issue 02/2022
Highlights: Masterbatch/Additives Thermoforming/Rigid packaging Basics: Plastic or no-plastic On-site: Tecnaro
Highlights:
Masterbatch/Additives
Thermoforming/Rigid packaging
Basics: Plastic or no-plastic
On-site: Tecnaro
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Bioplastics - CO 2<br />
-based Plastics - Advanced Recycling<br />
bioplastics MAGAZINE Vol. 17<br />
Basics<br />
Plastic or no plastic -<br />
that’s the question 47<br />
Highlights<br />
Thermoforming / Rigid packaging | 49<br />
Masterbatch / Additives | 30<br />
... is read in 92 countries<br />
... is read in 92 countries<br />
<strong>02</strong> / 2<strong>02</strong>2<br />
ISSN 1862-5258 March/April
What are<br />
bioplastics?
dear<br />
Editorial<br />
readers<br />
I recently read an essay in The New Yorker called ”In A World On Fire, Stop Burning<br />
Things” that resonated with me a lot. While the article did not touch on the <strong>issue</strong>s of<br />
our industry specifically (e.g. plastic pollution or bioplastics vs. fossil-plastics) it did<br />
touch on the <strong>issue</strong> that goes far beyond – climate change, or I should rather say<br />
the climate crisis. The key message that Bill McKibben, author of the essay, tries to<br />
bring across is that we can switch from fossil to renewable energy right now – and<br />
that it would be cheaper long term to boot.<br />
Current geopolitical developments are more than proof that such a switch<br />
would be advisable. The war in Ukraine has sent shock waves through our global<br />
community, especially in “the West”. The incredible dependency on imported<br />
fossil fuels turned out to have a couple of pitfalls that many politicians (especially<br />
in Germany) only seem to realize now. The “easy and cheap” solution is now<br />
neither easy nor cheap. And European leaders scramble to fill their gas tanks,<br />
by swapping the dependency on Russia with a dependency on one or another<br />
potentially questionable big fossil-fuel exporter.<br />
Yet, I remain hopeful, or rather my hope is reawakening. Hope that this horrible<br />
war will be a catalyst that finally pushes renewables to the forefront. We need more<br />
renewable energy and we need more renewable materials – two industries that<br />
are often complementary. Resource independence is something that we should<br />
thrive for, not just because renewables are better for the climate, but because<br />
they offer a stabler economic environment. And just like with renewable energy<br />
that has become cheaper and cheaper over the years I am sure the same will hold true<br />
with bioplastics, given the chance. And I am not alone with this view, on page 44 Remy<br />
Jongboom shares his opinion on the fossil-fuel addiction and how to overcome it.<br />
This is not an addiction we’ll be able to cold turkey on, and fossil fuels will still play an<br />
important role in the coming years – the degree of that role is up for us to decide.<br />
Of course, this <strong>issue</strong> is not only philosophical excursions on why we should finally<br />
“go green”. We also have plenty of articles under our focus point of Additives &<br />
Masterbatches and our first On-site report after quite a while. Furthermore, our very<br />
own Editor in Chief tackled the topic of “plastics or no plastics” in our Basics section,<br />
albeit it might as well carry the label “Opinion”. Last but not least we also have a<br />
review of the esteemed bio!PAC conference (with the 7 th PLA World Congress already<br />
on the horizon), and many more stories big and small all around our little corner of the<br />
bioeconomy.<br />
And until we meet again in person, stay safe, fight the good fight, and cling to the<br />
hope that tomorrow will change for the better.<br />
Yours sincerely<br />
EcoComunicazione.it<br />
WWW.MATERBI.COM<br />
as orange peel<br />
adv arancia_bioplasticmagazine_01_<strong>02</strong>.2<strong>02</strong>0_210x297.indd 1 24/01/20 10:26<br />
r1_01.2<strong>02</strong>0<br />
