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Vol. 2 ISSN 1862-5258<br />
Special editorial Focus:<br />
Bottles, Labels, Caps | 10<br />
02 | 2007<br />
bioplastics magazine<br />
Bioplastics vs. agricultural land | 36<br />
Logos, Part 4 | 38
Editorial<br />
dear readers<br />
Some 15 years ago, when the PET bottle really started to take off, the<br />
arguments in its favour were obvious. Compared to glass, the plastic<br />
bottles are lightweight, unbreakable and easy to carry because of their<br />
neck-ring. PET also has certain environmental advantages too - the<br />
lower weight reduces diesel consumption during transport, and PET<br />
melts at a temperature significantly lower than glass, so using less<br />
energy when bottles are initially produced and recycled.<br />
And now one more point can be added to the list of arguments in favour<br />
of plastic bottles. PLA, as an alternative plastic, is made from renewable<br />
resources - mainly starch derived from corn, sugar cane, sugar beet<br />
or even sweet potatoes. Not only is PLA made from products that can<br />
be relatively easily grown and therefore readily renewable, but after its<br />
initial use it can be recycled, composted under certain conditions, or<br />
cleanly incinerated with energy recovery.<br />
A number of beverage and dairy companies are evaluating the use of<br />
this rather new material, or already use PLA for bottle applications.<br />
The special editorial focus in this issue of bioplastics MAGAZINE is on<br />
bottle applications, including the use of bio-sourced and biodegradable<br />
labels and caps. We talked to five of the early pioneers that now use<br />
PLA for their bottles, and asked them about their motivation, their<br />
experiences and their future plans. All five still consider the decision<br />
to go for PLA as the right one.<br />
Those interested to learn more about PLA for bottles,<br />
bioplastic labels and caps, or who wish to discuss<br />
barrier issues, end of life options and many more<br />
detailed aspects than are covered in this issue, are<br />
cordially invited to the 1st PLA Bottle Conference<br />
organised by bioplastics MAGAZINE. We are running the<br />
two-day conference on the 12th and 13th of September in<br />
Hamburg, Germany. Please visit our website for details.<br />
Special editorial Focus:<br />
Bottles, Labels, Caps | 10<br />
02 | 2007<br />
Vol. 2 ISSN 1862-5258<br />
And in this, our fourth issue, you’ll also find more of the<br />
latest bioplastics news, updates on materials, processing,<br />
events and much more – and not only about bottles!<br />
Michael Thielen<br />
Publisher<br />
bioplastics MAGAZINE<br />
Bioplastics vs. agricultural land | 36<br />
Logos, Part 4 | 38<br />
bioplastics MAGAZINE [02/07] Vol. 2
Content<br />
June 02|2007<br />
Editorial 03<br />
News 05<br />
Suppliers Guide 43<br />
Events 45<br />
Applications<br />
Shrink sleeves 24<br />
Non-wovens made from PLA 26<br />
Mulch films made from PLA blends 28<br />
Politics<br />
What’s happening in the New World? 30<br />
From Science & Research<br />
Novel nanostructured polylactides 32<br />
Protein-based plastics 34<br />
Basics<br />
Bioplastics vs. agricultural land 36<br />
Logos Part 4: The Scandinavian „apples“ 38<br />
Glossary 40<br />
Review<br />
PLA hot topic at PETnology Forum 42<br />
Special<br />
Five PLA bottle pioneers 10<br />
Biodegradable caps 18<br />
Processing<br />
Blowing your own PLA bottles 20<br />
Interview: PLA blow moulding 22<br />
Impressum<br />
Publisher / Editorial<br />
Dr. Michael Thielen<br />
Samuel Brangenberg<br />
Layout/Production<br />
Mark Speckenbach, Jörg Neufert<br />
Head Office<br />
Polymedia Publisher GmbH<br />
Hackesstr. 99<br />
41066 Mönchengladbach<br />
Germany<br />
phone: +49 (0)2161 664864<br />
fax: +49 (0)2161 631045<br />
info@bioplasticsmagazine.com<br />
www.bioplasticsmagazine.com<br />
Media Adviser<br />
Elke Schulte, Katrin Stein<br />
phone: +49(0)2359-2996-0<br />
fax: +49(0)2359-2996-10<br />
es@bioplasticsmagazine.com<br />
Print<br />
Tölkes Druck + Medien GmbH<br />
Höffgeshofweg 12<br />
47807 Krefeld<br />
Germany<br />
Print run: 5,000 copies<br />
bioplastics magazine<br />
ISSN 1862-5258<br />
bioplastics magazine is published<br />
4 times in 2007 and 6 times a year<br />
from 2008.<br />
This publication is sent to qualified<br />
subscribers (149 Euro for 6 issues).<br />
bioplastics MAGAZINE is read<br />
in 80 countries.<br />
Not to be reproduced in any form<br />
without permission from the publisher<br />
The fact that product names may not<br />
be identified in our editorial as trade<br />
marks is not an indication that such<br />
names are not registered trade marks.<br />
bioplastics MAGAZINE tries to use<br />
British spelling. However, in articles<br />
based on information from the USA,<br />
American spelling may also be used.<br />
bioplastics MAGAZINE [02/07] Vol. 2
News<br />
New<br />
bioplastic<br />
bottles<br />
with<br />
pearl-lustre effect<br />
Biopearls R.O.J. Jongboom Holding B.V. from<br />
Zetten, The Netherlands is a company specialized<br />
on tailormade bioplastics injection moulding compounds.<br />
Remy Jongboom, Direktor of Biopearls<br />
now introduced bioplastics bottles with a pearllustre<br />
effect. The bottles are stretch blow moulded<br />
from preforms made of a material that is based on<br />
PLA.<br />
“In a cooperation with the Technical University<br />
of Eindhoven, The Netherlands, we could test the<br />
processing of a new formulation of Biopearlscompounds,“<br />
says Remy. “We extruded some sort<br />
of tapes and found out, that, when stretched, the<br />
mechanical properties of the tapes were significantly<br />
increased.“<br />
In cooperation with a company that makes preforms<br />
and PET bottles Remy Jongboom manufactured<br />
the first preforms and 0.5 Litre bottles with<br />
the new Biopearls compound. These bottles had<br />
such a good quality and beautiful appearance that<br />
not long after the first customers asked Biopearls<br />
B.V. for the supply of his new pearl-lustre effect<br />
bottles. The material is a blend of PLA and other<br />
bioplastics materials that is not as brittle as pure<br />
PLA, so that the bottles feature a certain soft touch<br />
effect. The majority of the mix is based on renewable<br />
resources, as Remy puts it. “And not only is the<br />
bottle made of this Biopearls compound, the cap is<br />
injection moulded from a similar material with a<br />
slightly different elasticity for a good seal.“<br />
Ideal applications are the cosmetics and healthcare<br />
sector, as Remy points out, especially for<br />
those neat little bottles you find in hotel rooms.<br />
Other customer requests target applications such<br />
as paraffin oil (lamp oil).<br />
Metabolix and<br />
AMD announce brand<br />
name Mirel TM<br />
and publish an amazing Internet survey<br />
Metabolix, Inc. of Cambridge, Massachusetts, USA, and Archer<br />
Daniels Midland (ADM) headquartered in Decatour, Illinois, USA,<br />
announced that they have named their Joint venture Telles TM , after<br />
the Roman goddess of the Earth. Telles is now building its<br />
first commercial scale plant for the production of PHA in Clinton,<br />
Iowa, USA. This plant is expected to start up in 2008 and will<br />
produce the corn-based polyhydroxyalkanoate at an annual rate<br />
of about 50,000 tons.<br />
The family of high performance natural plastics that are biobased,<br />
sustainable and completely biodegradable, as the company<br />
states, will be marketed and sold under the brand name<br />
Mirel Natural Plastics.<br />
Internet survey<br />
In April of 2007 the US online market research firm InsightExpress<br />
conducted a USA-wide online survey for Telles: Here are<br />
some of the results in brief, detailed results and their interpretation<br />
can be found at www.metabolix.com.<br />
1. 72% of respondents do not know that plastic is made out of<br />
crude oil/petroleum.<br />
2. On average, respondents estimated 38% of plastic material<br />
is recycled (the reality is less than 6%, according to the EPA<br />
(U.S. Environmental Protection Agency)).<br />
3. Nearly 40% (38.1%) of respondents said plastic will biodegrade<br />
under ground, in home compost, in landfills, or in the<br />
ocean (plastic will not biodegrade in any of these environments).<br />
4. After learning that plastic is made from oil and never biodegrades,<br />
half (50.1%) of respondents stated they would be<br />
likely or very likely to pay 5-10% more for a natural, biodegradable<br />
plastic. Only 24% were unlikely/very unlikely to pay<br />
this much more.<br />
“Everyone knows about the reliance on oil and the impact that<br />
petroleum use has on climate change,“ said Jim Barber, President<br />
and CEO of Metabolix. “Similarly, people see a lot of plastic<br />
waste in the form of litter. But the fact that so many people are<br />
unaware that plastic is made from oil and that it will persist in<br />
the environment for thousands of years, shows the need for education<br />
about the impact of plastic on the environment and the<br />
various alternatives made from renewable resources.“<br />
www.biopearls.nl<br />
www.metabolix.com<br />
www.admworld.com<br />
bioplastics MAGAZINE [02/07] Vol. 2
PLA bottle is used for<br />
a Noble cause<br />
Demonstrating its fresh thinking, Blue Lake Citrus<br />
Products, LLC, Winter Haven, Florida, USA, has become<br />
the first company to offer all-natural and organic juice beverages<br />
in bottles made from NatureWorks TM PLA . Explains<br />
Blue Lake president Wade J. Groetsch, the company selected<br />
the bio-based resin from NatureWorks for the material’s<br />
eco-friendly advantages. “We are always researching<br />
new ways to reduce packaging waste and energy in the<br />
production of packaging products such as our new bottle,”<br />
he says.<br />
Since last September, Blue Lake has offered its lines of<br />
Noble All Natural and Noble Organics premium juices in a<br />
clear, 32-oz PLA bottle molded by Consolidated Container<br />
Corp. using an existing, custom mold. Dubbed the “E bottle”<br />
by Blue Lake, the package provides a clarity comparable to<br />
the company’s previous polyethylene terephthalate bottle,<br />
as well as a sufficient oxygen barrier for the products’ 60-<br />
day shelf life. Noble juices are cold-packed, so PLA’s lower<br />
melt index is not an issue during filling. “However, we do<br />
have to control the temperature of the transportation and<br />
warehousing of bottles,” Groetsch relates.<br />
Based on its 2006 sales, Blue Lake estimates that the<br />
switch to PLA will save the fossil-fuel equivalent of burning<br />
114,000 gal of gasoline and will save greenhouse-gas<br />
emissions equivalent to driving a car more than 2.7 million<br />
miles in the U.S.<br />
www.bluelakecitrus.com<br />
www.cccllc.com<br />
This news was previously published in Packaging Digest,<br />
Feb. 2007, © Reed Business Information<br />
DuPont introduces<br />
PLA modifier<br />
FDA-compliant for food packaging<br />
DuPont Packaging has announced expansion of<br />
its DuPont Biomax ® Strong family of polymer additives<br />
to include an FDA compliant grade for food<br />
contact applications. Biomax Strong polymer additives<br />
improve the performance of PLA packaging.<br />
New Biomax Strong 120 is a polymer additive that<br />
toughens PLA packaging materials while maintaining<br />
compliance with food contact requirements in<br />
the United States (FDA), and in Europe. A similar<br />
additive was introduced in August 2006 for non-food<br />
applications. Both grades of Biomax Strong provide<br />
improved toughness performance with minimal reduction<br />
in package clarity.<br />
“Offering a food contact compliant grade of Biomax<br />
Strong gives DuPont a way to help food marketers<br />
take better advantage of an environmentally<br />
preferred solution in packages such as clamshells<br />
used in fresh produce sections,” said Shanna Moore,<br />
global market manager for DuPont Packaging.<br />
“We are firmly committed to developing sustainable<br />
solutions, including solutions that improve the<br />
performance of other sustainable offerings in the<br />
market,” Moore said. “By improving the performance<br />
of bio-based and biodegradable products, Biomax<br />
Strong can help the packaging industry deliver<br />
high performance at a competitive price.”<br />
DuPont – one of the first companies to publicly<br />
establish environmental goals 16 years ago – has<br />
broadened its sustainability commitments beyond<br />
internal footprint reduction to include market-driven<br />
targets for both revenue and research and development<br />
investment. The goals are tied directly to<br />
business growth, specifically to the development of<br />
safer and environmentally improved new products<br />
for key global markets.<br />
www.dupont.com<br />
bioplastics MAGAZINE [02/07] Vol. 2
Plantic raised<br />
£20 million of<br />
new funds<br />
Development project for barrier<br />
resins for plastic bottle applications<br />
Plantic Technologies Limited, from Altona,<br />
Victoria, Australia, a producer of starchbased<br />
packaging, is pleased to announce that<br />
it has raised £20 million of new funds on May<br />
23 on London’s Alternative Investment Market<br />
(AIM). Plantic will trade under the symbol<br />
‘PLNT’<br />
“The new funds will enable us to expand<br />
our range of unique biodegradable plastics.<br />
Our vision is for consumers everywhere to use<br />
Plantic-based products that play a significant<br />
role in reducing the world’s waste problem,”<br />
said Grant Dow, Managing Director and CEO<br />
of Plantic.<br />
Plantic’s proprietary technology is based on<br />
the use of high amylose corn starch sourced<br />
from renewable resources that are not genetically<br />
modifed.<br />
Having developed the core formulations and<br />
initial applications, Plantic aims further to<br />
develop, commercialise and distribute Plantic<br />
® by creating additional applications across<br />
a variety of industry sectors. To that end, the<br />
company has partnered with a number of<br />
plastics and packaging companies jointly to<br />
develop, commercialise and/or market a new<br />
range of applications through its partners’<br />
established manufacturing and distribution<br />
channels.<br />
Among others Plantic has a development<br />
agreement with Visy Industries Pty Ltd in<br />
Australia to develop barrier resins for rigid<br />
injection stretch blow moulded containers<br />
and bottles. The aim will be to use Plantic as<br />
a barrier layer within multi-layer containers<br />
(e.g. bottles and jars) for goods that require<br />
protection from oxygen ingress or carbonation<br />
loss, as in the case of carbonated beverages.<br />
This would allow existing PET bottles<br />
which require a barrier layer to be recycled<br />
without the need first to recover the barrier<br />
material which in itself is not recyclable.<br />
www.plantic.com.au<br />
“Bioplastics in Packaging“<br />
Exhibition at Interpack 2008<br />
Large group exhibition and stage programme announced<br />
Bioplastics and biopackaging will be presented in a large group exhibition<br />
at interpack 2008, to be held from 24-30 April 2008 at the Düsseldorf<br />
