strong>6, hall 15,<br />

booth B27 / C 2 4 / C 27 / D2 4<br />

Engineering Passion<br />

05/2<strong>01</strong>6 OCTOBER/NOVEMBER<br />

www.kraussmaffei.com/experts<br />

Lightweight<br />

construction/<br />

Composites<br />

Automoti<br />

tive<br />

inte<br />

ri<br />

ors<br />

Surf<br />

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Plasticizers, Processing Aids<br />

Activators, Silanes<br />

Desiccants, Antitack Agents<br />

Heat Transfer Fluids<br />

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tpe-e modification<br />

hard-soft composites<br />

new styrene-ethylene copolymer<br />

low-density tpu foam<br />

polytriazines as fire/flame retardant synergists<br />

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narocon<br />

Dr. Harald Kaeb<br />

Tel.: +49 30-28096930<br />

kaeb@narocon.de<br />

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9. Services (continued)<br />

BPI - The Biodegradable<br />

Products Institute<br />

331 West 57th Street, Suite 415<br />

New York, NY 10<strong>01</strong>9, USA<br />

Tel. +1-888-274-5646<br />

info@bpiworld.org<br />

Michigan State University<br />

Dept. of Chem. Eng & Mat. Sc.<br />

Professor Ramani Narayan<br />

East Lansing MI 48824, USA<br />

Tel. +1 517 719 7163<br />

narayan@msu.edu<br />

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10.3 Other Institutions<br />

For Example:<br />

nova-Institut GmbH<br />

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Tel.: +49(0)2233-48-14 40<br />

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39 mm<br />

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10. Institutions<br />

10.1 Associations<br />

IfBB – Institute for Bioplastics<br />

and Biocomposites<br />

University of Applied Sciences<br />

and Arts Hanover<br />

Faculty II – Mechanical and<br />

Bioprocess Engineering<br />

Heisterbergallee 12<br />

30453 Hannover, Germany<br />

Tel.: +49 5 11 / 92 96 - 22 69<br />

Fax: +49 5 11 / 92 96 - 99 - 22 69<br />

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SEEING POLYMERS<br />

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POLYURETHANES MAGAZINE INTERNATIONAL<br />

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Europäischer Weichschaummarkt 2<strong>01</strong>5<br />

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Biobasierte Polyolformulierungen<br />

Fachmagazin für die Polymerindustrie<br />

Ersatz von RFL-Systemen<br />

Lkw-Reifenrecycling<br />

Devulkanisation von S-vernetztem SBR<br />

Kühlmittelbeständigkeit von<br />

Elastomeren – Teil 1<br />

Spritzgießwerkzeugtechnik<br />

Mixing room cost optimization – part 2<br />

Sulfenamide accelerators<br />

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DOTG replacement for AEM, ACM, CR, NR<br />

Magazine for the Polymer Industry<br />

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Intelligent Solutions.<br />

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2<strong>01</strong>7 Intl. Technology & Application Conference on<br />

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organized by bioplastics MAGAZINE<br />

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Basics<br />

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r8_03.2<strong>01</strong>6<br />

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www.bio-based-conference.com<br />

+<br />

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23.05.2<strong>01</strong>7 - 25.05.2<strong>01</strong>7 - New York City Area, USA<br />

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SPC BIOPLASTICS CONVERGE<br />

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Bio-Based Live Europe<br />

31.05.2<strong>01</strong>7 - <strong>01</strong>.06.2<strong>01</strong>7 - Amsterdam, The Netherlands<br />

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Mention the promotion code ‘watch‘ or ‘book‘<br />

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Bioplastics Basics. Applications. Markets. for free<br />

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3) Gratis-Buch in Deutschland nicht möglich, no free book in Germany<br />

ESBP 2<strong>01</strong>7<br />

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6 th International Conference on Biobased and<br />