bioplastics MAGAZINE Vol. 17<br />
Bioplastics - CO 2 -based Plastics - Advanced Recycling<br />
Basics<br />
Plastic or no plastic -<br />
that’s the question 50<br />
Highlights<br />
Thermoforming / Rigid packaging | 45<br />
Masterbatch / Additives | 24<br />
... is read in 92 countries<br />
... is read in 92 countries<br />
Follow us on twitter!<br />
www.twitter.com/bioplasticsmag<br />
<strong>02</strong> / 2<strong>02</strong>2<br />
ISSN 1862-5258 March/April<br />
Like us on Facebook!<br />
www.facebook.com/bioplasticsmagazine<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 3
Imprint<br />
Content<br />
34 Porsche launches cars with biocomposites<br />
32 Bacteriostatic PLA compound for 3D printingz<br />
Mar/Apr <strong>02</strong>|2<strong>02</strong>2<br />
Materials<br />
26 A new packaging solution for aerosols<br />
3 Editorial<br />
5 News<br />
38 Application News<br />
47 Basics<br />
48 Brand Owner<br />
49 10 years ago<br />
50 Suppliers Guide<br />
54 Companies in this <strong>issue</strong><br />
Publisher / Editorial<br />
Dr. Michael Thielen (MT)<br />
Alex Thielen (AT)<br />
Samuel Brangenberg (SB)<br />
Head Office<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
41066 Mönchengladbach, Germany<br />
phone: +49 (0)2161 6884469<br />
fax: +49 (0)2161 6884468<br />
info@bioplasticsmagazine.com<br />
www.bioplasticsmagazine.com<br />
Media Adviser<br />
Samsales (German language)<br />
phone: +49(0)2161-6884467<br />
fax: +49(0)2161 6884468<br />
sb@bioplasticsmagazine.com<br />
Michael Thielen (English Language)<br />
(see head office)<br />
Layout/Production<br />
Michael Thielen<br />
Events<br />
10 7 th PLA World Congress<br />
12 4 th bio!PAC - Review<br />
CCU<br />
14 Melt spinning of CO 2<br />
-based<br />
thermoplastic polyurethanes<br />
16 Engineered bacteria upcycle<br />
carbon waste into commodity chemicals<br />
Advanced Recycling<br />
17 Enzymatic recycling technology for<br />
textile circularity<br />
18 Protective furniture packaging from<br />
pyrolysis oil<br />
19 Converting plastic waste into<br />
performance products<br />
Materials<br />
20 When Zero-Waste Meets 3D Printing<br />
22 There are no silver bullets<br />
but this one has a pretty shine<br />
24 100 % biobased surfactants and<br />
polyethylene glycols (PEGs)<br />
26 Plastics as CO 2<br />
sinks<br />
From Science & Research<br />
28 Self-cleaning bioplastics – the lotus effect<br />
Masterbatch / Additives<br />
30 Making the leap into a new era<br />
31 Let’s adopt the right BioHaviour<br />
32 Breakthrough for biobased HMDA<br />
33 New compostable mineral fillers<br />
& black masterbatches<br />
34 Unique antistatic ingredient for bioplastics<br />
36 Masterbatches for soil improvement<br />
Applications<br />
37 Home compostable<br />
3D printing filament<br />
On-Site<br />
42 Tecnaro<br />
Methodology<br />
46 Bioplastic Feedstock Alliance (BFA)<br />
– new guidance<br />
Opinion<br />
44 About reducing the fossil<br />
fuel addiction via compostables<br />
47 Plastic or nor plastic - that’s the question<br />
Print<br />
Poligrāfijas grupa Mūkusala Ltd.<br />
1004 Riga, Latvia<br />
bioplastics MAGAZINE is printed on<br />
chlorine-free FSC certified paper.<br />
bioplastics magazine<br />
Volume 17 - 2<strong>02</strong>2<br />
ISSN 1862-5258<br />
bM is published 6 times a year.<br />
This publication is sent to qualified subscribers<br />
(169 Euro for 6 <strong>issue</strong>s).<br />
bioplastics MAGAZINE is read in<br />
92 countries.<br />
Every effort is made to verify all Information<br />
published, but Polymedia Publisher<br />
cannot accept responsibility for any errors<br />
or omissions or for any losses that may<br />
arise as a result.<br />
All articles appearing in<br />
bioplastics MAGAZINE, or on the website<br />
www.bioplasticsmagazine.com are strictly<br />
covered by copyright. No part of this<br />
publication may be reproduced, copied,<br />
scanned, photographed and/or stored<br />
in any form, including electronic format,<br />
without the prior consent of the publisher.<br />