Exhibition Centre. With a planned total exhibition area of 1,000 m 2 , the<br />
exhibition space will be more than triple the size of the interpack 2005<br />
„Innovationparc Bioplastics in Packaging“. The organising trade association<br />
European Bioplastics is expecting more than 30 exhibiting companies<br />
and 10,000 trade visitors to attend.<br />
The event represents a global platform to showcase the progress of<br />
the bioplastics industry. European Bioplastics is offering companies<br />
from the entire value chain the opportunity to demonstrate their state of<br />
the art technology development. This includes raw materials, products,<br />
processes and machinery.<br />
The attractiveness for exhibitors, trade visitors and media will be further<br />
enhanced by an interesting supporting programme including podium<br />
discussions and presentations. European Bioplastics will invite<br />
politicians and industry and media representatives to discuss bioplastics<br />
in the context of the sustainable development, climate change and<br />
resource debate. Biobased and biodegradable plastics have shown a<br />
boom-like development in compostable packaging and other applications<br />
in recent years.<br />
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bioplastics MAGAZINE [02/07] Vol. 2
News<br />
Potential of bioplastics – an Internet survey<br />
The German Internet portal “plasticker – the home of plastics“ asks visitors on a monthly basis for their opinion<br />
on different topical questions around plastics and the plastics industry. However this online poll is carried out in the<br />
German language only.<br />
In May 2007 the question was about the expected potential of bioplastics:<br />
“How will demand for and production of bioplastics develop in the coming 10 years?”<br />
A) They will substitute most of<br />
today‘s commodity plastics<br />
6<br />
B) They will play a major role in<br />
many application areas<br />
56<br />
C) They will remain niche<br />
products<br />
35<br />
D) The hype, and with it the<br />
materials, will disappear<br />
3<br />
0% 10% 20% 30% 40% 50% 60%<br />
Here are the results:<br />
The general attitude was one of cautious confidence. A<br />
clear majority of those responding to the survey believe<br />
that in the foreseeable future bioplastics “will play a major<br />
role in many applications“. However only 6 percent believe<br />
that bioplastics have the potential to replace today‘s mass<br />
commodity plastics.<br />
Another significant group, accounting for about 35 percent<br />
of the replies, believes that bioplastics will not move<br />
significantly from their current position as a niche product.<br />
Those who think that bioplastics have no real future were<br />
in a clear minority, at only 3 percent.<br />
The online survey not only asked for the visitor‘s opinion,<br />
but also wanted to know which sector of the industry they<br />
were engaged in. Analysing the responses from this aspect<br />
also produced some very interesting results.<br />
In a nutshell* 74 percent of the raw materials sector<br />
(which is made up of traders and distributors, manufacturers<br />
and compounders, and plastics recyclers) expect a<br />
significant increase in the share of the market taken by<br />
bioplastics. 13 percent even went so far as to say that they<br />
would ultimately hold a dominant position in the market.<br />
This is probably because raw materials traders and manufacturers,<br />
who are sitting at the beginning of the value<br />
chain, have for longer been closely concerned with the<br />
subject than, say, most converters. They have also been<br />
forced to pay more attention to the subject of petroleum<br />
reserves.<br />
Amongst the suppliers of machinery about 50 percent expect<br />
bioplastics to play a major role and 50 percent think<br />
they will remain a niche product. Almost nobody thought<br />
that bioplastics would disappear, neither would they replace<br />
most of today‘s commodities.<br />
The biggest group, i.e the plastics processors and converters,<br />
making up 37 percent of all participants, is the most<br />
sceptical. The responses were: A:0% / B:43% / C:55% / D:2%.<br />
This could be put down to the fact that most of them have<br />
had no practical experience with bioplastics and have not<br />
been so closely concerned with the subject. Nevertheless<br />
only 2 percent of them said that they saw no long-term future<br />
for bioplastics<br />
As this online poll was only carried out in the German language,<br />
bioplastics MAGAZINE plans to expand the survey and<br />
ask all our readers and visitors to bioplasticsmagazine.com<br />
from around the world to respond to the same questions in<br />
the English language. From the beginning of June until the<br />
end of August you can give us your opinion on this question<br />
at www.bioplasticsmagazine.com/poll<br />
bioplastics MAGAZINE will publish the results of this global<br />
survey in the next issue.<br />
* all detailed results of the recent German poll can be reviewed at<br />
www.plasticker.com (in German and English language).<br />
bioplastics MAGAZINE [02/07] Vol. 2
Standard products can be found anywhere,<br />
but only at K can you find real innovations<br />
– unique in variety and quality. 3,000<br />
exhibitors from 50 countries provide a professional<br />
pool of innovation, from which<br />
you can create tailor-made solutions for<br />
your business. Be inspired – and turn your<br />
ideas into good business propositions,<br />
face-to-face with the best in the industry.<br />
K2007<br />
International Trade Fair<br />
No. 1 for Plastics and<br />
Rubber Worldwide<br />
Düsseldorf, Germany<br />
24 – 31 Oct. 2007<br />
MACHINERY<br />
AND EQUIPMENT<br />
SEMI-FINISHED PRODUCTS, TECHNICAL<br />
RAW MATERIALS<br />
PARTS AND<br />
AND AUXILIARIES<br />
REINFORCED PLASTICS<br />
SERVICES<br />
Messe Düsseldorf GmbH<br />
Postfach 1010 06<br />
40001 Düsseldorf<br />
Germany<br />
Tel. +49(0)211/45 60-01<br />
Fax +49(0)211/45 60-6 68<br />
www.messe-duesseldorf.de
Special<br />
Five<br />
PLA bottle<br />
pioneers<br />
BIOTA Brands of America, Inc. /<br />
Planet Friendly Products<br />
Telluride, Colorado, USA<br />
David M. Zutler, Founder and CEO<br />
Belu Mineral Water, London, UK<br />
Reed Paget, Co-founder<br />
and Managing Director<br />
Ihr Platz GmbH + Co. KG, Osnabrück, Germany<br />
Bernd Merzenich, former Consultant<br />
now: Managing Director of<br />
german bioplastics GmbH & Co. KG<br />
Plus One Water, Inc., Montreal, Canada<br />
Michael Keeffe, CEO<br />
Naturally Iowa, LLC, Clarinda, Iowa, USA<br />
William Horner, President<br />
A<br />
significant number of companies have launched beverages<br />
in PLA bottles in recent years. bioplastics<br />
MAGAZINE spoke to the responsible people at five of<br />
the early pioneers in this field about their motivation, their<br />
experience and their future plans.<br />
Motivation<br />
Being asked how they came to the idea of using PLA as a<br />
bottle material, David Zutler of BIOTA said, that as early as<br />
1996 he was already looking for a better material. In May<br />
of 2002 he read an article in the local Telluride newspaper<br />
how plastic bottles were helping to destroy the environment<br />
of our planet. Just shortly after Cargill and Dow opened<br />
their production plant for PLA in Blair, Nebraska, USA, he<br />
and Planet Friendly TM Products, a bioplastics consultancy<br />
firm also founded by him, contacted Cargill Dow (now NatureWorks<br />
LLC) and with the support of Cargill Dow, Husky<br />
and SIG Corpoplast they started the rollout of the World‘s<br />
First PLA preforms, bottles, and labels with the intention of<br />
“helping change the world as far as plastics is concerned,“<br />
as David puts it.<br />
A similar idea drove Bill Horner of Naturally Iowa, when<br />
his company established the guidelines for creating a new<br />
all natural or even all organic dairy company. In October of<br />
2005 they saw a major shift in consumer demand for organic<br />
products. “We decided to make a shift in our business plan<br />
as well, and with regard to packaging we wanted to set ourselves<br />
apart from all the others,“ says Bill, “and the only real<br />
breakthrough in plastics packaging that we could see was<br />
PLA“. Two years earlier they had contacted Cargill Dow, just<br />
an hour and a half down the road, and enjoyed the benefit<br />
of earlier experience gained with the help of BIOTA bottles.<br />
Naturally Iowa uses Norland blow moulding equipment for<br />
their in-house production of the bottles.<br />
London (UK) based Belu Mineral Water is an environmental<br />
initiative which contributes 100% of its net profits to clean<br />
water projects. Working with the charity WaterAid, every bottle<br />
of Belu water purchased in the UK provides someone in<br />
India or Africa with clean water for one month. About five<br />
years ago Belu contacted the Rocky Mountain Institute, an<br />
environmental organisation in the USA. “I discussed with<br />
them how to make a low impact bottle to create a more sus-<br />
10 bioplastics MAGAZINE [02/07] Vol. 2
Special<br />
tainable product,“ says Reed Paget of Belu, “and they suggested<br />
we use a sort of biopolymer“. As PLA was not ready<br />
for commercial use in those days, Belu started the launch of<br />
Belu Mineral Water with glass bottles. After the successful<br />
launch of BIOTA, Belu finally introduced in May 2006 the Belu<br />
PLA bottle, using preforms purchased from Planet Friendly<br />
Products. The bottles are blown on SIG Corpoplast stretch<br />
blow moulding machines and filled at Brecon Mineral Water<br />
in a factory located near Llandeilo in South Wales.<br />
To set up a socially responsible water company was the<br />
idea with which Michael Keeffe of +1Water in Canada approached<br />
co-founders Paul and David Smith a few years<br />
ago. “We wanted to contribute 20% of our profits towards<br />
water development organisations like WaterCan and Ryan‘s<br />
Well Foundation in Canada and Operation Hunger in South<br />
Africa,“ says Michael. These non profit organisations help<br />
provide communities in need with access to safe, clean water.<br />
“Unlike most people living in North America and Europe,<br />
there are over one billion people in the world that do not<br />
have access to safe drinking water,“ he adds. Within a few<br />
months they found out about PLA and decided it would provide<br />
the environmentally responsible component to round<br />
out the socially responsible dimension of the product. With<br />
the technical support of NatureWorks, Krones and Ben Benedict<br />
at Iroquois Water +1Water was able to launch their PLA<br />
+1 bio-bottle last January. +1 bottles natural spring water<br />
from a family owned spring called “Bell Falls“ in Quebec.<br />
Iroquois Water, use Krones equipment, to blow and fill the<br />
bottles for +1Water.<br />
Bernd Merzenich (today head of german bioplastics) has<br />
acted as a consultant to different companies with regard<br />
to the production and marketing of organic food for about<br />
25 years. In recent years he has also been keen to use bioplastics<br />
as a packaging material for organic produce. When<br />
working for the German drugstore chain “Ihr Platz“, establishing<br />
a new range of organic food products and natural<br />
cosmetics, he came across the BIOTA bottles. He found<br />
exciting the idea of using PLA as a packaging material for<br />
a pilot project of wellness beverages with a strong appeal<br />
to health and environment, which Ihr Platz was planning to<br />
introduce. When Hycail (today with Tate&Lyle) could not con-<br />
bioplastics MAGAZINE [02/07] Vol. 2 11
Special<br />
tinue their initial support Bernd started to cooperate with<br />
NatureWorks, “from whom we received considerable support<br />
towards sourcing and processing the material.“ The<br />
Luxembourg based company Plastipak supplied the preforms,<br />
made on Husky equipment, to the German mineral<br />
water company Quellenhof who blow-moulded and filled the<br />
bottles for Ihr Platz .<br />
Planet friendly cap<br />
Summing up the first part of our conversation, we can say<br />
that all of the parties interviewed consider their decision regarding<br />
the use of PLA as a material for their bottles as the<br />
right one. David Zutler: “Absolutely the right decision. Petroleum<br />
based plastics are one of the world‘s biggest problems.<br />
Just look at some of the developing countries where<br />
no recycling is in place for PET bottles and where they openly<br />
burn their overloaded landfills.“ Bill Horner: “100 percent<br />
the right decision. We are planning further products to be<br />
packaged in PLA.“ Reed Paget: “Almost any analysis shows<br />
that PLA is the most sustainable option.“ Michael Keeffe:<br />
“At this point in time we are convinced it was the right decision.<br />
We have outlets across three of the Canadian provinces<br />
here, and we are about to expand to the west coast of Canada.“<br />
And even though Ihr Platz recently discontinued selling<br />
the Vitamore wellness drinks, Bernd Merzenich considers<br />
the use of PLA as the right decision. Bernd: “It was good to<br />
make a statement in favour of bioplastics and to be the first<br />
on the German market. However, a drugstore chain is not<br />
a food store and beverages in bottles with, at the moment,<br />
limited barrier properties need a faster turnover.“<br />
Labels and caps<br />
How important are labels and caps from renewable resources<br />
for the companies that sell PLA bottled products?<br />
While the Vitamore and +1Water labels are made of paper<br />
and therefore made from a renewable - and biodegradable<br />
- source, BIOTA, Belu and Naturally Iowa are already using<br />
PLA labels. +1Water is eventually planning to switch to PLA<br />
labels.<br />
When it comes to caps, it‘s the other way round. Ihr Platz<br />
introduced the world‘s first compostable cap, made of<br />
MaterBi which is partly sourced from renewable raw materials.<br />
BIOTA is planning to roll out what David calls a planetfriendly<br />
cap, made of 100% renewables and 100% compostable.<br />
The resin composition is mainly based on PLA. This cap<br />
will be available to other bottlers too, as David points out.<br />
Reed says that “Belu will use a bioplastics cap as soon as<br />
we can find one that will work with our product“. Naturally<br />
Iowa is also interested in caps and “we‘ve been working with<br />
a company in Japan who‘s developing a PLA-blend that will<br />
work on closures,“ says Bill. He is confident of having one<br />
next year. +1Water will move to biobased caps, as soon as<br />
they are there,“ Michael points out.<br />
12 bioplastics MAGAZINE [02/07] Vol. 2
12 - 13 September 2007<br />
1st PLA-Bottle-Conference<br />
possibilities | limitations | prospects<br />
powered by<br />
PLA (Polylactide), a compostable plastic made from renewable<br />
resources such as corn, is a highly topical subject right now,<br />
especially in the light of increasing crude oil prices. The stretch blow<br />
moulded PLA bottles used by Biota or Natural Iowa (USA), Belu (UK),<br />
Vitamore (Germany) and +1water (Canada), as well as reports in<br />
