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Vol. 2 ISSN 1862-5258<br />

Special editorial Focus:<br />

Bottles, Labels, Caps | 10<br />

02 | 2007<br />

bioplastics magazine<br />

Bioplastics vs. agricultural land | 36<br />

Logos, Part 4 | 38


Editorial<br />

dear readers<br />

Some 15 years ago, when the PET bottle really started to take off, the<br />

arguments in its favour were obvious. Compared to glass, the plastic<br />

bottles are lightweight, unbreakable and easy to carry because of their<br />

neck-ring. PET also has certain environmental advantages too - the<br />

lower weight reduces diesel consumption during transport, and PET<br />

melts at a temperature significantly lower than glass, so using less<br />

energy when bottles are initially produced and recycled.<br />

And now one more point can be added to the list of arguments in favour<br />

of plastic bottles. PLA, as an alternative plastic, is made from renewable<br />

resources - mainly starch derived from corn, sugar cane, sugar beet<br />

or even sweet potatoes. Not only is PLA made from products that can<br />

be relatively easily grown and therefore readily renewable, but after its<br />

initial use it can be recycled, composted under certain conditions, or<br />

cleanly incinerated with energy recovery.<br />

A number of beverage and dairy companies are evaluating the use of<br />

this rather new material, or already use PLA for bottle applications.<br />

The special editorial focus in this issue of bioplastics MAGAZINE is on<br />

bottle applications, including the use of bio-sourced and biodegradable<br />

labels and caps. We talked to five of the early pioneers that now use<br />

PLA for their bottles, and asked them about their motivation, their<br />

experiences and their future plans. All five still consider the decision<br />

to go for PLA as the right one.<br />

Those interested to learn more about PLA for bottles,<br />

bioplastic labels and caps, or who wish to discuss<br />

barrier issues, end of life options and many more<br />

detailed aspects than are covered in this issue, are<br />

cordially invited to the 1st PLA Bottle Conference<br />

organised by bioplastics MAGAZINE. We are running the<br />

two-day conference on the 12th and 13th of September in<br />

Hamburg, Germany. Please visit our website for details.<br />

Special editorial Focus:<br />

Bottles, Labels, Caps | 10<br />

02 | 2007<br />

Vol. 2 ISSN 1862-5258<br />

And in this, our fourth issue, you’ll also find more of the<br />

latest bioplastics news, updates on materials, processing,<br />

events and much more – and not only about bottles!<br />

Michael Thielen<br />

Publisher<br />

bioplastics MAGAZINE<br />

Bioplastics vs. agricultural land | 36<br />

Logos, Part 4 | 38<br />

bioplastics MAGAZINE [02/07] Vol. 2


Content<br />

June 02|2007<br />

Editorial 03<br />

News 05<br />

Suppliers Guide 43<br />

Events 45<br />

Applications<br />

Shrink sleeves 24<br />

Non-wovens made from PLA 26<br />

Mulch films made from PLA blends 28<br />

Politics<br />

What’s happening in the New World? 30<br />

From Science & Research<br />

Novel nanostructured polylactides 32<br />

Protein-based plastics 34<br />

Basics<br />

Bioplastics vs. agricultural land 36<br />

Logos Part 4: The Scandinavian „apples“ 38<br />

Glossary 40<br />

Review<br />

PLA hot topic at PETnology Forum 42<br />

Special<br />

Five PLA bottle pioneers 10<br />

Biodegradable caps 18<br />

Processing<br />

Blowing your own PLA bottles 20<br />

Interview: PLA blow moulding 22<br />

Impressum<br />

Publisher / Editorial<br />

Dr. Michael Thielen<br />

Samuel Brangenberg<br />

Layout/Production<br />

Mark Speckenbach, Jörg Neufert<br />

Head Office<br />

Polymedia Publisher GmbH<br />

Hackesstr. 99<br />

41066 Mönchengladbach<br />

Germany<br />

phone: +49 (0)2161 664864<br />

fax: +49 (0)2161 631045<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Media Adviser<br />

Elke Schulte, Katrin Stein<br />

phone: +49(0)2359-2996-0<br />

fax: +49(0)2359-2996-10<br />

es@bioplasticsmagazine.com<br />

Print<br />

Tölkes Druck + Medien GmbH<br />

Höffgeshofweg 12<br />

47807 Krefeld<br />

Germany<br />

Print run: 5,000 copies<br />

bioplastics magazine<br />

ISSN 1862-5258<br />

bioplastics magazine is published<br />

4 times in 2007 and 6 times a year<br />

from 2008.<br />

This publication is sent to qualified<br />

subscribers (149 Euro for 6 issues).<br />

bioplastics MAGAZINE is read<br />

in 80 countries.<br />

Not to be reproduced in any form<br />

without permission from the publisher<br />

The fact that product names may not<br />

be identified in our editorial as trade<br />

marks is not an indication that such<br />

names are not registered trade marks.<br />

bioplastics MAGAZINE tries to use<br />

British spelling. However, in articles<br />

based on information from the USA,<br />

American spelling may also be used.<br />

bioplastics MAGAZINE [02/07] Vol. 2


News<br />

New<br />

bioplastic<br />

bottles<br />

with<br />

pearl-lustre effect<br />

Biopearls R.O.J. Jongboom Holding B.V. from<br />

Zetten, The Netherlands is a company specialized<br />

on tailormade bioplastics injection moulding compounds.<br />

Remy Jongboom, Direktor of Biopearls<br />

now introduced bioplastics bottles with a pearllustre<br />

effect. The bottles are stretch blow moulded<br />

from preforms made of a material that is based on<br />

PLA.<br />

“In a cooperation with the Technical University<br />

of Eindhoven, The Netherlands, we could test the<br />

processing of a new formulation of Biopearlscompounds,“<br />

says Remy. “We extruded some sort<br />

of tapes and found out, that, when stretched, the<br />

mechanical properties of the tapes were significantly<br />

increased.“<br />

In cooperation with a company that makes preforms<br />

and PET bottles Remy Jongboom manufactured<br />

the first preforms and 0.5 Litre bottles with<br />

the new Biopearls compound. These bottles had<br />

such a good quality and beautiful appearance that<br />

not long after the first customers asked Biopearls<br />

B.V. for the supply of his new pearl-lustre effect<br />

bottles. The material is a blend of PLA and other<br />

bioplastics materials that is not as brittle as pure<br />

PLA, so that the bottles feature a certain soft touch<br />

effect. The majority of the mix is based on renewable<br />

resources, as Remy puts it. “And not only is the<br />

bottle made of this Biopearls compound, the cap is<br />

injection moulded from a similar material with a<br />

slightly different elasticity for a good seal.“<br />

Ideal applications are the cosmetics and healthcare<br />

sector, as Remy points out, especially for<br />

those neat little bottles you find in hotel rooms.<br />

Other customer requests target applications such<br />

as paraffin oil (lamp oil).<br />

Metabolix and<br />

AMD announce brand<br />

name Mirel TM<br />

and publish an amazing Internet survey<br />

Metabolix, Inc. of Cambridge, Massachusetts, USA, and Archer<br />

Daniels Midland (ADM) headquartered in Decatour, Illinois, USA,<br />

announced that they have named their Joint venture Telles TM , after<br />

the Roman goddess of the Earth. Telles is now building its<br />

first commercial scale plant for the production of PHA in Clinton,<br />

Iowa, USA. This plant is expected to start up in 2008 and will<br />

produce the corn-based polyhydroxyalkanoate at an annual rate<br />

of about 50,000 tons.<br />

The family of high performance natural plastics that are biobased,<br />

sustainable and completely biodegradable, as the company<br />

states, will be marketed and sold under the brand name<br />

Mirel Natural Plastics.<br />

Internet survey<br />

In April of 2007 the US online market research firm InsightExpress<br />

conducted a USA-wide online survey for Telles: Here are<br />

some of the results in brief, detailed results and their interpretation<br />

can be found at www.metabolix.com.<br />

1. 72% of respondents do not know that plastic is made out of<br />

crude oil/petroleum.<br />

2. On average, respondents estimated 38% of plastic material<br />

is recycled (the reality is less than 6%, according to the EPA<br />

(U.S. Environmental Protection Agency)).<br />

3. Nearly 40% (38.1%) of respondents said plastic will biodegrade<br />

under ground, in home compost, in landfills, or in the<br />

ocean (plastic will not biodegrade in any of these environments).<br />

4. After learning that plastic is made from oil and never biodegrades,<br />

half (50.1%) of respondents stated they would be<br />

likely or very likely to pay 5-10% more for a natural, biodegradable<br />

plastic. Only 24% were unlikely/very unlikely to pay<br />

this much more.<br />

“Everyone knows about the reliance on oil and the impact that<br />

petroleum use has on climate change,“ said Jim Barber, President<br />

and CEO of Metabolix. “Similarly, people see a lot of plastic<br />

waste in the form of litter. But the fact that so many people are<br />

unaware that plastic is made from oil and that it will persist in<br />

the environment for thousands of years, shows the need for education<br />

about the impact of plastic on the environment and the<br />

various alternatives made from renewable resources.“<br />

www.biopearls.nl<br />

www.metabolix.com<br />

www.admworld.com<br />

bioplastics MAGAZINE [02/07] Vol. 2


PLA bottle is used for<br />

a Noble cause<br />

Demonstrating its fresh thinking, Blue Lake Citrus<br />

Products, LLC, Winter Haven, Florida, USA, has become<br />

the first company to offer all-natural and organic juice beverages<br />

in bottles made from NatureWorks TM PLA . Explains<br />

Blue Lake president Wade J. Groetsch, the company selected<br />

the bio-based resin from NatureWorks for the material’s<br />

eco-friendly advantages. “We are always researching<br />

new ways to reduce packaging waste and energy in the<br />

production of packaging products such as our new bottle,”<br />

he says.<br />

Since last September, Blue Lake has offered its lines of<br />

Noble All Natural and Noble Organics premium juices in a<br />

clear, 32-oz PLA bottle molded by Consolidated Container<br />

Corp. using an existing, custom mold. Dubbed the “E bottle”<br />

by Blue Lake, the package provides a clarity comparable to<br />

the company’s previous polyethylene terephthalate bottle,<br />

as well as a sufficient oxygen barrier for the products’ 60-<br />

day shelf life. Noble juices are cold-packed, so PLA’s lower<br />

melt index is not an issue during filling. “However, we do<br />

have to control the temperature of the transportation and<br />

warehousing of bottles,” Groetsch relates.<br />

Based on its 2006 sales, Blue Lake estimates that the<br />

switch to PLA will save the fossil-fuel equivalent of burning<br />

114,000 gal of gasoline and will save greenhouse-gas<br />

emissions equivalent to driving a car more than 2.7 million<br />

miles in the U.S.<br />

www.bluelakecitrus.com<br />

www.cccllc.com<br />

This news was previously published in Packaging Digest,<br />

Feb. 2007, © Reed Business Information<br />

DuPont introduces<br />

PLA modifier<br />

FDA-compliant for food packaging<br />

DuPont Packaging has announced expansion of<br />

its DuPont Biomax ® Strong family of polymer additives<br />

to include an FDA compliant grade for food<br />

contact applications. Biomax Strong polymer additives<br />

improve the performance of PLA packaging.<br />

New Biomax Strong 120 is a polymer additive that<br />

toughens PLA packaging materials while maintaining<br />

compliance with food contact requirements in<br />

the United States (FDA), and in Europe. A similar<br />

additive was introduced in August 2006 for non-food<br />

applications. Both grades of Biomax Strong provide<br />

improved toughness performance with minimal reduction<br />

in package clarity.<br />

“Offering a food contact compliant grade of Biomax<br />

Strong gives DuPont a way to help food marketers<br />

take better advantage of an environmentally<br />

preferred solution in packages such as clamshells<br />

used in fresh produce sections,” said Shanna Moore,<br />

global market manager for DuPont Packaging.<br />

“We are firmly committed to developing sustainable<br />

solutions, including solutions that improve the<br />

performance of other sustainable offerings in the<br />

market,” Moore said. “By improving the performance<br />

of bio-based and biodegradable products, Biomax<br />

Strong can help the packaging industry deliver<br />

high performance at a competitive price.”<br />

DuPont – one of the first companies to publicly<br />

establish environmental goals 16 years ago – has<br />

broadened its sustainability commitments beyond<br />

internal footprint reduction to include market-driven<br />

targets for both revenue and research and development<br />

investment. The goals are tied directly to<br />

business growth, specifically to the development of<br />

safer and environmentally improved new products<br />

for key global markets.<br />

www.dupont.com<br />

bioplastics MAGAZINE [02/07] Vol. 2


Plantic raised<br />

£20 million of<br />

new funds<br />

Development project for barrier<br />

resins for plastic bottle applications<br />

Plantic Technologies Limited, from Altona,<br />

Victoria, Australia, a producer of starchbased<br />

packaging, is pleased to announce that<br />

it has raised £20 million of new funds on May<br />

23 on London’s Alternative Investment Market<br />

(AIM). Plantic will trade under the symbol<br />

‘PLNT’<br />

“The new funds will enable us to expand<br />

our range of unique biodegradable plastics.<br />

Our vision is for consumers everywhere to use<br />

Plantic-based products that play a significant<br />

role in reducing the world’s waste problem,”<br />

said Grant Dow, Managing Director and CEO<br />

of Plantic.<br />

Plantic’s proprietary technology is based on<br />

the use of high amylose corn starch sourced<br />

from renewable resources that are not genetically<br />

modifed.<br />

Having developed the core formulations and<br />

initial applications, Plantic aims further to<br />

develop, commercialise and distribute Plantic<br />

® by creating additional applications across<br />

a variety of industry sectors. To that end, the<br />

company has partnered with a number of<br />

plastics and packaging companies jointly to<br />

develop, commercialise and/or market a new<br />

range of applications through its partners’<br />

established manufacturing and distribution<br />

channels.<br />

Among others Plantic has a development<br />

agreement with Visy Industries Pty Ltd in<br />

Australia to develop barrier resins for rigid<br />

injection stretch blow moulded containers<br />

and bottles. The aim will be to use Plantic as<br />

a barrier layer within multi-layer containers<br />

(e.g. bottles and jars) for goods that require<br />

protection from oxygen ingress or carbonation<br />

loss, as in the case of carbonated beverages.<br />

This would allow existing PET bottles<br />

which require a barrier layer to be recycled<br />

without the need first to recover the barrier<br />

material which in itself is not recyclable.<br />

www.plantic.com.au<br />

“Bioplastics in Packaging“<br />

Exhibition at Interpack 2008<br />

Large group exhibition and stage programme announced<br />

Bioplastics and biopackaging will be presented in a large group exhibition<br />

at interpack 2008, to be held from 24-30 April 2008 at the Düsseldorf<br />

Exhibition Centre. With a planned total exhibition area of 1,000 m 2 , the<br />

exhibition space will be more than triple the size of the interpack 2005<br />

„Innovationparc Bioplastics in Packaging“. The organising trade association<br />

