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ioplastics MAGAZINE Vol. 9 ISSN 1862-5258<br />

Highlights<br />

Foam | 26<br />

Automotive | 15<br />

Pharmafilter | 30<br />

Land use | 34<br />

January/February<br />

Cover-Story<br />

<strong>01</strong> | 2<strong>01</strong>4<br />

BioFoam ®<br />

Ice-cream container | 26<br />

... is read in 91 countries


Bio-Flex ® for mulch films<br />

Certified as compostable, Bio-Flex ® F 1130 is<br />

widely recommended for biodegradable mulch<br />

films. As a ready-to-use blend, Bio-Flex ® F 1130<br />

is easily processed using standard production<br />

equipment. In addition, biodegradable mulch<br />

films made from Bio-Flex ® F 1130 can be laid<br />

down on the field using the same equipment as<br />

conventional polyethylene films. Thus this material<br />

is a natural drop-in replacement for oil based PE.<br />

Mulch films made from Bio-Flex ® offer:<br />

• Compostability according to EN 13432,<br />

ASTM D 6400, NFU 520<strong>01</strong><br />

• Stable during use, good disintegration<br />

in soil after ploughing in<br />

• Cost efficient, no collection is required to dispose<br />

of the film after use, thickness reduction<br />

• Superior water resistance<br />

• High strength and tear resistance<br />

• Good weed suppression<br />

For more information visit<br />

www.fkur.com • www.fkur-biobased.com


Editorial<br />

dear<br />

readers<br />

It is early February, and it is cold in Germany (and not only here)… but<br />

ice cream is a thing that I can enjoy all year round. And thanks to modern<br />

logistics and modern insulating materials, it can be enjoyed far away<br />

from its production site – even in summer. Our cover story is about such<br />

a modern insulating packaging solution. It is part of one of the editorial<br />

focal topics in this issue: foam. The other highlight is Bioplastics in automotive<br />

applications. Here we can see that this is not just about projects,<br />

but about real applications that you can already find on the market – for<br />

example in Ford, Volkswagen or Mercedes vehicles.<br />

In the Basics section we again address the topic of land use. How<br />

much of the arable land on this planet is used for the production of<br />

bioplastics (and other products) today – and in future.<br />

A very interesting experience for me and some colleagues was a visit<br />

to the Reinier de Graaf hospital, in Delft, the Netherlands. We wanted to<br />

see with our own eyes what Pharmafilter is doing there. bioplastics<br />

MAGAZINE already reported about Pharmafilter (bM <strong>01</strong>/2<strong>01</strong>0 and 04/2<strong>01</strong>1)<br />

and the unique concept was awarded the second prize of the 8 th<br />

Bioplastics Award in December.<br />

But who was the actual winner of the 8 th Bioplastics Award? See yourself<br />

on page 9.<br />

Now, after a pause of two years, bioplastics MAGAZINE would like to<br />

invite you to the 3 rd PLA World Congress. We will hold this unique event<br />

again in Munich, Germany, on May 27 th and 28 th , 2<strong>01</strong>4. Please have a look<br />

in the preliminary programme on page 10. We are still able to accept<br />

proposals for presentations. A few slots are still available.<br />

Until then we hope you enjoy reading bioplastics MAGAZINE<br />

Sincerely yours<br />

Michael Thielen<br />

Follow us on twitter!<br />

www.twitter.com/bioplasticsmag<br />

Be our friend on Facebook!<br />

www.facebook.com/bioplasticsmagazine<br />

bioplastics MAGAZINE [<strong>01</strong>/14] Vol.9 3


Content<br />

Editorial ............................. 3<br />

News ............................. 5 - 7<br />

Event Calendar ....................... 42<br />

Suppliers Guide .................. 43 - 45<br />

Glossary ........................ 38 - 40<br />

Companies in this issue ............... 46<br />

<strong>01</strong>|2<strong>01</strong>4<br />

January/February<br />

Events<br />

8 th Bioplastics Award – and the winner is... . 8<br />

8 th European Bioplastics Conference ...... 9<br />

3 rd PLA World Congress ................ 10<br />

Report<br />

Do bioplastics disturb recycling streams? ...............12<br />

Recycling of PLA for packaging applications .............22<br />

Pharmafilter: Reinventing waste as a resource ...........30<br />

Automotive<br />

Bio-materials at Ford ................................15<br />

PLA compounds for the automotive sector. ..............16<br />

PA 410 makes inroads into automotive market ...........18<br />

Bio-PPA to replace metal & rubber. ....................21<br />

Applications<br />

New bioplastic applications in windows .................25<br />

Foam<br />

PLA foam protects ice cream. .........................26<br />

Foam grade PBAT ...................................28<br />

Mushroom packaging. ...............................29<br />

Basics<br />

Facts on land use for old and new biobased plastics ......34<br />

Imprint<br />

Publisher / Editorial<br />

Dr. Michael Thielen (MT)<br />

Samuel Brangenberg (SB)<br />

contributing editor: Karen Laird (KL)<br />

Layout/Production<br />

Mark Speckenbach<br />

Julia Hunold<br />

Head Office<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach, Germany<br />

phone: +49 (0)2161 6884469<br />

fax: +49 (0)2161 6884468<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Media Adviser<br />

Elke Hoffmann, Caroline Motyka<br />

phone: +49(0)2161-6884467<br />

fax: +49(0)2161 6884468<br />

eh@bioplasticsmagazine.com<br />

Print<br />

Kössinger AG<br />

84069 Schierling/Opf., Germany<br />

Print run: 4,000 copies<br />

bioplastics magazine<br />

ISSN 1862-5258<br />

bM is published 6 times a year.<br />

This publication is sent to qualified<br />

subscribers (149 Euro for 6 issues).<br />

bioplastics MAGAZINE is printed on<br />

chlorine-free FSC certified paper.<br />

bioplastics MAGAZINE is read in 91 countries.<br />

Not to be reproduced in any form<br />

without permission from the publisher.<br />

The fact that product names may not be<br />

identified in our editorial as trade marks is<br />

not an indication that such names are not<br />

registered trade marks.<br />

bioplastics MAGAZINE tries to use British<br />

spelling. However, in articles based on<br />

information from the USA, American<br />

spelling may also be used.<br />

Editorial contributions are always welcome.<br />

Please contact the editorial office via<br />

mt@bioplasticsmagazine.com.<br />

Envelopes<br />

A part of this print run is mailed to the readers<br />

wrapped in Green PE envelopes sponsored by<br />

FKuR Kunststoff GmbH and Oerlemans<br />

Plastics B.V<br />

Cover<br />

Cover Ad: Zandonella GmbH<br />

Foto: © Piotr Marcinski (fotolia)<br />

Follow us on twitter:<br />

http://twitter.com/bioplasticsmag<br />

Like us on Facebook:<br />

http://www.facebook.com/pages/bioplastics-MAGAZINE/103745406344904


News<br />

Compostable micro-irrigation systems<br />

Four companies are working together in the European<br />

Project DRIUS; the Spanish company Extruline Systems,<br />

the Israeli Metzerplas, the Spanish research organization<br />

AIMPLAS (Technological Institute of Plastics) and OWS N.V.<br />

(Belgium), as coordinator.<br />

The main objective of this project is to implement in the<br />

market new micro-irrigation systems 100% compostable as<br />

a solution to manage the plastic and the green waste in a<br />

composting plant at the end of the crop period. The new system<br />

will not require the separation or the burning of the pipes and<br />

green waste.<br />

The main applications of the system to be developed in<br />

DRIUS will be crops of small plants such as strawberries and<br />

tomatoes with short periods of cultivations, less than a year.<br />

Currently, the problem after the crop period is the difficulty<br />

in the recycling of the irrigation system because of the mix<br />

of plastic with plants and soil, so the common solution is the<br />

burning of the waste generated. However, the new compostable<br />

system will make possible to treat the waste in a composting<br />

plant.<br />

DRIUS is the continuation of a previous project called<br />

HYDRUS, where new biodegradable micro-irrigation pipes<br />

were developed and satisfactorily manufactured in industrial<br />

extrusion lines.<br />

The main focus of<br />

the present project<br />

is to manufacture<br />

biodegradable drippers<br />

by injection to obtain<br />

the complete system.<br />

The material and the<br />

geometry of drippers<br />

are important to have<br />

the water flow required in the different crops. The material<br />

adjusted for the drippers needs to be processable by injection,<br />

chemically compatible and weldable with the pipes and will<br />

maintain its shape and functionality during the use of the<br />

micro-irrigation systems in the field.<br />

The specific role of AIMPLAS in the project will be to<br />

optimize the suitable material for drippers to make possible<br />

the industrialization of the micro-irrigation system. Extruline<br />

Systems will be responsible for manufacturing the complete<br />

micro-irrigation system (pipes and drips) at industrial level.<br />

Metzerplas is going to design the new moulds and will be<br />

the injector for flat drippers. Lastly, Organic Waste Systems<br />

will carry out the complete study of biodegradation and<br />

compostability in order to obtain the compostability logo.<br />

www.drius.eu<br />

iBIB 2<strong>01</strong>4/15<br />

International Business Directory for Bio-based Materials + CO 2 based<br />

Pictures: nova-Institute,<br />

Sainsbury’s<br />

• Are you involved with Bio-based Materials,<br />

Intermediates or Raw Materials?<br />

• Do you know all of your potential suppliers<br />

and customers?<br />

• Do they know you?<br />

• If not, how about easily boosting<br />

your connectivity worldwide?<br />

Publisher<br />

www.nova-institute.eu<br />

www.bioplasticsmagazine.com<br />

Get visualized and findable! Present your company, products<br />

and services to more than 60,000 potential<br />

clients from all over the world!<br />

iBIB2<strong>01</strong>4/ 15: 250 pages – 100 companies,<br />

associations, R&D – 20 countries<br />

Book your pages now at:<br />

www.bio-based.eu/iBIB<br />

In cooperation with<br />

www.agrobiobase.com<br />

Register today at: www.bio-based.eu/iBIB


News<br />

Bio-based engineering<br />

plastic for automotive<br />

touch panels<br />

Mitsubishi Chemical Corporation (headquartered in Chiyodaku,<br />

Tokyo, Japan) recently announced the development of a<br />

new grade of high-performance, high-transparency bio-based<br />

engineering plastic called DURABIOTM, using plant-derived<br />

isosorbide as its raw material. The new material features<br />

excellent optical properties and high resistance to heat and<br />

humidity.<br />

MCC will move aggressively to promote sales of Durabio for<br />

use in touch panels on automobiles, a sector where demand is<br />

expected to increase significantly.<br />

Touch panels for automobiles are used mainly to control air<br />

conditioning, audio, and car navigation systems. Durabio offers<br />

excellent flexibility in design and can enhance the appearance<br />

of automobile interiors, so MCC anticipates much wider use<br />

and steady growth in demand.<br />

In contrast to easily breakable glass, transparent plastics<br />

such as impact-resistant polycarbonate, are used for the<br />

front plate of automobile touch panels for safety purposes.<br />

The disadvantage of polycarbonates, however, is distortion in<br />

light transmission, which makes it difficult for users to see the<br />

touch panel, so a material that could overcome this problem<br />

has been eagerly awaited.<br />

MCC’s new grade of Durabio features excellent optical<br />

properties, and nearly eliminates distortion in light<br />

transmission, making it easy to see the touch panel surface. MT<br />

www.www.m-kagaku.co.jp<br />

Biodegradable<br />

exfoliator for shower gels<br />

Lessonia (Saint-Thonan – France) is a leading supplier<br />

of natural exfoliators for shower gels and peeling products.<br />

The company recently launched CELLULOSCRUB, a major<br />

innovation to replace the polyethylene beads in cosmetic<br />

products. Celluloscrub is a 100% renewable and biodegradable<br />

exfoliating ingredient made of modified cellulose extracted<br />

from wood pulp. It is said to offer the same high performance<br />

of PE.<br />

Other eco-friendly alternatives for PE beads are for example<br />

exfoliating products made from shells, kernels, minerals,<br />

bamboo, rice, natural waxes, PLA or microcrystalline<br />

cellulose. However, all these ingredients are inferior in all<br />

their characteristics compared to PE (i.e. white colour, stability,<br />

abrasiveness, suspension capacity, etc).<br />

Micro beads made of conventional plastics used as exfoliating<br />

ingredients in personal care products have raised concern<br />

among many environmental groups for its assumed impact<br />

on marine ecosystems. Because sewage and waste water<br />

treatment systems cannot filter out these non-biodegradable<br />

particles they are pumped straight into water courses and end<br />

up in the ocean where they cause irreparable damage to the<br />

oceans. Micro plastics are present in all the seas and oceans<br />

of the world. It is the responsibility of the cosmetic industry to<br />

reduce their impact on the environment.<br />

Leading cosmetics makers, such as Unilever or Lush, as a<br />

consequence, have announced their intention to phase out the<br />

use of these beads and are looking for environmental friendly<br />

alternatives. MT (Source: Lessonia)<br />

Pretreating cellulosic biomass<br />

Aphios Corporation of Woburn, Massachussetts, USA recently<br />

today announced that it was granted a US patent for its cellulosic<br />

biomass pretreatment technology platform (Aosic).<br />

Cellulosic biomass resources are currently greatly<br />

underutilized around the world. If effectively exploited, these<br />

resources can reduce climate change while alleviating several<br />

energy and environmental problems. Dr. Trevor P. Castor,<br />

inventor of the Aosic platform states that “Cellulosic biomass<br />

is tightly wound for obvious mechanical strength reasons. In<br />

order to breakdown cellulose into its individual sugar molecules,<br />

cellulosic biomass must be expanded to enhance the access of<br />

enzymes that cleave the polymeric bonds between individual<br />

sugar molecules.”<br />

Steam explosion is the most commercially used method for<br />

expanding cellulosic fibers that has several disadvantages<br />

including degradation of cellulose and hemicelluloses, the<br />

generation of toxic byproducts and high water and energy<br />

consumption.<br />

In the Aosic process, biomass is contacted with SuperFluids<br />

such as CO 2<br />

with or without small quantities of polar cosolvents<br />

such as ethanol, both sourced from the downstream fermentation<br />

process. Pressure is released and fibers are made more accessible<br />

to enzymes as a result of expansive forces of SuperFluids (about<br />

10 times those of steam explosion) and carbonic acid hydrolysis.<br />

Additional fiber separation is achieved by ejecting biomass<br />

through mechanical impact devices. Carbon dioxide is recovered<br />

and recycled; pressure energy is recovered in a turbine.<br />

Dr. Castor points out that “CO 2<br />

is consumed in the Aosic<br />

process which is a net consumer of carbon. It also utilizes<br />

significantly less water than steam explosion and the dilute acid<br />

pre-hydrolysis pretreatment process. It can be used for wood<br />

cuttings, bagasse, newsprint, corn fodder and spent biomass<br />

from the manufacturing of natural pharmaceuticals and<br />

nutraceuticals.” The primary potential application is pretreating<br />

biomass waste for conversion into ethanol which could then be<br />

used as a precursor for e.g. biobased Polyethylene or PET and<br />

much more. MT<br />

www.aphios.com<br />

6 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


News<br />

Bacteria help convert syngas into Plexiglas<br />

For the first time, Evonik Industries has managed to use<br />

biotech methods to convert syngas to pure 2-hydroxyisobutyric<br />

acid (2-HIBA) under industrial conditions. 2-HIBA is a precursor<br />

used in the manufacture of PLEXIGLAS® (PMMA, Polymethyl<br />

methacrylate, acrylic glass). Waste gas is one example of a<br />

source of syngas.<br />

Syngases are gas mixtures consisting primarily of carbon<br />

monoxide or of carbon dioxide and hydrogen. These gases<br />

can be generated from municipal or agricultural waste, or<br />

from the waste gases produced in industries such as steel<br />

production. Syngas has been used for synthesizing chemicals<br />

for decades. For the ability to convert carbon monoxide, carbon<br />

dioxide, and hydrogen into more valuable molecules, Evonik<br />

looked to bacteria from earth’s earliest history—to a time when<br />

oxygen was not yet present in earth’s atmosphere. Certain<br />

microorganisms today still contain the genetic information for<br />

these processes. Evonik has used their enzymes to create a cell<br />

factory that generates specialty chemicals from syngas.<br />

Evonik scientists are now working at top speed to optimize<br />

these ideas and develop them still further. “We have a long way<br />

to go before we can use bacteria for converting syngas to highquality<br />

specialty chemicals on a large industrial scale,” says<br />

magnetic_148,5x105.ai 175.00 lpi 15.00° 75.00° 0.00° 45.00° 14.03.2009 10:13:31<br />

Prozess CyanProzess MagentaProzess GelbProzess Schwarz<br />

Dr. Thomas Haas, head of Biotechnology at Creavis, Evonik’s<br />

strategic innovation unit. “It will still take a couple of years until<br />

it is ready for the market.”<br />

As Haas explains, “We’re exploring third-generation<br />

biotechnology, because in addition to sugar or residual plant<br />

materials converted to syngas, waste from other sources such<br />

as municipal waste and industrial waste gas can also serve<br />

as raw materials. That makes us less dependent not only on<br />

fossil-based raw materials, but also on renewable resources<br />

that could potentially compete with the food supply.”<br />

2-HIBA can also be produced via chemical synthesis. Both<br />

the chemically-produced and biotech-produced products can<br />

be converted to methyl methacrylate (MMA). MMA is used in<br />

paints, varnishes, and anti-rust coatings, as well as in soft<br />

contact lenses and dental implants. Poly(methyl methacrylate)<br />

(PLEXIGLAS®) is used for creating sheets, profiles, roofs,<br />

soundproof walls, molded components for automotive<br />

engineering applications, and backlight units for illuminating<br />

flat-screen monitors and televisions. MT<br />

www.evonik.com<br />

Magnetic<br />

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from the Industrial Sector<br />

and the Plastics Markets<br />

• Current Market Prices<br />

for Plastics.<br />

• Buyer’s Guide<br />

for Plastics & Additives,<br />

Machinery & Equipment,<br />

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www.plasticker.com<br />

• Job Market<br />

for Specialists and<br />

Executive Staff in the<br />

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Up-to-date • Fast • Professional<br />

bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 7


Events<br />

Wolfgang Bauer (company Helmut<br />

Lingemann) with Michael Thielen<br />

Chung-Jen (Robin) Wu (Supla)<br />

Peter Kelly (Pharmafilter)<br />

And the winner is ...<br />

8 th Global Bioplastics Award for Helmut Lingemann<br />

This year the prestigious “Bioplastics Oskar” was given<br />

to Helmut Lingemann GmbH & Co. KG (Wuppertal,<br />

Germany) for their innovative spacer profiles NIROTEC<br />

EVO for insulating window glazing.<br />

The Annual Global Bioplastics Award, proudly presented<br />

by bioplastics MAGAZINE, was awarded for the 8 th time now.<br />

The award recognises innovation, success and achievements<br />

by manufacturers, processors, brand owners or users of<br />

bioplastic materials. It was given to Wolfgang Bauer, Head<br />

of Quality Management of Helmut Lingemann on December<br />

10 th 2<strong>01</strong>3, during the 8 th European Bioplastics Conference in<br />

