bioplasticsMAGAZINE_0704
ioplastics magazine Vol. 2 ISSN 1862-5258
Special editorial Focus:
Biodegradable bags
Review K2007
Düsseldorf | 8
Logos, Part 6 | 36
04 | 2007
Don’t worry,
the raw material for Ecovio ®
is renewable.
Ecovio ® , a biodegradable plastic from the PlasticsPlus TM product line,
is keeping up with the times when it comes to plastic bags and food
packaging. Ecovio ® is made of corn starch, a renewable raw material,
and it has properties like HD-PE, which translates into a double plus
point for you. Films made of Ecovio ® are water-resistant, very strong
and degrade completely in composting facilities within just a few weeks.
www.ecovio.com
I N N O VAT I O N R E L I A B I L I T Y PA R T N E R S H I P D I V E R S I T Y
Editorial
dear readers
Probably the most exciting event in the world of plastics processing and
applications is the K-exhibition, which takes place every three years.
This year, at the end of October, about 242,000 visitors from more than
100 countries came to the exhibition in Düsseldorf, Germany. 3,130
exhibitors presented their products, services and innovations, and
bioplastics were a part – albeit a small part – of that mega event.
More than 3,000 copies of bioplastics MAGAZINE were picked up from
our booth in hall 7 by interested visitors. We were pleased to meet so
many of you personally, and talk about so many different topics. We
were really quite reluctant to leave the booth from time to time, but we
too wanted to see the more than 40 companies exhibiting products such
as resins, additives, machines and services related to bioplastics.
But it was not only K‘2007 that caught our attention this fall. There was
the 2nd European Bioplastics Conference in Paris and the Bioplastics
Event in Cologne where the 2nd Bioplastics Awards were made to the
innovative and well-deserving winners. And there were in fact many
other bioplastics / biopackaging / bioresin events that our editorial
team simply could not attend, but I am sure that these too made a
significant contribution to disseminating information and promoting
networking between the delegates.
As well as many other topics from the bioplastics world, the markets,
science, politics and so on, the special editorial focus in this issue of
bioplastics MAGAZINE is ‘bags‘.
I hope you enjoy reading this last issue of 2007. From
2008 we will publish six issues per year and we look
forward to your comments, editorial contributions and
more exciting events where we can meet with you.
Special editorial Focus:
Biodegradable bags
04 | 2007
bioplastics MAGAZINE Vol. 2 ISSN 1862-5258
Michael Thielen
Publisher
Review K2007
Düsseldorf | 8
Logos, Part 6 | 36
bioplastics MAGAZINE [04/07] Vol. 2
Content
Editorial 03
News 05
Suppliers Guide 39
Events 42
December 04|2007
Review
K’2007 Review 08
2nd European Bioplastics Conference 14
Bioplastics Awards 2007 16
Special
Shopping bags, that dissolve in hot water 18
World‘s first biodegradable zipper bag 19
Compostable shopping carrier bags 20
Biobags: In-line production is the future 21
Materials
Lactide Monomers for the production of PLA 22
Processing
Oriented films continue their 25
successful run – even with PLA
From Science & Research
From Waste 2 Gold: Making bioplastic 28
products from biomass waste streams
Opinion
Biopolymers as an option for 32
sustainability – Quo vadis?
Mailbox
Letter to the Editor 35
Basics
Logos Part 6 36
Glossary 37
Impressum
Publisher / Editorial
Dr. Michael Thielen
Samuel Brangenberg
Dr. Thomas Isenburg, Contributing Editor
Layout/Production
Mark Speckenbach, Jörg Neufert
Head Office
Polymedia Publisher GmbH
Hackesstr. 99
41066 Mönchengladbach, Germany
phone: +49 (0)2161 664864
fax: +49 (0)2161 631045
info@bioplasticsmagazine.com
www.bioplasticsmagazine.com
Media Adviser
Elke Schulte, Katrin Stein
phone: +49(0)2359-2996-0
fax: +49(0)2359-2996-10
es@bioplasticsmagazine.com
Print
Tölkes Druck + Medien GmbH
Höffgeshofweg 12
47807 Krefeld, Germany
Print run: 4,000 copies
bioplastics magazine
ISSN 1862-5258
bioplastics magazine is published
4 times in 2007 and 6 times a year from 2008.
This publication is sent to qualified
subscribers (149 Euro for 6 issues).
bioplastics MAGAZINE is read
in more than 80 countries.
Not to be reproduced in any form
without permission from the publisher
The fact that product names may not
be identified in our editorial as trade
marks is not an indication that such
names are not registered trade marks.
bioplastics MAGAZINE tries to use British
spelling. However, in articles based on
information from the USA, American
spelling may also be used.
bioplastics MAGAZINE [04/07] Vol. 2
News
Sustainability a key
criterion for DuPont’s
Packaging Award
DuPont has announced that the packaging industry’s longest running,
independently judged global innovation awards program has
added a special emphasis on sustainability. Innovation in the journey
toward sustainable packaging will now be a key consideration in addition
to innovation in delivering quality packaging solutions.
DuPont, being one of the first companies to publicly establish environmental
goals 17 years ago, has broadened its sustainability commitments
beyond internal footprint reduction to include market-driven
targets for both revenue and research and development investment, as
stated by the company. The goals are tied directly to business growth,
specifically to the development of safer and environmentally improved
new products for key global markets.
The call for entries for the 20th DuPont Awards competition (closing
Jan 31, 2008) was announced at the Sustainable Packaging Forum in
Pittsburgh, Pa., by William F. Weber, vice president, DuPont Packaging.
“Today there are strong drivers toward sustainable packaging including
increasing consumer awareness, pull from brand owners and retailers,
legislation and other factors. As a global leader in packaging materials
and technologies, DuPont is working with customers on science-based
packaging innovations that address consumer demands for performance
and sustainability,” Weber said.
“DuPont is committed to creating shareholder and societal value
while reducing the environmental footprint in our value chains,” he
continued. “Consistent with this commitment, the DuPont Packaging
Awards now will honor materials, processing, technology and service
achievements that demonstrate progress toward sustainability, while
also meeting important market requirements for enhanced performance
such as improved freshness, convenience and shelf appeal,” Weber
said.
A prestigious international jury panel contributed to the evaluation
criteria for the 20th DuPont Packaging Awards. Factors such as innovation,
enhanced performance, responsible sourcing, clean production
and effective recovery will be considered in selecting the winners. As it
was the case in the previous years also; the usage of a DuPont material,
technology, process or service is not required for eligibility.
In a collaboration to showcase packaging solutions that implement
sustainability, information about entries in this year’s DuPont Awards
will be posted online at the GreenBlue/Sustainable Packaging Coalition
Design Library to be launched in early 2008. Capturing the innovations
represented among these entries will support best practices throughout
the packaging industry. GreenBlue is a nonprofit institute committed
to sustainability by design and is home to the Sustainable Packaging
Coalition, an industry working group recognized as the definitive
resource for credible information about packaging sustainability.
Potential growth
for Australian
bioproducts
A range of biologically-based products,
such as biodegradable plastics and packaging
materials produced from plants instead
of petroleum, offer new opportunities for
Australian farmers.
‘Biobased Products – Opportunities for
Australian agricultural industries‘ is one of
four new reports from the Rural Industries
Research and Development Corporation
(RIRDC) presenting a picture of the current
status and future prospects for Australia’s
biofuels and biobased product industries.
The reports examine a range of issues relevant
to government and policy-makers, the
biofuels industry, the agricultural and livestock
industries, scientists and consumers.
“Research into the development of Australia’s
biofuel and bioproducts industries
has become an integral part of determining
and securing our nation’s energy future,”
said RIRDC Chair Mary Boydell. “We are
particularly keen to identify new biobased
industries that will complement, rather
than compete with, food production,” she
said. “There … are … products like plastics
that are heavily reliant on petroleum. This
research identifies potential replacements
for fossil fuels with agricultural products
like sugar, soybeans, woody crops and corn
starch,” Ms Boydell added.
www.rirdc.gov.au
www.packaging.dupont.com
www.greenblue.org
bioplastics MAGAZINE [07/04] Vol. 2
News
Photo: RacingThePlanet Limited (www.racingtheplanet.com)
Novamont supported antarctic
marathon runner
The Italian marathon runner Francesco Galanzino joined six other athletes in
crossing the coldest landmass in the world, racing over 250 km in temperatures
ranging from -10 C° to -30°C. Starting out by sea from Argentina, they crossed
the Southern Polar ice cap in 5 days, from 21 November to 1 December, 2007.
Galanzino, wherever possible, replaced traditional plastics with biodegradable
and compostable plastics. Novamont provided him with kits of single-use
Mater-Bi tableware as well as sorted collection refuse bags. This allowed all
refuse to be returned to Italy for intelligent disposal. Every kg of organic matter
which is properly initiated in compositing allows for a saving of about 250gr in
CO 2
emissions, considerably reducing environmental impact.
www.novamont.com
www.4deserts/thelastdesert/
Novomer raises
$6.6 million to bring
novel ‘eco-plastics‘
to market
Novomer Inc., a Cornell University spin-off founded
in 2004, announced that it has raised US-$6.6
million in series A funding. Physic Ventures co-led
the financing in partnership with Flagship Ventures.
The company is today pioneering a family of highperformance,
biodegradable plastics, polymers and
other chemicals from renewable substances such
as carbon dioxide.
Founded in 2004, Novomer’s technology is based
on the discoveries of Professor Geoffrey Coates and
his research group at Cornell University. Coates is
an internationally recognized pioneer in the field of
polymer science and a leading innovator in the increasingly
vital arena of sustainable materials.
The national trade magazine of the American
Chemical Society wrote about Novomer‘s pioneering
work: “Geoffrey W. Coates and his group at Cornell
University have spent a decade developing catalysts
to incorporate CO 2
into polymers. Two successes,
building on work by other groups dating back to the
late 1960s, are β-diiminate zinc acetate and salen
cobalt carboxylate complexes. These catalysts promote
alternating copolymerization of various epoxides
with CO 2
to make biodegradable aliphatic polycarbonates.
www.novomer.com
Meredian Inc. announced
acquisition of PHA
technology from Procter
& Gamble
Meredian, Inc. a privately held corporation from Georgia, USA,
announced the acquisition of an extensive intellectual property
portfolio from The Procter & Gamble Company relating to Polyhydroxyalkanoate
(PHA) technology. Procter & Gamble developed the
technology through more than a decade of research, resulting in a
highly functional and cost effective material, which will now be produced
commercially by Meredian, Inc.
“We are very pleased and excited to bring leading-edge, green
technology to the marketplace,“ said S. Blake Lindsey, President of
Meredian, Inc. “Meredian biopolymers combined with our existing
DaniMer and Seluma biopolymers will enable us to provide synergies
within these technology platforms and will result in one of the
world‘s most versatile biopolymer product lines.“
Harry Coleman, director of P&G‘s External Business Development
adds, “As part of our open innovation strategy, P&G was seeking an
enthusiastic company that could efficiently commercialize our intellectual
property on polymers. We selected Meredian because of
their dedication to biopolymers and strong ability to take our development
work to the next level - delivering products to the market.
We look forward to future collaboration with Meredian in this area.“
Meredian expects to begin construction in 2008 on the first of four
planned production facilities; the first will be located in the Southeastern
United States. Meredian plans to produce over 600 million
pounds of biopolymers annually.
www.meredianpha.com
bioplastics MAGAZINE [07/04] Vol. 2
New study on
‘Nanohybrid’ PHB
News
In its November issue ACS‘ Biomacromolecules, a bi-monthly
journal, published a study on the development of a new biodegradable
‘nanohybrid’ plastic, based on PHB (polyhydroxybutyrate). In
this study, Pralay Maiti, Carl A. Batt, and Emmanuel P. Giannelis
(all from the Department of Material Science and Engineering or
the Department of Food Science, Cornell University, Ithaca, New
York) compared the strength and biodegradation rates of a ‘hybrid‘
of PHB which contains ‘nanoclays‘ (nanoparticles of clay) to
‘conventional‘ PHB. It was observed that the modified PHB showed
increased mechanical and thermal properties and decomposed
faster than regular PHB. The biodegradation rate of the nanohybrid
PHB is enhanced significantly in the presence of nanoclay. In
about seven weeks the material decomposed almost completely,
whereas the rate of biodegradation is quite slow in pristine PHB, as
the researchers discovered.
http://pubs.acs.org/cgi-bin/sample.cgi/bomaf6/
2007/8/i11/html/bm700500t.html
Biggest European
WPC Congress
After the great success of the First German WPC Congress in
2005 (WPC=Wood-Plastic-Composites) the organiser, nova-Institut
from Hürth, Germany, arranged the Second German WPC Congress
on 4th and 5th of December 2007 in Cologne. About 350 participants
from 24 countries saw presentations that were simultaneously
translated into English. 30 companies showed their innovations in
the accompanying exhibtion. Among the highlights of the event was
the first WPC Innovations award and the introduction of a ‘certificate
of quality‘ by the Association of the German Wood-Based Panels
Industries (VHI). Even though the matrix in WPCs is still mainly
made of polypropylene, an increasing number of developments also
cover the use of biobased polymers as matrix components.
www.wpc-kongress.de
www.vhi.de
Bio-coated paper
cup range launched
by Huhtamaki
Huhtamaki‘s range of single-use BioWare cups,
plates, containers and cutlery is now being completed
with bio-coated paper cups for hot and cold
drinks. The BioWare paper cup range is the first
complete bio-coated paper hot and cold cup range
launched in Europe, as the company stated. The
bio-coating allows the paper cups to be composted
in industrial composting facilities. Fibers for the paper
cups come from sustainably managed forests
and can be traced back to their origin. The cartonboard
material has Forestry Stewardship Council‘s
(FSC) chain of custody certificate.