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11.09.2<strong>01</strong>7 - 13.09.2<strong>01</strong>7 - Mons, Belgium<br />

www. biopol-conf.org<br />

bioplastics MAGAZINE [<strong>01</strong>/17] Vol. 12 49 57


Companies in this issue<br />

Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />

Advanced Biochemical Thailand 12<br />

Agrana 46<br />

Aimplas 11<br />

Akzo Nobel 34<br />

API Appl. Plastiche Industriali 46<br />

AVA-CO2 20<br />

Avalon 20<br />

Avantium 6<br />

BASF 8, 36 9<br />

Beoplast 47<br />

Billerudkorsnas/Fiberform 8<br />

Bio4Pack 8 41, 47<br />

BioAmber 5<br />

Bio-Fed Zweign. der Akro-Plastic 46<br />

Biopolymer Network 40<br />

Biosilutions 33<br />

Biotec 8 9, 47<br />

BPI 22 48<br />

Braskem 8 9<br />

Bunzl 8<br />

Buss 35, 47<br />

CJ CheilJedang 5<br />

Coffee Company 8<br />

ColorFABB 35<br />

Corbion 8 9, 46<br />

Cryostore 34<br />

Cumapol 8<br />

Danimer Scientific 5<br />

DIN Certco 22<br />

Dr. Heinz Gupta Verlag 48<br />

DuPont Performance Materials 8 46<br />

Eindhoven Univ. 26<br />

Elix Polymers 16<br />

EPEA 34<br />

Erema 47<br />

European Bioplastics 8, 9, 22, 40 48<br />

Fiat 11, 18<br />

Fiat Chrysler Automobile 18<br />

FKuR 2, 46<br />

FNR 9<br />

Fraunhofer UMSICHT 32 47<br />

Frost & Sullivan 16<br />

Futamura 8<br />

GRABIO Greentech Corporation 47<br />

Grafe 46, 47<br />

Granch Biopack 47<br />

Green Dot Bioplastics 20 46<br />

Green Serendpity 8, 9 48<br />

Green source 11<br />

Greeny 34<br />

Hallink 47<br />

Holland Bioplastics 8<br />

Infiana Germany 47<br />

Inst. F. Bioplastics & Biocomposites 7, 26 48<br />

Inst. F. Food & Env. Research 32<br />

Inst. Of Chemical Engieers 12<br />

IsoBouw 34<br />

JEC 12<br />

Jinhui Zhaolong 46<br />

Kingfa 46<br />

Kuraray EVAL Europe 8<br />

K-Zeitung 9<br />

Lindar 6<br />

Liquid Light 6<br />

Loick Biowertstoffe 32<br />

Mazda 10<br />

Meredian 5<br />

Metabolix 47<br />

MHG 5<br />

Michigan State University 48<br />

Minima Technology 47<br />

Mitsubishi Chemical 10, 15<br />

narocon 48<br />

NatureWorks 8<br />

Natur-Tec 47<br />

Nile Univ. 28<br />

NNRGY 8<br />

nova-Institute 8 10, 25, 31, 48<br />

Novamont 22 47, 52<br />

Novon Polymers 22<br />

Nurel 46<br />

O‘Right 8<br />

Organic Waste Systems 22<br />

OWS 8<br />

packaging europe 9<br />

Photanol 21<br />

plasticker 9 11<br />

Plastics in Packaging 9<br />

Plastimar 34<br />

polymediaconsult 48<br />

PolyOne 46, 47<br />

President Packaging 47<br />

Procter & Gamble 22<br />

PTT/MCC 8 46<br />

Purdue Univ. 27<br />

RadiciGroup 18<br />

Renault 14<br />

Rodenburg 8<br />

Roquette 46<br />

Saida 47<br />

Scion 8, 40<br />

Seepje 8<br />

Showa Denko 7 46<br />

Singapore Univ. 30<br />

Smithers-Rapra 29<br />

Snyprodo 34<br />

Solaris 11<br />

Solegear 6<br />

Solvay Epicerol 12<br />

Storopack Deutschland 32<br />

Styropack 34<br />

Supla 47<br />

Sustainability Consult 9<br />

Sustainable Packaging Coalition 9<br />

Swak Experience 26<br />

Synbra Group 34<br />

Taghleef Industrie 8<br />

Tecnaro 47<br />

Termo Komfort 34<br />

Tetra Pak 38<br />

thinkstep 34<br />

TianAn Biopolymer 47<br />

Uhde Inventa-Fischer 47<br />

Univ. Cantabria 11<br />