Berlin. From a list of almost 20 proposals five judges from<br />

the academic world, the press and industry associations<br />

from America, Europa and Asia have selected five finalists<br />

and now announced the winner.<br />

Helmut Lingemann GmbH & Co.KG have been involved for<br />

more than 30 years as an innovative market leader in The<br />

new spacer system NIROTEC EVO is applied in windows and<br />

facades with a high level of insulation to reduce the energy<br />

losses by using double and triple glazing.<br />

The technological requirements are high strength and<br />

structural reinforcement (e.g. tensile modulus), low thermal<br />

conductivity, no fogging when used in insulating glass, no<br />

incompatibility with other components in the insulation<br />

of windows and facades. In combination with the target of<br />

reducing the use of fossil fuels this can only be achieved by<br />

using a biopolymer. Together with a partner, a tailor-made<br />

blend of different biopolymers based on PLA, biopolyester<br />

and further additives were developed, which met the<br />

requirements 100%.<br />

Until now about 2 million metres of NIROTEC EVO have<br />

been processed into insulating glass units. The biopolymer<br />

ratio is approximately 40 tonnes. If NIROTEC EVO were used<br />

for the total annual production of insulating glass units in<br />

Europe, about 18,000 tonnes of this bioplastic material could<br />

be applied. The material selection of stainless steel foil and<br />

this bioplastic material for the manufacture of such spacers<br />

is unique. The applicability and thermal characteristics<br />

of the material combination for the spacer NIROTEC EVO<br />

represents a milestone in innovation for the insulating glass<br />

industry.<br />

“The judges decided for Helmut Lingemann’s spacer<br />

profiles, because this is an example which shows that potential<br />

applications can be found in areas that do not come to ones<br />

mind immediately. And even though it offers a potential for<br />

high volumes of a bioplastic material,” said Michael Thielen,<br />

publisher of bioplastics MAGAZINE and member of the jury.<br />

“And the application makes use of the biopolymers very<br />

special properties, in this case the mechanical and thermal<br />

properties combined with the very important feature of ‘no<br />

fogging’ which is essential for this application.<br />

In addition the chosen biopolymer blend features very<br />

special adhesion properties and allows high speed bending<br />

procedures of the profiles. Modern thermal insulation<br />

technology meets modern materials; this is how ecological<br />

development should look like in todays technology age”,<br />

Michael Thielen added.<br />

This year for the first time also a second prize was awarded.<br />

Since both proposals had received the same number of<br />

points from the judges, this year the secoind prize went to<br />

two runner-ups: Supla and Kuender received the prize for<br />

the PLA-compound application introduced in the last issue of<br />

bioplastics MAGAZINE: Kuender’s 21.5” all-in-one touch screen<br />

PC.<br />

The other second prize went to Pharmafilter for the<br />

holistic approach of an anaerobic digestion system<br />

for hospitals (and other facilities). For more detailed<br />

information please read the article on pages 30f.<br />

www.bioplastics-award.com<br />

8 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


Events<br />

More than 350 participants from 215 companies caught up<br />

on the latest discussions, developments and progress in<br />

the bioplastics industry during the 8 th European Bioplastics<br />

Conference. Once more, the leading European event for the<br />

bioplastics industry provided excellent opportunities for networking,<br />

knowledge exchange and business contacts. 86 %of the participants<br />

came from Europe, 8 % from North America and South<br />

America, and the majority of the remaining 6 % from Asia.<br />

“Bioplastics made from bio-feedstock, and reintegrated into the<br />

biosphere as a nutrient, or recycled together with conventional<br />

plastic, clearly have a potential for being a truly sustainable<br />

material. And it could reduce fossil fuel consumption,” stated<br />

EU Environment Commissioner Janez Potočnik in his opening<br />

speech to the 8 th European Bioplastics Conference on the 10 and<br />

11 December in Berlin, Germany. In his video message he pointed<br />

to the crucial role, bioplastics can play in Europe’s transition<br />

towards a circular biobased economy.<br />

Potočnik encouraged the bioplastics industry “to continue their<br />

work on making bioplastics a truly sustainable material, neutral<br />

in its impact on food production and biodiversity”. However,<br />

he also pointed out that the industry needs to continuously<br />

and transparently inform the public about their products and<br />

processes in order to clarify its position and prosper in the future.<br />

These recommendations were picked up directly by a group of<br />

experts in a panel discussion on sustainability criteria investigating<br />

the most relevant question: “How to assess the sustainability of<br />

bioplastics in a fair way?” The panel started with a presentation<br />

by Professor Matthias Finkbeiner from the Technical University<br />

Berlin on “Perspectives of Life Cycle Assessment of Bioplastics”.<br />

“LCA is still the best available tool to assess the environmental<br />

performance of bioplastics as fact-based as possible”, Finkbeiner<br />

stated and commented on the Product Environmental Footprint<br />

(PEF) approach introduced by the European Commission as<br />

“LCA overkill introducing pseudo solutions in order to achieve<br />

comparability”.<br />

8 th European<br />

Bioplastics<br />

Conference<br />

connected expert elite<br />

on bioplastics<br />

The panel discussion then focussed on the need to break down<br />

the complexity of assessing the sustainability of bioplastics, the<br />

need to use available and valid methodologies and to provide easy<br />

to use tools to consumers to understand these assessments and<br />

how they impact on the product they are using.<br />

Another highlight of the 8 th European Bioplastics Conference<br />

was the annual market data update by European Bioplastics and<br />

the Institute for Bioplastics and Biocomposites (IfBB - University<br />

of Applied Arts Hannover, Germany). The data once more<br />

emphasised the success of bioplastics industry with production<br />

capacities multiplying from around 1.4 million tonnes in 2<strong>01</strong>2 to<br />

more than 6 million tonnes in 2<strong>01</strong>7. All material types are gaining<br />

ground with biobased, non-biodegradable ‘drop-in’ solutions,<br />

such as biobased PE and biobased PET, leading the field.<br />

As in previous years, bioplastics MAGAZINE got the chance<br />

to honour the winner of the Annual Global Bioplastics Award.<br />

The prize was awarded to company Helmut Lingemann GmbH<br />

& Co.KG for their new spacer system NIROTEC EVO. For more<br />

details see page 8. MT<br />

www.european-bioplastics.org<br />

Mark your<br />

calendar:<br />

The 9th European Bioplastics<br />

Conference will be in<br />

Brussels/Belgium on<br />

02-03 December 2<strong>01</strong>4<br />

bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 9


Events<br />

3 rd PLA World Congress<br />

27 + 28 MAY 2<strong>01</strong>4 MUNICH › GERMANY<br />

bioplastics MAGAZINE presents:<br />

3 rd PLA World Congress<br />

The 3 rd PLA World Congress in Munich/Germany, organised by bioplastics MAGAZINE<br />

is the must-attend conference for everyone 27 + 28 MAY interested 2<strong>01</strong>4 in MUNICH PLA, its › benefits, GERMANY and<br />

challenges. The conference offers high class presentations from top individuals in<br />

the industry and also offers excellent networkung opportunities along with a table<br />

top exhibition. Please find below the preliminary programme. Find more details and<br />

register at the conference website<br />

www.pla-world-congress.com<br />

3 rd PLA World Congress, preliminary programme<br />

Tuesday, May 27, 2<strong>01</strong>4<br />

(subject to changes, visit www.pla-world-congress for updates)<br />

08:00 - 08:30 Registration, Welcome-Coffee<br />

08.30 - 08.45 Michael Thielen, Polymedia Publisher Welcome<br />

08:45 - 09:15 Hasso von Pogrell, European Bioplastics Keynote Speech: t.b.d.<br />

09:15 - 09:40 Udo Mühlbauer, Uhde Inventa-Fischer PLA for fibres and textiles<br />

09:40 - 10:05 Emmanuel Rapendy, Sulzer Chemtech Latest developments in High Performance PLA Production<br />

10:05 - 10:30 Marcel Dartee, Polyone Raising the bar: PLA for durable applications<br />

10:30 - 10:55 Q&A<br />

10:55 - 11:20 Coffeebreak<br />

11:20 - 11:45 Frank Diodato, NatureWorks latest developments in Ingeo Biopolymers for packaging,<br />

fibres and durable applications<br />

11:45 - 12:10 Francois de Bie, Corbion-Purac High Heat PLA, from concept to reality !<br />

12:10 - 12:35 Andrew Gill, Floreon Increasing the Functionality & Performance of PLA<br />

12:35 - 12:50 Q&A<br />

12:50 - 14:00 Lunch<br />

14:00 - 14:35 Patrick Zimmermann, FkUR Different markets, different requirements – Customized PLA-developments<br />

14:35 - 14:50 Daniela Jahn, IfBB Processing and stabilization of different types of PLA<br />

14:50 - 15:15 Kevin Moser, Fraunhofer ICT Profile Extrusion – New opportunities for PLA compounds<br />

15.15 - 15:40 Tang Junsheng, Tianjin Glory Tang Technology PLA commercial application & waste recycle<br />

15:40 - 15:55 Q&A<br />

15:55 - 16:30 Coffeebreak<br />

16:35 - 17:00 Bob Engle, Metabolix PLA modification using new PHA copolymers<br />

Wednesday, May 28, 2<strong>01</strong>4<br />

09:00 - 09:25 Paolo Serafini, Taghleef Industries NATIVIA – The BoPLA film for packaging and labelling applications<br />

09:25 - 09:50 Jarl De Bruyne, Sidaplax Specialty Films The next generation of PLA shrink films<br />

09:50 - 10:15 Francesca Brunori, Roechling Automotive Plantura, ecofriendly automotive biopolymer<br />

10:15 - 10:40 N.N., t.b.c. A brand owners view to PLA: Chances and challenges<br />

10:40 - 10:55 Q&A<br />

10.55 - 11:20 Coffeebreak<br />

11:20 - 11:45 Peter Matthijsen, Synbra BioFoam expanding further<br />

11:45 - 12:10 N.N. t.b.c.<br />

12:10 - 12:35 N.N. t.b.c.<br />

12:35 - 12:50 Q&A<br />

12:50 - 14:00 Lunch<br />

14:00 - 14:35 Ramani Narayan, Michigan State University New developments & Strategies in PLA end-of-life – biodegradability - compostability<br />

and recycling issues<br />

14:35 - 14:50 Gerold Breuer, Erema Boost in recycling efficiency - the new Counter Current technology<br />

14:50 - 15:15 Steve Dejonghe, Looplife Upcycling of PLA waste<br />

15.15 - 15:40 Tanja Siebert, Fraunhofer IVV PLA recycling-techniques. State of the art and research. Chances and<br />

opportunities.<br />

15:40 - 15:55 Q&A<br />

16:00 - 16:30 Panel discussion: t.b.d.<br />

Call for papers is still open.<br />

Please send your abstract to mt@bioplasticsmagazine.com<br />

10 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


3 rd PLA World Congress<br />

27 + 28 MAY 2<strong>01</strong>4 MUNICH › GERMANY<br />

PLA is a versatile bioplastics raw material from<br />

renewable resources. It is being used for films<br />

and rigid packaging, for fibres in woven and<br />

non-woven applications. Automotive industry<br />

and consumer electronics are thoroughly<br />

investigating and even already applying PLA.<br />

New methods of polymerizing, compounding<br />

or blending of PLA have broadened the range<br />

of properties and thus the range of possible<br />

applications.<br />

That‘s why bioplastics MAGAZINE is now<br />

organizing the 3 rd PLA World Congress on:<br />

27-28 May 2<strong>01</strong>4 in Munich / Germany<br />

Experts from all involved fields will share their<br />

knowledge and contribute to a comprehensive<br />

overview of today‘s opportunities and challenges<br />

and discuss the possibilities, limitations and<br />

future prospects of PLA for all kind of<br />

applications. Like the first two congresses<br />

the 3 rd PLA World Congress will also offer<br />

excellent networking opportunities for all<br />

delegates and speakers as well as exhibitors of<br />

the table-top exhibition.<br />

The conference will comprise high class presentations on<br />

Register now !<br />

Early Bird discount ends Feb 28<br />

register online before 28 th February 2<strong>01</strong>4 to<br />

benefit from the Early Bird discount.<br />

The conference fee is EUR 899.00<br />

before the Early Bird deadline you pay just<br />

EUR 799.00<br />

The conferece fee includes documentation,<br />

meals and refreshments. Don't miss the<br />

legendary Bavarian Night in a rustic Munich<br />

beerhouse<br />

› Please find the online registration form as well as<br />

an updated programme at<br />

www.pla-world-congress.com<br />

• Latest developments<br />

• High temperature behaviour<br />

• Blends and Compounds<br />

• Foam<br />

• Processing<br />

• Additives<br />

• Stabilization<br />

• Applications (packaging and durable applications)<br />

• Fibers, fabrics, textiles, nonwovens<br />

• Recycling<br />

organized by<br />

we thank our sponsors:


People Report<br />

Do bioplastics disturb<br />

recycling streams?<br />

Just as a reminder: Bioplastics are A) biobased plastics<br />

made from renewable resources (which can be biodegradable<br />

or not) or B) biodegradable plastics (which can<br />

be made from renewable resources or not), thus some bioplastics<br />

are both (see also definition on page 38).<br />

Summary<br />

Biobased (non-compostable) plastics films, e.g. made<br />

from Braskem’s Green PE, are chemically identical to<br />

conventional plastics and are no more difficult to manage in<br />

plastic recycling streams.<br />

Compostable plastics are designed for organic recycling.<br />

They are clearly marked for this purpose with logos such as<br />

the Seedling logo (cf. p 14).<br />

In the event that compostable plastics do end up in<br />

conventional plastic recycling streams, the prevalent sorting<br />

technologies are able to sort them with little residual waste.<br />

When residual amounts remain, they are similar to, or<br />

easier to handle than current residual wastes in the PE stream<br />

(e.g. PS, PP, PET). They should not then add significantly to<br />

the cost or complexity of recycling processes, or the valuable<br />

recovery of recycled PE.<br />

This remains true up to a share of 10% compostable<br />

plastics in the waste stream. At this level or below, studies<br />

show negligible impact on the technical performance of<br />

recycled PE.<br />

As the market share of compostable plastics increases it<br />

will be economically rewarding to sort them out positively.<br />

This is technically possible today and should create new and<br />

valuable markets for the Waste Management Industry.<br />

The authors believe then, aside from the social and<br />

environmental benefits of bioplastics, the best evidence<br />

clearly shows that these materials are an economic<br />

opportunity, not a threat to the waste management industry.<br />

Bioplastics in mixed waste streams<br />

Modern waste recovery systems cope with intermingled<br />

materials, including a variety of different polymer types.<br />

Automated plants sort out the profitable parts of the waste<br />

stream (for example PE, or PET). The promising polymers<br />

are separated. The rest ends up in another container, usually<br />

marked and resold as ‘mixed plastics’.<br />

To achieve this advanced sorting systems use a variety of<br />

analytical methods including near infrared, ultraviolet, x-ray,<br />

laser, polarized light, fluorescent light, electrostatic, melting<br />

point and other techniques. These methods are effective in<br />

keeping contamination of the main recycling streams with<br />

unwanted material low.<br />

Biodegradable plastics should end up in biowaste bins. If<br />

such bins are not available they can still be clearly identified<br />

from their labels and sorted out for delivery to a biowaste<br />

processer.<br />

However, even in well working systems an intermingling<br />

of waste streams cannot be completely avoided. Nonbiodegradable<br />

plastics can end up in the organic waste<br />

stream (e.g. misthrows) and biodegradable, compostable<br />

plastics might be found in mechanical recycling (e.g.<br />

misidentification ). It is already the case that conventional<br />

plastics find their way, in low volumes, to the wrong stream.<br />

12 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


Report<br />

photo: Fotolia/azthesmudger<br />

It can then be stated that in well run waste management<br />

facilities most residual bioplastic will end up as ‘mixed<br />

plastic’ until such a time as recovery is profitable. It can also<br />

be said, even when incorrectly sorted, that bioplastics today<br />

do not enter the waste stream in sufficient volume to cause<br />

concern more than any other type of plastic.<br />

The case against bioplastics is not<br />

evidence-based<br />

Voices in some parts of the waste management industry<br />

claim that bioplastics are a serious disturbance to the<br />

established recycling streams of for example, PE or PET.<br />

The following research and evidence refutes these<br />

assertions. It suggests the influence on the collection and<br />

processing of profitable materials is negligible.<br />

Biobased Polyethylene (PE, not<br />

biodegradable or compostable)<br />

Biobased PE is obtained by polymerisation of ethylene<br />

monomers. Depending on the polymerisation process<br />

biobased LDPE or biobased HDPE can be produced. The only<br />

difference to fossil-based PE is the source, which is plant<br />

based (bioethanol made from sugar cane, sugar beet, wheat<br />

etc.).<br />

As a result fossil and plant based PE are chemically<br />

identical. They share the exact same physical properties.<br />

Therefore biobased PE can be mechanically recycled with<br />

the fossil based PE in the corresponding recycling streams.<br />

There is no new issue.<br />

PLA/PBAT blends (compostable according<br />

to EN 13432, ASTM D6400, etc)<br />

Studies by the University of Hanover/Germany [1], [2]<br />

examined the influence of different compostable plastics<br />

on low-density polyethylene (LDPE). The tested mixtures<br />

contained between 0.5 % to 10 % foreign material. The LDPE<br />

contaminants were a PLA/PBAT blend (Ecovio® by BASF),<br />

pure PBAT and a starch blend. They found:<br />

• Mixtures of LDPE with PLA/PBAT showed the same<br />

viscosity behaviour, elasticity, and tensile strength as pure<br />

LDPE.<br />

• No optical (i.e. transparency or appearance) changes could<br />

be observed.<br />

• There was a slight decrease in the melt-flow rate at 10%<br />

foreign material.<br />

The biodegradable polyester PBAT was also tested as a<br />

possible contaminant for LDPE. The blending of pure PBAT<br />

with LDPE had no influence on the viscosity behaviour<br />

compared with pure LDPE and was affirmed to have no<br />

influence on the processing properties. The values for melt<br />

flow rate were close to the ones of pure LDPE and were also<br />

described to result in no distinctive disturbances during<br />

processing of the material. Optical changes could also not<br />

be observed.<br />

Below 10% contamination there is no issue<br />

bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 13


Report<br />

compostable<br />

Example of a compostability<br />

logo: the ‘Seedling’ logo of<br />

European Bioplastics, awarded by<br />

independent certification institutes<br />

Starch blends (compostable according<br />

to EN 13432)<br />

A study by BIOTEC [3] has evaluated tensile strength,<br />

elongation at break and specific impact resistance for<br />

mixtures of PE with possible contaminations with a starch/<br />

PBAT (Bioplast® by Biotec) blend as well as PP and PS. It<br />

was shown that the biodegradable starch blend contaminates<br />

PE no more than a contamination with conventional plastics<br />

such as PS or PP.<br />

In most cases the properties of the mixtures of PE with PS<br />

or PP as contaminants showed worse performances than the<br />

contamination of PE with a starch blend.<br />

However, the same study found out that even smallest<br />

amounts of PET (2%) in a PE recycling stream results in<br />

serious problems. Due to the comparatively high melting<br />

temperature of PET (approx. 250°C), it was impossible to run<br />

a PE-based blown-film.<br />

These results suggest that the contaminating effect<br />

of a compostable plastic on PE is actually less than the<br />

contaminating effect of PET on PE.<br />

A study by the University of Hanover [1] also examined<br />

a starch blend used in flexible packaging applications.<br />

It was found that the influence on the viscosity and flow<br />

characteristics was only marginal up to the tested ratio of<br />

10%.<br />

Concerning the melt flow rate the influence on the<br />

processing properties was described as low considered<br />

with the pure LDPE. A change of colour was observed with<br />

increasing amount of starch blend.<br />

Tests carried out at the Plastics Testing Laboratory<br />

Foundation of the Polytechnic Institute of Milan and the<br />

Proplast Laboratories in Tortona/Italy (on behalf of CONAI,<br />

the National Packaging Consortium in Italy) [4], have<br />

confirmed that it is possible to reprocess and recycle bags<br />

of a starch based material (MaterBi® by Novamont) and<br />

traditional plastic shopping bag waste up to a concentration<br />

of 10% of starch-blends as input material.<br />

CONAI found that flexible, compostable packaging can be<br />

recycled with common plastics packaging materials up to a<br />

content of 10% without any problems [5].<br />

CONAI concluded that even if biodegradable bags are not<br />

disposed off properly they do not interfere with the recycling<br />

stream of conventional plastics. MT<br />

This article is an abridged and edited version of a more<br />

comprehensive Meta-Study published by European<br />

Bioplastics. The complete Meta-Study can be downloaded<br />

from www.bioplasticsmagazine.de/2<strong>01</strong>4<strong>01</strong><br />

References:<br />

[1] A. Kitzler, Bioplastics in Waste<br />

Management Streams, Dissertation,<br />

University of Hannover, 2<strong>01</strong>3<br />

[2] H.-J. Endres, A.-A. de la Cruz, Influence<br />

of PLA/PBAT material (ecovio) on<br />

the recycling of conventional LD PE,<br />

University of Hannover, 2<strong>01</strong>3<br />

[3] C. Heß, Influence of BIOPLAST-Material<br />

and conventional non-PE Plastics on the<br />

mechanical Properties of recycled PE-<br />

Film, BIOTEC, Presented at K Fair 2<strong>01</strong>3<br />

[4] Italian National Packaging Consortium<br />

CONAI, Findings of Biodegradable<br />

Packaging Recovery Project. Presented<br />

at the European Bioplastics Conference,<br />

Berlin, 2<strong>01</strong>3.<br />

[5] http://www.ecodallecitta.it/notizie.<br />

php?id=114824, last accessed Jan21,<br />

2<strong>01</strong>4<br />

14 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


Automotive<br />

Bio-<br />

materials<br />

at Ford<br />

Instrument panel P Ford B-Max<br />

(Photo: IAC Group)<br />

As it is well-known, Ford Motor Company’s efforts to<br />

implement recycled and renewable materials in their<br />

vehicles are about a century old. In the early twentieth<br />

century, it was Henry Ford himself who led those efforts.<br />

Today, Ford has a comprehensive team working to fulfil its<br />

vision of ensuring that their products are engineered to enable<br />

their leadership on applying those sustainable materials<br />

without compromising product quality, durability, performance,<br />

or economics.<br />

The portfolio of biomaterials that Ford’s teams have been<br />

investigating and successfully managed to implement in their<br />

vehicles is quite extensive: from soy foams to ground tires<br />

mixed with bio-based foams; from natural fiber reinforced<br />

polypropylene to castor oil based polyamide (cf. bM <strong>01</strong>/2<strong>01</strong>3).<br />