Opinions expressed in articles do not necessarily<br />
reflect those of Polymedia Publisher.<br />
bioplastics MAGAZINE welcomes contributions<br />
for publication. Submissions are<br />
accepted on the basis of full assignment<br />
of copyright to Polymedia Publisher GmbH<br />
unless otherwise agreed in advance and in<br />
writing. We reserve the right to edit items<br />
for reasons of space, clarity or legality.<br />
Please contact the editorial office via<br />
mt@bioplasticsmagazine.com.<br />
The fact that product names may not be<br />
identified in our editorial as trade marks<br />
is not an indication that such names are<br />
not registered trade marks.<br />
bioplastics MAGAZINE tries to use British<br />
spelling. However, in articles based on<br />
information from the USA, American<br />
spelling may also be used.<br />
Envelopes<br />
A part of this print run is mailed to the<br />
readers wrapped bioplastic envelopes<br />
sponsored by Sidaplax/Plastic Suppliers<br />
(Belgium/USA). Another part is sponsored<br />
by Minima Technology,Taiwan.<br />
Cover<br />
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TerraVerdae Bioworks<br />
to acquire PolyFerm<br />
Canada<br />
TerraVerdae Bioworks (Edmonton, AL, Canada)<br />
announced that it has signed a binding letter of<br />
intent to acquire 100 % of the equity of PolyFerm<br />
Canada.<br />
TerraVerdae is a world-leading performance<br />
biopolymers company.<br />
PolyFerm (Harrowsmith, ON, Canada) has<br />
a unique technology portfolio of biobased and<br />
biodegradable elastomeric polymers known as mcl<br />
PHAs. The addition of PolyFerm will strengthen<br />
TerraVerdae’s core capabilities and enhance the<br />
Company’s ability to produce biopolymers and<br />
resins for a wider range of applications, including<br />
for films, coatings, and adhesives.<br />
“The addition of PolyFerm’s capabilities and<br />
know-how represents a significant opportunity for<br />
TerraVerdae to advance new and valuable solutions<br />
to help the world develop sustainable plastic<br />
solutions that can reduce its carbon footprint”,<br />
said William Bardosh, CEO of TerraVerdae.<br />
As part of the acquisition, Bruce Ramsay,<br />
President of PolyFerm, will join the TerraVerdae<br />
team to help expand its PHA technology<br />
development programs. Ramsay is a recognized<br />
leader in the field of biobased elastomeric PHA<br />
technologies. With over 30 years of significant<br />
achievements, he has developed a unique<br />
intellectual property portfolio in medium chain<br />
length (mcl) PHA technologies.<br />
“I am very pleased to be joining one of the<br />
biopolymer industry’s leading product development<br />
teams”, said Bruce Ramsay. “And, I look forward to<br />
accelerating TerraVerdae’s development process<br />
with the exceptional resources available at the<br />
Company”.<br />
The transaction is anticipated to close in the<br />
second quarter of 2<strong>02</strong>2. AT/MT<br />
www.terraverdae.com | www.polyfermcanada.com<br />
Chinaplas postponed<br />
Trade fair organizer Adsale announced on March 18 that the<br />
CHINAPLAS, one of the world's leading plastics and rubber<br />
trade fairs and widely recognized by the industry as the most<br />
influential exhibitions next to the K fair, will be postponed.<br />
In view of the latest COVID development and the further<br />
tightening of the pandemic control measures in Shanghai and<br />
other provinces of China, and to protect the health and safety of<br />
all show participants as well as to ensure the best participation<br />
result for the exhibitors, it was decided that the 35 th Chinaplas,<br />
International Exhibition on Plastics and Rubber Industries,<br />
scheduled to be held from 25-28 April 2<strong>02</strong>2 at National Exhibition<br />
and Convention Center in Shanghai will be postponed. New dates<br />
and other details of the exhibition are not known yet but will be<br />
announced soon.<br />