Univ. Nottingham 28<br />

Univ. Stuttgart (IKT) 47<br />

VDI 121<br />

Vegware 27<br />

Vinçotte 5, 22<br />

Wyss Institute (Harvard) 30<br />

Xinjiang Blue Ridge Tunhe Polyester 46<br />

Zandonella 34<br />

Zhejiang Hangzhou Xinfu Pharmaceutical 46<br />

Zhejiang Hisun Biomaterials 38, 47<br />

<strong>Issue</strong><br />

Editorial Planner<br />

Month<br />

02/2<strong>01</strong>7 Mar<br />

Apr<br />

03/2<strong>01</strong>7 May<br />

Jun<br />

04/2<strong>01</strong>7 Jul<br />

Aug<br />

05/2<strong>01</strong>7 Sep<br />

Oct<br />

06/2<strong>01</strong>7 Nov<br />

Dec<br />

Publ.<br />

Date<br />

edit/ad/<br />

Deadline<br />

2<strong>01</strong>7<br />

03 Apr 17 05 Mar 17 Thermoforming<br />

Rigid Packaging<br />

05 Jun 17 05 May 17 Injection<br />

moulding<br />

Edit. Focus 1 Edit. Focus 2 Edit. Focus 3 Basics<br />

Bioplastics in<br />

agriculture /<br />

horticulture<br />

07 Aug 17 07 Jul 17 Blow Moulding Biocomposites<br />

incl. Thermoset<br />

02 Oct 17 <strong>01</strong> Sep 17 Fiber / Textile /<br />

Nonwoven<br />

04 Dec 17 03 Nov 17 Films/Flexibles/<br />

Bags<br />

Germany/Austria<br />

Switzerland<br />

Special<br />

“Biodegradability/<br />

compostability”-<br />

standards & certification<br />

Trade-Fair<br />

Specials<br />

interpack &<br />

Chinaplas<br />

preview<br />

Food packaging China Special FAQ (update) interpack &<br />

Chinaplas<br />

review<br />

Beauty &<br />

Healthcare<br />

Polyurethanes/<br />

Elastomers/<br />

Rubber<br />

Scandinavia<br />

Special<br />

North America<br />

Special<br />

Italy/France<br />

Special<br />

"biobased" - standards<br />

and certification<br />

(C14; mass balance)<br />

Land use for bioplastics<br />

(update)<br />

Blown film extrusion<br />

Composites<br />

Europe<br />

Preview<br />

Subject to changes


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BIODEGRADABLE AND COMPOSTABLE BIOPLASTIC<br />

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EcoComunicazione.it<br />

QUALITY OUR TOP PRIORITY<br />

Using the MATER-BI trademark licence<br />

means that NOVAMONT’s partners agree<br />

to comply with strict quality parameters and<br />

testing of random samples from the market.<br />

These are designed to ensure that films<br />

are converted under ideal conditions<br />

and that articles produced in MATER-BI<br />

meet all essential requirements. To date<br />

over 1000 products have been tested.<br />

THE GUARANTEE<br />

OF AN ITALIAN BRAND<br />

MATER-BI is part of a virtuous<br />

production system, undertaken<br />

entirely on Italian territory.<br />

It enters into a production chain<br />

that involves everyone,<br />

from the farmer to the composter,<br />

from the converter via the retailer<br />

to the consumer.<br />

USED FOR ALL TYPES<br />

OF WASTE DISPOSAL<br />

MATER-BI has unique,<br />

environmentally-friendly properties.<br />

It is biodegradable and compostable<br />

and contains renewable raw materials.<br />

It is the ideal solution for organic<br />

waste collection bags and is<br />

organically recycled into fertile<br />

compost.<br />

r8_03.2<strong>01</strong>6

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