BioWare paper cups are as strong and rigid as
conventional Huhtamaki heavy board cups. The
complete range of hot and cold cups include cup
sizes from 100ml to 500ml, making this range suitable
for different beverages and drink sizes. Excellent
customized printing and promotional options,
but also attractive BioWare stock design with ‘compostable’
printing, are available.
Designed to fulfill the needs of various foodservice
operators, BioWare products work in uses
ranging from outdoor festivals and mass events to
catering and daily food and beverage service. By using
BioWare, restaurants and event organizers can
combine the waste stream for packaging and food.
www.huhtamaki.com
bioplastics MAGAZINE [07/04] Vol. 2
Review
show
review
K‘2007 the world‘s number 1 plastics and rubber fair
In the last issue, we reported about the bioplastics related exhibits of a
large number of companies, to be presented at K‘2007 in Düsseldorf Germany,
from October 24 to 31, 2007. Together with this review, we try to give
our readers a most complete overview about what K‘2007 offered in terms
of bioplastics materials, machinery and applications.
Arkema: Pebax Rnew
Arkema unveiled
latest innovations
Well known for its many years of experience
with Rilsan ® Polymaide 11 made from castor
oil (see bM 01/2007) Arkema, Paris, France
presented three new technical polymers produced
from renewable raw materials. Pebax ®
Rnew, a first range of thermoplastic elastomers
based on the chemistry of polyamide 11
produced from castor oil, offers properties
such as lightweight, flex fatigue resistance
and elasticity return, over a wide temperature
range.
Biostrength TM , an innovative impact modifier
for biodegradable PLA allows converters
to process the biobased resins using conventional
equipment. These additives also impart
to this new polymer made from renewable raw
materials the necessary mechanical, optical
and aesthetic properties to fulfill the requirements
of the main intended markets.
Also from 100% renewable raw materials
is Platamid ® Rnew, a new concept for thermoplastic
hotmelt adhesives. A new grade
has been developed to fulfill two new market
needs: reduced emissions as per standard
VDA 278, and eco-design by using raw materials
from 100% renewable raw materials.
The power of nature
BIOPLAST GmbH from Emmerich, Germany, a subsidiary of the Sphere
Group and Stanelco plc, presented BIOPLAST ® , a new generation of thermoplastic
and completely biodegradable materials. Its range of five major
products covers a wide number of rigid and flexible product applications.
BIOTEC‘s expertise lies in the know-how regarding blending and modifying
such resins to special compounds and blends, concentrates and
masterbatches. The materials are certified in accordance with DIN EN ISO
9001:2000 and DIN EN ISO 14001:2004. This certification is audited by an
independent certification agency annually.
www.biotec.de
Hishiecolo pipes, which
return to soil
Biodegradable plastic pipes and fittings from raw materials such as PLA
were presented by Mitsubishi Plastics Inc from Hiratsuka-City, Japan. The
pipes offer the same strength and impact properties as Mitsubishi‘s vinyl
chloride ‚Hishi Pipes‘, but they biodegrade and undergo hydrolysis from
water and microbes living in the natural world. Potential applications are
temporary pipes for short term use, pipes where retrieval is difficult and
pipes in areas where the natural environment is a concern (rainwater
ducts, etc.). Mitsubishi expect a variety of other uses to appear.
www.mpl.co.jp
Flexible PU-foam with
100% biobased polyol
Mitsui Chemicals Polyurethanes from Nagaura, Japan presented flexible
polyurethane foams with a polyol component made from 100% castor
oil. The final polyurethane contains 70% polyol and 30% isocyanate. The
main feature of this polyurethane foam is its low resilience property, which
makes it ideal for use in pillows. Other polyurethane foams with a biobased
content are rigid foams for insulation purposes. In these materials
the polyol consists of 30% renewable raw materials.
www.arkema.com
www.mcpu.mitsui-chem.co.jp
bioplastics MAGAZINE [07/04] Vol. 2
J.C. Grubisisch
No
rainforest to be cut for
sugarcane production?
bioplastics MAGAZINE reported about BRASKEM and the new
bio-polyethylene based on ethanol from sugarcane in the last
issue. However, once in a while people express their concerns
about rainforests being uprooted for new agricultural space to
grow sugarcane that is needed for the production of bio-ethanol.
In a press conference at K‘2007, J.C. Grubisich, CEO of Braskem
stated that in Brasil the rainforests are in the north of the vast
country, whereas the sugarcane plantations are in the southeast.
In addition, land and climate in the north – the rainforest
area - isn’t appropriate for sugarcane production. At least for
the time being, bio-ethanol production from sugarcane does not
threaten the brasilian rainforests.
www.braskem.com.br
PLA Nanoalloy
Toray Industries, Inc. presented a Polylactic Acid Nanoally
with improved properties. A small amount of high performance
polymer is finely dispersed at nanometer scale in PLA building
a network structure. The new materials reach impact and heat
resistance properties above those of PET, PS and even HI-PS.
Potential applications are for example mobile phone charger or
PC housings. Earlier this year Toray announced that it has successfully
developed a plant fiber-reinforced PLA plastic with improved
heat resistance, rigidity and moldability by compounding
cellulose-based plant fibers with PLA. Able to withstand heat
up to 150°C, which is the highest level in the world for biomass
plastics, the newly developed plastic has double the rigidity of
existing PLA plastics and has achieved significant reduction in
the time required for molding.
PLA - cast and
biaxially oriented
film equipment
Review
Brückner Formtec GmbH and Brückner Maschinenbau
GmbH & Co. KG presented their equipment for
converting thermoplastics including PLA into films.
bioplastics MAGAZINE reported about cast film lines
from Brückner Formtec in issue 01/2007. BOPLA (biaxially
oriented PLA) films can be produced on machinery
from Brückner Mashcinenbau (see page 25 in
this issue).
www.brueckner.com
BASF polyamide 6.10
based on castor oil
A material developed, produced and marketed by
BASF over fifty years ago in the pioneering phase of
engineering plastics is undergoing a renaissance. At
K‘2007 BASF unveiled Ultramid ® BALANCE, a polyamide
6.10. This is based to the extent of about 60% on
sebacic acid, a renewable raw material derived from
castor oil.
In the K-show preview we already mentioned Ecovio
L foam materials based on of Ecoflex and polylactic
acid (PLA). Ecovio L Foam’s content of PLA amounts
to more than 75% in weight. According to the standard
ASTM D6866 it has a “biobased content” of more than
75% as well. This number describes the amount of biobased
carbon atoms. BASF is anticipating its first production-scale
amounts by early 2008, so that Ecovio L
Foam will be introduced into the market among select
partners over the course of 2008.
www.basf.com
BASF: Eccovio L foam
www.toray.com
For details about the exhibits of the following companies,
see bioplastics MAGAZINE issue 03/2007:
A. Schulman GmbH
Clariant International AG
Biomer
FkuR Kunststoff GmbH
Fraunhofer Umsicht
Grafe Advanced Polymers GmbH
M-Base Engineering + Software GmbH
Novamont S.p.A.
PolyOne
Telles (Metabolix)
Roll-o-matic
Sukano Products Ltd.
FAS converting machinery see page 21 in this issue
bioplastics MAGAZINE [07/04] Vol. 2
Review
Dow and Crystalsev:
Polyethylene from
ethanol
The Dow Chemical Company, the world‘s largest producer
of polyethylene, and Crystalsev, one of Brazil‘s largest
ethanol players presented their plans for a world-scale
facility to manufacture polyethylene from sugar cane.
The two companies will form a joint venture in Brazil to
design and build the first integrated facility of its scale in
the world. Start of production is expected for 2011 with a
capacity of 350,000 metric tons.
www.dow.com
www.crystalsev.com.br.
Transforming
modified natural materials
into innovative
applications
VTT Technical Research Centre of Finland has built
up extensive knowledge in modifying and adding new
functions to natural polymers—such as starch, cellulose,
and wood fibres—over the past 10 years. This work
has resulted in a number of sustainable processes and
commercial products, such as starch derivates for tailoring
the surface properties of paper, starch-based
pigments, water-based and hot-melt glues, injection
moulding materials, dispersion formulations into coatings
and adhesives as well as coating and matrix materials
for the controlled release of ingedients.
Gehr: extruded rods
First in the world
extruded rods made of
biopolymer
The family owned company GEHR, which is located in Mannheim,
Germany, has extruded what is most probably the world’s
first ‘biological rod’. PLA-L is the name of this biopolymer.
PLA-L consists of Polylactide (PLA) and Lignin (= wood). With
PLA-L, the worldwide leading company for extruded thermoplastics
(POM, PVC, PEEK, etc), further expands its product
range in rods. PLA-L is available in the diameters from 10 to
40mm.
PLA-L is a thermoplastic material based on renewable,
ecologically harmless and biodegradable raw materials. Under
appropriate conditions it can be disposed of by either industrial
composting or by climate-neutral incineration. PLA-L
exhibits good mechanical properties that are similar to ABS.
It shows a high stiffness (modulus of elasticity is 2740 MPa)
and good impact strength. It also exhibits a good resistance to
polar media such as acids, bases and solvents. It can be used
in temperatures from - 30 °C to + 60 °C.
„You can hardly imagine the variety of applications“, says
Bernhard Grosskinsky, head of the technical department at
GEHR.
„Because of its advantages with regards to its biodegradability
and consequent low environmental impact, it is very
likely that PLA-L can be used in the toy and agricultural industry
as well as in mechanical engineering and the medical
industry.“
www.gehr.de
Elastogran: matress
www.vtt.fi
Matress made of
24% renewables
Elastogran GmbH, a company of the BASF group presented
Lupranol ® BALANCE. Through the application of a completely
novel type of catalyst it has been possible for the first time to employ
natural castor- oil in the production of low-emission flexible
foam polyols. The new product is made up of 31% castor oil. A
finished mattress made with Lupranol BALANCE contains up to
24% by weight of castor oil, without impairing the performance
of the foam. This very high percentage of renewable raw material
in the finished product is a breakthrough in the realm of
polyurethane base products.
www.elastogran.de
10 bioplastics MAGAZINE [07/04] Vol. 2
Biodegradable
compound
SAM-A C&I Corporation Ltd from Korea presented
their advanced technology to improve physical properties,
processability and chemical stability of biodegradable
resins which have inherently fragile properties.
SAM-A offers this by enhancing the compatibility of biodegradable
resins, proper composition and development
of additives based on many years of experience. SAM-A‘s
biodegradable resins are composed of PLA and aliphatic
polyester, environmentally friendly and biodegradable
plastics and can replace traditional plastics because
they offer excellent physical properties such as strength,
heat stability and chemical resistance, as can be read in
their K‘2007 brochure.
www.samacni.co.kr
3rd generation natural
fibre composites
At present Kareline Oy Ltd fom Joensuu, Finland say
they have the widest range of bio-composites available
in the market. These materials are based on PLA, but
also natural fibre composites with a matrix of PP, PE,
ABS, PS, POM are available. The natural fibre content
varies between 20 to 55 wt-%.
The reinforcing fibres used are wood-based cellulose
fibres manufactured in the most ecologically advanced
mills in the world. Wood raw material used in the process
is environmentally certified.
The Kareline ® composite granulates can be injection
moulded in all standard thermoplastic injection moulding
machines and tools. This material has already been
in use all over the world in a wide variety of different
machines and tools.
www.kareline.fi
Kareline: flexwood guitar
Symphony in
technology
Reifenhäuser GmbH & Co. KG presented their machinery in
Düsseldorf as well as in their premises in Troisdorf Germany.
In the Technology Center in Troisdorf a premium 3-layer blown
film line Filmtec 3-1700-IBC-RHS with IBC was shown among
others. The flexible line concept with an excellent price/performance
ratio features low-temperature screws and three
REItorque extruders, so that the range of applications is completed
by bio packaging.
Processing of PLA material was be demonstrated on the
high-performance thermoforming sheet line MIREX-W-3-
130/80/50-1000. The series is available as mono or coex line
for up to 7 layers.
www.reifenhauser.com
Review
BioLog: product examples
New compounding
process for bioplastics
BioLog GmbH from Queis, Germany have developed a new
patented bioplastic based on starch, chitosan and polyester.