European Bioplastics is expecting more than 30 exhibiting companies<br />

and 10,000 trade visitors to attend.<br />

The event represents a global platform to showcase the progress of<br />

the bioplastics industry. European Bioplastics is offering companies<br />

from the entire value chain the opportunity to demonstrate their state of<br />

the art technology development. This includes raw materials, products,<br />

processes and machinery.<br />

The attractiveness for exhibitors, trade visitors and media will be further<br />

enhanced by an interesting supporting programme including podium<br />

discussions and presentations. European Bioplastics will invite<br />

politicians and industry and media representatives to discuss bioplastics<br />

in the context of the sustainable development, climate change and<br />

resource debate. Biobased and biodegradable plastics have shown a<br />

boom-like development in compostable packaging and other applications<br />

in recent years.<br />

bioplastic study<br />

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More than 40 plastics by 30 manufacturers<br />

Intensive material testing and data research<br />

Comparative presentation of the technical<br />

characteristics and processing properties of tested<br />

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Additional summary on the current international<br />

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In cooperation with the Institute for<br />

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… comprises an industry directory and market<br />

overview<br />

More information at www.bioplastics24.com<br />

bioplastics MAGAZINE [02/07] Vol. 2


News<br />

Potential of bioplastics – an Internet survey<br />

The German Internet portal “plasticker – the home of plastics“ asks visitors on a monthly basis for their opinion<br />

on different topical questions around plastics and the plastics industry. However this online poll is carried out in the<br />

German language only.<br />

In May 2007 the question was about the expected potential of bioplastics:<br />

“How will demand for and production of bioplastics develop in the coming 10 years?”<br />

