Issue 01/2014
Highlights: Automotive Foam Pharmafilter Land use
Highlights:
Automotive
Foam
Pharmafilter
Land use
Create successful ePaper yourself
Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.
ioplastics MAGAZINE Vol. 9 ISSN 1862-5258<br />
Highlights<br />
Foam | 26<br />
Automotive | 15<br />
Pharmafilter | 30<br />
Land use | 34<br />
January/February<br />
Cover-Story<br />
<strong>01</strong> | 2<strong>01</strong>4<br />
BioFoam ®<br />
Ice-cream container | 26<br />
... is read in 91 countries
Bio-Flex ® for mulch films<br />
Certified as compostable, Bio-Flex ® F 1130 is<br />
widely recommended for biodegradable mulch<br />
films. As a ready-to-use blend, Bio-Flex ® F 1130<br />
is easily processed using standard production<br />
equipment. In addition, biodegradable mulch<br />
films made from Bio-Flex ® F 1130 can be laid<br />
down on the field using the same equipment as<br />
conventional polyethylene films. Thus this material<br />
is a natural drop-in replacement for oil based PE.<br />
Mulch films made from Bio-Flex ® offer:<br />
• Compostability according to EN 13432,<br />
ASTM D 6400, NFU 520<strong>01</strong><br />
• Stable during use, good disintegration<br />
in soil after ploughing in<br />
• Cost efficient, no collection is required to dispose<br />
of the film after use, thickness reduction<br />
• Superior water resistance<br />
• High strength and tear resistance<br />
• Good weed suppression<br />
For more information visit<br />
www.fkur.com • www.fkur-biobased.com
Editorial<br />
dear<br />
readers<br />
It is early February, and it is cold in Germany (and not only here)… but<br />
ice cream is a thing that I can enjoy all year round. And thanks to modern<br />
logistics and modern insulating materials, it can be enjoyed far away<br />
from its production site – even in summer. Our cover story is about such<br />
a modern insulating packaging solution. It is part of one of the editorial<br />
focal topics in this issue: foam. The other highlight is Bioplastics in automotive<br />
applications. Here we can see that this is not just about projects,<br />
but about real applications that you can already find on the market – for<br />
example in Ford, Volkswagen or Mercedes vehicles.<br />
In the Basics section we again address the topic of land use. How<br />
much of the arable land on this planet is used for the production of<br />
bioplastics (and other products) today – and in future.<br />
A very interesting experience for me and some colleagues was a visit<br />
to the Reinier de Graaf hospital, in Delft, the Netherlands. We wanted to<br />
see with our own eyes what Pharmafilter is doing there. bioplastics<br />
MAGAZINE already reported about Pharmafilter (bM <strong>01</strong>/2<strong>01</strong>0 and 04/2<strong>01</strong>1)<br />
and the unique concept was awarded the second prize of the 8 th<br />
Bioplastics Award in December.<br />
But who was the actual winner of the 8 th Bioplastics Award? See yourself<br />
on page 9.<br />
Now, after a pause of two years, bioplastics MAGAZINE would like to<br />
invite you to the 3 rd PLA World Congress. We will hold this unique event<br />
again in Munich, Germany, on May 27 th and 28 th , 2<strong>01</strong>4. Please have a look<br />
in the preliminary programme on page 10. We are still able to accept<br />
proposals for presentations. A few slots are still available.<br />
Until then we hope you enjoy reading bioplastics MAGAZINE<br />
Sincerely yours<br />
Michael Thielen<br />
Follow us on twitter!<br />
www.twitter.com/bioplasticsmag<br />
Be our friend on Facebook!<br />
www.facebook.com/bioplasticsmagazine<br />
bioplastics MAGAZINE [<strong>01</strong>/14] Vol.9 3
Content<br />
Editorial ............................. 3<br />
News ............................. 5 - 7<br />
Event Calendar ....................... 42<br />
Suppliers Guide .................. 43 - 45<br />
Glossary ........................ 38 - 40<br />
Companies in this issue ............... 46<br />
<strong>01</strong>|2<strong>01</strong>4<br />
January/February<br />
Events<br />
8 th Bioplastics Award – and the winner is... . 8<br />
8 th European Bioplastics Conference ...... 9<br />
3 rd PLA World Congress ................ 10<br />
Report<br />
Do bioplastics disturb recycling streams? ...............12<br />
Recycling of PLA for packaging applications .............22<br />
Pharmafilter: Reinventing waste as a resource ...........30<br />
Automotive<br />
Bio-materials at Ford ................................15<br />
PLA compounds for the automotive sector. ..............16<br />
PA 410 makes inroads into automotive market ...........18<br />
Bio-PPA to replace metal & rubber. ....................21<br />
Applications<br />
New bioplastic applications in windows .................25<br />
Foam<br />
PLA foam protects ice cream. .........................26<br />
Foam grade PBAT ...................................28<br />
Mushroom packaging. ...............................29<br />
Basics<br />
Facts on land use for old and new biobased plastics ......34<br />
Imprint<br />
Publisher / Editorial<br />
Dr. Michael Thielen (MT)<br />
Samuel Brangenberg (SB)<br />
contributing editor: Karen Laird (KL)<br />
Layout/Production<br />
Mark Speckenbach<br />
Julia Hunold<br />
Head Office<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
41066 Mönchengladbach, Germany<br />
phone: +49 (0)2161 6884469<br />
fax: +49 (0)2161 6884468<br />
info@bioplasticsmagazine.com<br />
www.bioplasticsmagazine.com<br />
Media Adviser<br />
Elke Hoffmann, Caroline Motyka<br />
phone: +49(0)2161-6884467<br />
fax: +49(0)2161 6884468<br />
eh@bioplasticsmagazine.com<br />
Print<br />
Kössinger AG<br />
84069 Schierling/Opf., Germany<br />
Print run: 4,000 copies<br />
bioplastics magazine<br />
ISSN 1862-5258<br />
bM is published 6 times a year.<br />
This publication is sent to qualified<br />
subscribers (149 Euro for 6 issues).<br />
bioplastics MAGAZINE is printed on<br />
chlorine-free FSC certified paper.<br />
bioplastics MAGAZINE is read in 91 countries.<br />
Not to be reproduced in any form<br />
without permission from the publisher.<br />
The fact that product names may not be<br />
identified in our editorial as trade marks is<br />
not an indication that such names are not<br />
registered trade marks.<br />
bioplastics MAGAZINE tries to use British<br />
spelling. However, in articles based on<br />
information from the USA, American<br />
spelling may also be used.<br />
Editorial contributions are always welcome.<br />
Please contact the editorial office via<br />
mt@bioplasticsmagazine.com.<br />
Envelopes<br />
A part of this print run is mailed to the readers<br />
wrapped in Green PE envelopes sponsored by<br />
FKuR Kunststoff GmbH and Oerlemans<br />
Plastics B.V<br />
Cover<br />
Cover Ad: Zandonella GmbH<br />
Foto: © Piotr Marcinski (fotolia)<br />
Follow us on twitter:<br />
http://twitter.com/bioplasticsmag<br />
Like us on Facebook:<br />
http://www.facebook.com/pages/bioplastics-MAGAZINE/103745406344904
News<br />
Compostable micro-irrigation systems<br />
Four companies are working together in the European<br />
Project DRIUS; the Spanish company Extruline Systems,<br />
the Israeli Metzerplas, the Spanish research organization<br />
AIMPLAS (Technological Institute of Plastics) and OWS N.V.<br />
(Belgium), as coordinator.<br />
The main objective of this project is to implement in the<br />
market new micro-irrigation systems 100% compostable as<br />
a solution to manage the plastic and the green waste in a<br />
composting plant at the end of the crop period. The new system<br />
will not require the separation or the burning of the pipes and<br />
green waste.<br />
The main applications of the system to be developed in<br />
DRIUS will be crops of small plants such as strawberries and<br />
tomatoes with short periods of cultivations, less than a year.<br />
Currently, the problem after the crop period is the difficulty<br />
in the recycling of the irrigation system because of the mix<br />
of plastic with plants and soil, so the common solution is the<br />
burning of the waste generated. However, the new compostable<br />
system will make possible to treat the waste in a composting<br />
plant.<br />
DRIUS is the continuation of a previous project called<br />
HYDRUS, where new biodegradable micro-irrigation pipes<br />
were developed and satisfactorily manufactured in industrial<br />
extrusion lines.<br />
The main focus of<br />
the present project<br />
is to manufacture<br />
biodegradable drippers<br />
by injection to obtain<br />
the complete system.<br />
The material and the<br />
geometry of drippers<br />
are important to have<br />
the water flow required in the different crops. The material<br />
adjusted for the drippers needs to be processable by injection,<br />
chemically compatible and weldable with the pipes and will<br />
maintain its shape and functionality during the use of the<br />
micro-irrigation systems in the field.<br />
The specific role of AIMPLAS in the project will be to<br />
optimize the suitable material for drippers to make possible<br />
the industrialization of the micro-irrigation system. Extruline<br />
Systems will be responsible for manufacturing the complete<br />
micro-irrigation system (pipes and drips) at industrial level.<br />
Metzerplas is going to design the new moulds and will be<br />
the injector for flat drippers. Lastly, Organic Waste Systems<br />
will carry out the complete study of biodegradation and<br />
compostability in order to obtain the compostability logo.<br />
www.drius.eu<br />
iBIB 2<strong>01</strong>4/15<br />
International Business Directory for Bio-based Materials + CO 2 based<br />
Pictures: nova-Institute,<br />
Sainsbury’s<br />
• Are you involved with Bio-based Materials,<br />
Intermediates or Raw Materials?<br />
• Do you know all of your potential suppliers<br />
and customers?<br />
• Do they know you?<br />
• If not, how about easily boosting<br />
your connectivity worldwide?<br />
Publisher<br />
www.nova-institute.eu<br />
www.bioplasticsmagazine.com<br />
Get visualized and findable! Present your company, products<br />
and services to more than 60,000 potential<br />
clients from all over the world!<br />
iBIB2<strong>01</strong>4/ 15: 250 pages – 100 companies,<br />
associations, R&D – 20 countries<br />
Book your pages now at:<br />
www.bio-based.eu/iBIB<br />
In cooperation with<br />
www.agrobiobase.com<br />
Register today at: www.bio-based.eu/iBIB
News<br />
Bio-based engineering<br />
plastic for automotive<br />
touch panels<br />
Mitsubishi Chemical Corporation (headquartered in Chiyodaku,<br />
Tokyo, Japan) recently announced the development of a<br />
new grade of high-performance, high-transparency bio-based<br />
engineering plastic called DURABIOTM, using plant-derived<br />
isosorbide as its raw material. The new material features<br />
excellent optical properties and high resistance to heat and<br />
humidity.<br />
MCC will move aggressively to promote sales of Durabio for<br />
use in touch panels on automobiles, a sector where demand is<br />
expected to increase significantly.<br />
Touch panels for automobiles are used mainly to control air<br />
conditioning, audio, and car navigation systems. Durabio offers<br />
excellent flexibility in design and can enhance the appearance<br />
of automobile interiors, so MCC anticipates much wider use<br />
and steady growth in demand.<br />
In contrast to easily breakable glass, transparent plastics<br />
such as impact-resistant polycarbonate, are used for the<br />
front plate of automobile touch panels for safety purposes.<br />
The disadvantage of polycarbonates, however, is distortion in<br />
light transmission, which makes it difficult for users to see the<br />
touch panel, so a material that could overcome this problem<br />
has been eagerly awaited.<br />
MCC’s new grade of Durabio features excellent optical<br />
properties, and nearly eliminates distortion in light<br />
transmission, making it easy to see the touch panel surface. MT<br />
www.www.m-kagaku.co.jp<br />
Biodegradable<br />
exfoliator for shower gels<br />
Lessonia (Saint-Thonan – France) is a leading supplier<br />
of natural exfoliators for shower gels and peeling products.<br />
The company recently launched CELLULOSCRUB, a major<br />
innovation to replace the polyethylene beads in cosmetic<br />
products. Celluloscrub is a 100% renewable and biodegradable<br />
exfoliating ingredient made of modified cellulose extracted<br />
from wood pulp. It is said to offer the same high performance<br />
of PE.<br />
Other eco-friendly alternatives for PE beads are for example<br />
exfoliating products made from shells, kernels, minerals,<br />
bamboo, rice, natural waxes, PLA or microcrystalline<br />
cellulose. However, all these ingredients are inferior in all<br />
their characteristics compared to PE (i.e. white colour, stability,<br />
abrasiveness, suspension capacity, etc).<br />
Micro beads made of conventional plastics used as exfoliating<br />
ingredients in personal care products have raised concern<br />
among many environmental groups for its assumed impact<br />
on marine ecosystems. Because sewage and waste water<br />
treatment systems cannot filter out these non-biodegradable<br />
particles they are pumped straight into water courses and end<br />
up in the ocean where they cause irreparable damage to the<br />
oceans. Micro plastics are present in all the seas and oceans<br />
of the world. It is the responsibility of the cosmetic industry to<br />
reduce their impact on the environment.<br />
Leading cosmetics makers, such as Unilever or Lush, as a<br />
consequence, have announced their intention to phase out the<br />
use of these beads and are looking for environmental friendly<br />
alternatives. MT (Source: Lessonia)<br />
Pretreating cellulosic biomass<br />
Aphios Corporation of Woburn, Massachussetts, USA recently<br />
today announced that it was granted a US patent for its cellulosic<br />
biomass pretreatment technology platform (Aosic).<br />
Cellulosic biomass resources are currently greatly<br />
underutilized around the world. If effectively exploited, these<br />
resources can reduce climate change while alleviating several<br />
energy and environmental problems. Dr. Trevor P. Castor,<br />
inventor of the Aosic platform states that “Cellulosic biomass<br />
is tightly wound for obvious mechanical strength reasons. In<br />
order to breakdown cellulose into its individual sugar molecules,<br />
cellulosic biomass must be expanded to enhance the access of<br />
enzymes that cleave the polymeric bonds between individual<br />
sugar molecules.”<br />
Steam explosion is the most commercially used method for<br />
expanding cellulosic fibers that has several disadvantages<br />
including degradation of cellulose and hemicelluloses, the<br />
generation of toxic byproducts and high water and energy<br />
consumption.<br />
In the Aosic process, biomass is contacted with SuperFluids<br />
such as CO 2<br />
with or without small quantities of polar cosolvents<br />
such as ethanol, both sourced from the downstream fermentation<br />
process. Pressure is released and fibers are made more accessible<br />
to enzymes as a result of expansive forces of SuperFluids (about<br />
10 times those of steam explosion) and carbonic acid hydrolysis.<br />
Additional fiber separation is achieved by ejecting biomass<br />
through mechanical impact devices. Carbon dioxide is recovered<br />
and recycled; pressure energy is recovered in a turbine.<br />
Dr. Castor points out that “CO 2<br />
is consumed in the Aosic<br />
process which is a net consumer of carbon. It also utilizes<br />
significantly less water than steam explosion and the dilute acid<br />
pre-hydrolysis pretreatment process. It can be used for wood<br />
cuttings, bagasse, newsprint, corn fodder and spent biomass<br />
from the manufacturing of natural pharmaceuticals and<br />
nutraceuticals.” The primary potential application is pretreating<br />
biomass waste for conversion into ethanol which could then be<br />
used as a precursor for e.g. biobased Polyethylene or PET and<br />
much more. MT<br />
www.aphios.com<br />
6 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
News<br />
Bacteria help convert syngas into Plexiglas<br />
For the first time, Evonik Industries has managed to use<br />
biotech methods to convert syngas to pure 2-hydroxyisobutyric<br />
acid (2-HIBA) under industrial conditions. 2-HIBA is a precursor<br />
used in the manufacture of PLEXIGLAS® (PMMA, Polymethyl<br />
methacrylate, acrylic glass). Waste gas is one example of a<br />
source of syngas.<br />
Syngases are gas mixtures consisting primarily of carbon<br />
monoxide or of carbon dioxide and hydrogen. These gases<br />
can be generated from municipal or agricultural waste, or<br />
from the waste gases produced in industries such as steel<br />
production. Syngas has been used for synthesizing chemicals<br />
for decades. For the ability to convert carbon monoxide, carbon<br />
dioxide, and hydrogen into more valuable molecules, Evonik<br />
looked to bacteria from earth’s earliest history—to a time when<br />
oxygen was not yet present in earth’s atmosphere. Certain<br />
microorganisms today still contain the genetic information for<br />
these processes. Evonik has used their enzymes to create a cell<br />
factory that generates specialty chemicals from syngas.<br />
Evonik scientists are now working at top speed to optimize<br />
these ideas and develop them still further. “We have a long way<br />
to go before we can use bacteria for converting syngas to highquality<br />
specialty chemicals on a large industrial scale,” says<br />
magnetic_148,5x105.ai 175.00 lpi 15.00° 75.00° 0.00° 45.00° 14.03.2009 10:13:31<br />
Prozess CyanProzess MagentaProzess GelbProzess Schwarz<br />
Dr. Thomas Haas, head of Biotechnology at Creavis, Evonik’s<br />
strategic innovation unit. “It will still take a couple of years until<br />
it is ready for the market.”<br />
As Haas explains, “We’re exploring third-generation<br />
biotechnology, because in addition to sugar or residual plant<br />
materials converted to syngas, waste from other sources such<br />
as municipal waste and industrial waste gas can also serve<br />
as raw materials. That makes us less dependent not only on<br />
fossil-based raw materials, but also on renewable resources<br />
that could potentially compete with the food supply.”<br />
2-HIBA can also be produced via chemical synthesis. Both<br />
the chemically-produced and biotech-produced products can<br />
be converted to methyl methacrylate (MMA). MMA is used in<br />
paints, varnishes, and anti-rust coatings, as well as in soft<br />
contact lenses and dental implants. Poly(methyl methacrylate)<br />
(PLEXIGLAS®) is used for creating sheets, profiles, roofs,<br />
soundproof walls, molded components for automotive<br />
engineering applications, and backlight units for illuminating<br />
flat-screen monitors and televisions. MT<br />
www.evonik.com<br />
Magnetic<br />
for Plastics<br />
• International Trade<br />
in Raw Materials,<br />
Machinery & Products<br />
Free of Charge<br />
• Daily News<br />
from the Industrial Sector<br />
and the Plastics Markets<br />
• Current Market Prices<br />
for Plastics.<br />
• Buyer’s Guide<br />
for Plastics & Additives,<br />
Machinery & Equipment,<br />
Subcontractors<br />
and Services.<br />
www.plasticker.com<br />
• Job Market<br />
for Specialists and<br />
Executive Staff in the<br />
Plastics Industry<br />
Up-to-date • Fast • Professional<br />
bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 7
Events<br />
Wolfgang Bauer (company Helmut<br />
Lingemann) with Michael Thielen<br />
Chung-Jen (Robin) Wu (Supla)<br />
Peter Kelly (Pharmafilter)<br />
And the winner is ...<br />
8 th Global Bioplastics Award for Helmut Lingemann<br />
This year the prestigious “Bioplastics Oskar” was given<br />
to Helmut Lingemann GmbH & Co. KG (Wuppertal,<br />
Germany) for their innovative spacer profiles NIROTEC<br />
EVO for insulating window glazing.<br />
The Annual Global Bioplastics Award, proudly presented<br />
by bioplastics MAGAZINE, was awarded for the 8 th time now.<br />
The award recognises innovation, success and achievements<br />
by manufacturers, processors, brand owners or users of<br />
bioplastic materials. It was given to Wolfgang Bauer, Head<br />
of Quality Management of Helmut Lingemann on December<br />
10 th 2<strong>01</strong>3, during the 8 th European Bioplastics Conference in<br />
Berlin. From a list of almost 20 proposals five judges from<br />
the academic world, the press and industry associations<br />
from America, Europa and Asia have selected five finalists<br />
and now announced the winner.<br />
Helmut Lingemann GmbH & Co.KG have been involved for<br />
more than 30 years as an innovative market leader in The<br />
new spacer system NIROTEC EVO is applied in windows and<br />
facades with a high level of insulation to reduce the energy<br />
losses by using double and triple glazing.<br />
The technological requirements are high strength and<br />
structural reinforcement (e.g. tensile modulus), low thermal<br />
conductivity, no fogging when used in insulating glass, no<br />
incompatibility with other components in the insulation<br />
of windows and facades. In combination with the target of<br />
reducing the use of fossil fuels this can only be achieved by<br />
using a biopolymer. Together with a partner, a tailor-made<br />
blend of different biopolymers based on PLA, biopolyester<br />
and further additives were developed, which met the<br />
requirements 100%.<br />
Until now about 2 million metres of NIROTEC EVO have<br />
been processed into insulating glass units. The biopolymer<br />
ratio is approximately 40 tonnes. If NIROTEC EVO were used<br />
for the total annual production of insulating glass units in<br />
Europe, about 18,000 tonnes of this bioplastic material could<br />
be applied. The material selection of stainless steel foil and<br />
this bioplastic material for the manufacture of such spacers<br />