It can be processed in film blowing (10-30 µm) e.g. for food
packaging or in thicknesses of 30-200 µm for mulch films,
bags, liners or covers. Monolayer as well as multilayer applications
are possible. Furthermore extrusion blow moulding,
thermoforming films, injection moulding applications such as
planting pots, cups, cutlery etc. Foam applications for building
industry and packaging applications round off the portfolio.
In Düsseldorf, BioLog presented themselves at the booth of
Reimelt Henschel MischSysteme GmbH from Kassel, Germany.
They developed a new process for the compounding of
BioLog material. A new screw design of the twin-screw extruder
allows to process higher amounts of starch even with a
higher moisture content.
www.biolog-heppe.de
www.reimelt-henschel.com
bioplastics MAGAZINE [07/04] Vol. 2 11
Review
PLA sheet material with
better impact properties
UK-based VitasheetGroup has developed a new range of biodegradable
PLA based materials which offer greater impact resistance and
improved processability — properties which are often challenging with
PLA.
ViForm Bio 9100 and ViPrint Bio 9100 offer the traditional benefits of
PLA products — compostability, renewable resources origins, but have
been modified so they will have a much better impact strength‚ improving
overall durability of the material and affording excellent performance
in die-cutting and folding.
Biodegradable materials such as PLA are currently used in a number
of applications ranging from food packaging to blisters, but until now
have had little interest for producers of horticulture labels or cosmetic
boxes due to issues with brittleness and folding ability.
“What has traditionally limited the use of bio-degradable materials in
certain applications has now become a thing of the past,“ says Stephane
Jacquet, VitasheetGroup Business Manager for the Packaging and
Graphic Arts sectors.
ViForm Bio 9100 and ViPrint Bio 9100 are available in white and transparent
and gauges ranging from 300 micron to 650 micron.
www.vitasheetgroup.com
DuPont expands portfolio of
renewably sourced polymers
With Sorona ® EP thermoplastic resins, Hytrel ® RS thermoplastic
elastomers, Biomax ® RS packaging resins and Selar ® VP breathable
films DuPont presented in Düsseldorf a number of new plastics based
on renewable resources.
A key ingredient in Sorona EP is Bio-PDO which is made by DuPont
and Tate & Lyle. Bio-PDO will be used in the two glass-reinforced grades
of Sorona EP that will initially be available.
Hytrel RS incorporates Cerenol renewably sourced polyol made with
Bio-PDO. Initial grades of Hytrel RS will have a renewable content range
of 25-50%.
Biomax RS 1001 is a renewably sourced polytrimethyl terephthalate
(PTT) offering aimed at rigid packaging applications such as injection
molded containers, caps and consumer items such as media cases
where it would replace polypropylene. Initial applications are targeted
for cosmetics, food and consumer goods packaging. Biomax RS 1001
incorporates has a renewable content of 35% with Bio-PDO as the key
ingredient.
Selar VP is a renewably sourced breathable film, designed for use in
applications where foods need to respire, such as fresh fish and produce.
It is up to 40% renewably sourced with the incorporation of a vegetable
based fatty acid.
www.dupont.com
The “green”
challenge
For high-potential applications – ranging
from refrigerator insulation to imitation
forest floors Bayer MaterialScience from
Leverkusen, Germany has now developed
polyols (as component for polyurethanes)
based up to 70% by weight on renewable raw
materials to help cut down emissions.
Polyurethane all-foam mattresses are currently
very much in vogue and their market
share has been rising for years. However, consumers
would be unwilling to accept compromises
in performance or above all durability.
Following extensive development work, experts
from Bayer MaterialScience were able
to raise the properties of the „green“ foams
up to the same high level as standard products.
At K 2007, Bayer MaterialScience also
presented a molded-foam part typically used
in car seats. The polyol used for this was also
based largely on renewable raw materials.
Another exhibit on display was a high-end
refrigerator. The proportion of renewable raw
materials it uses is double that of conventional
polyurethane insulating foam systems.
Walking or running on a soft surface provides
a more comfortable underfoot sensation.
An artificial forest floor that Bayer MaterialScience
has produced by combining a
viscoelastic flexible polyurethane foam with
textile overlays and a soft pile offers this feeling
for your own bathroom. An extremely high
volume of a polyol based on modified vegetable
oils is used in the formulation without
producing any adverse effect on technical
properties such as tensile strength and durability.
www.bayer.com
Photo: Bayer
12 bioplastics MAGAZINE [07/04] Vol. 2
Timberland shoesoles
with renewable content in
the polyol component
Dow Footwear Solutions announced during K‘2007 that it will supply its
VORALAST Soling System with renewable content to The Timberland Company
for the Miōn ® Spring 2008 line of outdoor footwear. Dow Footwear Solutions
is a business unit recently launched by The Dow Chemical Company
and is a leading provider of innovative solutions to the footwear industry
worldwide. „We are very excited about our development partnership with
Timberland that has used our VORALAST R series system with renewable
polyol content to deliver both a durable, water resistant polyurethane sole
and an advance in sustainability,” said Antonio Batistini, Research & Development
Director for Dow Footwear Solutions.
www.dowfootwear.com
PLA bottle blowing
machinery
Stretch blow moulding machines for the production of PLA bottles are part
of the scope of supply of Sistec srl. from Pordenone, Italy. Their models SSB-
02/03 are the ideal solution, versatile and easy to use, as a spokesman said.
Sistec presented themselves on the stand of MAG Plastic SA in Hall 13, right
next to SIG Corpoplast from Hamburg, Germany. SIG‘s BLOMAX machine series
were the first to produce the PLA bottles of Biota (USA) and Belu (UK). In
addition, sister company SIG Plasmax offers barrier coating systems to apply
an inner layer of SiOx (glass) to both, PLA and PET bottles for enhanced barrier
properties against water vapour, CO 2 and Oxygen.
www.sistec-pn.it, www.sig.biz
10mm twinscrew
compounder
An ideal solution for compounding minimal
amounts of test compositions, for example of
sensitive materials or with nano materials, is
the 10 mm twinscrew compounder of Rondol
from Stone, UK. Non Invasive mixing allows
rapid batch mixing at a selected degree of
specific energy allowing totally enclosed high
shear or low shear mixing. The twinscrew
compounding technique meets the essential
requirements of
• High torque dispersive mixing with optimised
screw profiles
• The capability of adding measured quantities
of nano materials to melt stream
• The facility to process small quantities
• A small equipment ‘footprint’ to allow
bench top/clean room installation
www.rondol.com
Eco-Smart TM hot runner
system for PLA
D-M-E, a Milacron company introduced Eco-Smart hot runner systems,
which are ideaI for processing “green“ plastic resins - proven successful with
PLA. Eco-Smart Hot Runner Systems provide an ecological molding advantage.
D-M-E is qualifying additional polymers as they become available.
Key Advantages of Eco-Smart Hot Runner Systems:
• Uninterrupted material flow path for reduced shear
• Corrosion-resistant components
• Front-removable heaters and thermocouples for easy system maintenance
• Thermal isolation component design for improved performance
• Superior thermal control from machine nozzle to moulded part surface
Masterbatches
for PLA
Masterbatched for PLA were shown by
VANETTI MASTERBATCHES from Marnate,
Italy. The masterbatches for PLA granulate
are particularly recommended for film extrusion.
Continuous research in this field, in cooperation
with University Politecnico Milano,
Italy, will allow the range of masterbatches to
be expanded in compliance with the standards
requested in the various fields of application.
Certification according to EN 13432 is expected
for the end of this year.
www.vanettimaster.com
www.dme.net
bioplastics MAGAZINE [07/04] Vol. 2 13
Review
2 nd European Bioplastics
Conference
in Disneyland Paris
Dr. Harald Käb
The 2nd European Bioplastics Conference has proven to
be the place to be in bioplastics industry. 360 bioplastics
professionals from 29 countries met in Paris at the largest
bioplastics event ever in Europe that was organised
for the second time by the industry association European
Bioplastics.
Record attendance of delegates, speakers and exhibitors
The number of delegates as well as the comprehensive
exhibition showed the relevance of the promising industry.
The delegates followed the presentations of 45 speakers
about material novelties, biopackaging innovations, consumer
insights, political frameworks to end of life options
in alternating plenary and parallel sessions.
The exhibition room, where 26 exhibiting companies
showcased their latest products and developments, provided
a unique environment for extended networking.
Keynotes on bioplastics
The first plenary session was opened by a welcome
adress of Dr. Harald Käb, Chairman of European Bioplastics
and Christophe Doukhi-de Boissoudy, Chairman of the
French Clubbioplastiques. Käb introduced the challenges
for the future bioplastics development: „Sufficient material
supply will be a very basic parameter for the future
of bioplastics. This can be achieved by utilising existing
production capacities to the full, building up new production
sites by known and yet unknown market players and
broadening the scope of materials and material properties.“
Also waste management will play a crucial role as
well as material developments.
„The bioplastics industry is at a cutting edge. Fortunately,
politics become more and more aware of the potential
of reducing dependency on crude oil not only for fuels but
also in material use of renewable ressources.“ The representative
of the French Ministry of Agriculture, Julien
Turienne, took up the thread and explained the French
policies for bio-based products, which are motivated by
14 bioplastics MAGAZINE [07/04] Vol. 2
Review
360 bioplastics experts 26 exhibitors
their advantages, i.e. the substitution of non renewable
resources, the improvement of innovation and competitiveness
and the preservation and creation of jobs in agriculture
and agro-industry. Amongst the French actions
are the proposal to prefer bioplastic bags regulated by law
(which was rejected by the European Commission due to
the free trade and packaging directive; France now works
on transforming these measures in incentive measures,
e.g. ecotax).
Production capacities
European Bioplastics estimates the global production
capacities of bioplastics to sextuple until 2011. The shares
of the three material classes synthetic/biodegradable,
biobased/biodegradable and biobased/non-biodegradable
are expected to change significantly towards biobased/
nonbiodegradable bioplastics. While their share is about
12% in 2007 (of a total production capacity of 262.000
tonnes/year), in 2011 the share of biobased/non-biodegradable
bioplastics will be almost 40% of total capacity.
The overall capacity will increase to 766.000 tonnes/year
in 2009 to about 1.500.000 tonnes/year in 2011.
European Bioplastics bases its estimations on publicly
available announcements that have been published in the
last months as well as on information gathered amongst
their members. Provided a positive access to capital markets
and thus investments production capacities can grow
even faster.
Material properties and material types
To capture an even broader application range than today
some bioplastics need to improve their material properties.
Basically, this applies for barrier properties and heat
resistance. Usual PLA softens at a temperature of about
60°C and is not deployable for several applications. According
to a manufacturer, PLA composed from D- and L-
lactic acid shall be heat resistant up to 175°C. Thus, PLA
will become applicable for e.g. micro-wave suitable products.
According to several studies PLA bottles have a large
growth potential. To capture more applications the barrier
properties need improvement.The high permeability of
water vapour for instance reduces the shelf-life. However,
it is expected that new PLA types and barrier solutions will
widen the scope of applications very soon. It is likely that
new bioplastic materials and an increasing availability of
bioplastics will accelerate product innovations.
Waste management and bioplastics treatment
Waste management will be a key success factor of bioplastics
in two different ways. On the one hand, for compostable
plastic products it is crucial to have composting
infrastructures in place. That’s the reason why European
Bioplastics advocates for a separate collection of organic
and residual waste and for installing composting sites
across Europe. In the EU, organic waste accounts for
around 38% of municipal waste. This amounts to around
120 million tonnes of organic waste per year, with the potential
to obtain over 50 million tonnes of compost annually
(in EU 25).
On the other hand European Bioplastics is strongly supporting
an adequate treatment of bioplastics given the
quantities of the material. Organizing the most optimized
waste management system is dependent on local infrastructures
for collection and recycling, local and regional
regulations, the total volume on the market available and
the composition of waste streams.
With both bioplastics and biopackaging in their infancy,
the development of the market should not be delayed even
though the most optimal recovery systems have often not
been recognized by local authorities. The risks associated
with existing recovery schemes should be monitored.
These will be limited at this time given the relatively small
volumes that currently enter the market. Once volumes
reach a critical mass, waste management systems which
make most sense from an environmental and economic
point of view can be set up. Over time, recycling may be
the best option for certain bioplastics, especially if a homogenous
stream can be organized such as in place for
plastic bottles.
www.european-bioplastics.org
bioplastics MAGAZINE [07/04] Vol. 2 15
Review
Bioplastics Awards 2007
The second Bioplastics Awards took place together
with the ninth Bioplastics conference
in Cologne, Germany, on December 5 th . Organised
by European Plastics News, an audience of
around 100 people attended the event to witness the
recognition of some of the best bioplastics developments
and applications.
Launched in 2006, the Bioplastics Awards are intended
to raise the profile of bioplastics, which, although
a developing market, is still very much a niche.