the trade press, have aroused significant interest from the PET and<br />
beverage industry.<br />
Would you like to find out more about the possibilities, limitations and<br />
future prospects of PLA for bottle applications?<br />
That‘s exactly why bioplastics MAGAZINE is organising the 1st PLA<br />
Bottle Conference on the 12 th and 13 th of September 2007 in the Grand<br />
Elysee Hotel in Hamburg, Germany. This 1½ day conference offers a<br />
comprehensive overview of today‘s opportunities and challenges.<br />
Experts from companies such as Purac, Uhde Inventa-Fischer,<br />
Natureworks, Netstal, SIG Corpoplast, Wiedmer, Treofan, Sidaplax,<br />
SIG Plasmax, Doehler, Polyone, Ihr Platz, Coca-Cola, Interseroh, and<br />
more, will share their knowledge and …<br />
…on the afternoon of Thursday September 13th delegates will visit SIG<br />
Corpoplast, the manufacturer of the stretch blow moulding equipment<br />
that is used to produce for example the Biota and the Belu bottles.<br />
€ 850.00<br />
Sponsors<br />
Supported by<br />
There will be sessions covering:<br />
• Raw materials, from corn to PLA<br />
• PLA preform manufacture<br />
• Stretch blow moulding of PLA<br />
• Caps, labels, shrink-sleeves made<br />
from biodegradable plastics<br />
• Barrier solutions for PLA bottles<br />
• Temperature stability of PLA<br />
• Additives, from processing<br />
agents to colorants<br />
• Reports „from the market“<br />
• End of life options, recycling, energy<br />
recovery, composting<br />
More information and registration:<br />
www.pla-bottle-conference.com
Special<br />
Planet Friendly TM bottle<br />
The cost issue<br />
“The higher price of PLA is acceptable to us and should be<br />
acceptable to everyone because the planet is worth it,“ says<br />
David Zutler. And he thinks that the majority of consumers<br />
“who care“ think so too. Eventually, David is convinced, when<br />
the economy of scale kicks in, the price of PLA will drop.<br />
Reed Paget too believes that in the long run, the price of<br />
PLA will come down while petrochemical plastics will become<br />
more expensive. The environmental sustainability is<br />
the starting point for Belu and Reed too thinks that some<br />
consumers would accept a slightly higher price. “However,<br />
we try to be cost effective as much as we can,“ he says.<br />
“I really think the price is dominant and I would like to say<br />
the environmental advantages would outweigh the price“,<br />
says Bill Horner. On the other hand he considers that the<br />
price of PLA today already is almost competitive with PET.<br />
“The price for PET is going higher and higher, and although<br />
we had a fight on the corn prices that was just temporary.<br />
On a long term view the prices for starch are much more<br />
stable“, he adds.<br />
Michael Keeffe doesn‘t feel that the price is a super-critical<br />
factor for the consumer. “As soon as it becomes clear<br />
that it is an environmentally friendly bottle, that seals the<br />
decision for most people,“ Michael explains. „We hope that<br />
the increasing demand for sugar, for example for making<br />
bio-ethanol, does not push the price of PLA up through the<br />
roof, but as of now the price for us is workable“.<br />
“We are talking about environmentally and health conscious<br />
consumers who are willing to accept a premium price<br />
for corresponding items,“ says Bernd Merzenich. “But you<br />
really need a very clear communication strategy with these<br />
products,“ he adds. “You need to be transparent and critical,<br />
and clearly explain what is bio with these materials.“<br />
Barrier properties and heat resistance<br />
As how important do our interview partners consider enhanced<br />
barrier properties and the heat resistance of PLA?<br />
None of them is currently packaging products that need<br />
a container with elevated temperature resistance. However,<br />
all confirm that for certain applications such as hot-filled<br />
juices etc. enhanced thermal properties will be needed.<br />
When it comes to barrier, the picture looks different. Reed<br />
Paget thinks that, as for other plastic materials, PLA also<br />
needs an enhanced barrier. Michael Keeffe confirms this<br />
thought, for their current product, flat water, improved barrier<br />
properties will provide greater production and distribution<br />
options. “For the long term viability of PLA for other<br />
products, such as carbonated beverages or fruit juice, we<br />
will also need a barrier against CO 2<br />
and Oxygen“.<br />
Bernd Merzenich: “PLA definitely needs to be improved<br />
regarding its barrier properties and heat stability. For still<br />
water the presently available level of material and technology<br />
is OK, on the premise that the turnover at the point of<br />
sale is sufficiently fast. But for more sophisticated uses in<br />
the beverage and food industry we need material improvements<br />
by developing new bioplastic compounds on the basis<br />
of PLA, as well as by using additives, coatings or the like,<br />
such as, for instance, the SIG Plasmax plasma coating process<br />
or a bioplastic barrier resin for multilayer applications,<br />
which has been announced by Plantic.“<br />
Naturally Iowa, cold filling their products, are very satisfied<br />
with the quality of the PLA they get from NatureWorks today.<br />
Their milk is a short shelflife product and is sold through the<br />
cold chain, so that up to now better barrier or temperature<br />
properties have not been needed.<br />
David Zutler however, is already active in this field. Together<br />
with strategic partners Danimer, and the Australian<br />
packaging and recycling group Visy, BIOTA is developing a<br />
Planet Friendly bottle, that is made of PLA plus an additive<br />
which enhances the elasticity properties, and will help provide<br />
some additional properties as well. “Our goal is to have<br />
such a bottle within the next six months, and in addition to<br />
that, to have a bottle material with barrier properties even for<br />
use with CSD (carbonated soft drinks) and resistant to water<br />
vapour, heat, and O 2<br />
ingress within a year,“ says David.<br />
14 bioplastics MAGAZINE [02/07] Vol. 2
Special<br />
End-of-life options<br />
There has to be a way for consumers, and recyclers to<br />
easily tell the difference between biobased products and<br />
petroleum based products. “All our bottles say Planet<br />
Friendly. When the consumer, and recycler, see those<br />
words, they know what they are,“ says David. “My number<br />
one end-of-life option is what I would call reclaiming,“ he<br />
adds. „Reuse or recycle to bottles or into other products<br />
such as garden pots etc. And my second favourite is energy<br />
recovery. PLA burns cleanly and can help augment the use<br />
of fossil fuels (petroleum, coal, etc.) in power plants, helping<br />
to generate greenhouse neutral energy and alleviate the<br />
devastating problem of burning plastics in landfills.“<br />
Reuse and recycle are also the preferred end-of-life options<br />
for Reed Paget, making up the top four together with<br />
composting/energy recovery, and with landfill as the last option.<br />
Belu is currently working on life cycle assessments and<br />
even home composting seems to be a viable option instead<br />
of shipping the waste across town to a waste facility. “I did it<br />
myself in my backyard,“ says Reed, “and if you know how to<br />
do it, it works.“<br />
“Our +1 bio-bottle is clearly stamped both with the number<br />
seven recycling logo as well as the word ‚compostable‘ informing<br />
consumers that they have disposal options, says<br />
Michael Keeffe. +1Water is working (with a number of recyclers)<br />
on a pilot project with a company called “Turtle Island<br />
Recycling“ in Ontario focused on both bioplastics recycling<br />
and composting. And when, after reuse or recycling, PLA<br />
ends up in an incineration plant, because it‘s not petrochemical<br />
based it is also more environmentally friendly as well.<br />
Today, Naturally Iowa‘s percentage of the market is rather<br />
small, so that the bottles end up in a landfill where they<br />
degrade. But Bill Horner says that first attempts are being<br />
made to set up industrial composting facilities.<br />
Bernd Merzenich says: “To be pragmatic, just now I only<br />
see incineration with energy recovery as meaningful. From<br />
an LCA point of view I would favour thermal disposal, because<br />
it generates CO 2<br />
neutral energy. Last but not least,<br />
looking at the present hype regarding biofuels, the aspect<br />
of eco-friendly energy recovery from bioplastics should be<br />
stressed: Bioplastics create a much higher added value<br />
from agricultural raw materials than biofuels and can generate<br />
a similar output of CO 2<br />
neutral energy when incinerated<br />
at their end of life.“ As soon as barrier properties and<br />
heat resistance are improved, biodegradability as an option<br />
will anyway become much less an issue, Bernd adds. “Personally<br />
I don‘t believe in biodegradability unless it has practical<br />
reasons,“ he says. “For instance when you pack fruit<br />
and vegetables you can compost the waste together with the<br />
packaging, or when bioplastic shopping bags are available<br />
they can be used to collect and compost organic waste.“<br />
Future prospects<br />
BIOTA will remain a bottled water company, but Planet<br />
Friendly is going to work with different manufacturers to<br />
promote PLA and other bio-based packaging. “I would<br />
rather help other manufacturers with the different additives<br />
and different material properties that are being developed,“<br />
David says.<br />
Belu as well as +1Water have further projects on the drawing<br />
board. However, “they are not too far down the road as of<br />
yet“, Reed Paget points out.<br />
“So far we just produce the 0.5 gallon milk bottles,“ says<br />
Bill Horner, “but starting in June we are going to be bottling<br />
milk in 10 and 12 oz. and possibly even 8 oz ‚grab-and-go‘<br />
containers, and in the fall we start with a probiotic drinkable<br />
yoghurt with an extended life that we are really excited<br />
about,“ he proudly adds. All of the products will be packaged<br />
in PLA, the single serve units with a PLA shrink sleeve.<br />
Bernd Merzenich thinks that for many companies in Germany<br />
it is a drawback to start using PLA as long as there is<br />
only one supplier. First of all, if a company wants to introduce<br />
PLA, they can‘t get the material, and secondly, no one<br />
wants to rely on a single source. And David Zutler says that<br />
governments should support companies that want to build<br />
up production capacities.<br />
bioplastics MAGAZINE [02/07] Vol. 2 15
Special<br />
Final remarks<br />
David Zutlers says: “The big beverage companies in the world will not<br />
convert to PLA bottles unless they are required to do so.“ They may be<br />
pushed to do so because of economic advantages, or by law. “And governments<br />
should consider, when the barrier and heat deflection problems that<br />
we are working on have been solved, making the use of PLA or other biobased<br />
packaging a requirement.“<br />
Reed Paget wants to stress that all the companies involved today are really<br />
pioneers that have taken a significant financial risk and that deserve to<br />
be acknowledged and thanked. “Waste in our modern lifestyle is a growing<br />
and significant issue, as is energy consumption,“ he says, “and biopolymers<br />
are offering a way to maintain a fairly modern lifestyle with the prospect of<br />
not leaving a legacy of pollution which the planet cannot sustain.“<br />
Michael Keeffe is very excited about the potential for PLA particularly<br />
given growing consumer demands for more environmentally sustainable<br />
and socially responsible products. Our PLA water bottle is both of these,<br />
a healthier choice for the environment and a healthier choice for the consumer<br />
while helping others get clean water too:<br />
Bill Horner is very happy “that we made the decision early on and have<br />
stuck with it through all the research and development rollercoaster that<br />
we‘ve been through. But it‘s been worth it all.“ Not only is Bill very pleased<br />
with what they have achieved so far, they are also willing to share the lessons<br />
they have learned with other dairy companies around the world.<br />
Bernd Merzenich, with a very focused view on the German beverage<br />
packaging situation, thinks it essential that government accepts PLA as<br />
an ecologically favourable packaging material so that PLA bottles are exempted<br />
from the mandatory deposit fee laid down in the German Packaging<br />
Ordinance. “If this can be achieved, it will really be a breakthrough for PLA<br />
because we then enter into a new environmental quality. That will make<br />
PLA attractive for a mass market,“ he says.<br />
The very final words in this talk with major bioplastics users are from<br />
our cover-girl Janina (11). She says: “In school we learned that crude oil<br />
is a limited resource and that alternative energies such as wind or solar<br />
power can save oil. I didn‘t know that plastics were made from oil and I like<br />
the idea that plastics can be made from plants.“ And her little sister Lena<br />
(6) adds: “Michael Thielen said, microorganisms that live in the compost<br />
heap eat the bioplastics. But I can‘t even imagine what microorganisms<br />
look like!“<br />
www.biotaspringwater.com<br />
www.ihrplatz.de<br />
www.belu.org<br />
www.plusonewater.ca<br />
www.naturallyiowa.com<br />
16 bioplastics MAGAZINE [02/07] Vol. 2
Biodegradable Plastics<br />
in Packaging Applications<br />
Early bird offer – book before<br />
July 13, 2007 and save 10%!<br />
see reverse for more details<br />
Thursday, September 13<br />
Friday, September 14<br />
2007<br />
Doubletree Hotel Chicago<br />
O’Hare Airport – Rosemont<br />
Chicago, IL, US<br />
Commercially viable bioplastics for sustainable packaging applications<br />
Two day IntertechPira conference plus half day pre-conference workshop<br />
With presentations<br />
from leading companies:<br />
BioBag<br />
BIOTA/Planet Friendly Products<br />
Blue Lake Citrus Products<br />
Ciba Expert Services<br />
Clarifoil<br />
Earthcycle<br />
Environmental Packaging<br />
International<br />
EPI Environmental Products<br />
Excellent Packaging & Supply<br />
Gilbreth Packaging<br />
G.S. Polymer Consultants<br />
Innovia Films<br />
Kraft Foods Global<br />
Metabolix<br />
Michigan State University<br />
Microsoft<br />
MonoSol<br />
NNZ – The Packaging Network<br />
Naturally Iowa<br />
NatureWorks<br />
Plantic Technologies<br />
Whole Foods Market<br />
Wild Oats Natural<br />
Including presentations from:<br />
Media Partner:<br />
Plus!<br />
Don’t miss the<br />
pre-conference workshop on<br />
Wednesday, September 12,<br />
2007:<br />
New Markets<br />
for Bioplastics
Special<br />
Biodegradable caps<br />
Last year, in combination with the “Vitamore“<br />
PLA bottle sold by the German drugstore chain<br />
“Ihr Platz“, the Swiss company Wiedmer AG from<br />
Näfels in the Canton of Glarus introduced the world‘s first<br />
biodegradable closure for beverage bottles. Wiedmer AG<br />