is unique. The applicability and thermal characteristics<br />
of the material combination for the spacer NIROTEC EVO<br />
represents a milestone in innovation for the insulating glass<br />
industry.<br />
“The judges decided for Helmut Lingemann’s spacer<br />
profiles, because this is an example which shows that potential<br />
applications can be found in areas that do not come to ones<br />
mind immediately. And even though it offers a potential for<br />
high volumes of a bioplastic material,” said Michael Thielen,<br />
publisher of bioplastics MAGAZINE and member of the jury.<br />
“And the application makes use of the biopolymers very<br />
special properties, in this case the mechanical and thermal<br />
properties combined with the very important feature of ‘no<br />
fogging’ which is essential for this application.<br />
In addition the chosen biopolymer blend features very<br />
special adhesion properties and allows high speed bending<br />
procedures of the profiles. Modern thermal insulation<br />
technology meets modern materials; this is how ecological<br />
development should look like in todays technology age”,<br />
Michael Thielen added.<br />
This year for the first time also a second prize was awarded.<br />
Since both proposals had received the same number of<br />
points from the judges, this year the secoind prize went to<br />
two runner-ups: Supla and Kuender received the prize for<br />
the PLA-compound application introduced in the last issue of<br />
bioplastics MAGAZINE: Kuender’s 21.5” all-in-one touch screen<br />
PC.<br />
The other second prize went to Pharmafilter for the<br />
holistic approach of an anaerobic digestion system<br />
for hospitals (and other facilities). For more detailed<br />
information please read the article on pages 30f.<br />
www.bioplastics-award.com<br />
8 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
Events<br />
More than 350 participants from 215 companies caught up<br />
on the latest discussions, developments and progress in<br />
the bioplastics industry during the 8 th European Bioplastics<br />
Conference. Once more, the leading European event for the<br />
bioplastics industry provided excellent opportunities for networking,<br />
knowledge exchange and business contacts. 86 %of the participants<br />
came from Europe, 8 % from North America and South<br />
America, and the majority of the remaining 6 % from Asia.<br />
“Bioplastics made from bio-feedstock, and reintegrated into the<br />
biosphere as a nutrient, or recycled together with conventional<br />
plastic, clearly have a potential for being a truly sustainable<br />
material. And it could reduce fossil fuel consumption,” stated<br />
EU Environment Commissioner Janez Potočnik in his opening<br />
speech to the 8 th European Bioplastics Conference on the 10 and<br />
11 December in Berlin, Germany. In his video message he pointed<br />
to the crucial role, bioplastics can play in Europe’s transition<br />
towards a circular biobased economy.<br />
Potočnik encouraged the bioplastics industry “to continue their<br />
work on making bioplastics a truly sustainable material, neutral<br />
in its impact on food production and biodiversity”. However,<br />
he also pointed out that the industry needs to continuously<br />
and transparently inform the public about their products and<br />
processes in order to clarify its position and prosper in the future.<br />
These recommendations were picked up directly by a group of<br />
experts in a panel discussion on sustainability criteria investigating<br />
the most relevant question: “How to assess the sustainability of<br />
bioplastics in a fair way?” The panel started with a presentation<br />
by Professor Matthias Finkbeiner from the Technical University<br />
Berlin on “Perspectives of Life Cycle Assessment of Bioplastics”.<br />
“LCA is still the best available tool to assess the environmental<br />
performance of bioplastics as fact-based as possible”, Finkbeiner<br />
stated and commented on the Product Environmental Footprint<br />
(PEF) approach introduced by the European Commission as<br />
“LCA overkill introducing pseudo solutions in order to achieve<br />
comparability”.<br />
8 th European<br />
Bioplastics<br />
Conference<br />
connected expert elite<br />
on bioplastics<br />
The panel discussion then focussed on the need to break down<br />
the complexity of assessing the sustainability of bioplastics, the<br />
need to use available and valid methodologies and to provide easy<br />
to use tools to consumers to understand these assessments and<br />
how they impact on the product they are using.<br />
Another highlight of the 8 th European Bioplastics Conference<br />
was the annual market data update by European Bioplastics and<br />
the Institute for Bioplastics and Biocomposites (IfBB - University<br />
of Applied Arts Hannover, Germany). The data once more<br />
emphasised the success of bioplastics industry with production<br />
capacities multiplying from around 1.4 million tonnes in 2<strong>01</strong>2 to<br />
more than 6 million tonnes in 2<strong>01</strong>7. All material types are gaining<br />
ground with biobased, non-biodegradable ‘drop-in’ solutions,<br />
such as biobased PE and biobased PET, leading the field.<br />
As in previous years, bioplastics MAGAZINE got the chance<br />
to honour the winner of the Annual Global Bioplastics Award.<br />
The prize was awarded to company Helmut Lingemann GmbH<br />
& Co.KG for their new spacer system NIROTEC EVO. For more<br />
details see page 8. MT<br />
www.european-bioplastics.org<br />
Mark your<br />
calendar:<br />
The 9th European Bioplastics<br />
Conference will be in<br />
Brussels/Belgium on<br />
02-03 December 2<strong>01</strong>4<br />
bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 9
Events<br />
3 rd PLA World Congress<br />
27 + 28 MAY 2<strong>01</strong>4 MUNICH › GERMANY<br />
bioplastics MAGAZINE presents:<br />
3 rd PLA World Congress<br />
The 3 rd PLA World Congress in Munich/Germany, organised by bioplastics MAGAZINE<br />
is the must-attend conference for everyone 27 + 28 MAY interested 2<strong>01</strong>4 in MUNICH PLA, its › benefits, GERMANY and<br />
challenges. The conference offers high class presentations from top individuals in<br />
the industry and also offers excellent networkung opportunities along with a table<br />
top exhibition. Please find below the preliminary programme. Find more details and<br />
register at the conference website<br />
www.pla-world-congress.com<br />
3 rd PLA World Congress, preliminary programme<br />
Tuesday, May 27, 2<strong>01</strong>4<br />
(subject to changes, visit www.pla-world-congress for updates)<br />
08:00 - 08:30 Registration, Welcome-Coffee<br />
08.30 - 08.45 Michael Thielen, Polymedia Publisher Welcome<br />
08:45 - 09:15 Hasso von Pogrell, European Bioplastics Keynote Speech: t.b.d.<br />
09:15 - 09:40 Udo Mühlbauer, Uhde Inventa-Fischer PLA for fibres and textiles<br />
09:40 - 10:05 Emmanuel Rapendy, Sulzer Chemtech Latest developments in High Performance PLA Production<br />
10:05 - 10:30 Marcel Dartee, Polyone Raising the bar: PLA for durable applications<br />
10:30 - 10:55 Q&A<br />
10:55 - 11:20 Coffeebreak<br />
11:20 - 11:45 Frank Diodato, NatureWorks latest developments in Ingeo Biopolymers for packaging,<br />
fibres and durable applications<br />
11:45 - 12:10 Francois de Bie, Corbion-Purac High Heat PLA, from concept to reality !<br />
12:10 - 12:35 Andrew Gill, Floreon Increasing the Functionality & Performance of PLA<br />
12:35 - 12:50 Q&A<br />
12:50 - 14:00 Lunch<br />
14:00 - 14:35 Patrick Zimmermann, FkUR Different markets, different requirements – Customized PLA-developments<br />
14:35 - 14:50 Daniela Jahn, IfBB Processing and stabilization of different types of PLA<br />
14:50 - 15:15 Kevin Moser, Fraunhofer ICT Profile Extrusion – New opportunities for PLA compounds<br />
15.15 - 15:40 Tang Junsheng, Tianjin Glory Tang Technology PLA commercial application & waste recycle<br />
15:40 - 15:55 Q&A<br />
15:55 - 16:30 Coffeebreak<br />
16:35 - 17:00 Bob Engle, Metabolix PLA modification using new PHA copolymers<br />
Wednesday, May 28, 2<strong>01</strong>4<br />
09:00 - 09:25 Paolo Serafini, Taghleef Industries NATIVIA – The BoPLA film for packaging and labelling applications<br />
09:25 - 09:50 Jarl De Bruyne, Sidaplax Specialty Films The next generation of PLA shrink films<br />
09:50 - 10:15 Francesca Brunori, Roechling Automotive Plantura, ecofriendly automotive biopolymer<br />
10:15 - 10:40 N.N., t.b.c. A brand owners view to PLA: Chances and challenges<br />
10:40 - 10:55 Q&A<br />
10.55 - 11:20 Coffeebreak<br />
11:20 - 11:45 Peter Matthijsen, Synbra BioFoam expanding further<br />
11:45 - 12:10 N.N. t.b.c.<br />
12:10 - 12:35 N.N. t.b.c.<br />
12:35 - 12:50 Q&A<br />
12:50 - 14:00 Lunch<br />
14:00 - 14:35 Ramani Narayan, Michigan State University New developments & Strategies in PLA end-of-life – biodegradability - compostability<br />
and recycling issues<br />
14:35 - 14:50 Gerold Breuer, Erema Boost in recycling efficiency - the new Counter Current technology<br />
14:50 - 15:15 Steve Dejonghe, Looplife Upcycling of PLA waste<br />
15.15 - 15:40 Tanja Siebert, Fraunhofer IVV PLA recycling-techniques. State of the art and research. Chances and<br />
opportunities.<br />
15:40 - 15:55 Q&A<br />
16:00 - 16:30 Panel discussion: t.b.d.<br />
Call for papers is still open.<br />
Please send your abstract to mt@bioplasticsmagazine.com<br />
10 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
3 rd PLA World Congress<br />
27 + 28 MAY 2<strong>01</strong>4 MUNICH › GERMANY<br />
PLA is a versatile bioplastics raw material from<br />
renewable resources. It is being used for films<br />
and rigid packaging, for fibres in woven and<br />
non-woven applications. Automotive industry<br />
and consumer electronics are thoroughly<br />
investigating and even already applying PLA.<br />
New methods of polymerizing, compounding<br />
or blending of PLA have broadened the range<br />
of properties and thus the range of possible<br />
applications.<br />
That‘s why bioplastics MAGAZINE is now<br />
organizing the 3 rd PLA World Congress on:<br />
27-28 May 2<strong>01</strong>4 in Munich / Germany<br />
Experts from all involved fields will share their<br />
knowledge and contribute to a comprehensive<br />
overview of today‘s opportunities and challenges<br />
and discuss the possibilities, limitations and<br />
future prospects of PLA for all kind of<br />
applications. Like the first two congresses<br />
the 3 rd PLA World Congress will also offer<br />
excellent networking opportunities for all<br />
delegates and speakers as well as exhibitors of<br />
the table-top exhibition.<br />
The conference will comprise high class presentations on<br />
Register now !<br />
Early Bird discount ends Feb 28<br />
register online before 28 th February 2<strong>01</strong>4 to<br />
benefit from the Early Bird discount.<br />
The conference fee is EUR 899.00<br />
before the Early Bird deadline you pay just<br />
EUR 799.00<br />
The conferece fee includes documentation,<br />
meals and refreshments. Don't miss the<br />
legendary Bavarian Night in a rustic Munich<br />
beerhouse<br />
› Please find the online registration form as well as<br />
an updated programme at<br />
www.pla-world-congress.com<br />
• Latest developments<br />
• High temperature behaviour<br />
• Blends and Compounds<br />
• Foam<br />
• Processing<br />
• Additives<br />
• Stabilization<br />
• Applications (packaging and durable applications)<br />
• Fibers, fabrics, textiles, nonwovens<br />
• Recycling<br />
organized by<br />
we thank our sponsors:
People Report<br />
Do bioplastics disturb<br />
recycling streams?<br />
Just as a reminder: Bioplastics are A) biobased plastics<br />
made from renewable resources (which can be biodegradable<br />
or not) or B) biodegradable plastics (which can<br />
be made from renewable resources or not), thus some bioplastics<br />
are both (see also definition on page 38).<br />
Summary<br />
Biobased (non-compostable) plastics films, e.g. made<br />
from Braskem’s Green PE, are chemically identical to<br />
conventional plastics and are no more difficult to manage in<br />
plastic recycling streams.<br />
Compostable plastics are designed for organic recycling.<br />
They are clearly marked for this purpose with logos such as<br />
the Seedling logo (cf. p 14).<br />
In the event that compostable plastics do end up in<br />
conventional plastic recycling streams, the prevalent sorting<br />
technologies are able to sort them with little residual waste.<br />
When residual amounts remain, they are similar to, or<br />
easier to handle than current residual wastes in the PE stream<br />
(e.g. PS, PP, PET). They should not then add significantly to<br />
the cost or complexity of recycling processes, or the valuable<br />
recovery of recycled PE.<br />
This remains true up to a share of 10% compostable<br />
plastics in the waste stream. At this level or below, studies<br />
show negligible impact on the technical performance of<br />
recycled PE.<br />
As the market share of compostable plastics increases it<br />
will be economically rewarding to sort them out positively.<br />
This is technically possible today and should create new and<br />
valuable markets for the Waste Management Industry.<br />
The authors believe then, aside from the social and<br />
environmental benefits of bioplastics, the best evidence<br />
clearly shows that these materials are an economic<br />
opportunity, not a threat to the waste management industry.<br />
Bioplastics in mixed waste streams<br />
Modern waste recovery systems cope with intermingled<br />
materials, including a variety of different polymer types.<br />
Automated plants sort out the profitable parts of the waste<br />
stream (for example PE, or PET). The promising polymers<br />
are separated. The rest ends up in another container, usually<br />
marked and resold as ‘mixed plastics’.<br />
To achieve this advanced sorting systems use a variety of<br />
analytical methods including near infrared, ultraviolet, x-ray,<br />
laser, polarized light, fluorescent light, electrostatic, melting<br />
point and other techniques. These methods are effective in<br />
keeping contamination of the main recycling streams with<br />
unwanted material low.<br />
Biodegradable plastics should end up in biowaste bins. If<br />
such bins are not available they can still be clearly identified<br />
from their labels and sorted out for delivery to a biowaste<br />
processer.<br />
However, even in well working systems an intermingling<br />
of waste streams cannot be completely avoided. Nonbiodegradable<br />
plastics can end up in the organic waste<br />
stream (e.g. misthrows) and biodegradable, compostable<br />
plastics might be found in mechanical recycling (e.g.<br />
misidentification ). It is already the case that conventional<br />
plastics find their way, in low volumes, to the wrong stream.<br />
12 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
Report<br />
photo: Fotolia/azthesmudger<br />
It can then be stated that in well run waste management<br />
facilities most residual bioplastic will end up as ‘mixed<br />
plastic’ until such a time as recovery is profitable. It can also<br />
be said, even when incorrectly sorted, that bioplastics today<br />
do not enter the waste stream in sufficient volume to cause<br />
concern more than any other type of plastic.<br />
The case against bioplastics is not<br />
evidence-based<br />
Voices in some parts of the waste management industry<br />
claim that bioplastics are a serious disturbance to the<br />
established recycling streams of for example, PE or PET.<br />
The following research and evidence refutes these<br />
assertions. It suggests the influence on the collection and<br />
processing of profitable materials is negligible.<br />
Biobased Polyethylene (PE, not<br />
biodegradable or compostable)<br />
Biobased PE is obtained by polymerisation of ethylene<br />
monomers. Depending on the polymerisation process<br />
biobased LDPE or biobased HDPE can be produced. The only<br />
difference to fossil-based PE is the source, which is plant<br />
based (bioethanol made from sugar cane, sugar beet, wheat<br />
etc.).<br />
As a result fossil and plant based PE are chemically<br />
identical. They share the exact same physical properties.<br />
Therefore biobased PE can be mechanically recycled with<br />
the fossil based PE in the corresponding recycling streams.<br />
There is no new issue.<br />
PLA/PBAT blends (compostable according<br />
to EN 13432, ASTM D6400, etc)<br />
Studies by the University of Hanover/Germany [1], [2]<br />
examined the influence of different compostable plastics<br />
on low-density polyethylene (LDPE). The tested mixtures<br />
contained between 0.5 % to 10 % foreign material. The LDPE<br />
contaminants were a PLA/PBAT blend (Ecovio® by BASF),<br />
pure PBAT and a starch blend. They found:<br />
• Mixtures of LDPE with PLA/PBAT showed the same<br />
viscosity behaviour, elasticity, and tensile strength as pure<br />
LDPE.<br />
• No optical (i.e. transparency or appearance) changes could<br />
be observed.<br />
• There was a slight decrease in the melt-flow rate at 10%<br />
foreign material.<br />
The biodegradable polyester PBAT was also tested as a<br />
possible contaminant for LDPE. The blending of pure PBAT<br />
with LDPE had no influence on the viscosity behaviour<br />
compared with pure LDPE and was affirmed to have no<br />
influence on the processing properties. The values for melt<br />
flow rate were close to the ones of pure LDPE and were also<br />
described to result in no distinctive disturbances during<br />
processing of the material. Optical changes could also not<br />
be observed.<br />
Below 10% contamination there is no issue<br />
bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 13
Report<br />
compostable<br />
Example of a compostability<br />
logo: the ‘Seedling’ logo of<br />
European Bioplastics, awarded by<br />
independent certification institutes<br />
Starch blends (compostable according<br />
to EN 13432)<br />
A study by BIOTEC [3] has evaluated tensile strength,<br />
elongation at break and specific impact resistance for<br />
mixtures of PE with possible contaminations with a starch/<br />
PBAT (Bioplast® by Biotec) blend as well as PP and PS. It<br />
was shown that the biodegradable starch blend contaminates<br />
PE no more than a contamination with conventional plastics<br />
such as PS or PP.<br />
In most cases the properties of the mixtures of PE with PS<br />
or PP as contaminants showed worse performances than the<br />
contamination of PE with a starch blend.<br />
However, the same study found out that even smallest<br />
amounts of PET (2%) in a PE recycling stream results in<br />
serious problems. Due to the comparatively high melting<br />
temperature of PET (approx. 250°C), it was impossible to run<br />
a PE-based blown-film.<br />
These results suggest that the contaminating effect<br />
of a compostable plastic on PE is actually less than the<br />
contaminating effect of PET on PE.<br />
A study by the University of Hanover [1] also examined<br />
a starch blend used in flexible packaging applications.<br />
It was found that the influence on the viscosity and flow<br />
characteristics was only marginal up to the tested ratio of<br />
10%.<br />
Concerning the melt flow rate the influence on the<br />
processing properties was described as low considered<br />
with the pure LDPE. A change of colour was observed with<br />
increasing amount of starch blend.<br />
Tests carried out at the Plastics Testing Laboratory<br />
Foundation of the Polytechnic Institute of Milan and the<br />
Proplast Laboratories in Tortona/Italy (on behalf of CONAI,<br />
the National Packaging Consortium in Italy) [4], have<br />
confirmed that it is possible to reprocess and recycle bags<br />
of a starch based material (MaterBi® by Novamont) and<br />
traditional plastic shopping bag waste up to a concentration<br />
of 10% of starch-blends as input material.<br />
CONAI found that flexible, compostable packaging can be<br />
recycled with common plastics packaging materials up to a<br />
content of 10% without any problems [5].<br />
CONAI concluded that even if biodegradable bags are not<br />
disposed off properly they do not interfere with the recycling<br />
stream of conventional plastics. MT<br />
This article is an abridged and edited version of a more<br />
comprehensive Meta-Study published by European<br />
Bioplastics. The complete Meta-Study can be downloaded<br />
from www.bioplasticsmagazine.de/2<strong>01</strong>4<strong>01</strong><br />
References:<br />
[1] A. Kitzler, Bioplastics in Waste<br />
Management Streams, Dissertation,<br />
University of Hannover, 2<strong>01</strong>3<br />
[2] H.-J. Endres, A.-A. de la Cruz, Influence<br />
of PLA/PBAT material (ecovio) on<br />
the recycling of conventional LD PE,<br />
University of Hannover, 2<strong>01</strong>3<br />
[3] C. Heß, Influence of BIOPLAST-Material<br />
and conventional non-PE Plastics on the<br />
mechanical Properties of recycled PE-<br />
Film, BIOTEC, Presented at K Fair 2<strong>01</strong>3<br />
[4] Italian National Packaging Consortium<br />
CONAI, Findings of Biodegradable<br />
Packaging Recovery Project. Presented<br />
at the European Bioplastics Conference,<br />
Berlin, 2<strong>01</strong>3.<br />
[5] http://www.ecodallecitta.it/notizie.<br />
php?id=114824, last accessed Jan21,<br />
2<strong>01</strong>4<br />
14 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
Automotive<br />
Bio-<br />
materials<br />
at Ford<br />
Instrument panel P Ford B-Max<br />
(Photo: IAC Group)<br />
As it is well-known, Ford Motor Company’s efforts to<br />
implement recycled and renewable materials in their<br />
vehicles are about a century old. In the early twentieth<br />
century, it was Henry Ford himself who led those efforts.<br />
Today, Ford has a comprehensive team working to fulfil its<br />
vision of ensuring that their products are engineered to enable<br />