The result is that the sector’s achievements tend to be
overshadowed by innovations in the mainstream packaging
and plastics industries.
The seven categories of the Bioplastics Awards intend
to change all that, providing a platform to promote
the innovative ideas that are driving the bioplastics
market forward.
EPN Editor and Conference manager, Chris Smith,
said: “The 2007 Bioplastics Awards come at an important
time for the bioplastics industry as we are seeing
new and important developments not only in traditional
compostable bioplastics but also in bio-sourced
versions of traditional polymers, such as PE, PA, PU
and TPEs. When this industry looks back in 10 years
or so we might say that 2007 marked the beginning
of a new renewable era in bioplastics production and
application.”
www.bpevent.com
Nominees & Winners
Category
Best Innovation
in Bioplastics
Best Bioplastics
Processor
Best Bioplastics
Application –
Packaging
Nominees & Winners
Braskem, Brazil
(Polyethylene from ethanol derived from
sugar cane)
Dow Polyurethanes, USA
(Renuva range of bio-derived polyols,
derived from vegetable oils)
Merquinsa Mercados Quimicos, Spain
(Pearlthane ECO TPUs, with 40 – 49%
renewable contents)
Teijin, Japan
(BioFront PLA fibres with a melting point
of 210°C)
Amcor Flexibles, UK
(heat sealable VFFS film using Mater-bi
and much more)
Leoplast, Italy
(High quality PLA cases and packaging
for the cosmetics industry)
Treofan, Germany
(Production of Biophan PLA films)
Alcan Packaging, Ireland
(Lamination of a range of fully compostable
printed film products using PLA and
Mater-bi)
Alcan Packaging, Ireland
(first fully printable laminate of Natureflex
cellulose and Mater-bi, which can be
home composted)
Amcor Flexibles, UK
(heat sealable VFFS Mater-bi film for
packaging of Sainsbury’s So Organic
salad potato range)
Coopbox Europe, Italy
(Naturalbox PLA foamed PLA tray and
capping film meat packaging system)
Wiedmer AG, Switzerland
(Compostable PCO28 closure in Mater-bi
resin for packaging of still beverages)
16 bioplastics MAGAZINE [07/04] Vol. 2
Photos: European Plastics News
Review
Category
Nominees & Winners
Category
Nominees & Winners
Best Bioplastics
Application –
Non-Packaging
WIP, Italy
(Lov’N range of biodegradable hypoallergenic
sanitary pads, exploiting the
breathability of Mater-bi to retain moisture
and keep the skin dry while moisture
is absorbed by three PLA Ingeo fibre
filtering layers)
Arkema, France
(Use of Pebax Renew in the Wave Creation
training shoe by Mizuno of Japan)
Elastogran, Germany
(Use of bio-derived polyurethane resins
in the Elastocoast coastal erosion defence
system)
NEC Corporation, Japan
(Use of kenaf fibre reinforced PLA in a
mobile phone casing)
Teijin, Japan
(Use of BioFront heat resistant PLA
fibres in automotive prototype seat
Best Bioplastics
Retailer
Delhaize, Belgium
(One of the longest standing supporters
of bioplastics, Delhaize has used more
than 7 million PLA salad packs over the
past two years replacing more than 120
tonnes of traditional plastics. This year
it switched its single-use carrier bags
to starch-based plastics, estimating it
will use 100 tonnes of the resins over the
first 12 months. The group is also working
with its national retail association
FEDIS and waste association Fost-Plus
to develop suitable end-of-life options)
Sainsbury’s Supermarkets, UK
(The 2006 winner in this category,
Sainsbury’s environmental packaging
approach continues to set the standard
in the UK retail sector)
Wal-Mart, US
(Not a company with the greatest record
on sustainability, Wal-Mart’s conversion
to sustainable thinking and launch of its
environmental scorecard have has really
kick-started interest in bioplastics in the
Best Bioplastics
Marketing
Initiative
Excellent Packaging & Supply, US
(provides customers with assistance in
selecting the right product for its needs,
The company is also highly active in the
US in promoting organised composting
schemes, without which many biodegradable
products make little sense)
Alcan Packaging, Ireland
(Promotion of its fully customisable
laminated packaging film materials)
Novamont, Italy
(Supply of two million sets of Mater-bi
disposable tableware for the Loreto
Agorà dei Giovani two-day eco-meeting
in Italy, which was addressed by the
Pope)
Personal
Contribution
to Bioplastics
NOTE:
The Personal
Contribution
award is made
by EPN alone.
Martin K Patel
(Martin Patel is not, perhaps, seen by
many as part of the bioplastics industry,
but the work he has been doing over the
past 15 years in the techno-economic
analysis of energy saving and emission
reductions achievable through new and
existing industrial biotechnologies is
likely to become hugely important in the
years to come.)
bioplastics MAGAZINE [07/04] Vol. 2 17
Special
Shopping bags, that
dissolve in hot water
Figure 1: degradation in soil after 3 months
Headquartered Singapore, Biostarch Technology
Pte Ltd was registered in 2004. However the Biostarch
journey began with research in 1998. The
technological process to produce the Biostarch biopolymer
film was registered for international patent in 2005.
The manufacturing headquarter is in Beijing, China.
According to a company‘s spokesman, Biostarch offers
a cost-effective, EN13432 certified, OK Compost mark approved,
100% compostable biopolymer shopping bag solution
and film for packaging. Biostarch products also meet
the American ASTM-6400-99 Standard for Compostable
Plastics and Australian AS4736-2006 Biodegradable
Standard.
Features
The unique biodegradable and compostable nature of
the Biostarch film is demonstrated by its ability to be dissolved
in hot water. The rapid disintegration in a natural
environment can be seen in fig. 1, showing a Biostarch
bag before and after 3 months in the soil of an Australian
garden.
Other features include the following:
• Comparable strength to conventional plastic bags
• Made principally from the renewable resource corn
starch
• Does not contain the conventional plastic constituents
such as polyethylene and polypropylene
• Can be re-used (encouraged)
• Ideally suited for dry goods but tolerates short term
exposure to moisture.
Shopping Bags
For supermarkets, retail and department stores,
Bio-starch Bags provide a variety of solutions:
• Bio-Fresh bags on a roll, with perforation for easy
separation. Ideal for fruit and vegetables.
• Bio-Light, a lightweight bag for dry goods.
• Bio-Mist, a lightweight bag for moist/refrigerated
goods.
• Bio-Multi, a heavy duty flexi loop bag for dry goods
• Bio-Max, a grip hold bag ideal for retail outlets and
department stores
Film for Packaging and Plastic Converters
Biostarch film is ideal for the packaging of dry goods
and rolls are also available for plastic converters to
manufacture bags to their own specifications. Biostarch
film can be processed on conventional plastic bag
manufacturing equipment with some adjustments.
Biostarch‘s Vision
Biostarch recognizes the environmental hazard
caused by plastic bags and products. „We believe that
government, business and environmental groups and
individuals all need to work together to solve this problem,”
says Dr. Jian Mao, CEO of Biostarch Technology.
„Changes in patterns of behaviour are essential and
the provision of certified biodegradable, 100% compostable
biopolymer alternatives is mandatory,” he
adds. Biostarch is excited to be able to be a part of the
solution by offering a cost effective alternative to plastic
bags and packaging and a more environmentally
responsible alternative to paper bags. Together we can
make a difference.
www.biostarch.com
18 bioplastics MAGAZINE [07/04] Vol. 2
Special
Paperflex-Bio; paper plus bioplastic film
Zipper-Bio bag
World‘s first
biodegradable zipper bag
Forapack, an Italian flexible packaging films converter
from Poggiofiorito, has expanded its product
range of ready-made bags and pouches with a new
series for food producers and retailers. The three product
lines follow the approved design and application but
are made completely of biodegradable and compostable
material.
The Bagflex-F-Bio line consists of bags and pouches
made from a single web of bioplastic film, such as PLA,
Materbi, Naturflex and the like. These bags are hot-wire
sealed, and can be custom-printed and micro-perforated.
The Bagflex-HS-Bio series of bags and pouches is made
from a laminate composed of Kraft paper and a bioplastic
film. They come in a wide range of options, e.g. with or
without die-punched handle or custom-printed. The Kraft
paper is available in white or havana colour. The bioplastic
film can be PLA, Materbi or Natureflex, depending on the
application. Organic adhesives are used between the two
layers to allow for 100% biodegradability. In this respect,
Forapack also carries out flexo printing in up to eight colours
with water-based inks. As required the central film is
produced opaque or transparent to show the contents.
The Paperflex-Bio series of bags and pouches consists
of a laminate of paper plus a bioplastic film, with or without
a central „window“. In comparison with the abovementioned
products Paperflex-Bio is produced in reels for
automatic packaging machine applications.
The Zipper-Bio bags are made of paper laminate plus
biodegradable compostable plastic laminates. Its unique
feature is the world‘s first re-closable zippers made of
biodegradable plastic (a Forapack exclusive speciality),
making the contents watertight and airtight. The applica-
tion of the biodegradable zipper to a bag or pouch made
of biodegradable compostable laminate is a Forapack patent.
One of the latest developments is a PLA film with enhanced
oxygen barrier properties to protect the contents
from oxidation. It was developed in collaboration with
an Italian barrier film producer. Barrier enhancement is
obtained by applying a very thin layer of a special, highly
transparent and food-grade lacquer onto the film surface.
The barrier film is converted as a single web (Bagflex-F-Bio)
or alternatively Forapack laminates it to paper
(Bagflex-HS-Bio and Paperflex-Bio) resulting in a biodegradable
laminate that ensures better protection for the
product, and offers a longer shelf life.
All mentioned products are being tested by independent
laboratories and the results will show full comparability
with the properties of fossil oil based plastic films,
including conformity to food contact regulations, machineability,
transparency, natural permeability, long shelflife
and antifog properties. Beside ensuring the necessary
hygiene and food protection, Forapack promises that the
new packaging solutions to be a valid marketing tool and
offer distributors, food producers and final consumers a
number of additional features that rarely come with other
packaging solutions.
www.forapack.it
bioplastics MAGAZINE [07/04] Vol. 2 19
Special
Article contributed by Christian Garaffa,
Marketing Department, Project Manager
Waste Management Area.
After Ireland, San Francisco and Oakland in California,
Modbury in Britain, the debate on disposable
carrier bags has recently moved to London. Many
other countries and cities are looking to introduce or already
have some form of ban, tax, levy or some voluntary
agreement on throwaway shopping bags (e.g. France or
Italy).
The question is always the same: how to manage the
environmental issue posed by non biodegradable carrier
bags? The common logic permeating the different choices
is always the one dictated by the waste hierarchy: prevent,
reuse, recover, dispose of.
Factors like an intensive communication to the consumers
and the introduction of reusable bags “for life”
which can be used for several times before they are finally
thrown away or given back to the store, are an essential
part of this schemes.
Compostable shopping
carrier bags: what is the
logic for their contribution
to the environment?
How do compostable carrier bags place themselves into
this picture?
www.novamont.com
Compostable carriers can actually be a powerful aid to
waste minimization and recovery policies especially there
were organic waste collection schemes are to be set up
or are already in place. In order for such schemes to be
successful they must be hygienic for both consumer and
collection crews and be as convenient as possible. The
best way to ensure both these criteria is for consumers
to line their kitchen caddy with a compostable liner which
can then be tied and placed in the larger container. Using
liners in this fashion not only keeps the system clean and
hygienic from kitchen to collection to treatment facility,
but by being simple to use, they also lead to higher levels
of participation and subsequently greater amounts of food
waste are recovered and less material is landfilled.
A proper communication and the possibility for the
householder to easily identify the compostable bags are
completing the picture for this kind of schemes which are
able to recover as much as 90% of the kitchen organics
present in the household waste.
20 bioplastics MAGAZINE [07/04] Vol. 2
Special
Article contributed by Jonas Hellström,
Marketing & After Sales Manager,
FAS Converting Machinery AB, Ystad, Sweden
Biobags: in-line
production is the future
The Scandinavian company BioBag International A/S,
headquartered in Askim, Norway has great faith in
the future. They have a long experience of making
plastic bags and have used converting machines from FAS
Converting Machinery AB, Ystad, Sweden for more than 15
years. About three years ago BioBag International started
to specialise in making plastic bags which are 100% biodegradable
and compostable (according to standards such
as EN 13432 or ASTM D6400) and which can be recycled or
incinerated with a neutral greenhouse gas impact. Converting
material from the Italian company Novamont into
bags in-line on a machine from FAS is a very cost-effective
way of making bags on a roll.
”We believe in the future of this project”, says Jorn Johansen,
president and CEO at BioBag International. Many
people are becoming more aware of how important it is
to take care of our Earth. BioBag International A/S has
activities in 18 countries and the list of products is long. In
Belgium for example, BioBag has a business arrangement
with Jemaco nv. (also a customer of FAS), regarding the
marketing and production of high quality bio-products.
Jorn Johansen appreciates the quality of the machines
and the good service from FAS, which fit well in this environmentally
friendly future.