Among these available bio-based materials, the natural<br />

fiber reinforced polypropylene (NF-PP) presents a great<br />

potential to multiply the number of applications in the<br />

short to-mid-term due to its good mechanical properties,<br />

environmental performance and attractive weight saving<br />

potential when replacing mineral and glass filled compounds.<br />

In order to exploit this potential, Ford Motor Company has<br />

been cooperating with material and component developers in<br />

several fields to fill up the gap preventing PP-NF large scale<br />

production of (and usage in) injection molded parts.<br />

Due to today’s short vehicle development time and the<br />

many and multifaceted requirements, the development of<br />

all car components using CAE methods and models is a<br />

crucial topic to series implementation. In order to fulfil this<br />

demand, the Ford Research and Advanced Engineering team<br />

in Aachen, Germany, has been leading a project to generate<br />

data and develop CAE methods that allow the simulation of<br />

natural fiber composites.<br />

The project, which is called Natural Fiber Composite-/<br />

NFC-Simulation, is funded by the German Federal Ministry<br />

of Food, Agriculture and Consumer Protection (BMELV)<br />

through the Agency for Renewable Resources e.V. (FNR). It<br />

includes eleven partners covering the whole supplier chain<br />

and features experts from academic areas. This project<br />

aims at generating a complete and integrated solution for<br />

the simulation of NF composites, from material processing<br />

to crash simulation of automotive parts. In order to achieve<br />

these capabilities, many technical and scientific challenges<br />

had to be addressed and solved in detail and the results<br />

integrated into a holistic solution. The detailed tasks are:<br />

• establishing the micro-mechanical characteristics<br />

of natural fibers before and after compounding with<br />

polymer(s)<br />

• deriving suitable fiber orientation models<br />

• modeling typical side-effects when using NF plastics<br />

(fiber damage, separation etc.)<br />

• manufacturing NF compounds and test parts produced<br />

under uniform processing conditions<br />

• describing the rheological and thermal characteristics of<br />

NF compounds completely<br />

• determining quasi-static and dynamic mechanical<br />

characteristics<br />

• scaling up compound production for selected materials to<br />

(near-)series conditions<br />

• integrating material models with commercial CAE<br />

software, especially for processing and crash simulation<br />

purposes<br />

• simulating a series component (process and crash<br />

simulation)<br />

• producing the series component and conducting extensive<br />

mechanical testing, including crash response of high<br />

dynamic impact tests<br />

This project is running until mid of 2<strong>01</strong>4. Once the work is<br />

completed, Ford Motor Company expects to have contributed<br />

to improving the acceptance of such materials and opening<br />

the door for NF compounds into mass production in the<br />

entire automotive industry.<br />

www.ford.com<br />

bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 15


People Automotive<br />

PLA compounds<br />

for the automotive sector<br />

By:<br />

Francesca Brunori<br />

Advanced Development<br />

Engine Systems<br />

Röchling Automotive<br />

Laives, Italy<br />

www.roechling.com<br />

Francesca.Brunori@roechling-automotive.it<br />

Röchling Automotive (headquartered in Mannheim Germany) is now<br />

prepared to produce a wide range of automotive plastic parts made of<br />

Plantura PLA based biopolymers. According to the specialists in airflow,<br />

acoustic and thermal solutions for passenger cars and trucks, Plantura<br />

is a very interesting ecological and economical alternative to the usage of<br />

other (conventional) thermoplastic materials used for such applications today.<br />

It was in the early 1970s when Röchling Automotive started production of<br />

plastic applications with natural fibre reinforcement. A large quantity and<br />

variety of thermoplastic and thermoset solutions for the interior of passenger<br />

vehicles made the group one of the leaders in this field. From biologically<br />

reinforced parts to Plantura Röchling Automotive has taken various steps of<br />

development.<br />

Up to 95% Bio<br />

Röchling Automotive has built up internal competences in raw materials<br />

development for many years. together with various partners. For Plantura a<br />

very fruitful cooperation with a compounder and Corbion Purac (Gorinchem,<br />

The Netherlands) was established to enhance the technical expertise and<br />

abilities in the fields of bio-chemicals, polymerization and compounding.<br />

From the beginning, the target was to create a new bio-polymer family that<br />

can cope with the high technical requirements and specifications, set for<br />

Röchling Automotive’s product portfolio in the engine compartment, under<br />

the body and in the interior.<br />

The result of the hard work is the material family called Plantura. Due to<br />

the possibility of fine tuning the grades according to the applications, it is<br />

possible to have both hard and soft materials, maintaining good properties<br />

and a high biobased carbon content of up to 95%. As a result, the developed<br />

grades could be capable of competing with most polyesters available on the<br />

market (PC, PET, PBT) but also with polystyrenes (ABS), polyolefines (such as<br />

PP) and polyamides (PA6).<br />

Various grades for different requirements<br />

Four standard grades are already available and can target low to medium<br />

demanding under the hood applications, as well as interiors and underbody<br />

applications. The use in other than automotive markets, such as white goods,<br />

sports goods and many others, is not excluded. Every standard grade can be<br />

fine-tuned to meet customer needs and final application requirements. The<br />

compounds can be processed as well as recycled with established plastic<br />

processing and recycling technologies.<br />

Two of these grades were already certified for their biobased content by<br />

Vinçotte with the highest Class 4 score. The Ok Biobased conformity mark<br />

16 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


Automotive<br />

Fig. 1: Deflector made of<br />

unreinforced Plantura<br />

Fig. 2: Air - Filter-housing<br />

made of Plantura , 30 %<br />

reinforced with wood fibres<br />

can be applied on the products made from these grades.<br />

Plantura, in comparison to standard PLA, showed significant<br />

improvements in thermal stability and chemical resistance.<br />

An outstanding impact resistance for shockproof parts has<br />

been tested down to -30°C with the talcum filled standard<br />

grade. The materials exhibit an excellent hydrolysis resistance<br />

in a 100% humid environment at 70°C. The scratch resistance<br />

behavior of PLA, important for aesthetic trims, is well known<br />

and considered in the Plantura formulations.<br />

Tailor made with exceptional properties<br />

Prototype filter boxes were tested according to OEM’s<br />

specifications, withstanding thermal cycles up to 140°C<br />

with glass fiber reinforcement. The same parts performed<br />

also a vehicle testing and run 100.000 km without showing<br />

problems. By comparison, unreinforced standard PLA is not<br />

at all suitable for technical applications due to its low long<br />

term heat resistance of just 60°C.<br />

One of the four standard grades has been specially<br />

developed for automotive interior applications. The testing<br />

performed on this grade, according to OEM‘s specifications,<br />

showed very good results, especially in term of scratch and<br />

UV resistance. Plantura has a very good colourability, which<br />

can be further optimized by the addition of bio fillers. It is<br />

quite easy to obtain a glossy surface and a very natural<br />

aesthetic look.<br />

Supporting sustainability<br />

The environmental impact of Plantura is indeed much lower.<br />

Considerable improvements on automotive applications<br />

made in against PP, PC, ABS, or PA are possible. More in<br />

detail, the CO2 equivalent emission of Plantura for each kg of<br />

produced material is around 7 times lower with respect to PP<br />

and approximately 12 times lower than PA.<br />

A middle class passenger car contains approximately 147<br />

kg of petrochemical plastics which could be easily substituted<br />

by Plantura. This would mean a CO 2<br />

equivalent emission<br />

reduction of around 515 Kg CO 2<br />

equivalent per car.<br />

The continuous development of the material has led to<br />

higher, and increasingly interesting cost efficiency. With its<br />

significant contribution to an improved CO 2<br />

balance, Plantura<br />

could become an important concept in the automotive world.<br />

Fig. 3: Air-Filter-housing<br />

made of Plantura , 30 %<br />

reinforced with wood fibres<br />

Fig. 4: Interior trim parts made of Plantura<br />

grade (left natural color, unfilled, right ‘natural<br />

look’ 30%reinforced with wood fibres<br />

bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 17


People Automotive<br />

PA 410 makes inroads<br />

into automotive market<br />

Polyamides based on renewable feedstocks are well suited for highperformance<br />

applications in the automotive industry, where OEMs are<br />

particularly keen to improve the sustainability of their operations and<br />

of their vehicles. DSM’s polyamide 410, trade named EcoPaXX ® , is 70% biobased<br />

derived from a renewable feedstock, castor oil.<br />

EcoPaXX has a very interesting property set: on the one hand it has<br />

mechanical properties such as stiffness and toughness that are similar to<br />

those of conventional aliphatic polyamides such as PA66, PA6; on the other<br />

hand, it has properties typical of long-chain polyamides such as PA610 and<br />

PA612: low moisture uptake, chemical- and hydrolysis resistance, and high<br />

thermal stability, for example.<br />

The main raw material of the polymer is sebacic acid, which is derived from<br />

castor plants, which can grow on semi-arid land in countries such as India,<br />

China and Brazil. EcoPaXX is carbon neutral from cradle-to-gate (see fig. 1),<br />

meaning that the carbon dioxide generated in producing the polymer is<br />

compensated by the carbon dioxide absorbed during plant growth.<br />

Polyamide 410 has a glass transition temperature, T g<br />

, of 70°C, a very high<br />

crystalline melting point, T m<br />

of 250°C, the highest of any bio-plastic, and a<br />

high crystallization rate. This results in a high tensile modulus in the dry state,<br />

close to that of PA66. Moreover, due to its low moisture uptake, the decrease<br />

of its tensile modulus after conditioning is limited. Its deflection temperature<br />

under load (DTUL or HDT-B ) is also impressive: 175°C under 0.45 MPa load.<br />

The material’s high melting point and rapid crystallization rate ensure short<br />

injection molding cycles. It also offers a broad processing window.<br />

Ideal for parts in engine compartments and exhaust systems<br />

Numerous automotive applications—notably engine compartment<br />

components—are increasingly subject to tougher specifications, be they<br />

in temperature resistance, dimensional stability or chemical resistance.<br />

EcoPaXX is a serious contender in such applications.<br />

The good hydrolysis resistance of EcoPaXX is important for several<br />

applications in engine compartment cooling systems: these include radiator<br />

& charge air cooler end caps, thermostat housings, water pump housings<br />

and impellers, water valves, coolant recovery tanks, and cooling water pipes.<br />

EcoPaXX provides a better/safer solution in cooling applications than current<br />

PA66 based applications, especially when temperatures increase above 130oC.<br />

Even at elevated temperatures, EcoPaXX resists everything from automotive<br />

liquids such as coolants, fuels, oil and grease to dilute acids, bases and<br />

detergents, to aqueous salt solutions such as calcium-and-zinc chloride.<br />

18 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


Automotive<br />

EcoPaXX shows superior retention of mechanical properties<br />

upon ageing in CE10 and B30 biodiesel. For example, while<br />

stiffness and strength of 30% glass reinforced PA12 after 500<br />

hours at 100°C in CE10 fuel is already at the level of an unfilled<br />

resin, performance of an equivalent reinforced EcoPaXX grade<br />

remains high for up to 1500 h.<br />

With its higher chemical resistance, EcoPaXX provides a<br />

better solution in AdBlue applications in SCR (selective catalytic<br />

reduction) systems than PA66 (see fig. 2), especially when<br />

temperatures increase to 80°C. AdBlue is a solution of urea in<br />

water used in SCR catalytic converters on diesel engines to break<br />

down hazardous nitrogen oxides (NOx) formed during combustion<br />

into nitrogen and water.<br />

DSM currently has five commercial injection molding grades<br />

of EcoPaXX: a general purpose, unfilled injection molding grade<br />

(Q150-D); two glass-reinforced types (30% and 50% respectively,<br />

Q-HG6 and Q-HG10) for use in applications where high stiffness<br />

and toughness are needed; a glass/mineral reinforced injection<br />

molding grade, especially suited for the injection molding of<br />

large parts which should have low warpage and excellent surface<br />

quality (Q-HGM24); and a halogen-free flame-retardant glass<br />

reinforced (30%) compound, with a UL 94 V-0 rating at 0.75 mm<br />

(Q-KGS6).Impact modified grades and grades with carbon fibre<br />

reinforcement are available for sampling.<br />

Proven applications<br />

Several interesting applications involving EcoPaXX have recently<br />

been commercialized. Mercedes-Benz, for example, chose<br />

EcoPaXX Q-HGM24, a glass/mineral reinforced injection molding<br />

grade, for the engine beauty cover of the latest version of its<br />

A-Class small family car (cf. bM 02/2<strong>01</strong>3). The cover meets strict<br />

performance requirements and it provides good aesthetics. And<br />

even more, Mercedes Benz achieved its targets in reducing fuel<br />

consumption compared with the previous A-Class generation, as<br />

well as in reducing carbon footprint.<br />

Mercedes-Benz says production of an engine cover in EcoPaXX<br />

results in only around 40% of the quantity of carbon dioxide<br />

emissions that would be necessary in order to produce the same<br />

component from a conventional polyamide.<br />

Global Warming Potential**<br />

120%<br />

100%<br />

Retention of Ts [%]<br />

80%<br />

60%<br />

40%<br />

20%<br />

0 PA66 PC ABS PA610 PA1<strong>01</strong>0 PP Eco-<br />

PaXX<br />

Base polymers*<br />

Assessment method: IPCC 2007 GWP 100a<br />

*Sources: Ecolnvent database; external publications; DSM primary data.<br />

**All GWP values are normalized to the highest value.<br />

Fig. 1: Cradle to gate carbon footprint of several polymers<br />

110<br />

100<br />

90<br />

80<br />

70<br />

60 0 10 20 30<br />

Time [Days]<br />

40<br />

PA410-GF30 PA410-GF40-I PA66-GF30<br />

Fig. 2: Ts after AdBlue-ageing<br />

bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 19


Automotive<br />

DSM has also partnered with automotive component<br />

specialist KACO in the development of a lightweight multifunctional<br />

crank shaft cover (cf. bioplastics MAGZINE issue<br />

05/2<strong>01</strong>3) in EcoPaXX for the latest generation of diesel<br />

engines developed by the Volkswagen Group, resulting in<br />

a significant cost and weight reduction.<br />

Fig. 3: Concept in-mold-formed<br />

housing cover<br />

Future developments<br />

DSM is developing new high-performance reinforced<br />

injection moulding compounds of EcoPaXX. It is also<br />

actively involved in programs to develop high-speed<br />

processing technologies to produce automotive structural<br />

and semi-structural components in thermoplastics<br />

composites containing mats and tapes of continuous fibres<br />

pre-impregnated with thermoplastics. In an integrated<br />

production cell, parts are made by first creating a preform<br />

from the mat and/or tape, and then overmoulding it with<br />

an advanced polyamide such as EcoPaXX. At K2<strong>01</strong>3, DSM<br />

showcased a concept in-mold-formed housing cover<br />

(fig. 3), developed with Weberit. This cover is made in a<br />

combination of a continuous glass reinforced EcoPaXXbased<br />

composite and an injection molded EcoPaXX<br />

compound.<br />

Composites containing carbon fibers based on EcoPaXX<br />

(as well as Akulon polyamide 6 and Stanyl polyamide 46) will<br />

facilitate significant weight reduction in automobile body<br />

and chassis parts, while glass fiber reinforced composites<br />

will be targeted at reducing the weight of semi-structural<br />

components. In all cases, the light weighting will result in<br />

increased vehicle fuel efficiency and reduced emissions of<br />

carbon dioxide.<br />

DSM is also a partner in the four-year EU-sponsored<br />

ENLIGHT project, which also includes several car<br />

companies and which aims to accelerate the technological<br />

development of materials capable of cutting weight and<br />

overall carbon footprint in medium-to-high volume<br />

next-generation electric vehicles. DSM further shows<br />

its strong commitment to the development of advanced<br />

thermoplastic composites by being one of the founding<br />

partners in AZL, the Aachen Center for Integrative<br />

Lightweight Production.<br />

www.ecopaxx.com<br />

20 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


Automotive<br />

Bio-PPA<br />

to replace metal & rubber<br />

Rilsan ® HT, the first flexible thermoplastic from the polyphthalamide<br />

(PPA) family available on the market, combines high temperature<br />

resistance with flexibility. Rilsan HT, made by Arkema (Colombes,<br />

France) is therefore filling a gap in the high heat resistant and flexible polymers<br />

as the inherent brittleness of classical PPA and other high-temperature<br />

thermoplastics has restricted their use to mainly rigid components<br />

and injection moulded parts.<br />

These characteristics make it aptly suited to replace metal and rubber<br />

in under-the-hood tubing applications. Weighing only a sixth of steel and<br />

a third of aluminium, it therefore helps reduce the weight of vehicles, their<br />

fuel consumption and their overall emission output (CO 2<br />

, CO, NO x<br />

, HC) –<br />

all at reduced cost compared to classical metal tubing or rubber hoses<br />

assembly.<br />

The impressive performance of Rilsan HT is further enhanced by<br />

environmental benefits. Rilsan HT is a durable high-temperature<br />

thermoplastic derived largely from renewable non-food-crop vegetable<br />

feedstock, thus offering a significant reduction in CO 2<br />

emissions compared<br />

to conventional petroleum-based high-temperature plastics and a reduced<br />

dependence on oil resources. Rilsan HT resin features a renewable carbon<br />

content of up to 70%, naturally fitting into the ecodesign concepts of many<br />

OEMs.<br />

Fig. 1 and 2: Rilsan HT flexible tubing in the engine<br />

compartment (top: exhaust gas recirculation system,<br />

bottom: blow by Line)<br />

Typical examples of use where Rilsan HT has established itself<br />

successfully to replace metal and rubber in flexible engine compartment<br />

tubing include the oil transport, blow by and control of exhaust gas<br />

recirculation.<br />

Thanks to its excellent hydrolysis resistance, Rilsan HT has been<br />

also recently successfully used in the most challenging application for<br />

polyamides, the aqueous media management, in the engine cooling and<br />

selective catalytic reduction (SCR) circuit where the material needs to<br />

withstand the hydrolysis attack at temperatures of the engine compartment.<br />

Cooling lines, until today, have been limited to the use of metal and<br />

rubber due to the lack of flexible thermoplastic materials with sufficient<br />

hydrolysis resistance at high temperatures. Now, Rilsan HT has been<br />

chosen for engine cooling lines, providing significant weight reduction<br />

versus metal-rubber assemblies.<br />

With the new Euro 6 emission regulation which will come into force next<br />

year, SCR becomes a crucial part of diesel engines and thereby Adblue ®<br />

tubing for SCR. The combination of resistance to aqueous Adblue solution<br />

with thermal aging tubing when close to the engine, is a challenge that<br />

Rilsan HT has proven to take.<br />

Finally, when temperature demands go extreme, Arkema has developed<br />

a new Rilsan HT grade specially designed for excellent hydrolysis stability<br />

at even higher temperatures.<br />

Now, cost-effective manufacturing of light-weight flexible tubing for even<br />

most challenging under-the-hood tubing applications is possible.<br />

Fig. 3: Rilsan HT flexible tubing for engine<br />

cooling lines<br />

www.rilsanht.com<br />

bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 21


People Report<br />

Recycling of PLA for<br />

By:<br />

Christian Hopmann<br />

Sebastian Schippers<br />

Institute of Plastics Processing<br />

(IKV) at RWTH Aachen University<br />

Aachen, Germany<br />

Fig. 3: Fractions of multiple recycled<br />

material during continuous production<br />

with constant recycling rates<br />

21%<br />

25%<br />

70%<br />

11%<br />

2% 1%<br />

6%<br />

Recycling of<br />

30% waste<br />

2% 2%<br />

5%<br />

Recycling of<br />

45% waste<br />

Virgin PLA<br />

1<br />

2<br />

3<br />

4<br />

5+<br />

55%<br />

In cooperation with two Belgian Institutes (Celabor of Herve, and Flanders’<br />

PlasticVision Kortrijk) and the Fraunhofer Institute for Structural Durability<br />

and System Reliability (LBF) in Darmstadt, Germany, the Institute of Plastic<br />

Processing (IKV), Aachen, analyses the recycling of PLA in flat film extrusion.<br />

The focus is on the evaluation of relevant packaging properties such as permeability<br />

and mechanical properties as well as the chemical structure (molecular<br />

weight) during various recycling routes. Preparation of internal PLA waste by<br />

means of crystallisation and drying is also included in the scope of the research.<br />

In this article the recycling with varying percentages of recycled PET,<br />

and the multiple recycling of films, is reviewed. Mechanical as well as chemical<br />

properties are evaluated.<br />

The extrusion trials are carried out on a 60 mm single screw extruder (L=38 D)<br />

and a calender stack. The extrusion line is equipped with a melt pump and<br />

a 400 mm flat film die. Additionally, a bypass-rheometer is included. Films<br />

produced from virgin PLA (Ingeo 2003D, Nature Works) are used for recycling.<br />

A shredder processes these films to flakes which are subsequently used<br />

as r-PLA (recycled PLA). The twin screw extruder ZSK26MC (Coperion) is<br />

combined with a water quenching system and a strand pelletizer unit. It is<br />

used to convert the flakes back to granules.<br />

The typical recycling route of converters includes shredding, crystallising,<br />

drying, re-granulation and reprocessing of the recycled waste to a new product.<br />