their leadership on applying those sustainable materials<br />
without compromising product quality, durability, performance,<br />
or economics.<br />
The portfolio of biomaterials that Ford’s teams have been<br />
investigating and successfully managed to implement in their<br />
vehicles is quite extensive: from soy foams to ground tires<br />
mixed with bio-based foams; from natural fiber reinforced<br />
polypropylene to castor oil based polyamide (cf. bM <strong>01</strong>/2<strong>01</strong>3).<br />
Among these available bio-based materials, the natural<br />
fiber reinforced polypropylene (NF-PP) presents a great<br />
potential to multiply the number of applications in the<br />
short to-mid-term due to its good mechanical properties,<br />
environmental performance and attractive weight saving<br />
potential when replacing mineral and glass filled compounds.<br />
In order to exploit this potential, Ford Motor Company has<br />
been cooperating with material and component developers in<br />
several fields to fill up the gap preventing PP-NF large scale<br />
production of (and usage in) injection molded parts.<br />
Due to today’s short vehicle development time and the<br />
many and multifaceted requirements, the development of<br />
all car components using CAE methods and models is a<br />
crucial topic to series implementation. In order to fulfil this<br />
demand, the Ford Research and Advanced Engineering team<br />
in Aachen, Germany, has been leading a project to generate<br />
data and develop CAE methods that allow the simulation of<br />
natural fiber composites.<br />
The project, which is called Natural Fiber Composite-/<br />
NFC-Simulation, is funded by the German Federal Ministry<br />
of Food, Agriculture and Consumer Protection (BMELV)<br />
through the Agency for Renewable Resources e.V. (FNR). It<br />
includes eleven partners covering the whole supplier chain<br />
and features experts from academic areas. This project<br />
aims at generating a complete and integrated solution for<br />
the simulation of NF composites, from material processing<br />
to crash simulation of automotive parts. In order to achieve<br />
these capabilities, many technical and scientific challenges<br />
had to be addressed and solved in detail and the results<br />
integrated into a holistic solution. The detailed tasks are:<br />
• establishing the micro-mechanical characteristics<br />
of natural fibers before and after compounding with<br />
polymer(s)<br />
• deriving suitable fiber orientation models<br />
• modeling typical side-effects when using NF plastics<br />
(fiber damage, separation etc.)<br />
• manufacturing NF compounds and test parts produced<br />
under uniform processing conditions<br />
• describing the rheological and thermal characteristics of<br />
NF compounds completely<br />
• determining quasi-static and dynamic mechanical<br />
characteristics<br />
• scaling up compound production for selected materials to<br />
(near-)series conditions<br />
• integrating material models with commercial CAE<br />
software, especially for processing and crash simulation<br />
purposes<br />
• simulating a series component (process and crash<br />
simulation)<br />
• producing the series component and conducting extensive<br />
mechanical testing, including crash response of high<br />
dynamic impact tests<br />
This project is running until mid of 2<strong>01</strong>4. Once the work is<br />
completed, Ford Motor Company expects to have contributed<br />
to improving the acceptance of such materials and opening<br />
the door for NF compounds into mass production in the<br />
entire automotive industry.<br />
www.ford.com<br />
bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 15
People Automotive<br />
PLA compounds<br />
for the automotive sector<br />
By:<br />
Francesca Brunori<br />
Advanced Development<br />
Engine Systems<br />
Röchling Automotive<br />
Laives, Italy<br />
www.roechling.com<br />
Francesca.Brunori@roechling-automotive.it<br />
Röchling Automotive (headquartered in Mannheim Germany) is now<br />
prepared to produce a wide range of automotive plastic parts made of<br />
Plantura PLA based biopolymers. According to the specialists in airflow,<br />
acoustic and thermal solutions for passenger cars and trucks, Plantura<br />
is a very interesting ecological and economical alternative to the usage of<br />
other (conventional) thermoplastic materials used for such applications today.<br />
It was in the early 1970s when Röchling Automotive started production of<br />
plastic applications with natural fibre reinforcement. A large quantity and<br />
variety of thermoplastic and thermoset solutions for the interior of passenger<br />
vehicles made the group one of the leaders in this field. From biologically<br />
reinforced parts to Plantura Röchling Automotive has taken various steps of<br />
development.<br />
Up to 95% Bio<br />
Röchling Automotive has built up internal competences in raw materials<br />
development for many years. together with various partners. For Plantura a<br />
very fruitful cooperation with a compounder and Corbion Purac (Gorinchem,<br />
The Netherlands) was established to enhance the technical expertise and<br />
abilities in the fields of bio-chemicals, polymerization and compounding.<br />
From the beginning, the target was to create a new bio-polymer family that<br />
can cope with the high technical requirements and specifications, set for<br />
Röchling Automotive’s product portfolio in the engine compartment, under<br />
the body and in the interior.<br />
The result of the hard work is the material family called Plantura. Due to<br />
the possibility of fine tuning the grades according to the applications, it is<br />
possible to have both hard and soft materials, maintaining good properties<br />
and a high biobased carbon content of up to 95%. As a result, the developed<br />
grades could be capable of competing with most polyesters available on the<br />
market (PC, PET, PBT) but also with polystyrenes (ABS), polyolefines (such as<br />
PP) and polyamides (PA6).<br />
Various grades for different requirements<br />
Four standard grades are already available and can target low to medium<br />
demanding under the hood applications, as well as interiors and underbody<br />
applications. The use in other than automotive markets, such as white goods,<br />
sports goods and many others, is not excluded. Every standard grade can be<br />
fine-tuned to meet customer needs and final application requirements. The<br />
compounds can be processed as well as recycled with established plastic<br />
processing and recycling technologies.<br />
Two of these grades were already certified for their biobased content by<br />
Vinçotte with the highest Class 4 score. The Ok Biobased conformity mark<br />
16 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
Automotive<br />
Fig. 1: Deflector made of<br />
unreinforced Plantura<br />
Fig. 2: Air - Filter-housing<br />
made of Plantura , 30 %<br />
reinforced with wood fibres<br />
can be applied on the products made from these grades.<br />
Plantura, in comparison to standard PLA, showed significant<br />
improvements in thermal stability and chemical resistance.<br />
An outstanding impact resistance for shockproof parts has<br />
been tested down to -30°C with the talcum filled standard<br />
grade. The materials exhibit an excellent hydrolysis resistance<br />
in a 100% humid environment at 70°C. The scratch resistance<br />
behavior of PLA, important for aesthetic trims, is well known<br />
and considered in the Plantura formulations.<br />
Tailor made with exceptional properties<br />
Prototype filter boxes were tested according to OEM’s<br />
specifications, withstanding thermal cycles up to 140°C<br />
with glass fiber reinforcement. The same parts performed<br />
also a vehicle testing and run 100.000 km without showing<br />
problems. By comparison, unreinforced standard PLA is not<br />
at all suitable for technical applications due to its low long<br />
term heat resistance of just 60°C.<br />
One of the four standard grades has been specially<br />
developed for automotive interior applications. The testing<br />
performed on this grade, according to OEM‘s specifications,<br />
showed very good results, especially in term of scratch and<br />
UV resistance. Plantura has a very good colourability, which<br />
can be further optimized by the addition of bio fillers. It is<br />
quite easy to obtain a glossy surface and a very natural<br />
aesthetic look.<br />
Supporting sustainability<br />
The environmental impact of Plantura is indeed much lower.<br />
Considerable improvements on automotive applications<br />
made in against PP, PC, ABS, or PA are possible. More in<br />
detail, the CO2 equivalent emission of Plantura for each kg of<br />
produced material is around 7 times lower with respect to PP<br />
and approximately 12 times lower than PA.<br />
A middle class passenger car contains approximately 147<br />
kg of petrochemical plastics which could be easily substituted<br />
by Plantura. This would mean a CO 2<br />
equivalent emission<br />
reduction of around 515 Kg CO 2<br />
equivalent per car.<br />
The continuous development of the material has led to<br />
higher, and increasingly interesting cost efficiency. With its<br />
significant contribution to an improved CO 2<br />
balance, Plantura<br />
could become an important concept in the automotive world.<br />
Fig. 3: Air-Filter-housing<br />
made of Plantura , 30 %<br />
reinforced with wood fibres<br />
Fig. 4: Interior trim parts made of Plantura<br />
grade (left natural color, unfilled, right ‘natural<br />
look’ 30%reinforced with wood fibres<br />
bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 17
People Automotive<br />
PA 410 makes inroads<br />
into automotive market<br />
Polyamides based on renewable feedstocks are well suited for highperformance<br />
applications in the automotive industry, where OEMs are<br />
particularly keen to improve the sustainability of their operations and<br />
of their vehicles. DSM’s polyamide 410, trade named EcoPaXX ® , is 70% biobased<br />
derived from a renewable feedstock, castor oil.<br />
EcoPaXX has a very interesting property set: on the one hand it has<br />
mechanical properties such as stiffness and toughness that are similar to<br />
those of conventional aliphatic polyamides such as PA66, PA6; on the other<br />
hand, it has properties typical of long-chain polyamides such as PA610 and<br />
PA612: low moisture uptake, chemical- and hydrolysis resistance, and high<br />
thermal stability, for example.<br />
The main raw material of the polymer is sebacic acid, which is derived from<br />
castor plants, which can grow on semi-arid land in countries such as India,<br />
China and Brazil. EcoPaXX is carbon neutral from cradle-to-gate (see fig. 1),<br />
meaning that the carbon dioxide generated in producing the polymer is<br />
compensated by the carbon dioxide absorbed during plant growth.<br />
Polyamide 410 has a glass transition temperature, T g<br />
, of 70°C, a very high<br />
crystalline melting point, T m<br />
of 250°C, the highest of any bio-plastic, and a<br />
high crystallization rate. This results in a high tensile modulus in the dry state,<br />
close to that of PA66. Moreover, due to its low moisture uptake, the decrease<br />
of its tensile modulus after conditioning is limited. Its deflection temperature<br />
under load (DTUL or HDT-B ) is also impressive: 175°C under 0.45 MPa load.<br />
The material’s high melting point and rapid crystallization rate ensure short<br />
injection molding cycles. It also offers a broad processing window.<br />
Ideal for parts in engine compartments and exhaust systems<br />
Numerous automotive applications—notably engine compartment<br />
components—are increasingly subject to tougher specifications, be they<br />
in temperature resistance, dimensional stability or chemical resistance.<br />
EcoPaXX is a serious contender in such applications.<br />
The good hydrolysis resistance of EcoPaXX is important for several<br />
applications in engine compartment cooling systems: these include radiator<br />
& charge air cooler end caps, thermostat housings, water pump housings<br />
and impellers, water valves, coolant recovery tanks, and cooling water pipes.<br />
EcoPaXX provides a better/safer solution in cooling applications than current<br />
PA66 based applications, especially when temperatures increase above 130oC.<br />
Even at elevated temperatures, EcoPaXX resists everything from automotive<br />
liquids such as coolants, fuels, oil and grease to dilute acids, bases and<br />
detergents, to aqueous salt solutions such as calcium-and-zinc chloride.<br />
18 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
Automotive<br />
EcoPaXX shows superior retention of mechanical properties<br />
upon ageing in CE10 and B30 biodiesel. For example, while<br />
stiffness and strength of 30% glass reinforced PA12 after 500<br />
hours at 100°C in CE10 fuel is already at the level of an unfilled<br />
resin, performance of an equivalent reinforced EcoPaXX grade<br />
remains high for up to 1500 h.<br />
With its higher chemical resistance, EcoPaXX provides a<br />
better solution in AdBlue applications in SCR (selective catalytic<br />
reduction) systems than PA66 (see fig. 2), especially when<br />
temperatures increase to 80°C. AdBlue is a solution of urea in<br />
water used in SCR catalytic converters on diesel engines to break<br />
down hazardous nitrogen oxides (NOx) formed during combustion<br />
into nitrogen and water.<br />
DSM currently has five commercial injection molding grades<br />
of EcoPaXX: a general purpose, unfilled injection molding grade<br />
(Q150-D); two glass-reinforced types (30% and 50% respectively,<br />
Q-HG6 and Q-HG10) for use in applications where high stiffness<br />
and toughness are needed; a glass/mineral reinforced injection<br />
molding grade, especially suited for the injection molding of<br />
large parts which should have low warpage and excellent surface<br />
quality (Q-HGM24); and a halogen-free flame-retardant glass<br />
reinforced (30%) compound, with a UL 94 V-0 rating at 0.75 mm<br />
(Q-KGS6).Impact modified grades and grades with carbon fibre<br />
reinforcement are available for sampling.<br />
Proven applications<br />
Several interesting applications involving EcoPaXX have recently<br />
been commercialized. Mercedes-Benz, for example, chose<br />
EcoPaXX Q-HGM24, a glass/mineral reinforced injection molding<br />
grade, for the engine beauty cover of the latest version of its<br />
A-Class small family car (cf. bM 02/2<strong>01</strong>3). The cover meets strict<br />
performance requirements and it provides good aesthetics. And<br />
even more, Mercedes Benz achieved its targets in reducing fuel<br />
consumption compared with the previous A-Class generation, as<br />
well as in reducing carbon footprint.<br />
Mercedes-Benz says production of an engine cover in EcoPaXX<br />
results in only around 40% of the quantity of carbon dioxide<br />
emissions that would be necessary in order to produce the same<br />
component from a conventional polyamide.<br />
Global Warming Potential**<br />
120%<br />
100%<br />
Retention of Ts [%]<br />
80%<br />
60%<br />
40%<br />
20%<br />
0 PA66 PC ABS PA610 PA1<strong>01</strong>0 PP Eco-<br />
PaXX<br />
Base polymers*<br />
Assessment method: IPCC 2007 GWP 100a<br />
*Sources: Ecolnvent database; external publications; DSM primary data.<br />
**All GWP values are normalized to the highest value.<br />
Fig. 1: Cradle to gate carbon footprint of several polymers<br />
110<br />
100<br />
90<br />
80<br />
70<br />
60 0 10 20 30<br />
Time [Days]<br />
40<br />
PA410-GF30 PA410-GF40-I PA66-GF30<br />
Fig. 2: Ts after AdBlue-ageing<br />
bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 19
Automotive<br />
DSM has also partnered with automotive component<br />
specialist KACO in the development of a lightweight multifunctional<br />
crank shaft cover (cf. bioplastics MAGZINE issue<br />
05/2<strong>01</strong>3) in EcoPaXX for the latest generation of diesel<br />
engines developed by the Volkswagen Group, resulting in<br />
a significant cost and weight reduction.<br />
Fig. 3: Concept in-mold-formed<br />
housing cover<br />
Future developments<br />
DSM is developing new high-performance reinforced<br />
injection moulding compounds of EcoPaXX. It is also<br />
actively involved in programs to develop high-speed<br />
processing technologies to produce automotive structural<br />
and semi-structural components in thermoplastics<br />
composites containing mats and tapes of continuous fibres<br />
pre-impregnated with thermoplastics. In an integrated<br />
production cell, parts are made by first creating a preform<br />
from the mat and/or tape, and then overmoulding it with<br />
an advanced polyamide such as EcoPaXX. At K2<strong>01</strong>3, DSM<br />
showcased a concept in-mold-formed housing cover<br />
(fig. 3), developed with Weberit. This cover is made in a<br />
combination of a continuous glass reinforced EcoPaXXbased<br />
composite and an injection molded EcoPaXX<br />
compound.<br />
Composites containing carbon fibers based on EcoPaXX<br />
(as well as Akulon polyamide 6 and Stanyl polyamide 46) will<br />
facilitate significant weight reduction in automobile body<br />
and chassis parts, while glass fiber reinforced composites<br />
will be targeted at reducing the weight of semi-structural<br />
components. In all cases, the light weighting will result in<br />
increased vehicle fuel efficiency and reduced emissions of<br />
carbon dioxide.<br />
DSM is also a partner in the four-year EU-sponsored<br />
ENLIGHT project, which also includes several car<br />
companies and which aims to accelerate the technological<br />
development of materials capable of cutting weight and<br />
overall carbon footprint in medium-to-high volume<br />
next-generation electric vehicles. DSM further shows<br />
its strong commitment to the development of advanced<br />
thermoplastic composites by being one of the founding<br />
partners in AZL, the Aachen Center for Integrative<br />
Lightweight Production.<br />
www.ecopaxx.com<br />
20 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
Automotive<br />
Bio-PPA<br />
to replace metal & rubber<br />
Rilsan ® HT, the first flexible thermoplastic from the polyphthalamide<br />
(PPA) family available on the market, combines high temperature<br />
resistance with flexibility. Rilsan HT, made by Arkema (Colombes,<br />
France) is therefore filling a gap in the high heat resistant and flexible polymers<br />
as the inherent brittleness of classical PPA and other high-temperature<br />
thermoplastics has restricted their use to mainly rigid components<br />
and injection moulded parts.<br />
These characteristics make it aptly suited to replace metal and rubber<br />
in under-the-hood tubing applications. Weighing only a sixth of steel and<br />
a third of aluminium, it therefore helps reduce the weight of vehicles, their<br />
fuel consumption and their overall emission output (CO 2<br />
, CO, NO x<br />
, HC) –<br />
all at reduced cost compared to classical metal tubing or rubber hoses<br />
assembly.<br />
The impressive performance of Rilsan HT is further enhanced by<br />
environmental benefits. Rilsan HT is a durable high-temperature<br />
thermoplastic derived largely from renewable non-food-crop vegetable<br />
feedstock, thus offering a significant reduction in CO 2<br />
emissions compared<br />
to conventional petroleum-based high-temperature plastics and a reduced<br />
dependence on oil resources. Rilsan HT resin features a renewable carbon<br />
content of up to 70%, naturally fitting into the ecodesign concepts of many<br />
OEMs.<br />
Fig. 1 and 2: Rilsan HT flexible tubing in the engine<br />
compartment (top: exhaust gas recirculation system,<br />
bottom: blow by Line)<br />
Typical examples of use where Rilsan HT has established itself<br />
successfully to replace metal and rubber in flexible engine compartment<br />
tubing include the oil transport, blow by and control of exhaust gas<br />
recirculation.<br />
Thanks to its excellent hydrolysis resistance, Rilsan HT has been<br />
also recently successfully used in the most challenging application for<br />
polyamides, the aqueous media management, in the engine cooling and<br />
selective catalytic reduction (SCR) circuit where the material needs to<br />
withstand the hydrolysis attack at temperatures of the engine compartment.<br />
Cooling lines, until today, have been limited to the use of metal and<br />
rubber due to the lack of flexible thermoplastic materials with sufficient<br />
hydrolysis resistance at high temperatures. Now, Rilsan HT has been<br />
chosen for engine cooling lines, providing significant weight reduction<br />
versus metal-rubber assemblies.<br />
With the new Euro 6 emission regulation which will come into force next<br />
year, SCR becomes a crucial part of diesel engines and thereby Adblue ®<br />
tubing for SCR. The combination of resistance to aqueous Adblue solution<br />
with thermal aging tubing when close to the engine, is a challenge that<br />
Rilsan HT has proven to take.<br />
Finally, when temperature demands go extreme, Arkema has developed<br />
a new Rilsan HT grade specially designed for excellent hydrolysis stability<br />
at even higher temperatures.<br />
Now, cost-effective manufacturing of light-weight flexible tubing for even<br />
most challenging under-the-hood tubing applications is possible.<br />
Fig. 3: Rilsan HT flexible tubing for engine<br />
cooling lines<br />
www.rilsanht.com<br />
bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 21
People Report<br />
Recycling of PLA for<br />
By:<br />
Christian Hopmann<br />
Sebastian Schippers<br />
Institute of Plastics Processing<br />
(IKV) at RWTH Aachen University<br />
Aachen, Germany<br />
Fig. 3: Fractions of multiple recycled<br />
material during continuous production<br />
with constant recycling rates<br />
21%<br />
25%<br />
70%<br />
11%<br />
2% 1%<br />
6%<br />