focuses on tooling and mould-making parts as well as the<br />
production of injection moulded parts.<br />
The BioCap ® is a 3.6 gram standard PCO-28 cap with<br />
tamper-evident ring. The material is a compostable<br />
Mater-Bi polymer from Novamont, Italy. The geometry of<br />
the cap and the elastic Mater-Bi material allow the production<br />
of a perfectly leak-proof bottle.<br />
With oxygen permeability very much in mind Wiedmer<br />
asked the Fraunhofer Institute for Process Engineering<br />
and Packaging IVV in Freising, Germany, to carry out permeation<br />
tests. All BioCaps exhibited an oxygen permeation<br />
rate of 0.035-0.039 (cm3/d bar) - a comparable HDPE<br />
cap showed 0.027 to 0.032 (cm3/d bar). The tests were<br />
performed in line with DIN Standard 53380, part 3.<br />
Initially Wiedmer manufactured the caps on a two-cavity<br />
prototype mould. They were totally satisfied with the<br />
results and the very good processability of the MaterBi<br />
material. Detlef Wellner, Marketing and Sales Director<br />
at Wiedmer would like to stress that Wiedmer is grateful<br />
to Novamont of their support in finding the right MaterBi<br />
recipe, the mould design (shrinkage behaviour) and the<br />
processing parameters. Wiedmer have now built a 16-cavity<br />
production mould, that is currently on test. Wiedmer<br />
manufactures the BioCaps on a Netstal injection moulding<br />
machine. “And the caps were not exclusively developed<br />
for the Vitamore bottle“ says Detlef Wellner, “anyone looking<br />
for a compostable closure for PLA bottles can have<br />
them.“<br />
Wiedmer AG puts great emphasis on protecting the environment.<br />
One example of ongoing production process<br />
improvements is the successful reduction of the amount<br />
of waste thanks to the recycling of injection mouldings.<br />
In the manufacture of plastic closures the use of a hot<br />
runner system has reduced waste to practically zero. The<br />
consequence is that the energy required for manufacturing,<br />
and the emissions produced, have been considerably<br />
reduced. In addition, all injection moulding production<br />
takes place within a closed loop system, including heat<br />
recovery. This heat is then re-used for heating the entire<br />
company site. Environmental protection, which has been<br />
actively integrated into the optimisation of Wiedmer‘s operating<br />
procedures by their employees, offers potential for<br />
further cost reductions.<br />
www.wiedmer-plastic.com<br />
18 bioplastics MAGAZINE [02/07] Vol. 2
Internationales Symposium<br />
»Werkstoffe aus Nachwachsenden<br />
Rohstoffen«<br />
Internationaler Kongress<br />
zu Pflanzenöl-Kraftstoffen<br />
Europäische Kooperationsbörse<br />
Fachtagung Biogas<br />
www.narotech.de
Processing<br />
Blowing Your Own<br />
Reprinted in part with permission of Water Conditioning<br />
& Purification Magazine, © September<br />
2006. Any reuse or republication, in part or whole,<br />
must be with the written consent of the Publisher.<br />
Publicom, Inc., Tucson, Arizona USA<br />
www.norlandintl.com<br />
Article contributed by<br />
Bruce Kucera,<br />
Vice President of Norland<br />
International Inc.,<br />
Lincoln, Nebraska, USA<br />
PLA Bottles<br />
For the time being, PLA as a raw material<br />
for bottle applications is suitable rather for<br />
niche markets and certain filling goods than<br />
for the big CSD (carbonated soft drinks) etc. But<br />
even for such niche markets, supplied by small to<br />
medium-sized bottling companies on-site manufacturing<br />
of PLA or PET bottles has advantages.<br />
Why take a do-it-yourself approach? Because it<br />
pays!<br />
Manufacturing your own bottles on site can yield<br />
a dramatic cost-per-bottle savings, primarily by<br />
cutting out the shipping costs. Current petroleum<br />
pricing negatively impacts transportation costs,<br />
of course. In some cases, bottlers can save up to<br />
50 percent on their bottles by making their own,<br />
Actual savings varies business by business, based<br />
on distance from suppliers, and other considerations.<br />
On-site manufacturing also helps alleviate inventory<br />
problems. When bottlers make their own,<br />
they minimize the required warehouse space. Additionally,<br />
they eliminate concerns about the timing<br />
of vendor deliveries. Preform purchase and<br />
shipping issues, of course, remain the same.<br />
Blow molding machines specifically designed<br />
for use by the small- to medium-sized bottling<br />
companies are now available. No longer are the<br />
bigger operations the only ones who can benefit<br />
from making their own bottles.<br />
20 bioplastics MAGAZINE [02/07] Vol. 2
Processing<br />
PLA Bottle-making<br />
The technology of PLA-preform making was described in bioplastics<br />
MAGAZINE issue 02/2006. Here, we address the issues<br />
involved in designing a blow molder capable of manufacturing<br />
bottles from PLA preforms. We also look at the added benefits<br />
to the bottlers who use PLA bottles in the business.<br />
There is little difference between PLA and PET bottles in<br />
terms of appearance and performance. In most cases, what<br />
you can do with PET, you can do with PLA, including shape,<br />
size, color and other design features. Customers will not know<br />
the bottle is made of PLA unless you tell them. The difference<br />
is found in material characteristics. Hence, the requirement<br />
for PLA-specific blow molders, which must address special issues.<br />
Traditional PET blow molders cannot handle PLA successfully.<br />
The primary issue is one of material temperature, which<br />
includes both preheating of the preforms before entering the<br />
stretch-molding process, and subsequent cooling down of<br />
blown bottles.<br />
PLA preforms must be heated to approximately 75°C before<br />
entering the stretch-molding process, as opposed to 100°C for<br />
PET. At the higher temperature, PLA starts to shrink, so the<br />
typical PET blow molder is problematic with PLA.<br />
While PLA preforms heat up easily, the material is difficult<br />
to cool down; bottle deformation results when they are not<br />
adequately cooled before they exit the molds. Therefore, the<br />
freshly blown bottles must be cooled down quickly before they<br />
leave their molds. Consequently, special cooling techniques,<br />
therefore, must be designed and built into each mold.<br />
Additionally, precision process control over all heating lamps<br />
and blowing sequences is a must. Fluctuation of a degree or<br />
two either way leads to finished bottle quality issues. PLA‘s<br />
temperature sensitivity also requires enhanced airflow to ensure<br />
even heating in the heat tunnels. When multiple heat tunnels<br />
are involved, it is critical to precisely compensate for potentially<br />
different heat lamps and airflow so that bottles from<br />
each tunnel are consistently heated for optimal performance<br />
in the molds. This ensures a consistently high quality finished<br />
bottle.<br />
Precision control over air pressure and flows are equally<br />
critical. This technology helps move PLA material down from<br />
the preform‘s neck area to the bottom to make sure desired<br />
thickness is achieved in the bottle from bottom to top.<br />
Marketing benefits<br />
From a marketing perspective, there are several<br />
key advantages for bottlers to convert to<br />
PLA bottles.<br />
The first is product differentiation. Let‘s face it.<br />
In the case of bottled water for example, there‘s<br />
not much difference between one bottle of water<br />
and another. Brand name, methods of water<br />
purification, and price are points of differentiation.<br />
PLA becomes another point to help bottlers<br />
distinguish their product from their competition,<br />
particularly those still using PET bottles.<br />
The bottled water market often targets a demographic<br />
that prides itself in healthy lifestyles.<br />
Typically, this also includes environmental concern<br />
and a proclivity for "eco-friendly“ products.<br />
PLA offers a tangible environmentally friendly argument<br />
for its use. There‘s publicity to be gained<br />
and media attention to be earned by announcing<br />
a switch to PLA and by promoting product as using<br />
eco-friendly materials.<br />
Following are points about PLA that capture<br />
attention of the market, and result in legitimate<br />
environmental benefits:<br />
1. The production process of NatureWorks PLA<br />
uses 68 percent less fossil fuel resources than<br />
traditional PET plastics. NatureWorks has found<br />
that producing 1,000 bottles from PLA resin requires<br />
33 percent less fossil fuel resources and<br />
emits 42 percent less greenhouse gases than<br />
making 1,000 bottles from PET. (LCA Consultants<br />
Report).<br />
2. PLA is the world‘s first greenhouse-gasneutral<br />
polymer.<br />
Bottlers considering switching from PET preforms<br />
to PLA must be aware that preform selection<br />
and bottle design are critical to producing<br />
high-quality bottles. Make sure your blowmolding<br />
machine supplier approves your perform<br />
supplier and bottle design for optimal performance.<br />
bioplastics MAGAZINE [02/07] Vol. 2 21
Processing<br />
Frank Haesendonckx, Product Manager at SIG Corpoplast<br />
answers a few questions about high speed stretch blowmoulding<br />
of PLA-bottles.<br />
bioplastics MAGAZINE (bM): Can PLA be blowmoulded on standard<br />
equipment?<br />
Frank Haesendonckx: Even though the processing of PLA preforms<br />
and bottles can be implemented on “standard“ machines,<br />
several aspects have to be taken into account to produce bottles<br />
which meet the economical and industrial requirements.<br />
bM: For example?<br />
Interview:<br />
PLA blow<br />
moulding<br />
The first PLA-bottle in the USA,<br />
introduced by Biota from Ouray,<br />
Colorado and the first one in Europe<br />
from Belu, London, UK are stretch<br />
blowmoulded on BLOMAX<br />
machines from SIG Corpoplast,<br />
Hamburg, Germany.<br />
www.sigcorpoplast.com<br />
Frank Haesendonckx: For example the preform geometry: The<br />
behaviour of PLA is different from PET when stretching on a stretch<br />
blow moulding machine. It is therefore essential to adjust the preform<br />
geometry accordingly. We offer our Bottles&Shapes TM - expertise<br />
to help customers design the optimal preform.<br />
bM: What else has to be considered?<br />
Frank Haesendonckx: For optimal preheating in the infrared<br />
oven, the absorption behaviour of PLA requires additional “Carbon-<br />
Black“ additives which are also used in PET. The industry already<br />
provides biodegradable additives for this purpose. The transparency<br />
of the bottle is not or only inconspicuously influenced. Low heating<br />
temperatures are sufficient for PLA preheating. The heating profile<br />
in the oven must be adjusted to the preform geometry and the material<br />
properties.<br />
bM: And what about the actual blowing process?<br />
Frank Haesendonckx: The preblow-pressure for PLA stretch<br />
blowing corresponds to the pressure required for PET. The starting<br />
point for pre-blowing as well as the stretching rate must be adjusted<br />
for PLA.<br />
bM: We often hear about limited mechanical and thermal properties<br />
of PLA bottles?<br />
Frank Haesendonckx: The mechanical properties of PLA, which<br />
still do not meet those of PET, can be compensated for via skilful<br />
bottle design. For example, the stackability can be improved by an<br />
optimized bottle geometry. The thermal properties of PLA can still<br />
not be compared to PET. The bottle shrinkage which already starts<br />
at 45°C can partially be improved by deploying a so-called “relax“<br />
process.<br />
bM: How do you see the future of PLA as a bottle material?<br />
Frank Haesendonckx: PLA will be an increasingly interesting material<br />
for stretch blow moulding due to the rising oil price in the<br />
medium and long term. However, further improvements with regard<br />
to raw material as well as thermal and mechanical properties are<br />
essential.<br />
The main areas of application are still waters, products with short<br />
shelf life and products which are not hot filled.<br />
Further applications are provided if the barrier properties can be<br />
enhanced. A complete separation between material and product<br />
is guaranteed via use of SIG’s PLASMAX inner coating technology<br />
which enables packaging of sensitive beverages or food in PLA and<br />
ensures product quality.<br />
bM: Thank you very much<br />
22 bioplastics MAGAZINE [02/07] Vol. 2
Week 1<br />
Week 2<br />
Week 3<br />
Week 4<br />
BIODEGRADATION PROCESS<br />
EcoWorks ®<br />
www.EcoFilm.com<br />
info@CortecVCI.com<br />
1-800-4-CORTEC<br />
St. Paul, MN 55110 USA<br />
© Cortec Corporation 2006<br />
70®<br />
100%<br />
Biodegradable EcoWorks<br />
Replacement for Plastic and Polyethylene<br />
Up to 70% Bio-based With<br />
Annually Renewable Resources<br />
From thick rigid plastic cards to fl exible protective wrap,<br />
EcoWorks ® 70 by Cortec ® Research Chemists offers universal,<br />
biodegradable replacement to traditional plastic<br />
and polyethylene films. This patent pending breakthrough<br />
meets ASTM D6400 and DIN V 54 900. EcoWorks ® 70<br />
does not contain polyethylene or starch but relies heavily<br />
on renewable, bio-based polyester from corn. 100%<br />
biodegradable, it turns into water and carbon dioxide in<br />
commercial composting.<br />
ioPlastic.indd 1<br />
8/2/06 8:44:40 AM
Applications<br />
Sustainable Shrink -<br />
Solutions for the Shrink<br />
Sleeve Label Market<br />
Article contributed by<br />
Plastics Suppliers,<br />
Inc., Columbus, OH, USA<br />
Apple juice bottle<br />
sleeved with 50µ EarthFirst PLA<br />
TDO shrink sleeve film; printed<br />
by Folienprint, Germany<br />
www.earthfirstpla.com<br />
Today’s label market is facing challenges as well as<br />
great opportunities. With a push on being “green” as<br />
well as offering sustainable options, wouldn’t it be nice<br />
to have an alternative shrink sleeve label that is compostable,<br />
made from an annually renewable resource and reduces your<br />
environmental footprint? To achieve that goal, EarthFirst ® PLA<br />
TDO shrink sleeve label film is the solution. EarthFirst films<br />
are as good and often times better than petrochemical-based<br />
films when it comes to an economical environmental solution.<br />
EarthFirst is a biopolymer film made from PLA resin. Biopolymers<br />
are not new to the plastics’ industry. When they<br />
were first introduced, the cost to manufacture them was prohibitive.<br />
In the last five years, the cost has come down, making<br />
it a viable film to manufacture. One of the most common<br />
biopolymers used today is NatureWorks ® Polymer, made from<br />
# 2 field corn.<br />
The biopolymer shrink film, EarthFirst PLA TDO, has been<br />
on the market since October of 2005. Plastic Suppliers, Inc<br />
is the first company to manufacture this sustainable shrink<br />
film alternative changing the shrink sleeve label market. With<br />
impressive mechanical and thermal properties, EarthFirst<br />
shrink films are available as a viable replacement for most<br />