Bag production in-line using the film blowing process
is well known, and has been improved over the years by
FAS, followed by other machine suppliers, as pointed out
by Jonas Hellstrom, Marketing Manager at FAS.
Especially with the combination of tensionless sealing
and sealing from both sides, FAS perforation and sealing
units are the ideal equipment to process biodegradable
products. The FAS sealing system is one of the few that
can handle a wide variety of film materials, e.g. all kinds
of PE from HD to LD, recycled plastics and biodegradable
materials, without any special adjustments required.
In addition to the above-mentioned features, the FAS
perforating and sealing units offer the benefits of constant
or intermittent heating and adjustable seal pressure,
which has proven to give many producers advantages
when running different products on the same machine.
The in-line process of film blowing and bag production
brings a number of additional benefits, such as faster
quality control of the plastic film, no capital locked up in
storage for master rolls or floor space, and a better cash
flow. And - thanks to converting a warm film which enables
thick film to fold easily and the final winding to be
easier – the final products often just look better.
When it comes to total machine investment cost, an
in-line set-up offers advantages over an off-line solution.
One reason is a simpler blown film unit, as there is no
need for a rotating head or winding equipment when running
in-line.
Other costs for a producer are the handling of master
rolls and for the personnel needed to run the machines.
In an in-line environment less operators are needed compared
to an off-line set-up, which also provides financial
benefits.
As one of the biggest bag producers in Europe once
said: “Produce this morning – deliver in the afternoon -
and invoice tomorrow! That´s the key to success!”.
www.fasconverting.se
bioplastics MAGAZINE [07/04] Vol. 2 21
Materials
Lactide
Monomers
for the
production
Article contributed by Hans van der Pol, Marketing Manager,
PURAC biochem BV, Gorinchem, the Netherlands
of PLA
So far the focus for bioplastics developments has
been in particular on the environmental and
social elements. To make PLA sustainable on
the long-term it is now crucial that the economic sustainability
is secured. L- and D-lactide produced with
PURAC technology in combination with PURAC’s value
proposition for the value-chain members will allow
PLA to become an attractive economic reality.
Accelerating PLA potential
Although many PLA applications have been developed
over the last years, PLA is currently in short
supply. In order for the bioplastics market to grow at
the pace dictated by the customer demand, there is a
need for a higher level of PLA supply. The main factors
hampering the growth in supply are PLA product quality
and the availability of an economically sustainable
production technology as part of the PLA value-chain.
The key factor in this chain is the technology to produce
high purity, polymer grade, lactic acid with high
carbohydrate efficiency – the core expertise of PURAC,
whose technology has been optimized over decades.
PLA for packaging applications was developed in the
nineties but it is not until very recently that the value
chain for PLA applications has been seriously expanded.
The Kyoto protocol and the associated trading
schemes for carbon dioxide certificates are providing
companies with real incentives to reduce their carbon
dioxide emissions by investing in more environmentally
benign technologies and products. Bioplastics and
bio-fuels are at the forefront of this trend.
Market opportunities
With improvements in PLA supply and quality as
well as development of value added applications it is
expected that the market for PLA can grow to a level
of several hundreds of ktons over the next 10 years.
The bioplastics industry is still in a very early stage of
its development. Institutional, legal and policy framework
conditions are adjusted continuously in order to
stimulate a continuous growth of sustainable materials.
The market for traditional polymers is over 250
mio tons and growing. Many framework conditions for
these traditional polymers actually act as barriers for
the new polymers. The bioplastics industry has grown
so far without the huge subsidies heaped upon bioethanol.
The opportunities to capitalize on this are immense.
The total consumption of biodegradable polymers
stood at around 140 ktons in 2006, with packaging representing
31% of the total consumption. The projected
growth for PLA in this segment is estimated 23%
per year.
With improvements in technology, higher value added
applications such as fibers and engineering plastics
can be developed. Such higher value added applications
are important to turn a bio-based economy into
reality, as it will improve the economic sustainability of
the value-proposition.
Retailers and brand-owners recognize possibilities
to capitalize on the sustainability trend by re-branding
their image as an environmentally conscious company
22 bioplastics MAGAZINE [07/04] Vol. 2
Materials
by incorporating innovative bio-based packaging
solutions into their product lines. This allows them
to create additional added value to their customers,
who are also becoming more environmentally
conscious.
The use of annually renewable resources as a
feed-stock is the main driving force behind sustainable
plastics in the 21st century. Biodegradability
of PLA packaging materials is an advantage
in those countries that have an industrial composting
infrastructure in place. However, no material
can find a sustainable position in the market without
the right functional attributes. For many applications
the biodegradability has no added value,
and PLA is perfectly stable under normal use conditions.
Added value
The added value of PLA polymers comes in the
first place from its unique combination of properties,
such as very high optical clarity, good mechanical
properties, gas and water barrier properties,
etc.. These properties can be influenced
and further improved or modified by value added
polymer technologies, such as compounding, copolymerization,
combining materials or films with
different properties or applying nano-technologies.
Properties that will need improvement to make the
polymer applicable to high-end applications are
its heat deformation temperature and its impact
strength. For bottle applications for example the
gas barrier properties needs improvement.
PLA Value proposition
Due to its strong technology position in lactic
acid, moving one step further in the value-chain is
a logical step for PURAC. This enables polymerand
plastics producers to make the step into PLA
bioplastics. PURAC itself has in-depth experience
with PLA in the relatively small, but high value
added market of medical-grade lactide monomers
and polymers.
The scale to economically produce lactide is
much bigger than the scale to economically produce
PLA. In PURAC’s concept, polymer producers
will not need to invest in complex lactide technology,
but can focus instead on their core expertise:
adding value through the production of specialized
PLA (co-)polymers. By allowing PLA producers to
bioplastics MAGAZINE [07/04] Vol. 2 23
Materials
invest in smaller scale plants, the efficiency of PLA
production can be enhanced by focusing on dedicated
grades for certain application areas. Further
value can be added to these (co-) polymers by compounding
them into plastics and using nano- and
other technologies to improve the properties.
PURAC allows polymer producers to add value
in a revolutionary new way by offering two types
of lactide (L-lactide and D-lactide). By combining
these lactides in new and unconventional ways, the
improvement of the PLA heat-stability – one of its
key issues – can become a reality.
PURAC will deploy a business model, where lactide
is manufactured at an advantageous scale and
offered as a premium quality, competitively positioned
product to PLA producers. Based on this
lactide monomer customers will be able produce
superior quality polymer. This business concept allows
medium size and starting PLA companies to
be competitive in the PLA market.
The production of lactide is integrated into the
manufacturing of lactic acid and as such different
grades will be either processed or marketed
through PURAC’s global sales network. PURAC
partners do not have to concern themselves with
the production of lactic acid or lactide and hence
will see a reduced risk profile for the investment,
product management, logistics and warehousing
and operation of facilities.
Outlook
The flexible production unit in PURAC production
site in Spain will be used for lactide production
for selected partners early 2008. This unit will
be extended with the required steps to make high
quality lactide shippable to selected customers all
over the world. The investment path leads to the
industrial scale availability of a lactide production
unit in Thailand.
Since the availability of D(-) lactid acid is essential
for the highest PLA grades, PURAC’s lactic acid
production unit in Spain is being revamped into a
high quality D(-) production plant. The product will
also become available as D-lactide for PDLA production.
PURAC has commenced a focused application
development effort to support customers in
their use of lactide and D(-) products.
www.purac.com
24 bioplastics MAGAZINE [07/04] Vol. 2
Practically everybody uses them to protect sensitive
goods – high-quality stretched plastics are
undoubtedly the number one within the world of
packaging material. More and more they are replacing
paper, cardboard, tin foil and other materials. Upon applying
a particular process, mono- or biaxial orientation, the
films obtain a wealth of advantageous properties, due to a
change in the morphology of the film’s molecular structure:
• excellent mechanical properties, e.g. stiffness, tear,
shock or puncture resistance
• impermeability to moisture and water vapour
• high resistance to oils, fats and solvents, as well as to
heat and cold
• dimensional stability and scratch resistance
• attractive glossy appearance, thanks to brilliant surface
quality and high transparency
• excellent convertibility, printability and sealability.
Packaging has become a key marketing tool at the point
of sales. As a result, customers in supermarkets and
stores are placing greater emphasis on attractive packaging.
This leads to a greater demand for a variety of speciality
films:
• co-extruded multi-layer structures, up to 7 layers for
ultra-high barrier
• shrink film and sleeves for trendy, full body sleeves
• ultra-high barrier film for lamination
• bio-degradable films for environmental protection and
sustainability
• BOPA (bi-axially oriented Polyamide) film highly suitable
for freezable and cookable (microwavable) packaging
• mono-axial shrink films for bundles and labels
Orientation methods
The orientation methods applied to manufacture such
films are the film blowing process and the tenter frame
process. Blown film extrusion process is based on the
principle of extruding a tube having a thickness that is 40
– 50 times thicker than that of the film to be produced.
As part of the tenter frame process, the cast film derived
from plastic granulate by means of extrusion is stretched
in longitudinal and transverse direction to attain the required
film dimensions. This film is then processed either
sequentially or simultaneously in order to obtain a very
thin, high-rigid end film. Sequential lines first stretch the
cast film in machine direction through a system of rollers.
This stretching is achieved by different speeds between
groups of rolls. Then the film enters the tenter, an ovenlike
device, which uses two endless chains to grip and
stretch the web in transverse direction on diverting rails.
Simultaneous systems stretch the film in both directions
at the same time. The limited yield and inflexibility
of mechanical solutions led to the development of LISIM ®
Oriented
films continue
their
Processing
successful
run – even
with PLA
Article contributed by Christian Aigner,
Marketing Manager, Brückner Maschinenbau
GmbH & Co. KG, Siegsdorf, Germany
Photo: Treofan
bioplastics MAGAZINE [07/04] Vol. 2 25
Processing
°C
1 : 2.0 - 3.5
1 : 3.0 - 5.0
Sequential BO stretching line - TDO inlet
Typical temperatures during BOPLA process
technology, which uses linear motors driving clips without
chain connections. This drive principle, also used on the
“Transrapid” (Germany’s high-speed monorail train using
magnetic levitation), allows a new level of freedom to be
obtained when manufacturing high quality film in fast and
extremely flexible production.
Biodegradable oriented film is gaining great
interest
Excellent properties in stiffness, transparency, gloss,
and dead-fold retention, combined with the environmental
benefits clearly emphasize the breadth of its appeal for
use in consumer packaging applications.
• As an alternative to cellophane in: confectionery twist
wrap, premium wrapping for flowers, toiletries and
prestige gifts
• Bags for compost and garden refuse, as well as agricultural
mulch films to replace paper (when wet strength
is required)
• Multi-layer films for packaging uses, especially food
• Lamination films where cellulose acetate can be replaced
• Co-extruded structures with low temperature heat seal
layers and/or flavor and aroma barriers where properties
allow layer simplification or replacement of nylons
• Shrink sleeve films and high modulus label films
• Non-fogging films for fresh produce packaging
Key performance indicators of Brückner’s stretching
lines for biodegradable film
Due to the fact that PLA resin is sensitive to humidity,
special raw material handling and extrusion technology
is needed. Particularly in the storage system, Brückner’s
line layouts include silos with humidity protection. Resin
dryers guarantee the resin’s low moisture content prior
to extrusion.
For the extrusion, Brückner utilizes their over ten year’s
worth of experience in twin screw technology. Benefit: no
additional material drying is needed. The special screw
design creates uniform melt properties. Stainless steel
melt pipes, polymer filters with short dwell times, static
mixers and a three-layer adapter block designed for PLA
are essential to the entire process.
The pinning and stretching properties of PLA are very
similar to the behavior of PET. Therefore, an electrostatic
pinning device is needed to fix the extruded sheet to the
chill roll. A shockless speed variation is realized with a
drive motor concept, which assures a constant take off
speed. A special roll design guarantees a temperature accuracy
of ± 1 K (Kelvin) across the roll surface.
The MDO (machine direction orienter) is equipped with
the same drive technology.
Special drive functions called MSD (MD soft drive system)
assure a “scratch-free” surface of the MD stretched
film. The elongation ratios in machine direction (MD) are
in a range of 2 - 3.5.
The stretching ratios within the transversal direction
(TD) are around 3 to 5. The TDO (transversal direction orienter)
is characterized by accurate and adjustable air distribution
and a reliable chain track system.
Stretching profile
1.767 mm Die
Neck-in
80 mm
Neck-in
120 mm
Clip Range
30 mm
7. 435 mm
1.687 mm Castfilm
1.567 mm MD Film
6.600 mm
Edge trim 150 mm
26 bioplastics MAGAZINE [07/04] Vol. 2
CF-PLA
BOPLA (2,2 x 6,0)
s-BOPLA (4,5 x 5,2)
220
180
3510
4110
5155
4616
Processing
180
180
120
3000
3050
90
100
70
53
52
17
6
MD
TD
MD
TD
MD
TD
Tensile Strength
[N/mm²]
Elongation at Break
[%]
E-Modulus
[N/mm²]
Mechanical
Properties
Improvement of mechanical properties by biaxial stretching
Sequential BO streching line - Winder
The stretched film needs to be surface treated and the
thickness gauge must be measured. Brückner’s stateof-the-art
treatment systems and scanning devices combined
with a ultra-fast die-bolt system guarantee highest
surface properties and a constant gauge throughout the
complete production.