Recycling of<br />
30% waste<br />
2% 2%<br />
5%<br />
Recycling of<br />
45% waste<br />
Virgin PLA<br />
1<br />
2<br />
3<br />
4<br />
5+<br />
55%<br />
In cooperation with two Belgian Institutes (Celabor of Herve, and Flanders’<br />
PlasticVision Kortrijk) and the Fraunhofer Institute for Structural Durability<br />
and System Reliability (LBF) in Darmstadt, Germany, the Institute of Plastic<br />
Processing (IKV), Aachen, analyses the recycling of PLA in flat film extrusion.<br />
The focus is on the evaluation of relevant packaging properties such as permeability<br />
and mechanical properties as well as the chemical structure (molecular<br />
weight) during various recycling routes. Preparation of internal PLA waste by<br />
means of crystallisation and drying is also included in the scope of the research.<br />
In this article the recycling with varying percentages of recycled PET,<br />
and the multiple recycling of films, is reviewed. Mechanical as well as chemical<br />
properties are evaluated.<br />
The extrusion trials are carried out on a 60 mm single screw extruder (L=38 D)<br />
and a calender stack. The extrusion line is equipped with a melt pump and<br />
a 400 mm flat film die. Additionally, a bypass-rheometer is included. Films<br />
produced from virgin PLA (Ingeo 2003D, Nature Works) are used for recycling.<br />
A shredder processes these films to flakes which are subsequently used<br />
as r-PLA (recycled PLA). The twin screw extruder ZSK26MC (Coperion) is<br />
combined with a water quenching system and a strand pelletizer unit. It is<br />
used to convert the flakes back to granules.<br />
The typical recycling route of converters includes shredding, crystallising,<br />
drying, re-granulation and reprocessing of the recycled waste to a new product.<br />
To prevent a high level of down-cycling typically the waste is not reprocessed<br />
at 100 %. Instead it is reprocessed with a defined recycled content. Depending<br />
on the packaging application, the recycling content may be up to 50 % of<br />
internal production waste. The molecular weight of different processing steps<br />
measured by GPC (Gel permeation chromatography) is shown in Fig. 1.<br />
The molecular weights shown are in a narrow range. To be able to detect any<br />
effect of a narrow variation of the molecular weight it is necessary to measure<br />
a test series with different films in the same GPC series, which is done here.<br />
In general, the molecular weight loss is low and due to deviations in the<br />
GPC measurements small effects are hardly significant. Virgin PLA loses<br />
molecular weight when processed to film. The molecular weight loss is in<br />
the range of 9 %. The molecular loss occurs due to the thermal and thermooxidative<br />
degradation which is inevitable during extrusion, especially for<br />
polycondensates like PLA.<br />
The film made of virgin PLA is milled into flakes and processed to granules by<br />
means of a twin screw extruder. Granules are advantageous since the material<br />
transport in pipes and dosing units, for example, is easier. Additionally, the<br />
process behaviour in the extruder during plastification is better. The melting<br />
process is more homogeneous than the melting of flakes since the geometry<br />
of the granules is similar to the geometry of the virgin PLA granules. During<br />
granulation in the twin screw extruder a marginal molecular weight loss is<br />
measured, which is a result of the additional processing step.<br />
During the subsequent reprocessing to new films with varying percentages<br />
of recycled PLA the molecular weight loss is low again. The difference between<br />
recycling quotas up to 45 % and film made from virgin PLA is very small. It<br />
accounts for less than 3 % during the recycling of 45 % r-PLA. The effect upon<br />
22 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
Report<br />
packaging applications<br />
the film properties is negligible. Only the processing of 100 %<br />
r-PLA leads to a higher molecular weight loss in comparison<br />
with the molecular weight of the film made by virgin PLA. A<br />
loss of approx. 5 % occurs.<br />
The same effect can be seen for the mechanical properties.<br />
Fig. 2 shows the Young’s modulus in a transverse direction<br />
(TD) for film with varying recycling content.<br />
The drop in the Young´s modulus accounts for nearly 8 %.<br />
The chain scission, which is due to the down-cycling of the<br />
PLA, leads to a lower tensile strength and a lower ductility.<br />
As a result the Young´s modulus decreases.<br />
During continuous recycling a decreasing amount<br />
of material runs multiple times through the extrusion<br />
equipment. To evaluate this influence on the PLA it is<br />
recycled to 100 % for a multiple of times. This leads to a<br />
higher degradation which enables the easier detection of the<br />
effects. The fraction of multiple recycled material decreases<br />
exponentially with increasing recycling steps. Fig 3. shows,<br />
as examples, the fractions for a continuous recycling rate of<br />
30 % and 45 %.<br />
Even for a recycling rate of 45 % the fraction of material<br />
which is recycled 3 times and more is often very low.<br />
Fig. 4 summarises the molecular weight and the viscosity<br />
(measured by the bypass rheometer) of multiple processed<br />
films. After each extrusion step the film is shredded to<br />
flakes and dried to below 250 ppm as recommended by the<br />
PLA supplier. Following this it is reprocessed to 100 %. The<br />
reprocessing in this way is repeated 6 times.<br />
A continuous decrease in both values can be seen. The<br />
increase in step 5 is the result of the blending of two different<br />
batches. R-PLA which is processed in two different trial<br />
series is mixed here. Both batches have been processed four<br />
times prior to mixing. The blending is necessary since a high<br />
amount of r-PLA is needed for the trials, which cannot be<br />
prepared in one test series. Due to start-up waste the amount<br />
of r-PLA is reduced at every step and the volume of the drying<br />
equipment is limited. The increase is visible in the molecular<br />
weight as well as in the viscosity, and other properties.<br />
The overall loss of the molecular weight over 7 extrusion<br />
steps accounts for 17 % percent. A loss of 17 % is relatively<br />
little, especially when taking into account that less than<br />
2 % of 5 times recycled PLA will be in a product which is<br />
continuously produced with 45 % r-PLA.<br />
The Young’s Modulus in machine (MD) as well as in<br />
transverse (TD) direction and the results of the dart drop<br />
tests of PLA processed 1, 3 and 7 times are shown in Fig. 5.<br />
Weight average molecular<br />
weight [kg/mol]<br />
Weight average molecular<br />
weight [kg/mol]<br />
220<br />
210<br />
200<br />
190<br />
180 Virgin<br />
PLA<br />
Film<br />
made<br />
of virgin<br />
PLA<br />
Granules 10%<br />
r-PLA<br />
240 2200<br />
230 2000<br />
220 1800<br />
210 1600<br />
200 1400<br />
190 1200<br />
180 Virgin<br />
PLA<br />
1 2 3 4 5 6 7 1000<br />
Number of extrusion steps [-]<br />
Molecular weight | Average viscosity<br />
30%<br />
r-PLA<br />
Fig. 1: Molecular weight at different process<br />
stages during recycling<br />
Young‘s modulus TD<br />
[MPa]<br />
1850<br />
1800<br />
1750<br />
1700<br />
1650<br />
1600<br />
1550<br />
1500 Film made of<br />
virgin PLA<br />
45%<br />
r-PLA<br />
100%<br />
r-PLA<br />
10% r-PLA 45% r-PLA 100% r-PLA<br />
Fig. 2: Young’s modulus in transverse direction<br />
of film with varying recycling quotas<br />
Fig. 4: Molecular weight and viscosity of multipleprocessed<br />
PLA films<br />
Viscosity [Pas]<br />
bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 23
Report<br />
Young’s Modulus [MPa]<br />
2000 500<br />
1900 450<br />
1800 400<br />
1700 350<br />
1600 300<br />
1500 250<br />
1400 200<br />
1300 150<br />
1200 100<br />
1100 50<br />
1000<br />
1 3 7 0<br />
Number of extrusion steps [-]<br />
Young’s Modulus (MD) | Young’s Modulus (TD) | Dart drop<br />
Fig. 5: Young’s Modulus and dart drop<br />
of multiple processed PLA<br />
Number of extrusion steps<br />
1 3 7<br />
Degree of crystallinity [%] 1.2 2 2.7<br />
Table 1: Degree of crystallinity for multiple extruded<br />
PLA films measured by DSC<br />
References:<br />
[1] THRONE, J.; BEINE, J.: Thermoformen.<br />
Munich, Vienna: Carl Hanser Verlag,<br />
1999<br />
www.ikv-aachen.de<br />
Impact failure weight [g]<br />
The Young’s Modulus of the film increases with the<br />
number of extrusion steps. A growth of 5 % in both directions<br />
(TD and MD) is achieved between processing steps 1 and<br />
7. The impact failure weight as a result of the dart drop<br />
test is increased, too. This is due to a higher degree of<br />
crystallinity of the film. Unlike the results of the recycling<br />
with varying recycling quotas the molecular weight loss of<br />
the 3 times (10 %) and 7 times (17 %) recycled PLA is higher.<br />
A low average chain length (molecular weight) enables the<br />
polymer to crystallise more during the solidifying on the<br />
calender stack. This is well covered in published literature<br />
[1]. The degree of crystallinity is shown in table 1.<br />
The higher crystallinity increases the mechanical<br />
properties (Young’s Modulus). Since the increase in<br />
crystallinity is little, the overall effect on the mechanical<br />
properties is marginal. The crystallinity between steps 3<br />
and 7 does not change much. The mechanical properties<br />
remain almost constant. Chain scission through<br />
degradation compensates for the effect of crystallisation.<br />
With regard to further decreasing of the molecular weight<br />
the dart drop resistance decreases slightly.<br />
Conclusion<br />
The investigations into the recycling of PLA show that<br />
the industrial recycling of PLA is possible with a low loss<br />
of film properties. Because of the hygroscopicity and the<br />
hydrolysis of PLA the drying of r-PLA is necessary. The<br />
reprocessing with a recycling quota of up to 45 % leads to<br />
a marginal degradation of the PLA. The molecular weight<br />
drops around 3 % and the mechanical properties decrease<br />
by 8 %.<br />
Multiple recycling shows the long term behaviour of<br />
material which stays in the process over multiple recycling<br />
steps during continuous recycling. A low decrease of the<br />
molecular weight below 20 % of a 7 times extruded film can<br />
be found. This degradation can be ignored. Especially, when<br />
taking into account that during the continuous recycling<br />
only a small amount stays for 5 or more cycles in the<br />
process. The effect of the lower molecular weight affects<br />
the degree of crystallinity. This has a bigger effect on the<br />
properties than the achieved molecular weight loss. The<br />
mechanical properties of multiple recycled films are slightly<br />
increased with nearly constant elongation properties. The<br />
thermoforming behaviour is slightly decreased due to a<br />
higher crystallinity haze and clarity increase.<br />
The research project 44 EN of the “Forschungsvereinigung<br />
Kunststoffverarbeitung” has been sponsored as part of the<br />
“Collective Research Networking“ (Cornet) by the German<br />
ministry for technology and commerce (BMWi) following an<br />
act of the German parliament through the AiF. We would<br />
like to extend our thanks to all organizations mentioned.<br />
24 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
Applications<br />
New bioplastic<br />
applications in windows<br />
More and more architects and clients are demanding new,<br />
ecologically viable products which have maximum potential<br />
for reducing CO 2<br />
and conserving natural resources. With its<br />
green generation of products, German window and façade expert<br />
Schüco from Bielefeld is addressing the issue of finding potential<br />
alternative materials for petroleum based plastics.<br />
The FW 50 + .SI Green façade system and the AWS 90.SI + Green<br />
aluminium window system integrate components such as insulating<br />
bars, gaskets and pressure plates with a proportion of renewable<br />
materials.<br />
This development is possible in part due to the use of partly<br />
biobased polyamide (made using sebacic acid generated from<br />
castor oil), that forms the basis for the pressure plates of the FW<br />
50 + .SI Green façade system and for the green insulating bars which<br />
are integrated into the Schüco AWS 90.SI + Green window system.<br />
The castor oil is even used for the foam of these insulating bars.<br />
Schüco is also making a marketing contribution for the transfer of<br />
biotechnology for gaskets in both of these profile systems, by using<br />
EPDM (synthetic rubber) made from sugar cane based bio-ethanol.<br />
The same standards apply to all these materials: an initial and then<br />
annual inspection by an independent certification process (DIN<br />
CERTCO, 14 C analysis) guarantees that the proportion of renewable<br />
raw materials strived for is also achieved. With the Schüco AWS<br />
90.SI + Green and Schüco FW 50 + .SI Green system enhancements,<br />
the company is combining the approved use of renewable raw<br />
materials with thermal insulation to passive house level and above.<br />
The FW 50 + .SI Green façade system meets the strict passive house<br />
certification criteria set by the Passive House Institute in Darmstadt<br />
and has been certified as passive house standard since BAU 2<strong>01</strong>3<br />
(building and construction trade fair in Munich/Germany).<br />
Combination of sustainability and energy efficiency<br />
Thermal insulation is the primary decisive factor in the energy<br />
revolution. Many local authorities have already pledged to<br />
implement thermal insulation to passive house level as standard<br />
when constructing new public buildings. The Schüco Green window<br />
and façade systems fulfil precisely these requirements. Both<br />
constructions combine the advantages of durable aluminium with<br />
thermal insulation to passive house standard, thereby conserving<br />
natural resources and reducing CO 2<br />
emissions. Equipped with<br />
plastics containing a significant proportion of renewable raw<br />
materials, these windows and façades now make a double<br />
contribution to the reduction of greenhouse gases, since they have a<br />
lower potential for global warming. This means that using renewable<br />
raw materials releases fewer greenhouse gases into the atmosphere<br />
during manufacturing and it also conserves natural resources. MT<br />
Schüco Window AWS 90.SI+ Green<br />
(photo: Schüco International KG)<br />
1: Insulating bars: Bio-Polyamide<br />
Bio-content ( 14 C): > 25 %<br />
2: Insulating zone: Biobased PUR-foam<br />
Bio-content ( 14 C): > 25 %<br />
3: Glass rebate gasket: Bio-EPDM<br />
Bio-content ( 14 C): > 20 %<br />
Schüco Façade FW 50+.SI Green<br />
(photo: Schüco International KG)<br />
2<br />
1<br />
1: Contact pressure profile: BIO-Polyamide<br />
Bio-content ( 14 C): > 25 %<br />
2: Glass rebate gaskets: BIO-EPDM<br />
Bio-content ( 14 C): > 20 %<br />
System achieves level of „Passivhausniveau“<br />
U cw<br />
≤ 0,80 W/m²K<br />
3<br />
www.schueco.de/aws-90si-plus-green-en<br />
2<br />
2<br />
1<br />
1<br />
2<br />
bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 25
People Cover Story<br />
PLA foam<br />
protects<br />
ice cream<br />
By:<br />
Michael Thielen<br />
Sandro Zandonella, and his ancestors of the Zandonella<br />
family, have produced and sold gourmet ice cream for<br />
four generations - not in Italy, as the name would suggest,<br />
but in Landau, Germany. The ice cream specialties are<br />
not only sold in their local ice cream parlours but are also<br />
available in single-serve and multi packs, as well as in household<br />
size containers. Zandonella have recently introduced<br />
their new brand Sandro’s Bio with an exceptional natural<br />
taste, as Sandro Zandonella, Managing Director and inventor<br />
of Sandro’s Bio explains. The flavour line comprises classics<br />
such as chocolate or vanilla, cocktail types like Piña Colada<br />
as well as the very trendy vegan sorbet specialties. All these<br />
products are made with biological 1 or organic 1 ingredients<br />
grown locally in the vicinity of their company. “Zandonella is<br />
proud that the gourmet quality of their ice cream has been<br />
frequently confirmed in blind taste tests,” says Werner Oelschlaeger,<br />
Managing Partner of Zandonella. “We are always<br />
happy to invite new testers to compare our products with other<br />
ice creams, which is always a fun day…,” he adds.<br />
PLA BioFoam ®<br />
And what is it, which makes Sandro’s Bio unique? “This<br />
product is the first ice cream, worldwide, to be packed in<br />
PLA BioFoam made by Synprodo,” explains Mr. Oelschlager.<br />
This PLA particle foam is comparable to EPS (expanded<br />
polystyrene particle foam, sometimes also referred to as<br />
Styropor ® ). BioFoam is made from non-GMO crops, notably<br />
sugar cane. It is also compostable in industrial composting<br />
facilities, where a respective infrastructure is available. The<br />
ecological advantages of this packaging material are in line<br />
with the advantages concerning the deep-freeze-logistics<br />
and customer convenience, i.e. the ice cream can retain its<br />
deep-freeze temperature about one hour even in a warm<br />
environment, such as inside a sun-heated car.<br />
The first packaging product for Sandro’s Bio ice-cream<br />
made from BioFoam is a half litre household size container.<br />
In order to ensure maximum product safety, and not only with<br />
respect to the temperature, the whole packaging product is<br />
rather complex. The insulating outer box and lid are made<br />
from BioFoam. In addition a thermoformed inlay made of PLA<br />
and a PLA lidding film are used. Then the pack is wrapped<br />
in shrink film and an outer sleeve made of paper. It is the<br />
declared aim of Zandonella to replace even the shrink film<br />
and the sleeve by bioplastic materials by the end of this year.<br />
Werner Oelschlaeger, himself quite interested in<br />
environmental issues since his university times, explains<br />
to bioplastics MAGAZINE Zandonella’s motivation for using<br />
BioFoam: “One reason was some critical comments from our<br />
customers concerning the use of polystyrene. In addition to<br />
the fossil resources there is pentane being used as a blowing<br />
agent,” he says. “BioFoam gives us the unique position of<br />
using a packaging product that, just like expanded polystyrene<br />
before it, allows the ice cream to be kept safe and cold, but<br />
which is made from renewable resources and with CO 2<br />
as<br />
a blowing agent.” For Oelschlaeger it is important that the<br />
agricultural products which are used for their packaging do<br />
not compete with food.<br />
26 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
Foam<br />
Sandro Zandonella with a farmer in his local area<br />
During the development of the PLA packaging system, which<br />
was performed in a rather tight time-frame, some challenges<br />
had to be faced and solved. For example an existing mould,<br />
previously being used for the EPS version, could not be used,<br />
due to different wall thickness requirements. Together with<br />
Synprodo (Wijchen, The Netherlands) and even assisted by<br />
the expertise of the bio-packaging specialist Bio4Pack from<br />
Rheine/Germany, all problems were solved in time, so that a<br />
launch of the product at the BioFach trade fair in February in<br />
Nuremburg/Germany became an achievable goal.<br />
End of Life<br />
As an end-of-life scenario of the new Sandro’s Bio PLA foam<br />
packaging the company pursues different approaches. Of<br />
course all bioplastic parts of the packaging are compostable<br />
and even the whole system (foamed box, liner and lid-film)<br />
will be certified compostable according to EN 13432. Thus<br />
in areas where the respective infrastructure of bio-waste<br />
collection and commercial composting is available, a cradleto-cradle<br />
closed loop is the perfect solution. In countries such<br />
as Germany, where currently only bio-waste bags are allowed<br />
in the bio-waste collection bins, a source-separation into the<br />
yellow bins/bags-system is the most reasonable approach.<br />
Here the biobased plastics will end up in a waste-to-energy<br />
recycling process and renewable energy can be exploited.<br />
Since the plants have sequestered the same amount of<br />
CO 2<br />
from the atmosphere as is being exhausted during<br />
incineration, this also is a closed loop. And certainly, as soon<br />
as sufficient PLA ends up in the waste stream, it should be<br />
separated and recycled into PLA or lactic acid again. The only<br />
thing that is being considered a No-go is littering. And this<br />
should certainly be communicated to the end consumers.<br />
Come and see the BioFoam-ice<br />
cream packaging and taste the<br />
delicious ice cream at BioFach<br />
(12-14. Feb., Nuremberg/Germany)<br />
Hall 9 – booth 326<br />
1: Both words by the way are not exactly “precise“ terms to describe, what is really meant<br />
here. Unfortunately in many countries these expressions are being used to describe<br />
products that are produced on a “as much as possible” natural way, without using<br />
pesticides, fertilizers or even genetically modified organisms. MT<br />
www.sandros-bio.de<br />
www.synprodo.com<br />
www.bio4pack.com<br />
bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 27
Foam<br />
Foam grade<br />
PBAT<br />
Jinhui ZhaoLong High Tech Co.Ltd is located at Shanxi<br />
Province, China with an annual PBAT (polybutylene<br />
adipate-co-terephthalate) production capacity of<br />
20,000 tonnes. Jinhui is using a one step ring-opening polymerization<br />
technology and started PBAT production in<br />