To prevent a high level of down-cycling typically the waste is not reprocessed<br />

at 100 %. Instead it is reprocessed with a defined recycled content. Depending<br />

on the packaging application, the recycling content may be up to 50 % of<br />

internal production waste. The molecular weight of different processing steps<br />

measured by GPC (Gel permeation chromatography) is shown in Fig. 1.<br />

The molecular weights shown are in a narrow range. To be able to detect any<br />

effect of a narrow variation of the molecular weight it is necessary to measure<br />

a test series with different films in the same GPC series, which is done here.<br />

In general, the molecular weight loss is low and due to deviations in the<br />

GPC measurements small effects are hardly significant. Virgin PLA loses<br />

molecular weight when processed to film. The molecular weight loss is in<br />

the range of 9 %. The molecular loss occurs due to the thermal and thermooxidative<br />

degradation which is inevitable during extrusion, especially for<br />

polycondensates like PLA.<br />

The film made of virgin PLA is milled into flakes and processed to granules by<br />

means of a twin screw extruder. Granules are advantageous since the material<br />

transport in pipes and dosing units, for example, is easier. Additionally, the<br />

process behaviour in the extruder during plastification is better. The melting<br />

process is more homogeneous than the melting of flakes since the geometry<br />

of the granules is similar to the geometry of the virgin PLA granules. During<br />

granulation in the twin screw extruder a marginal molecular weight loss is<br />

measured, which is a result of the additional processing step.<br />

During the subsequent reprocessing to new films with varying percentages<br />

of recycled PLA the molecular weight loss is low again. The difference between<br />

recycling quotas up to 45 % and film made from virgin PLA is very small. It<br />

accounts for less than 3 % during the recycling of 45 % r-PLA. The effect upon<br />

22 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


Report<br />

packaging applications<br />

the film properties is negligible. Only the processing of 100 %<br />

r-PLA leads to a higher molecular weight loss in comparison<br />

with the molecular weight of the film made by virgin PLA. A<br />

loss of approx. 5 % occurs.<br />

The same effect can be seen for the mechanical properties.<br />

Fig. 2 shows the Young’s modulus in a transverse direction<br />

(TD) for film with varying recycling content.<br />

The drop in the Young´s modulus accounts for nearly 8 %.<br />

The chain scission, which is due to the down-cycling of the<br />

PLA, leads to a lower tensile strength and a lower ductility.<br />

As a result the Young´s modulus decreases.<br />

During continuous recycling a decreasing amount<br />

of material runs multiple times through the extrusion<br />

equipment. To evaluate this influence on the PLA it is<br />

recycled to 100 % for a multiple of times. This leads to a<br />

higher degradation which enables the easier detection of the<br />

effects. The fraction of multiple recycled material decreases<br />

exponentially with increasing recycling steps. Fig 3. shows,<br />

as examples, the fractions for a continuous recycling rate of<br />

30 % and 45 %.<br />

Even for a recycling rate of 45 % the fraction of material<br />

which is recycled 3 times and more is often very low.<br />

Fig. 4 summarises the molecular weight and the viscosity<br />

(measured by the bypass rheometer) of multiple processed<br />

films. After each extrusion step the film is shredded to<br />

flakes and dried to below 250 ppm as recommended by the<br />

PLA supplier. Following this it is reprocessed to 100 %. The<br />

reprocessing in this way is repeated 6 times.<br />

A continuous decrease in both values can be seen. The<br />

increase in step 5 is the result of the blending of two different<br />

batches. R-PLA which is processed in two different trial<br />

series is mixed here. Both batches have been processed four<br />

times prior to mixing. The blending is necessary since a high<br />

amount of r-PLA is needed for the trials, which cannot be<br />

prepared in one test series. Due to start-up waste the amount<br />

of r-PLA is reduced at every step and the volume of the drying<br />

equipment is limited. The increase is visible in the molecular<br />

weight as well as in the viscosity, and other properties.<br />

The overall loss of the molecular weight over 7 extrusion<br />

steps accounts for 17 % percent. A loss of 17 % is relatively<br />

little, especially when taking into account that less than<br />

2 % of 5 times recycled PLA will be in a product which is<br />

continuously produced with 45 % r-PLA.<br />

The Young’s Modulus in machine (MD) as well as in<br />

transverse (TD) direction and the results of the dart drop<br />

tests of PLA processed 1, 3 and 7 times are shown in Fig. 5.<br />

Weight average molecular<br />

weight [kg/mol]<br />

Weight average molecular<br />

weight [kg/mol]<br />

220<br />

210<br />

200<br />

190<br />

180 Virgin<br />

PLA<br />

Film<br />

made<br />

of virgin<br />

PLA<br />

Granules 10%<br />

r-PLA<br />

240 2200<br />

230 2000<br />

220 1800<br />

210 1600<br />

200 1400<br />

190 1200<br />

180 Virgin<br />

PLA<br />

1 2 3 4 5 6 7 1000<br />

Number of extrusion steps [-]<br />

Molecular weight | Average viscosity<br />

30%<br />

r-PLA<br />

Fig. 1: Molecular weight at different process<br />

stages during recycling<br />

Young‘s modulus TD<br />

[MPa]<br />

1850<br />

1800<br />

1750<br />

1700<br />

1650<br />

1600<br />

1550<br />

1500 Film made of<br />

virgin PLA<br />

45%<br />

r-PLA<br />

100%<br />

r-PLA<br />

10% r-PLA 45% r-PLA 100% r-PLA<br />

Fig. 2: Young’s modulus in transverse direction<br />

of film with varying recycling quotas<br />

Fig. 4: Molecular weight and viscosity of multipleprocessed<br />

PLA films<br />

Viscosity [Pas]<br />

bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 23


Report<br />

Young’s Modulus [MPa]<br />

2000 500<br />

1900 450<br />

1800 400<br />

1700 350<br />

1600 300<br />

1500 250<br />

1400 200<br />

1300 150<br />

1200 100<br />

1100 50<br />

1000<br />

1 3 7 0<br />

Number of extrusion steps [-]<br />

Young’s Modulus (MD) | Young’s Modulus (TD) | Dart drop<br />

Fig. 5: Young’s Modulus and dart drop<br />

of multiple processed PLA<br />

Number of extrusion steps<br />

1 3 7<br />

Degree of crystallinity [%] 1.2 2 2.7<br />

Table 1: Degree of crystallinity for multiple extruded<br />

PLA films measured by DSC<br />

References:<br />

[1] THRONE, J.; BEINE, J.: Thermoformen.<br />

Munich, Vienna: Carl Hanser Verlag,<br />

1999<br />

www.ikv-aachen.de<br />

Impact failure weight [g]<br />

The Young’s Modulus of the film increases with the<br />

number of extrusion steps. A growth of 5 % in both directions<br />

(TD and MD) is achieved between processing steps 1 and<br />

7. The impact failure weight as a result of the dart drop<br />

test is increased, too. This is due to a higher degree of<br />

crystallinity of the film. Unlike the results of the recycling<br />

with varying recycling quotas the molecular weight loss of<br />

the 3 times (10 %) and 7 times (17 %) recycled PLA is higher.<br />

A low average chain length (molecular weight) enables the<br />

polymer to crystallise more during the solidifying on the<br />

calender stack. This is well covered in published literature<br />

[1]. The degree of crystallinity is shown in table 1.<br />

The higher crystallinity increases the mechanical<br />

properties (Young’s Modulus). Since the increase in<br />

crystallinity is little, the overall effect on the mechanical<br />

properties is marginal. The crystallinity between steps 3<br />

and 7 does not change much. The mechanical properties<br />

remain almost constant. Chain scission through<br />

degradation compensates for the effect of crystallisation.<br />

With regard to further decreasing of the molecular weight<br />

the dart drop resistance decreases slightly.<br />

Conclusion<br />

The investigations into the recycling of PLA show that<br />

the industrial recycling of PLA is possible with a low loss<br />

of film properties. Because of the hygroscopicity and the<br />

hydrolysis of PLA the drying of r-PLA is necessary. The<br />

reprocessing with a recycling quota of up to 45 % leads to<br />

a marginal degradation of the PLA. The molecular weight<br />

drops around 3 % and the mechanical properties decrease<br />

by 8 %.<br />

Multiple recycling shows the long term behaviour of<br />

material which stays in the process over multiple recycling<br />

steps during continuous recycling. A low decrease of the<br />

molecular weight below 20 % of a 7 times extruded film can<br />

be found. This degradation can be ignored. Especially, when<br />

taking into account that during the continuous recycling<br />

only a small amount stays for 5 or more cycles in the<br />

process. The effect of the lower molecular weight affects<br />

the degree of crystallinity. This has a bigger effect on the<br />

properties than the achieved molecular weight loss. The<br />

mechanical properties of multiple recycled films are slightly<br />

increased with nearly constant elongation properties. The<br />

thermoforming behaviour is slightly decreased due to a<br />

higher crystallinity haze and clarity increase.<br />

The research project 44 EN of the “Forschungsvereinigung<br />

Kunststoffverarbeitung” has been sponsored as part of the<br />

“Collective Research Networking“ (Cornet) by the German<br />

ministry for technology and commerce (BMWi) following an<br />

act of the German parliament through the AiF. We would<br />

like to extend our thanks to all organizations mentioned.<br />

24 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


Applications<br />

New bioplastic<br />

applications in windows<br />

More and more architects and clients are demanding new,<br />

ecologically viable products which have maximum potential<br />

for reducing CO 2<br />

and conserving natural resources. With its<br />

green generation of products, German window and façade expert<br />

Schüco from Bielefeld is addressing the issue of finding potential<br />

alternative materials for petroleum based plastics.<br />

The FW 50 + .SI Green façade system and the AWS 90.SI + Green<br />

aluminium window system integrate components such as insulating<br />

bars, gaskets and pressure plates with a proportion of renewable<br />

materials.<br />

This development is possible in part due to the use of partly<br />

biobased polyamide (made using sebacic acid generated from<br />

castor oil), that forms the basis for the pressure plates of the FW<br />

50 + .SI Green façade system and for the green insulating bars which<br />

are integrated into the Schüco AWS 90.SI + Green window system.<br />

The castor oil is even used for the foam of these insulating bars.<br />

Schüco is also making a marketing contribution for the transfer of<br />

biotechnology for gaskets in both of these profile systems, by using<br />

EPDM (synthetic rubber) made from sugar cane based bio-ethanol.<br />

The same standards apply to all these materials: an initial and then<br />

annual inspection by an independent certification process (DIN<br />

CERTCO, 14 C analysis) guarantees that the proportion of renewable<br />

raw materials strived for is also achieved. With the Schüco AWS<br />

90.SI + Green and Schüco FW 50 + .SI Green system enhancements,<br />

the company is combining the approved use of renewable raw<br />

materials with thermal insulation to passive house level and above.<br />

The FW 50 + .SI Green façade system meets the strict passive house<br />

certification criteria set by the Passive House Institute in Darmstadt<br />

and has been certified as passive house standard since BAU 2<strong>01</strong>3<br />

(building and construction trade fair in Munich/Germany).<br />

Combination of sustainability and energy efficiency<br />

Thermal insulation is the primary decisive factor in the energy<br />

revolution. Many local authorities have already pledged to<br />

implement thermal insulation to passive house level as standard<br />

when constructing new public buildings. The Schüco Green window<br />

and façade systems fulfil precisely these requirements. Both<br />

constructions combine the advantages of durable aluminium with<br />

thermal insulation to passive house standard, thereby conserving<br />

natural resources and reducing CO 2<br />

emissions. Equipped with<br />

plastics containing a significant proportion of renewable raw<br />

materials, these windows and façades now make a double<br />

contribution to the reduction of greenhouse gases, since they have a<br />

lower potential for global warming. This means that using renewable<br />

raw materials releases fewer greenhouse gases into the atmosphere<br />

during manufacturing and it also conserves natural resources. MT<br />

Schüco Window AWS 90.SI+ Green<br />

(photo: Schüco International KG)<br />

1: Insulating bars: Bio-Polyamide<br />

Bio-content ( 14 C): > 25 %<br />

2: Insulating zone: Biobased PUR-foam<br />

Bio-content ( 14 C): > 25 %<br />

3: Glass rebate gasket: Bio-EPDM<br />

Bio-content ( 14 C): > 20 %<br />

Schüco Façade FW 50+.SI Green<br />

(photo: Schüco International KG)<br />

2<br />

1<br />

1: Contact pressure profile: BIO-Polyamide<br />

Bio-content ( 14 C): > 25 %<br />

2: Glass rebate gaskets: BIO-EPDM<br />

Bio-content ( 14 C): > 20 %<br />

System achieves level of „Passivhausniveau“<br />

U cw<br />

≤ 0,80 W/m²K<br />

3<br />

www.schueco.de/aws-90si-plus-green-en<br />

2<br />

2<br />

1<br />

1<br />

2<br />

bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 25


People Cover Story<br />

PLA foam<br />

protects<br />

ice cream<br />

By:<br />

Michael Thielen<br />

Sandro Zandonella, and his ancestors of the Zandonella<br />

family, have produced and sold gourmet ice cream for<br />

four generations - not in Italy, as the name would suggest,<br />

but in Landau, Germany. The ice cream specialties are<br />

not only sold in their local ice cream parlours but are also<br />

available in single-serve and multi packs, as well as in household<br />

size containers. Zandonella have recently introduced<br />

their new brand Sandro’s Bio with an exceptional natural<br />

taste, as Sandro Zandonella, Managing Director and inventor<br />

of Sandro’s Bio explains. The flavour line comprises classics<br />

such as chocolate or vanilla, cocktail types like Piña Colada<br />

as well as the very trendy vegan sorbet specialties. All these<br />

products are made with biological 1 or organic 1 ingredients<br />

grown locally in the vicinity of their company. “Zandonella is<br />

proud that the gourmet quality of their ice cream has been<br />

frequently confirmed in blind taste tests,” says Werner Oelschlaeger,<br />

Managing Partner of Zandonella. “We are always<br />

happy to invite new testers to compare our products with other<br />

ice creams, which is always a fun day…,” he adds.<br />

PLA BioFoam ®<br />

And what is it, which makes Sandro’s Bio unique? “This<br />

product is the first ice cream, worldwide, to be packed in<br />

PLA BioFoam made by Synprodo,” explains Mr. Oelschlager.<br />

This PLA particle foam is comparable to EPS (expanded<br />

polystyrene particle foam, sometimes also referred to as<br />

Styropor ® ). BioFoam is made from non-GMO crops, notably<br />

sugar cane. It is also compostable in industrial composting<br />

facilities, where a respective infrastructure is available. The<br />

ecological advantages of this packaging material are in line<br />

with the advantages concerning the deep-freeze-logistics<br />

and customer convenience, i.e. the ice cream can retain its<br />

deep-freeze temperature about one hour even in a warm<br />

environment, such as inside a sun-heated car.<br />

The first packaging product for Sandro’s Bio ice-cream<br />

made from BioFoam is a half litre household size container.<br />

In order to ensure maximum product safety, and not only with<br />

respect to the temperature, the whole packaging product is<br />

rather complex. The insulating outer box and lid are made<br />

from BioFoam. In addition a thermoformed inlay made of PLA<br />

and a PLA lidding film are used. Then the pack is wrapped<br />

in shrink film and an outer sleeve made of paper. It is the<br />

declared aim of Zandonella to replace even the shrink film<br />

and the sleeve by bioplastic materials by the end of this year.<br />

Werner Oelschlaeger, himself quite interested in<br />

environmental issues since his university times, explains<br />

to bioplastics MAGAZINE Zandonella’s motivation for using<br />

BioFoam: “One reason was some critical comments from our<br />

customers concerning the use of polystyrene. In addition to<br />

the fossil resources there is pentane being used as a blowing<br />

agent,” he says. “BioFoam gives us the unique position of<br />

using a packaging product that, just like expanded polystyrene<br />

before it, allows the ice cream to be kept safe and cold, but<br />

which is made from renewable resources and with CO 2<br />

as<br />

a blowing agent.” For Oelschlaeger it is important that the<br />

agricultural products which are used for their packaging do<br />

not compete with food.<br />

26 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


Foam<br />

Sandro Zandonella with a farmer in his local area<br />

During the development of the PLA packaging system, which<br />

was performed in a rather tight time-frame, some challenges<br />

had to be faced and solved. For example an existing mould,<br />

previously being used for the EPS version, could not be used,<br />

due to different wall thickness requirements. Together with<br />

Synprodo (Wijchen, The Netherlands) and even assisted by<br />

the expertise of the bio-packaging specialist Bio4Pack from<br />

Rheine/Germany, all problems were solved in time, so that a<br />

launch of the product at the BioFach trade fair in February in<br />

Nuremburg/Germany became an achievable goal.<br />

End of Life<br />

As an end-of-life scenario of the new Sandro’s Bio PLA foam<br />

packaging the company pursues different approaches. Of<br />

course all bioplastic parts of the packaging are compostable<br />

and even the whole system (foamed box, liner and lid-film)<br />

will be certified compostable according to EN 13432. Thus<br />

in areas where the respective infrastructure of bio-waste<br />

collection and commercial composting is available, a cradleto-cradle<br />

closed loop is the perfect solution. In countries such<br />

as Germany, where currently only bio-waste bags are allowed<br />

in the bio-waste collection bins, a source-separation into the<br />

yellow bins/bags-system is the most reasonable approach.<br />

Here the biobased plastics will end up in a waste-to-energy<br />

recycling process and renewable energy can be exploited.<br />

Since the plants have sequestered the same amount of<br />

CO 2<br />

from the atmosphere as is being exhausted during<br />

incineration, this also is a closed loop. And certainly, as soon<br />

as sufficient PLA ends up in the waste stream, it should be<br />

separated and recycled into PLA or lactic acid again. The only<br />

thing that is being considered a No-go is littering. And this<br />

should certainly be communicated to the end consumers.<br />

Come and see the BioFoam-ice<br />

cream packaging and taste the<br />

delicious ice cream at BioFach<br />

(12-14. Feb., Nuremberg/Germany)<br />

Hall 9 – booth 326<br />

1: Both words by the way are not exactly “precise“ terms to describe, what is really meant<br />

here. Unfortunately in many countries these expressions are being used to describe<br />

products that are produced on a “as much as possible” natural way, without using<br />

pesticides, fertilizers or even genetically modified organisms. MT<br />

www.sandros-bio.de<br />

www.synprodo.com<br />

www.bio4pack.com<br />

bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 27


Foam<br />

Foam grade<br />

PBAT<br />

Jinhui ZhaoLong High Tech Co.Ltd is located at Shanxi<br />

Province, China with an annual PBAT (polybutylene<br />

adipate-co-terephthalate) production capacity of<br />

20,000 tonnes. Jinhui is using a one step ring-opening polymerization<br />

technology and started PBAT production in<br />

July 2<strong>01</strong>3. A compostability test (according to EN 13432)<br />

was completed at Beijing Technology and Business University.<br />

The products will obtain DIN-Certco certification<br />

(EN 13432) in March 2<strong>01</strong>4. FDA certification for food contact<br />

is also available.<br />

Foam products are widely used in packing industry<br />

because of high impact absorption rate, low density, high<br />

specific strength, high heat and sound insulation abilities.<br />

Conventional plastic foam products not only may have<br />

isocyanate residue problem (in the case of polyurethane),<br />

they are quite difficult to re-collect or re-use due to their<br />

bulky volume. In order to avoid white pollution, there is a<br />

strong market demand for biodegradable foam products.<br />

Drive Innovation<br />

Become a Member<br />

In many cases biodegradable plastic foam products<br />

show a low melt flow rate resulting at low expansion<br />

ratio as well as a low yield ratio (broken foam bubbles).<br />

Jinhui is offering a foam grade PBAT resin which offers an<br />

expansion ratio of around factor 10 using carbon dioxide<br />

as a foaming agent. The foam products have a density<br />

between 0.13 g/cm 3 to 0.2 g/cm 3 , foam bubble diameters<br />

below 20 μm and a resilience of more than 80%.<br />

Jinhui’s marketing strategy is focused on excellent<br />

consulting and after sales service. Their foam grade PBAT<br />

customers will benefit from on-site technical support at<br />

no extra cost as well as unique customer tailor-made<br />

solution. As an example, by adding a nucleating agent<br />

the degree of crystallization can be increased to obtain<br />

a higher impact resistance surface in order to meet the<br />

customer’s exact requirements. MT<br />

www.ecoworld.jinhuigroup.com<br />

28 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


Foam<br />

Mushroom<br />

packaging<br />

About a year and a half ago Sealed Air Corporation (Elmwood<br />

Park, New Jersey, USA) and Ecovative Design LLC (Green Island,<br />

New York) completed an agreement about the production,<br />

sales and distribution of Ecovative’s EcoCradle ® Mushroom ®<br />

Packaging, a unique technology for environmentally responsible<br />

packaging materials made from agricultural byproducts and mycelium,<br />

or mushroom roots.<br />

As part of the agreement, Sealed Air would be the exclusive<br />

licensee of Ecovative’s mycelium based material technology in<br />

North America and Europe for protective packaging applications.<br />

Sealed Air and Ecovative developed together plans for sales and<br />

marketing as well as the augmentation of production capabilities.<br />

Just recently, end of 2<strong>01</strong>3, Sealed air started production in a<br />