A) They will substitute most of<br />

today‘s commodity plastics<br />

6<br />

B) They will play a major role in<br />

many application areas<br />

56<br />

C) They will remain niche<br />

products<br />

35<br />

D) The hype, and with it the<br />

materials, will disappear<br />

3<br />

0% 10% 20% 30% 40% 50% 60%<br />

Here are the results:<br />

The general attitude was one of cautious confidence. A<br />

clear majority of those responding to the survey believe<br />

that in the foreseeable future bioplastics “will play a major<br />

role in many applications“. However only 6 percent believe<br />

that bioplastics have the potential to replace today‘s mass<br />

commodity plastics.<br />

Another significant group, accounting for about 35 percent<br />

of the replies, believes that bioplastics will not move<br />

significantly from their current position as a niche product.<br />

Those who think that bioplastics have no real future were<br />

in a clear minority, at only 3 percent.<br />

The online survey not only asked for the visitor‘s opinion,<br />

but also wanted to know which sector of the industry they<br />

were engaged in. Analysing the responses from this aspect<br />

also produced some very interesting results.<br />

In a nutshell* 74 percent of the raw materials sector<br />

(which is made up of traders and distributors, manufacturers<br />

and compounders, and plastics recyclers) expect a<br />

significant increase in the share of the market taken by<br />

bioplastics. 13 percent even went so far as to say that they<br />

would ultimately hold a dominant position in the market.<br />

This is probably because raw materials traders and manufacturers,<br />

who are sitting at the beginning of the value<br />

chain, have for longer been closely concerned with the<br />

subject than, say, most converters. They have also been<br />

forced to pay more attention to the subject of petroleum<br />

reserves.<br />

Amongst the suppliers of machinery about 50 percent expect<br />

bioplastics to play a major role and 50 percent think<br />

they will remain a niche product. Almost nobody thought<br />

that bioplastics would disappear, neither would they replace<br />

most of today‘s commodities.<br />

The biggest group, i.e the plastics processors and converters,<br />

making up 37 percent of all participants, is the most<br />

sceptical. The responses were: A:0% / B:43% / C:55% / D:2%.<br />

This could be put down to the fact that most of them have<br />

had no practical experience with bioplastics and have not<br />

been so closely concerned with the subject. Nevertheless<br />

only 2 percent of them said that they saw no long-term future<br />

for bioplastics<br />

As this online poll was only carried out in the German language,<br />

bioplastics MAGAZINE plans to expand the survey and<br />

ask all our readers and visitors to bioplasticsmagazine.com<br />

from around the world to respond to the same questions in<br />

the English language. From the beginning of June until the<br />

end of August you can give us your opinion on this question<br />

at www.bioplasticsmagazine.com/poll<br />

bioplastics MAGAZINE will publish the results of this global<br />

survey in the next issue.<br />

* all detailed results of the recent German poll can be reviewed at<br />

www.plasticker.com (in German and English language).<br />

bioplastics MAGAZINE [02/07] Vol. 2


Standard products can be found anywhere,<br />

but only at K can you find real innovations<br />

– unique in variety and quality. 3,000<br />

exhibitors from 50 countries provide a professional<br />

pool of innovation, from which<br />

you can create tailor-made solutions for<br />

your business. Be inspired – and turn your<br />

ideas into good business propositions,<br />

face-to-face with the best in the industry.<br />

K2007<br />

International Trade Fair<br />

No. 1 for Plastics and<br />

Rubber Worldwide<br />

Düsseldorf, Germany<br />

24 – 31 Oct. 2007<br />

MACHINERY<br />

AND EQUIPMENT<br />

SEMI-FINISHED PRODUCTS, TECHNICAL<br />

RAW MATERIALS<br />

PARTS AND<br />

AND AUXILIARIES<br />

REINFORCED PLASTICS<br />

SERVICES<br />

Messe Düsseldorf GmbH<br />

Postfach 1010 06<br />

40001 Düsseldorf<br />

Germany<br />

Tel. +49(0)211/45 60-01<br />

Fax +49(0)211/45 60-6 68<br />

www.messe-duesseldorf.de


Special<br />

Five<br />

PLA bottle<br />

pioneers<br />

BIOTA Brands of America, Inc. /<br />

Planet Friendly Products<br />

Telluride, Colorado, USA<br />

David M. Zutler, Founder and CEO<br />

Belu Mineral Water, London, UK<br />

Reed Paget, Co-founder<br />

and Managing Director<br />

Ihr Platz GmbH + Co. KG, Osnabrück, Germany<br />

Bernd Merzenich, former Consultant<br />

now: Managing Director of<br />

german bioplastics GmbH & Co. KG<br />

Plus One Water, Inc., Montreal, Canada<br />

Michael Keeffe, CEO<br />

Naturally Iowa, LLC, Clarinda, Iowa, USA<br />

William Horner, President<br />

A<br />

significant number of companies have launched beverages<br />

in PLA bottles in recent years. bioplastics<br />

MAGAZINE spoke to the responsible people at five of<br />

the early pioneers in this field about their motivation, their<br />

experience and their future plans.<br />

Motivation<br />

Being asked how they came to the idea of using PLA as a<br />

bottle material, David Zutler of BIOTA said, that as early as<br />

1996 he was already looking for a better material. In May<br />

of 2002 he read an article in the local Telluride newspaper<br />

how plastic bottles were helping to destroy the environment<br />

of our planet. Just shortly after Cargill and Dow opened<br />

their production plant for PLA in Blair, Nebraska, USA, he<br />

and Planet Friendly TM Products, a bioplastics consultancy<br />

firm also founded by him, contacted Cargill Dow (now NatureWorks<br />

LLC) and with the support of Cargill Dow, Husky<br />

and SIG Corpoplast they started the rollout of the World‘s<br />

First PLA preforms, bottles, and labels with the intention of<br />

“helping change the world as far as plastics is concerned,“<br />

as David puts it.<br />

A similar idea drove Bill Horner of Naturally Iowa, when<br />

his company established the guidelines for creating a new<br />

all natural or even all organic dairy company. In October of<br />

2005 they saw a major shift in consumer demand for organic<br />

products. “We decided to make a shift in our business plan<br />

as well, and with regard to packaging we wanted to set ourselves<br />

apart from all the others,“ says Bill, “and the only real<br />

breakthrough in plastics packaging that we could see was<br />

PLA“. Two years earlier they had contacted Cargill Dow, just<br />

an hour and a half down the road, and enjoyed the benefit<br />

of earlier experience gained with the help of BIOTA bottles.<br />

Naturally Iowa uses Norland blow moulding equipment for<br />

their in-house production of the bottles.<br />

London (UK) based Belu Mineral Water is an environmental<br />

initiative which contributes 100% of its net profits to clean<br />

water projects. Working with the charity WaterAid, every bottle<br />

of Belu water purchased in the UK provides someone in<br />

India or Africa with clean water for one month. About five<br />

years ago Belu contacted the Rocky Mountain Institute, an<br />

environmental organisation in the USA. “I discussed with<br />

them how to make a low impact bottle to create a more sus-<br />

10 bioplastics MAGAZINE [02/07] Vol. 2


Special<br />

tainable product,“ says Reed Paget of Belu, “and they suggested<br />

we use a sort of biopolymer“. As PLA was not ready<br />

for commercial use in those days, Belu started the launch of<br />

Belu Mineral Water with glass bottles. After the successful<br />

launch of BIOTA, Belu finally introduced in May 2006 the Belu<br />

PLA bottle, using preforms purchased from Planet Friendly<br />

Products. The bottles are blown on SIG Corpoplast stretch<br />

blow moulding machines and filled at Brecon Mineral Water<br />

in a factory located near Llandeilo in South Wales.<br />

To set up a socially responsible water company was the<br />

idea with which Michael Keeffe of +1Water in Canada approached<br />

co-founders Paul and David Smith a few years<br />

ago. “We wanted to contribute 20% of our profits towards<br />

water development organisations like WaterCan and Ryan‘s<br />

Well Foundation in Canada and Operation Hunger in South<br />

Africa,“ says Michael. These non profit organisations help<br />

provide communities in need with access to safe, clean water.<br />

“Unlike most people living in North America and Europe,<br />

there are over one billion people in the world that do not<br />

have access to safe drinking water,“ he adds. Within a few<br />

months they found out about PLA and decided it would provide<br />

the environmentally responsible component to round<br />

out the socially responsible dimension of the product. With<br />

the technical support of NatureWorks, Krones and Ben Benedict<br />

at Iroquois Water +1Water was able to launch their PLA<br />

+1 bio-bottle last January. +1 bottles natural spring water<br />

from a family owned spring called “Bell Falls“ in Quebec.<br />

Iroquois Water, use Krones equipment, to blow and fill the<br />

bottles for +1Water.<br />

Bernd Merzenich (today head of german bioplastics) has<br />

acted as a consultant to different companies with regard<br />

to the production and marketing of organic food for about<br />

25 years. In recent years he has also been keen to use bioplastics<br />

as a packaging material for organic produce. When<br />

working for the German drugstore chain “Ihr Platz“, establishing<br />

a new range of organic food products and natural<br />

cosmetics, he came across the BIOTA bottles. He found<br />

exciting the idea of using PLA as a packaging material for<br />

a pilot project of wellness beverages with a strong appeal<br />

to health and environment, which Ihr Platz was planning to<br />

introduce. When Hycail (today with Tate&Lyle) could not con-<br />

bioplastics MAGAZINE [02/07] Vol. 2 11


Special<br />

tinue their initial support Bernd started to cooperate with<br />

NatureWorks, “from whom we received considerable support<br />

towards sourcing and processing the material.“ The<br />

Luxembourg based company Plastipak supplied the preforms,<br />

made on Husky equipment, to the German mineral<br />

water company Quellenhof who blow-moulded and filled the<br />

bottles for Ihr Platz .<br />

Planet friendly cap<br />

Summing up the first part of our conversation, we can say<br />

that all of the parties interviewed consider their decision regarding<br />

the use of PLA as a material for their bottles as the<br />

right one. David Zutler: “Absolutely the right decision. Petroleum<br />

based plastics are one of the world‘s biggest problems.<br />

Just look at some of the developing countries where<br />

no recycling is in place for PET bottles and where they openly<br />

burn their overloaded landfills.“ Bill Horner: “100 percent<br />

the right decision. We are planning further products to be<br />

packaged in PLA.“ Reed Paget: “Almost any analysis shows<br />

that PLA is the most sustainable option.“ Michael Keeffe:<br />

“At this point in time we are convinced it was the right decision.<br />

We have outlets across three of the Canadian provinces<br />

here, and we are about to expand to the west coast of Canada.“<br />

And even though Ihr Platz recently discontinued selling<br />

the Vitamore wellness drinks, Bernd Merzenich considers<br />

the use of PLA as the right decision. Bernd: “It was good to<br />

make a statement in favour of bioplastics and to be the first<br />

on the German market. However, a drugstore chain is not<br />

a food store and beverages in bottles with, at the moment,<br />

limited barrier properties need a faster turnover.“<br />

Labels and caps<br />

How important are labels and caps from renewable resources<br />

for the companies that sell PLA bottled products?<br />

While the Vitamore and +1Water labels are made of paper<br />

and therefore made from a renewable - and biodegradable<br />

- source, BIOTA, Belu and Naturally Iowa are already using<br />

PLA labels. +1Water is eventually planning to switch to PLA<br />

labels.<br />

When it comes to caps, it‘s the other way round. Ihr Platz<br />

introduced the world‘s first compostable cap, made of<br />

MaterBi which is partly sourced from renewable raw materials.<br />

BIOTA is planning to roll out what David calls a planetfriendly<br />

cap, made of 100% renewables and 100% compostable.<br />

The resin composition is mainly based on PLA. This cap<br />

will be available to other bottlers too, as David points out.<br />

Reed says that “Belu will use a bioplastics cap as soon as<br />

we can find one that will work with our product“. Naturally<br />

Iowa is also interested in caps and “we‘ve been working with<br />

a company in Japan who‘s developing a PLA-blend that will<br />

work on closures,“ says Bill. He is confident of having one<br />

next year. +1Water will move to biobased caps, as soon as<br />

they are there,“ Michael points out.<br />

12 bioplastics MAGAZINE [02/07] Vol. 2


12 - 13 September 2007<br />

1st PLA-Bottle-Conference<br />

possibilities | limitations | prospects<br />

powered by<br />

PLA (Polylactide), a compostable plastic made from renewable<br />

resources such as corn, is a highly topical subject right now,<br />

especially in the light of increasing crude oil prices. The stretch blow<br />

moulded PLA bottles used by Biota or Natural Iowa (USA), Belu (UK),<br />

Vitamore (Germany) and +1water (Canada), as well as reports in<br />

the trade press, have aroused significant interest from the PET and<br />

beverage industry.<br />

Would you like to find out more about the possibilities, limitations and<br />

future prospects of PLA for bottle applications?<br />

That‘s exactly why bioplastics MAGAZINE is organising the 1st PLA<br />

Bottle Conference on the 12 th and 13 th of September 2007 in the Grand<br />

Elysee Hotel in Hamburg, Germany. This 1½ day conference offers a<br />

comprehensive overview of today‘s opportunities and challenges.<br />

Experts from companies such as Purac, Uhde Inventa-Fischer,<br />

Natureworks, Netstal, SIG Corpoplast, Wiedmer, Treofan, Sidaplax,<br />

SIG Plasmax, Doehler, Polyone, Ihr Platz, Coca-Cola, Interseroh, and<br />

more, will share their knowledge and …<br />

…on the afternoon of Thursday September 13th delegates will visit SIG<br />

Corpoplast, the manufacturer of the stretch blow moulding equipment<br />

that is used to produce for example the Biota and the Belu bottles.<br />

€ 850.00<br />

Sponsors<br />

Supported by<br />

There will be sessions covering:<br />

• Raw materials, from corn to PLA<br />

• PLA preform manufacture<br />

• Stretch blow moulding of PLA<br />

• Caps, labels, shrink-sleeves made<br />

from biodegradable plastics<br />

• Barrier solutions for PLA bottles<br />

• Temperature stability of PLA<br />

• Additives, from processing<br />

agents to colorants<br />

• Reports „from the market“<br />

• End of life options, recycling, energy<br />

recovery, composting<br />

More information and registration:<br />

www.pla-bottle-conference.com


Special<br />

Planet Friendly TM bottle<br />

The cost issue<br />

“The higher price of PLA is acceptable to us and should be<br />

acceptable to everyone because the planet is worth it,“ says<br />

David Zutler. And he thinks that the majority of consumers<br />

“who care“ think so too. Eventually, David is convinced, when<br />

the economy of scale kicks in, the price of PLA will drop.<br />

Reed Paget too believes that in the long run, the price of<br />

PLA will come down while petrochemical plastics will become<br />

more expensive. The environmental sustainability is<br />

the starting point for Belu and Reed too thinks that some<br />

consumers would accept a slightly higher price. “However,<br />

we try to be cost effective as much as we can,“ he says.<br />

“I really think the price is dominant and I would like to say<br />

the environmental advantages would outweigh the price“,<br />

says Bill Horner. On the other hand he considers that the<br />

price of PLA today already is almost competitive with PET.<br />

“The price for PET is going higher and higher, and although<br />

we had a fight on the corn prices that was just temporary.<br />

On a long term view the prices for starch are much more<br />

stable“, he adds.<br />

Michael Keeffe doesn‘t feel that the price is a super-critical<br />

factor for the consumer. “As soon as it becomes clear<br />

that it is an environmentally friendly bottle, that seals the<br />

decision for most people,“ Michael explains. „We hope that<br />

the increasing demand for sugar, for example for making<br />

bio-ethanol, does not push the price of PLA up through the<br />

roof, but as of now the price for us is workable“.<br />

“We are talking about environmentally and health conscious<br />

consumers who are willing to accept a premium price<br />

for corresponding items,“ says Bernd Merzenich. “But you<br />

really need a very clear communication strategy with these<br />

products,“ he adds. “You need to be transparent and critical,<br />

and clearly explain what is bio with these materials.“<br />

Barrier properties and heat resistance<br />

As how important do our interview partners consider enhanced<br />

barrier properties and the heat resistance of PLA?<br />

None of them is currently packaging products that need<br />

a container with elevated temperature resistance. However,<br />

all confirm that for certain applications such as hot-filled<br />

juices etc. enhanced thermal properties will be needed.<br />

When it comes to barrier, the picture looks different. Reed<br />

Paget thinks that, as for other plastic materials, PLA also<br />

needs an enhanced barrier. Michael Keeffe confirms this<br />

thought, for their current product, flat water, improved barrier<br />

properties will provide greater production and distribution<br />

options. “For the long term viability of PLA for other<br />

products, such as carbonated beverages or fruit juice, we<br />

will also need a barrier against CO 2<br />

and Oxygen“.<br />

Bernd Merzenich: “PLA definitely needs to be improved<br />

regarding its barrier properties and heat stability. For still<br />

water the presently available level of material and technology<br />

is OK, on the premise that the turnover at the point of<br />

sale is sufficiently fast. But for more sophisticated uses in<br />

the beverage and food industry we need material improvements<br />

by developing new bioplastic compounds on the basis<br />

of PLA, as well as by using additives, coatings or the like,<br />

such as, for instance, the SIG Plasmax plasma coating process<br />

or a bioplastic barrier resin for multilayer applications,<br />

which has been announced by Plantic.“<br />

Naturally Iowa, cold filling their products, are very satisfied<br />

with the quality of the PLA they get from NatureWorks today.<br />

Their milk is a short shelflife product and is sold through the<br />

cold chain, so that up to now better barrier or temperature<br />

properties have not been needed.<br />

David Zutler however, is already active in this field. Together<br />

with strategic partners Danimer, and the Australian<br />

packaging and recycling group Visy, BIOTA is developing a<br />

Planet Friendly bottle, that is made of PLA plus an additive<br />

which enhances the elasticity properties, and will help provide<br />

some additional properties as well. “Our goal is to have<br />

such a bottle within the next six months, and in addition to<br />

that, to have a bottle material with barrier properties even for<br />

use with CSD (carbonated soft drinks) and resistant to water<br />

vapour, heat, and O 2<br />

ingress within a year,“ says David.<br />

14 bioplastics MAGAZINE [02/07] Vol. 2


Special<br />

End-of-life options<br />

There has to be a way for consumers, and recyclers to<br />

easily tell the difference between biobased products and<br />

petroleum based products. “All our bottles say Planet<br />

Friendly. When the consumer, and recycler, see those<br />

words, they know what they are,“ says David. “My number<br />

one end-of-life option is what I would call reclaiming,“ he<br />

adds. „Reuse or recycle to bottles or into other products<br />

such as garden pots etc. And my second favourite is energy<br />

recovery. PLA burns cleanly and can help augment the use<br />

of fossil fuels (petroleum, coal, etc.) in power plants, helping<br />

to generate greenhouse neutral energy and alleviate the<br />

devastating problem of burning plastics in landfills.“<br />

Reuse and recycle are also the preferred end-of-life options<br />

for Reed Paget, making up the top four together with<br />

composting/energy recovery, and with landfill as the last option.<br />

Belu is currently working on life cycle assessments and<br />

even home composting seems to be a viable option instead<br />

of shipping the waste across town to a waste facility. “I did it<br />

myself in my backyard,“ says Reed, “and if you know how to<br />

do it, it works.“<br />

“Our +1 bio-bottle is clearly stamped both with the number<br />

seven recycling logo as well as the word ‚compostable‘ informing<br />

consumers that they have disposal options, says<br />

Michael Keeffe. +1Water is working (with a number of recyclers)<br />

on a pilot project with a company called “Turtle Island<br />

Recycling“ in Ontario focused on both bioplastics recycling<br />

and composting. And when, after reuse or recycling, PLA<br />

ends up in an incineration plant, because it‘s not petrochemical<br />

based it is also more environmentally friendly as well.<br />

Today, Naturally Iowa‘s percentage of the market is rather<br />

small, so that the bottles end up in a landfill where they<br />

degrade. But Bill Horner says that first attempts are being<br />

made to set up industrial composting facilities.<br />

Bernd Merzenich says: “To be pragmatic, just now I only<br />

see incineration with energy recovery as meaningful. From<br />

an LCA point of view I would favour thermal disposal, because<br />

it generates CO 2<br />

neutral energy. Last but not least,<br />

looking at the present hype regarding biofuels, the aspect<br />

of eco-friendly energy recovery from bioplastics should be<br />

stressed: Bioplastics create a much higher added value<br />

from agricultural raw materials than biofuels and can generate<br />

a similar output of CO 2<br />

neutral energy when incinerated<br />

at their end of life.“ As soon as barrier properties and<br />

heat resistance are improved, biodegradability as an option<br />

will anyway become much less an issue, Bernd adds. “Personally<br />

I don‘t believe in biodegradability unless it has practical<br />

reasons,“ he says. “For instance when you pack fruit<br />

and vegetables you can compost the waste together with the<br />

packaging, or when bioplastic shopping bags are available<br />

they can be used to collect and compost organic waste.“<br />

Future prospects<br />

BIOTA will remain a bottled water company, but Planet<br />

Friendly is going to work with different manufacturers to<br />

promote PLA and other bio-based packaging. “I would<br />

rather help other manufacturers with the different additives<br />

and different material properties that are being developed,“<br />

David says.<br />

Belu as well as +1Water have further projects on the drawing<br />

board. However, “they are not too far down the road as of<br />

yet“, Reed Paget points out.<br />

“So far we just produce the 0.5 gallon milk bottles,“ says<br />

Bill Horner, “but starting in June we are going to be bottling<br />

milk in 10 and 12 oz. and possibly even 8 oz ‚grab-and-go‘<br />

containers, and in the fall we start with a probiotic drinkable<br />

yoghurt with an extended life that we are really excited<br />

about,“ he proudly adds. All of the products will be packaged<br />

in PLA, the single serve units with a PLA shrink sleeve.<br />

Bernd Merzenich thinks that for many companies in Germany<br />

it is a drawback to start using PLA as long as there is<br />

only one supplier. First of all, if a company wants to introduce<br />

PLA, they can‘t get the material, and secondly, no one<br />

wants to rely on a single source. And David Zutler says that<br />

governments should support companies that want to build<br />

up production capacities.<br />

bioplastics MAGAZINE [02/07] Vol. 2 15


Special<br />

Final remarks<br />

David Zutlers says: “The big beverage companies in the world will not<br />

convert to PLA bottles unless they are required to do so.“ They may be<br />

pushed to do so because of economic advantages, or by law. “And governments<br />

should consider, when the barrier and heat deflection problems that<br />

we are working on have been solved, making the use of PLA or other biobased<br />

packaging a requirement.“<br />

Reed Paget wants to stress that all the companies involved today are really<br />

pioneers that have taken a significant financial risk and that deserve to<br />

be acknowledged and thanked. “Waste in our modern lifestyle is a growing<br />

and significant issue, as is energy consumption,“ he says, “and biopolymers<br />

are offering a way to maintain a fairly modern lifestyle with the prospect of<br />

not leaving a legacy of pollution which the planet cannot sustain.“<br />

Michael Keeffe is very excited about the potential for PLA particularly<br />

given growing consumer demands for more environmentally sustainable<br />

and socially responsible products. Our PLA water bottle is both of these,<br />

a healthier choice for the environment and a healthier choice for the consumer<br />

while helping others get clean water too:<br />

Bill Horner is very happy “that we made the decision early on and have<br />

stuck with it through all the research and development rollercoaster that<br />

we‘ve been through. But it‘s been worth it all.“ Not only is Bill very pleased<br />

with what they have achieved so far, they are also willing to share the lessons<br />

they have learned with other dairy companies around the world.<br />

Bernd Merzenich, with a very focused view on the German beverage<br />

packaging situation, thinks it essential that government accepts PLA as<br />

an ecologically favourable packaging material so that PLA bottles are exempted<br />

from the mandatory deposit fee laid down in the German Packaging<br />

Ordinance. “If this can be achieved, it will really be a breakthrough for PLA<br />

because we then enter into a new environmental quality. That will make<br />

PLA attractive for a mass market,“ he says.<br />

The very final words in this talk with major bioplastics users are from<br />

our cover-girl Janina (11). She says: “In school we learned that crude oil<br />

is a limited resource and that alternative energies such as wind or solar<br />

power can save oil. I didn‘t know that plastics were made from oil and I like<br />

the idea that plastics can be made from plants.“ And her little sister Lena<br />