July 2<strong>01</strong>3. A compostability test (according to EN 13432)<br />
was completed at Beijing Technology and Business University.<br />
The products will obtain DIN-Certco certification<br />
(EN 13432) in March 2<strong>01</strong>4. FDA certification for food contact<br />
is also available.<br />
Foam products are widely used in packing industry<br />
because of high impact absorption rate, low density, high<br />
specific strength, high heat and sound insulation abilities.<br />
Conventional plastic foam products not only may have<br />
isocyanate residue problem (in the case of polyurethane),<br />
they are quite difficult to re-collect or re-use due to their<br />
bulky volume. In order to avoid white pollution, there is a<br />
strong market demand for biodegradable foam products.<br />
Drive Innovation<br />
Become a Member<br />
In many cases biodegradable plastic foam products<br />
show a low melt flow rate resulting at low expansion<br />
ratio as well as a low yield ratio (broken foam bubbles).<br />
Jinhui is offering a foam grade PBAT resin which offers an<br />
expansion ratio of around factor 10 using carbon dioxide<br />
as a foaming agent. The foam products have a density<br />
between 0.13 g/cm 3 to 0.2 g/cm 3 , foam bubble diameters<br />
below 20 μm and a resilience of more than 80%.<br />
Jinhui’s marketing strategy is focused on excellent<br />
consulting and after sales service. Their foam grade PBAT<br />
customers will benefit from on-site technical support at<br />
no extra cost as well as unique customer tailor-made<br />
solution. As an example, by adding a nucleating agent<br />
the degree of crystallization can be increased to obtain<br />
a higher impact resistance surface in order to meet the<br />
customer’s exact requirements. MT<br />
www.ecoworld.jinhuigroup.com<br />
28 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
Foam<br />
Mushroom<br />
packaging<br />
About a year and a half ago Sealed Air Corporation (Elmwood<br />
Park, New Jersey, USA) and Ecovative Design LLC (Green Island,<br />
New York) completed an agreement about the production,<br />
sales and distribution of Ecovative’s EcoCradle ® Mushroom ®<br />
Packaging, a unique technology for environmentally responsible<br />
packaging materials made from agricultural byproducts and mycelium,<br />
or mushroom roots.<br />
As part of the agreement, Sealed Air would be the exclusive<br />
licensee of Ecovative’s mycelium based material technology in<br />
North America and Europe for protective packaging applications.<br />
Sealed Air and Ecovative developed together plans for sales and<br />
marketing as well as the augmentation of production capabilities.<br />
Just recently, end of 2<strong>01</strong>3, Sealed air started production in a<br />
converted facility in Cedar Rapids, Iowa.<br />
The packaging material — albeit not exactly a bioplastic — can<br />
replace conventional plastic foams, such as those made from<br />
polystyrene, polyethylene or polypropylene. It is made by inoculating<br />
agricultural waste, that can be anything from corn husks, rice hulls<br />
to chopped up plant stocks with fungal mycelia. The mycelia grow<br />
extensively to form an intricate, interwoven network as they feed on<br />
the substrate. The composite is then heated to kill the mycelia and<br />
fuse the mass into a rigid, plastic-like substance. The properties<br />
of the material can be tailored by varying the organic substrate<br />
and type of fungus to grow in it. Target markets include protective<br />
packaging, automotive components, construction materials, shoes<br />
and floral foam [1].<br />
There are several problems with polystyrene foams, Ecovative<br />
CEO Eben Bayer said. Polystyrene is made from oil, a limited<br />
resource with a fluctuating price, in a process that uses a lot of<br />
energy. And plastic packaging, which typically ends up getting<br />
thrown away, takes a very long time to degrade – and finds its<br />
way to oceans and beaches around the world. By contrast, he<br />
said, Mushroom Packaging, is renewable and biodegradable, and<br />
made from crop waste bought from farmers, providing them with<br />
additional income [2].<br />
Examples for protective packaging are a wine-botttle box or<br />
protective corners for (e.g.) household appliances. Other applications<br />
for Ecovative’s Mushroom materials include insulating panels in<br />
building and construction, surf boards and much more. MT<br />
www.sealedair.com<br />
www.ecovativedesign.com<br />
www.mushroompackaging.com<br />
References:<br />
[1] Plastics News online, Nov. 12, 2<strong>01</strong>3<br />
[2] The Guardian online, Oct. 22, 2<strong>01</strong>3<br />
Info:<br />
watch video clip at bit.ly/LjWfm2<br />
bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 29
People Report<br />
2<strong>01</strong>3<br />
2<br />
bioplastics MAGAZINE<br />
Reinventing waste<br />
as a resource<br />
Bacteria and biopolymers key players in<br />
innovative hospital waste management system<br />
By:<br />
Karen Laird<br />
www.pharmafilter.nl<br />
Due to the specific nature of health care activities, waste management<br />
in hospital environments poses problems not encountered<br />
elsewhere. In most hospitals, therefore, elaborate procedures<br />
have been put in place to ensure that the health-care waste they produce<br />
is appropriately managed. However, even with the strictest of segregation,<br />
transport and disposal regulations in force, cross-contamination<br />
and errors occur. Pharmafilter is a young Dutch company offering a new<br />
and innovative approach that completely eliminates these problems. At<br />
the heart of its solution is an anaerobic digester; over time, biopolymers<br />
will become a major source of digestible input material.<br />
Health-care waste includes a large component of general waste and<br />
a smaller proportion of hazardous waste. According to Eduardo van den<br />
Berg, director of Pharmafilter, one of the main problems is where to draw<br />
the line between the two. “In hospitals, waste is managed by segregating<br />
it, which creates a great many separate waste streams. We found that<br />
fully one-third of all movement in hospitals is related to waste. A lot of<br />
effort, for example, goes into carefully separating all the infectious waste<br />
from the general waste.” He added: “But then, if a patient - the source of<br />
the infection – uses a bedpan or goes to the toilet, that is infectious waste<br />
that goes directly into the sewer.”<br />
Down the drain<br />
Van den Berg is a creative thinker with a proven track record and<br />
experience in health-care settings. An earlier idea – the development of<br />
a hygienic, environmentally friendly, disposable vase for hospital flowers –<br />
had been successfully introduced in hospitals throughout the Netherlands<br />
and Germany. He was convinced that there had to be a safer, cleaner<br />
and especially, a more efficient approach to the transport, handling and<br />
treatment of the health-care waste produced in hospitals. So when he was<br />
approached by Reinier de Graaf hospital, in Delft, the Netherlands, who<br />
asked him to help devise a modern, safe and efficient waste management<br />
system for the new facilities that were being planned, he came up with an<br />
solution that was both impressively simple and remarkably effective.<br />
“I thought, why not simply treat all the waste produced as biohazardous<br />
waste? Then, instead of separating everything for segregated disposal, all<br />
the waste streams could be combined into a single stream, disposed of<br />
in a single contaminated area and processed all together,” he explained.<br />
How? “Simply by using the hospital’s existing sewage system.”<br />
30 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
Report<br />
Using the hospital’s internal drainage system would greatly<br />
decrease the amount of waste being transported through the<br />
hospital, thus considerably reducing the number of contact<br />
moments and contamination risks. In a purely practical<br />
sense, it would have the added advantage that far less use<br />
would be made of the elevators, reducing the waiting time for<br />
them, as well.<br />
First, however, a safe and workable system for<br />
implementation needed to be devised. “Obviously, because<br />
the municipality it not equipped to handle contaminated waste<br />
through the sewage system, some kind of self-contained<br />
treatment facility would be needed on site to process this<br />
waste. This was the start of Pharmafilter,” said Van den Berg.<br />
In 2008, the first Pharmafilter pilot plant was built, in order<br />
to test the feasibility of the idea and the configuration of the<br />
installation developed by Van den Berg. This pilot facility<br />
operated on a 10% scale at Reinier de Graaf Gasthuis in<br />
Delft and proved such a success that a full-scale system was<br />
installed in the existing H-building, which went on stream in<br />
the autumn of 2<strong>01</strong>0.<br />
And today, construction of the new hospital facilities in Delft<br />
is in full swing, together with the integrated new Pharmafilter<br />
installation that will be ready for operation from day one.<br />
The new waste disposal system has also attracted attention<br />
from other hospitals as well, both in the Netherlands<br />
and abroad. Pharmafilter currently has 10 more projects<br />
for similar systems with hospitals in Belgium, Denmark,<br />
Germany, Holland, Ireland, Sweden and the United Kingdom.<br />
Powered by bacteria<br />
Standing in one of the containers housing the Pharmafilter<br />
installation, Van den Berg called attention to the fact that<br />
there was no odor – nothing at all – even though underneath<br />
the floor all the waste from the hospital was going through a<br />
giant sieve to separate the solids from the water.<br />
“On all the wards, where the bedpan washers used to be,<br />
and in the operating rooms and other strategic locations,<br />
we’ve installed shredders, called Tontos, into which all waste<br />
is deposited, including food, sharps, disposables, human<br />
organic waste, plastic, paper, whatever. The self-cleaning<br />
Tonto unit grinds up the waste, adds water and delivers it<br />
via the hospital’s internal sewer system to where we are<br />
standing, together with the waste water from showers,<br />
washbasins and toilets,” explains Van den Berg. “We purify<br />
the air of all aerosols and possible pathogens, so there’s no<br />
smell or danger of contamination at all.”<br />
After sieving, the solids – metals, plastics, feces, food -<br />
are ground into pulp, suctioned into the hydrolysis unit and<br />
then fed into the anaerobic digester. Here, the organic waste,<br />
including all bioplastics, is digested by the bacteria in this<br />
unit, a process that takes around thirty days and occurs at<br />
a temperature of 60°C. The biogas produced in the process<br />
meets 65-70% of the power needs of the installation.<br />
The non-digestible remainder is largely decontaminated<br />
during the process as well, but is nonetheless treated at<br />
100°C prior to being compressed and further processed into<br />
briquettes that for instance can serve as fuel in the cement<br />
industry. Van den Berg hopes that, as the volumes increase,<br />
it will be possible to separate the metals and conventional<br />
non-digestable plastics out for recycling in order to achieve a<br />
true end-of-life cycle closed loop.<br />
No more pharmaceutical pollution<br />
The wastewater, which next to all else contains high<br />
amounts of pharmaceutical substances, from cardiovascular<br />
medicines to X-ray contrast fluids, undergoes rigorous<br />
purification treatment, as well. The water from the sewagesieving<br />
step and from the digester is first fed through<br />
a membrane bioreactor equipped with ultrafiltration<br />
membranes, where bacteria are responsible for nitrogen<br />
and phosphate removal and most of the contaminants are<br />
eliminated. Next, ozone is introduced into the water to get rid<br />
of any color, micro particles of cosmetics and pharmaceuticals<br />
remaining. The ozone causes chain scission into basic<br />
elements and metabolites. “After the ozone treatment, an<br />
bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 31
Report<br />
active carbon step is carried out to filter out any toxic residue. We buffer the water, subject<br />
it to UV light and then reuse it,” says Van den Berg. “It’s a closed loop. It’s led to the hospital<br />
using 70% less drinking water.”<br />
He added: “Actually, this water is cleaner than drinking water – the amount of microcontaminants<br />
it contains is under the detection limit. Our process eliminates residual<br />
pharmaceuticals far better than the water purification plants do. However, it can’t be used<br />
as drinking water due to legal restrictions. It may be used as process water, though, and<br />
in the new building, the infrastructure is being put in place, so that there it will be used for<br />
everything except drinking purposes.”<br />
In fact, at the current Delft facility, the purified water is used to fill a fish aquarium, in<br />
which numerous goldfish are happily swimming around. Once a month, a fish is caught and<br />
thoroughly examined for any sign of problems..<br />
Biopolymers hold the future<br />
A key element in the Pharmafilter concept is the replacement of the use of conventional<br />
hospital supplies by products made of biopolymers, as, next to providing a “green” alternative<br />
to conventional materials, these will serve to increase the amount of digestible organic matter,<br />
allowing the installation to produce more biogas and become a truly closed-loop system.<br />
According to Van den Berg, the hospitals are ready to embrace the use of biopolymers.<br />
Already, a list of over 200 products eligible for replacement by bioplastic alternatives has been<br />
compiled, opening up exciting possibilities for a host of new bioplastic applications.<br />
It will take time, however. Pharmafilter is investigating the possibilities of developing the<br />
new products itself, as manufacturers are generally reluctant to invest in unproven products<br />
with uncertain volumes. Van den Berg: “It’s a chicken and the egg situation. So we are currently<br />
experimenting with different blends of PHA and PLA to develop these products ourselves.<br />
What’s important is their digestibility. PLA is not anaerobically degradable, although in a<br />
blend, in a certain proportion, we have found that with the Pharmafilter patented system<br />
the bacteria will handle these blends.” and how this is achieved is Pharmafilters proprietary<br />
knowledge.”<br />
Already, PHA and starch-based bioplastics have been shown to be easily digestible in the<br />
digester. “Traditional metal bedpans have already been replaced by the bioplastic Olla, made<br />
of PHA,” noted Van den Berg. “It was designed for patient comfort, comes with an airtight lid<br />
and fits easily into the Tonto.” Prior to the introduction of the disposable bedpans, it was not<br />
uncommon for the (used) bedpans to pile up in the bedpan washer station because they could<br />
not be cleaned fast enough. “Imagine the smell,” he added.<br />
Other products include catheters, urinals and urine collection bags, with many others,<br />
such as serviceware, containers and trash bags, due to be introduced in the near future.<br />
But: “What we’re really looking forward to is the development of bioplastic incontinence<br />
material and diapers,” said Van den Berg. “It’s already a disposable. The volumes are huge.<br />
It’s a perfect product for us.”<br />
32 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
Join the international trade fair<br />
for horticulture technology<br />
THE BRAND NEW BIENNIAL EXHIBITION<br />
GREENTECH IS THE GLOBAL MEETING<br />
PLACE FOR ALL PROFESSIONALS<br />
INVOLVED IN HORTICULTURE<br />
TECHNOLOGY, OFFERING:<br />
> Unique focus on horticulture technology<br />
> Complete overview of the latest products,<br />
technologies and innovations<br />
> Worldwide innovations in the spotlight<br />
> Inspiration through three sustainable themes:<br />
Water - Energy - Biobased<br />
> Unrivalled networking and cutting-edge<br />
knowledge programme<br />
> Exciting Amsterdam<br />
MARK YOUR<br />
CALENDAR<br />
10 -11-12<br />
June 2<strong>01</strong>4<br />
Amsterdam,<br />
The Netherlands<br />
THE BEATING HEART OF THE<br />
INTERNATIONAL HORTICULTURE<br />
INDUSTRY IN AMSTERDAM AND<br />
ITS SURROUNDINGS.<br />
DON’T MISS IT !<br />
IN COOPERATION WITH<br />
FOR MORE INFORMATION<br />
ORGANISED BY<br />
www.greentech.nl
People Report<br />
Facts on land use for<br />
old and new biobased plastics<br />
Methodology of land use calculation – using the example of PLA<br />
0.37 ha 1.04 ha<br />
0.18 ha 0.16 ha<br />
Fermentation<br />
CO 2<br />
H 2<br />
O<br />
H<br />
Hydrolysis<br />
2<br />
O<br />
H 2<br />
O<br />
Enzymes<br />
Dextrins<br />
Sugar beet Sugar cane<br />
Corn<br />
Wheat<br />
9.19 t 11.31 t<br />
2.39 t 3.54 t<br />
ferment. Sugar<br />
Starch<br />
1.47 t<br />
1.67 t<br />
Lactic Acid*<br />
1.25 t<br />
Dehydration<br />
Lactide<br />
1.00 t<br />
H 2<br />
O<br />
Glucose<br />
1.47 t<br />
Fermentation<br />
Lactic Acid*<br />
1.25 t<br />
CO 2<br />
H 2<br />
O<br />
Step 3<br />
Step 2<br />
Step 1<br />
By:<br />
Hans-Josef Endres and co-workers<br />
IfBB - Institute for bioplastics and Biocomposites<br />
Hanover, Germany<br />
Current discussions on land use requirements for bioplastics,<br />
or of the amount of renewable resources needed,<br />
are often centered on rather irrational estimates and<br />
groundless reservations. To counteract the widespread scepticism<br />
towards bioplastics and return to a more fact-based debate,<br />
the following contribution is made to show the relevant<br />
data on current and future land use for bioplastics and to support<br />
these data by drawing various comparisons.<br />
Catalyst<br />
Polymerization<br />
PLA<br />
1.00 t<br />
* Conversion Rates<br />
Sugar – Lactic Acid 85%<br />
Catalyst<br />
Dehydration<br />
Lactide<br />
1.00 t<br />
Polymerization<br />
PLA<br />
1.00 t<br />
H 2<br />
O<br />
Step 3: To calculate land use in this<br />
bottom-up approach, the producer-specific<br />
productioncapacities of a type of bioplastics<br />
were multiplied by the output data of the<br />
corresponding process routes<br />
Step 2: Feedstock requirements were<br />
calculated for the use of different crops.<br />
For final land use calculation only the<br />
most common used crop was taken into<br />
consideration. Yield data from FAO statistics<br />
served as a basis for calculation (global, nonweighted,<br />
average over the past 10 years).<br />
Step 1: Process routes show the<br />
manufacturing steps involved from the raw<br />
material to the finished product, specifying<br />
the individual process steps, intermediate<br />
products, and input-output streams.<br />
The mass flows were first calculated using<br />
a molar method based on the chemical<br />
process, with the introduction of known<br />
rates and conversion factors. The routes so<br />
established were confirmed with polymer<br />
manufacturers and the industry generally as<br />
far as possible. In so far as no loss rates due<br />
to the chemical processes or the process<br />
stages were included, the calculations were<br />
made basically assuming no losses.<br />
The mass flows differ depending on which<br />
of the following two aspects is considered:<br />
feedstock and/or land use requirements<br />
for the production of one metric ton of<br />
bioplastics, bioplastics output from one<br />
metric ton of feedstock, or per hectare or<br />
square kilometre.<br />
Bioplastics production capacities 2<strong>01</strong>2 (by material type)<br />
Bioplastics production capacities 2<strong>01</strong>7 (by material type)<br />
56.6%**<br />
Biobased/non-biodegradable<br />
43.4%<br />
Biodegradable<br />
83.8%*<br />
Biobased/non-biodegradable<br />
16.2%<br />
Biodegradable<br />
1.1 %<br />
Other (biobased/<br />
non-biodegradable)<br />
2.4 %<br />
Bio-PA<br />
14.3 %<br />
Bio-PE<br />
38.8 %<br />
Bio-PET 30<br />
* Only hydrated cellulose foils<br />
** Comprises drop-in solutions and<br />
technical performance polymers<br />
in %<br />
total: 1.4 million<br />
tonnes<br />
13.4 %<br />
PLA<br />
13.7 %<br />
Biodegradable<br />
polyester<br />
11.4 %<br />
Biodegradable<br />
starch blends<br />
2.4 %<br />
PHA<br />
2.0 %<br />
Regenerated<br />
cellulose*<br />
2.0 %<br />
Other (biodegradable)<br />
1.6%<br />
Other (biobased/<br />
non-biodegradable)<br />
1.4%<br />
Bio-PA<br />
4.4%<br />
Bio-PE<br />
76.4%<br />
Bio-PET 30<br />
in %<br />
total: 6.2 million<br />
tonnes<br />
* Comprises drop-in solutions and technical<br />
performance polymers<br />
Source European Bioplastics / Institute for<br />
Bioplastics and Biocomposites (December 2<strong>01</strong>3)<br />
13.4 %<br />
PLA<br />
6.9%<br />
PLA<br />
3.6%<br />
Biodegradable polyester<br />
2.7%<br />
Biodegradable starch blends<br />
2.4%<br />
PHA<br />
0.6%<br />
Other<br />
(biodegradable)<br />
34 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
Report<br />
The importance of transparency for<br />
generating clear-cut estimates of land use<br />
Two sources of information served as a basis for an accurate<br />
estimate of land use. First, the production process of various<br />
biobased plastics including their feedstock conversion rates<br />
for individual process steps, and second, official data on<br />
agricultural yields as feedstock. See the example of PLA, as<br />
shown in Fig.1.<br />
When considering these process routes and the respective<br />
market volumes of the various bioplastics, the feedstock and<br />
land use requirements for these bioplastics can be derived in<br />
a clear and understandable way.<br />
Defining the scope of biopolymer<br />
materials under consideration<br />