converted facility in Cedar Rapids, Iowa.<br />

The packaging material — albeit not exactly a bioplastic — can<br />

replace conventional plastic foams, such as those made from<br />

polystyrene, polyethylene or polypropylene. It is made by inoculating<br />

agricultural waste, that can be anything from corn husks, rice hulls<br />

to chopped up plant stocks with fungal mycelia. The mycelia grow<br />

extensively to form an intricate, interwoven network as they feed on<br />

the substrate. The composite is then heated to kill the mycelia and<br />

fuse the mass into a rigid, plastic-like substance. The properties<br />

of the material can be tailored by varying the organic substrate<br />

and type of fungus to grow in it. Target markets include protective<br />

packaging, automotive components, construction materials, shoes<br />

and floral foam [1].<br />

There are several problems with polystyrene foams, Ecovative<br />

CEO Eben Bayer said. Polystyrene is made from oil, a limited<br />

resource with a fluctuating price, in a process that uses a lot of<br />

energy. And plastic packaging, which typically ends up getting<br />

thrown away, takes a very long time to degrade – and finds its<br />

way to oceans and beaches around the world. By contrast, he<br />

said, Mushroom Packaging, is renewable and biodegradable, and<br />

made from crop waste bought from farmers, providing them with<br />

additional income [2].<br />

Examples for protective packaging are a wine-botttle box or<br />

protective corners for (e.g.) household appliances. Other applications<br />

for Ecovative’s Mushroom materials include insulating panels in<br />

building and construction, surf boards and much more. MT<br />

www.sealedair.com<br />

www.ecovativedesign.com<br />

www.mushroompackaging.com<br />

References:<br />

[1] Plastics News online, Nov. 12, 2<strong>01</strong>3<br />

[2] The Guardian online, Oct. 22, 2<strong>01</strong>3<br />

Info:<br />

watch video clip at bit.ly/LjWfm2<br />

bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 29


People Report<br />

2<strong>01</strong>3<br />

2<br />

bioplastics MAGAZINE<br />

Reinventing waste<br />

as a resource<br />

Bacteria and biopolymers key players in<br />

innovative hospital waste management system<br />

By:<br />

Karen Laird<br />

www.pharmafilter.nl<br />

Due to the specific nature of health care activities, waste management<br />

in hospital environments poses problems not encountered<br />

elsewhere. In most hospitals, therefore, elaborate procedures<br />

have been put in place to ensure that the health-care waste they produce<br />

is appropriately managed. However, even with the strictest of segregation,<br />

transport and disposal regulations in force, cross-contamination<br />

and errors occur. Pharmafilter is a young Dutch company offering a new<br />

and innovative approach that completely eliminates these problems. At<br />

the heart of its solution is an anaerobic digester; over time, biopolymers<br />

will become a major source of digestible input material.<br />

Health-care waste includes a large component of general waste and<br />

a smaller proportion of hazardous waste. According to Eduardo van den<br />

Berg, director of Pharmafilter, one of the main problems is where to draw<br />

the line between the two. “In hospitals, waste is managed by segregating<br />

it, which creates a great many separate waste streams. We found that<br />

fully one-third of all movement in hospitals is related to waste. A lot of<br />

effort, for example, goes into carefully separating all the infectious waste<br />

from the general waste.” He added: “But then, if a patient - the source of<br />

the infection – uses a bedpan or goes to the toilet, that is infectious waste<br />

that goes directly into the sewer.”<br />

Down the drain<br />

Van den Berg is a creative thinker with a proven track record and<br />

experience in health-care settings. An earlier idea – the development of<br />

a hygienic, environmentally friendly, disposable vase for hospital flowers –<br />

had been successfully introduced in hospitals throughout the Netherlands<br />

and Germany. He was convinced that there had to be a safer, cleaner<br />

and especially, a more efficient approach to the transport, handling and<br />

treatment of the health-care waste produced in hospitals. So when he was<br />

approached by Reinier de Graaf hospital, in Delft, the Netherlands, who<br />

asked him to help devise a modern, safe and efficient waste management<br />

system for the new facilities that were being planned, he came up with an<br />

solution that was both impressively simple and remarkably effective.<br />

“I thought, why not simply treat all the waste produced as biohazardous<br />

waste? Then, instead of separating everything for segregated disposal, all<br />

the waste streams could be combined into a single stream, disposed of<br />

in a single contaminated area and processed all together,” he explained.<br />

How? “Simply by using the hospital’s existing sewage system.”<br />

30 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


Report<br />

Using the hospital’s internal drainage system would greatly<br />

decrease the amount of waste being transported through the<br />

hospital, thus considerably reducing the number of contact<br />

moments and contamination risks. In a purely practical<br />

sense, it would have the added advantage that far less use<br />

would be made of the elevators, reducing the waiting time for<br />

them, as well.<br />

First, however, a safe and workable system for<br />

implementation needed to be devised. “Obviously, because<br />

the municipality it not equipped to handle contaminated waste<br />

through the sewage system, some kind of self-contained<br />

treatment facility would be needed on site to process this<br />

waste. This was the start of Pharmafilter,” said Van den Berg.<br />

In 2008, the first Pharmafilter pilot plant was built, in order<br />

to test the feasibility of the idea and the configuration of the<br />

installation developed by Van den Berg. This pilot facility<br />

operated on a 10% scale at Reinier de Graaf Gasthuis in<br />

Delft and proved such a success that a full-scale system was<br />

installed in the existing H-building, which went on stream in<br />

the autumn of 2<strong>01</strong>0.<br />

And today, construction of the new hospital facilities in Delft<br />

is in full swing, together with the integrated new Pharmafilter<br />

installation that will be ready for operation from day one.<br />

The new waste disposal system has also attracted attention<br />

from other hospitals as well, both in the Netherlands<br />

and abroad. Pharmafilter currently has 10 more projects<br />

for similar systems with hospitals in Belgium, Denmark,<br />

Germany, Holland, Ireland, Sweden and the United Kingdom.<br />

Powered by bacteria<br />

Standing in one of the containers housing the Pharmafilter<br />

installation, Van den Berg called attention to the fact that<br />

there was no odor – nothing at all – even though underneath<br />

the floor all the waste from the hospital was going through a<br />

giant sieve to separate the solids from the water.<br />

“On all the wards, where the bedpan washers used to be,<br />

and in the operating rooms and other strategic locations,<br />

we’ve installed shredders, called Tontos, into which all waste<br />

is deposited, including food, sharps, disposables, human<br />

organic waste, plastic, paper, whatever. The self-cleaning<br />

Tonto unit grinds up the waste, adds water and delivers it<br />

via the hospital’s internal sewer system to where we are<br />

standing, together with the waste water from showers,<br />

washbasins and toilets,” explains Van den Berg. “We purify<br />

the air of all aerosols and possible pathogens, so there’s no<br />

smell or danger of contamination at all.”<br />

After sieving, the solids – metals, plastics, feces, food -<br />

are ground into pulp, suctioned into the hydrolysis unit and<br />

then fed into the anaerobic digester. Here, the organic waste,<br />

including all bioplastics, is digested by the bacteria in this<br />

unit, a process that takes around thirty days and occurs at<br />

a temperature of 60°C. The biogas produced in the process<br />

meets 65-70% of the power needs of the installation.<br />

The non-digestible remainder is largely decontaminated<br />

during the process as well, but is nonetheless treated at<br />

100°C prior to being compressed and further processed into<br />

briquettes that for instance can serve as fuel in the cement<br />

industry. Van den Berg hopes that, as the volumes increase,<br />

it will be possible to separate the metals and conventional<br />

non-digestable plastics out for recycling in order to achieve a<br />

true end-of-life cycle closed loop.<br />

No more pharmaceutical pollution<br />

The wastewater, which next to all else contains high<br />

amounts of pharmaceutical substances, from cardiovascular<br />

medicines to X-ray contrast fluids, undergoes rigorous<br />

purification treatment, as well. The water from the sewagesieving<br />

step and from the digester is first fed through<br />

a membrane bioreactor equipped with ultrafiltration<br />

membranes, where bacteria are responsible for nitrogen<br />

and phosphate removal and most of the contaminants are<br />

eliminated. Next, ozone is introduced into the water to get rid<br />

of any color, micro particles of cosmetics and pharmaceuticals<br />

remaining. The ozone causes chain scission into basic<br />

elements and metabolites. “After the ozone treatment, an<br />

bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 31


Report<br />

active carbon step is carried out to filter out any toxic residue. We buffer the water, subject<br />

it to UV light and then reuse it,” says Van den Berg. “It’s a closed loop. It’s led to the hospital<br />

using 70% less drinking water.”<br />

He added: “Actually, this water is cleaner than drinking water – the amount of microcontaminants<br />

it contains is under the detection limit. Our process eliminates residual<br />

pharmaceuticals far better than the water purification plants do. However, it can’t be used<br />

as drinking water due to legal restrictions. It may be used as process water, though, and<br />

in the new building, the infrastructure is being put in place, so that there it will be used for<br />

everything except drinking purposes.”<br />

In fact, at the current Delft facility, the purified water is used to fill a fish aquarium, in<br />

which numerous goldfish are happily swimming around. Once a month, a fish is caught and<br />

thoroughly examined for any sign of problems..<br />

Biopolymers hold the future<br />

A key element in the Pharmafilter concept is the replacement of the use of conventional<br />

hospital supplies by products made of biopolymers, as, next to providing a “green” alternative<br />

to conventional materials, these will serve to increase the amount of digestible organic matter,<br />

allowing the installation to produce more biogas and become a truly closed-loop system.<br />

According to Van den Berg, the hospitals are ready to embrace the use of biopolymers.<br />

Already, a list of over 200 products eligible for replacement by bioplastic alternatives has been<br />

compiled, opening up exciting possibilities for a host of new bioplastic applications.<br />

It will take time, however. Pharmafilter is investigating the possibilities of developing the<br />

new products itself, as manufacturers are generally reluctant to invest in unproven products<br />

with uncertain volumes. Van den Berg: “It’s a chicken and the egg situation. So we are currently<br />

experimenting with different blends of PHA and PLA to develop these products ourselves.<br />

What’s important is their digestibility. PLA is not anaerobically degradable, although in a<br />

blend, in a certain proportion, we have found that with the Pharmafilter patented system<br />

the bacteria will handle these blends.” and how this is achieved is Pharmafilters proprietary<br />

knowledge.”<br />

Already, PHA and starch-based bioplastics have been shown to be easily digestible in the<br />

digester. “Traditional metal bedpans have already been replaced by the bioplastic Olla, made<br />

of PHA,” noted Van den Berg. “It was designed for patient comfort, comes with an airtight lid<br />

and fits easily into the Tonto.” Prior to the introduction of the disposable bedpans, it was not<br />

uncommon for the (used) bedpans to pile up in the bedpan washer station because they could<br />

not be cleaned fast enough. “Imagine the smell,” he added.<br />

Other products include catheters, urinals and urine collection bags, with many others,<br />

such as serviceware, containers and trash bags, due to be introduced in the near future.<br />

But: “What we’re really looking forward to is the development of bioplastic incontinence<br />

material and diapers,” said Van den Berg. “It’s already a disposable. The volumes are huge.<br />

It’s a perfect product for us.”<br />

32 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


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People Report<br />

Facts on land use for<br />

old and new biobased plastics<br />

Methodology of land use calculation – using the example of PLA<br />

0.37 ha 1.04 ha<br />

0.18 ha 0.16 ha<br />

Fermentation<br />

CO 2<br />

H 2<br />

O<br />

H<br />

Hydrolysis<br />

2<br />

O<br />

H 2<br />

O<br />

Enzymes<br />

Dextrins<br />

Sugar beet Sugar cane<br />

Corn<br />

Wheat<br />

9.19 t 11.31 t<br />

2.39 t 3.54 t<br />

ferment. Sugar<br />

Starch<br />

1.47 t<br />

1.67 t<br />

Lactic Acid*<br />

1.25 t<br />

Dehydration<br />

Lactide<br />

1.00 t<br />

H 2<br />

O<br />

Glucose<br />

1.47 t<br />

Fermentation<br />

Lactic Acid*<br />

1.25 t<br />

CO 2<br />

H 2<br />

O<br />

Step 3<br />

Step 2<br />

Step 1<br />

By:<br />

Hans-Josef Endres and co-workers<br />

IfBB - Institute for bioplastics and Biocomposites<br />

Hanover, Germany<br />

Current discussions on land use requirements for bioplastics,<br />

or of the amount of renewable resources needed,<br />

are often centered on rather irrational estimates and<br />

groundless reservations. To counteract the widespread scepticism<br />

towards bioplastics and return to a more fact-based debate,<br />

the following contribution is made to show the relevant<br />

data on current and future land use for bioplastics and to support<br />

these data by drawing various comparisons.<br />

Catalyst<br />

Polymerization<br />

PLA<br />

1.00 t<br />

* Conversion Rates<br />

Sugar – Lactic Acid 85%<br />

Catalyst<br />

Dehydration<br />

Lactide<br />

1.00 t<br />

Polymerization<br />

PLA<br />

1.00 t<br />

H 2<br />

O<br />

Step 3: To calculate land use in this<br />

bottom-up approach, the producer-specific<br />

productioncapacities of a type of bioplastics<br />

were multiplied by the output data of the<br />

corresponding process routes<br />

Step 2: Feedstock requirements were<br />

calculated for the use of different crops.<br />

For final land use calculation only the<br />

most common used crop was taken into<br />

consideration. Yield data from FAO statistics<br />

served as a basis for calculation (global, nonweighted,<br />

average over the past 10 years).<br />

Step 1: Process routes show the<br />

manufacturing steps involved from the raw<br />

material to the finished product, specifying<br />

the individual process steps, intermediate<br />

products, and input-output streams.<br />

The mass flows were first calculated using<br />

a molar method based on the chemical<br />

process, with the introduction of known<br />

rates and conversion factors. The routes so<br />

established were confirmed with polymer<br />

manufacturers and the industry generally as<br />

far as possible. In so far as no loss rates due<br />

to the chemical processes or the process<br />

stages were included, the calculations were<br />

made basically assuming no losses.<br />

The mass flows differ depending on which<br />

of the following two aspects is considered:<br />

feedstock and/or land use requirements<br />

for the production of one metric ton of<br />

bioplastics, bioplastics output from one<br />

metric ton of feedstock, or per hectare or<br />

square kilometre.<br />

Bioplastics production capacities 2<strong>01</strong>2 (by material type)<br />

Bioplastics production capacities 2<strong>01</strong>7 (by material type)<br />

56.6%**<br />

Biobased/non-biodegradable<br />

43.4%<br />

Biodegradable<br />

83.8%*<br />

Biobased/non-biodegradable<br />

16.2%<br />

Biodegradable<br />

1.1 %<br />

Other (biobased/<br />

non-biodegradable)<br />

2.4 %<br />

Bio-PA<br />

14.3 %<br />

Bio-PE<br />

38.8 %<br />

Bio-PET 30<br />

* Only hydrated cellulose foils<br />

** Comprises drop-in solutions and<br />

technical performance polymers<br />

in %<br />

total: 1.4 million<br />

tonnes<br />

13.4 %<br />

PLA<br />

13.7 %<br />

Biodegradable<br />

polyester<br />

11.4 %<br />

Biodegradable<br />

starch blends<br />

2.4 %<br />

PHA<br />

2.0 %<br />

Regenerated<br />

cellulose*<br />

2.0 %<br />

Other (biodegradable)<br />

1.6%<br />

Other (biobased/<br />

non-biodegradable)<br />

1.4%<br />

Bio-PA<br />

4.4%<br />

Bio-PE<br />

76.4%<br />

Bio-PET 30<br />

in %<br />

total: 6.2 million<br />

tonnes<br />

* Comprises drop-in solutions and technical<br />

performance polymers<br />

Source European Bioplastics / Institute for<br />

Bioplastics and Biocomposites (December 2<strong>01</strong>3)<br />

13.4 %<br />

PLA<br />

6.9%<br />

PLA<br />

3.6%<br />

Biodegradable polyester<br />

2.7%<br />

Biodegradable starch blends<br />

2.4%<br />

PHA<br />

0.6%<br />

Other<br />

(biodegradable)<br />

34 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


Report<br />

The importance of transparency for<br />

generating clear-cut estimates of land use<br />

Two sources of information served as a basis for an accurate<br />

estimate of land use. First, the production process of various<br />

biobased plastics including their feedstock conversion rates<br />

for individual process steps, and second, official data on<br />

agricultural yields as feedstock. See the example of PLA, as<br />

shown in Fig.1.<br />

When considering these process routes and the respective<br />

market volumes of the various bioplastics, the feedstock and<br />

land use requirements for these bioplastics can be derived in<br />

a clear and understandable way.<br />

Defining the scope of biopolymer<br />

materials under consideration<br />

Another essential aspect in the discussion is to clarify, or<br />

concretize, which biobased materials are considered and in<br />

particular also which ones are excluded.<br />

• For example, do the data for land use or feedstock refer<br />

to the resources required specifically for new types of<br />

bioplastics, i.e., those developed within the last 20 - 30<br />

years (New Economy)? What about traditional biopolymers<br />

such as cellulose derivatives (cellulose acetate, cellophane,<br />

etc.), rubber, linoleum, etc. (Old Economy) – are they also<br />

considered?<br />

• Are ready-to-use polymers the only ones covered?<br />

What about biobased polymer raw materials (bio-acids,<br />

alcohols, etc.) and functional oligomers or other polymers<br />

(plasticizers, etc.)?<br />

• Are biobased synthetic fibres, or even natural fibres, also<br />

included?<br />

• Are composites with biobased reinforcements (starch-filled<br />

polymers, natural-fibre reinforced composites, etc.) also<br />

covered?<br />

If no clear distinction is made regarding whether certain<br />

materials are included or excluded, this will result in a wide<br />

spread of values and lack of clarity in the assessment of land<br />

use and resource consumption for bioplastics. Eventually,<br />

there will be confusion on all sides.<br />

Resource consumption for biobased plastics:<br />

New Economy (2<strong>01</strong>2 and 2<strong>01</strong>7)<br />

When, based on these pre-considerations, New Economy<br />

bioplastics, with their annual production capacity of currently<br />

1.4 million tonnes are taken into focus, and it turns out that<br />

their land use is as low as 0.4 million tonnes per hectare. This<br />

is equivalent to only 0.008 % of the global agricultural area (5<br />

billion hectare) or 0,03 % of the global arable land (1.4 billion<br />

hectare)<br />

Even though global forecasts predict a rapidly growing<br />

market for these novel bioplastics in the next few years, the<br />

need for agricultural areas will be kept at a very low level.<br />

While the market for new bioplastics has been growing<br />

by around 15 % annually during the last three years and<br />

a sustained growth is anticipated for the future it can be<br />

assumed that land use for New Economy bioplastics by 2<strong>01</strong>7<br />

(6.2 million tonnes), for example, will be as low as 0.02 % of<br />

the global agricultural area or less than 0.4 % of the arable<br />

land.<br />

Regardless of the significant growth rates, it should be<br />

mentioned that the market share of these New Economy<br />

bioplastics is still hovering at less than 1 % of the global<br />

plastics market and is likely not to exceed 2 - 3 % in the near<br />

future.<br />

Global production capacities of bioplastics<br />

6,185<br />

6,000<br />

1,000<br />

Biobased<br />

(partly or completely)<br />

Durable<br />

(and biobased)<br />

Chemically novel<br />

z.B. PLA, starch,<br />

PTT, PBS, PBAT<br />

Thermoplastics<br />

„New Economy“<br />

Bio-Polymers<br />

Petroleum based<br />

(and biodegradable)<br />

Biodegradable<br />

(compostable)<br />

Biobased<br />

„Drop-Ins“, e.g.<br />

Bio-PE, Bio-PET, Bio-PA<br />

Thermoset resins<br />

Elastomers, TPE<br />

„Old Economy“<br />

e.g. caoutchouc,<br />

Viscose, Linoleum,<br />

CA, Cellophane<br />

1,000 metric t<br />

5,000<br />

4,000<br />

3,000<br />

5,185<br />

2,000<br />

1,395<br />

1,161<br />

1,<strong>01</strong>6<br />

1,000<br />

342<br />

674<br />

486<br />

675<br />

604<br />

791<br />

0<br />

2<strong>01</strong>0 2<strong>01</strong>1 2<strong>01</strong>2 2<strong>01</strong>7<br />