petrochemical-based shrink sleeve films.<br />
EarthFirst has many attributes that make it attractive to<br />
the shrink sleeve label market. EarthFirst has a natural dyne<br />
level of 38, is clear and rigid, and has direct food contact compliance.<br />
It shrinks at a lower temperature than for instance<br />
PET and is capable of shrinking up to 75 percent In addition,<br />
EarthFirst shrink sleeve film can be stored up to 40° Celsius.<br />
Therefore this film is extremely stable and can perform on all<br />
types of shrink label tunnels regardless if steam or hot air is<br />
used. All of these features and a great upside; it’s made from<br />
corn, an annually renewable resource.<br />
Plastic Suppliers, Inc. is committed to a strong environmental<br />
leadership role in protecting our planet. The world is going<br />
“green” and the trend toward biopolymers and environmentally<br />
friendly films continues to expand. Nationally, Plastic<br />
Suppliers and its’ European subsidiary Sidaplax play active<br />
24 bioplastics MAGAZINE [02/07] Vol. 2
oles as members of the Sustainable Packaging Coalition<br />
(SPC), European Bioplastics, Belgian Biopackaging<br />
and UK compostable group. EarthFirst has been<br />
certified by the Biodegradable Products Institute and<br />
DinCertco stating it is a compostable film under the<br />
ASTM 6400 and EN 13432 standards. Plastic Suppliers<br />
is committed to understanding the impact of such<br />
products upon the environment and will continue to<br />
seek out opportunities to participate in environmental<br />
research and associations to create an understanding<br />
of how biopolymers may be used in the future. There<br />
are many different biopolymers out in the marketplace<br />
today that are produced by various manufacturing<br />
means. The revolutionary EarthFirst TDO is the only<br />
film targeting the shrink sleeve label market. It is paving<br />
the way in this high profile industry.<br />
Soda drink bottle sleeved by<br />
PackStar, USA for Plastic Suppliers<br />
Inc. with a 50µ EarthFirst PLA TDO<br />
shrink sleeve film.<br />
bioplastics MAGAZINE [02/07] Vol. 2 25
Applications<br />
Talud<br />
protection<br />
Biodegradable non-wovens<br />
made from PLA<br />
DS Technical Nonwovens, a Belgian company based<br />
in Flanders, offers Hortaflex ® , a biodegradable<br />
non-woven with or without the inclusion of (grass)<br />
seeds. The non-woven is used as agro, geo or horticultural<br />
fibre fleece. It can be used as protection against erosion of<br />
slopes, battering, and as landscape protection. DS Technical<br />
is currently looking for customers interested in further<br />
developing the possibilities of this new biomaterial.<br />
Soil and root protection<br />
The new product is a fully biodegradable non-woven made<br />
of PLA fibres and is an answer to various EU regulations (e.g.<br />
Kyoto, REACH, reduced use of herbicides, etc.). Originally it<br />
was developed for the carpet and technical textiles industry.<br />
The production process has been developed in-house.<br />
The non-wovens can be offered with different properties:<br />
mass per unit area (from 120g/m² up to 1.5 kg /m²), needlepunched<br />
or not; structured and calendered. Also tenacity,<br />
elongation or other mechanical properties can be varied.<br />
Other options are the introduction of additives, lamination,<br />
etc. The recently-developed biodegradable non-woven has<br />
been used as a base for the new product, and the process<br />
has been adapted to include (grass) seeds. First tests show<br />
that the results when growing grass were better than when<br />
using carpets with a cellulose base, which is a promising<br />
sign for other applications. First ideas for possible applications<br />
of this product are as a substitute for non-biodegradable<br />
products such as the plastics materials that are used to<br />
avoid weeds, etc. It offers a good alternative to the existing<br />
mulch-mats - certainly where weight becomes important<br />
(e.g. roof gardens). On the other hand other applications<br />
also appear possible (e.g. the building sector). As a result<br />
the company is looking for new applications for this nonwoven,<br />
which it would be pleased to develop in collaboration<br />
with customers.<br />
dirk@dstextileplatform.com<br />
26 bioplastics MAGAZINE [02/07] Vol. 2
Bio-plastics for<br />
BIO CAPS<br />
• Made from wheat, corn and<br />
potatoe starch<br />
• Compostable<br />
• Biodegradable<br />
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Phone: ++41 (0)55 618 44 99 · Fax: ++41 (0)55 618 44 98 · info@wiedmer-plastic.com · www.wiedmer-plastic.com<br />
Incorporating the 2nd global<br />
Bioplastics Awards<br />
Recognising innovation in bioplastics<br />
Don’t let your company miss out. Email<br />
chris.smith@emap.com for full details and entry pack.<br />
Book before 20th July to<br />
receive a Super Early Bird<br />
Discount of €250 plus<br />
a further €100 off!<br />
Performance Through Innovation<br />
With growing emphasis on sustainable manufacturing,<br />
bioplastics certainly have a role to play in the future of<br />
the plastics industry. But there are always questions.<br />
What materials are available? How do they really<br />
perform? What are the real environmental and<br />
financial costs? What are the end-of-life options?<br />
How can bioplastics fit into existing waste<br />
management programmes?<br />
5-6 December 2007 - Frankfurt, Germany<br />
The Bioplastics conference is the place to find<br />
out the answers to these and all other questions.<br />
The programme is assembled by plastics industry<br />
professionals for buyers, processors and users of<br />
plastics, and will be launched in full later this year.<br />
However, if you book your place now, you can<br />
take advantage of a saving of €350.<br />
The worlds longest running independant Bioplastics<br />
conference - now in its 9th year<br />
To register -<br />
Tel: +44 (0)20 7841 4811 (International)<br />
0845 056 5069 (UK Only)<br />
Email: EPNconferences@emap.com EPNJUNAD
Applications<br />
Article contributed by<br />
Patrick Zimmermann,<br />
FkuR Kunststoff GmbH,<br />
Willich, Germany<br />
Compostable<br />
mulch films<br />
made from<br />
PLA blends<br />
www.fkur.com<br />
www.umsicht.fraunhofer.de<br />
www.oerlemansplastics.nl<br />
FKuR Kunststoff GmbH of Willich, in cooperation with<br />
the Fraunhofer Institute UMSICHT, has developed and<br />
brought to market the first compostable mulch film<br />
based on a PLA blend. The PLA blends used are a mixture of<br />
PLA (polylactide) and further biodegradable polymers plus additives.<br />
Industrial production and application testing of the PLA<br />
mulch films have been carried out by Oerlemans Plastics B.V.<br />
of Genderen in the Netherlands. In comparison to other biodegradable<br />
films this novel bio mulch film has the significant<br />
advantage of degrading more slowly and being less sensitive to<br />
climatic variations.<br />
In 2004 FKuR had already initiated the first tests for biodegradable<br />
mulch films. The degradation behaviour of the film<br />
under “open-air conditions“ was assayed in laboratory tests.<br />
Since 2005 the industrial application of the film has been carried<br />
out together with Oerlemans Plastics. A crucial factor that<br />
persuaded Oerlemans Plastics to go for the FKuR PLA mulch<br />
film was, amongst others, the problem-free processing of the<br />
film on conventional extruders, as used in the production of<br />
LDPE films. In the run-up to industrial production the application<br />
of the Bio-Flex ® mulch film was successfully tested on<br />
various crops by several European research institutes and experimental<br />
stations.<br />
Since 2005 the compostable PLA mulch films have been<br />
tested worldwide on a variety of crops in several climates.<br />
The crop yield with this biofilm is comparable to conventional<br />
mulch films made from PE. The PLA mulch films are laid out<br />
using conventional laying machines without any difficulty. An<br />
important advantage in comparison to other biofilms based on,<br />
for example starch, lies in the considerably slower degradation<br />
of the film and its resistance to climatic variations. A further<br />
advantage of the application of bio mulch films for agriculture<br />
is that the film can be easily ploughed in after harvesting, and<br />
continues to degrade in the soil. The application of Bio-Flex<br />
mulch films reduces the amount of work and the costs of disposal.<br />
The granules and the film are fully compostable according to<br />
EN 13432. Additionally they are certified in accordance with to<br />
DIN Certco, OK Compost, NFU 52001 and Ecocert.<br />
28 bioplastics MAGAZINE [02/07] Vol. 2
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Politics<br />
What’s happening in the<br />
www.bpiworld.org<br />
www.biocycle.net<br />
www.findacomposter.com<br />
www.beps.org<br />
Article contributed by Steven Mojo,<br />
Executive Director of the<br />
Biodegradable Products Institute (BPI),<br />
New York, NY, USA<br />
It is truly a new world in North America, as the<br />
pace of organics diversion continues to increase.<br />
Discussions around the issues of sustainability,<br />
increasing use of renewable resources<br />
and greenhouse gas reductions are coming to the<br />
forefront.<br />
Retailer Concerns about Packaging<br />
In late 2005, Wal-Mart announced its sustainability<br />
drive focused on three aggressive goals:<br />
1. “To Be Supplied 100% By Renewable Energy”:<br />
2. ”To Create Zero Waste”:<br />
3. ”To Sell Products That Sustain Our Resources<br />
& Environment”:<br />
As part of this effort, Wal-Mart has developed a<br />
“scorecard” for packaging and is asking suppliers<br />
to document the use of recyclable and compostable<br />
packaging (via ASTM D6400) and to verify the<br />
use of renewable feedstocks (using ASTM D6866).<br />
This scorecard came on-line in March 2007 and<br />
manufacturers will be feeding it data throughout<br />
this year.<br />
Wal-Mart’s efforts, like Sainsbury’s in the UK,<br />
call attention to the growing array of new materials<br />
available to packagers around the globe. At the<br />
same time, packagers are starting to inquire about<br />
BPI certification and the benefits of the BPI Compostable<br />
Logo. Also, manufacturers are striving to<br />
increase the percentage of renewably based materials,<br />
in order to help reduce their environmental<br />
footprint and earn credits from Wal-Mart.<br />
The BPI and its members are immersed in the<br />
issues of renewable resources, compostability and<br />
biodegradability for almost a decade. As such, they<br />
are in a position to help Wal-Mart and others understand<br />
the importance of using ASTM Test Methods<br />
and Specifications for verifying claims.<br />
This project is a “work in progress”. It will continue<br />
to evolve as technology and properties improve<br />
and importantly will impact suppliers, consumers<br />
and everyone in between.<br />
30 bioplastics MAGAZINE [02/07] Vol. 2
New World?<br />
New Legislation in California<br />
California continues to set the pace in the area of<br />
compostables. Last year, Governor Schwarzenegger<br />
signed labeling legislation which restricts the<br />
use of the terms “biodegradable”, “compostable”<br />
and “degradable” on plastic food containers to<br />
only those products that meet ASTM D6400. This<br />
legislation is similar to the one passed in 2004 for<br />
labelling on plastic bags. Both of the new laws<br />
are designed to address the abuse and misuse of<br />
these terms and the resulting confusion.<br />
New Ordinances in San Francisco<br />
In 2006, San Francisco passed ordinance No<br />
295-06 which bans the use of polystyrene food<br />
service packaging and mandates the use of compostable<br />
or recyclable alternatives, if their additional<br />
costs are within 15% of non-compostable<br />
or non-recyclable alternatives. This ordinance<br />
is designed to help minimize the waste going to<br />
landfills from these operations. Also, this ordinance<br />
takes advantage of the City’s well developed<br />
recycling and composting infrastructure for<br />
businesses and households.<br />
On March 27, 2007, San Francisco passed an<br />
ordinance mandating the use of compostable<br />
plastic bags or recyclable kraft paper bags by<br />
large food chains and pharmacies. Given the city’s<br />
widespread organic collection system, the compostable<br />
bags can serve two purposes. First they<br />
will bring home the groceries and then will have<br />
a second life as a liner for residential “kitchen<br />
catchers”. The new law takes effect by the end of<br />
this year.<br />
Food Scrap Diversion Programs Grow<br />
More communities, especially in Eastern Canada<br />
and on the West Coast are implementing food<br />
scrap diversion efforts. Portland (Oregon) and<br />
Seattle (Washington), join the ranks of San Francisco<br />
and Oakland, (California) in implementing<br />
commercial collection programs and in some<br />
communities’ residential ones as well. In the<br />
Canadian province of Ontario organics diversion<br />
efforts are beginning to “skyrocket” according to<br />
one BPI member.<br />
These are driven by the dual goals of continuing<br />
to increase the overall diversion rate from landfills<br />
as well as to reduce greenhouse gas emissions<br />
from landfills. For example, in the US, landfills<br />
are the single largest of anthropomorphic<br />
methane releases into the atmosphere, according<br />
to the US Environmental Protection Agency. Further<br />
the same study shows that landfills are the<br />
number 4 contributor of global warming gases.<br />
Findacomposter.com introduced<br />
The BPI and BioCycle magazine from Emmaus<br />
(Pennsylvania) are joint sponsors of a<br />
new website dedicated to increasing the awareness<br />
of composting in the US. The new site<br />
“findacomposter.com” was debuted in April 2007<br />
at the BioCycle West Coast Conference in San Diego<br />
(California). The site will provide consumers<br />
information about food scrap collection programs<br />
near them and will be available for all to use at<br />
no charge. Composters can participate at no cost<br />
and all entries will be verified by BioCycle. The BPI<br />
and its members are proud to be the first sponsor<br />
to support this effort and to help put composting<br />
on the map.<br />
The BPI and BEPS team up on<br />
a meeting in October, 2007<br />
The BEPS and BPI are jointly sponsoring a<br />
conference from Oct. 17-19th in Vancouver,<br />
Washington. This meeting will combine presentations<br />
and discussions on biodegradable and<br />
renewable materials from both academia and<br />
industry. Presenters are being lined up from<br />
North America, Europe and Asia. The conference<br />
will be a “zero waste” event. It is being held at<br />
the Hilton Hotel, which has been cited for sustainable<br />
practices and it will have an active food<br />
scrap diversion effort by the end of the summer.<br />
Learn more about the conference at beps.org<br />
bioplastics MAGAZINE [02/07] Vol. 2 31
From Science & Research<br />
Novel Nanostructured<br />
Crosslinked<br />
hyperbranched<br />