(6) adds: “Michael Thielen said, microorganisms that live in the compost<br />

heap eat the bioplastics. But I can‘t even imagine what microorganisms<br />

look like!“<br />

www.biotaspringwater.com<br />

www.ihrplatz.de<br />

www.belu.org<br />

www.plusonewater.ca<br />

www.naturallyiowa.com<br />

16 bioplastics MAGAZINE [02/07] Vol. 2


Biodegradable Plastics<br />

in Packaging Applications<br />

Early bird offer – book before<br />

July 13, 2007 and save 10%!<br />

see reverse for more details<br />

Thursday, September 13<br />

Friday, September 14<br />

2007<br />

Doubletree Hotel Chicago<br />

O’Hare Airport – Rosemont<br />

Chicago, IL, US<br />

Commercially viable bioplastics for sustainable packaging applications<br />

Two day IntertechPira conference plus half day pre-conference workshop<br />

With presentations<br />

from leading companies:<br />

BioBag<br />

BIOTA/Planet Friendly Products<br />

Blue Lake Citrus Products<br />

Ciba Expert Services<br />

Clarifoil<br />

Earthcycle<br />

Environmental Packaging<br />

International<br />

EPI Environmental Products<br />

Excellent Packaging & Supply<br />

Gilbreth Packaging<br />

G.S. Polymer Consultants<br />

Innovia Films<br />

Kraft Foods Global<br />

Metabolix<br />

Michigan State University<br />

Microsoft<br />

MonoSol<br />

NNZ – The Packaging Network<br />

Naturally Iowa<br />

NatureWorks<br />

Plantic Technologies<br />

Whole Foods Market<br />

Wild Oats Natural<br />

Including presentations from:<br />

Media Partner:<br />

Plus!<br />

Don’t miss the<br />

pre-conference workshop on<br />

Wednesday, September 12,<br />

2007:<br />

New Markets<br />

for Bioplastics


Special<br />

Biodegradable caps<br />

Last year, in combination with the “Vitamore“<br />

PLA bottle sold by the German drugstore chain<br />

“Ihr Platz“, the Swiss company Wiedmer AG from<br />

Näfels in the Canton of Glarus introduced the world‘s first<br />

biodegradable closure for beverage bottles. Wiedmer AG<br />

focuses on tooling and mould-making parts as well as the<br />

production of injection moulded parts.<br />

The BioCap ® is a 3.6 gram standard PCO-28 cap with<br />

tamper-evident ring. The material is a compostable<br />

Mater-Bi polymer from Novamont, Italy. The geometry of<br />

the cap and the elastic Mater-Bi material allow the production<br />

of a perfectly leak-proof bottle.<br />

With oxygen permeability very much in mind Wiedmer<br />

asked the Fraunhofer Institute for Process Engineering<br />

and Packaging IVV in Freising, Germany, to carry out permeation<br />

tests. All BioCaps exhibited an oxygen permeation<br />

rate of 0.035-0.039 (cm3/d bar) - a comparable HDPE<br />

cap showed 0.027 to 0.032 (cm3/d bar). The tests were<br />

performed in line with DIN Standard 53380, part 3.<br />

Initially Wiedmer manufactured the caps on a two-cavity<br />

prototype mould. They were totally satisfied with the<br />

results and the very good processability of the MaterBi<br />

material. Detlef Wellner, Marketing and Sales Director<br />

at Wiedmer would like to stress that Wiedmer is grateful<br />

to Novamont of their support in finding the right MaterBi<br />

recipe, the mould design (shrinkage behaviour) and the<br />

processing parameters. Wiedmer have now built a 16-cavity<br />

production mould, that is currently on test. Wiedmer<br />

manufactures the BioCaps on a Netstal injection moulding<br />

machine. “And the caps were not exclusively developed<br />

for the Vitamore bottle“ says Detlef Wellner, “anyone looking<br />

for a compostable closure for PLA bottles can have<br />

them.“<br />

Wiedmer AG puts great emphasis on protecting the environment.<br />

One example of ongoing production process<br />

improvements is the successful reduction of the amount<br />

of waste thanks to the recycling of injection mouldings.<br />

In the manufacture of plastic closures the use of a hot<br />

runner system has reduced waste to practically zero. The<br />

consequence is that the energy required for manufacturing,<br />

and the emissions produced, have been considerably<br />

reduced. In addition, all injection moulding production<br />

takes place within a closed loop system, including heat<br />

recovery. This heat is then re-used for heating the entire<br />

company site. Environmental protection, which has been<br />

actively integrated into the optimisation of Wiedmer‘s operating<br />

procedures by their employees, offers potential for<br />

further cost reductions.<br />

www.wiedmer-plastic.com<br />

18 bioplastics MAGAZINE [02/07] Vol. 2


Internationales Symposium<br />

»Werkstoffe aus Nachwachsenden<br />

Rohstoffen«<br />

Internationaler Kongress<br />

zu Pflanzenöl-Kraftstoffen<br />

Europäische Kooperationsbörse<br />

Fachtagung Biogas<br />

www.narotech.de


Processing<br />

Blowing Your Own<br />

Reprinted in part with permission of Water Conditioning<br />

& Purification Magazine, © September<br />

2006. Any reuse or republication, in part or whole,<br />

must be with the written consent of the Publisher.<br />

Publicom, Inc., Tucson, Arizona USA<br />

www.norlandintl.com<br />

Article contributed by<br />

Bruce Kucera,<br />

Vice President of Norland<br />

International Inc.,<br />

Lincoln, Nebraska, USA<br />

PLA Bottles<br />

For the time being, PLA as a raw material<br />

for bottle applications is suitable rather for<br />

niche markets and certain filling goods than<br />

for the big CSD (carbonated soft drinks) etc. But<br />

even for such niche markets, supplied by small to<br />

medium-sized bottling companies on-site manufacturing<br />

of PLA or PET bottles has advantages.<br />

Why take a do-it-yourself approach? Because it<br />

pays!<br />

Manufacturing your own bottles on site can yield<br />

a dramatic cost-per-bottle savings, primarily by<br />

cutting out the shipping costs. Current petroleum<br />

pricing negatively impacts transportation costs,<br />

of course. In some cases, bottlers can save up to<br />

50 percent on their bottles by making their own,<br />

Actual savings varies business by business, based<br />

on distance from suppliers, and other considerations.<br />

On-site manufacturing also helps alleviate inventory<br />

problems. When bottlers make their own,<br />

they minimize the required warehouse space. Additionally,<br />

they eliminate concerns about the timing<br />

of vendor deliveries. Preform purchase and<br />

shipping issues, of course, remain the same.<br />

Blow molding machines specifically designed<br />

for use by the small- to medium-sized bottling<br />

companies are now available. No longer are the<br />

bigger operations the only ones who can benefit<br />

from making their own bottles.<br />

20 bioplastics MAGAZINE [02/07] Vol. 2


Processing<br />

PLA Bottle-making<br />

The technology of PLA-preform making was described in bioplastics<br />

MAGAZINE issue 02/2006. Here, we address the issues<br />

involved in designing a blow molder capable of manufacturing<br />

bottles from PLA preforms. We also look at the added benefits<br />

to the bottlers who use PLA bottles in the business.<br />

There is little difference between PLA and PET bottles in<br />

terms of appearance and performance. In most cases, what<br />

you can do with PET, you can do with PLA, including shape,<br />

size, color and other design features. Customers will not know<br />

the bottle is made of PLA unless you tell them. The difference<br />

is found in material characteristics. Hence, the requirement<br />

for PLA-specific blow molders, which must address special issues.<br />

Traditional PET blow molders cannot handle PLA successfully.<br />

The primary issue is one of material temperature, which<br />

includes both preheating of the preforms before entering the<br />

stretch-molding process, and subsequent cooling down of<br />

blown bottles.<br />

PLA preforms must be heated to approximately 75°C before<br />

entering the stretch-molding process, as opposed to 100°C for<br />

PET. At the higher temperature, PLA starts to shrink, so the<br />

typical PET blow molder is problematic with PLA.<br />

While PLA preforms heat up easily, the material is difficult<br />

to cool down; bottle deformation results when they are not<br />

adequately cooled before they exit the molds. Therefore, the<br />

freshly blown bottles must be cooled down quickly before they<br />

leave their molds. Consequently, special cooling techniques,<br />

therefore, must be designed and built into each mold.<br />

Additionally, precision process control over all heating lamps<br />

and blowing sequences is a must. Fluctuation of a degree or<br />

two either way leads to finished bottle quality issues. PLA‘s<br />

temperature sensitivity also requires enhanced airflow to ensure<br />

even heating in the heat tunnels. When multiple heat tunnels<br />

are involved, it is critical to precisely compensate for potentially<br />

different heat lamps and airflow so that bottles from<br />

each tunnel are consistently heated for optimal performance<br />

in the molds. This ensures a consistently high quality finished<br />

bottle.<br />

Precision control over air pressure and flows are equally<br />

critical. This technology helps move PLA material down from<br />

the preform‘s neck area to the bottom to make sure desired<br />

thickness is achieved in the bottle from bottom to top.<br />

Marketing benefits<br />

From a marketing perspective, there are several<br />

key advantages for bottlers to convert to<br />

PLA bottles.<br />

The first is product differentiation. Let‘s face it.<br />

In the case of bottled water for example, there‘s<br />

not much difference between one bottle of water<br />

and another. Brand name, methods of water<br />

purification, and price are points of differentiation.<br />

PLA becomes another point to help bottlers<br />

distinguish their product from their competition,<br />

particularly those still using PET bottles.<br />

The bottled water market often targets a demographic<br />

that prides itself in healthy lifestyles.<br />

Typically, this also includes environmental concern<br />

and a proclivity for "eco-friendly“ products.<br />

PLA offers a tangible environmentally friendly argument<br />

for its use. There‘s publicity to be gained<br />

and media attention to be earned by announcing<br />

a switch to PLA and by promoting product as using<br />

eco-friendly materials.<br />

Following are points about PLA that capture<br />

attention of the market, and result in legitimate<br />

environmental benefits:<br />

1. The production process of NatureWorks PLA<br />

uses 68 percent less fossil fuel resources than<br />

traditional PET plastics. NatureWorks has found<br />

that producing 1,000 bottles from PLA resin requires<br />

33 percent less fossil fuel resources and<br />

emits 42 percent less greenhouse gases than<br />

making 1,000 bottles from PET. (LCA Consultants<br />

Report).<br />

2. PLA is the world‘s first greenhouse-gasneutral<br />

polymer.<br />

Bottlers considering switching from PET preforms<br />

to PLA must be aware that preform selection<br />

and bottle design are critical to producing<br />

high-quality bottles. Make sure your blowmolding<br />

machine supplier approves your perform<br />

supplier and bottle design for optimal performance.<br />

bioplastics MAGAZINE [02/07] Vol. 2 21


Processing<br />

Frank Haesendonckx, Product Manager at SIG Corpoplast<br />

answers a few questions about high speed stretch blowmoulding<br />

of PLA-bottles.<br />

bioplastics MAGAZINE (bM): Can PLA be blowmoulded on standard<br />

equipment?<br />

Frank Haesendonckx: Even though the processing of PLA preforms<br />

and bottles can be implemented on “standard“ machines,<br />

several aspects have to be taken into account to produce bottles<br />

which meet the economical and industrial requirements.<br />

bM: For example?<br />

Interview:<br />

PLA blow<br />

moulding<br />

The first PLA-bottle in the USA,<br />

introduced by Biota from Ouray,<br />

Colorado and the first one in Europe<br />

from Belu, London, UK are stretch<br />

blowmoulded on BLOMAX<br />

machines from SIG Corpoplast,<br />

Hamburg, Germany.<br />

www.sigcorpoplast.com<br />

Frank Haesendonckx: For example the preform geometry: The<br />

behaviour of PLA is different from PET when stretching on a stretch<br />

blow moulding machine. It is therefore essential to adjust the preform<br />

geometry accordingly. We offer our Bottles&Shapes TM - expertise<br />

to help customers design the optimal preform.<br />

bM: What else has to be considered?<br />

Frank Haesendonckx: For optimal preheating in the infrared<br />

oven, the absorption behaviour of PLA requires additional “Carbon-<br />

Black“ additives which are also used in PET. The industry already<br />

provides biodegradable additives for this purpose. The transparency<br />

of the bottle is not or only inconspicuously influenced. Low heating<br />

temperatures are sufficient for PLA preheating. The heating profile<br />

in the oven must be adjusted to the preform geometry and the material<br />

properties.<br />

bM: And what about the actual blowing process?<br />

Frank Haesendonckx: The preblow-pressure for PLA stretch<br />

blowing corresponds to the pressure required for PET. The starting<br />

point for pre-blowing as well as the stretching rate must be adjusted<br />

for PLA.<br />

bM: We often hear about limited mechanical and thermal properties<br />

of PLA bottles?<br />

Frank Haesendonckx: The mechanical properties of PLA, which<br />

still do not meet those of PET, can be compensated for via skilful<br />

bottle design. For example, the stackability can be improved by an<br />

optimized bottle geometry. The thermal properties of PLA can still<br />

not be compared to PET. The bottle shrinkage which already starts<br />

at 45°C can partially be improved by deploying a so-called “relax“<br />

process.<br />

bM: How do you see the future of PLA as a bottle material?<br />

Frank Haesendonckx: PLA will be an increasingly interesting material<br />

for stretch blow moulding due to the rising oil price in the<br />

medium and long term. However, further improvements with regard<br />

to raw material as well as thermal and mechanical properties are<br />

essential.<br />

The main areas of application are still waters, products with short<br />

shelf life and products which are not hot filled.<br />

Further applications are provided if the barrier properties can be<br />

enhanced. A complete separation between material and product<br />

is guaranteed via use of SIG’s PLASMAX inner coating technology<br />

which enables packaging of sensitive beverages or food in PLA and<br />

ensures product quality.<br />

bM: Thank you very much<br />

22 bioplastics MAGAZINE [02/07] Vol. 2


Week 1<br />

Week 2<br />

Week 3<br />

Week 4<br />

BIODEGRADATION PROCESS<br />

EcoWorks ®<br />

www.EcoFilm.com<br />

info@CortecVCI.com<br />

1-800-4-CORTEC<br />

St. Paul, MN 55110 USA<br />

© Cortec Corporation 2006<br />

70®<br />

100%<br />

Biodegradable EcoWorks<br />

Replacement for Plastic and Polyethylene<br />

Up to 70% Bio-based With<br />

Annually Renewable Resources<br />

From thick rigid plastic cards to fl exible protective wrap,<br />

EcoWorks ® 70 by Cortec ® Research Chemists offers universal,<br />

biodegradable replacement to traditional plastic<br />

and polyethylene films. This patent pending breakthrough<br />

meets ASTM D6400 and DIN V 54 900. EcoWorks ® 70<br />

does not contain polyethylene or starch but relies heavily<br />

on renewable, bio-based polyester from corn. 100%<br />

biodegradable, it turns into water and carbon dioxide in<br />

commercial composting.<br />

ioPlastic.indd 1<br />

8/2/06 8:44:40 AM


Applications<br />

Sustainable Shrink -<br />

Solutions for the Shrink<br />

Sleeve Label Market<br />

Article contributed by<br />

Plastics Suppliers,<br />

Inc., Columbus, OH, USA<br />

Apple juice bottle<br />

sleeved with 50µ EarthFirst PLA<br />

TDO shrink sleeve film; printed<br />

by Folienprint, Germany<br />

www.earthfirstpla.com<br />

Today’s label market is facing challenges as well as<br />

great opportunities. With a push on being “green” as<br />

well as offering sustainable options, wouldn’t it be nice<br />

to have an alternative shrink sleeve label that is compostable,<br />

made from an annually renewable resource and reduces your<br />

environmental footprint? To achieve that goal, EarthFirst ® PLA<br />

TDO shrink sleeve label film is the solution. EarthFirst films<br />

are as good and often times better than petrochemical-based<br />

films when it comes to an economical environmental solution.<br />

EarthFirst is a biopolymer film made from PLA resin. Biopolymers<br />

are not new to the plastics’ industry. When they<br />

were first introduced, the cost to manufacture them was prohibitive.<br />

In the last five years, the cost has come down, making<br />

it a viable film to manufacture. One of the most common<br />

biopolymers used today is NatureWorks ® Polymer, made from<br />

# 2 field corn.<br />

The biopolymer shrink film, EarthFirst PLA TDO, has been<br />

on the market since October of 2005. Plastic Suppliers, Inc<br />

is the first company to manufacture this sustainable shrink<br />

film alternative changing the shrink sleeve label market. With<br />

impressive mechanical and thermal properties, EarthFirst<br />

shrink films are available as a viable replacement for most<br />

petrochemical-based shrink sleeve films.<br />

EarthFirst has many attributes that make it attractive to<br />

the shrink sleeve label market. EarthFirst has a natural dyne<br />

level of 38, is clear and rigid, and has direct food contact compliance.<br />

It shrinks at a lower temperature than for instance<br />

PET and is capable of shrinking up to 75 percent In addition,<br />

EarthFirst shrink sleeve film can be stored up to 40° Celsius.<br />

Therefore this film is extremely stable and can perform on all<br />

types of shrink label tunnels regardless if steam or hot air is<br />

used. All of these features and a great upside; it’s made from<br />

corn, an annually renewable resource.<br />

Plastic Suppliers, Inc. is committed to a strong environmental<br />

leadership role in protecting our planet. The world is going<br />

“green” and the trend toward biopolymers and environmentally<br />

friendly films continues to expand. Nationally, Plastic<br />

Suppliers and its’ European subsidiary Sidaplax play active<br />

24 bioplastics MAGAZINE [02/07] Vol. 2


oles as members of the Sustainable Packaging Coalition<br />

(SPC), European Bioplastics, Belgian Biopackaging<br />

and UK compostable group. EarthFirst has been<br />

certified by the Biodegradable Products Institute and<br />

DinCertco stating it is a compostable film under the<br />

ASTM 6400 and EN 13432 standards. Plastic Suppliers<br />

is committed to understanding the impact of such<br />

products upon the environment and will continue to<br />

seek out opportunities to participate in environmental<br />

research and associations to create an understanding<br />

of how biopolymers may be used in the future. There<br />

are many different biopolymers out in the marketplace<br />

today that are produced by various manufacturing<br />

means. The revolutionary EarthFirst TDO is the only<br />

film targeting the shrink sleeve label market. It is paving<br />

the way in this high profile industry.<br />

Soda drink bottle sleeved by<br />

PackStar, USA for Plastic Suppliers<br />

Inc. with a 50µ EarthFirst PLA TDO<br />

shrink sleeve film.<br />

bioplastics MAGAZINE [02/07] Vol. 2 25


Applications<br />

Talud<br />

protection<br />

Biodegradable non-wovens<br />

made from PLA<br />

DS Technical Nonwovens, a Belgian company based<br />

in Flanders, offers Hortaflex ® , a biodegradable<br />

non-woven with or without the inclusion of (grass)<br />

seeds. The non-woven is used as agro, geo or horticultural<br />

fibre fleece. It can be used as protection against erosion of<br />

slopes, battering, and as landscape protection. DS Technical<br />

is currently looking for customers interested in further<br />

developing the possibilities of this new biomaterial.<br />

Soil and root protection<br />

The new product is a fully biodegradable non-woven made<br />

of PLA fibres and is an answer to various EU regulations (e.g.<br />

Kyoto, REACH, reduced use of herbicides, etc.). Originally it<br />

was developed for the carpet and technical textiles industry.<br />

The production process has been developed in-house.<br />

The non-wovens can be offered with different properties:<br />

mass per unit area (from 120g/m² up to 1.5 kg /m²), needlepunched<br />

or not; structured and calendered. Also tenacity,<br />

elongation or other mechanical properties can be varied.<br />

Other options are the introduction of additives, lamination,<br />

etc. The recently-developed biodegradable non-woven has<br />

been used as a base for the new product, and the process<br />

has been adapted to include (grass) seeds. First tests show<br />

that the results when growing grass were better than when<br />

using carpets with a cellulose base, which is a promising<br />

sign for other applications. First ideas for possible applications<br />

of this product are as a substitute for non-biodegradable<br />

products such as the plastics materials that are used to<br />

avoid weeds, etc. It offers a good alternative to the existing<br />

mulch-mats - certainly where weight becomes important<br />

(e.g. roof gardens). On the other hand other applications<br />

also appear possible (e.g. the building sector). As a result<br />

the company is looking for new applications for this nonwoven,<br />

which it would be pleased to develop in collaboration<br />

with customers.<br />

dirk@dstextileplatform.com<br />

26 bioplastics MAGAZINE [02/07] Vol. 2


Bio-plastics for<br />

BIO CAPS<br />

• Made from wheat, corn and<br />

potatoe starch<br />

• Compostable<br />

• Biodegradable<br />

NEW!<br />

Wiedmer AG · Am Linthli 2 · 8752 Näfels · Switzerland<br />

Phone: ++41 (0)55 618 44 99 · Fax: ++41 (0)55 618 44 98 · info@wiedmer-plastic.com · www.wiedmer-plastic.com<br />