Biodegradable | Biobased/non-biodegradable| Total capacity<br />

Forecast<br />

bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 35


Report<br />

Old and New Economy (2<strong>01</strong>2 and 2<strong>01</strong>7)<br />

In addition to these innovative and novel bioplastics, when<br />

considering the most important Old Economy bioplastics with<br />

their global production capacity of 17 million tonnes annually,<br />

it turns out that the share of New Economy bioplastics is 15<br />

times lower, i.e. 7.5 % of the market volume of all biobased<br />

plastics (including the Old Economy bioplastics), with rising<br />

tendency.<br />

By and large, Old and New Economy bioplastics (about<br />

18.5 million tonnes) have a combined share of presently<br />

6 - 7 % of the global plastics market. Taking into account<br />

the anticipated market growth, especially of New Economy<br />

bioplastics, over a 5-year period the market share of Old and<br />

New Economy bioplastics is expected to reach a maximum of<br />

10 % of the global market for plastics within the next 5 years.<br />

The corresponding land use of Old and New Economy<br />

bioplastics is currently at approximately 15.5 million hectares,<br />

which is equivalent to only 0.3 % of the global agricultural<br />

area or approximately 1% of the arable land.<br />

Comparing these figures reveals that New Economy<br />

bioplastics, which tend to be the sole focus of interest in land<br />

use discussions, use up only 3 % of the area required for all<br />

biobased plastics combined.<br />

Total substitution of all petro-based<br />

plastics by biobased plastics<br />

Even assuming, as a theory, that innovative biobased<br />

plastics would be introduced globally to fully substitute for<br />

the entire range of conventional petroleum-based plastics,<br />

this scenario would require just 1.5 - 2 % of the globally<br />

available agricultural area (approx. 5 billion hectares) or<br />

about 5 - 7 % of the currently available arable land (approx.<br />

1.4 billion hectares).<br />

Contrary to common belief, this indicates that, even in<br />

view of significant growth forecasts, bioplastics are not in<br />

competition with food production!<br />

Alternative utilisation of renewable resources:<br />

Energy-related utilisation of renewable<br />

resources<br />

In the past few years energy crops, which are grown as<br />

biomass for generating heat, fuels and electricity, were<br />

covering an area of 2 million hectares in Germany. This is<br />

equivalent to almost 17 % of the total arable land in Germany.<br />

On the other hand, the cultivation of sugar, oil or starchbearing<br />

crops for material usage takes up a negligible area of<br />

0.26 million hectares (2.1 % of the arable land) in Germany. On<br />

the other hand the German land use for biogas crops is nearly<br />

1 million hectare. So it can be inferred that less than 50 %<br />

of the arable land used to grow corn for biogas production in<br />

Germany would currently be sufficient for the entire global<br />

production of bioplastics. To modify the example, German<br />

arable land for biogas production could be used to produce<br />

feedstock for 1.6 million tonnes of bio-PET. This means that<br />

almost 10 % of the global demand for PET (or more than 50 %<br />

of the European, and 350 % of the German demand), could be<br />

satisfied with the German biogas land use.<br />

German bio-ethanol for global biobased PE production:<br />

613,000 tonnes of bio-ethanol, the total amount generated<br />

from growing fodder cereals and industrial beets on around<br />

250,000 hectares of German arable land, would suffice to<br />

produce 295,000 tonnes of bio-PE. This means that even<br />

with the German land use for bioethanol the current global<br />

demand for the biobased PE, of approximately 200,000<br />

tonnes, would be over-satisfied.<br />

To make things even more compelling, it is a fact that<br />

biobased plastics, even after multiple material usage,<br />

can still serve as an energy carrier. This means that<br />

additional crop lands, which are currently used for direct<br />

energy production, could be set aside for the production<br />

of bioplastics. Prior material usage of biomass, as in the<br />

case of bioplastics, still permits subsequent trouble-free<br />

energy recovery, whereas direct incineration of biomass (and<br />

also crude oil based products!) precludes an immediate<br />

Old and New Economy Biopolymers<br />

1<br />

PLA, PHA, PTT, PBAT, Starch blends,<br />

Drop-Ins (Bio-PE, Bio-PET, Bio-PA) and other<br />

2<br />

material use excl. paperindustry<br />

3<br />

calculations include linseedoil only<br />

56.000<br />

Linoleum 3<br />

400.000<br />

New Economy<br />

Biopolymers 1 2.900.000<br />

140.000<br />

Linoleum 3<br />

1.395.000<br />

New Economy<br />

Biopolymers 1<br />

Global<br />

land use (ha)<br />

Cellulose 2<br />

Global<br />

production<br />

capacity (t)<br />

5.800.000<br />

Cellulose 2<br />

12.000.000<br />

Natural Rubber<br />

10.978.000<br />

Natural Rubber<br />

36 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


Report<br />

subsequent material usage. In this case, furthermore arable<br />

land for plant cultivation is needed and consequently another<br />

photosynthesis process, in order to gain new resources once<br />

again as feedstock for material usage.<br />

Starch consumption rate for the paper<br />

industry<br />

The starch consumption rate for the paper and board<br />

industry, for instance in Germany (2<strong>01</strong>0 about 660.000 tonnes),<br />

would be enough to cover one third of the total amount of<br />

petro-based PET needed for the plastics processing industry<br />

in that country with a 100 % biobased PET. With a 30 %<br />

biobased PET even the whole German petro based PET could<br />

be substituted with the starch used for Paper and board<br />

industry in Germany.<br />

Renewable resources instead of food waste<br />

25 % of all food products bought in Germany remain<br />

unused and are discarded. This amounts to 6.6 million<br />

tonnes (approximately 80 kg per person) each year. Increased<br />

awareness and prudent food purchases would avoid these<br />

losses and lead to an extra gain of 2.4 million hectares of<br />

arable land in Germany alone. This is six times the area<br />

currently used for New Economy bioplastics. Given that<br />

avoidably taken up area was used to produce bioplastics<br />

instead, it could substitute more than two-thirds of Germany’s<br />

PE demand with Bio-PE. Regarding PET with this wasted<br />

area in case of 100 % biobased PET more than 20 % of global<br />

PET and in case of a 30 % biobased PET even almost 80 % of<br />

global PET, i.e. 12.9 million tonnes could be substituted.<br />

Furthermore much less than 0.1 % of the global agricultural<br />

land taken up for producing discarded food (ca. 1.4 billion<br />

hectares according to FAO), would suffice to cover the<br />

current total production of New Economy bioplastics. Even<br />

when relating this context to the aforementioned maximum<br />

scenario of substituting biobased plastics for all petroleum<br />

based plastics, it can be reasonably calculated that around 7 %<br />

(in numbers 100 million hectares) of the global arable area<br />

that is now blocked in favour of discarded food would be<br />

sufficient.<br />

Against this background it seems entirely overstated to<br />

look at bioplastics - particulary the New Economy bioplastics<br />

- as the main cause or even a risk for food shortages! Plastic<br />

materials, including bioplastics, continue to make important<br />

contributions to improved transportation and storage of food<br />

products and help protect these from spoiling.<br />

More information on the market for<br />

bioplastics – free of charge<br />

A comprehensive statistical database for bioplastics has<br />

been established by the IfBB – Institute for Bioplastics and<br />

Biocomposites (Hanover University of Applied Sciences and<br />

Arts) and made available in 2<strong>01</strong>3 via the Internet (see link in<br />

the box below). This platform provides free access to a wide<br />

range of information, including market figures, production<br />

capacities, regional distribution of bioplastics production,<br />

market shares for specific materials, detailed process routes<br />

for nearly all types of bioplastics, including conversion<br />

rates for the various process steps as well as feedstock and<br />

land use requirements, comparisons of area and feedstock<br />

efficiency, future forecasts, and more. Unrestricted access,<br />

free of charge, is provided via the Internet. All graphics and<br />

charts can be downloaded for free and used according to the<br />

copyright notice.<br />

www.ifbb-hannover.de<br />

100 %<br />

Global land area<br />

13,4 billion ha<br />

37 %<br />

10 Arable % land<br />

1,4 billion ha<br />

Global agricultural area<br />

5 billion ha<br />

Arable land<br />

1,4 billion ha<br />

The database, with statistics, can be found at:<br />

www.downloads.ifbb-hannover.de<br />

0,9 %<br />

Material Use<br />

0,12 billion ha<br />

Bioplastics<br />

0,003 % 0,00004 billion ha<br />

bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 37


Basics<br />

Glossary 3.2 last update issue 02/2<strong>01</strong>3<br />

In bioplastics MAGAZINE again and again<br />

the same expressions appear that some of our readers<br />

might not (yet) be familiar with. This glossary shall help<br />

with these terms and shall help avoid repeated explanations<br />

Bioplastics (as defined by European Bioplastics<br />

e.V.) is a term used to define two different<br />

kinds of plastics:<br />

a. Plastics based on → renewable resources<br />

(the focus is the origin of the raw material<br />

used). These can be biodegradable or not.<br />

b. → Biodegradable and → compostable<br />

plastics according to EN13432 or similar<br />

standards (the focus is the compostability of<br />

the final product; biodegradable and compostable<br />

plastics can be based on renewable<br />

(biobased) and/or non-renewable (fossil) resources).<br />

Bioplastics may be<br />

- based on renewable resources and biodegradable;<br />

- based on renewable resources but not be<br />

biodegradable; and<br />

- based on fossil resources and biodegradable.<br />

Aerobic - anaerobic | aerobic = in the presence<br />

of oxygen (e.g. in composting) | anaerobic<br />

= without oxygen being present (e.g. in<br />

biogasification, anaerobic digestion)<br />

[bM 06/09]<br />

Anaerobic digestion | conversion of organic<br />

waste into bio-gas. Other than in → composting<br />

in anaerobic degradation there is no oxygen<br />

present. In bio-gas plants for example,<br />

this type of degradation leads to the production<br />

of methane that can be captured in a controlled<br />

way and used for energy generation.<br />

[14] [bM 06/09]<br />

Amorphous | non-crystalline, glassy with unordered<br />

lattice<br />

Amylopectin | Polymeric branched starch<br />

molecule with very high molecular weight (biopolymer,<br />

monomer is → Glucose)<br />

[bM 05/09]<br />

Amylose | Polymeric non-branched starch<br />

molecule with high molecular weight (biopolymer,<br />

monomer is → Glucose) [bM 05/09]<br />

Biobased plastic/polymer | A plastic/polymer<br />

in which constitutional units are totally or in<br />

part from → biomass [3]. If this claim is used,<br />

a percentage should always be given to which<br />

extent the product/material is → biobased [1]<br />

[bM <strong>01</strong>/07, bM 03/10]<br />

such as ‘PLA (Polylactide)‘ in various articles.<br />

Since this Glossary will not be printed<br />

in each issue you can download a pdf version<br />

from our website (bit.ly/OunBB0)<br />

bioplastics MAGAZINE is grateful to European Bioplastics for the permission to use parts of their Glossary (see [1])<br />

Readers who would like to suggest better or other explanations to be added to the list, please contact the editor.<br />

[*: bM ... refers to more comprehensive article previously published in bioplastics MAGAZINE)<br />