polymer (HBP)<br />
Fig 1: Transmission electron photomicrograph of modified PLA<br />
showing nanoscale dimension of crosslinked HBP i.e. < 100nm<br />
(stained dark phase). Scale bar: 100 nm.<br />
95 wt.% Modified PLA<br />
+ 5 wt.% Talc<br />
98 wt.% Modified PLA<br />
+ 2 wt.% Organo-clay<br />
Modified PLA<br />
Unmodified PLA<br />
3,2<br />
3,2<br />
3,2<br />
3,5<br />
4<br />
37<br />
83<br />
104<br />
Tensile Modulus<br />
(GPa)<br />
Elongation at<br />
break (%)<br />
0 20 40 60 80 100 120<br />
Fig 2: Tensile properties of hyperbranched polymer modified PLA,<br />
its organo-clay based nanocomposites and talc filled composites.<br />
Renewable resource based bioplastics<br />
are the next generation of materials,<br />
which are expected to play a major<br />
role in building of a sustainable bioeconomy.<br />
Polylactide (PLA) is a renewable resource<br />
based bioplastic. However, the inherent<br />
brittleness (poor elongation at break and impact<br />
strength) of PLA poses considerable scientific<br />
challenges and limits its large-scale<br />
commercial applications. Numerous approaches<br />
such as plasticization, blending with<br />
tough polymers and elastomers have been attempted<br />
to overcome its brittleness however<br />
with huge sacrifice of strength and modulus of<br />
the polylactides.<br />
At Michigan State University, recently new<br />
polylactide based materials having unique<br />
stiffness-toughness properties were invented<br />
by the authors. The research was focused on<br />
exploring the role of emerging hyperbranched<br />
polymers in modifying the PLA base resin. Hyperbranched<br />
polymers (HBP) are considered<br />
as mutant offspring of dendrimers. The nanoscale<br />
dimensions, unique physical and chemical<br />
properties of HBP make them a unique<br />
design tool for tailoring the material properties.<br />
Hydroxyl functional aliphatic polyesters<br />
are HBPs that consist of a polyalcohol core<br />
from which branches extend, forming a coreshell<br />
structure. These HBPs can have abundant<br />
hydroxyl groups on their periphery leading<br />
to their high surface functionalities .<br />
This research is based on creating new nanoscale<br />
hyperbranched organic particles in<br />
a PLA matrix (Biomer ® L9000 from Biomer,<br />
Germany) during industrially relevant melt<br />
processing. In this approach, a commercially<br />
32 bioplastics MAGAZINE [02/07] Vol. 2
From Science & Research<br />
Polylactide Bioplastics<br />
for Multifarious Applications<br />
Article contributed by Dr. Amar K. Mohanty,<br />
associate professor and Rahul Bhardwaj,<br />
PhD student, both at School of Packaging,<br />
Michigan State University, East Lansing,<br />
MI, USA<br />
available hydroxyl functional hyperbranched<br />
polymer (BOLTORN TM H2004 from Perstorp,<br />
Sweden) was selectively in-situ crosslinked<br />
with a polyanhydride (PA-18, LV from Chevron-<br />
Phillips, USA) in the PLA matrix by reactive extrusion.<br />
There was formation of a novel nanostructured<br />
polylactide based two-phase system<br />
(Figure 1), in which crosslinked HBP particles<br />
were present in nano-domains (< 100 nm). The<br />
modified PLA, having 90-92 weight-% of pure<br />
PLA, exhibited an improvement in elongation at<br />
break of about 800-1000% with minimal sacrifice<br />
of tensile strength and modulus.<br />
The findings showed that such a modified<br />
PLA bioplastic material can act as an ideal matrix<br />
for nano-clay or talc as well as natural fiber<br />
reinforcements leading to the development<br />
of many PLA based materials with attractive<br />
properties. Figure 2 represents the tensile<br />
properties of such a modified PLA, its organoclay<br />
(Southern Clay Products, USA) reinforced<br />
nanocomposites and talc (Luzenac, USA) filled<br />
composites. The modified PLA surprisingly exhibited<br />
20 and 25 fold improvement in elongation<br />
at break on specific loadings of nanoclay<br />
and talc particles. These findings also revealed<br />
that the modified PLA can act as an additive for<br />
the dispersion of nanoclay in polylactide based<br />
nanocomposites. The potential impact of this<br />
research on PLA can lead to the enhancement<br />
of its stiffness-toughness balance, improved<br />
melt strength, tailored melt viscosity and ease<br />
of processing, which can be exploited in a variety<br />
of products and processes. This research<br />
is financially supported by the US National Science<br />
Foundation- Division of Design, Manufacture,<br />
and Industrial Innovation (NSF-DMII)<br />
program.<br />
www.egr.msu.edu/cmsc/biomaterials<br />
105x148_bioplastics www.msu.edu/~mohantya/<br />
MAG_4c 16.05.2007 12:49 Uhr Seite 1<br />
www.packaging.msu.edu/Mohanty.php<br />
Organizer<br />
NürnbergMesse<br />
Tel +49 (0) 9 11. 86 06-0<br />
info@nuernbergmesse.de<br />
www.brau-beviale.de<br />
C M Y CM MY CY CMY K<br />
Note the date!<br />
Nuremberg, Germany<br />
14 – 16.11.2007<br />
47. European Trade Fair<br />
for the Beverage Industry<br />
2007<br />
Raw Materials – Technologies –<br />
Logistics – Marketing<br />
bioplastics MAGAZINE [02/07] Vol. 2 33
From Science & Research<br />
Protein-Based Plastics and<br />
The adoption of protein-based plastic by industry<br />
has been slow for several reasons; principal among<br />
them are costs of raw materials, limited thermalmechanical<br />
strength, and solvent sensitivity. There are,<br />
however, strong reasons for using protein-based plastics,<br />
including the reduction of petrochemical dependence as<br />
well as the reduction of greenhouse gases and other environmental<br />
impacts, such as landfill usage. In addition,<br />
the poor properties can be significantly enhanced with<br />
appropriate additives and through careful processing<br />
techniques. For these reasons there is a renewed push<br />
for industry to seriously consider the adoption of proteinbased<br />
polymers for many existing applications which use<br />
petroleum-derived plastics.<br />
Article contributed by<br />
David Grewell, Dpt. of Agricultural<br />
and Biosystems Engineering;<br />
Michael Kessler, Dpt. of Materials Science<br />
and Engineering;<br />
William Graves, Dpt. of Horticulture; all from<br />
Iowa State University, Ames, Iowa, USA<br />
www.egr.msu.edu/cmsc/biomaterials<br />
Fig 2: Plant pots formulated from Zein (left)<br />
and petrochemical plastic pot<br />
Additives and Processing<br />
Proteins in their native state can be resilient, strong,<br />
and low density macromolecules, as evident by several<br />
biological protein structures, such as bone and hair.<br />
However, to utilize the proteins, their structure must fist<br />
be partially broken down during processing and reformed<br />
to a new structure. As such, the thermal-mechanical<br />
and water absorption properties of protein-based plastics<br />
depend heavily on several factors, such as the plasticizers<br />
used (e.g., glycerol, ethylene glycerol, butanediol,<br />
sorghum wax, ethanol and sorbitol), the addition of<br />
cross-linking agents (e.g., zinc sulfate, acedic anhydride,<br />
formaldehyde), and processing parameters (e.g., extrusion<br />
pressure and temperature and initial moisture content).<br />
Reduce Moisture Susceptibility<br />
Work at Iowa State University (ISU) is under way to<br />
characterize these protein derived polymers and evaluate<br />
various treatments and formulations to enhance<br />
their properties. For example, it is now understood that<br />
the addition of selective salts, such as zinc stearate and<br />
zinc sulfate, can reduce the water sensitivity of plastics<br />
derived from soybean proteins. In addition, it has been<br />
demonstrated that thermal treatments (ranging from 80<br />
to 120 °C) can reduce the susceptibility of these plastics<br />
to water. Soy plastics were also co-blended 50:50 with<br />
polycaprolactone (PCL), a biodegradable polyester, in order<br />
to reduce water absorption.<br />
Figure 1 shows that the control sample, untreated<br />
soy plastics, absorbs over 150% water by weight<br />
within a few hours. It is also seen that by heat<br />
treatment the water absorption decreased<br />
significantly after 24 hrs. However, the largest<br />
improvement was seen when the soy plastic was<br />
blended with biodegradable PCL, where the water<br />
absorption was less than 20% even after 24 hrs. of<br />
exposure. It is believed that the relatively water insoluble<br />
PCL formed a continuous phase within the<br />
blend and shrouded the soy plastic from the water.<br />
This allows the PCL to reduce water exposure of the<br />
soy plastic thus reducing the overall water sensitivity.<br />
While the addition of 2 parts of zinc stearate and zinc<br />
sulfate did reduce the water absorption, the reduction is<br />
limited compared to heat treatment and co-blending with<br />
PCL.<br />
34 bioplastics MAGAZINE [02/07] Vol. 2
From Science & Research<br />
Applications<br />
Nano-Clays and Foamed Structures<br />
Other mechanical, thermal, and physicochemical property<br />
enhancement techniques being investigated at ISU<br />
include the use of high powered ultrasonics to promote<br />
exfoliation of nano-clays. These polymer-layered silicate<br />
nanocomposites can have enhanced vapor barrier properties,<br />
further reducing water absorption, while simultaneously<br />
increasing tensile modulus and strength and<br />
heat distortion temperature.<br />
Fig 3: Natural fiber reinforcement<br />
200<br />
In order to overcome the issues related to costs of raw<br />
materials, researchers at ISU are working with Trexel<br />
Corp. (Woburn, Massachusetts) to characterize foamed<br />
substrates. It is expected that these materials will reduce<br />
the raw material requirements while maintaining<br />
mechanical strength.<br />
Potential Applications<br />
Resulting data from this work were used to formulate<br />
selected grades and processing conditions for application<br />
studies. In two initial application examples, Creative<br />
Composites (Brooklyn, Iowa), and Vermeer Manufacturing<br />
Co. (Pella, Iowa) are supplying materials to evaluate<br />
their use for selected products, including hay bale sealing<br />
films and locomotive grease applicators.<br />
Some studies have shown that water resistant films<br />
formulated from Zein, a protein derived from corn, can be<br />
formed as thin as 100 μm. The films are flexible and relatively<br />
strong. Currently, processing and characterization<br />
tests are being performed with these films.<br />
Other applications include bio-degradable pots for<br />
plants. The photograph (Fig. 2) shows a pot formulated<br />
from Zein (left) next to a conventional petrochemical plastic<br />
pot (right). Other formulations include the reinforcement<br />
of the Zein polymer with natural fibers (Fig 3).<br />
While this research is in its early stages, the preliminary<br />
results are promising. It has already been shown<br />
that the water sensitivity of soy protein plastics can be<br />
decreased through simple blending or heat treatment.<br />
Similar enhancement in mechanical properties and cost<br />
with the incorporation of exfoliated clay platelets and<br />
Zein-based proteins is expected. The authors would like<br />
to gratefully acknowledge the Grow Iowa Value Funds for<br />
supporting this work, as well as Zein Corporation, Trexel<br />
Corporation, Creative Composites, and Vermeer Manufacturing<br />
Co.<br />
Moisture absorbition (%wt)<br />
150<br />
100<br />
50<br />
0<br />
0 5 10 15 20 25 30<br />
Fig 1: Moisture absorption<br />
over time<br />
Time (hrs)<br />
Fig 4: Reinforcing rib structure<br />
Control<br />
ZnS=4<br />
Zinc Steartate<br />
80 °C<br />
100 °C<br />
120 °C<br />
PCL Coblend<br />
bioplastics MAGAZINE [02/07] Vol. 2 35
Basics<br />
Bioplastics vs.<br />
Agricultural Land<br />
Calculations, estimates,<br />
assumptions and conclusions<br />
How much bioplastics do I get from agricultural land?<br />
How much bioplastics can be obtained from 1 hectare of land? Differ<br />
ent figures are available to answer this question. We look at just three<br />
bioplastics as examples.<br />
PLA:<br />
There is a lot of confusion about the<br />
amounts of bioplastics that can be<br />
obtained from a given quantity of<br />
agricultural crops, and how much of these<br />
agricultural crops can be harvested from<br />
a given agricultural area. And last but not<br />
least: Is there enough agricultural land<br />
available to grow crops for bioplastics?<br />
This article can be regarded as a first<br />
attempt to shed some light onto this<br />
confusion, although the considerations<br />
are very much simplified in order<br />
to arrive at an initial overview. As with<br />
other articles in this „Basics“ section of<br />
bioplastics MAGAZINE, experts in the aspects<br />
discussed here are expressly invited<br />
to share their knowledge. Please contact<br />
the editor. We will assemble all of the information<br />
received and present an update<br />
in one of the following issues.<br />
Sources<br />
[1] FAQ at www.natureworksllc.com<br />
[2] University of Nebraska (www.ianrpubs.<br />
unl.edu/epublic/pages/publicationD.<br />
jsp?publicationId=144)<br />
[3] Personal information, Erwin Vink,<br />
NatureWorks<br />
[4] The Concept of Novamont‘s Biorefinery<br />
integrated in the Territory, Catia Bastioli,<br />
Novamont, Brussels, Nov. 2006<br />
[5] National Corn Growers Association<br />
(www.ncga.com/CYC/Winners/national.asp)<br />
[6] Fachagentur nachwachsende Rohstoffe,<br />
brochure: „Bioplastics – Plants, Raw Materials,<br />
Products“ (www.fnr-server.de/pdf/literatur/pdf_237bioplastics2006.pdf)<br />
[7] Personal information, Brian Igoe, Metabolix<br />
[8] D. Bockey, UFOP, based on information<br />
from the Bayerisches Staatsministerium für<br />
Landwirtschaft und Forsten (in Bioenergie<br />
- ein Markt der Zukunft, TTL Jena, A. Vetter,<br />
2006)<br />
[9] www.european-bioplastics.org<br />
The FAQ page at natureworksllc.com reports that on average, approximately<br />
2.5 kg of corn (15% moisture) are required per kg of PLA. This<br />
does not mean that the difference (1.5 kg corn) is all waste. A part of this<br />
difference is simply water, a part of it ends up in other corn wet mill products<br />
such as germ oil, corn gluten meal and corn gluten feed, and part<br />
represents the yield losses in the different processes [1].<br />
Depending on the geographical location and whether a field is irrigated<br />
or not, the yield of corn per hectare differs significantly. Yields vary from<br />
60 bushels/acre (3.7 tons/hectare) from Western Nebraska dryland [2]<br />
through 148 bushels/acre (9.3 t/ha) as the average corn yield in the USA in<br />
2004/2005 [3] and 12 t/ha in Europe [4], going right up to 332 bu/acre (20.7<br />
t/ha) reported from the National Corn Yield Contest in the USA 2006 [5]<br />
If we take the US average in 2004/2005 we can calculate an average<br />
“yield“ of 3.72 tons of PLA that can be “harvested“ from one hectare of<br />
land. Other sources report approximately 2 tons [6] or 2.5 tons [1] of PLA<br />
per hectare.<br />
è PLA: Approx. 2-3.7 tons / hectare<br />
PHA:<br />
Metabolix report that currently corn is the major source for their PHA.<br />