The winder winds up the final treated film on steel
reels.
Criteria like winding tension, roll profile, roll density and
perfect roll build-up are essential for the further process
steps. Technologies like LIWIND ® (winding technology with
linear motors), tension control systems and winder oscillation
systems are essential for perfect further processing.
The output of such a state-of-the-art stretching line is
1,300 kg/h, with the end film having a thickness range between
15 and 50 µm.
Unique technology center
Brückner‘s experience in processing PLA using an orientation
process is based on their worldwide unique technology
center.
The variety of stretching methods, ranging from monoaxial
to sequential and simultaneous stretching, gave the
possibility to run PLA in each production mode.
Produced PLA film:
• MOPLA (mono-axially oriented PLA) shrink film for
sleeves applications
• BOPLA (bi-axially oriented PLA) thin film
• BOPLA thick film for thermoformapplications
(190 – 350 µm)
All produced film types displayed improved film properties
after the stretching process.
Considering that cast – PLA is brittle and inflexible the
stretching process made the final film flexible, while at the
same time improving its tensile strength and E-modulus.
The final film exhibited excellent dead fold and twist
wrap properties.
The simultaneous stretching mode also presented
amazing results.
Sequentially, PLA can be processed with a MD ration of
2.2 and a TD ration of 6.0. The main challenge in this line
configuration is the maximum pinning speed.
The use of simultaneous technology is completely
changing the situation. Stretching ratios of 4.5 times 5.2
are no longer a problem. Therefore, line output can be dramatically
increased. In addition, film properties were better
when compared to the sequential stretching process.
• Mechanical properties
• Sealing properties (by using a low sealing skin layer)
• Adjustable shrink properties due to the special process
• Better optical quality (no scratches, higher gloss)
Overall, the PLA tests at Brückner’s technology center
were surprisingly successful and they gained a lot of new
experience and insight from these trials. The successful
thermoform application tests for the thick film were carried
out at Brückner’s new Group Company Kiefel GmbH
in Freilassing, Germany.
More PLA technology from Brückner Group
Brückner Formtec, supplier of cast film and sheet extrusion
lines, developed a process to produce PLA film
and sheet for rigid packaging in a very cost effective way
by increasing productivity through high outputs and high
speeds. Highlights of the line concepts are: Twin screw
extrusion for highest efficiency, outputs of up to 2,000 kg/
h, speeds of up to 75 m/min, thickness range from 250 µm
up to 1,200 µm, proven pinning technology, especially suitable
for inline processed high volume applications.
www.brueckner.com
bioplastics MAGAZINE [07/04] Vol. 2 27
From Science & Research
Reactor contents transfer
From Waste 2 Gold: Making
bioplastic products from
biomass waste streams
Article contributed by Dr Alan Fernyhough,
Unit Manager of the Bioplastics Engineering
Group, Scion, Rotorua, New Zealand
New Zealand is widely regarded as pristine and
uncluttered. But the country has waste management
challenges just like everywhere else. A large
volume of these wastes arise from its prolific agricultural,
forestry and horticultural sectors. Innovative research
programmes aimed at turning these organic wastes into
high-value bioplastic products are being run by Scion, a
Crown Research Institute based in Rotorua, at the heart
of New Zealand’s green hinterland. At Scion, teams working
on wastewater and environmental (bio)technologies
have come together with those working on biopolymers,
and materials formulation and processing technologies to
create a suite of technology options for converting wastes
into bioplastic related products. The programmes include
turning wastes into bioplastics, or into functional additives
for use in bioplastics, or directly into processed bioplastics
products.
Dr Trevor Stuthridge is the leader of the ‘Waste 2 Gold‘
programme, an overarching framework developed by Scion
for turning wastes into valuable products. He explains
why this research is of vital interest to a nation focused on
minimising waste:
“New Zealanders landfill the equivalent of 872 kg of solid
waste per year per person – one of the highest per capita
rates in the OECD (Organisation for Economic Co-operation
and Development). Our primary industries contribute
55% of this total; a major proportion is organic material
28 bioplastics MAGAZINE [07/04] Vol. 2
From Science & Research
which can generate methane, a potent greenhouse gas
(GHG), and harmful leachates.”
In a bid to help minimise GHG emissions, New Zealand
has implemented a Waste Management Strategy that aims
to see 95% of these industrial organic wastes re-directed
from landfills by 2010. Dr Stuthridge believes that New
Zealand’s primary sectors can best meet this challenge
by actively exploiting the intrinsic worth of their organic
wastes.
“The only effective way to provide incentives for minimising
liquid and solid wastes and redirecting organic
material from landfills is to ensure that the resource has
an economic value. The ‘Waste 2 Gold‘ initiative is proactively
generating sustainable solutions, which will simultaneously
help to increase revenues, reduce costs and add
value to businesses,” he says.
Carbon-rich industrial wastes, such as those from the
pulp and paper, food processing, and biorefinery sectors
are low cost, high volume feedstocks that are ideal
for sustainable production of biopolymers, fine chemicals
and biofuels. Microbial biotechnologies and chemical
functionalisation technologies are under development by
Scion scientists who are exploring ways of utilising these
feedstocks.
One project involves the use of mixed and/or pure cultures
of bacteria that directly fix nitrogen from the atmosphere,
allowing them to remediate carbon-rich wastes
from these sources, without the need for additional costly
chemicals, and convert the carbon into useful products.
Dr Stuthridge explains that a novel function of these nitrogen-fixing
bacteria is their ability to store excess carbon
in the form of polyhydroxyalkanoates (PHAs, >50% of
dry cell mass).
“We are exploiting this characteristic to produce biopolymers
and biopolymer composites from industrial waste
streams. Given that feedstock costs can comprise over
60% of manufacturing costs, this type of process is expected
to offer substantial economic advantages.”
Nitrogen fixation processes produce very low ecological
footprints since no supplemental nitrogen needs to
be added to achieve microbial growth. This approach can
give a 35% saving in operational costs over conventional
bioconversion methods. In addition, very low nutrient final
wastewater discharges are achieved, amounting to over
90% reductions in nitrogen and phosphorus over conventional
methods. Finally, these aerobic nitrogen fixation
processes have a lower oxygen demand than normal systems,
offering a 25% saving in aeration energy costs.
“Of course, in the case of solid wastes, there is a requirement
to make them more easily accessible for microbial
bioconversion”, explains Dr Stuthridge. “Here, we
are integrating proprietary green chemistry-based technologies
that break down the solid organic material, such
Bacteria with PHA
Biodegradable pots
bioplastics MAGAZINE [07/04] Vol. 2 29
From Science & Research
as proteins, lipids and polymeric carbohydrates, into
readily degradable feedstocks for the bacteria.”
The ‘Waste 2 Gold‘ framework demands a multi-disciplinary
approach, encompassing microbiology, bioprocess
engineering, biomaterials chemistry, polymer
engineering, and ecotoxicology. Advanced biomaterial
engineering concepts also enhance these opportunities
by taking the bioplastics from bacteria and integrating
functional attributes, such as programmed degradation
and biofunctional additives.
The author of this article is leader of the Biomaterials
Engineering Group and leads many of the bioplastic
pro-duct developments at Scion. They are functionalising
selected wastes, and mixing benign solid wastes
from other sources (such as the horticultural, food
processing and agricultural sectors), with renewableresourced-based
plastics, and selected additives, to
create a range of novel biopolymer products. These
products include controlled-release fertilisers, biodegradable
plant pots, panels, packaging materials, and
other moulded plastic products.
As future disposal options become more limited, these
technologies will provide a viable alternative for not only
reducing waste, but for utilising it as a valuable resource.
Though the initial interest has been from commodity
based product developments, we increasingly see greater
interest in accessing functional attributes of particular
pro-cessed or functionalised wastes in bioplastic products.
This is leading to a range of advanced performance
bioplastic product developments.
Scion has taken this concept outside the lab to some
leading New Zealand plastics processors and has also
worked to directly involve those who generate much of
New Zealand’s organic wastes. Scientists have conducted
surveys to assess primary industry processing activities
within New Zealand and to identify current waste production
and disposal patterns. The surveys highlighted the
availability of high-volume, good quality waste streams,
with producers indicating a clear desire for better options
to use this waste.
This need led to the formation of a partnership between
Scion and a number of major pulp and paper and horticultural
producers and processors to explore opportunities
for developing new products from these waste streams.
This partnership exploits a ‘Waste 2 Gold‘ ‘hotspot’ based
in the Bay of Plenty region, where significant volumes of
the ideal raw materials are available to this programme.
The fledgling regional initiative may be a model for extension
into other sectors in New Zealand as scientists
develop ways of making bio-derived plastics and biobased
composites out of a range of organic wastes from
kiwifruit to cow dung.
“From a purely economic perspective, industrial
wastes can no longer be considered ‘wastes’ but rather
‘untapped resources’. While reducing the amount of
waste generated is the first priority, even the most efficient
manufacturing processes create surplus materials.
The future sustainability of industrial production depends
on the smart utilisation of these residues,” Dr Stuthridge
concludes.
30 bioplastics MAGAZINE [07/04] Vol. 2
Our Covergirl Maria says:“ I‘ve known
about these biodegradable bags made
from starch. But I like the idea that
scientist try to make bioplastics even
from waste.“
Week 1
Week 2
Week 3
Week 4
BIODEGRADATION PROCESS
EcoWorks ®
www.EcoFilm.com
info@CortecVCI.com
1-800-4-CORTEC
St. Paul, MN 55110 USA
© Cortec Corporation 2006
70®
100%
Biodegradable EcoWorks
Replacement for Plastic and Polyethylene
Up to 70% Bio-based With
Annually Renewable Resources
From thick rigid plastic cards to fl exible protective wrap,
EcoWorks ® 70 by Cortec ® Research Chemists offers universal,
biodegradable replacement to traditional plastic
and polyethylene films. This patent pending breakthrough
meets ASTM D6400 and DIN V 54 900. EcoWorks ® 70
does not contain polyethylene or starch but relies heavily
on renewable, bio-based polyester from corn. 100%
biodegradable, it turns into water and carbon dioxide in
commercial composting.
Opinion
Article contributed by
Miriam Wehrli, Project Manager and
Dr. Markus A. Meier, Head Market Platform Packaging
Market Platform Packaging, Ciba Inc., Basel, Switzerland
Biopolymers as an
option for sustainability
– Quo vadis?
Sustainability has become the new buzzword
in our modern and environmentally aware
society. Government authorities, organizations
and companies all over the world are increasingly
coming up with initiatives to improve
sustainable development while striking the right
balance between environmental, social and economic
concerns.
Specifically relating to the packaging market, the
focus is on reducing carbon footprint and in this
regard, biopolymers are consistently in the spotlight.
When compared to traditional plastics, these
new types of emerging polymers bring numerous
modified properties such as a higher water-vapor
transmission rate (WVTR) and biodegradability.
The latter, however, often leads to confusion and
consumers too often do not know how to deal with
this new feature, what makes them unsure of the
real benefits of biopolymers.
Do we need biodegradable polymers?
Biodegradability is an attribute which is often
associated on the one hand with environmental
friendliness but on the other hand, also with
instability of the polymer and low performance.
Currently biodegradability is frequently used as a
marketing tool, although not all aspects of biodegradability
are known and therefore hardly foreseeable.
32 bioplastics MAGAZINE [07/04] Vol. 2
Opinion
Life-cycle: Oil-based polymers
Net CO 2
Exploration Refinery Use Collection
Incineration
with energy recovery
0
Recycling
+
+
Life-cycle: Biopolymers
Growth Processing Use Collection
Incineration
with energy recovery
-
Recycling
+
0
No significant difference between polymers
Net CO 2 production (+)
Overall target: CO 2
reduction by process optimization
Figure 1: CO 2 balance
comparison of oil-based
polymers and biopolymers.
Legend:
+ : CO 2
production and release to the atmosphere (emission),
- : CO 2
elimination of plants during growth (photosynthesis),
0 : CO 2
neutral (overall no emission nor elimination)
Already today we are confronted with headlines pointing
at the rising prices for corn tortillas in Mexico due to
increasing demand of bio-resources causing corn shortages.
Feedstock and farmland for biopolymers are in
competition with biofuels as well as land capacity which
could be used to feed people. The benefits of biopolymers
capable of being chemically recycled rather than composted
are therefore obvious. Collecting industrial and
post consumer waste of polylactic acid (PLA), for instance,
and converting it back to lactic acid by depolymerization
results again in a purified base material for the polylactic
acid production. In doing so, corn production, corn wet
milling and fermentation could be avoided and leading to
an overall reduction of costs and energy consumption.