Biobased | The term biobased describes the<br />

part of a material or product that is stemming<br />

from → biomass. When making a biobasedclaim,<br />

the unit (→ biobased carbon content,<br />

→ biobased mass content), a percentage and<br />

the measuring method should be clearly stated [1]<br />

Biobased carbon | carbon contained in or<br />

stemming from → biomass. A material or<br />

product made of fossil and → renewable resources<br />

contains fossil and → biobased carbon.<br />

The 14 C method [4, 5] measures the amount<br />

of biobased carbon in the material or product<br />

as fraction weight (mass) or percent weight<br />

(mass) of the total organic carbon content [1] [6]<br />

Biobased mass content | describes the<br />

amount of biobased mass contained in a material<br />

or product. This method is complementary<br />

to the 14 C method, and furthermore, takes<br />

other chemical elements besides the biobased<br />

carbon into account, such as oxygen, nitrogen<br />

and hydrogen. A measuring method is currently<br />

being developed and tested by the Association<br />

Chimie du Végétal (ACDV) [1]<br />

Biodegradable Plastics | Biodegradable Plastics<br />

are plastics that are completely assimilated<br />

by the → microorganisms present a defined<br />

environment as food for their energy. The<br />

carbon of the plastic must completely be converted<br />

into CO 2<br />

during the microbial process.<br />

The process of biodegradation depends on<br />

the environmental conditions, which influence<br />

it (e.g. location, temperature, humidity) and<br />

on the material or application itself. Consequently,<br />

the process and its outcome can vary<br />

considerably. Biodegradability is linked to the<br />

structure of the polymer chain; it does not depend<br />

on the origin of the raw materials.<br />

There is currently no single, overarching standard<br />

to back up claims about biodegradability.<br />

One standard for example is ISO or in Europe:<br />

EN 14995 Plastics- Evaluation of compostability<br />

- Test scheme and specifications<br />

[bM 02/06, bM <strong>01</strong>/07]<br />

Biomass | Material of biological origin excluding<br />

material embedded in geological formations<br />

and material transformed to fossilised<br />

material. This includes organic material, e.g.<br />

trees, crops, grasses, tree litter, algae and<br />

waste of biological origin, e.g. manure [1, 2]<br />

Biorefinery | the co-production of a spectrum<br />

of bio-based products (food, feed, materials,<br />

chemicals including monomers or building<br />

blocks for bioplastics) and energy (fuels, power,<br />

heat) from biomass.[bM 02/13]<br />

Blend | Mixture of plastics, polymer alloy of at<br />

least two microscopically dispersed and molecularly<br />

distributed base polymers<br />

Bisphenol-A (BPA) | Monomer used to produce<br />

different polymers. BPA is said to cause<br />

health problems, due to the fact that is behaves<br />

like a hormone. Therefore it is banned<br />

for use in children’s products in many countries.<br />

BPI | Biodegradable Products Institute, a notfor-profit<br />

association. Through their innovative<br />

compostable label program, BPI educates<br />

manufacturers, legislators and consumers<br />

about the importance of scientifically based<br />

standards for compostable materials which<br />

biodegrade in large composting facilities.<br />

Carbon footprint | (CFPs resp. PCFs – Product<br />

Carbon Footprint): Sum of → greenhouse<br />

gas emissions and removals in a product system,<br />

expressed as CO 2<br />

equivalent, and based<br />

on a → life cycle assessment. The CO 2<br />

equivalent<br />

of a specific amount of a greenhouse gas<br />

is calculated as the mass of a given greenhouse<br />

gas multiplied by its → global warmingpotential<br />

[1, 2]<br />

Carbon neutral, CO 2<br />

neutral | Carbon neutral<br />

describes a product or process that has<br />

a negligible impact on total atmospheric CO 2<br />

levels. For example, carbon neutrality means<br />

that any CO 2<br />

released when a plant decomposes<br />

or is burnt is offset by an equal amount<br />

of CO 2<br />

absorbed by the plant through photosynthesis<br />

when it is growing.<br />

Carbon neutrality can also be achieved<br />

through buying sufficient carbon credits to<br />

make up the difference. The latter option is<br />

not allowed when communicating → LCAs<br />

or carbon footprints regarding a material or<br />

product [1, 2].<br />

Carbon-neutral claims are tricky as products<br />

will not in most cases reach carbon neutrality<br />

if their complete life cycle is taken into consideration<br />

(including the end-of life).<br />

If an assessment of a material, however, is<br />

conducted (cradle to gate), carbon neutrality<br />

might be a valid claim in a B2B context. In this<br />

case, the unit assessed in the complete life<br />

cycle has to be clarified [1]<br />

Catalyst | substance that enables and accelerates<br />

a chemical reaction<br />

Cellophane | Clear film on the basis of → cellulose<br />

[bM <strong>01</strong>/10]<br />

Cellulose | Cellulose is the principal component<br />

of cell walls in all higher forms of plant<br />

life, at varying percentages. It is therefore the<br />

most common organic compound and also<br />

the most common polysaccharide (multisugar)<br />

[11]. C. is a polymeric molecule with<br />

very high molecular weight (monomer is →<br />

Glucose), industrial production from wood or<br />

cotton, to manufacture paper, plastics and fibres<br />

[bM <strong>01</strong>/10]<br />

Cellulose ester| Cellulose esters occur by the<br />

esterification of cellulose with organic acids.<br />

The most important cellulose esters from a<br />

technical point of view are cellulose acetate<br />

38 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


Basics<br />

(CA with acetic acid), cellulose propionate (CP<br />

with propionic acid) and cellulose butyrate<br />

(CB with butanoic acid). Mixed polymerisates,<br />

such as cellulose acetate propionate<br />

(CAP) can also be formed. One of the most<br />

well-known applications of cellulose aceto<br />

butyrate (CAB) is the moulded handle on the<br />

Swiss army knife [11]<br />

Cellulose acetate CA| → Cellulose ester<br />

CEN | Comité Européen de Normalisation<br />

(European organisation for standardization)<br />

Compost | A soil conditioning material of decomposing<br />

organic matter which provides nutrients<br />

and enhances soil structure.<br />

[bM 06/08, 02/09]<br />

Compostable Plastics | Plastics that are<br />

→ biodegradable under ‘composting’ conditions:<br />

specified humidity, temperature,<br />

→ microorganisms and timefame. In order<br />

to make accurate and specific claims about<br />

compostability, the location (home, → industrial)<br />

and timeframe need to be specified [1].<br />

Several national and international standards<br />

exist for clearer definitions, for example EN<br />

14995 Plastics - Evaluation of compostability -<br />

Test scheme and specifications. [bM 02/06, bM <strong>01</strong>/07]<br />

Composting | A solid waste management<br />

technique that uses natural process to convert<br />

organic materials to CO 2<br />

, water and humus<br />

through the action of → microorganisms.<br />

When talking about composting of bioplastics,<br />

usually → industrial composting in a managed<br />

composting plant is meant [bM 03/07]<br />

Compound | plastic mixture from different<br />

raw materials (polymer and additives) [bM 04/10)<br />

Copolymer | Plastic composed of different<br />

monomers.<br />

Cradle-to-Gate | Describes the system<br />

boundaries of an environmental →Life Cycle<br />

Assessment (LCA) which covers all activities<br />

from the ‘cradle’ (i.e., the extraction of raw<br />

materials, agricultural activities and forestry)<br />

up to the factory gate<br />

Cradle-to-Cradle | (sometimes abbreviated<br />

as C2C): Is an expression which communicates<br />

the concept of a closed-cycle economy,<br />

in which waste is used as raw material<br />

(‘waste equals food’). Cradle-to-Cradle is not<br />

a term that is typically used in →LCA studies.<br />

Cradle-to-Grave | Describes the system<br />

boundaries of a full →Life Cycle Assessment<br />

from manufacture (‘cradle’) to use phase and<br />

disposal phase (‘grave’).<br />

Crystalline | Plastic with regularly arranged<br />

molecules in a lattice structure<br />

Density | Quotient from mass and volume of<br />

a material, also referred to as specific weight<br />

DIN | Deutsches Institut für Normung (German<br />

organisation for standardization)<br />

DIN-CERTCO | independant certifying organisation<br />

for the assessment on the conformity<br />

of bioplastics<br />

Dispersing | fine distribution of non-miscible<br />

liquids into a homogeneous, stable mixture<br />

Drop-In Bioplastics | chemically indentical<br />

to conventional petroleum based plastics,<br />

but made from renewable resources. Examples<br />

are bio-PE made from bio-ethanol (from<br />

e.g. sugar cane) or partly biobased PET (the<br />

monoethylene glykol made from bio-ethanol<br />

(from e.g. sugar cane, a development to make<br />

terephthalic acid from renewable resources<br />

are under way). Other examples are polyamides<br />

(partly biobased e.g. PA 4.10 or PA 10.10<br />

or fully biobased like PA 5.10 or 10.10)<br />

Elastomers | rigid, but under force flexible<br />

and elastically formable plastics with rubbery<br />

properties<br />

EN 13432 | European standard for the assessment<br />

of the → compostability of plastic<br />

packaging products<br />

Energy recovery | recovery and exploitation<br />

of the energy potential in (plastic) waste for<br />

the production of electricity or heat in waste<br />

incineration pants (waste-to-energy)<br />

Enzymes | proteins that catalyze chemical<br />

reactions<br />

Ethylen | colour- and odourless gas, made<br />

e.g. from, Naphtha (petroleum) by cracking,<br />

monomer of the polymer polyethylene (PE)<br />

European Bioplastics e.V. | The industry association<br />

representing the interests of Europe’s<br />

thriving bioplastics’ industry. Founded<br />

in Germany in 1993 as IBAW, European Bioplastics<br />

today represents the interests of over<br />

70 member companies throughout the European<br />

Union. With members from the agricultural<br />

feedstock, chemical and plastics industries,<br />

as well as industrial users and recycling<br />

companies, European Bioplastics serves as<br />

both a contact platform and catalyst for advancing<br />

the aims of the growing bioplastics<br />

industry.<br />

Extrusion | process used to create plastic<br />

profiles (or sheet) of a fixed cross-section<br />

consisting of mixing, melting, homogenising<br />

and shaping of the plastic.<br />

Fermentation | Biochemical reactions controlled<br />

by → microorganisms or → enyzmes (e.g.<br />

the transformation of sugar into lactic acid).<br />

FSC | Forest Stewardship Council. FSC is an<br />

independent, non-governmental, not-forprofit<br />

organization established to promote the<br />

responsible and sustainable management of<br />

the world’s forests.<br />

Gelatine | Translucent brittle solid substance,<br />

colorless or slightly yellow, nearly tasteless<br />

and odorless, extracted from the collagen inside<br />

animals‘ connective tissue.<br />

Genetically modified organism (GMO) | Organisms,<br />

such as plants and animals, whose<br />

genetic material (DNA) has been altered<br />

are called genetically modified organisms<br />

(GMOs). Food and feed which contain or<br />

consist of such GMOs, or are produced from<br />

GMOs, are called genetically modified (GM)<br />

food or feed [1]<br />

Global Warming | Global warming is the rise<br />

in the average temperature of Earth’s atmosphere<br />

and oceans since the late 19th century<br />

and its projected continuation [8]. Global<br />

warming is said to be accelerated by → green<br />

house gases.<br />

Glucose | Monosaccharide (or simple sugar).<br />

G. is the most important carbohydrate (sugar)<br />

in biology. G. is formed by photosynthesis or<br />

hydrolyse of many carbohydrates e. g. starch.<br />

Greenhouse gas GHG | Gaseous constituent<br />

of the atmosphere, both natural and anthropogenic,<br />

that absorbs and emits radiation at<br />

specific wavelengths within the spectrum of<br />

infrared radiation emitted by the earth’s surface,<br />

the atmosphere, and clouds [1, 9]<br />

Greenwashing | The act of misleading consumers<br />

regarding the environmental practices<br />

of a company, or the environmental benefits<br />

of a product or service [1, 10]<br />

Granulate, granules | small plastic particles<br />

(3-4 millimetres), a form in which plastic is<br />

sold and fed into machines, easy to handle<br />

and dose.<br />

Humus | In agriculture, ‘humus’ is often used<br />

simply to mean mature → compost, or natural<br />

compost extracted from a forest or other<br />

spontaneous source for use to amend soil.<br />

Hydrophilic | Property: ‘water-friendly’, soluble<br />

in water or other polar solvents (e.g. used<br />

in conjunction with a plastic which is not water<br />

resistant and weather proof or that absorbs<br />

water such as Polyamide (PA).<br />

Hydrophobic | Property: ‘water-resistant’, not<br />

soluble in water (e.g. a plastic which is water<br />

resistant and weather proof, or that does not<br />

absorb any water such as Polyethylene (PE)<br />

or Polypropylene (PP).<br />

IBAW | → European Bioplastics<br />

Industrial composting | Industrial composting<br />

is an established process with commonly<br />

agreed upon requirements (e.g. temperature,<br />

timeframe) for transforming biodegradable<br />

waste into stable, sanitised products to be<br />

used in agriculture. The criteria for industrial<br />

compostability of packaging have been defined<br />

in the EN 13432. Materials and products<br />

complying with this standard can be certified<br />

and subsequently labelled accordingly [1, 7]<br />

[bM 06/08, bM 02/09]<br />

Integral Foam | foam with a compact skin and<br />

porous core and a transition zone in between.<br />

ISO | International Organization for Standardization<br />

JBPA | Japan Bioplastics Association<br />

LCA | Life Cycle Assessment (sometimes also<br />

referred to as life cycle analysis, ecobalance,<br />

and → cradle-to-grave analysis) is the investigation<br />

and valuation of the environmental<br />

impacts of a given product or service caused.<br />

[bM <strong>01</strong>/09]<br />

Microorganism | Living organisms of microscopic<br />

size, such as bacteria, funghi or yeast.<br />

Molecule | group of at least two atoms held<br />

together by covalent chemical bonds.<br />

Monomer | molecules that are linked by polymerization<br />

to form chains of molecules and<br />

then plastics<br />

Mulch film | Foil to cover bottom of farmland<br />

PBAT | Polybutylene adipate terephthalate, is<br />

an aliphatic-aromatic copolyester that has the<br />

properties of conventional polyethylene but is<br />

fully biodegradable under industrial composting.<br />

PBAT is made from fossil petroleum with<br />

first attempts being made to produce it partly<br />

from renewable resources [bM 06/09]<br />

PBS | Polybutylene succinate, a 100% biodegradable<br />

polymer, made from (e.g. bio-BDO)<br />

and succinic acid, which can also be produced<br />

biobased [bM 03/12].<br />

PC | Polycarbonate, thermoplastic polyester,<br />

petroleum based, used for e.g. baby bottles<br />

or CDs. Criticized for its BPA (→ Bisphenol-A)<br />

content.<br />

bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 39


Basics<br />

PCL | Polycaprolactone, a synthetic (fossil<br />

based), biodegradable bioplastic, e.g. used as<br />

a blend component.<br />

PE | Polyethylene, thermoplastic polymerised<br />

from ethylene. Can be made from renewable<br />

resources (sugar cane via bio-ethanol)<br />

[bM 05/10]<br />

PET | Polyethylenterephthalate, transparent<br />

polyester used for bottles and film<br />

PGA | Polyglycolic acid or Polyglycolide is a<br />

biodegradable, thermoplastic polymer and<br />

the simplest linear, aliphatic polyester. Besides<br />

ist use in the biomedical field, PGA has<br />

been introduced as a barrier resin [bM 03/09]<br />

PHA | Polyhydroxyalkanoates are linear polyesters<br />

produced in nature by bacterial fermentation<br />

of sugar or lipids. The most common<br />

type of PHA is → PHB.<br />

PHB | Polyhydroxybutyrate (better poly-3-hydroxybutyrate),<br />

is a polyhydroxyalkanoate<br />

(PHA), a polymer belonging to the polyesters<br />

class. PHB is produced by micro-organisms<br />

apparently in response to conditions of physiological<br />

stress. The polymer is primarily a<br />

product of carbon assimilation (from glucose<br />

or starch) and is employed by micro-organisms<br />

as a form of energy storage molecule to<br />

be metabolized when other common energy<br />

sources are not available. PHB has properties<br />

similar to those of PP, however it is stiffer and<br />

more brittle.<br />

PHBH | Polyhydroxy butyrate hexanoate (better<br />

poly 3-hydroxybutyrate-co-3-hydroxyhexanoate)<br />

is a polyhydroxyalkanoate (PHA),<br />

Like other biopolymers from the family of the<br />

polyhydroxyalkanoates PHBH is produced by<br />

microorganisms in the fermentation process,<br />

where it is accumulated in the microorganism’s<br />

body for nutrition. The main features of<br />

PHBH are its excellent biodegradability, combined<br />

with a high degree of hydrolysis and<br />

heat stability. [bM 03/09, <strong>01</strong>/10, 03/11]<br />

PLA | Polylactide or Polylactic Acid (PLA), a<br />

biodegradable, thermoplastic, linear aliphatic<br />

polyester based on lactic acid, a natural acid,<br />

is mainly produced by fermentation of sugar<br />

or starch with the help of micro-organisms.<br />

Lactic acid comes in two isomer forms, i.e.<br />

as laevorotatory D(-)lactic acid and as dextrorotary<br />

L(+)lactic acid. In each case two<br />

lactic acid molecules form a circular lactide<br />

molecule which, depending on its composition,<br />

can be a D-D-lactide, an L-L-lactide<br />

or a meso-lactide (having one D and one L<br />

molecule). The chemist makes use of this<br />

variability. During polymerisation the chemist<br />

combines the lactides such that the PLA<br />

plastic obtained has the characteristics that<br />

he desires. The purity of the infeed material is<br />

an important factor in successful polymerisation<br />

and thus for the economic success of the<br />

process, because so far the cleaning of the<br />

lactic acid produced by the fermentation has<br />

been relatively costly [12].<br />

Modified PLA types can be produced by the<br />

use of the right additives or by a combinations<br />

of L- and D- lactides (stereocomplexing),<br />

which then have the required rigidity for use<br />

at higher temperatures [13] [bM <strong>01</strong>/09]<br />

Plastics | Materials with large molecular<br />

chains of natural or fossil raw materials, produced<br />

by chemical or biochemical reactions.<br />

PPC | Polypropylene Carbonate, a bioplastic<br />

made by copolymerizing CO 2<br />

with propylene<br />

oxide (PO) [bM 04/12]<br />

Renewable Resources | agricultural raw materials,<br />

which are not used as food or feed, but<br />

as raw material for industrial products or to<br />

generate energy<br />

Saccharins or carbohydrates | Saccharins or<br />

carbohydrates are name for the sugar-family.<br />

Saccharins are monomer or polymer sugar<br />

units. For example, there are known mono-,<br />

di- and polysaccharose. → glucose is a monosaccarin.<br />

They are important for the diet and<br />

produced biology in plants.<br />

Semi-finished products | plastic in form of<br />

sheet, film, rods or the like to be further processed<br />

into finshed products<br />

Sorbitol | Sugar alcohol, obtained by reduction<br />

of glucose changing the aldehyde group<br />

to an additional hydroxyl group. S. is used as<br />

a plasticiser for bioplastics based on starch.<br />

Starch | Natural polymer (carbohydrate)<br />

consisting of → amylose and → amylopectin,<br />

gained from maize, potatoes, wheat, tapioca<br />

etc. When glucose is connected to polymerchains<br />

in definite way the result (product) is<br />

called starch. Each molecule is based on 300<br />

-12000-glucose units. Depending on the connection,<br />

there are two types → amylose and →<br />

amylopectin known. [bM 05/09]<br />

Starch derivate | Starch derivates are based<br />

on the chemical structure of → starch. The<br />

chemical structure can be changed by introducing<br />

new functional groups without changing<br />

the → starch polymer. The product has<br />

different chemical qualities. Mostly the hydrophilic<br />

character is not the same.<br />

Starch-ester | One characteristic of every<br />

starch-chain is a free hydroxyl group. When<br />

every hydroxyl group is connect with ethan<br />

acid one product is starch-ester with different<br />

chemical properties.<br />

Starch propionate and starch butyrate |<br />

Starch propionate and starch butyrate can be<br />

synthesised by treating the → starch with propane<br />

or butanic acid. The product structure<br />

is still based on → starch. Every based → glucose<br />

fragment is connected with a propionate<br />

or butyrate ester group. The product is more<br />

hydrophobic than → starch.<br />

Sustainable | An attempt to provide the best<br />

outcomes for the human and natural environments<br />

both now and into the indefinite future.<br />

One of the most often cited definitions of sustainability<br />

is the one created by the Brundtland<br />

Commission, led by the former Norwegian<br />

Prime Minister Gro Harlem Brundtland.<br />

The Brundtland Commission defined sustainable<br />

development as development that ‘meets<br />

the needs of the present without compromising<br />

the ability of future generations to meet<br />

their own needs.’ Sustainability relates to the<br />

continuity of economic, social, institutional<br />

and environmental aspects of human society,<br />

as well as the non-human environment).<br />

Sustainability | (as defined by European Bioplastics<br />

e.V.) has three dimensions: economic,<br />

social and environmental. This has been<br />

known as “the triple bottom line of sustainability”.<br />

This means that sustainable development<br />

involves the simultaneous pursuit of<br />

economic prosperity, environmental protection<br />

and social equity. In other words, businesses<br />

have to expand their responsibility to include<br />

these environmental and social dimensions.<br />

Sustainability is about making products useful<br />

to markets and, at the same time, having societal<br />

benefits and lower environmental impact<br />

than the alternatives currently available. It also<br />

implies a commitment to continuous improvement<br />

that should result in a further reduction<br />

of the environmental footprint of today’s products,<br />

processes and raw materials used.<br />

Thermoplastics | Plastics which soften or<br />

melt when heated and solidify when cooled<br />

(solid at room temperature).<br />

Thermoplastic Starch | (TPS) → starch that<br />

was modified (cooked, complexed) to make it<br />

a plastic resin<br />

Thermoset | Plastics (resins) which do not<br />

soften or melt when heated. Examples are<br />

epoxy resins or unsaturated polyester resins.<br />

Vinçotte | independant certifying organisation<br />

for the assessment on the conformity of bioplastics<br />

WPC | Wood Plastic Composite. Composite<br />

materials made of wood fiber/flour and plastics<br />

(mostly polypropylene).<br />

Yard Waste | Grass clippings, leaves, trimmings,<br />

garden residue.<br />

References:<br />

[1] Environmental Communication Guide,<br />

European Bioplastics, Berlin, Germany,<br />

2<strong>01</strong>2<br />

[2] ISO 14067. Carbon footprint of products -<br />

Requirements and guidelines for quantification<br />

and communication<br />

[3] CEN TR 15932, Plastics - Recommendation<br />

for terminology and characterisation<br />

of biopolymers and bioplastics, 2<strong>01</strong>0<br />

[4] CEN/TS 16137, Plastics - Determination<br />

of bio-based carbon content, 2<strong>01</strong>1<br />

[5] ASTM D6866, Standard Test Methods for<br />

Determining the Biobased Content of<br />

Solid, Liquid, and Gaseous Samples Using<br />

Radiocarbon Analysis<br />

[6] SPI: Understanding Biobased Carbon<br />

Content, 2<strong>01</strong>2<br />

[7] EN 13432, Requirements for packaging<br />

recoverable through composting and biodegradation.<br />

Test scheme and evaluation<br />

criteria for the final acceptance of packaging,<br />

2000<br />

[8] Wikipedia<br />

[9] ISO 14064 Greenhouse gases -- Part 1:<br />

Specification with guidance..., 2006<br />

[10] Terrachoice, 2<strong>01</strong>0, www.terrachoice.com<br />

[11] Thielen, M.: Bioplastics: Basics. Applications.<br />

Markets, Polymedia Publisher,<br />

2<strong>01</strong>2<br />

[12] Lörcks, J.: Biokunststoffe, Broschüre der<br />

FNR, 2005<br />

[13] de Vos, S.: Improving heat-resistance of<br />

PLA using poly(D-lactide),<br />

bioplastics MAGAZINE, Vol. 3, <strong>Issue</strong> 02/2008<br />

[14] de Wilde, B.: Anaerobic Digestion, bioplastics<br />

MAGAZINE, Vol 4., <strong>Issue</strong> 06/2009<br />

40 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


Exhibition area exceeds 220,000 sqm<br />

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2<strong>01</strong>3-10-18


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World Bio Markets 2<strong>01</strong>4<br />

04.03.2<strong>01</strong>4 - 06.03.2<strong>01</strong>4 - Amsterdam, The Netherlands<br />

RAI Amsterdam<br />

www.worldbiofuelsmarkets.com<br />

BioPlastics 2<strong>01</strong>4: The Re-Invention of Plastics<br />

04.03.2<strong>01</strong>4 - 06.03.2<strong>01</strong>4 - Las Vegas, NV, USA<br />

Caesars Palace<br />

www.BioplastConference.com<br />

5th International Seminar on<br />

Biopolymers and Sustainable Composites<br />

06.03.2<strong>01</strong>4 - 07.03.2<strong>01</strong>4 - Valencia, Spain<br />

www.biopolymersmeeting.com/en/<br />

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or<br />

Green Polymer Chemistry 2<strong>01</strong>4<br />

18.03.2<strong>01</strong>4 - 20.03.2<strong>01</strong>4 - Cologne, Germany<br />

Maritim Hotel, Cologne<br />

amiplastics.com/events/Event.aspx?code=C564&sec=3717<br />

Tage der Holzforschung 2<strong>01</strong>4<br />

20.03.2<strong>01</strong>4 - 21.03.2<strong>01</strong>4 - Braunschweig,Germany<br />

www.ivth.org<br />

Plastics in Automotive Engineering (VDI)<br />

02.04.2<strong>01</strong>4 - 03.04.2<strong>01</strong>4 - Mannheim, Germany<br />

www.kunststoffe-im-auto.de<br />

7th International Conference on Bio-based Materials<br />

08.04.2<strong>01</strong>4 - 10.04.2<strong>01</strong>4 - Cologne, Germany<br />

Maternushaus<br />

www.bio-based.eu/conference<br />

Biopolymers Symposium 2<strong>01</strong>4<br />

12.05.2<strong>01</strong>4 - 13.05.2<strong>01</strong>4 - Philadelphia PA, USA<br />

Loews Philadelphia Hotel<br />

www.biopolymersummit.com/venue.aspx<br />

3rd PLA World Congress<br />

27.05.2<strong>01</strong>4 – 28.05.2<strong>01</strong>4 – Munich, Germany<br />

Holiday Inn Munich City Centre<br />

www.pla-world-congress.com<br />

GreenTech<br />

10.06.2<strong>01</strong>4 - 12.06.2<strong>01</strong>4 - Amsterdam, The Netherlands<br />

RAI Amsterdam<br />

www.greentech.nl<br />

Biobased Materials<br />

24.06.2<strong>01</strong>4 - 25.06.2<strong>01</strong>4 - Stuttgart, Germany<br />

10th Congress for Biobased Materials, Natural Fibres and WPC<br />

www.biobased-materials.com<br />

Mention the promotion code ‘watch‘ or ‘book‘<br />

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9th European Bioplastics<br />

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The Square, Brussels<br />

www.european-bioplastics.org<br />

You can meet us! Please contact us in advance by e-mail.


Suppliers Guide<br />

1. Raw Materials<br />

AGRANA Starch<br />

Thermoplastics<br />

Conrathstrasse 7<br />

A-3950 Gmuend, Austria<br />

Tel: +43 676 8926 19374<br />

lukas.raschbauer@agrana.com<br />

www.agrana.com<br />

Shandong Fuwin New Material Co., Ltd.<br />

Econorm ® Biodegradable &<br />

Compostable Resin<br />

North of Baoshan Road, Zibo City,<br />

Shandong Province P.R. China.<br />

Phone: +86 533 7986<strong>01</strong>6<br />

Fax: +86 533 62<strong>01</strong>788<br />

Mobile: +86-13953357190<br />

CNMHELEN@GMAIL.COM<br />

www.sdfuwin.com<br />

FKuR Kunststoff GmbH<br />

Siemensring 79<br />

D - 47 877 Willich<br />

Tel. +49 2154 9251-0<br />

Tel.: +49 2154 9251-51<br />

sales@fkur.com<br />

www.fkur.com<br />

39 mm<br />

Simply contact:<br />

Tel.: +49 2161 6884467<br />

suppguide@bioplasticsmagazine.com<br />

Stay permanently listed in the<br />

Suppliers Guide with your company<br />

logo and contact information.<br />

For only 6,– EUR per mm, per issue you<br />

can be present among top suppliers in<br />

the field of bioplastics.<br />

For Example:<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach<br />

Germany<br />

Tel. +49 2161 664864<br />

Fax +49 2161 631045<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Showa Denko Europe GmbH<br />

Konrad-Zuse-Platz 4<br />

81829 Munich, Germany<br />

Tel.: +49 89 93996226<br />

www.showa-denko.com<br />

support@sde.de<br />

DuPont de Nemours International S.A.<br />

2 chemin du Pavillon<br />

1218 - Le Grand Saconnex<br />

Switzerland<br />

Tel.: +41 22 171 51 11<br />

Fax: +41 22 580 22 45<br />

plastics@dupont.com<br />

www.renewable.dupont.com<br />

www.plastics.dupont.com<br />

Tel: +86 351-8689356<br />

Fax: +86 351-8689718<br />

www.ecoworld.jinhuigroup.com<br />

jinhuibio@126.com<br />

Jincheng, Lin‘an, Hangzhou,<br />

Zhejiang 311300, P.R. China<br />

China contact: Grace Jin<br />

mobile: 0086 135 7578 9843<br />

Grace@xinfupharm.com<br />

Europe contact(Belgium): Susan Zhang<br />

mobile: 0032 478 991619<br />

zxh0612@hotmail.com<br />

www.xinfupharm.com<br />

1.1 bio based monomers<br />

Corbion Purac<br />

Arkelsedijk 46, P.O. Box 21<br />

4200 AA Gorinchem -<br />

The Netherlands<br />

Tel.: +31 (0)183 695 695<br />

Fax: +31 (0)183 695 604<br />

www.corbion.com/bioplastics<br />

bioplastics@corbion.com<br />

1.2 compounds<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

Natur-Tec ® - Northern Technologies<br />

42<strong>01</strong> Woodland Road<br />

Circle Pines, MN 55<strong>01</strong>4 USA<br />

Tel. +1 763.225.6600<br />

Fax +1 763.225.6645<br />

info@natur-tec.com<br />

www.natur-tec.com<br />

PolyOne<br />

Avenue Melville Wilson, 2<br />

Zoning de la Fagne<br />

5330 Assesse<br />

Belgium<br />

Tel.: + 32 83 660 211<br />

www.polyone.com<br />

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Sample Charge for one year:<br />