For 1 kg of PHA approximately 4.66 kg corn is needed [7].<br />
Based on the information on corn yield above (average 9.3 t/ha), it is<br />
clear that about 2 tons of PHA per hectare can be harvested.<br />
è PHA: Approx. 2 tons / hectare<br />
MaterBi:<br />
MaterBi by Novamont [4] is a bioplastics material based on starch derived<br />
from corn and oils (derived in turn from oilseeds). Approximately 0.5<br />
kg of corn and 1.4 kg of oilseeds, plus other components and additives,<br />
are needed to produce 1 kg of one example formulation of MaterBi.<br />
Given the corn yield of about 12 t/ha and a vegetable oil productivity of<br />
1 t/ha [g] Novamont calculate a yield of approximately 2.5 tons of an average<br />
of different MaterBi resins that can be harvested from one hectare.<br />
è MaterBi: Approx. 2.5 tons / ha<br />
36 bioplastics MAGAZINE [02/07] Vol. 2
Basics<br />
Photo: Novamont<br />
How much agricultural crop<br />
land is available?<br />
We will start with some basic figures. The total land<br />
area of this planet is about 13 billion hectares. The usable<br />
agricultural and silvicultural (forestry) area is about<br />
5 billion hectares and agricultural crop land is given as<br />
approximately 1.38 billion ha [8]. The remaining question<br />
is: How much of this can be used for the production of<br />
agricultural crops for bioplastics?<br />
Here are some figures as a general indication:<br />
It is known that in many countries of the world a certain<br />
amount of agricultural crop land is not permitted to be<br />
used for food production, because the overproduction of<br />
food leads to an “imbalance in market prices“. In Europe<br />
the Common Agricultural Policy therefore has required<br />
the establishment of so called “set-aside zones“ where<br />
food products must not be grown. This measure is aimed<br />
at reducing the high level of agricultural subsidies in Europe.<br />
European Bioplastics estimates the available area<br />
for non-food production in the European Union (EU27) at<br />
around 20 million hectares [9] Based on the figures above<br />
this is enough for 40-50 million tons of bioplastics.<br />
So even if bioenergy, bioethanol and biodiesel to<br />
power our cars, and other chemical intermediate<br />
products, require agricultural crops there should be<br />
enough agricultural land available for the production<br />
of bioplastics. And bioplastics can after their material<br />
life be recovered by e.g. incineration, which gives<br />
a “double dividend“ from the respective agricultural<br />
resource. Both in ecological as well as in economical<br />
terms, bioplastics should therefore be a very favourable<br />
way of making use of agricultural commodities.<br />
In addition to this, it should be mentioned that we<br />
have discussed only primary agricultural crops here.<br />
However, developments are under way to create bioplastics<br />
from secondary biomaterial such as straw,<br />
stems and leaves, and even from municipal waste<br />
water.<br />
In this respect, it is interesting to consider the situation<br />
in the U.S.: The full capacity of NatureWorks‘ PLA plant<br />
of 140,000 tons per year needs only about 0.14% of the<br />
total corn produced in the USA.<br />
How much bioplastics<br />
will be needed?<br />
Latest figures say that the annual global production of<br />
all plastics today is about 240 million tons. If estimates<br />
that say about 10% of all plastics could be replaced by<br />
bioplastics are correct, this would amount to 24 million<br />
tons. For these 24 million tons, according to the figures<br />
above, agricultural crop land of approximalety 10 million<br />
hectares would be needed.<br />
This is 0.7 percent of the global agricultural crop land<br />
or 50 percent of the European set-aside zones - which<br />
are not even being used for food production.<br />
bioplastics MAGAZINE [02/07] Vol. 2 37
Basics<br />
A certain number of products made of bioplastics are<br />
already available in the market. Almost all of them are<br />
labelled with some kind of a logo that tells the consumer<br />
about the special character of the plastics material<br />
used. These logos and their background are introduced by<br />
bioplastics MAGAZINE in this series. Here questions such as:<br />
What is the origin and history of a logo? What does it mean?<br />
Which rules are involved with it? will be adressed.<br />
Logos Part 4:<br />
The Scandinavian<br />
Once in a while you find an “apple” logo on bioplastics<br />
products. In fact there are two different “apple” logos,<br />
one being used in Norway and the other in Finland.<br />
The Finnish Solid Waste Association, FSWA (in Finnish<br />
Jätelaitosyhdistys), represents Finnish regional and municipal<br />
waste management companies. The member companies<br />
take care of the waste management for about five million<br />
citizens (94 % of the total population).<br />
FSWA is an organisation that acts as a link between the<br />
member companies, the Finnish authorities and the European<br />
Union. It is a strong developer of waste management in<br />
Finland and guarantees a sound basis for the member companies‘<br />
operations.<br />
About ten years ago FSWA member companies started to<br />
collect biowaste, mainly organic kitchen waste, from households.<br />
“We encourage people to compost their yard waste<br />
at home in their own gardens or in special compost bins,“<br />
says Markku Salo, Director of FSWA. Part of a large communication<br />
and promotion campaign in which the Ministry<br />
for Environment was also involved, was the creation of the<br />
biowaste-bin for the<br />
kitchen, lined with a<br />
bioplastics-bag<br />
www.jly.fi<br />
www.avfallnorge.no<br />
“Finnish apple logo“. The reason for creating the logo was<br />
quite simple. When biodegradable waste bags became<br />
available people saw the bags in biowaste bins and thought<br />
they could dispose of their kitchen waste in plastic bags.<br />
So in order to distinguish compostable biowaste bags from<br />
“normal“ plastic bags, the apple-logo was printed on the<br />
bio-bags. “In Finland, biowaste bags are more or less the<br />
only compostable plastics products that are available,“ says<br />
Markku Salo. All biowaste bags carrying the apple logo are<br />
certified in line with EN 13432. In Finland today five suppliers<br />
sell certified biowaste bags with the apple logo. The<br />
logo is printed on each bag. The composting bag producers<br />
get a “brand” and a regularly promoted logo for their products.<br />
Consumers can be sure that the product meets the<br />
requirements of the standard. The same logo is well known<br />
from the waste organisation information material, biowaste<br />
bins and collection vehicles.<br />
In Norway, the situation is quite similar, as Henrik Lystad<br />
of Avfall Norge explains.<br />
The system for recommendation and labelling of compostable<br />
waste bags is operated since 2002 by Avfall Norge<br />
(Waste Management Norway, formerly NRF). Avfall Norge<br />
is a branch and interest organisation for approximately 90<br />
municipal and intermunicipal solid waste organisations and<br />
about 50 private companies. The municipal members cover<br />
approximately 95 percent of Norway’s inhabitants.<br />
In Norway, source separation is introduced for over<br />
60 % of the population. The municipality often buys the<br />
waste bags for their inhabitants, i.e. the provision of the<br />
bags being incluced in the refuse collection charge. Thus<br />
the logo was not created as a marketing instrument, “but<br />
to help the municipalities to distinguish the ‘good from the<br />
less good’ waste bag products,” as Henrik Lystad puts it.<br />
When the logo was created, Henrik worked with a soil research<br />
institute where he prepared the “System for recommendation<br />
and labelling of compostable waste bags”. In<br />
38 bioplastics MAGAZINE [02/07] Vol. 2
Basics<br />
“apples“<br />
his report he suggested an apple logo, based<br />
on an already existing logo. The apple was<br />
originally created as a logo for stickers etc<br />
to put on source separation bins for biowaste<br />
together with other logos for paper, glass, textiles,<br />
residual waste etc. Later, in 2002 the apple<br />
logo for compostable waste bags was created, using<br />
the apple in conjunction with a frame all around,<br />
the word “compostable” and a certification number<br />
to be used with biowaste-bags, distinguishing<br />
it from the waste bin sticker.<br />
Like in Finland, the Norwegian<br />
apple logo is only to be used in<br />
conjunction with biowaste-bags.<br />
It may be used when the respective<br />
CEN or DIN standards for compostability<br />
are fulfilled. To ensure the functionality<br />
of the waste bags an additional criterion was<br />
defined focusing on the durability of the bags.<br />
The test method was adapted from the Belgian VGS;<br />
”D9 programme: Bags made of bioplastics intended to collect biodegradable<br />
houehold refuse” (AIB Vincotte 1999). According to this test<br />
bags are filled with an artivicial biowaste mix and stored at up to 40° C<br />
for one week and the bag is not allowed to brake apart.<br />
Finnish apple logo<br />
The compostable logo, which is available for use on paper bags too,<br />
has, for whatever reason, not yet been adopted by the paper industry.<br />
In fact in Norway today just one company offers bio-plastic waste bags<br />
with this logo. In order to open up market competition when municipalites<br />
call for tenders, Henrik Lystad says „Avfallnorge is now considering<br />
opening the biowaste system to bag products that fulfil similar standards,<br />
for example those with the Seedling* Logo.“<br />
*: See Logos part 1 in bioplastics MAGZINE 01/2006<br />
Norwegian apple logo
Basics Glossary<br />
Glossary<br />
In bioplastics MAGAZINE again<br />
and again the same expressions<br />
appear that some of our readers<br />
might (not yet) be familiar with.<br />
This glossary shall help with<br />
these terms and shall help avoid<br />
repeated explanations such as<br />
„PLA (Polylactide)“ in various<br />
articles.<br />
Amylopectin<br />
Polymeric branched starch molecule with very high<br />
molecular weight (biopolymer, monomer is à Glucose).<br />
Amylose<br />
Polymeric non-branched starch molecule with high<br />
molecular weight (biopolymer, monomer is à Glucose).<br />
Biodegradable Plastics<br />
Biodegradable Plastics are plastics that are completely<br />
assimilated by the à microorganisms present a defined<br />
environment as food for their energy. The carbon of the<br />
plastic must completely be converted into CO 2<br />
.during the<br />
microbial process. For an official definition, please refer<br />
to the standards e.g. ISO or in Europe: EN 14995 Plastics-<br />
Evaluation of compostability - Test scheme and specifications.<br />
[bM* 02/2006 p. 34f, bM 01/2007 p38].<br />
Blend<br />
Mixture of plastics, polymer alloy of at least two microscopically<br />
dispersed and molecularly distributed base<br />
polymers.<br />
Cellophane<br />
Clear film on the basis of à cellulose.<br />
Cellulose<br />
Polymeric molecule with very high molecular weight<br />
(biopolymer, monomer is à Glucose), industrial production<br />
from wood or cotton, to manufacture paper, plastics<br />
and fibres.<br />
Compost<br />
A soil conditioning material of decomposing organic<br />
matter which provides nutrients and enhances soil structure.<br />
Compostable Plastics<br />
Readers who know better explanations or<br />
who would like to suggest other explanations<br />
to be added to the list, please contact the editor.<br />
Explanantions we are currenty looking for<br />
are for example “organic“ or “renewable“<br />
[*: bM ... refers to more comprehensive article previously<br />
published in bioplastics MAGAZINE)<br />
Plastics that are biodegradable under “composting“<br />
conditions: specified humidity, temperature, à microorganisms<br />
and timefame. Several national and international<br />
standards exist for clearer definitions, for example<br />
EN 14995 Plastics - Evaluation of compostability - Test<br />
scheme and specifications [bM 02/2006 p. 34f, bM 01/2007<br />
p38].<br />
Composting<br />
A solid waste management technique that uses natural<br />
process to convert organic materials to CO 2<br />
, water and<br />
humus through the action of à microorganisms.<br />
40 bioplastics MAGAZINE [02/07] Vol. 2
Basics Glossary<br />
Copolymer<br />
Plastic composed of different monomers.<br />
Fermentation<br />
Biochemical reactions controlled by à microorganisms<br />
or enyzmes (e.g. the transformation of sugar into<br />
lactic acid).<br />
Gelatine<br />
Translucent brittle solid substance, colorless or slightly<br />
yellow, nearly tasteless and odorless, extracted from<br />
the collagen inside animals‘ connective tissue.<br />
Glucose<br />
Monosaccharide (or simple sugar). G. is the most important<br />
carbohydrate (sugar) in biology. G. is formed by<br />
photosyntheses or hydrolysis of many carbohydrates e.g.<br />
starch.<br />
Humus<br />
In agriculture, “humus“ is often used simply to mean<br />
mature à compost, or natural compost extracted from<br />
a forest or other spontaneous source for use to amend<br />
soil.<br />
Hydrophilic<br />
Property: “water-friendly“, soluble in water or other<br />
polar solvents (e.g. used in conjunction with a plastic<br />
which is not waterresistant and weatherproof or that absorbs<br />
water such as Polyamide (PA)).<br />
Hydrophobic<br />
Property: “water-resistant“, not soluble in water (e.g. a<br />
plastic which is waterresistant and weatherproof, or that<br />
does not absorb any water such as Polethylene (PE) or<br />
Polypropylene (PP)).<br />
Microorganism<br />
Living organisms of microscopic size, such as bacteria,<br />
funghi or yeast.<br />
PCL<br />
Polycaprolactone, a synthetic (fossil based), biodegradable<br />
bioplastic, e.g. used as a blend component.<br />
PHA<br />
Polyhydroxyalkanoates are linear polyesters produced<br />
in nature by bacterial fermentation of sugar or lipids. The<br />
most common type of PHA is à PHB.<br />
PHB<br />
Polyhydroxyl buteric acid (better poly-3-hydroxybutyrate),<br />
is a polyhydroxyalkanoate (PHA), a polymer belonging to the<br />
polyesters class. PHB is produced by micro-organisms apparently<br />
in response to conditions of physiological stress.<br />
The polymer is primarily a product of carbon assimilation<br />
(from glucose or starch) and is employed by micro-organisms<br />
as a form of energy storage molecule to be metabolized<br />
when other common energy sources are not available.<br />
PHB has properties similar to those of PP, however it is<br />
stiffer and more brittle.<br />
PLA<br />
Polylactide, a bioplastic made of polymerised lactic acid.<br />
Sorbitol<br />
Sugar alcohol, obtained by reduction of glucose changing<br />
the aldehyde group to an additional hydroxyl group. S. is<br />
used as a plasticiser for bioplastics based on starch .<br />
Starch<br />
Natural polymer (carbohydrate) consisting of à amylose<br />
and à amylopectin, gained from maize, potatoes, heat,<br />
tapioca etc.<br />
Sustainable<br />
An attempt to provide the best outcomes for the human<br />
and natural environments both now and into the indefinite<br />