Furthermore, when considering the high efforts presently
made to improve the mechanical and technical properties
of biopolymers, future biopolymer solutions will
most probably end up losing the biodegradability at the
expense of strength. In essence, the development of biobased
polymers should target a polymer which is recyclable
rather than biodegradable.
Carbon footprint
In this context, the main driver for biopolymers on the
market turns out to be the fact that they are based on
renewable raw materials. This is presumably linked with
the increasing pressure to reduce the environmental impact
of products and furthermore to comply with internal
sustainability commitments. Biopolymer resin producers
especially enhance their life cycle studies by purchasing
renewable energy credits, but this option is certainly independent
of the polymer produced.
For the time being, Ciba’s market analysis in collaboration
with Pira International and life cycle assessment
(LCA) studies of biopolymers in cooperation with the Swiss
Federal Institute of Technology (ETH Zurich) show neither
clear advantages nor disadvantages of biopolymers compared
with traditional mineral oil based polymers.
As processing, use, collection and even waste management
(except composting) do so far not show significant
difference and are comparable for all kind of polymers in
terms of energy demand and greenhouse gas emissions,
a fully greenhouse gas neutral option (from cradle-tograve)
can only be achieved by using renewable resources.
Even if 100% recycling could be feasible, traditional plastics
would still need crude oil as a feedstock and therefore
release net CO 2 to the atmosphere.
So, the long-term vision for a sustainable solution
points to biopolymers which are 100% recyclable. If this
is considered not feasible, then at least incineration with
heat recovery should be the option and not composting, in
which, neither energy nor base material can be recovered
(destroying value).
Alternatives – biobased polyethylene (PE)
Biopolymers like PLA and starch-based solutions still
show performance drawbacks in end-use packaging applications
compared with traditional polymers. While the
higher WVTR of biopolymers could be a benefit for several
fresh produce packaging applications, they then shortly
bioplastics MAGAZINE [07/04] Vol. 2 33
Opinion
reach their limits due to e.g. insufficient heat stability,
brittleness and relatively low gas barriers for other
applications.
Alternatively, there are companies like Dow and
Braskem planning to make polyethylene from sugar
cane. The advantages of this approach are that PE is
already fully established in the market and the properties
for processing and applications are well known.
Even the waste streams do already exist and there
will be no issue of contamination, since the bio-based
polymer is chemically identical with its oil-based analog.
At least short- to mid-term, the bio-based PE could
be a viable alternative to PLA and starch-based biopolymers
and it remains to be seen which solution
will win recognition long-term.
Role of raw material suppliers
Ciba continuously strives for superior performance
and is committed to contribute to long-term sustainable
development. Regarding biopolymers simply as
a new type of polymer on the market, Ciba is committed
to learn more about these new materials. The
company is capitalizing on its expertise in polymers,
colorants and additives to support the development
of biopolymers by improving their technical performance
through additives, focusing on testing compatibility
with polymers and recycling rather than biodegradability.
Beyond the interests in the embryonic biopolymer
market, Ciba offers a wide range of sustainable solutions
for plastics and paper/paperboard packaging.
Consequently Ciba‘s contribution to sustainable
packaging will not only concentrate on additives and
colorants for biopolymers, but also include strength
solutions which allow significant light-weighing of
packaging as well as improvement of recycled resin
performance.
There will be no standard solution eliminating all
present and future concerns. Rather, the point is to
find individual ways to change general attitudes and
develop technologies to balance environmental, economic
and social aspects of sustainability in order to
ensure the same quality of life also for future generations.
www.ciba.com
34 bioplastics MAGAZINE [07/04] Vol. 2
Mailbox
!
!
Dear Editor,
It is always with great interest that we read bioplastics MAGAZINE as
it brings together a vital collection of news and views in bioplastics, an
industry that we at NatureWorks LLC are deeply committed to. In a recent
editorial in the 03/2007 issue it was suggested that availability in general
of NatureWorks ® biopolymer is causing signs of hesitation in the market.
This is an inaccurate statement and we feel this is an appropriate the time
to bring greater clarity on our current manufacturing position.
Due to the strong and unexpected market growth throughout 2006,
NatureWorks channeled available biopolymer in a secure and strategic
way to our existing partners by carefully mapping supply chains and material
flows. At the same time we reported that NatureWorks LLC continued
to increase production volume by de-bottlenecking production in our
Blair, NE, facility and as a result we are able to secure all existing end
user demands. Today we are also in a position to support and develop
new opportunities, confirming the continued and robust market growth
for NatureWorks biopolymer applications.
In all of what we do, NatureWorks seeks to include our core values
around sustainability and responsibility meaning that we are actively
seeking and having dialogue with key stakeholders to make sure everyone’s
effort follows the same approach.
I think most people close to this industry are aware of our peer reviewed
eco-profiles that have been updated and published recently to reflect key
progress made in this field, as well as position papers laying out our response
to issues such as feedstock sourcing, waste management and our
overall environmental footprint. Our colleague, Erwin Vink, will elaborate
on this in a paper that will be included in the next issue.
As people around the globe are working to make us less dependent on
fossil raw materials, the use of bioplastics contributes to this in a meaningful
way and bio-packaging solutions are a valuable way to demonstrate
this important evolution.
We are more than happy to provide more details around any of these
topics and we welcome innovative companies to bring their own responsible
products to market and join the growing assortment of applications
based on NatureWorks biopolymer and marketed as Ingeo innovations.
These include not only a complete range of biopackaging solutions but
also high value durable goods such as cosmetics and electronics, as well
as a full range of Ingeo fiber applications.
Please do not hesitate to contact us should you require further details.
Regards,
Mark Vergauwen – Commercial Director Europe, NatureWorks LLC
bioplastics MAGAZINE [07/04] Vol. 2 35
Basics
Logos Part 6:
A number of products made from bioplastics are already on
the market. Almost all of them are labelled with some kind of
a logo that tells the consumer about the special character of
the plastic material used. In this series of articles the logos
and their background are introduced by bioplastics MAGAZINE.
Here we address such questions as: What is the origin and
history of a logo? What does it mean? Which type of legislation
or regulation is it concerned with?
In previous issues bioplastics MAGAZINE introduced six
different logos that inform consumers about the biodagradability
or compostability of packaging and other products
made of bioplastics.
Before we start a new series in 2008, where we introduce
logos informing about the biobased origin of bioplastics products,
we‘d like to summarize the compostable/biodegradable
logos in the following table.
But also in future issues, we will inform our readers about
all modifications, consolidations or cooperations which might
arise about the existing logos.
Logo Name Association Meaning Certifying institute(s) Countries
Compostability
Mark, called
„the Seedling“
(bM 01/2006)
The “Compostable”
logo of BPI
(bM 02/2006)
The “OK Compost”
logo
(bM 01/2007)
European
Bioplastics
www.europeanbioplastics.org
Biodegradable
Products Institute,
USA
www.bpiworld.org
Vinçotte, Belgium
www.vincotte.com
compostable bioplastic
products according to
EN 13432, ASTM
D 6400, ISO 17088
compostable products
according to ASTM D
6400 (Compostable
Plastics) or ASTM
D6868 (Compostable
Packaging)
compostable bioplastic
packaging according to
EN 13432
DIN-Certco (D),
The Composting
Association (UK),
Keurmerk Instituut (NL),
Cobro (PL).
(others to follow)
BPI
Vinçotte, Belgium
Germany, Switzerland, the
Netherlands, Poland and the
United Kongdom.
In Austria the label is used in
model projects in Linz and St.
Pölten. European Bioplastics
promotes the use of product
certification and the use of a
unified label in Europe
USA, Canada
Belgium, France
The Finnish Apple
(bM 02/2007)
Finnish Solid Waste
Association, FSWA
www.jly.fi
mainly for compostable
biowaste bags,
certified in line with EN
13432
Finnish Solid Waste
Association, FSWA
Finnland
The Norwegian
Apple
(bM 02/2007)
Avfall Norge (Waste
Management Norway,
formerly NRF)
www.avfallnorge.no
mainly for compostable
biowaste bags,
certified in line with EN
13432
Avfall Norge
(Waste Management
Norway, formerly NRF)
Norway
“GreenPla”
logo Japan
(bM 03/2007)
Japan BioPlastics
Association(JBPA)
www.jbpaweb.net
Biodegradability according
to Japanese
and international
standards such as ISO
14851, 14852, 14855
Japan BioPlastics
Association (JBPA)
Japan
36 bioplastics MAGAZINE [07/04] Vol. 2
Basics Glossary
Glossary
Readers who know better explanations
or who would like to suggest
other explanations to be added
to the list, please contact the editor.
[*: bM ... refers to more comprehensive
article previously published in
bioplastics MAGAZINE)
In bioplastics MAGAZINE again
and again the same expressions
appear that some of our readers
might (not yet) be familiar with.
This glossary shall help with
these terms and shall help avoid
repeated explanations such as
„PLA (Polylactide)“ in various
articles.
Amylopectin
Polymeric branched starch molecule with very high molecular
weight (biopolymer, monomer is à Glucose).
Amyloseacetat
Linear polymeric glucose-chains are called à amylose.
If this compound is treated with ethan acid one product is
amylacetat. The hydroxyl group is connected with the organic
acid fragment.
Amylose
Polymeric non-branched starch molecule with high molecular
weight (biopolymer, monomer is à Glucose).
Biodegradable Plastics
Biodegradable Plastics are plastics that are completely
assimilated by the à microorganisms present a defined environment
as food for their energy. The carbon of the plastic
must completely be converted into CO 2
.during the microbial
process. For an official definition, please refer to the standards
e.g. ISO or in Europe: EN 14995 Plastics- Evaluation
of compostability - Test scheme and specifications. [bM*
02/2006 p. 34f, bM 01/2007 p38].
Blend
Mixture of plastics, polymer alloy of at least two microscopically
dispersed and molecularly distributed base polymers.
Cellophane
Clear film on the basis of à cellulose.
Cellulose
Polymeric molecule with very high molecular weight (biopolymer,
monomer is à Glucose), industrial production
from wood or cotton, to manufacture paper, plastics and
fibres.
Compost
A soil conditioning material of decomposing organic
matter which provides nutrients and enhances soil
structure.
Compostable Plastics
Plastics that are biodegradable under “composting“
conditions: specified humidity, temperature, à microorganisms
and timefame. Several national and international
standards exist for clearer definitions, for example
EN 14995 Plastics - Evaluation of compostability
- Test scheme and specifications [bM 02/2006 p. 34f, bM
01/2007 p38].
Composting
A solid waste management technique that uses natural
process to convert organic materials to CO 2
, water
and humus through the action of à microorganisms.
Copolymer
Plastic composed of different monomers.
Fermentation
Biochemical reactions controlled by à microorganisms
or enyzmes (e.g. the transformation of sugar into
lactic acid).
Gelatine
Translucent brittle solid substance, colorless or
slightly yellow, nearly tasteless and odorless, extracted
from the collagen inside animals‘ connective tissue.
Glucose
Monosaccharide (or simple sugar). G. is the most
important carbohydrate (sugar) in biology. G. is formed
by photosynthesis or hydrolyse of many carbohydrates
e. g. starch.
bioplastics MAGAZINE [07/04] Vol. 2 37
Basics Glossary
Humus
In agriculture, “humus“ is often used simply to mean
mature à compost, or natural compost extracted from
a forest or other spontaneous source for use to amend
soil.
Hydrophilic
Property: “water-friendly“, soluble in water or other
polar solvents (e.g. used in conjunction with a plastic
which is not waterresistant and weatherproof or that
absorbs water such as Polyamide (PA)).
Hydrophobic
Property: “water-resistant“, not soluble in water (e.g.
a plastic which is waterresistant and weatherproof, or
that does not absorb any water such as Polethylene (PE)
or Polypropylene (PP)).
Microorganism
Living organisms of microscopic size, such as bacteria,
funghi or yeast.
PCL
Polycaprolactone, a synthetic (fossil based), biodegradable
bioplastic, e.g. used as a blend component.
PHA
Polyhydroxyalkanoates are linear polyesters produced
in nature by bacterial fermentation of sugar or lipids.
The most common type of PHA is à PHB.
PHB
Polyhydroxyl buteric acid (better poly-3-hydroxybutyrate),
is a polyhydroxyalkanoate (PHA), a polymer belonging
to the polyesters class. PHB is produced by micro-organisms
apparently in response to conditions of
physiological stress. The polymer is primarily a product
of carbon assimilation (from glucose or starch) and is
employed by micro-organisms as a form of energy storage
molecule to be metabolized when other common
energy sources are not available. PHB has properties
similar to those of PP, however it is stiffer and more
brittle.
PLA
Polylactide, a bioplastic made of polymerised lactic
acid.
Saccharins or carbohydrates
Saccharins or carbohydrates are name for the sugar-family.