The World Health Organization (WHO), announced that China<br />
had nearly 16,000 new cases within 24 hours around the date<br />
of Adsale’s announcement. The daily total number of cases has<br />
dropped by more than 50% though over a week's time. Other<br />
news reported the big industrial cities of Shenzhen, Changchun,<br />
Dongguan, Jilin City, and Langfang were completely shut down.<br />
Although the 35 th Chinaplas cannot be held as scheduled, the<br />
organisers assure that the promotion of companies and their<br />
products via their different online channels will continue. “CPS+<br />
eMarketplace” is ready and positioned to connect interested<br />
parties with buyers from China and overseas. AT<br />
https://www.chinaplasonline.com<br />
News<br />
daily updated News at<br />
www.bioplasticsmagazine.com<br />
Picks & clicks<br />
Most frequently clicked news<br />
Here’s a look at our most popular online content of the past two months.<br />
The story that got the most clicks from the visitors to bioplasticsmagazine.com was:<br />
tinyurl.com/news-2<strong>02</strong>20128<br />
Huntsman develops biobased polyurethane for<br />
Keen's plant-based soles<br />
(28 January 2<strong>02</strong>2)<br />
Footwear experts at Huntsman have helped Keen develop a breakthrough<br />
production innovation – a range of sneakers with plant-based soles. The<br />
Field to Foot (F2F) sneakers were created by Keen’s Advanced Concepts<br />
Team, utilizing a specially developed biobased polyurethane system from<br />
Huntsman that contains a by-product from agricultural processing.<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 5
News<br />
daily updated News at<br />
www.bioplasticsmagazine.com<br />
Sulzer PLA technology<br />
for China<br />
Sulzer has been awarded by Yangzhou Huitong<br />
Biological New Material to supply technology and key<br />
equipment for its polylactic acid (PLA) production facility<br />
in Jiangsu Province, China. The facility will have a<br />
production capacity of 30,000 tonnes per year.<br />
The plant will be able to produce a large portfolio<br />
of PLA grades serving a broad range of end-use<br />
applications from food packaging to kitchen utensils or<br />
toys. Replacing traditional plastics with non-fossil based<br />
plastics directly contributes to an improved carbon<br />
footprint.<br />
The versatility of Sulzer’s PLA technology allows the<br />
production of a large range of molecular weights and<br />
stereoisomer ratios while meeting product high-quality<br />
standards.<br />
To meet Yangzhou Huitong Biological New Material’s<br />
requirements, Sulzer Chemtech will design and provide<br />
its lactide purification, polymerization, devolatilization<br />
and post-reaction proprietary technologies. The<br />
licensing agreement framework also includes extensive<br />
service support from engineering to technical assistance<br />
and field services. Sulzer Chemtech was selected for its<br />
proven track record as market leader, delivering scalable<br />
production solutions with both improved efficiency and<br />
quality for the production of PLA.<br />
Zhang JianGang, President of Yangzhou Huitong<br />
Biological New Material, adds: “This new facility will<br />
allow us to enter the fast-growing bioplastic market.<br />
We consider Sulzer an extremely valuable partner in<br />
this project. The company’s comprehensive technical<br />
services and cutting-edge production technologies<br />
for PLA will help us to effectively produce sustainable<br />
plastics and meet our customers’ strategic demands”.<br />
Torsten Wintergerste, Division President of Sulzer<br />
Chemtech, comments: “We are excited to support<br />
Yangzhou Huitong Biological New Material in their<br />
flagship project. Our PLA technologies are currently used<br />
in most PLA facilities worldwide. We couldn’t be prouder<br />
to be supporting customers with monomer purification<br />
and polymer production units that are helping advance<br />
the sustainable and circular plastics sector”. MT<br />
www.sulzer.com<br />