Incorporating the 2nd global<br />

Bioplastics Awards<br />

Recognising innovation in bioplastics<br />

Don’t let your company miss out. Email<br />

chris.smith@emap.com for full details and entry pack.<br />

Book before 20th July to<br />

receive a Super Early Bird<br />

Discount of €250 plus<br />

a further €100 off!<br />

Performance Through Innovation<br />

With growing emphasis on sustainable manufacturing,<br />

bioplastics certainly have a role to play in the future of<br />

the plastics industry. But there are always questions.<br />

What materials are available? How do they really<br />

perform? What are the real environmental and<br />

financial costs? What are the end-of-life options?<br />

How can bioplastics fit into existing waste<br />

management programmes?<br />

5-6 December 2007 - Frankfurt, Germany<br />

The Bioplastics conference is the place to find<br />

out the answers to these and all other questions.<br />

The programme is assembled by plastics industry<br />

professionals for buyers, processors and users of<br />

plastics, and will be launched in full later this year.<br />

However, if you book your place now, you can<br />

take advantage of a saving of €350.<br />

The worlds longest running independant Bioplastics<br />

conference - now in its 9th year<br />

To register -<br />

Tel: +44 (0)20 7841 4811 (International)<br />

0845 056 5069 (UK Only)<br />

Email: EPNconferences@emap.com EPNJUNAD


Applications<br />

Article contributed by<br />

Patrick Zimmermann,<br />

FkuR Kunststoff GmbH,<br />

Willich, Germany<br />

Compostable<br />

mulch films<br />

made from<br />

PLA blends<br />

www.fkur.com<br />

www.umsicht.fraunhofer.de<br />

www.oerlemansplastics.nl<br />

FKuR Kunststoff GmbH of Willich, in cooperation with<br />

the Fraunhofer Institute UMSICHT, has developed and<br />

brought to market the first compostable mulch film<br />

based on a PLA blend. The PLA blends used are a mixture of<br />

PLA (polylactide) and further biodegradable polymers plus additives.<br />

Industrial production and application testing of the PLA<br />

mulch films have been carried out by Oerlemans Plastics B.V.<br />

of Genderen in the Netherlands. In comparison to other biodegradable<br />

films this novel bio mulch film has the significant<br />

advantage of degrading more slowly and being less sensitive to<br />

climatic variations.<br />

In 2004 FKuR had already initiated the first tests for biodegradable<br />

mulch films. The degradation behaviour of the film<br />

under “open-air conditions“ was assayed in laboratory tests.<br />

Since 2005 the industrial application of the film has been carried<br />

out together with Oerlemans Plastics. A crucial factor that<br />

persuaded Oerlemans Plastics to go for the FKuR PLA mulch<br />

film was, amongst others, the problem-free processing of the<br />

film on conventional extruders, as used in the production of<br />

LDPE films. In the run-up to industrial production the application<br />

of the Bio-Flex ® mulch film was successfully tested on<br />

various crops by several European research institutes and experimental<br />

stations.<br />

Since 2005 the compostable PLA mulch films have been<br />

tested worldwide on a variety of crops in several climates.<br />

The crop yield with this biofilm is comparable to conventional<br />

mulch films made from PE. The PLA mulch films are laid out<br />

using conventional laying machines without any difficulty. An<br />

important advantage in comparison to other biofilms based on,<br />

for example starch, lies in the considerably slower degradation<br />

of the film and its resistance to climatic variations. A further<br />

advantage of the application of bio mulch films for agriculture<br />

is that the film can be easily ploughed in after harvesting, and<br />

continues to degrade in the soil. The application of Bio-Flex<br />

mulch films reduces the amount of work and the costs of disposal.<br />

The granules and the film are fully compostable according to<br />

EN 13432. Additionally they are certified in accordance with to<br />

DIN Certco, OK Compost, NFU 52001 and Ecocert.<br />

28 bioplastics MAGAZINE [02/07] Vol. 2


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Politics<br />

What’s happening in the<br />

www.bpiworld.org<br />

www.biocycle.net<br />

www.findacomposter.com<br />

www.beps.org<br />

Article contributed by Steven Mojo,<br />

Executive Director of the<br />

Biodegradable Products Institute (BPI),<br />

New York, NY, USA<br />

It is truly a new world in North America, as the<br />

pace of organics diversion continues to increase.<br />

Discussions around the issues of sustainability,<br />

increasing use of renewable resources<br />

and greenhouse gas reductions are coming to the<br />

forefront.<br />

Retailer Concerns about Packaging<br />

In late 2005, Wal-Mart announced its sustainability<br />

drive focused on three aggressive goals:<br />

1. “To Be Supplied 100% By Renewable Energy”:<br />

2. ”To Create Zero Waste”:<br />

3. ”To Sell Products That Sustain Our Resources<br />

& Environment”:<br />

As part of this effort, Wal-Mart has developed a<br />

“scorecard” for packaging and is asking suppliers<br />

to document the use of recyclable and compostable<br />

packaging (via ASTM D6400) and to verify the<br />

use of renewable feedstocks (using ASTM D6866).<br />

This scorecard came on-line in March 2007 and<br />

manufacturers will be feeding it data throughout<br />

this year.<br />

Wal-Mart’s efforts, like Sainsbury’s in the UK,<br />

call attention to the growing array of new materials<br />

available to packagers around the globe. At the<br />

same time, packagers are starting to inquire about<br />

BPI certification and the benefits of the BPI Compostable<br />

Logo. Also, manufacturers are striving to<br />

increase the percentage of renewably based materials,<br />

in order to help reduce their environmental<br />

footprint and earn credits from Wal-Mart.<br />

The BPI and its members are immersed in the<br />

issues of renewable resources, compostability and<br />

biodegradability for almost a decade. As such, they<br />

are in a position to help Wal-Mart and others understand<br />

the importance of using ASTM Test Methods<br />

and Specifications for verifying claims.<br />

This project is a “work in progress”. It will continue<br />

to evolve as technology and properties improve<br />

and importantly will impact suppliers, consumers<br />

and everyone in between.<br />

30 bioplastics MAGAZINE [02/07] Vol. 2


New World?<br />

New Legislation in California<br />

California continues to set the pace in the area of<br />

compostables. Last year, Governor Schwarzenegger<br />

signed labeling legislation which restricts the<br />

use of the terms “biodegradable”, “compostable”<br />

and “degradable” on plastic food containers to<br />

only those products that meet ASTM D6400. This<br />

legislation is similar to the one passed in 2004 for<br />

labelling on plastic bags. Both of the new laws<br />

are designed to address the abuse and misuse of<br />

these terms and the resulting confusion.<br />

New Ordinances in San Francisco<br />

In 2006, San Francisco passed ordinance No<br />

295-06 which bans the use of polystyrene food<br />

service packaging and mandates the use of compostable<br />

or recyclable alternatives, if their additional<br />

costs are within 15% of non-compostable<br />

or non-recyclable alternatives. This ordinance<br />

is designed to help minimize the waste going to<br />

landfills from these operations. Also, this ordinance<br />

takes advantage of the City’s well developed<br />

recycling and composting infrastructure for<br />

businesses and households.<br />

On March 27, 2007, San Francisco passed an<br />

ordinance mandating the use of compostable<br />

plastic bags or recyclable kraft paper bags by<br />

large food chains and pharmacies. Given the city’s<br />

widespread organic collection system, the compostable<br />

bags can serve two purposes. First they<br />

will bring home the groceries and then will have<br />

a second life as a liner for residential “kitchen<br />

catchers”. The new law takes effect by the end of<br />

this year.<br />

Food Scrap Diversion Programs Grow<br />

More communities, especially in Eastern Canada<br />

and on the West Coast are implementing food<br />

scrap diversion efforts. Portland (Oregon) and<br />

Seattle (Washington), join the ranks of San Francisco<br />

and Oakland, (California) in implementing<br />

commercial collection programs and in some<br />

communities’ residential ones as well. In the<br />

Canadian province of Ontario organics diversion<br />

efforts are beginning to “skyrocket” according to<br />

one BPI member.<br />

These are driven by the dual goals of continuing<br />

to increase the overall diversion rate from landfills<br />

as well as to reduce greenhouse gas emissions<br />

from landfills. For example, in the US, landfills<br />

are the single largest of anthropomorphic<br />

methane releases into the atmosphere, according<br />

to the US Environmental Protection Agency. Further<br />

the same study shows that landfills are the<br />

number 4 contributor of global warming gases.<br />

Findacomposter.com introduced<br />

The BPI and BioCycle magazine from Emmaus<br />

(Pennsylvania) are joint sponsors of a<br />

new website dedicated to increasing the awareness<br />

of composting in the US. The new site<br />

“findacomposter.com” was debuted in April 2007<br />

at the BioCycle West Coast Conference in San Diego<br />

(California). The site will provide consumers<br />

information about food scrap collection programs<br />

near them and will be available for all to use at<br />

no charge. Composters can participate at no cost<br />

and all entries will be verified by BioCycle. The BPI<br />

and its members are proud to be the first sponsor<br />

to support this effort and to help put composting<br />

on the map.<br />

The BPI and BEPS team up on<br />

a meeting in October, 2007<br />

The BEPS and BPI are jointly sponsoring a<br />

conference from Oct. 17-19th in Vancouver,<br />

Washington. This meeting will combine presentations<br />

and discussions on biodegradable and<br />

renewable materials from both academia and<br />

industry. Presenters are being lined up from<br />

North America, Europe and Asia. The conference<br />

will be a “zero waste” event. It is being held at<br />

the Hilton Hotel, which has been cited for sustainable<br />

practices and it will have an active food<br />

scrap diversion effort by the end of the summer.<br />

Learn more about the conference at beps.org<br />

bioplastics MAGAZINE [02/07] Vol. 2 31


From Science & Research<br />

Novel Nanostructured<br />

Crosslinked<br />

hyperbranched<br />

polymer (HBP)<br />

Fig 1: Transmission electron photomicrograph of modified PLA<br />

showing nanoscale dimension of crosslinked HBP i.e. < 100nm<br />

(stained dark phase). Scale bar: 100 nm.<br />

95 wt.% Modified PLA<br />

+ 5 wt.% Talc<br />

98 wt.% Modified PLA<br />

+ 2 wt.% Organo-clay<br />

Modified PLA<br />

Unmodified PLA<br />

3,2<br />

3,2<br />

3,2<br />

3,5<br />

4<br />

37<br />

83<br />

104<br />

Tensile Modulus<br />

(GPa)<br />

Elongation at<br />

break (%)<br />

0 20 40 60 80 100 120<br />

Fig 2: Tensile properties of hyperbranched polymer modified PLA,<br />

its organo-clay based nanocomposites and talc filled composites.<br />

Renewable resource based bioplastics<br />

are the next generation of materials,<br />

which are expected to play a major<br />

role in building of a sustainable bioeconomy.<br />

Polylactide (PLA) is a renewable resource<br />

based bioplastic. However, the inherent<br />

brittleness (poor elongation at break and impact<br />

strength) of PLA poses considerable scientific<br />

challenges and limits its large-scale<br />

commercial applications. Numerous approaches<br />

such as plasticization, blending with<br />

tough polymers and elastomers have been attempted<br />

to overcome its brittleness however<br />

with huge sacrifice of strength and modulus of<br />

the polylactides.<br />

At Michigan State University, recently new<br />

polylactide based materials having unique<br />

stiffness-toughness properties were invented<br />

by the authors. The research was focused on<br />

exploring the role of emerging hyperbranched<br />

polymers in modifying the PLA base resin. Hyperbranched<br />

polymers (HBP) are considered<br />

as mutant offspring of dendrimers. The nanoscale<br />

dimensions, unique physical and chemical<br />

properties of HBP make them a unique<br />

design tool for tailoring the material properties.<br />

Hydroxyl functional aliphatic polyesters<br />

are HBPs that consist of a polyalcohol core<br />

from which branches extend, forming a coreshell<br />

structure. These HBPs can have abundant<br />

hydroxyl groups on their periphery leading<br />

to their high surface functionalities .<br />

This research is based on creating new nanoscale<br />

hyperbranched organic particles in<br />

a PLA matrix (Biomer ® L9000 from Biomer,<br />

Germany) during industrially relevant melt<br />

processing. In this approach, a commercially<br />

32 bioplastics MAGAZINE [02/07] Vol. 2


From Science & Research<br />

Polylactide Bioplastics<br />

for Multifarious Applications<br />

Article contributed by Dr. Amar K. Mohanty,<br />

associate professor and Rahul Bhardwaj,<br />

PhD student, both at School of Packaging,<br />