Another essential aspect in the discussion is to clarify, or<br />
concretize, which biobased materials are considered and in<br />
particular also which ones are excluded.<br />
• For example, do the data for land use or feedstock refer<br />
to the resources required specifically for new types of<br />
bioplastics, i.e., those developed within the last 20 - 30<br />
years (New Economy)? What about traditional biopolymers<br />
such as cellulose derivatives (cellulose acetate, cellophane,<br />
etc.), rubber, linoleum, etc. (Old Economy) – are they also<br />
considered?<br />
• Are ready-to-use polymers the only ones covered?<br />
What about biobased polymer raw materials (bio-acids,<br />
alcohols, etc.) and functional oligomers or other polymers<br />
(plasticizers, etc.)?<br />
• Are biobased synthetic fibres, or even natural fibres, also<br />
included?<br />
• Are composites with biobased reinforcements (starch-filled<br />
polymers, natural-fibre reinforced composites, etc.) also<br />
covered?<br />
If no clear distinction is made regarding whether certain<br />
materials are included or excluded, this will result in a wide<br />
spread of values and lack of clarity in the assessment of land<br />
use and resource consumption for bioplastics. Eventually,<br />
there will be confusion on all sides.<br />
Resource consumption for biobased plastics:<br />
New Economy (2<strong>01</strong>2 and 2<strong>01</strong>7)<br />
When, based on these pre-considerations, New Economy<br />
bioplastics, with their annual production capacity of currently<br />
1.4 million tonnes are taken into focus, and it turns out that<br />
their land use is as low as 0.4 million tonnes per hectare. This<br />
is equivalent to only 0.008 % of the global agricultural area (5<br />
billion hectare) or 0,03 % of the global arable land (1.4 billion<br />
hectare)<br />
Even though global forecasts predict a rapidly growing<br />
market for these novel bioplastics in the next few years, the<br />
need for agricultural areas will be kept at a very low level.<br />
While the market for new bioplastics has been growing<br />
by around 15 % annually during the last three years and<br />
a sustained growth is anticipated for the future it can be<br />
assumed that land use for New Economy bioplastics by 2<strong>01</strong>7<br />
(6.2 million tonnes), for example, will be as low as 0.02 % of<br />
the global agricultural area or less than 0.4 % of the arable<br />
land.<br />
Regardless of the significant growth rates, it should be<br />
mentioned that the market share of these New Economy<br />
bioplastics is still hovering at less than 1 % of the global<br />
plastics market and is likely not to exceed 2 - 3 % in the near<br />
future.<br />
Global production capacities of bioplastics<br />
6,185<br />
6,000<br />
1,000<br />
Biobased<br />
(partly or completely)<br />
Durable<br />
(and biobased)<br />
Chemically novel<br />
z.B. PLA, starch,<br />
PTT, PBS, PBAT<br />
Thermoplastics<br />
„New Economy“<br />
Bio-Polymers<br />
Petroleum based<br />
(and biodegradable)<br />
Biodegradable<br />
(compostable)<br />
Biobased<br />
„Drop-Ins“, e.g.<br />
Bio-PE, Bio-PET, Bio-PA<br />
Thermoset resins<br />
Elastomers, TPE<br />
„Old Economy“<br />
e.g. caoutchouc,<br />
Viscose, Linoleum,<br />
CA, Cellophane<br />
1,000 metric t<br />
5,000<br />
4,000<br />
3,000<br />
5,185<br />
2,000<br />
1,395<br />
1,161<br />
1,<strong>01</strong>6<br />
1,000<br />
342<br />
674<br />
486<br />
675<br />
604<br />
791<br />
0<br />
2<strong>01</strong>0 2<strong>01</strong>1 2<strong>01</strong>2 2<strong>01</strong>7<br />
Biodegradable | Biobased/non-biodegradable| Total capacity<br />
Forecast<br />
bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 35
Report<br />
Old and New Economy (2<strong>01</strong>2 and 2<strong>01</strong>7)<br />
In addition to these innovative and novel bioplastics, when<br />
considering the most important Old Economy bioplastics with<br />
their global production capacity of 17 million tonnes annually,<br />
it turns out that the share of New Economy bioplastics is 15<br />
times lower, i.e. 7.5 % of the market volume of all biobased<br />
plastics (including the Old Economy bioplastics), with rising<br />
tendency.<br />
By and large, Old and New Economy bioplastics (about<br />
18.5 million tonnes) have a combined share of presently<br />
6 - 7 % of the global plastics market. Taking into account<br />
the anticipated market growth, especially of New Economy<br />
bioplastics, over a 5-year period the market share of Old and<br />
New Economy bioplastics is expected to reach a maximum of<br />
10 % of the global market for plastics within the next 5 years.<br />
The corresponding land use of Old and New Economy<br />
bioplastics is currently at approximately 15.5 million hectares,<br />
which is equivalent to only 0.3 % of the global agricultural<br />
area or approximately 1% of the arable land.<br />
Comparing these figures reveals that New Economy<br />
bioplastics, which tend to be the sole focus of interest in land<br />
use discussions, use up only 3 % of the area required for all<br />
biobased plastics combined.<br />
Total substitution of all petro-based<br />
plastics by biobased plastics<br />
Even assuming, as a theory, that innovative biobased<br />
plastics would be introduced globally to fully substitute for<br />
the entire range of conventional petroleum-based plastics,<br />
this scenario would require just 1.5 - 2 % of the globally<br />
available agricultural area (approx. 5 billion hectares) or<br />
about 5 - 7 % of the currently available arable land (approx.<br />
1.4 billion hectares).<br />
Contrary to common belief, this indicates that, even in<br />
view of significant growth forecasts, bioplastics are not in<br />
competition with food production!<br />
Alternative utilisation of renewable resources:<br />
Energy-related utilisation of renewable<br />
resources<br />
In the past few years energy crops, which are grown as<br />
biomass for generating heat, fuels and electricity, were<br />
covering an area of 2 million hectares in Germany. This is<br />
equivalent to almost 17 % of the total arable land in Germany.<br />
On the other hand, the cultivation of sugar, oil or starchbearing<br />
crops for material usage takes up a negligible area of<br />
0.26 million hectares (2.1 % of the arable land) in Germany. On<br />
the other hand the German land use for biogas crops is nearly<br />
1 million hectare. So it can be inferred that less than 50 %<br />
of the arable land used to grow corn for biogas production in<br />
Germany would currently be sufficient for the entire global<br />
production of bioplastics. To modify the example, German<br />
arable land for biogas production could be used to produce<br />
feedstock for 1.6 million tonnes of bio-PET. This means that<br />
almost 10 % of the global demand for PET (or more than 50 %<br />
of the European, and 350 % of the German demand), could be<br />
satisfied with the German biogas land use.<br />
German bio-ethanol for global biobased PE production:<br />
613,000 tonnes of bio-ethanol, the total amount generated<br />
from growing fodder cereals and industrial beets on around<br />
250,000 hectares of German arable land, would suffice to<br />
produce 295,000 tonnes of bio-PE. This means that even<br />
with the German land use for bioethanol the current global<br />
demand for the biobased PE, of approximately 200,000<br />
tonnes, would be over-satisfied.<br />
To make things even more compelling, it is a fact that<br />
biobased plastics, even after multiple material usage,<br />
can still serve as an energy carrier. This means that<br />
additional crop lands, which are currently used for direct<br />
energy production, could be set aside for the production<br />
of bioplastics. Prior material usage of biomass, as in the<br />
case of bioplastics, still permits subsequent trouble-free<br />
energy recovery, whereas direct incineration of biomass (and<br />
also crude oil based products!) precludes an immediate<br />
Old and New Economy Biopolymers<br />
1<br />
PLA, PHA, PTT, PBAT, Starch blends,<br />
Drop-Ins (Bio-PE, Bio-PET, Bio-PA) and other<br />
2<br />
material use excl. paperindustry<br />
3<br />
calculations include linseedoil only<br />
56.000<br />
Linoleum 3<br />
400.000<br />
New Economy<br />
Biopolymers 1 2.900.000<br />
140.000<br />
Linoleum 3<br />
1.395.000<br />
New Economy<br />
Biopolymers 1<br />
Global<br />
land use (ha)<br />
Cellulose 2<br />
Global<br />
production<br />
capacity (t)<br />
5.800.000<br />
Cellulose 2<br />
12.000.000<br />
Natural Rubber<br />
10.978.000<br />
Natural Rubber<br />
36 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
Report<br />
subsequent material usage. In this case, furthermore arable<br />
land for plant cultivation is needed and consequently another<br />
photosynthesis process, in order to gain new resources once<br />
again as feedstock for material usage.<br />
Starch consumption rate for the paper<br />
industry<br />
The starch consumption rate for the paper and board<br />
industry, for instance in Germany (2<strong>01</strong>0 about 660.000 tonnes),<br />
would be enough to cover one third of the total amount of<br />
petro-based PET needed for the plastics processing industry<br />
in that country with a 100 % biobased PET. With a 30 %<br />
biobased PET even the whole German petro based PET could<br />
be substituted with the starch used for Paper and board<br />
industry in Germany.<br />
Renewable resources instead of food waste<br />
25 % of all food products bought in Germany remain<br />
unused and are discarded. This amounts to 6.6 million<br />
tonnes (approximately 80 kg per person) each year. Increased<br />
awareness and prudent food purchases would avoid these<br />
losses and lead to an extra gain of 2.4 million hectares of<br />
arable land in Germany alone. This is six times the area<br />
currently used for New Economy bioplastics. Given that<br />
avoidably taken up area was used to produce bioplastics<br />
instead, it could substitute more than two-thirds of Germany’s<br />
PE demand with Bio-PE. Regarding PET with this wasted<br />
area in case of 100 % biobased PET more than 20 % of global<br />
PET and in case of a 30 % biobased PET even almost 80 % of<br />
global PET, i.e. 12.9 million tonnes could be substituted.<br />
Furthermore much less than 0.1 % of the global agricultural<br />
land taken up for producing discarded food (ca. 1.4 billion<br />
hectares according to FAO), would suffice to cover the<br />
current total production of New Economy bioplastics. Even<br />
when relating this context to the aforementioned maximum<br />
scenario of substituting biobased plastics for all petroleum<br />
based plastics, it can be reasonably calculated that around 7 %<br />
(in numbers 100 million hectares) of the global arable area<br />
that is now blocked in favour of discarded food would be<br />
sufficient.<br />
Against this background it seems entirely overstated to<br />
look at bioplastics - particulary the New Economy bioplastics<br />
- as the main cause or even a risk for food shortages! Plastic<br />
materials, including bioplastics, continue to make important<br />
contributions to improved transportation and storage of food<br />
products and help protect these from spoiling.<br />
More information on the market for<br />
bioplastics – free of charge<br />
A comprehensive statistical database for bioplastics has<br />
been established by the IfBB – Institute for Bioplastics and<br />
Biocomposites (Hanover University of Applied Sciences and<br />
Arts) and made available in 2<strong>01</strong>3 via the Internet (see link in<br />
the box below). This platform provides free access to a wide<br />
range of information, including market figures, production<br />
capacities, regional distribution of bioplastics production,<br />
market shares for specific materials, detailed process routes<br />
for nearly all types of bioplastics, including conversion<br />
rates for the various process steps as well as feedstock and<br />
land use requirements, comparisons of area and feedstock<br />
efficiency, future forecasts, and more. Unrestricted access,<br />
free of charge, is provided via the Internet. All graphics and<br />
charts can be downloaded for free and used according to the<br />
copyright notice.<br />
www.ifbb-hannover.de<br />
100 %<br />
Global land area<br />
13,4 billion ha<br />
37 %<br />
10 Arable % land<br />
1,4 billion ha<br />
Global agricultural area<br />
5 billion ha<br />
Arable land<br />
1,4 billion ha<br />
The database, with statistics, can be found at:<br />
www.downloads.ifbb-hannover.de<br />
0,9 %<br />
Material Use<br />
0,12 billion ha<br />
Bioplastics<br />
0,003 % 0,00004 billion ha<br />
bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 37
Basics<br />
Glossary 3.2 last update issue 02/2<strong>01</strong>3<br />
In bioplastics MAGAZINE again and again<br />
the same expressions appear that some of our readers<br />
might not (yet) be familiar with. This glossary shall help<br />
with these terms and shall help avoid repeated explanations<br />
Bioplastics (as defined by European Bioplastics<br />
e.V.) is a term used to define two different<br />
kinds of plastics:<br />
a. Plastics based on → renewable resources<br />
(the focus is the origin of the raw material<br />
used). These can be biodegradable or not.<br />
b. → Biodegradable and → compostable<br />
plastics according to EN13432 or similar<br />
standards (the focus is the compostability of<br />
the final product; biodegradable and compostable<br />
plastics can be based on renewable<br />
(biobased) and/or non-renewable (fossil) resources).<br />
Bioplastics may be<br />
- based on renewable resources and biodegradable;<br />
- based on renewable resources but not be<br />
biodegradable; and<br />
- based on fossil resources and biodegradable.<br />
Aerobic - anaerobic | aerobic = in the presence<br />
of oxygen (e.g. in composting) | anaerobic<br />
= without oxygen being present (e.g. in<br />
biogasification, anaerobic digestion)<br />
[bM 06/09]<br />
Anaerobic digestion | conversion of organic<br />
waste into bio-gas. Other than in → composting<br />
in anaerobic degradation there is no oxygen<br />
present. In bio-gas plants for example,<br />
this type of degradation leads to the production<br />
of methane that can be captured in a controlled<br />
way and used for energy generation.<br />
[14] [bM 06/09]<br />
Amorphous | non-crystalline, glassy with unordered<br />
lattice<br />
Amylopectin | Polymeric branched starch<br />
molecule with very high molecular weight (biopolymer,<br />
monomer is → Glucose)<br />
[bM 05/09]<br />
Amylose | Polymeric non-branched starch<br />
molecule with high molecular weight (biopolymer,<br />
monomer is → Glucose) [bM 05/09]<br />
Biobased plastic/polymer | A plastic/polymer<br />
in which constitutional units are totally or in<br />
part from → biomass [3]. If this claim is used,<br />
a percentage should always be given to which<br />
extent the product/material is → biobased [1]<br />
[bM <strong>01</strong>/07, bM 03/10]<br />
such as ‘PLA (Polylactide)‘ in various articles.<br />
Since this Glossary will not be printed<br />
in each issue you can download a pdf version<br />
from our website (bit.ly/OunBB0)<br />
bioplastics MAGAZINE is grateful to European Bioplastics for the permission to use parts of their Glossary (see [1])<br />
Readers who would like to suggest better or other explanations to be added to the list, please contact the editor.<br />
[*: bM ... refers to more comprehensive article previously published in bioplastics MAGAZINE)<br />
Biobased | The term biobased describes the<br />
part of a material or product that is stemming<br />
from → biomass. When making a biobasedclaim,<br />
the unit (→ biobased carbon content,<br />
→ biobased mass content), a percentage and<br />
the measuring method should be clearly stated [1]<br />
Biobased carbon | carbon contained in or<br />
stemming from → biomass. A material or<br />
product made of fossil and → renewable resources<br />
contains fossil and → biobased carbon.<br />
The 14 C method [4, 5] measures the amount<br />
of biobased carbon in the material or product<br />
as fraction weight (mass) or percent weight<br />
(mass) of the total organic carbon content [1] [6]<br />
Biobased mass content | describes the<br />
amount of biobased mass contained in a material<br />
or product. This method is complementary<br />
to the 14 C method, and furthermore, takes<br />
other chemical elements besides the biobased<br />
carbon into account, such as oxygen, nitrogen<br />
and hydrogen. A measuring method is currently<br />
being developed and tested by the Association<br />
Chimie du Végétal (ACDV) [1]<br />
Biodegradable Plastics | Biodegradable Plastics<br />
are plastics that are completely assimilated<br />
by the → microorganisms present a defined<br />
environment as food for their energy. The<br />
carbon of the plastic must completely be converted<br />
into CO 2<br />
during the microbial process.<br />
The process of biodegradation depends on<br />
the environmental conditions, which influence<br />
it (e.g. location, temperature, humidity) and<br />
on the material or application itself. Consequently,<br />
the process and its outcome can vary<br />
considerably. Biodegradability is linked to the<br />
structure of the polymer chain; it does not depend<br />
on the origin of the raw materials.<br />
There is currently no single, overarching standard<br />
to back up claims about biodegradability.<br />
One standard for example is ISO or in Europe:<br />
EN 14995 Plastics- Evaluation of compostability<br />
- Test scheme and specifications<br />
[bM 02/06, bM <strong>01</strong>/07]<br />
Biomass | Material of biological origin excluding<br />
material embedded in geological formations<br />
and material transformed to fossilised<br />
material. This includes organic material, e.g.<br />
trees, crops, grasses, tree litter, algae and<br />
waste of biological origin, e.g. manure [1, 2]<br />
Biorefinery | the co-production of a spectrum<br />
of bio-based products (food, feed, materials,<br />
chemicals including monomers or building<br />
blocks for bioplastics) and energy (fuels, power,<br />
heat) from biomass.[bM 02/13]<br />
Blend | Mixture of plastics, polymer alloy of at<br />
least two microscopically dispersed and molecularly<br />
distributed base polymers<br />
Bisphenol-A (BPA) | Monomer used to produce<br />
different polymers. BPA is said to cause<br />
health problems, due to the fact that is behaves<br />
like a hormone. Therefore it is banned<br />
for use in children’s products in many countries.<br />
BPI | Biodegradable Products Institute, a notfor-profit<br />
association. Through their innovative<br />
compostable label program, BPI educates<br />
manufacturers, legislators and consumers<br />
about the importance of scientifically based<br />
standards for compostable materials which<br />
biodegrade in large composting facilities.<br />
Carbon footprint | (CFPs resp. PCFs – Product<br />
Carbon Footprint): Sum of → greenhouse<br />
gas emissions and removals in a product system,<br />
expressed as CO 2<br />
equivalent, and based<br />
on a → life cycle assessment. The CO 2<br />
equivalent<br />
of a specific amount of a greenhouse gas<br />
is calculated as the mass of a given greenhouse<br />
gas multiplied by its → global warmingpotential<br />
[1, 2]<br />
Carbon neutral, CO 2<br />
neutral | Carbon neutral<br />
describes a product or process that has<br />
a negligible impact on total atmospheric CO 2<br />
levels. For example, carbon neutrality means<br />
that any CO 2<br />
released when a plant decomposes<br />
or is burnt is offset by an equal amount<br />
of CO 2<br />
absorbed by the plant through photosynthesis<br />
when it is growing.<br />
Carbon neutrality can also be achieved<br />
through buying sufficient carbon credits to<br />
make up the difference. The latter option is<br />
not allowed when communicating → LCAs<br />
or carbon footprints regarding a material or<br />
product [1, 2].<br />
Carbon-neutral claims are tricky as products<br />
will not in most cases reach carbon neutrality<br />
if their complete life cycle is taken into consideration<br />
(including the end-of life).<br />
If an assessment of a material, however, is<br />
conducted (cradle to gate), carbon neutrality<br />
might be a valid claim in a B2B context. In this<br />
case, the unit assessed in the complete life<br />
cycle has to be clarified [1]<br />
Catalyst | substance that enables and accelerates<br />
a chemical reaction<br />
Cellophane | Clear film on the basis of → cellulose<br />
[bM <strong>01</strong>/10]<br />
Cellulose | Cellulose is the principal component<br />
of cell walls in all higher forms of plant<br />
life, at varying percentages. It is therefore the<br />
most common organic compound and also<br />
the most common polysaccharide (multisugar)<br />
[11]. C. is a polymeric molecule with<br />
very high molecular weight (monomer is →<br />
Glucose), industrial production from wood or<br />
cotton, to manufacture paper, plastics and fibres<br />
[bM <strong>01</strong>/10]<br />
Cellulose ester| Cellulose esters occur by the<br />
esterification of cellulose with organic acids.<br />
The most important cellulose esters from a<br />
technical point of view are cellulose acetate<br />
38 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
Basics<br />
(CA with acetic acid), cellulose propionate (CP<br />
with propionic acid) and cellulose butyrate<br />
(CB with butanoic acid). Mixed polymerisates,<br />
such as cellulose acetate propionate<br />
(CAP) can also be formed. One of the most<br />
well-known applications of cellulose aceto<br />
butyrate (CAB) is the moulded handle on the<br />
Swiss army knife [11]<br />
Cellulose acetate CA| → Cellulose ester<br />
CEN | Comité Européen de Normalisation<br />
(European organisation for standardization)<br />
Compost | A soil conditioning material of decomposing<br />
organic matter which provides nutrients<br />