The Bioplastics Award<br />
is facing new<br />
horizons<br />
After 15 editions of the Global<br />
Bioplastics Award, the last 11<br />
hosted by bioplastics MAGAZINE,<br />
this prestigious prize is now<br />
facing new horizons.<br />
bioplastics MAGAZINE decided to<br />
discontinue this award. Instead,<br />
after pausing for one year,<br />
European Bioplastics will come<br />
up with a new edition of the<br />
award in 2<strong>02</strong>3.<br />
Of course, bioplastics MAGAZINE<br />
will continue to report about<br />
nominees and winners. So stay<br />
tuned. MT<br />
Plant-derived<br />
ethylene & propylene<br />
Mitsubishi Chemical Corporation (Tokyo, Japan) and<br />
Toyota Tsusho Corporation (Nagoya, Japan) have begun<br />
a joint consideration to manufacture and sale ethylene,<br />
propylene, and their derivatives using bioethanol as raw<br />
material, with an aim to commence operation in 2<strong>02</strong>5.<br />
There is a growing need for plastic reuse and recycling to<br />
achieve the realization of a sustainable recycling-oriented<br />
society. There are also strong expectations for realizing a<br />
sustainable life cycle by using plant-derived materials.<br />
MCC and Toyota Tsusho are working on the<br />
commercialization of various recycling processes and<br />
aim to realize a recycling-oriented society by switching<br />
from raw materials derived from fossil fuels to plantderived<br />
materials.<br />
In order to make a wide range of products more<br />
sustainable, including products that are generally difficult<br />
to collect and recycle among packaging/containers and<br />
sanitary goods, both companies have decided to examine<br />
how to commercialize the manufacture and sale of<br />
ethylene, propylene, and their derivatives made from<br />
plant-derived raw materials.<br />
MCC and Toyota Tsusho will evaluate the manufacture<br />
of 100 % plant-derived ethylene (bioethylene) and<br />
its derivatives using bioethanol as raw material,<br />
and the manufacture and sale of the first plantderived<br />
propylene in Japan (biopropylene) and its<br />
derivatives using bioethylene as its raw material. AT<br />
www.m-chemical.co.jp | www.toyota-tsusho.com/english/<br />
6 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
Global treaty targeting plastic pollution<br />
Heads of State, Ministers of environment and other representatives from 175 nations endorsed a historic resolution at the UN<br />
Environment Assembly (UNEA-5) on the 2 nd of March 2<strong>02</strong>2 in Nairobi (Kenia) to End Plastic Pollution and forge an international legally<br />
binding agreement by 2<strong>02</strong>4. The resolution addresses the full lifecycle of plastic, including its production, design, and disposal.<br />
The resolution, based on three initial draft resolutions from various nations, establishes an Intergovernmental Negotiating<br />
Committee (INC), which will begin its work in 2<strong>02</strong>2, with the ambition of completing a draft global legally binding agreement by the<br />
end of 2<strong>02</strong>4. It is expected to present a legally binding instrument, which would reflect diverse alternatives to address the full lifecycle<br />
of plastics, the design of reusable and recyclable products and materials, and the need for enhanced international collaboration to<br />
facilitate access to technology, capacity building and scientific and technical cooperation.<br />
The UN Environment Programme (UNEP) will convene a forum by the end of 2<strong>02</strong>2 that is open to all stakeholders in conjunction<br />
with the first session of the INC, to share knowledge and best practices in different parts of the world. It will facilitate open discussions<br />
and ensure they are informed by science, reporting on progress throughout the next two years. Finally, upon completion of the INC’s<br />
work, UNEP will convene a diplomatic conference to adopt its outcome and open it for signatures.<br />