Michigan State University, East Lansing,<br />

MI, USA<br />

available hydroxyl functional hyperbranched<br />

polymer (BOLTORN TM H2004 from Perstorp,<br />

Sweden) was selectively in-situ crosslinked<br />

with a polyanhydride (PA-18, LV from Chevron-<br />

Phillips, USA) in the PLA matrix by reactive extrusion.<br />

There was formation of a novel nanostructured<br />

polylactide based two-phase system<br />

(Figure 1), in which crosslinked HBP particles<br />

were present in nano-domains (< 100 nm). The<br />

modified PLA, having 90-92 weight-% of pure<br />

PLA, exhibited an improvement in elongation at<br />

break of about 800-1000% with minimal sacrifice<br />

of tensile strength and modulus.<br />

The findings showed that such a modified<br />

PLA bioplastic material can act as an ideal matrix<br />

for nano-clay or talc as well as natural fiber<br />

reinforcements leading to the development<br />

of many PLA based materials with attractive<br />

properties. Figure 2 represents the tensile<br />

properties of such a modified PLA, its organoclay<br />

(Southern Clay Products, USA) reinforced<br />

nanocomposites and talc (Luzenac, USA) filled<br />

composites. The modified PLA surprisingly exhibited<br />

20 and 25 fold improvement in elongation<br />

at break on specific loadings of nanoclay<br />

and talc particles. These findings also revealed<br />

that the modified PLA can act as an additive for<br />

the dispersion of nanoclay in polylactide based<br />

nanocomposites. The potential impact of this<br />

research on PLA can lead to the enhancement<br />

of its stiffness-toughness balance, improved<br />

melt strength, tailored melt viscosity and ease<br />

of processing, which can be exploited in a variety<br />

of products and processes. This research<br />

is financially supported by the US National Science<br />

Foundation- Division of Design, Manufacture,<br />

and Industrial Innovation (NSF-DMII)<br />

program.<br />

www.egr.msu.edu/cmsc/biomaterials<br />

105x148_bioplastics www.msu.edu/~mohantya/<br />

MAG_4c 16.05.2007 12:49 Uhr Seite 1<br />

www.packaging.msu.edu/Mohanty.php<br />

Organizer<br />

NürnbergMesse<br />

Tel +49 (0) 9 11. 86 06-0<br />

info@nuernbergmesse.de<br />

www.brau-beviale.de<br />

C M Y CM MY CY CMY K<br />

Note the date!<br />

Nuremberg, Germany<br />

14 – 16.11.2007<br />

47. European Trade Fair<br />

for the Beverage Industry<br />

2007<br />

Raw Materials – Technologies –<br />

Logistics – Marketing<br />

bioplastics MAGAZINE [02/07] Vol. 2 33


From Science & Research<br />

Protein-Based Plastics and<br />

The adoption of protein-based plastic by industry<br />

has been slow for several reasons; principal among<br />

them are costs of raw materials, limited thermalmechanical<br />

strength, and solvent sensitivity. There are,<br />

however, strong reasons for using protein-based plastics,<br />

including the reduction of petrochemical dependence as<br />

well as the reduction of greenhouse gases and other environmental<br />

impacts, such as landfill usage. In addition,<br />

the poor properties can be significantly enhanced with<br />

appropriate additives and through careful processing<br />

techniques. For these reasons there is a renewed push<br />

for industry to seriously consider the adoption of proteinbased<br />

polymers for many existing applications which use<br />

petroleum-derived plastics.<br />

Article contributed by<br />

David Grewell, Dpt. of Agricultural<br />

and Biosystems Engineering;<br />

Michael Kessler, Dpt. of Materials Science<br />

and Engineering;<br />

William Graves, Dpt. of Horticulture; all from<br />

Iowa State University, Ames, Iowa, USA<br />

www.egr.msu.edu/cmsc/biomaterials<br />

Fig 2: Plant pots formulated from Zein (left)<br />

and petrochemical plastic pot<br />

Additives and Processing<br />

Proteins in their native state can be resilient, strong,<br />

and low density macromolecules, as evident by several<br />

biological protein structures, such as bone and hair.<br />

However, to utilize the proteins, their structure must fist<br />

be partially broken down during processing and reformed<br />

to a new structure. As such, the thermal-mechanical<br />

and water absorption properties of protein-based plastics<br />

depend heavily on several factors, such as the plasticizers<br />

used (e.g., glycerol, ethylene glycerol, butanediol,<br />

sorghum wax, ethanol and sorbitol), the addition of<br />

cross-linking agents (e.g., zinc sulfate, acedic anhydride,<br />

formaldehyde), and processing parameters (e.g., extrusion<br />

pressure and temperature and initial moisture content).<br />

Reduce Moisture Susceptibility<br />

Work at Iowa State University (ISU) is under way to<br />

characterize these protein derived polymers and evaluate<br />

various treatments and formulations to enhance<br />

their properties. For example, it is now understood that<br />

the addition of selective salts, such as zinc stearate and<br />

zinc sulfate, can reduce the water sensitivity of plastics<br />

derived from soybean proteins. In addition, it has been<br />

demonstrated that thermal treatments (ranging from 80<br />

to 120 °C) can reduce the susceptibility of these plastics<br />

to water. Soy plastics were also co-blended 50:50 with<br />

polycaprolactone (PCL), a biodegradable polyester, in order<br />

to reduce water absorption.<br />

Figure 1 shows that the control sample, untreated<br />

soy plastics, absorbs over 150% water by weight<br />

within a few hours. It is also seen that by heat<br />

treatment the water absorption decreased<br />

significantly after 24 hrs. However, the largest<br />

improvement was seen when the soy plastic was<br />

blended with biodegradable PCL, where the water<br />

absorption was less than 20% even after 24 hrs. of<br />

exposure. It is believed that the relatively water insoluble<br />

PCL formed a continuous phase within the<br />

blend and shrouded the soy plastic from the water.<br />

This allows the PCL to reduce water exposure of the<br />

soy plastic thus reducing the overall water sensitivity.<br />

While the addition of 2 parts of zinc stearate and zinc<br />

sulfate did reduce the water absorption, the reduction is<br />

limited compared to heat treatment and co-blending with<br />

PCL.<br />

34 bioplastics MAGAZINE [02/07] Vol. 2


From Science & Research<br />

Applications<br />

Nano-Clays and Foamed Structures<br />

Other mechanical, thermal, and physicochemical property<br />

enhancement techniques being investigated at ISU<br />

include the use of high powered ultrasonics to promote<br />

exfoliation of nano-clays. These polymer-layered silicate<br />

nanocomposites can have enhanced vapor barrier properties,<br />

further reducing water absorption, while simultaneously<br />

increasing tensile modulus and strength and<br />

heat distortion temperature.<br />

Fig 3: Natural fiber reinforcement<br />

200<br />

In order to overcome the issues related to costs of raw<br />

materials, researchers at ISU are working with Trexel<br />

Corp. (Woburn, Massachusetts) to characterize foamed<br />

substrates. It is expected that these materials will reduce<br />

the raw material requirements while maintaining<br />

mechanical strength.<br />

Potential Applications<br />

Resulting data from this work were used to formulate<br />

selected grades and processing conditions for application<br />

studies. In two initial application examples, Creative<br />

Composites (Brooklyn, Iowa), and Vermeer Manufacturing<br />

Co. (Pella, Iowa) are supplying materials to evaluate<br />

their use for selected products, including hay bale sealing<br />

films and locomotive grease applicators.<br />

Some studies have shown that water resistant films<br />

formulated from Zein, a protein derived from corn, can be<br />

formed as thin as 100 μm. The films are flexible and relatively<br />

strong. Currently, processing and characterization<br />

tests are being performed with these films.<br />

Other applications include bio-degradable pots for<br />

plants. The photograph (Fig. 2) shows a pot formulated<br />

from Zein (left) next to a conventional petrochemical plastic<br />

pot (right). Other formulations include the reinforcement<br />

of the Zein polymer with natural fibers (Fig 3).<br />

While this research is in its early stages, the preliminary<br />

results are promising. It has already been shown<br />

that the water sensitivity of soy protein plastics can be<br />

decreased through simple blending or heat treatment.<br />

Similar enhancement in mechanical properties and cost<br />

with the incorporation of exfoliated clay platelets and<br />

Zein-based proteins is expected. The authors would like<br />

to gratefully acknowledge the Grow Iowa Value Funds for<br />

supporting this work, as well as Zein Corporation, Trexel<br />

Corporation, Creative Composites, and Vermeer Manufacturing<br />

Co.<br />

Moisture absorbition (%wt)<br />

150<br />

100<br />

50<br />

0<br />

0 5 10 15 20 25 30<br />

Fig 1: Moisture absorption<br />

over time<br />

Time (hrs)<br />

Fig 4: Reinforcing rib structure<br />

Control<br />

ZnS=4<br />

Zinc Steartate<br />

80 °C<br />

100 °C<br />

120 °C<br />

PCL Coblend<br />

bioplastics MAGAZINE [02/07] Vol. 2 35


Basics<br />

Bioplastics vs.<br />

Agricultural Land<br />

Calculations, estimates,<br />

assumptions and conclusions<br />

How much bioplastics do I get from agricultural land?<br />

How much bioplastics can be obtained from 1 hectare of land? Differ<br />

ent figures are available to answer this question. We look at just three<br />

bioplastics as examples.<br />

PLA:<br />

There is a lot of confusion about the<br />

amounts of bioplastics that can be<br />

obtained from a given quantity of<br />

agricultural crops, and how much of these<br />

agricultural crops can be harvested from<br />

a given agricultural area. And last but not<br />

least: Is there enough agricultural land<br />

available to grow crops for bioplastics?<br />

This article can be regarded as a first<br />

attempt to shed some light onto this<br />

confusion, although the considerations<br />

are very much simplified in order<br />

to arrive at an initial overview. As with<br />

other articles in this „Basics“ section of<br />

bioplastics MAGAZINE, experts in the aspects<br />

discussed here are expressly invited<br />

to share their knowledge. Please contact<br />

the editor. We will assemble all of the information<br />

received and present an update<br />

in one of the following issues.<br />

Sources<br />

[1] FAQ at www.natureworksllc.com<br />

[2] University of Nebraska (www.ianrpubs.<br />

unl.edu/epublic/pages/publicationD.<br />

jsp?publicationId=144)<br />

[3] Personal information, Erwin Vink,<br />

NatureWorks<br />

[4] The Concept of Novamont‘s Biorefinery<br />

integrated in the Territory, Catia Bastioli,<br />

Novamont, Brussels, Nov. 2006<br />

[5] National Corn Growers Association<br />

(www.ncga.com/CYC/Winners/national.asp)<br />

[6] Fachagentur nachwachsende Rohstoffe,<br />

brochure: „Bioplastics – Plants, Raw Materials,<br />

Products“ (www.fnr-server.de/pdf/literatur/pdf_237bioplastics2006.pdf)<br />

[7] Personal information, Brian Igoe, Metabolix<br />

[8] D. Bockey, UFOP, based on information<br />

from the Bayerisches Staatsministerium für<br />

Landwirtschaft und Forsten (in Bioenergie<br />

- ein Markt der Zukunft, TTL Jena, A. Vetter,<br />

2006)<br />

[9] www.european-bioplastics.org<br />

The FAQ page at natureworksllc.com reports that on average, approximately<br />

2.5 kg of corn (15% moisture) are required per kg of PLA. This<br />

does not mean that the difference (1.5 kg corn) is all waste. A part of this<br />

difference is simply water, a part of it ends up in other corn wet mill products<br />

such as germ oil, corn gluten meal and corn gluten feed, and part<br />

represents the yield losses in the different processes [1].<br />

Depending on the geographical location and whether a field is irrigated<br />

or not, the yield of corn per hectare differs significantly. Yields vary from<br />

60 bushels/acre (3.7 tons/hectare) from Western Nebraska dryland [2]<br />

through 148 bushels/acre (9.3 t/ha) as the average corn yield in the USA in<br />

2004/2005 [3] and 12 t/ha in Europe [4], going right up to 332 bu/acre (20.7<br />

t/ha) reported from the National Corn Yield Contest in the USA 2006 [5]<br />

If we take the US average in 2004/2005 we can calculate an average<br />

“yield“ of 3.72 tons of PLA that can be “harvested“ from one hectare of<br />

land. Other sources report approximately 2 tons [6] or 2.5 tons [1] of PLA<br />

per hectare.<br />

è PLA: Approx. 2-3.7 tons / hectare<br />

PHA:<br />

Metabolix report that currently corn is the major source for their PHA.<br />

For 1 kg of PHA approximately 4.66 kg corn is needed [7].<br />

Based on the information on corn yield above (average 9.3 t/ha), it is<br />

clear that about 2 tons of PHA per hectare can be harvested.<br />

è PHA: Approx. 2 tons / hectare<br />

MaterBi:<br />

MaterBi by Novamont [4] is a bioplastics material based on starch derived<br />

from corn and oils (derived in turn from oilseeds). Approximately 0.5<br />

kg of corn and 1.4 kg of oilseeds, plus other components and additives,<br />

are needed to produce 1 kg of one example formulation of MaterBi.<br />

Given the corn yield of about 12 t/ha and a vegetable oil productivity of<br />

1 t/ha [g] Novamont calculate a yield of approximately 2.5 tons of an average<br />