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The entry in our Suppliers Guide is<br />

bookable for one year (6 issues) and<br />

extends automatically if it’s not canceled<br />

three month before expiry.<br />

Evonik Industries AG<br />

Paul Baumann Straße 1<br />

45772 Marl, Germany<br />

Tel +49 2365 49-4717<br />

evonik-hp@evonik.com<br />

www.vestamid-terra.com<br />

www.evonik.com<br />

API S.p.A.<br />

Via Dante Alighieri, 27<br />

36065 Mussolente (VI), Italy<br />

Telephone +39 0424 579711<br />

www.apiplastic.com<br />

www.apinatbio.com<br />

WinGram Industry CO., LTD<br />

Great River(Qin Xin)<br />

Plastic Manufacturer CO., LTD<br />

Mobile (China): +86-13113833156<br />

Mobile (Hong Kong): +852-63078857<br />

Fax: +852-3184 8934<br />

Email: Benson@wingram.hk<br />

www.facebook.com<br />

www.issuu.com<br />

www.twitter.com<br />

www.youtube.com<br />

Natureplast<br />

11 rue François Arago<br />

14123 Ifs – France<br />

Tel. +33 2 31 83 50 87<br />

www.natureplast.eu<br />

t.lefevre@natureplast.eu<br />

Kingfa Sci. & Tech. Co., Ltd.<br />

No.33 Kefeng Rd, Sc. City, Guangzhou<br />

Hi-Tech Ind. Development Zone,<br />

Guangdong, P.R. China. 510663<br />

Tel: +86 (0)20 6622 1696<br />

info@ecopond.com.cn<br />

www.ecopond.com.cn<br />

FLEX-162 Biodeg. Blown Film Resin!<br />

Bio-873 4-Star Inj. Bio-Based Resin!<br />

1.3 PLA<br />

Shenzhen Esun Ind. Co;Ltd<br />

www.brightcn.net<br />

www.esun.en.alibaba.com<br />

bright@brightcn.net<br />

Tel: +86-755-2603 1978<br />

bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 43


Suppliers Guide<br />

1.4 starch-based bioplastics<br />

6. Equipment<br />

Limagrain Céréales Ingrédients<br />

ZAC „Les Portes de Riom“ - BP 173<br />

63204 Riom Cedex - France<br />

Tel. +33 (0)4 73 67 17 00<br />

Fax +33 (0)4 73 67 17 10<br />

www.biolice.com<br />

Metabolix, Inc.<br />

Bio-based and biodegradable resins<br />

and performance additives<br />

21 Erie Street<br />

Cambridge, MA 02139, USA<br />

US +1-617-583-1700<br />

DE +49 (0) 221 / 88 88 94 00<br />

www.metabolix.com<br />

info@metabolix.com<br />

1.6 masterbatches<br />

www.earthfirstpla.com<br />

www.sidaplax.com<br />

www.plasticsuppliers.com<br />

Sidaplax UK : +44 (1) 604 76 66 99<br />

Sidaplax Belgium: +32 9 210 80 10<br />

Plastic Suppliers: +1 866 378 4178<br />

6.1 Machinery & Molds<br />

Molds, Change Parts and Turnkey<br />

Solutions for the PET/Bioplastic<br />

Container Industry<br />

284 Pinebush Road<br />

Cambridge Ontario<br />

Canada N1T 1Z6<br />

Tel. +1 519 624 9720<br />

Fax +1 519 624 9721<br />

info@hallink.com<br />

www.hallink.com<br />

BIOTEC<br />

Biologische Naturverpackungen<br />

Werner-Heisenberg-Strasse 32<br />

46446 Emmerich/Germany<br />

Tel.: +49 (0) 2822 – 92510<br />

info@biotec.de<br />

www.biotec.de<br />

ROQUETTE<br />

62 136 LESTREM, FRANCE<br />

00 33 (0) 3 21 63 36 00<br />

www.gaialene.com<br />

www.roquette.com<br />

Grabio Greentech Corporation<br />

Tel: +886-3-598-6496<br />

No. 91, Guangfu N. Rd., Hsinchu<br />

Industrial Park,Hukou Township,<br />

Hsinchu County 30351, Taiwan<br />

sales@grabio.com.tw<br />

www.grabio.com.tw<br />

PSM Bioplastic HK<br />

Room 19<strong>01</strong>B,19/F, Allied Kajima<br />

Buil- ding 138 Gloucester Road,<br />

Wanchai, Hongkong<br />

Tel: +852-31767566<br />

Fax: +852-31767567<br />

support@psm.com.cn<br />

www.psm.com.cn<br />

1.5 PHA<br />

TianAn Biopolymer<br />

No. 68 Dagang 6th Rd,<br />

Beilun, Ningbo, China, 315800<br />

Tel. +86-57 48 68 62 50 2<br />

Fax +86-57 48 68 77 98 0<br />

enquiry@tianan-enmat.com<br />

www.tianan-enmat.com<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

PolyOne<br />

Avenue Melville Wilson, 2<br />

Zoning de la Fagne<br />

5330 Assesse<br />

Belgium<br />

Tel.: + 32 83 660 211<br />

www.polyone.com<br />

2. Additives/Secondary raw materials<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

Rhein Chemie Rheinau GmbH<br />

Duesseldorfer Strasse 23-27<br />

68219 Mannheim, Germany<br />

Phone: +49 (0)621-8907-233<br />

Fax: +49 (0)621-8907-8233<br />

bioadimide.eu@rheinchemie.com<br />

www.bioadimide.com<br />

3. Semi finished products<br />

3.1 films<br />

Huhtamaki Films<br />

Sonja Haug<br />

Zweibrückenstraße 15-25<br />

913<strong>01</strong> Forchheim<br />

Tel. +49-9191 81203<br />

Fax +49-9191 811203<br />

www.huhtamaki-films.com<br />

Taghleef Industries SpA, Italy<br />

Via E. Fermi, 46<br />

33058 San Giorgio di Nogaro (UD)<br />

Contact Frank Ernst<br />

Tel. +49 2402 7096989<br />

Mobile +49 160 4756573<br />

frank.ernst@ti-films.com<br />

www.ti-films.com<br />

4. Bioplastics products<br />

Minima Technology Co., Ltd.<br />

Esmy Huang, Marketing Manager<br />

No.33. Yichang E. Rd., Taipin City,<br />

Taichung County<br />

411, Taiwan (R.O.C.)<br />

Tel. +886(4)2277 6888<br />

Fax +883(4)2277 6989<br />

Mobil +886(0)982-829988<br />

esmy@minima-tech.com<br />

Skype esmy325<br />

www.minima-tech.com<br />

NOVAMONT S.p.A.<br />

Via Fauser , 8<br />

28100 Novara - ITALIA<br />

Fax +39.0321.699.6<strong>01</strong><br />

Tel. +39.0321.699.611<br />

www.novamont.com<br />

President Packaging Ind., Corp.<br />

PLA Paper Hot Cup manufacture<br />

In Taiwan, www.ppi.com.tw<br />

Tel.: +886-6-570-4066 ext.5531<br />

Fax: +886-6-570-4077<br />

sales@ppi.com.tw<br />

ProTec Polymer Processing GmbH<br />

Stubenwald-Allee 9<br />

64625 Bensheim, Deutschland<br />

Tel. +49 6251 77061 0<br />

Fax +49 6251 77061 500<br />

info@sp-protec.com<br />

www.sp-protec.com<br />

6.2 Laboratory Equipment<br />

MODA: Biodegradability Analyzer<br />

SAIDA FDS INC.<br />

143-10 Isshiki, Yaizu,<br />

Shizuoka,Japan<br />

Tel:+81-54-624-6260<br />

Info2@moda.vg<br />

www.saidagroup.jp<br />

7. Plant engineering<br />

EREMA Engineering Recycling<br />

Maschinen und Anlagen GmbH<br />

Unterfeldstrasse 3<br />

4052 Ansfelden, AUSTRIA<br />

Phone: +43 (0) 732 / 3190-0<br />

Fax: +43 (0) 732 / 3190-23<br />

erema@erema.at<br />

www.erema.at<br />

Uhde Inventa-Fischer GmbH<br />

Holzhauser Strasse 157–159<br />

D-13509 Berlin<br />

Tel. +49 30 43 567 5<br />

Fax +49 30 43 567 699<br />

sales.de@uhde-inventa-fischer.com<br />

Uhde Inventa-Fischer AG<br />

Via Innovativa 31<br />

CH-7<strong>01</strong>3 Domat/Ems<br />

Tel. +41 81 632 63 11<br />

Fax +41 81 632 74 03<br />

sales.ch@uhde-inventa-fischer.com<br />

www.uhde-inventa-fischer.com<br />

44 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


Suppliers Guide<br />

9. Services<br />

10.2 Universities<br />

Biopolynov<br />

11 rue François Arago<br />

14123 Ifs – France<br />

Tel. +33 2 31 83 50 87<br />

www. biopolynov.com<br />

t.lefevre@natureplast.eu<br />

Osterfelder Str. 3<br />

46047 Oberhausen<br />

Tel.: +49 (0)208 8598 1227<br />

Fax: +49 (0)208 8598 1424<br />

thomas.wodke@umsicht.fhg.de<br />

www.umsicht.fraunhofer.de<br />

Institut für Kunststofftechnik<br />

Universität Stuttgart<br />

Böblinger Straße 70<br />

7<strong>01</strong>99 Stuttgart<br />

Tel +49 711/685-62814<br />

Linda.Goebel@ikt.uni-stuttgart.de<br />

www.ikt.uni-stuttgart.de<br />

narocon<br />

Dr. Harald Kaeb<br />

Tel.: +49 30-28096930<br />

kaeb@narocon.de<br />

www.narocon.de<br />

nova-Institut GmbH<br />

Chemiepark Knapsack<br />

Industriestrasse 300<br />

50354 Huerth, Germany<br />

Tel.: +49(0)2233-48-14 40<br />

E-Mail: contact@nova-institut.de<br />

www.biobased.eu<br />

Bioplastics Consulting<br />

Tel. +49 2161 664864<br />

info@polymediaconsult.com<br />

UL International TTC GmbH<br />

Rheinuferstrasse 7-9, Geb. R33<br />

47829 Krefeld-Uerdingen, Germany<br />

Tel: +49 (0)2151 88 3324<br />

Fax: +49 (0)2151 88 5210<br />

ttc@ul.com<br />

www.ulttc.com<br />

10. Institutions<br />

10.1 Associations<br />

BPI - The Biodegradable<br />

Products Institute<br />

331 West 57th Street, Suite 415<br />

New York, NY 10<strong>01</strong>9, USA<br />

Tel. +1-888-274-5646<br />

info@bpiworld.org<br />

European Bioplastics e.V.<br />

Marienstr. 19/20<br />

1<strong>01</strong>17 Berlin, Germany<br />

Tel. +49 30 284 82 350<br />

Fax +49 30 284 84 359<br />

info@european-bioplastics.org<br />

www.european-bioplastics.org<br />

IfBB – Institute for Bioplastics<br />

and Biocomposites<br />

University of Applied Sciences<br />

and Arts Hanover<br />

Faculty II – Mechanical and<br />

Bioprocess Engineering<br />

Heisterbergallee 12<br />

30453 Hannover, Germany<br />

Tel.: +49 5 11 / 92 96 - 22 69<br />

Fax: +49 5 11 / 92 96 - 99 - 22 69<br />

lisa.mundzeck@fh-hannover.de<br />

http://www.ifbb-hannover.de/<br />

Michigan State University<br />

Department of Chemical<br />

Engineering & Materials Science<br />

Professor Ramani Narayan<br />

East Lansing MI 48824, USA<br />

Tel. +1 517 719 7163<br />

narayan@msu.edu<br />

7. Biowerkstoff-Kongress<br />

International Conference<br />

on Bio-based Materials<br />

8–10 April 2<strong>01</strong>4, Maternushaus, Cologne, Germany<br />

Organiser<br />

Venue & Accomodation<br />

Maternushaus Cologne, Germany<br />

Kardinal-Frings-Str. 1–3, 50668 Cologne<br />

+49 (0)221 163 10 | info@maternushaus.de<br />

HIGHLIGHTS FROM EUROPE: Bio-based Plastics and Composites<br />

– Biorefineries and Industrial Biotechnology<br />

1 st Day (8 April 2<strong>01</strong>4): Policy and Industry<br />

• Policy & Strategy<br />

• Biorefineries in Europe<br />

• Innovation Award (6 presentations)<br />

2 nd Day (9 April 2<strong>01</strong>4): Industry<br />

• Industrial Biotechnology & Bio-based building blocks<br />

• Bio-based plastics & polymers<br />

• Bio-based Composites<br />

3 rd Day (10 April 2<strong>01</strong>4): Science<br />

• Science & Start-ups<br />

Book now<br />

10% reduction – enter code bio-based<br />

during your booking.<br />

www.nova-institute.eu<br />

Contact<br />

Dominik Vogt<br />

Exhibition, Partners,<br />

Media partners, Sponsors<br />

+49 (0)2233 4814-49<br />

dominik.vogt@nova-institut.de<br />

www.bio-based.eu/conference<br />

bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9 45


Companies in this issue<br />

Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />

Agrana Starch Thermoplastics 43<br />

AIMPLAS 5<br />

Aphios Corporation 6<br />

API 43<br />

Arkema 21<br />

BASF 13<br />

Bio4Pack 27<br />

Biopolynov 45<br />

Biotec 14 44<br />

BPI - The Biodegradable Products Institute 45<br />

Braskem 11<br />

Celabor 22<br />

Center for Bioplastics and Biocomposites 28<br />

CONAI 14<br />

Coperion 22<br />

Corbion Purac 10, 16 43<br />

DSM 18<br />

DuPont 43<br />

Ecovative Design 29<br />

Erema 10 44<br />

European Bioplastics 9, 10 45<br />

Evonik Industries 7 43, 47<br />

Extruline Systems 5<br />

FKuR 10 2, 43<br />

Flanders Plast Vision 22<br />

Floreon 10<br />

Ford 3, 15<br />

Fraunhofer ICT 10<br />

Fraunhofer IVV 10<br />

Fraunhofer LBF 22<br />

Fraunhofer UMSICHT 45<br />

Grabio Greentech Corporation 44<br />

Grafe 43, 44<br />

GreenTech 33<br />

Hallink 44<br />

Hanover University 13<br />

Helmut Lingemann 8, 9<br />

Huhtamaki Films 44<br />

Institut for Bioplastics & Biocomposites (IfBB) 9, 10, 34 45<br />

Institut für Kunststofftechnik 45<br />

Institute for Plastics Processing (IKV) 22<br />

Jinhui ZhaoLong High Tech 28 43<br />

KACO 20<br />

Kingfa 43<br />

Kuender 8<br />

Lessonia 6<br />

Limagrain Céréales Ingrédients 44<br />

Looplife 10<br />

Mercedes 3, 19<br />

Metabolix 10<br />

Metzerplas 5<br />

Michigan State University 10 45<br />

Minima Technology 44<br />

Mitsubishi Chemical 6<br />

narocon 45<br />

NaturePlast 43<br />

NatureWorks 10, 22<br />

Natur-Tec 43<br />

nova-Institut 5, 45<br />

Novamont 14 44, 48<br />

Organic Waste Systems 5<br />

Passive House Institute 25<br />

Pharmafilter 3, 8, 30<br />

Plastic Suppliers 44<br />

plasticker 7<br />

polymediaconsult 45<br />

PolyOne 10 43, 44<br />

Polytechnic Institute (Milan) 14<br />

President Packaging 44<br />

ProTec Polymer Processing 44<br />

PSM 44<br />

Rhein Chemie 44<br />

Roechling Automotive 10, 16<br />

Roquette 44<br />

Saida 44<br />

Schüco 25<br />

Sealed Air Corporation 29<br />

Shandong Fuwin 20, 43<br />

Shenzhen Esun Industrial 43<br />

Showa Denko 43<br />

Sidaplax 10 44<br />

Sulzer Chemtech 10<br />

Supla 8<br />

Synprodo 10, 26<br />

Taghleef Industries 10 44<br />

Technical University Berlin 9<br />

TianAn Biopolymer 44<br />

Tianjin Glory Tang 10<br />

Uhde Inventa-Fischer 10 44<br />

UL International 45<br />

University of Hanover 12<br />

Volkswagen 3, 20<br />

WinGram 43<br />

Wuhan Huali 7<br />

Xinfu Pharm 43<br />

Zandonella 26 1<br />

Roquette 34<br />

Saida 59<br />

Seemore New Materials 59<br />

ShanDong DongCheng 32<br />

Shandong Fuwin New Material Co 27, 58<br />

Shanghai Disoxidation 33<br />

Shenzhen Esun Industrial 58<br />

Showa Denko 58<br />

Sidaplax 59<br />

Siemens 37<br />

Solvay 31, 42<br />

Supla 13, 38<br />

Swiss Fed. Lab. f. Mat. Sc.+ Techn. 44<br />

Synbra 36<br />

Taghleef Industries 59<br />

Tecnaro 10, 12, 34<br />

Tecniq 36<br />

Texchem 30<br />

TianAn Biopolymer 59<br />

TPG 7<br />

Uhde Inventa-Fischer 15, 60<br />

UL International 60<br />

Univ. Modena + Reggio Emilia 26<br />

Univ. Pisa 26, 28<br />

Univ. Stuttgart IKT 60<br />

Wei Mon 59<br />

Weihenstephan Univ. App. Sc. 19<br />

Wifag Polytype 5<br />

WinGram 58<br />

Wuhan Huali 35, 59<br />

WWF 6<br />

Xinfu Pharm 58<br />

Zejiang Huju GreenWorks 31<br />

Editorial Planner 2<strong>01</strong>4<br />

<strong>Issue</strong> Month Publ.-Date<br />

edit/ad/<br />

Deadline<br />

02/2<strong>01</strong>4 Mar/Apr 07.04.14 07.03.14 Thermoforming<br />

(Rigid packaging)<br />

Editorial Focus (1) Editorial Focus (2) Basics Fair Specials<br />

Polyurethanes /<br />

Elastomers<br />

Polyurethanes<br />

Chinaplas &<br />

Interpack Preview<br />

03/2<strong>01</strong>4 May/Jun 02.06.14 02.05.14 Injection moulding Thermoset Injection Moulding Chinaplas &<br />

Interpack Review<br />

04/2<strong>01</strong>4 Jul/Aug 04.08.14 04.07.14 Bottles /<br />

Blow Moulding<br />

05/2<strong>01</strong>4 Sept/Oct 06.10.14 06.09.14 Fiber / Textile /<br />

Nonwoven<br />

06/2<strong>01</strong>4 Nov/Dec <strong>01</strong>.12.14 <strong>01</strong>.11.14 Films / Flexibles /<br />

Bags<br />

Fibre Reinforced<br />

Composites<br />

Toys<br />

Consumer<br />

Electronics<br />

PET<br />

Building Blocks<br />

Sustainability<br />

Subject to changes<br />

www.bioplasticsmagazine.com Follow us on twitter! Be our friend on Facebook!<br />

www.facebook.com/bioplasticsmagazine<br />

46 bioplastics MAGAZINE [<strong>01</strong>/14] Vol. 9


VESTAMID® Terra<br />

High Performance Naturally<br />

Technical biobased polyamides which achieve<br />

performance by natural means<br />

VESTAMID® Terra DS (= PA1<strong>01</strong>0) 100% renewable<br />

VESTAMID® Terra HS (= PA610) 62% renewable<br />

VESTAMID® Terra DD (= PA1<strong>01</strong>2) 100% renewable<br />

• Outstanding mechanical and physical properties<br />

• Same performance as conventional engineering polyamides<br />

• Significant lower CO 2<br />

emission compared to petroleum-based polymers<br />

• A wide variety of compound solutions are available<br />

www.vestamid-terra.com


A real sign<br />

of sustainable<br />

development.<br />

There is such a thing as genuinely sustainable<br />

development.<br />

Since 1989, Novamont researchers have been working<br />

on an ambitious project that combines the chemical<br />

industry, agriculture and the environment: “Living Chemistry<br />

for Quality of Life”. Its objective has been to create products<br />

with a low environmental impact. The result of Novamont’s<br />

innovative research is the new bioplastic Mater-Bi ® .<br />

Mater-Bi ® is a family of materials, completely biodegradable and compostable<br />

which contain renewable raw materials such as starch and vegetable oil<br />

derivates. Mater-Bi ® performs like traditional plastics but it saves energy,<br />

contributes to reducing the greenhouse effect and at the end of its life cycle,<br />

it closes the loop by changing into fertile humus. Everyone’s dream has<br />

become a reality.<br />

Living Chemistry for Quality of Life.<br />

www.novamont.com<br />

Visit us<br />

at K 2<strong>01</strong>3<br />

in Dusseldorf,<br />

Germany,<br />

at Booth E09,<br />

Hall 06<br />

Within Mater-Bi ® product range the following certifications are available<br />

The “OK Compost” certificate guarantees conformity with the NF EN 13432 standard<br />

(biodegradable and compostable packaging)<br />

6_2<strong>01</strong>3

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