“Today marks a triumph by planet earth over single-use plastics. This is the most significant environmental multilateral deal since<br />
the Paris accord. It is an insurance policy for this generation and future ones, so they may live with plastic and not be doomed by it”.<br />
“Let it be clear that the INC’s mandate does not grant any stakeholder a two-year pause. In parallel to negotiations over an<br />
internationally binding agreement, UNEP will work with any willing government and business across the value chain to shift away<br />
from single-use plastics, as well as to mobilise private finance and remove barriers to investments in research and in a new circular<br />
economy”, said Inger Andersen, Executive Director of UNEP.<br />
Plastic production soared from 2 million tonnes in 1950 to 348 million tonnes in 2017, becoming a global industry valued at USD<br />
522.6 billion, and it is expected to double in capacity by 2040. The impacts of plastic production and pollution on the triple planetary<br />
crisis of climate change, nature loss and pollution are a catastrophe in the making.<br />
The historic resolution, titled “End Plastic Pollution: Towards an internationally legally binding instrument” was adopted with the<br />
conclusion of the three-day UNEA-5.2 meeting, attended by more than 3,400 in-person and 1,500 online participants from 175 UN<br />
Member States, including 79 ministers and 17 high-level officials. AT<br />
https://www.unep.org<br />
News<br />
daily updated News at<br />
www.bioplasticsmagazine.com<br />
We design colors with a purpose to allow our<br />
planet to remain as colorful today and tomorrow.<br />
Our SUKANO® PHA color Portfolio, designed for direct food contact, available for industrially<br />
and home compostable applications and allows soil and marine biodegradability.<br />
Formulated to your needs and requirements.<br />
www.sukano.com<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 7
News<br />
daily updated News at<br />
www.bioplasticsmagazine.com<br />
PHA production capacity to increase tenfold<br />
A new market report “Mimicking Nature – The PHA Industry Landscape. Latest trends and 28 producer profiles” was recently<br />
published by GO!PHA and nova-Institute.<br />
Natural PHAs are a class of materials that exist in nature for millions of years. These materials are both biobased and<br />
biodegradable, similar to other natural materials such as cellulose, proteins, and starch. Natural PHAs are produced by<br />
an extensive variety of microorganisms through bacterial fermentation. Due to its high performance, biocompatibility,<br />
biodegradability, and green credentials, the PHA family has a large design space and accommodates a wide range of market<br />
applications, as a broad variety of different polymers can be produced and blended. The potential of PHAs is enormous.<br />
Natural PHAs have been intensively researched for many years and many hopes for more environmentally friendly polymers<br />
are based on these PHAs. There have been highs and lows over the last 20 years, several expansions and scale-up plans have<br />
been postponed or even cancelled. A few reasons for that were the challenges of technology scale-up, product and application<br />
development needs, an underestimation of how much time it takes for a new polymer-platform to penetrate the market, and<br />
the time it takes for previously unconnected disciplines to understand each other for the benefit of successfully addressing all<br />
opportunities. But now, the momentum for this new polymer platform is rapidly changing for the better.<br />
At the end of 2<strong>02</strong>1, there was an installed manufacturing capacity of about 48,000 tonnes per up and running, based on the<br />
information from the companies described in the market report “Mimicking Nature – The PHA Industry Landscape. Latest<br />
trends and 28 producer profiles”. Capacity expansions have been announced and there are numerous plants under construction.<br />
Together, the manufacturers aim for a manufacturing capacity of about 570,000 tonnes per annum by 2<strong>02</strong>7.<br />