future. One of the most often cited definitions of sustainability<br />
is the one created by the Brundtland Commission,<br />
led by the former Norwegian Prime Minister Gro Harlem<br />
Brundtland. The Brundtland Commission defined sustainable<br />
development as development that „meets the needs of<br />
the present without compromising the ability of future generations<br />
to meet their own needs.“ Sustainability relates to<br />
the continuity of economic, social, institutional and environmental<br />
aspects of human society, as well as the non-human<br />
environment).<br />
Thermoplastics<br />
Plastics which soften or melt when heated and solidify<br />
when cooled (solid at room temperature).<br />
Yard Waste<br />
Grass clippings, leaves, trimmings, garden residue.<br />
bioplastics MAGAZINE [02/07] Vol. 2 41
Review<br />
PLA hot topic at<br />
PETnology Forum<br />
At the 10th PETnology Forum in Munich, Germany, technical<br />
experts and senior managers from the beverage<br />
and packaging industry, raw material and machinery<br />
suppliers, as well as suppliers of peripheral equipment, caps,<br />
colorants and consultants, shared their latest developments<br />
and innovations with more than 280 delegates from 33 countries.<br />
The number of delegates is a new record for PETnology<br />
GmbH of Regensburg, Germany.<br />
Recognising the trend towards sustainability and so towards<br />
bioplastics, this year‘s PETnology Forum for the second time<br />
dedicated a special session to the “Potential and Developments<br />
for Renewable Plastics in Packaging“. This session was<br />
chaired by Dr. Harald Kaeb, Chairman of European Bioplastics.<br />
from left to right: Luc Vervynck, Bernd Merzenich,<br />
Brian Glasbrenner, Dr. Harald Kaeb<br />
Erwin Vink<br />
in PLA Workshop<br />
www.petnology.com<br />
Harald Kaeb himself opened the session with a presentation<br />
on “Market Introduction and Policy Measures in Europe“.<br />
In his presentation “Additives to Improve Processing & Properties<br />
of PLA“ Luc Vervynck of the ColorMatrix Group Inc. introduced<br />
additives to minimise yellowing effects and processing<br />
aids such as ColorMatrix Eze TM . The Joule TM reheat additives<br />
improve the heat uptake of PLA in the oven of the stretch blow<br />
moulding machine.<br />
Bernd Merzenich, formerly a consultant for the German<br />
drugstore chain “Ihr platz“, shared his positive experience<br />
when introducing the “Vitamore“ wellness beverages in PLA<br />
bottles with the world‘s first biodegradable cap.<br />
NatureWorks‘ Global Director - Bottles, Brian Glasbrenner,<br />
talked about „Responsible Packaging and Disposal - from<br />
Resin to Recycling“. For him a critical mass is important when<br />
trying to understand the economic sustainability of recycling<br />
a new polymer. Therefore retailers, brand owners and other<br />
stakeholders should be involved.<br />
With regard to bioplastics the PETnology Forum was rounded<br />
off by a workshop on the subject of “PLA“. Here Brian Glasbrenner<br />
and Erwin Vink of NatureWorks LLC introduced a variety of<br />
PLA applications - not only bottles. At the end of the workshop<br />
they pointed out that NatureWorks is attempting to increase<br />
the environmental benefits of PLA by using wind energy. NatureWorks<br />
is one of the top 20 purchasers of renewable energy<br />
certificates (RECs). The net result of purchasing RECs and using<br />
a renewable feedstock leads to a reduction of 62-69 percent<br />
in fossil fuel use for the manufacture of NatureWworks PLA<br />
compared with traditional plastics.<br />
42 bioplastics MAGAZINE [02/07] Vol. 2
Stay permanently listed in the Suppliers Guide with<br />
your company logo and contact information.<br />
For only 6,– EUR per mm, per issue you can be present<br />
among top suppliers in the field of bioplastics.<br />
Suppliers Guide<br />
Simply contact: Tel.: +49-2359-2996-0 or<br />
suppguide@bioplasticsmagazine.com<br />
1. Raw Materials<br />
1.1 bio based monomers<br />
Du Pont de Nemours International S.A.<br />
2, Chemin du Pavillon, PO Box 50<br />
CH 1218 Le Grand Saconnex,<br />
Geneva, Switzerland<br />
Phone: + 41(0) 22 717 5176<br />
Fax: + 41(0) 22 580 2360<br />
thomas.philipon@che.dupont.com<br />
www.packaging.dupont.com<br />
1.2 compounds<br />
R.O.J. Jongboom Holding B.V.<br />
Biopearls<br />
Damstraat 28<br />
6671 AE Zetten<br />
The Netherlands<br />
Tel.: +31 488 451318<br />
Mob: +31 646104345<br />
info@biopearls.nl<br />
www.biopearls.nl<br />
BIOTEC Biologische<br />
Naturverpackungen GmbH & Co. KG<br />
Werner-Heisenberg-Straße 32<br />
46446 Emmerich<br />
Germany<br />
Tel.: +49 2822 92510<br />
Fax: +49 2822 51840<br />
info@biotec.de<br />
www.biotec.de<br />
FKuR Kunststoff GmbH<br />
Siemensring 79<br />
D - 47 877 Willich<br />
Tel.: +49 (0) 2154 9251-26<br />
Tel.: +49 (0) 2154 9251-51<br />
patrick.zimmermann@fkur.de<br />
www.fkur.de<br />
Transmare Compounding B.V.<br />
Ringweg 7, 6045 JL<br />
Roermond, The Netherlands<br />
Phone: +31 (0)475 345 900<br />
Fax: +31 (0)475 345 910<br />
info@transmare.nl<br />
www.compounding.nl<br />
1.3 PLA<br />
Uhde Inventa-Fischer GmbH<br />
Holzhauser Str. 157 - 159<br />
13509 Berlin<br />
Germany<br />
Tel.: +49 (0)30 43567 5<br />
fax: +49 (0)30 43567 699<br />
sales.de@thyssenkrupp.com<br />
www.uhde-inventa-fischer.com<br />
1.4 starch-based bioplastics<br />
BIOTEC Biologische<br />
Naturverpackungen GmbH & Co. KG<br />
Werner-Heisenberg-Straße 32<br />
46446 Emmerich<br />
Germany<br />
Tel.: +49 2822 92510<br />
Fax: +49 2822 51840<br />
info@biotec.de<br />
www.biotec.de<br />
1.5 PHA<br />
1.6 masterbatches<br />
PolyOne<br />
Avenue Melville Wilson, 2<br />
Zoning de la Fagne<br />
5330 Assesse<br />
Belgium<br />
Tel.: + 32 83 660 211<br />
info.color@polyone.com<br />
www.polyone.com<br />
Sukano Products Ltd.<br />
Chaltenbodenstrasse 23<br />
CH-8834 Schindellegi<br />
Phone +41 44 787 57 77<br />
Fax +41 44 787 57 78<br />
www.sukano.com<br />
1.7 reinforcing fibres/fillers<br />
made from RRM<br />
2. Additives /<br />
Secondary raw materials<br />
Du Pont de Nemours International S.A.<br />
2, Chemin du Pavillon, PO Box 50<br />
CH 1218 Le Grand Saconnex,<br />
Geneva, Switzerland<br />
Phone: + 41(0) 22 717 5176<br />
Fax: + 41(0) 22 580 2360<br />
thomas.philipon@che.dupont.com<br />
www.packaging.dupont.com<br />
3. Semi finished products<br />
3.1 films<br />
Maag GmbH<br />
Leckingser Straße 12<br />
58640 Iserlohn<br />
Germany<br />
Tel.: + 49 2371 9779-30<br />
Fax: + 49 2371 9779-97<br />
shonke@maag.de<br />
www.maag.de<br />
Treofan Germany GmbH & Co. KG<br />
Am Prime Parc 17<br />
65479 Raunheim<br />
Tel +49 6142 200-0<br />
Fax +49 6142 200-3299<br />
www.biophanfilms.com<br />
www.earthfirstpla.com<br />
www.sidaplax.com<br />
www.plasticsuppliers.com<br />
Sidaplax UK : +44 (1) 604 76 66 99<br />
Sidaplax Belgium: +32 9 210 80 10<br />
Plastic Suppliers: 1 866 378 4178<br />
3.1.1 cellulose based films<br />
INNOVIA FILMS LTD<br />
Wigton<br />
Cumbria CA7 9BG<br />
England<br />
Contact: Andy Sweetman<br />
Tel.: +44 16973 41549<br />
Fax: +44 16973 41452<br />
andy.sweetman@innoviafilms.com<br />
www.innoviafilms.com<br />
4. Bioplastics products<br />
natura Verpackungs GmbH<br />
Industriestr. 55 - 57<br />
48432 Rheine<br />
Tel.: +49 5975 303-57<br />
Fax: +49 5975 303-42<br />
info@naturapackaging.com<br />
www.naturapackagign.com<br />
Veriplast Holland BV<br />
Stadhoudersmolenweg 70<br />
NL - 7317 AW Apeldoorn<br />
www.veripure.eu<br />
Info@veripure.eu<br />
4.1 trays<br />
5. Traders<br />
5.1 wholesale<br />
6. Machinery & Molds<br />
Molds, Change Parts and Turnkey<br />
Solutions for the PET/Bioplastic<br />
Container Industry<br />
284 Pinebush Road<br />
Cambridge Ontario<br />
Canada N1T 1Z6<br />
Tel.: 001 519 624 9720<br />
Fax: 001 519 624 9721<br />
info@hallink.com<br />
www.hallink.com<br />
SIG CORPOPLAST<br />
GMBH & CO.KG<br />
Meiendorfer Str. 203<br />
22145 Hamburg, Germany<br />
Tel. 0049-40-679-070<br />
Fax 0049-40-679-07270<br />
sigcorpoplast@sig.biz<br />
www.sigcorpoplast.com<br />
7 Ancillary equipment<br />
8. Services<br />
9. Research institutes / Universities<br />
bioplastics MAGAZINE [02/07] Vol. 2 43
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44 bioplastics MAGAZINE [02/07] Vol. 2
Event-Calendar<br />
Events<br />
June 14-15, 2007<br />
Biofolien für Bioverpackungen<br />
Steigenberger Hotel, Osnabrück, Germany<br />
www.innoform-coaching.de<br />
June 26-27, 2007<br />
Packaging Summit Europe<br />
Hotel Okura, Amsterdam, The Netherlands<br />
www.pkgeurope.com<br />
July 3-4, 2007<br />
Biodegradable Plastics in Packaging Applications<br />
Hilton Munich Park Hotel, Munich, Germany<br />
www.intertechpira.com<br />
July 9-11, 2007<br />
The 8th International Conference of Eco-Materials<br />
Brunel University, West London, London, UK<br />
sed.temp@brunel.ac.uk<br />
September 6-9, 2007<br />
naro.tec 2007<br />
Messe und Kongresse für Nachwachsende Rohstoffe<br />
Messezentrum Erfurt, Germany<br />
www.narotec.de<br />
September 12-13, 2007<br />
1st PLA-Bottle-Conference<br />
organized by bioplastics MAGAZINE<br />
Grand Elysee Hotel Hamburg, Germany<br />
www.pla-bottle-conference.com<br />
September 13-14, 2007<br />
Biodegradable Plastics in Packaging Applications<br />
Chicago, IL, USA<br />
www.intertechpira.com<br />
September 18-19, 2007<br />
Biokunststoffe, Herstellung - Verarbeitung - Anwendung<br />
University of Duisburg, Germany<br />
www.hanser.de/biokunststoffe<br />
September 25-26, 2007<br />
Sustainable Packaging<br />
Central London, UK<br />
www.epn-sustainablepackaging.com<br />
October 17-19, 2007<br />
BioEnvironmental Polymer Society 14th Annual Meeting<br />
International Symposium on Polymers and the Environment:<br />
Emerging Technology and Science<br />
Hilton Vancouver Hotel, Vancouver, Washington<br />
Call for Papers: gmg@pw.usda.gov<br />
October 24-31, 2007<br />
K‘2007, International Trade Fair<br />
No 1 for Plastic and Rubber Worldwide<br />
Düsseldorf, Germany<br />
www.k-online.de<br />
meet bioplastics MAGAZINE in Hall 7, 07C09<br />
November 21-22, 2007<br />
2nd European Bioplastics 2007<br />
Convention Centre Newport Bay Club<br />
Disneyland Paris, France<br />
www.european-bioplastics.org<br />
November 27-28, 2007<br />
PETnology Asia<br />
Shanghai<br />
www.petnology.com<br />
December 5-6, 2007<br />
Bioplastics 2007<br />
including Bioplastics Awards 2007<br />
Frankfurt/Main, Germany<br />
www.bpevent.com (for the awards contact chris.smith@emap.com)<br />
March 3-4, 2008<br />
3rd International Seminar on Biodegradable Polymers<br />
Valencia, Spain<br />
http://www.azom.com/details.asp?newsID=7345<br />
June 18-19, 2008<br />
7th Global WPC and Natural Fibre Composites<br />
Congress and Exhibition<br />
Kongress Palais, Stadthalle, Kassel, Germany<br />
www.wpc-nfk.de<br />
K‘2007 - show preview<br />
One of the biggest events for the plastics<br />
industry is certainly the K’2007 in Düsseldorf,<br />
Germany from 24-31 October, 2007.<br />
At the “number 1 for plastics and rubber worldwide”<br />
more than 2,900 exhibitors will show their expertise and<br />
products on an extended fairground of 265,000 square<br />
metres. The last “K-Show” in 2004 attracted almost<br />
231,000 visitors from all over the world.<br />
For the next issue bioplastics MAGAZINE will prepare<br />
a special K’2007 show preview. Therefore we ask all<br />
suppliers of products or services exhibiting at K’2007<br />
to send us your press releases, information about your<br />
exhibits etc..<br />
Come and see us at K’2007. bioplastics MAGAZINE would<br />
be happy to welcome you in hall 7, booth 7C09.<br />
bioplastics MAGAZINE [02/07] Vol. 2 45
Companies in this issue<br />
Company Editorial Advert<br />
Arhcer Daniels Midland (ADM) 5<br />
Avfall Norge (Waste Management Norway) 38<br />
Belu Mineral Water 10<br />
Bio Environmental Polymer Society (BEPS) 31<br />
BioCycle Magazine 31<br />
Biodegradable Products Institute (BPI) 30<br />
Biomer 32<br />
Biopearls 5 37<br />
Bioplastics24.com 7<br />
Biota Brands of America 10<br />
Blue Lake Citrus Products 6<br />
Brau Beviale (Messe Nürnberg) 33<br />
Brecon Mineral Water 11<br />
Chevron Phillips 33<br />
ColorMatrix 42<br />
Consolidated Container Corporation 6<br />
Cortec 23<br />
Creative Composites 35<br />
Danimer 14<br />
DS Technical Nowovens 26<br />
DuPont Packaging 6<br />
Emap 7<br />
European Bioplastics 7, 37, 42<br />
Fachagentur Nachwachsende Rohstoffe (FNR) 36<br />
Finnish Solid Waste Association (FSWA) 38<br />
FkUR Kunststoff 28<br />
Fraunhofer Institut UMSICHT 28<br />
German Bioplastics 11<br />
Grow Iowa Value Funds 35<br />
Hallink 25<br />
Husky 10<br />
Ihr Platz 10, 18, 43<br />
Intertech Pira 17<br />
Iowa State University 34<br />
Iroquois Water 11<br />
K‘2007 (Messe Düsseldorf) 45 9<br />
Krones 11<br />
Luzenac 33<br />
Company Editorial Advert<br />
Metabolix 5, 36<br />
Michigan State University 32<br />
Naro.tect (Messe Erfurt) 19<br />
National Science Foundation 33<br />
Natura Packaging 47<br />
Naturally Iowa 10<br />
NatureWorks 6, 10, 21, 24,<br />
36, 42<br />
Netstal 18<br />
Norland International 10, 20<br />
Novamont (MaterBi) 11, 18, 36 48<br />
Oerlemans Plastics 28<br />
Perstorp 33<br />
PETnology 42<br />
Planet Friendly Priducts 10<br />
Plantic Technologies 7, 14<br />
Plasticker 8 23<br />
Plastics Supplers 24 23<br />
Plastipak 11<br />
Plus One Water 10<br />
Quellenhof 11<br />
Sainsbury‘s 30<br />
Sidaplax 24 23<br />
SIG Corpoplast 10, 22 2<br />
SIG Plasmax 14, 22<br />
Souther Clay Products 33<br />
Tate&Lyle 11<br />
Telles 5<br />
Trexel 35<br />
Turtle Island Project 15<br />
Vermeer Manufacturing 35<br />
Visy Industries 7, 14<br />
Wal-Mart 30<br />
Wiedmer AG 18 17<br />
Zenith Publishing 29<br />
Next Issue<br />
For the next issue of bioplastics MAGAZINE<br />
(among others) the following subjects are scheduled:<br />
Special:<br />
Basics:<br />
Events:<br />
Next issues:<br />
Trays, films<br />
What exactly happens in industrial<br />
composting<br />
Logos Part 5<br />
Review and preview of events like<br />
exhibitions and conferences<br />
e.g. K‘2007 preview<br />
03/07 October 2007<br />
04/07 December 2007<br />
01/08 February 2008<br />
01/08 April 2008<br />
46 bioplastics MAGAZINE [02/07] Vol. 2
A real sign<br />
of sustainable<br />
development.<br />
There is such a thing as genuinely sustainable development.<br />
Since 1989, Novamont researchers have been working<br />
on an ambitious project that combines the chemical<br />
industry, agriculture and the environment: “Living<br />
Chemistry for Quality of Life”. Its objective has been to<br />
create products that have a low environmental impact.<br />
The innovative result of Novamont’s research is the new<br />
bioplastic Mater-Bi ® .The Mater-Bi ® polymer comes from maize starch and<br />
other vegetable starches; it is completely biodegradable and compostable.<br />
Mater-Bi ® performs like plastic, but it saves energy, contributes to reducing<br />
the greenhouse effect, and at the end of its life cycle, it closes the loop by<br />
changing into fertile humus. Everyone’s dream has become a reality.<br />
Living Chemistry for Quality of Life.<br />
www.novamont.com<br />
Mater-Bi ® : certified and recommended biodegradability and compostability.