of different MaterBi resins that can be harvested from one hectare.<br />

è MaterBi: Approx. 2.5 tons / ha<br />

36 bioplastics MAGAZINE [02/07] Vol. 2


Basics<br />

Photo: Novamont<br />

How much agricultural crop<br />

land is available?<br />

We will start with some basic figures. The total land<br />

area of this planet is about 13 billion hectares. The usable<br />

agricultural and silvicultural (forestry) area is about<br />

5 billion hectares and agricultural crop land is given as<br />

approximately 1.38 billion ha [8]. The remaining question<br />

is: How much of this can be used for the production of<br />

agricultural crops for bioplastics?<br />

Here are some figures as a general indication:<br />

It is known that in many countries of the world a certain<br />

amount of agricultural crop land is not permitted to be<br />

used for food production, because the overproduction of<br />

food leads to an “imbalance in market prices“. In Europe<br />

the Common Agricultural Policy therefore has required<br />

the establishment of so called “set-aside zones“ where<br />

food products must not be grown. This measure is aimed<br />

at reducing the high level of agricultural subsidies in Europe.<br />

European Bioplastics estimates the available area<br />

for non-food production in the European Union (EU27) at<br />

around 20 million hectares [9] Based on the figures above<br />

this is enough for 40-50 million tons of bioplastics.<br />

So even if bioenergy, bioethanol and biodiesel to<br />

power our cars, and other chemical intermediate<br />

products, require agricultural crops there should be<br />

enough agricultural land available for the production<br />

of bioplastics. And bioplastics can after their material<br />

life be recovered by e.g. incineration, which gives<br />

a “double dividend“ from the respective agricultural<br />

resource. Both in ecological as well as in economical<br />

terms, bioplastics should therefore be a very favourable<br />

way of making use of agricultural commodities.<br />

In addition to this, it should be mentioned that we<br />

have discussed only primary agricultural crops here.<br />

However, developments are under way to create bioplastics<br />

from secondary biomaterial such as straw,<br />

stems and leaves, and even from municipal waste<br />

water.<br />

In this respect, it is interesting to consider the situation<br />

in the U.S.: The full capacity of NatureWorks‘ PLA plant<br />

of 140,000 tons per year needs only about 0.14% of the<br />

total corn produced in the USA.<br />

How much bioplastics<br />

will be needed?<br />

Latest figures say that the annual global production of<br />

all plastics today is about 240 million tons. If estimates<br />

that say about 10% of all plastics could be replaced by<br />

bioplastics are correct, this would amount to 24 million<br />

tons. For these 24 million tons, according to the figures<br />

above, agricultural crop land of approximalety 10 million<br />

hectares would be needed.<br />

This is 0.7 percent of the global agricultural crop land<br />

or 50 percent of the European set-aside zones - which<br />

are not even being used for food production.<br />

bioplastics MAGAZINE [02/07] Vol. 2 37


Basics<br />

A certain number of products made of bioplastics are<br />

already available in the market. Almost all of them are<br />

labelled with some kind of a logo that tells the consumer<br />

about the special character of the plastics material<br />

used. These logos and their background are introduced by<br />

bioplastics MAGAZINE in this series. Here questions such as:<br />

What is the origin and history of a logo? What does it mean?<br />

Which rules are involved with it? will be adressed.<br />

Logos Part 4:<br />

The Scandinavian<br />

Once in a while you find an “apple” logo on bioplastics<br />

products. In fact there are two different “apple” logos,<br />

one being used in Norway and the other in Finland.<br />

The Finnish Solid Waste Association, FSWA (in Finnish<br />

Jätelaitosyhdistys), represents Finnish regional and municipal<br />

waste management companies. The member companies<br />

take care of the waste management for about five million<br />

citizens (94 % of the total population).<br />

FSWA is an organisation that acts as a link between the<br />

member companies, the Finnish authorities and the European<br />

Union. It is a strong developer of waste management in<br />

Finland and guarantees a sound basis for the member companies‘<br />

operations.<br />

About ten years ago FSWA member companies started to<br />

collect biowaste, mainly organic kitchen waste, from households.<br />

“We encourage people to compost their yard waste<br />

at home in their own gardens or in special compost bins,“<br />

says Markku Salo, Director of FSWA. Part of a large communication<br />

and promotion campaign in which the Ministry<br />

for Environment was also involved, was the creation of the<br />

biowaste-bin for the<br />

kitchen, lined with a<br />

bioplastics-bag<br />

www.jly.fi<br />

www.avfallnorge.no<br />

“Finnish apple logo“. The reason for creating the logo was<br />

quite simple. When biodegradable waste bags became<br />

available people saw the bags in biowaste bins and thought<br />

they could dispose of their kitchen waste in plastic bags.<br />

So in order to distinguish compostable biowaste bags from<br />

“normal“ plastic bags, the apple-logo was printed on the<br />

bio-bags. “In Finland, biowaste bags are more or less the<br />

only compostable plastics products that are available,“ says<br />

Markku Salo. All biowaste bags carrying the apple logo are<br />

certified in line with EN 13432. In Finland today five suppliers<br />

sell certified biowaste bags with the apple logo. The<br />

logo is printed on each bag. The composting bag producers<br />

get a “brand” and a regularly promoted logo for their products.<br />

Consumers can be sure that the product meets the<br />

requirements of the standard. The same logo is well known<br />

from the waste organisation information material, biowaste<br />

bins and collection vehicles.<br />

In Norway, the situation is quite similar, as Henrik Lystad<br />

of Avfall Norge explains.<br />

The system for recommendation and labelling of compostable<br />

waste bags is operated since 2002 by Avfall Norge<br />

(Waste Management Norway, formerly NRF). Avfall Norge<br />

is a branch and interest organisation for approximately 90<br />

municipal and intermunicipal solid waste organisations and<br />

about 50 private companies. The municipal members cover<br />

approximately 95 percent of Norway’s inhabitants.<br />

In Norway, source separation is introduced for over<br />

60 % of the population. The municipality often buys the<br />

waste bags for their inhabitants, i.e. the provision of the<br />

bags being incluced in the refuse collection charge. Thus<br />

the logo was not created as a marketing instrument, “but<br />

to help the municipalities to distinguish the ‘good from the<br />

less good’ waste bag products,” as Henrik Lystad puts it.<br />

When the logo was created, Henrik worked with a soil research<br />

institute where he prepared the “System for recommendation<br />

and labelling of compostable waste bags”. In<br />

38 bioplastics MAGAZINE [02/07] Vol. 2


Basics<br />

“apples“<br />

his report he suggested an apple logo, based<br />

on an already existing logo. The apple was<br />

originally created as a logo for stickers etc<br />

to put on source separation bins for biowaste<br />

together with other logos for paper, glass, textiles,<br />

residual waste etc. Later, in 2002 the apple<br />

logo for compostable waste bags was created, using<br />

the apple in conjunction with a frame all around,<br />

the word “compostable” and a certification number<br />

to be used with biowaste-bags, distinguishing<br />

it from the waste bin sticker.<br />

Like in Finland, the Norwegian<br />

apple logo is only to be used in<br />

conjunction with biowaste-bags.<br />

It may be used when the respective<br />

CEN or DIN standards for compostability<br />

are fulfilled. To ensure the functionality<br />

of the waste bags an additional criterion was<br />

defined focusing on the durability of the bags.<br />

The test method was adapted from the Belgian VGS;<br />

”D9 programme: Bags made of bioplastics intended to collect biodegradable<br />

houehold refuse” (AIB Vincotte 1999). According to this test<br />

bags are filled with an artivicial biowaste mix and stored at up to 40° C<br />

for one week and the bag is not allowed to brake apart.<br />

Finnish apple logo<br />

The compostable logo, which is available for use on paper bags too,<br />

has, for whatever reason, not yet been adopted by the paper industry.<br />

In fact in Norway today just one company offers bio-plastic waste bags<br />

with this logo. In order to open up market competition when municipalites<br />

call for tenders, Henrik Lystad says „Avfallnorge is now considering<br />

opening the biowaste system to bag products that fulfil similar standards,<br />

for example those with the Seedling* Logo.“<br />

*: See Logos part 1 in bioplastics MAGZINE 01/2006<br />

Norwegian apple logo


Basics Glossary<br />

Glossary<br />

In bioplastics MAGAZINE again<br />

and again the same expressions<br />

appear that some of our readers<br />

might (not yet) be familiar with.<br />

This glossary shall help with<br />

these terms and shall help avoid<br />

repeated explanations such as<br />

„PLA (Polylactide)“ in various<br />

articles.<br />

Amylopectin<br />

Polymeric branched starch molecule with very high<br />

molecular weight (biopolymer, monomer is à Glucose).<br />

Amylose<br />

Polymeric non-branched starch molecule with high<br />

molecular weight (biopolymer, monomer is à Glucose).<br />

Biodegradable Plastics<br />

Biodegradable Plastics are plastics that are completely<br />

assimilated by the à microorganisms present a defined<br />

environment as food for their energy. The carbon of the<br />

plastic must completely be converted into CO 2<br />

.during the<br />

microbial process. For an official definition, please refer<br />

to the standards e.g. ISO or in Europe: EN 14995 Plastics-<br />

Evaluation of compostability - Test scheme and specifications.<br />

[bM* 02/2006 p. 34f, bM 01/2007 p38].<br />

Blend<br />

Mixture of plastics, polymer alloy of at least two microscopically<br />

dispersed and molecularly distributed base<br />

polymers.<br />

Cellophane<br />

Clear film on the basis of à cellulose.<br />

Cellulose<br />

Polymeric molecule with very high molecular weight<br />

(biopolymer, monomer is à Glucose), industrial production<br />

from wood or cotton, to manufacture paper, plastics<br />

and fibres.<br />

Compost<br />

A soil conditioning material of decomposing organic<br />

matter which provides nutrients and enhances soil structure.<br />

Compostable Plastics<br />

Readers who know better explanations or<br />

who would like to suggest other explanations<br />

to be added to the list, please contact the editor.<br />

Explanantions we are currenty looking for<br />

are for example “organic“ or “renewable“<br />

[*: bM ... refers to more comprehensive article previously<br />

published in bioplastics MAGAZINE)<br />

Plastics that are biodegradable under “composting“<br />

conditions: specified humidity, temperature, à microorganisms<br />

and timefame. Several national and international<br />

standards exist for clearer definitions, for example<br />

EN 14995 Plastics - Evaluation of compostability - Test<br />

scheme and specifications [bM 02/2006 p. 34f, bM 01/2007<br />

p38].<br />

Composting<br />

A solid waste management technique that uses natural<br />

process to convert organic materials to CO 2<br />

, water and<br />

humus through the action of à microorganisms.<br />

40 bioplastics MAGAZINE [02/07] Vol. 2


Basics Glossary<br />

Copolymer<br />

Plastic composed of different monomers.<br />

Fermentation<br />

Biochemical reactions controlled by à microorganisms<br />

or enyzmes (e.g. the transformation of sugar into<br />

lactic acid).<br />

Gelatine<br />

Translucent brittle solid substance, colorless or slightly<br />

yellow, nearly tasteless and odorless, extracted from<br />

the collagen inside animals‘ connective tissue.<br />

Glucose<br />

Monosaccharide (or simple sugar). G. is the most important<br />

carbohydrate (sugar) in biology. G. is formed by<br />

photosyntheses or hydrolysis of many carbohydrates e.g.<br />

starch.<br />

Humus<br />

In agriculture, “humus“ is often used simply to mean<br />

mature à compost, or natural compost extracted from<br />

a forest or other spontaneous source for use to amend<br />

soil.<br />

Hydrophilic<br />

Property: “water-friendly“, soluble in water or other<br />

polar solvents (e.g. used in conjunction with a plastic<br />

which is not waterresistant and weatherproof or that absorbs<br />

water such as Polyamide (PA)).<br />

Hydrophobic<br />

Property: “water-resistant“, not soluble in water (e.g. a<br />

plastic which is waterresistant and weatherproof, or that<br />

does not absorb any water such as Polethylene (PE) or<br />

Polypropylene (PP)).<br />

Microorganism<br />

Living organisms of microscopic size, such as bacteria,<br />

funghi or yeast.<br />

PCL<br />

Polycaprolactone, a synthetic (fossil based), biodegradable<br />

bioplastic, e.g. used as a blend component.<br />

PHA<br />

Polyhydroxyalkanoates are linear polyesters produced<br />

in nature by bacterial fermentation of sugar or lipids. The<br />

most common type of PHA is à PHB.<br />

PHB<br />

Polyhydroxyl buteric acid (better poly-3-hydroxybutyrate),<br />

is a polyhydroxyalkanoate (PHA), a polymer belonging to the<br />

polyesters class. PHB is produced by micro-organisms apparently<br />

in response to conditions of physiological stress.<br />

The polymer is primarily a product of carbon assimilation<br />

(from glucose or starch) and is employed by micro-organisms<br />

as a form of energy storage molecule to be metabolized<br />

when other common energy sources are not available.<br />

PHB has properties similar to those of PP, however it is<br />

stiffer and more brittle.<br />

PLA<br />

Polylactide, a bioplastic made of polymerised lactic acid.<br />

Sorbitol<br />

Sugar alcohol, obtained by reduction of glucose changing<br />

the aldehyde group to an additional hydroxyl group. S. is<br />

used as a plasticiser for bioplastics based on starch .<br />

Starch<br />

Natural polymer (carbohydrate) consisting of à amylose<br />

and à amylopectin, gained from maize, potatoes, heat,<br />

tapioca etc.<br />

Sustainable<br />

An attempt to provide the best outcomes for the human<br />

and natural environments both now and into the indefinite<br />

future. One of the most often cited definitions of sustainability<br />

is the one created by the Brundtland Commission,<br />

led by the former Norwegian Prime Minister Gro Harlem<br />

Brundtland. The Brundtland Commission defined sustainable<br />

development as development that „meets the needs of<br />

the present without compromising the ability of future generations<br />

to meet their own needs.“ Sustainability relates to<br />