Developing new products to create a sustainable future for polymers, respecting the environment and our future generations<br />
is the motivation for most parties working on this new materials platform. They are in tune with a rapidly changing plastics<br />
industry. Most companies portrayed in the market report are/were start-ups when they began their natural PHA activities. Only<br />
six companies are already established in the market. The report is a must-read for all those interested in the very latest in<br />
PHAs, as developers, producers or, above all, users. The information on the companies described has been checked with each<br />
of them and is state-of-the-art for February 2<strong>02</strong>2.<br />
The Author of “Mimicking Nature” is Jan Ravenstijn, who has been working intensively on the topic of PHAs for 20 years,<br />
is the author of numerous publications and co-founder of the Global Organization for PHA, GO!PHA. The report is a joint<br />
publication of GO!PHA and nova-Institute.<br />
“Mimicking Nature – The PHA Industry Landscape. Latest trends and 28 producer profiles” is available at www.renewablecarbon.eu/publications<br />
starting at EUR 1,500” (see also p. 9). AT<br />
www.nova-institute.eu | www.gopha.org<br />
ECO profile of PLA available to product designers<br />
To support designers TotalEnergies Corbion (Gorinchem,<br />
The Netherlands) has enabled Sphera’s Product<br />
Sustainability (formerly GaBi) database users to access the<br />
Luminy ® PLA ecological product profile. The ECO profile<br />
allows designers to quantify the environmental impact of<br />
PLA in product design and production choosing Luminy PLA.<br />
Sphera’s Product Sustainability software is the world's<br />
leading Life Cycle Assessment (LCA) modelling and<br />
reporting software with intuitive data collection and result<br />
analytics. LCA is a scientific-based technique that allows<br />
optimizing the environmental impact of a product, through a<br />
comprehensive assessment of its lifecycle. From extraction<br />
of a raw material to its disposal or preparation for reuse,<br />
all relevant environmental impacts are considered, as far<br />
as quantifiable. Sphera’s Product Sustainability database<br />
has by far the largest Lifecycle Inventory (LCI) data industry<br />
coverage worldwide. Also, regionalized water and land use<br />
data are included throughout.<br />
“The detailed analysis of scenarios in the production and<br />
end-of-life phase enables our customers to choose the<br />
most sustainable solution for their products. Making our<br />
LCA data available in the leading databases will give access<br />
to our data to every Sphera LCA Software user globally. All<br />
users will be able to add our data to their own modelling to<br />
complete their view on the environmental impacts of their<br />
supply chain”, says François de Bie, Senior Marketing and<br />
Supply Chain Director at TotalEnergies Corbion. He adds<br />
“now producers and brand owners are quickly able to quantify<br />
the Green House Gas emissions saving that a conversion<br />
to biobased Luminy PLA will bring for their products. Such<br />
‘cradle to grave’ analyses are helpful to comply with the<br />
latest EU Taxonomy regulations and allow brand owners to<br />
make credible claims about the CO 2<br />
reductions”.<br />
Informed decision-making in production, setup and<br />
design will contribute to achieving sustainability goals<br />
across industries. Sphera’s Product Sustainability<br />
databases provide explicit knowledge of the product’s<br />
environmental performance through scenario analysis. This<br />
is an important tool to meet today’s market expectations<br />
and for the contribution of product designers to tackling<br />
environmental concerns. TotalEnergies Corbion believes in<br />
an unbiased and transparent reporting of the environmental<br />
impact of its PLA resins. MT<br />
www.totalenergies-corbion.com | www.sphera.com<br />