and enhances soil structure.<br />
[bM 06/08, 02/09]<br />
Compostable Plastics | Plastics that are<br />
→ biodegradable under ‘composting’ conditions:<br />
specified humidity, temperature,<br />
→ microorganisms and timefame. In order<br />
to make accurate and specific claims about<br />
compostability, the location (home, → industrial)<br />
and timeframe need to be specified [1].<br />
Several national and international standards<br />
exist for clearer definitions, for example EN<br />
14995 Plastics - Evaluation of compostability -<br />
Test scheme and specifications. [bM 02/06, bM <strong>01</strong>/07]<br />
Composting | A solid waste management<br />
technique that uses natural process to convert<br />
organic materials to CO 2<br />
, water and humus<br />
through the action of → microorganisms.<br />
When talking about composting of bioplastics,<br />
usually → industrial composting in a managed<br />
composting plant is meant [bM 03/07]<br />
Compound | plastic mixture from different<br />
raw materials (polymer and additives) [bM 04/10)<br />
Copolymer | Plastic composed of different<br />
monomers.<br />
Cradle-to-Gate | Describes the system<br />
boundaries of an environmental →Life Cycle<br />
Assessment (LCA) which covers all activities<br />
from the ‘cradle’ (i.e., the extraction of raw<br />
materials, agricultural activities and forestry)<br />
up to the factory gate<br />
Cradle-to-Cradle | (sometimes abbreviated<br />
as C2C): Is an expression which communicates<br />
the concept of a closed-cycle economy,<br />
in which waste is used as raw material<br />
(‘waste equals food’). Cradle-to-Cradle is not<br />
a term that is typically used in →LCA studies.<br />
Cradle-to-Grave | Describes the system<br />
boundaries of a full →Life Cycle Assessment<br />
from manufacture (‘cradle’) to use phase and<br />
disposal phase (‘grave’).<br />
Crystalline | Plastic with regularly arranged<br />
molecules in a lattice structure<br />
Density | Quotient from mass and volume of<br />
a material, also referred to as specific weight<br />
DIN | Deutsches Institut für Normung (German<br />
organisation for standardization)<br />
DIN-CERTCO | independant certifying organisation<br />
for the assessment on the conformity<br />
of bioplastics<br />
Dispersing | fine distribution of non-miscible<br />
liquids into a homogeneous, stable mixture<br />
Drop-In Bioplastics | chemically indentical<br />
to conventional petroleum based plastics,<br />
but made from renewable resources. Examples<br />
are bio-PE made from bio-ethanol (from<br />
e.g. sugar cane) or partly biobased PET (the<br />
monoethylene glykol made from bio-ethanol<br />
(from e.g. sugar cane, a development to make<br />
terephthalic acid from renewable resources<br />
are under way). Other examples are polyamides<br />
(partly biobased e.g. PA 4.10 or PA 10.10<br />
or fully biobased like PA 5.10 or 10.10)<br />
Elastomers | rigid, but under force flexible<br />
and elastically formable plastics with rubbery<br />
properties<br />
EN 13432 | European standard for the assessment<br />
of the → compostability of plastic<br />
packaging products<br />
Energy recovery | recovery and exploitation<br />
of the energy potential in (plastic) waste for<br />
the production of electricity or heat in waste<br />
incineration pants (waste-to-energy)<br />
Enzymes | proteins that catalyze chemical<br />
reactions<br />
Ethylen | colour- and odourless gas, made<br />
e.g. from, Naphtha (petroleum) by cracking,<br />
monomer of the polymer polyethylene (PE)<br />
European Bioplastics e.V. | The industry association<br />
representing the interests of Europe’s<br />
thriving bioplastics’ industry. Founded<br />
in Germany in 1993 as IBAW, European Bioplastics<br />
today represents the interests of over<br />
70 member companies throughout the European<br />
Union. With members from the agricultural<br />
feedstock, chemical and plastics industries,<br />
as well as industrial users and recycling<br />
companies, European Bioplastics serves as<br />
both a contact platform and catalyst for advancing<br />
the aims of the growing bioplastics<br />
industry.<br />
Extrusion | process used to create plastic<br />
profiles (or sheet) of a fixed cross-section<br />
consisting of mixing, melting, homogenising<br />
and shaping of the plastic.<br />
Fermentation | Biochemical reactions controlled<br />
by → microorganisms or → enyzmes (e.g.<br />
the transformation of sugar into lactic acid).<br />
FSC | Forest Stewardship Council. FSC is an<br />
independent, non-governmental, not-forprofit<br />
organization established to promote the<br />
responsible and sustainable management of<br />
the world’s forests.<br />
Gelatine | Translucent brittle solid substance,<br />
colorless or slightly yellow, nearly tasteless<br />
and odorless, extracted from the collagen inside<br />
animals‘ connective tissue.<br />
Genetically modified organism (GMO) | Organisms,<br />
such as plants and animals, whose<br />
genetic material (DNA) has been altered<br />
are called genetically modified organisms<br />
(GMOs). Food and feed which contain or<br />
consist of such GMOs, or are produced from<br />
GMOs, are called genetically modified (GM)<br />
food or feed [1]<br />
Global Warming | Global warming is the rise<br />
in the average temperature of Earth’s atmosphere<br />
and oceans since the late 19th century<br />
and its projected continuation [8]. Global<br />
warming is said to be accelerated by → green<br />
house gases.<br />
Glucose | Monosaccharide (or simple sugar).<br />
G. is the most important carbohydrate (sugar)<br />
in biology. G. is formed by photosynthesis or<br />
hydrolyse of many carbohydrates e. g. starch.<br />
Greenhouse gas GHG | Gaseous constituent<br />
of the atmosphere, both natural and anthropogenic,<br />
that absorbs and emits radiation at<br />
specific wavelengths within the spectrum of<br />
infrared radiation emitted by the earth’s surface,<br />
the atmosphere, and clouds [1, 9]<br />
Greenwashing | The act of misleading consumers<br />
regarding the environmental practices<br />
of a company, or the environmental benefits<br />
of a product or service [1, 10]<br />
Granulate, granules | small plastic particles<br />
(3-4 millimetres), a form in which plastic is<br />
sold and fed into machines, easy to handle<br />
and dose.<br />
Humus | In agriculture, ‘humus’ is often used<br />
simply to mean mature → compost, or natural<br />
compost extracted from a forest or other<br />
spontaneous source for use to amend soil.<br />
Hydrophilic | Property: ‘water-friendly’, soluble<br />
in water or other polar solvents (e.g. used<br />
in conjunction with a plastic which is not water<br />
resistant and weather proof or that absorbs<br />
water such as Polyamide (PA).<br />
Hydrophobic | Property: ‘water-resistant’, not<br />
soluble in water (e.g. a plastic which is water<br />
resistant and weather proof, or that does not<br />
absorb any water such as Polyethylene (PE)<br />
or Polypropylene (PP).<br />
IBAW | → European Bioplastics<br />
Industrial composting | Industrial composting<br />
is an established process with commonly<br />
agreed upon requirements (e.g. temperature,<br />
timeframe) for transforming biodegradable<br />
waste into stable, sanitised products to be<br />
used in agriculture. The criteria for industrial<br />
compostability of packaging have been defined<br />
in the EN 13432. Materials and products<br />
complying with this standard can be certified<br />
and subsequently labelled accordingly [1, 7]<br />
[bM 06/08, bM 02/09]<br />
Integral Foam | foam with a compact skin and<br />
porous core and a transition zone in between.<br />
ISO | International Organization for Standardization<br />
JBPA | Japan Bioplastics Association<br />
LCA | Life Cycle Assessment (sometimes also<br />
referred to as life cycle analysis, ecobalance,<br />
and → cradle-to-grave analysis) is the investigation<br />
and valuation of the environmental<br />
impacts of a given product or service caused.<br />
[bM <strong>01</strong>/09]<br />
Microorganism | Living organisms of microscopic<br />
size, such as bacteria, funghi or yeast.<br />
Molecule | group of at least two atoms held<br />
together by covalent chemical bonds.<br />
Monomer | molecules that are linked by polymerization<br />
to form chains of molecules and<br />
then plastics<br />
Mulch film | Foil to cover bottom of farmland<br />
PBAT | Polybutylene adipate terephthalate, is<br />
an aliphatic-aromatic copolyester that has the<br />
properties of conventional polyethylene but is<br />
fully biodegradable under industrial composting.<br />
PBAT is made from fossil petroleum with<br />
first attempts being made to produce it partly<br />
from renewable resources [bM 06/09]<br />
PBS | Polybutylene succinate, a 100% biodegradable<br />
polymer, made from (e.g. bio-BDO)<br />
and succinic acid, which can also be produced<br />
biobased [bM 03/12].<br />
PC | Polycarbonate, thermoplastic polyester,<br />
petroleum based, used for e.g. baby bottles<br />
or CDs. Criticized for its BPA (→ Bisphenol-A)<br />
content.<br />
bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 39
Basics<br />
PCL | Polycaprolactone, a synthetic (fossil<br />
based), biodegradable bioplastic, e.g. used as<br />
a blend component.<br />
PE | Polyethylene, thermoplastic polymerised<br />
from ethylene. Can be made from renewable<br />
resources (sugar cane via bio-ethanol)<br />
[bM 05/10]<br />
PET | Polyethylenterephthalate, transparent<br />
polyester used for bottles and film<br />
PGA | Polyglycolic acid or Polyglycolide is a<br />
biodegradable, thermoplastic polymer and<br />
the simplest linear, aliphatic polyester. Besides<br />
ist use in the biomedical field, PGA has<br />
been introduced as a barrier resin [bM 03/09]<br />
PHA | Polyhydroxyalkanoates are linear polyesters<br />
produced in nature by bacterial fermentation<br />
of sugar or lipids. The most common<br />
type of PHA is → PHB.<br />
PHB | Polyhydroxybutyrate (better poly-3-hydroxybutyrate),<br />
is a polyhydroxyalkanoate<br />
(PHA), a polymer belonging to the polyesters<br />
class. PHB is produced by micro-organisms<br />
apparently in response to conditions of physiological<br />
stress. The polymer is primarily a<br />
product of carbon assimilation (from glucose<br />
or starch) and is employed by micro-organisms<br />
as a form of energy storage molecule to<br />
be metabolized when other common energy<br />
sources are not available. PHB has properties<br />
similar to those of PP, however it is stiffer and<br />
more brittle.<br />
PHBH | Polyhydroxy butyrate hexanoate (better<br />
poly 3-hydroxybutyrate-co-3-hydroxyhexanoate)<br />
is a polyhydroxyalkanoate (PHA),<br />
Like other biopolymers from the family of the<br />
polyhydroxyalkanoates PHBH is produced by<br />
microorganisms in the fermentation process,<br />
where it is accumulated in the microorganism’s<br />
body for nutrition. The main features of<br />
PHBH are its excellent biodegradability, combined<br />
with a high degree of hydrolysis and<br />
heat stability. [bM 03/09, <strong>01</strong>/10, 03/11]<br />
PLA | Polylactide or Polylactic Acid (PLA), a<br />
biodegradable, thermoplastic, linear aliphatic<br />
polyester based on lactic acid, a natural acid,<br />
is mainly produced by fermentation of sugar<br />
or starch with the help of micro-organisms.<br />
Lactic acid comes in two isomer forms, i.e.<br />
as laevorotatory D(-)lactic acid and as dextrorotary<br />
L(+)lactic acid. In each case two<br />
lactic acid molecules form a circular lactide<br />
molecule which, depending on its composition,<br />
can be a D-D-lactide, an L-L-lactide<br />
or a meso-lactide (having one D and one L<br />
molecule). The chemist makes use of this<br />
variability. During polymerisation the chemist<br />
combines the lactides such that the PLA<br />
plastic obtained has the characteristics that<br />
he desires. The purity of the infeed material is<br />
an important factor in successful polymerisation<br />
and thus for the economic success of the<br />
process, because so far the cleaning of the<br />
lactic acid produced by the fermentation has<br />
been relatively costly [12].<br />
Modified PLA types can be produced by the<br />
use of the right additives or by a combinations<br />
of L- and D- lactides (stereocomplexing),<br />
which then have the required rigidity for use<br />
at higher temperatures [13] [bM <strong>01</strong>/09]<br />
Plastics | Materials with large molecular<br />
chains of natural or fossil raw materials, produced<br />
by chemical or biochemical reactions.<br />
PPC | Polypropylene Carbonate, a bioplastic<br />
made by copolymerizing CO 2<br />
with propylene<br />
oxide (PO) [bM 04/12]<br />
Renewable Resources | agricultural raw materials,<br />
which are not used as food or feed, but<br />
as raw material for industrial products or to<br />
generate energy<br />
Saccharins or carbohydrates | Saccharins or<br />
carbohydrates are name for the sugar-family.<br />
Saccharins are monomer or polymer sugar<br />
units. For example, there are known mono-,<br />
di- and polysaccharose. → glucose is a monosaccarin.<br />
They are important for the diet and<br />
produced biology in plants.<br />
Semi-finished products | plastic in form of<br />
sheet, film, rods or the like to be further processed<br />
into finshed products<br />
Sorbitol | Sugar alcohol, obtained by reduction<br />
of glucose changing the aldehyde group<br />
to an additional hydroxyl group. S. is used as<br />
a plasticiser for bioplastics based on starch.<br />
Starch | Natural polymer (carbohydrate)<br />
consisting of → amylose and → amylopectin,<br />
gained from maize, potatoes, wheat, tapioca<br />
etc. When glucose is connected to polymerchains<br />
in definite way the result (product) is<br />
called starch. Each molecule is based on 300<br />
-12000-glucose units. Depending on the connection,<br />
there are two types → amylose and →<br />
amylopectin known. [bM 05/09]<br />
Starch derivate | Starch derivates are based<br />
on the chemical structure of → starch. The<br />
chemical structure can be changed by introducing<br />
new functional groups without changing<br />
the → starch polymer. The product has<br />
different chemical qualities. Mostly the hydrophilic<br />
character is not the same.<br />
Starch-ester | One characteristic of every<br />
starch-chain is a free hydroxyl group. When<br />
every hydroxyl group is connect with ethan<br />
acid one product is starch-ester with different<br />
chemical properties.<br />
Starch propionate and starch butyrate |<br />
Starch propionate and starch butyrate can be<br />
synthesised by treating the → starch with propane<br />
or butanic acid. The product structure<br />
is still based on → starch. Every based → glucose<br />
fragment is connected with a propionate<br />
or butyrate ester group. The product is more<br />
hydrophobic than → starch.<br />
Sustainable | An attempt to provide the best<br />
outcomes for the human and natural environments<br />
both now and into the indefinite future.<br />
One of the most often cited definitions of sustainability<br />
is the one created by the Brundtland<br />
Commission, led by the former Norwegian<br />
Prime Minister Gro Harlem Brundtland.<br />
The Brundtland Commission defined sustainable<br />
development as development that ‘meets<br />
the needs of the present without compromising<br />
the ability of future generations to meet<br />
their own needs.’ Sustainability relates to the<br />
continuity of economic, social, institutional<br />
and environmental aspects of human society,<br />
as well as the non-human environment).<br />
Sustainability | (as defined by European Bioplastics<br />
e.V.) has three dimensions: economic,<br />
social and environmental. This has been<br />
known as “the triple bottom line of sustainability”.<br />
This means that sustainable development<br />
involves the simultaneous pursuit of<br />
economic prosperity, environmental protection<br />
and social equity. In other words, businesses<br />
have to expand their responsibility to include<br />
these environmental and social dimensions.<br />
Sustainability is about making products useful<br />
to markets and, at the same time, having societal<br />
benefits and lower environmental impact<br />
than the alternatives currently available. It also<br />
implies a commitment to continuous improvement<br />
that should result in a further reduction<br />
of the environmental footprint of today’s products,<br />
processes and raw materials used.<br />
Thermoplastics | Plastics which soften or<br />
melt when heated and solidify when cooled<br />
(solid at room temperature).<br />
Thermoplastic Starch | (TPS) → starch that<br />
was modified (cooked, complexed) to make it<br />
a plastic resin<br />
Thermoset | Plastics (resins) which do not<br />
soften or melt when heated. Examples are<br />
epoxy resins or unsaturated polyester resins.<br />
Vinçotte | independant certifying organisation<br />
for the assessment on the conformity of bioplastics<br />
WPC | Wood Plastic Composite. Composite<br />
materials made of wood fiber/flour and plastics<br />
(mostly polypropylene).<br />
Yard Waste | Grass clippings, leaves, trimmings,<br />
garden residue.<br />
References:<br />
[1] Environmental Communication Guide,<br />
European Bioplastics, Berlin, Germany,<br />
2<strong>01</strong>2<br />
[2] ISO 14067. Carbon footprint of products -<br />
Requirements and guidelines for quantification<br />
and communication<br />
[3] CEN TR 15932, Plastics - Recommendation<br />
for terminology and characterisation<br />
of biopolymers and bioplastics, 2<strong>01</strong>0<br />
[4] CEN/TS 16137, Plastics - Determination<br />
of bio-based carbon content, 2<strong>01</strong>1<br />
[5] ASTM D6866, Standard Test Methods for<br />
Determining the Biobased Content of<br />
Solid, Liquid, and Gaseous Samples Using<br />
Radiocarbon Analysis<br />
[6] SPI: Understanding Biobased Carbon<br />
Content, 2<strong>01</strong>2<br />
[7] EN 13432, Requirements for packaging<br />
recoverable through composting and biodegradation.<br />
Test scheme and evaluation<br />
criteria for the final acceptance of packaging,<br />
2000<br />
[8] Wikipedia<br />
[9] ISO 14064 Greenhouse gases -- Part 1:<br />
Specification with guidance..., 2006<br />
[10] Terrachoice, 2<strong>01</strong>0, www.terrachoice.com<br />
[11] Thielen, M.: Bioplastics: Basics. Applications.<br />
Markets, Polymedia Publisher,<br />
2<strong>01</strong>2<br />
[12] Lörcks, J.: Biokunststoffe, Broschüre der<br />
FNR, 2005<br />
[13] de Vos, S.: Improving heat-resistance of<br />
PLA using poly(D-lactide),<br />
bioplastics MAGAZINE, Vol. 3, <strong>Issue</strong> 02/2008<br />
[14] de Wilde, B.: Anaerobic Digestion, bioplastics<br />
MAGAZINE, Vol 4., <strong>Issue</strong> 06/2009<br />
40 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
Exhibition area exceeds 220,000 sqm<br />
Over 2,900 exhibitors from 39 countries & regions<br />
14 country / region pavilions including Austria,<br />
Germany, Italy, USA, PR China & Taiwan<br />
120,000+ trade visitors from 130 countries<br />
2<strong>01</strong>3-10-18
Events<br />
Subscribe<br />
now at<br />
bioplasticsmagazine.com<br />
the next six issues for €149.– 1)<br />
Event Calendar<br />
Special offer<br />
for students and<br />
young professionals 1,2)<br />
€ 99.-<br />
2) aged 35 and below. Send a scan<br />
of your student card, your ID or<br />
similar proof ...<br />
World Bio Markets 2<strong>01</strong>4<br />
04.03.2<strong>01</strong>4 - 06.03.2<strong>01</strong>4 - Amsterdam, The Netherlands<br />
RAI Amsterdam<br />
www.worldbiofuelsmarkets.com<br />
BioPlastics 2<strong>01</strong>4: The Re-Invention of Plastics<br />
04.03.2<strong>01</strong>4 - 06.03.2<strong>01</strong>4 - Las Vegas, NV, USA<br />
Caesars Palace<br />
www.BioplastConference.com<br />
5th International Seminar on<br />
Biopolymers and Sustainable Composites<br />
06.03.2<strong>01</strong>4 - 07.03.2<strong>01</strong>4 - Valencia, Spain<br />
www.biopolymersmeeting.com/en/<br />
+<br />
or<br />
Green Polymer Chemistry 2<strong>01</strong>4<br />
18.03.2<strong>01</strong>4 - 20.03.2<strong>01</strong>4 - Cologne, Germany<br />
Maritim Hotel, Cologne<br />
amiplastics.com/events/Event.aspx?code=C564&sec=3717<br />
Tage der Holzforschung 2<strong>01</strong>4<br />
20.03.2<strong>01</strong>4 - 21.03.2<strong>01</strong>4 - Braunschweig,Germany<br />
www.ivth.org<br />
Plastics in Automotive Engineering (VDI)<br />
02.04.2<strong>01</strong>4 - 03.04.2<strong>01</strong>4 - Mannheim, Germany<br />
www.kunststoffe-im-auto.de<br />
7th International Conference on Bio-based Materials<br />
08.04.2<strong>01</strong>4 - 10.04.2<strong>01</strong>4 - Cologne, Germany<br />
Maternushaus<br />
www.bio-based.eu/conference<br />
Biopolymers Symposium 2<strong>01</strong>4<br />
12.05.2<strong>01</strong>4 - 13.05.2<strong>01</strong>4 - Philadelphia PA, USA<br />
Loews Philadelphia Hotel<br />
www.biopolymersummit.com/venue.aspx<br />
3rd PLA World Congress<br />
27.05.2<strong>01</strong>4 – 28.05.2<strong>01</strong>4 – Munich, Germany<br />
Holiday Inn Munich City Centre<br />
www.pla-world-congress.com<br />
GreenTech<br />
10.06.2<strong>01</strong>4 - 12.06.2<strong>01</strong>4 - Amsterdam, The Netherlands<br />
RAI Amsterdam<br />
www.greentech.nl<br />
Biobased Materials<br />
24.06.2<strong>01</strong>4 - 25.06.2<strong>01</strong>4 - Stuttgart, Germany<br />
10th Congress for Biobased Materials, Natural Fibres and WPC<br />
www.biobased-materials.com<br />
Mention the promotion code ‘watch‘ or ‘book‘<br />
and you will get our watch or the book 3)<br />
Bioplastics Basics. Applications. Markets. for free<br />
1) Offer valid until 31 Apr. 2<strong>01</strong>4<br />
3) Gratis-Buch in Deutschland nicht möglich, no free book in Germany<br />
9th European Bioplastics<br />
02.12.2<strong>01</strong>4 - 03.12.2<strong>01</strong>4 - Brussels, Belgien<br />
The Square, Brussels<br />
www.european-bioplastics.org<br />
You can meet us! Please contact us in advance by e-mail.