the continuity of economic, social, institutional and environmental<br />

aspects of human society, as well as the non-human<br />

environment).<br />

Thermoplastics<br />

Plastics which soften or melt when heated and solidify<br />

when cooled (solid at room temperature).<br />

Yard Waste<br />

Grass clippings, leaves, trimmings, garden residue.<br />

bioplastics MAGAZINE [02/07] Vol. 2 41


Review<br />

PLA hot topic at<br />

PETnology Forum<br />

At the 10th PETnology Forum in Munich, Germany, technical<br />

experts and senior managers from the beverage<br />

and packaging industry, raw material and machinery<br />

suppliers, as well as suppliers of peripheral equipment, caps,<br />

colorants and consultants, shared their latest developments<br />

and innovations with more than 280 delegates from 33 countries.<br />

The number of delegates is a new record for PETnology<br />

GmbH of Regensburg, Germany.<br />

Recognising the trend towards sustainability and so towards<br />

bioplastics, this year‘s PETnology Forum for the second time<br />

dedicated a special session to the “Potential and Developments<br />

for Renewable Plastics in Packaging“. This session was<br />

chaired by Dr. Harald Kaeb, Chairman of European Bioplastics.<br />

from left to right: Luc Vervynck, Bernd Merzenich,<br />

Brian Glasbrenner, Dr. Harald Kaeb<br />

Erwin Vink<br />

in PLA Workshop<br />

www.petnology.com<br />

Harald Kaeb himself opened the session with a presentation<br />

on “Market Introduction and Policy Measures in Europe“.<br />

In his presentation “Additives to Improve Processing & Properties<br />

of PLA“ Luc Vervynck of the ColorMatrix Group Inc. introduced<br />

additives to minimise yellowing effects and processing<br />

aids such as ColorMatrix Eze TM . The Joule TM reheat additives<br />

improve the heat uptake of PLA in the oven of the stretch blow<br />

moulding machine.<br />

Bernd Merzenich, formerly a consultant for the German<br />

drugstore chain “Ihr platz“, shared his positive experience<br />

when introducing the “Vitamore“ wellness beverages in PLA<br />

bottles with the world‘s first biodegradable cap.<br />

NatureWorks‘ Global Director - Bottles, Brian Glasbrenner,<br />

talked about „Responsible Packaging and Disposal - from<br />

Resin to Recycling“. For him a critical mass is important when<br />

trying to understand the economic sustainability of recycling<br />

a new polymer. Therefore retailers, brand owners and other<br />

stakeholders should be involved.<br />

With regard to bioplastics the PETnology Forum was rounded<br />

off by a workshop on the subject of “PLA“. Here Brian Glasbrenner<br />

and Erwin Vink of NatureWorks LLC introduced a variety of<br />

PLA applications - not only bottles. At the end of the workshop<br />

they pointed out that NatureWorks is attempting to increase<br />

the environmental benefits of PLA by using wind energy. NatureWorks<br />

is one of the top 20 purchasers of renewable energy<br />

certificates (RECs). The net result of purchasing RECs and using<br />

a renewable feedstock leads to a reduction of 62-69 percent<br />

in fossil fuel use for the manufacture of NatureWworks PLA<br />

compared with traditional plastics.<br />

42 bioplastics MAGAZINE [02/07] Vol. 2


Stay permanently listed in the Suppliers Guide with<br />

your company logo and contact information.<br />

For only 6,– EUR per mm, per issue you can be present<br />

among top suppliers in the field of bioplastics.<br />

Suppliers Guide<br />

Simply contact: Tel.: +49-2359-2996-0 or<br />

suppguide@bioplasticsmagazine.com<br />

1. Raw Materials<br />

1.1 bio based monomers<br />

Du Pont de Nemours International S.A.<br />

2, Chemin du Pavillon, PO Box 50<br />

CH 1218 Le Grand Saconnex,<br />

Geneva, Switzerland<br />

Phone: + 41(0) 22 717 5176<br />

Fax: + 41(0) 22 580 2360<br />

thomas.philipon@che.dupont.com<br />

www.packaging.dupont.com<br />

1.2 compounds<br />

R.O.J. Jongboom Holding B.V.<br />

Biopearls<br />

Damstraat 28<br />

6671 AE Zetten<br />

The Netherlands<br />

Tel.: +31 488 451318<br />

Mob: +31 646104345<br />

info@biopearls.nl<br />

www.biopearls.nl<br />

BIOTEC Biologische<br />

Naturverpackungen GmbH & Co. KG<br />

Werner-Heisenberg-Straße 32<br />

46446 Emmerich<br />

Germany<br />

Tel.: +49 2822 92510<br />

Fax: +49 2822 51840<br />

info@biotec.de<br />

www.biotec.de<br />

FKuR Kunststoff GmbH<br />

Siemensring 79<br />

D - 47 877 Willich<br />

Tel.: +49 (0) 2154 9251-26<br />

Tel.: +49 (0) 2154 9251-51<br />

patrick.zimmermann@fkur.de<br />

www.fkur.de<br />

Transmare Compounding B.V.<br />

Ringweg 7, 6045 JL<br />

Roermond, The Netherlands<br />

Phone: +31 (0)475 345 900<br />

Fax: +31 (0)475 345 910<br />

info@transmare.nl<br />

www.compounding.nl<br />

1.3 PLA<br />

Uhde Inventa-Fischer GmbH<br />

Holzhauser Str. 157 - 159<br />

13509 Berlin<br />

Germany<br />

Tel.: +49 (0)30 43567 5<br />

fax: +49 (0)30 43567 699<br />

sales.de@thyssenkrupp.com<br />

www.uhde-inventa-fischer.com<br />

1.4 starch-based bioplastics<br />

BIOTEC Biologische<br />

Naturverpackungen GmbH & Co. KG<br />

Werner-Heisenberg-Straße 32<br />

46446 Emmerich<br />

Germany<br />

Tel.: +49 2822 92510<br />

Fax: +49 2822 51840<br />

info@biotec.de<br />

www.biotec.de<br />

1.5 PHA<br />

1.6 masterbatches<br />

PolyOne<br />

Avenue Melville Wilson, 2<br />

Zoning de la Fagne<br />

5330 Assesse<br />

Belgium<br />

Tel.: + 32 83 660 211<br />

info.color@polyone.com<br />

www.polyone.com<br />

Sukano Products Ltd.<br />

Chaltenbodenstrasse 23<br />

CH-8834 Schindellegi<br />

Phone +41 44 787 57 77<br />

Fax +41 44 787 57 78<br />

www.sukano.com<br />

1.7 reinforcing fibres/fillers<br />

made from RRM<br />

2. Additives /<br />

Secondary raw materials<br />

Du Pont de Nemours International S.A.<br />

2, Chemin du Pavillon, PO Box 50<br />

CH 1218 Le Grand Saconnex,<br />

Geneva, Switzerland<br />

Phone: + 41(0) 22 717 5176<br />

Fax: + 41(0) 22 580 2360<br />

thomas.philipon@che.dupont.com<br />

www.packaging.dupont.com<br />

3. Semi finished products<br />

3.1 films<br />

Maag GmbH<br />

Leckingser Straße 12<br />

58640 Iserlohn<br />

Germany<br />

Tel.: + 49 2371 9779-30<br />

Fax: + 49 2371 9779-97<br />

shonke@maag.de<br />

www.maag.de<br />

Treofan Germany GmbH & Co. KG<br />

Am Prime Parc 17<br />

65479 Raunheim<br />

Tel +49 6142 200-0<br />

Fax +49 6142 200-3299<br />

www.biophanfilms.com<br />

www.earthfirstpla.com<br />

www.sidaplax.com<br />

www.plasticsuppliers.com<br />

Sidaplax UK : +44 (1) 604 76 66 99<br />

Sidaplax Belgium: +32 9 210 80 10<br />

Plastic Suppliers: 1 866 378 4178<br />

3.1.1 cellulose based films<br />

INNOVIA FILMS LTD<br />

Wigton<br />

Cumbria CA7 9BG<br />

England<br />

Contact: Andy Sweetman<br />

Tel.: +44 16973 41549<br />

Fax: +44 16973 41452<br />

andy.sweetman@innoviafilms.com<br />

www.innoviafilms.com<br />

4. Bioplastics products<br />

natura Verpackungs GmbH<br />

Industriestr. 55 - 57<br />

48432 Rheine<br />

Tel.: +49 5975 303-57<br />

Fax: +49 5975 303-42<br />

info@naturapackaging.com<br />

www.naturapackagign.com<br />

Veriplast Holland BV<br />

Stadhoudersmolenweg 70<br />

NL - 7317 AW Apeldoorn<br />

www.veripure.eu<br />

Info@veripure.eu<br />

4.1 trays<br />

5. Traders<br />

5.1 wholesale<br />

6. Machinery & Molds<br />

Molds, Change Parts and Turnkey<br />

Solutions for the PET/Bioplastic<br />

Container Industry<br />

284 Pinebush Road<br />

Cambridge Ontario<br />

Canada N1T 1Z6<br />

Tel.: 001 519 624 9720<br />

Fax: 001 519 624 9721<br />

info@hallink.com<br />

www.hallink.com<br />

SIG CORPOPLAST<br />

GMBH & CO.KG<br />

Meiendorfer Str. 203<br />

22145 Hamburg, Germany<br />

Tel. 0049-40-679-070<br />

Fax 0049-40-679-07270<br />

sigcorpoplast@sig.biz<br />

www.sigcorpoplast.com<br />

7 Ancillary equipment<br />

8. Services<br />

9. Research institutes / Universities<br />

bioplastics MAGAZINE [02/07] Vol. 2 43


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44 bioplastics MAGAZINE [02/07] Vol. 2


Event-Calendar<br />

Events<br />

June 14-15, 2007<br />

Biofolien für Bioverpackungen<br />

Steigenberger Hotel, Osnabrück, Germany<br />

www.innoform-coaching.de<br />

June 26-27, 2007<br />

Packaging Summit Europe<br />

Hotel Okura, Amsterdam, The Netherlands<br />

www.pkgeurope.com<br />

July 3-4, 2007<br />

Biodegradable Plastics in Packaging Applications<br />

Hilton Munich Park Hotel, Munich, Germany<br />

www.intertechpira.com<br />

July 9-11, 2007<br />

The 8th International Conference of Eco-Materials<br />

Brunel University, West London, London, UK<br />

sed.temp@brunel.ac.uk<br />

September 6-9, 2007<br />

naro.tec 2007<br />

Messe und Kongresse für Nachwachsende Rohstoffe<br />

Messezentrum Erfurt, Germany<br />

www.narotec.de<br />

September 12-13, 2007<br />

1st PLA-Bottle-Conference<br />

organized by bioplastics MAGAZINE<br />

Grand Elysee Hotel Hamburg, Germany<br />

www.pla-bottle-conference.com<br />

September 13-14, 2007<br />

Biodegradable Plastics in Packaging Applications<br />

Chicago, IL, USA<br />

www.intertechpira.com<br />

September 18-19, 2007<br />

Biokunststoffe, Herstellung - Verarbeitung - Anwendung<br />

University of Duisburg, Germany<br />

www.hanser.de/biokunststoffe<br />

September 25-26, 2007<br />

Sustainable Packaging<br />

Central London, UK<br />

www.epn-sustainablepackaging.com<br />

October 17-19, 2007<br />

BioEnvironmental Polymer Society 14th Annual Meeting<br />

International Symposium on Polymers and the Environment:<br />

Emerging Technology and Science<br />

Hilton Vancouver Hotel, Vancouver, Washington<br />

Call for Papers: gmg@pw.usda.gov<br />

October 24-31, 2007<br />

K‘2007, International Trade Fair<br />

No 1 for Plastic and Rubber Worldwide<br />

Düsseldorf, Germany<br />

www.k-online.de<br />

meet bioplastics MAGAZINE in Hall 7, 07C09<br />

November 21-22, 2007<br />

2nd European Bioplastics 2007<br />

Convention Centre Newport Bay Club<br />

Disneyland Paris, France<br />

www.european-bioplastics.org<br />

November 27-28, 2007<br />

PETnology Asia<br />

Shanghai<br />

www.petnology.com<br />

December 5-6, 2007<br />

Bioplastics 2007<br />

including Bioplastics Awards 2007<br />

Frankfurt/Main, Germany<br />

www.bpevent.com (for the awards contact chris.smith@emap.com)<br />

March 3-4, 2008<br />

3rd International Seminar on Biodegradable Polymers<br />

Valencia, Spain<br />

http://www.azom.com/details.asp?newsID=7345<br />

June 18-19, 2008<br />

7th Global WPC and Natural Fibre Composites<br />

Congress and Exhibition<br />

Kongress Palais, Stadthalle, Kassel, Germany<br />

www.wpc-nfk.de<br />

K‘2007 - show preview<br />

One of the biggest events for the plastics<br />

industry is certainly the K’2007 in Düsseldorf,<br />

Germany from 24-31 October, 2007.<br />

At the “number 1 for plastics and rubber worldwide”<br />

more than 2,900 exhibitors will show their expertise and<br />

products on an extended fairground of 265,000 square<br />

metres. The last “K-Show” in 2004 attracted almost<br />

231,000 visitors from all over the world.<br />

For the next issue bioplastics MAGAZINE will prepare<br />

a special K’2007 show preview. Therefore we ask all<br />

suppliers of products or services exhibiting at K’2007<br />

to send us your press releases, information about your<br />

exhibits etc..<br />

Come and see us at K’2007. bioplastics MAGAZINE would<br />

be happy to welcome you in hall 7, booth 7C09.<br />

bioplastics MAGAZINE [02/07] Vol. 2 45


Companies in this issue<br />

Company Editorial Advert<br />

Arhcer Daniels Midland (ADM) 5<br />

Avfall Norge (Waste Management Norway) 38<br />

Belu Mineral Water 10<br />

Bio Environmental Polymer Society (BEPS) 31<br />

BioCycle Magazine 31<br />

Biodegradable Products Institute (BPI) 30<br />

Biomer 32<br />

Biopearls 5 37<br />

Bioplastics24.com 7<br />

Biota Brands of America 10<br />

Blue Lake Citrus Products 6<br />

Brau Beviale (Messe Nürnberg) 33<br />

Brecon Mineral Water 11<br />

Chevron Phillips 33<br />

ColorMatrix 42<br />

Consolidated Container Corporation 6<br />

Cortec 23<br />

Creative Composites 35<br />

Danimer 14<br />

DS Technical Nowovens 26<br />

DuPont Packaging 6<br />

Emap 7<br />

European Bioplastics 7, 37, 42<br />

Fachagentur Nachwachsende Rohstoffe (FNR) 36<br />

Finnish Solid Waste Association (FSWA) 38<br />

FkUR Kunststoff 28<br />

Fraunhofer Institut UMSICHT 28<br />

German Bioplastics 11<br />

Grow Iowa Value Funds 35<br />

Hallink 25<br />

Husky 10<br />

Ihr Platz 10, 18, 43<br />

Intertech Pira 17<br />

Iowa State University 34<br />

Iroquois Water 11<br />

K‘2007 (Messe Düsseldorf) 45 9<br />

Krones 11<br />

Luzenac 33<br />

Company Editorial Advert<br />

Metabolix 5, 36<br />

Michigan State University 32<br />

Naro.tect (Messe Erfurt) 19<br />

National Science Foundation 33<br />

Natura Packaging 47<br />

Naturally Iowa 10<br />

NatureWorks 6, 10, 21, 24,<br />

36, 42<br />

Netstal 18<br />

Norland International 10, 20<br />

Novamont (MaterBi) 11, 18, 36 48<br />

Oerlemans Plastics 28<br />

Perstorp 33<br />

PETnology 42<br />

Planet Friendly Priducts 10<br />

Plantic Technologies 7, 14<br />

Plasticker 8 23<br />

Plastics Supplers 24 23<br />

Plastipak 11<br />

Plus One Water 10<br />

Quellenhof 11<br />

Sainsbury‘s 30<br />

Sidaplax 24 23<br />

SIG Corpoplast 10, 22 2<br />

SIG Plasmax 14, 22<br />

Souther Clay Products 33<br />

Tate&Lyle 11<br />

Telles 5<br />

Trexel 35<br />

Turtle Island Project 15<br />

Vermeer Manufacturing 35<br />

Visy Industries 7, 14<br />

Wal-Mart 30<br />

Wiedmer AG 18 17<br />

Zenith Publishing 29<br />

Next Issue<br />

For the next issue of bioplastics MAGAZINE<br />

(among others) the following subjects are scheduled:<br />

Special:<br />

Basics:<br />

Events:<br />

Next issues:<br />

Trays, films<br />

What exactly happens in industrial<br />

composting<br />

Logos Part 5<br />

Review and preview of events like<br />

exhibitions and conferences<br />

e.g. K‘2007 preview<br />

03/07 October 2007<br />

04/07 December 2007<br />

01/08 February 2008<br />

01/08 April 2008<br />

46 bioplastics MAGAZINE [02/07] Vol. 2


A real sign<br />

of sustainable<br />

development.<br />

There is such a thing as genuinely sustainable development.<br />

Since 1989, Novamont researchers have been working<br />

on an ambitious project that combines the chemical<br />

industry, agriculture and the environment: “Living<br />

Chemistry for Quality of Life”. Its objective has been to<br />

create products that have a low environmental impact.<br />

The innovative result of Novamont’s research is the new<br />

bioplastic Mater-Bi ® .The Mater-Bi ® polymer comes from maize starch and<br />

other vegetable starches; it is completely biodegradable and compostable.<br />

Mater-Bi ® performs like plastic, but it saves energy, contributes to reducing<br />

the greenhouse effect, and at the end of its life cycle, it closes the loop by<br />

changing into fertile humus. Everyone’s dream has become a reality.<br />

Living Chemistry for Quality of Life.<br />

www.novamont.com<br />

Mater-Bi ® : certified and recommended biodegradability and compostability.

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