Saccharins are monomer or polymer sugar
units. For example, there are known mono-, di- and
polysaccharose. à glucose is a monosaccarin. They are
important for the diet and produced biology in plants.
Sorbitol
Sugar alcohol, obtained by reduction of glucose changing
the aldehyde group to an additional hydroxyl group. S. is
used as a plasticiser for bioplastics based on starch .
Starch
Natural polymer (carbohydrate) consisting of à amylose
and à amylopectin, gained from maize, potatoes, wheat,
tapioca etc. When glucose is connected to polymer-chains
in definite way the result (product) is called starch. Each
molecule is based on 300 -12000-glucose units. Depending
on the connection, there are two types à amylose and
à amylopectin known.
Starch (-derivate)
Starch (-derivates) are based on the chemical structure
of à starch. The chemical structure can be changed by
introducing new functional groups without changing the
à starch polymer. The product has different chemical qualities.
Mostly the hydrophilic character is not the same.
Starch-ester
One characteristic of every starch-chain is a free hydroxyl
group. When every hydroxyl group is connect with ethan acid
one product is starch-ester with different chemical properties.
Starch propionate and starch butyrate
Starch propionate and starch butyrate can be synthesis
by treating the à starch with propane or butanic acid. The
product structure is still based on à starch. Every based
à glucose fragment is connected with a propionate or butyrate
ester group. The product is more hydrophobic than
à starch.
Sustainable
An attempt to provide the best outcomes for the human
and natural environments both now and into the indefinite
future. One of the most often cited definitions of sustainability
is the one created by the Brundtland Commission,
led by the former Norwegian Prime Minister Gro Harlem
Brundtland. The Brundtland Commission defined sustainable
development as development that „meets the needs of
the present without compromising the ability of future generations
to meet their own needs.“ Sustainability relates to
the continuity of economic, social, institutional and environmental
aspects of human society, as well as the non-human
environment).
Thermoplastics
Plastics which soften or melt when heated and solidify
when cooled (solid at room temperature).
Yard Waste
Grass clippings, leaves, trimmings, garden residue.
38 bioplastics MAGAZINE [07/04] Vol. 2
Simply contact:
Tel.: +49-2359-2996-0 or suppguide@bioplasticsmagazine.com
Suppliers Guide
Stay permanently listed in the Suppliers Guide with your company logo and contact information.
For only 6,– EUR per mm, per issue you can be present among top suppliers in the field of bioplastics.
1. Raw Materials
1.1 bio based monomers
1.3 PLA
1.4 starch-based bioplastics
2. Additives /
Secondary raw materials
4. Bioplastics products
Du Pont de Nemours International S.A.
2, Chemin du Pavillon, PO Box 50
CH 1218 Le Grand Saconnex,
Geneva, Switzerland
Phone: + 41(0) 22 717 5176
Fax: + 41(0) 22 580 2360
thomas.philipon@che.dupont.com
www.packaging.dupont.com
1.2 compounds
BIOTEC Biologische
Naturverpackungen GmbH & Co. KG
Werner-Heisenberg-Straße 32
46446 Emmerich
Germany
Tel.: +49 2822 92510
Fax: +49 2822 51840
info@biotec.de
www.biotec.de
Du Pont de Nemours International S.A.
2, Chemin du Pavillon, PO Box 50
CH 1218 Le Grand Saconnex,
Geneva, Switzerland
Phone: + 41(0) 22 717 5176
Fax: + 41(0) 22 580 2360
thomas.philipon@che.dupont.com
www.packaging.dupont.com
3. Semi finished products
3.1 films
natura Verpackungs GmbH
Industriestr. 55 - 57
48432 Rheine
Tel.: +49 5975 303-57
Fax: +49 5975 303-42
info@naturapackaging.com
www.naturapackagign.com
Veriplast Holland BV
Stadhoudersmolenweg 70
NL - 7317 AW Apeldoorn
www.veripure.eu
Info@veripure.eu
R.O.J. Jongboom Holding B.V.
Biopearls
Damstraat 28
6671 AE Zetten
The Netherlands
Tel.: +31 488 451318
Mob: +31 646104345
info@biopearls.nl
www.biopearls.nl
BIOTEC Biologische
Naturverpackungen GmbH & Co. KG
Werner-Heisenberg-Straße 32
46446 Emmerich
Germany
Tel.: +49 2822 92510
Fax: +49 2822 51840
info@biotec.de
www.biotec.de
Plantic Technologies GmbH
Heinrich-Busold-Straße 50
D-61169 Friedberg
Germany
Tel: +49 6031 6842 650
Tel: +44 794 096 4681 (UK)
Fax: +49 6031 6842 656
info@plantic.eu
www.plantic.eu
1.5 PHA
1.6 masterbatches
PolyOne
Avenue Melville Wilson, 2
Zoning de la Fagne
5330 Assesse
Belgium
Tel.: + 32 83 660 211
info.color@polyone.com
www.polyone.com
Maag GmbH
Leckingser Straße 12
58640 Iserlohn
Germany
Tel.: + 49 2371 9779-30
Fax: + 49 2371 9779-97
shonke@maag.de
www.maag.de
Treofan Germany GmbH & Co. KG
Am Prime Parc 17
65479 Raunheim
Tel +49 6142 200-0
Fax +49 6142 200-3299
www.biophanfilms.com
www.earthfirstpla.com
www.sidaplax.com
www.plasticsuppliers.com
Sidaplax UK : +44 (1) 604 76 66 99
Sidaplax Belgium: +32 9 210 80 10
Plastic Suppliers: +1 866 378 4178
4.1 trays
5. Traders
5.1 wholesale
6. Machinery & Molds
Molds, Change Parts and Turnkey
Solutions for the PET/Bioplastic
Container Industry
284 Pinebush Road
Cambridge Ontario
Canada N1T 1Z6
Tel.: +1 519 624 9720
Fax: +1 519 624 9721
info@hallink.com
www.hallink.com
SIG Corpoplast GmbH & CO. KG
Meiendorfer Str. 203
22145 Hamburg, Germany
Tel. +49-40-679-070
Fax +49-40-679-07270
sigcorpoplast@sig.biz
www.sigcorpoplast.com
7. Plant engineering
FKuR Kunststoff GmbH
Siemensring 79
D - 47 877 Willich
Tel.: +49 (0) 2154 9251-26
Tel.: +49 (0) 2154 9251-51
patrick.zimmermann@fkur.de
www.fkur.de
Transmare Compounding B.V.
Ringweg 7, 6045 JL
Roermond, The Netherlands
Phone: +31 (0)475 345 900
Fax: +31 (0)475 345 910
info@transmare.nl
www.compounding.nl
Sukano Products Ltd.
Chaltenbodenstrasse 23
CH-8834 Schindellegi
Phone +41 44 787 57 77
Fax +41 44 787 57 78
www.sukano.com
1.7 reinforcing fibres/fillers
made from RRM
3.1.1 cellulose based films
INNOVIA FILMS LTD
Wigton
Cumbria CA7 9BG
England
Contact: Andy Sweetman
Tel.: +44 16973 41549
Fax: +44 16973 41452
andy.sweetman@innoviafilms.com
www.innoviafilms.com
Uhde Inventa-Fischer GmbH
Holzhauser Str. 157 - 159
13509 Berlin
Germany
Tel.: +49 (0)30 43567 5
fax: +49 (0)30 43567 699
sales.de@thyssenkrupp.com
www.uhde-inventa-fischer.com
8. Ancillary equipment
9. Services
10. Research institutes /
Universities
bioplastics MAGAZINE [07/03] Vol. 2 39
Companies in this issue
Company Editorial Advert
Afvall Norge 36
Alcan Packaging 16
Amcor Flexibles 16
Arkema 8,17
BASF 9 2
Bayer Material Science 12
Biobag International 21
Biodegradable Products Institute (BPI) 36
BioLog 11
Bioplastics24 31
Biostarch 18
Biotec 8 39
Braskem 9,16
Brückner 9, 25
Ciba 32
Clubbioplastique 14
Cobro 36
Coopbox Europe 16
Cornell University, Ithaca, New York) 7
Cortec 31
Crystalsev 10
Delhaize 17
DIN Certco 36
D-M-E 13
Dow 10,13, 16
Du Pont de Nemours 5, 12 39
Elastogran 10,17
ETH Zürich 33
European Bioplastics 14
European Plastics News 16
Excellent Packaging & Supply 17
FAS Converting Machinery 21
Finnish Solid Waste Assiciation (FSWA) 36
FkuR 39
Forapack 19
Gehr 10
Greenblue 5
Hallink 39
Huhtamaki 7
Innovia Films 39
Japan BioPlastics Association (JBPA) 36
Jemaco 21
Kareline 11
Keurmerk Instituut 36
Leoplast 16
Maag 39
Meredian 6
Merquinsa Mercados Quimicos 16
Mitsubishi Plastics 8
Company Editorial Advert
Mitsui Chemicals 8
natura 39,43
Natureworks 35
NEC Corporation 17
nova Institut 7
Novamont 6, 17, 20 44
Novomer 6
Pira International 33
Plantic Technologies 39
Plasticker 31
Plasticsuppliers 39
PolyOne 39
Procter & Gamble 6
Purac 22
R.O.J. Jongboom Holding B.V., Biopearls 39
Reifenhäuser 11
Reimelt Henschel MischSysteme 11
Rondol 13
Rural Industries Research and Development 5
Corporation (RIRDC)
Sainsbury’s Supermarkets 17
SAM-A C&I 11
Scion 28
Sidaplax 39
SIG Corpoplast 13 39
SIG Plasmax 13
Sistec 13
Sphere 8
Stanelco 8
Sukano Products 39
Tejin 16
The Composting Association 36
Timberland 13
Toray Industries 9
Transmare Compounding 39
Treofan 16
Treofan Germany 39
Uhde Inventa-Fischer 39
Vanetti Materbatches 13
Veriplast 39
Vinçotte 36
Vitasheet 12
VTT Technical Research Center 10
Wal-Mart 17
Wiedmer 16
WIP 17
Next Issue
For the next issue of bioplastics MAGAZINE
(among others) the following subjects are scheduled:
Topics:
Foamed bioplastics
End of life options
Basics:
Sustainability
Logos (7)
Next issues:
01/08 January 2008
02/08 March 2008
03/08 April 2008
04/08 June 2008
05/08 September 2008
40 bioplastics MAGAZINE [04/07] Vol. 2
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bioplastics MAGAZINE [04/07] Vol. 2 41
Events
Event-Calendar
February, 18-20, 2008
Agricultural Film 2008
Fira Palace Hotel, Barcelona, Spain
www.amiplastics.com
March 3-4, 2008
3rd International Seminar on Biodegradable Polymers
Valencia, Spain
http://www.azom.com/details.asp?newsID=7345
April 1-3, 2008
JEC Composites Paris
including biobasesd polymers and natural fibers
Paris, France
www.jeccomposites.com
April 22-23, 2008
„Connecting comPETence“: PETnology Europe 2008
Düsseldorf/Neuss , Germany, prior to Interpack
http://www.petnology.com
April 24-30, 2008
Interpack - 2008
and here:
Bioplastics in Packaging
The interpack 2008 Group Exhibition
Düsseldorf, Germany
www.european-bioplastics.org
www.interpack.com
meet bioplastics MAGAZINE here
June 18-19, 2008
7th Global WPC and Natural Fibre Composites
Congress and Exhibition
Kongress Palais, Stadthalle, Kassel, Germany
www.wpc-nfk.de
42 bioplastics MAGAZINE [04/07] Vol. 2
natura means
business
natura packaging develops and markets
innovative, 100% biodegradable
packaging solutions. Our Europewide
activities can be divided into three main
categories;
• Fruit and vegetable packaging
• Waste management
(including the MaxAir system)
• Shopping bags (including our
popular ‘happy bag’)
Let natura help you get the most
out of your business.
Call +49 (0)5975 30357
or send an e-mail to
info@naturapackaging.com.
Industriestraße 55 - 57 48432 Rheine Tel. : +49 (0)5975/303-57 Fax. : +49 (0)5975/303-42 Email : info@naturapackaging.com
w w w . n a t u r a p a c k a g i n g . c o m
A real sign
of sustainable
development.
There is such a thing as genuinely sustainable development.
Since 1989, Novamont researchers have been working
on an ambitious project that combines the chemical
industry, agriculture and the environment: “Living
Chemistry for Quality of Life”. Its objective has been to
create products that have a low environmental impact.
The innovative result of Novamont’s research is the new
bioplastic Mater-Bi ® .The Mater-Bi ® polymer comes from maize starch and
other vegetable starches; it is completely biodegradable and compostable.
Mater-Bi ® performs like plastic, but it saves energy, contributes to reducing
the greenhouse effect, and at the end of its life cycle, it closes the loop by
changing into fertile humus. Everyone’s dream has become a reality.
Living Chemistry for Quality of Life.
www.novamont.com
Mater-Bi ® : certified and recommended biodegradability and compostability.