Suppliers Guide<br />
1. Raw Materials<br />
AGRANA Starch<br />
Thermoplastics<br />
Conrathstrasse 7<br />
A-3950 Gmuend, Austria<br />
Tel: +43 676 8926 19374<br />
lukas.raschbauer@agrana.com<br />
www.agrana.com<br />
Shandong Fuwin New Material Co., Ltd.<br />
Econorm ® Biodegradable &<br />
Compostable Resin<br />
North of Baoshan Road, Zibo City,<br />
Shandong Province P.R. China.<br />
Phone: +86 533 7986<strong>01</strong>6<br />
Fax: +86 533 62<strong>01</strong>788<br />
Mobile: +86-13953357190<br />
CNMHELEN@GMAIL.COM<br />
www.sdfuwin.com<br />
FKuR Kunststoff GmbH<br />
Siemensring 79<br />
D - 47 877 Willich<br />
Tel. +49 2154 9251-0<br />
Tel.: +49 2154 9251-51<br />
sales@fkur.com<br />
www.fkur.com<br />
39 mm<br />
Simply contact:<br />
Tel.: +49 2161 6884467<br />
suppguide@bioplasticsmagazine.com<br />
Stay permanently listed in the<br />
Suppliers Guide with your company<br />
logo and contact information.<br />
For only 6,– EUR per mm, per issue you<br />
can be present among top suppliers in<br />
the field of bioplastics.<br />
For Example:<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
41066 Mönchengladbach<br />
Germany<br />
Tel. +49 2161 664864<br />
Fax +49 2161 631045<br />
info@bioplasticsmagazine.com<br />
www.bioplasticsmagazine.com<br />
Showa Denko Europe GmbH<br />
Konrad-Zuse-Platz 4<br />
81829 Munich, Germany<br />
Tel.: +49 89 93996226<br />
www.showa-denko.com<br />
support@sde.de<br />
DuPont de Nemours International S.A.<br />
2 chemin du Pavillon<br />
1218 - Le Grand Saconnex<br />
Switzerland<br />
Tel.: +41 22 171 51 11<br />
Fax: +41 22 580 22 45<br />
plastics@dupont.com<br />
www.renewable.dupont.com<br />
www.plastics.dupont.com<br />
Tel: +86 351-8689356<br />
Fax: +86 351-8689718<br />
www.ecoworld.jinhuigroup.com<br />
jinhuibio@126.com<br />
Jincheng, Lin‘an, Hangzhou,<br />
Zhejiang 311300, P.R. China<br />
China contact: Grace Jin<br />
mobile: 0086 135 7578 9843<br />
Grace@xinfupharm.com<br />
Europe contact(Belgium): Susan Zhang<br />
mobile: 0032 478 991619<br />
zxh0612@hotmail.com<br />
www.xinfupharm.com<br />
1.1 bio based monomers<br />
Corbion Purac<br />
Arkelsedijk 46, P.O. Box 21<br />
4200 AA Gorinchem -<br />
The Netherlands<br />
Tel.: +31 (0)183 695 695<br />
Fax: +31 (0)183 695 604<br />
www.corbion.com/bioplastics<br />
bioplastics@corbion.com<br />
1.2 compounds<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
Natur-Tec ® - Northern Technologies<br />
42<strong>01</strong> Woodland Road<br />
Circle Pines, MN 55<strong>01</strong>4 USA<br />
Tel. +1 763.225.6600<br />
Fax +1 763.225.6645<br />
info@natur-tec.com<br />
www.natur-tec.com<br />
PolyOne<br />
Avenue Melville Wilson, 2<br />
Zoning de la Fagne<br />
5330 Assesse<br />
Belgium<br />
Tel.: + 32 83 660 211<br />
www.polyone.com<br />
Sample Charge:<br />
39mm x 6,00 €<br />
= 234,00 € per entry/per issue<br />
Sample Charge for one year:<br />
6 issues x 234,00 EUR = 1,404.00 €<br />
The entry in our Suppliers Guide is<br />
bookable for one year (6 issues) and<br />
extends automatically if it’s not canceled<br />
three month before expiry.<br />
Evonik Industries AG<br />
Paul Baumann Straße 1<br />
45772 Marl, Germany<br />
Tel +49 2365 49-4717<br />
evonik-hp@evonik.com<br />
www.vestamid-terra.com<br />
www.evonik.com<br />
API S.p.A.<br />
Via Dante Alighieri, 27<br />
36065 Mussolente (VI), Italy<br />
Telephone +39 0424 579711<br />
www.apiplastic.com<br />
www.apinatbio.com<br />
WinGram Industry CO., LTD<br />
Great River(Qin Xin)<br />
Plastic Manufacturer CO., LTD<br />
Mobile (China): +86-13113833156<br />
Mobile (Hong Kong): +852-63078857<br />
Fax: +852-3184 8934<br />
Email: Benson@wingram.hk<br />
www.facebook.com<br />
www.issuu.com<br />
www.twitter.com<br />
www.youtube.com<br />
Natureplast<br />
11 rue François Arago<br />
14123 Ifs – France<br />
Tel. +33 2 31 83 50 87<br />
www.natureplast.eu<br />
t.lefevre@natureplast.eu<br />
Kingfa Sci. & Tech. Co., Ltd.<br />
No.33 Kefeng Rd, Sc. City, Guangzhou<br />
Hi-Tech Ind. Development Zone,<br />
Guangdong, P.R. China. 510663<br />
Tel: +86 (0)20 6622 1696<br />
info@ecopond.com.cn<br />
www.ecopond.com.cn<br />
FLEX-162 Biodeg. Blown Film Resin!<br />
Bio-873 4-Star Inj. Bio-Based Resin!<br />
1.3 PLA<br />
Shenzhen Esun Ind. Co;Ltd<br />
www.brightcn.net<br />
www.esun.en.alibaba.com<br />
bright@brightcn.net<br />
Tel: +86-755-2603 1978<br />
bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 43
Suppliers Guide<br />
1.4 starch-based bioplastics<br />
6. Equipment<br />
Limagrain Céréales Ingrédients<br />
ZAC „Les Portes de Riom“ - BP 173<br />
63204 Riom Cedex - France<br />
Tel. +33 (0)4 73 67 17 00<br />
Fax +33 (0)4 73 67 17 10<br />
www.biolice.com<br />
Metabolix, Inc.<br />
Bio-based and biodegradable resins<br />
and performance additives<br />
21 Erie Street<br />
Cambridge, MA 02139, USA<br />
US +1-617-583-1700<br />
DE +49 (0) 221 / 88 88 94 00<br />
www.metabolix.com<br />
info@metabolix.com<br />
1.6 masterbatches<br />
www.earthfirstpla.com<br />
www.sidaplax.com<br />
www.plasticsuppliers.com<br />
Sidaplax UK : +44 (1) 604 76 66 99<br />
Sidaplax Belgium: +32 9 210 80 10<br />
Plastic Suppliers: +1 866 378 4178<br />
6.1 Machinery & Molds<br />
Molds, Change Parts and Turnkey<br />
Solutions for the PET/Bioplastic<br />
Container Industry<br />
284 Pinebush Road<br />
Cambridge Ontario<br />
Canada N1T 1Z6<br />
Tel. +1 519 624 9720<br />
Fax +1 519 624 9721<br />
info@hallink.com<br />
www.hallink.com<br />
BIOTEC<br />
Biologische Naturverpackungen<br />
Werner-Heisenberg-Strasse 32<br />
46446 Emmerich/Germany<br />
Tel.: +49 (0) 2822 – 92510<br />
info@biotec.de<br />
www.biotec.de<br />
ROQUETTE<br />
62 136 LESTREM, FRANCE<br />
00 33 (0) 3 21 63 36 00<br />
www.gaialene.com<br />
www.roquette.com<br />
Grabio Greentech Corporation<br />
Tel: +886-3-598-6496<br />
No. 91, Guangfu N. Rd., Hsinchu<br />
Industrial Park,Hukou Township,<br />
Hsinchu County 30351, Taiwan<br />
sales@grabio.com.tw<br />
www.grabio.com.tw<br />
PSM Bioplastic HK<br />
Room 19<strong>01</strong>B,19/F, Allied Kajima<br />
Buil- ding 138 Gloucester Road,<br />
Wanchai, Hongkong<br />
Tel: +852-31767566<br />
Fax: +852-31767567<br />
support@psm.com.cn<br />
www.psm.com.cn<br />
1.5 PHA<br />
TianAn Biopolymer<br />
No. 68 Dagang 6th Rd,<br />
Beilun, Ningbo, China, 315800<br />
Tel. +86-57 48 68 62 50 2<br />
Fax +86-57 48 68 77 98 0<br />
enquiry@tianan-enmat.com<br />
www.tianan-enmat.com<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
PolyOne<br />
Avenue Melville Wilson, 2<br />
Zoning de la Fagne<br />
5330 Assesse<br />
Belgium<br />
Tel.: + 32 83 660 211<br />
www.polyone.com<br />
2. Additives/Secondary raw materials<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
Rhein Chemie Rheinau GmbH<br />
Duesseldorfer Strasse 23-27<br />
68219 Mannheim, Germany<br />
Phone: +49 (0)621-8907-233<br />
Fax: +49 (0)621-8907-8233<br />
bioadimide.eu@rheinchemie.com<br />
www.bioadimide.com<br />
3. Semi finished products<br />
3.1 films<br />
Huhtamaki Films<br />
Sonja Haug<br />
Zweibrückenstraße 15-25<br />
913<strong>01</strong> Forchheim<br />
Tel. +49-9191 81203<br />
Fax +49-9191 811203<br />
www.huhtamaki-films.com<br />
Taghleef Industries SpA, Italy<br />
Via E. Fermi, 46<br />
33058 San Giorgio di Nogaro (UD)<br />
Contact Frank Ernst<br />
Tel. +49 2402 7096989<br />
Mobile +49 160 4756573<br />
frank.ernst@ti-films.com<br />
www.ti-films.com<br />
4. Bioplastics products<br />
Minima Technology Co., Ltd.<br />
Esmy Huang, Marketing Manager<br />
No.33. Yichang E. Rd., Taipin City,<br />
Taichung County<br />
411, Taiwan (R.O.C.)<br />
Tel. +886(4)2277 6888<br />
Fax +883(4)2277 6989<br />
Mobil +886(0)982-829988<br />
esmy@minima-tech.com<br />
Skype esmy325<br />
www.minima-tech.com<br />
NOVAMONT S.p.A.<br />
Via Fauser , 8<br />
28100 Novara - ITALIA<br />
Fax +39.0321.699.6<strong>01</strong><br />
Tel. +39.0321.699.611<br />
www.novamont.com<br />
President Packaging Ind., Corp.<br />
PLA Paper Hot Cup manufacture<br />
In Taiwan, www.ppi.com.tw<br />
Tel.: +886-6-570-4066 ext.5531<br />
Fax: +886-6-570-4077<br />
sales@ppi.com.tw<br />
ProTec Polymer Processing GmbH<br />
Stubenwald-Allee 9<br />
64625 Bensheim, Deutschland<br />
Tel. +49 6251 77061 0<br />
Fax +49 6251 77061 500<br />
info@sp-protec.com<br />
www.sp-protec.com<br />
6.2 Laboratory Equipment<br />
MODA: Biodegradability Analyzer<br />
SAIDA FDS INC.<br />
143-10 Isshiki, Yaizu,<br />
Shizuoka,Japan<br />
Tel:+81-54-624-6260<br />
Info2@moda.vg<br />
www.saidagroup.jp<br />
7. Plant engineering<br />
EREMA Engineering Recycling<br />
Maschinen und Anlagen GmbH<br />
Unterfeldstrasse 3<br />
4052 Ansfelden, AUSTRIA<br />
Phone: +43 (0) 732 / 3190-0<br />
Fax: +43 (0) 732 / 3190-23<br />
erema@erema.at<br />
www.erema.at<br />
Uhde Inventa-Fischer GmbH<br />
Holzhauser Strasse 157–159<br />
D-13509 Berlin<br />
Tel. +49 30 43 567 5<br />
Fax +49 30 43 567 699<br />
sales.de@uhde-inventa-fischer.com<br />
Uhde Inventa-Fischer AG<br />
Via Innovativa 31<br />
CH-7<strong>01</strong>3 Domat/Ems<br />
Tel. +41 81 632 63 11<br />
Fax +41 81 632 74 03<br />
sales.ch@uhde-inventa-fischer.com<br />
www.uhde-inventa-fischer.com<br />
44 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
Suppliers Guide<br />
9. Services<br />
10.2 Universities<br />
Biopolynov<br />
11 rue François Arago<br />
14123 Ifs – France<br />
Tel. +33 2 31 83 50 87<br />
www. biopolynov.com<br />
t.lefevre@natureplast.eu<br />
Osterfelder Str. 3<br />
46047 Oberhausen<br />
Tel.: +49 (0)208 8598 1227<br />
Fax: +49 (0)208 8598 1424<br />
thomas.wodke@umsicht.fhg.de<br />
www.umsicht.fraunhofer.de<br />
Institut für Kunststofftechnik<br />
Universität Stuttgart<br />
Böblinger Straße 70<br />
7<strong>01</strong>99 Stuttgart<br />
Tel +49 711/685-62814<br />
Linda.Goebel@ikt.uni-stuttgart.de<br />
www.ikt.uni-stuttgart.de<br />
narocon<br />
Dr. Harald Kaeb<br />
Tel.: +49 30-28096930<br />
kaeb@narocon.de<br />
www.narocon.de<br />
nova-Institut GmbH<br />
Chemiepark Knapsack<br />
Industriestrasse 300<br />
50354 Huerth, Germany<br />
Tel.: +49(0)2233-48-14 40<br />
E-Mail: contact@nova-institut.de<br />
www.biobased.eu<br />
Bioplastics Consulting<br />
Tel. +49 2161 664864<br />
info@polymediaconsult.com<br />
UL International TTC GmbH<br />
Rheinuferstrasse 7-9, Geb. R33<br />
47829 Krefeld-Uerdingen, Germany<br />
Tel: +49 (0)2151 88 3324<br />
Fax: +49 (0)2151 88 5210<br />
ttc@ul.com<br />
www.ulttc.com<br />
10. Institutions<br />
10.1 Associations<br />
BPI - The Biodegradable<br />
Products Institute<br />
331 West 57th Street, Suite 415<br />
New York, NY 10<strong>01</strong>9, USA<br />
Tel. +1-888-274-5646<br />
info@bpiworld.org<br />
European Bioplastics e.V.<br />
Marienstr. 19/20<br />
1<strong>01</strong>17 Berlin, Germany<br />
Tel. +49 30 284 82 350<br />
Fax +49 30 284 84 359<br />
info@european-bioplastics.org<br />
www.european-bioplastics.org<br />
IfBB – Institute for Bioplastics<br />
and Biocomposites<br />
University of Applied Sciences<br />
and Arts Hanover<br />
Faculty II – Mechanical and<br />
Bioprocess Engineering<br />
Heisterbergallee 12<br />
30453 Hannover, Germany<br />
Tel.: +49 5 11 / 92 96 - 22 69<br />
Fax: +49 5 11 / 92 96 - 99 - 22 69<br />
lisa.mundzeck@fh-hannover.de<br />
http://www.ifbb-hannover.de/<br />
Michigan State University<br />
Department of Chemical<br />
Engineering & Materials Science<br />
Professor Ramani Narayan<br />
East Lansing MI 48824, USA<br />
Tel. +1 517 719 7163<br />
narayan@msu.edu<br />
7. Biowerkstoff-Kongress<br />
International Conference<br />
on Bio-based Materials<br />
8–10 April 2<strong>01</strong>4, Maternushaus, Cologne, Germany<br />
Organiser<br />
Venue & Accomodation<br />
Maternushaus Cologne, Germany<br />
Kardinal-Frings-Str. 1–3, 50668 Cologne<br />
+49 (0)221 163 10 | info@maternushaus.de<br />
HIGHLIGHTS FROM EUROPE: Bio-based Plastics and Composites<br />
– Biorefineries and Industrial Biotechnology<br />
1 st Day (8 April 2<strong>01</strong>4): Policy and Industry<br />
• Policy & Strategy<br />
• Biorefineries in Europe<br />
• Innovation Award (6 presentations)<br />
2 nd Day (9 April 2<strong>01</strong>4): Industry<br />
• Industrial Biotechnology & Bio-based building blocks<br />
• Bio-based plastics & polymers<br />
• Bio-based Composites<br />
3 rd Day (10 April 2<strong>01</strong>4): Science<br />
• Science & Start-ups<br />
Book now<br />
10% reduction – enter code bio-based<br />
during your booking.<br />
www.nova-institute.eu<br />
Contact<br />
Dominik Vogt<br />
Exhibition, Partners,<br />
Media partners, Sponsors<br />
+49 (0)2233 4814-49<br />
dominik.vogt@nova-institut.de<br />
www.bio-based.eu/conference<br />
bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 45
Companies in this issue<br />
Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />
Agrana Starch Thermoplastics 43<br />
AIMPLAS 5<br />
Aphios Corporation 6<br />
API 43<br />
Arkema 21<br />
BASF 13<br />
Bio4Pack 27<br />
Biopolynov 45<br />
Biotec 14 44<br />
BPI - The Biodegradable Products Institute 45<br />
Braskem 11<br />
Celabor 22<br />
Center for Bioplastics and Biocomposites 28<br />
CONAI 14<br />
Coperion 22<br />
Corbion Purac 10, 16 43<br />
DSM 18<br />
DuPont 43<br />
Ecovative Design 29<br />
Erema 10 44<br />
European Bioplastics 9, 10 45<br />
Evonik Industries 7 43, 47<br />
Extruline Systems 5<br />
FKuR 10 2, 43<br />
Flanders Plast Vision 22<br />
Floreon 10<br />
Ford 3, 15<br />
Fraunhofer ICT 10<br />
Fraunhofer IVV 10<br />
Fraunhofer LBF 22<br />
Fraunhofer UMSICHT 45<br />
Grabio Greentech Corporation 44<br />
Grafe 43, 44<br />
GreenTech 33<br />
Hallink 44<br />
Hanover University 13<br />
Helmut Lingemann 8, 9<br />
Huhtamaki Films 44<br />
Institut for Bioplastics & Biocomposites (IfBB) 9, 10, 34 45<br />
Institut für Kunststofftechnik 45<br />
Institute for Plastics Processing (IKV) 22<br />
Jinhui ZhaoLong High Tech 28 43<br />
KACO 20<br />
Kingfa 43<br />
Kuender 8<br />
Lessonia 6<br />
Limagrain Céréales Ingrédients 44<br />
Looplife 10<br />
Mercedes 3, 19<br />
Metabolix 10<br />
Metzerplas 5<br />
Michigan State University 10 45<br />
Minima Technology 44<br />
Mitsubishi Chemical 6<br />
narocon 45<br />
NaturePlast 43<br />
NatureWorks 10, 22<br />
Natur-Tec 43<br />
nova-Institut 5, 45<br />
Novamont 14 44, 48<br />
Organic Waste Systems 5<br />
Passive House Institute 25<br />
Pharmafilter 3, 8, 30<br />
Plastic Suppliers 44<br />
plasticker 7<br />
polymediaconsult 45<br />
PolyOne 10 43, 44<br />
Polytechnic Institute (Milan) 14<br />
President Packaging 44<br />
ProTec Polymer Processing 44<br />
PSM 44<br />
Rhein Chemie 44<br />
Roechling Automotive 10, 16<br />
Roquette 44<br />
Saida 44<br />
Schüco 25<br />
Sealed Air Corporation 29<br />
Shandong Fuwin 20, 43<br />
Shenzhen Esun Industrial 43<br />
Showa Denko 43<br />
Sidaplax 10 44<br />
Sulzer Chemtech 10<br />
Supla 8<br />
Synprodo 10, 26<br />
Taghleef Industries 10 44<br />
Technical University Berlin 9<br />
TianAn Biopolymer 44<br />
Tianjin Glory Tang 10<br />
Uhde Inventa-Fischer 10 44<br />
UL International 45<br />
University of Hanover 12<br />
Volkswagen 3, 20<br />
WinGram 43<br />
Wuhan Huali 7<br />
Xinfu Pharm 43<br />
Zandonella 26 1<br />
Roquette 34<br />
Saida 59<br />
Seemore New Materials 59<br />
ShanDong DongCheng 32<br />
Shandong Fuwin New Material Co 27, 58<br />
Shanghai Disoxidation 33<br />
Shenzhen Esun Industrial 58<br />
Showa Denko 58<br />
Sidaplax 59<br />
Siemens 37<br />
Solvay 31, 42<br />
Supla 13, 38<br />
Swiss Fed. Lab. f. Mat. Sc.+ Techn. 44<br />
Synbra 36<br />
Taghleef Industries 59<br />
Tecnaro 10, 12, 34<br />
Tecniq 36<br />
Texchem 30<br />
TianAn Biopolymer 59<br />
TPG 7<br />
Uhde Inventa-Fischer 15, 60<br />
UL International 60<br />
Univ. Modena + Reggio Emilia 26<br />
Univ. Pisa 26, 28<br />
Univ. Stuttgart IKT 60<br />
Wei Mon 59<br />
Weihenstephan Univ. App. Sc. 19<br />
Wifag Polytype 5<br />
WinGram 58<br />
Wuhan Huali 35, 59<br />
WWF 6<br />
Xinfu Pharm 58<br />
Zejiang Huju GreenWorks 31<br />
Editorial Planner 2<strong>01</strong>4<br />
<strong>Issue</strong> Month Publ.-Date<br />
edit/ad/<br />
Deadline<br />
02/2<strong>01</strong>4 Mar/Apr 07.04.14 07.03.14 Thermoforming<br />
(Rigid packaging)<br />
Editorial Focus (1) Editorial Focus (2) Basics Fair Specials<br />
Polyurethanes /<br />
Elastomers<br />
Polyurethanes<br />
Chinaplas &<br />
Interpack Preview<br />
03/2<strong>01</strong>4 May/Jun 02.06.14 02.05.14 Injection moulding Thermoset Injection Moulding Chinaplas &<br />
Interpack Review<br />
04/2<strong>01</strong>4 Jul/Aug 04.08.14 04.07.14 Bottles /<br />
Blow Moulding<br />
05/2<strong>01</strong>4 Sept/Oct 06.10.14 06.09.14 Fiber / Textile /<br />
Nonwoven<br />
06/2<strong>01</strong>4 Nov/Dec <strong>01</strong>.12.14 <strong>01</strong>.11.14 Films / Flexibles /<br />
Bags<br />
Fibre Reinforced<br />
Composites<br />
Toys<br />
Consumer<br />
Electronics<br />
PET<br />
Building Blocks<br />
Sustainability<br />
Subject to changes<br />
www.bioplasticsmagazine.com Follow us on twitter! Be our friend on Facebook!<br />
www.facebook.com/bioplasticsmagazine<br />
46 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9
VESTAMID® Terra<br />
High Performance Naturally<br />
Technical biobased polyamides which achieve<br />
performance by natural means<br />
VESTAMID® Terra DS (= PA1<strong>01</strong>0) 100% renewable<br />
VESTAMID® Terra HS (= PA610) 62% renewable<br />
VESTAMID® Terra DD (= PA1<strong>01</strong>2) 100% renewable<br />
• Outstanding mechanical and physical properties<br />
• Same performance as conventional engineering polyamides<br />
• Significant lower CO 2<br />
emission compared to petroleum-based polymers<br />
• A wide variety of compound solutions are available<br />
www.vestamid-terra.com
A real sign<br />
of sustainable<br />
development.<br />
There is such a thing as genuinely sustainable<br />
development.<br />
Since 1989, Novamont researchers have been working<br />
on an ambitious project that combines the chemical<br />
industry, agriculture and the environment: “Living Chemistry<br />
for Quality of Life”. Its objective has been to create products<br />
with a low environmental impact. The result of Novamont’s<br />
innovative research is the new bioplastic Mater-Bi ® .<br />
Mater-Bi ® is a family of materials, completely biodegradable and compostable<br />
which contain renewable raw materials such as starch and vegetable oil<br />
derivates. Mater-Bi ® performs like traditional plastics but it saves energy,<br />
contributes to reducing the greenhouse effect and at the end of its life cycle,<br />
it closes the loop by changing into fertile humus. Everyone’s dream has<br />
become a reality.<br />
Living Chemistry for Quality of Life.<br />
www.novamont.com<br />
Visit us<br />
at K 2<strong>01</strong>3<br />
in Dusseldorf,<br />
Germany,<br />
at Booth E09,<br />
Hall 06<br />
Within Mater-Bi ® product range the following certifications are available<br />
The “OK Compost” certificate guarantees conformity with the NF EN 13432 standard<br />
(biodegradable and compostable packaging)<br />
6_2<strong>01</strong>3