8 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
All figures available at www.bio-based.eu/markets<br />
Adipic acid (AA)<br />
11-Aminoundecanoic acid (11-AA)<br />
1,4-Butanediol (1,4-BDO)<br />
Dodecanedioic acid (DDDA)<br />
Epichlorohydrin (ECH)<br />
Ethylene<br />
Furan derivatives<br />
D-lactic acid (D-LA)<br />
L-lactic acid (L-LA)<br />
Lactide<br />
Monoethylene glycol (MEG)<br />
Monopropylene glycol (MPG)<br />
Naphtha<br />
1,5-Pentametylenediamine (DN5)<br />
1,3-Propanediol (1,3-PDO)<br />
Sebacic acid<br />
Succinic acid (SA)<br />
© -Institute.eu | 2<strong>02</strong>0<br />
fossil<br />
available at www.renewable-carbon.eu/graphics<br />
Refining<br />
Polymerisation<br />
Formulation<br />
Processing<br />
Use<br />
renewable<br />
Depolymerisation<br />
Solvolysis<br />
Thermal depolymerisation<br />
Enzymolysis<br />
Purification<br />
Dissolution<br />
Recycling<br />
Conversion<br />
Pyrolysis<br />
Gasification<br />
allocated<br />
Recovery<br />
Recovery<br />
Recovery<br />
conventional<br />
© -Institute.eu | 2<strong>02</strong>1<br />
© -Institute.eu | 2<strong>02</strong>0<br />
PVC<br />
EPDM<br />
PP<br />
PMMA<br />
PE<br />
Vinyl chloride<br />
Propylene<br />
Unsaturated polyester resins<br />
Methyl methacrylate<br />
PEF<br />
Polyurethanes<br />
MEG<br />
Building blocks<br />
Natural rubber<br />
Aniline Ethylene<br />
for UPR<br />
Cellulose-based<br />
2,5-FDCA<br />
polymers<br />
Building blocks<br />
for polyurethanes<br />
Levulinic<br />
acid<br />
Lignin-based polymers<br />
Naphtha<br />
Ethanol<br />
PET<br />
PFA<br />
5-HMF/5-CMF FDME<br />
Furfuryl alcohol<br />
Waste oils<br />
Casein polymers<br />
Furfural<br />
Natural rubber<br />
Saccharose<br />
PTF<br />
Starch-containing<br />
Hemicellulose<br />
Lignocellulose<br />
1,3 Propanediol<br />
polymer compounds<br />
Casein<br />
Fructose<br />
PTT<br />
Terephthalic<br />
Non-edible milk<br />
acid<br />
MPG NOPs<br />
Starch<br />
ECH<br />
Glycerol<br />
p-Xylene<br />
SBR<br />
Plant oils<br />
Fatty acids<br />
Castor oil<br />
11-AA<br />
Glucose Isobutanol<br />
THF<br />
Sebacic<br />
Lysine<br />
PBT<br />
acid<br />
1,4-Butanediol<br />
Succinic<br />
acid<br />
DDDA<br />
PBAT<br />
Caprolactame<br />
Adipic<br />
acid<br />
HMDA DN5<br />
Sorbitol<br />
3-HP<br />
Lactic<br />
acid<br />
Itaconic<br />
Acrylic<br />
PBS(x)<br />
acid<br />
acid<br />
Isosorbide<br />
PA<br />
Lactide<br />
Superabsorbent polymers<br />
Epoxy resins<br />
ABS<br />
PHA<br />
APC<br />
PLA<br />
available at www.renewable-carbon.eu/graphics<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
OH<br />
O<br />
OH<br />
HO<br />
OH<br />
HO<br />
OH<br />
O<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
■<br />
OH<br />
HO<br />
OH<br />
O<br />
OH<br />
O<br />
© -Institute.eu | 2<strong>02</strong>1<br />
nova Market and Trend Reports<br />
on Renewable Carbon<br />
The Best Available on Bio- and CO2-based Polymers<br />
& Building Blocks and Chemical Recycling<br />
Mimicking Nature –<br />
The PHA Industry Landscape<br />
Latest trends and 28 producer profiles<br />
Bio-based Naphtha<br />
and Mass Balance Approach<br />
Status & Outlook, Standards &<br />
Certification Schemes<br />
Bio-based Building Blocks and<br />
Polymers – Global Capacities,<br />
Production and Trends 2<strong>02</strong>0–2<strong>02</strong>5<br />
Polymers<br />
News<br />
daily updated News at<br />
www.bioplasticsmagazine.com<br />
Principle of Mass Balance Approach<br />
Feedstock<br />
Process<br />
Products<br />
Use of renewable feedstock<br />
in very first steps of<br />
chemical production<br />
(e.g. steam cracker)<br />
Utilisation of existing<br />
integrated production for<br />
all production steps<br />
Allocation of the<br />
renewable share to<br />
selected products<br />
Author: Jan Ravenstijn<br />
March 2<strong>02</strong>2<br />
This and other reports on renewable carbon are available at<br />
www.renewable-carbon.eu/publications<br />
Authors: Michael Carus, Doris de Guzman and Harald Käb<br />
March 2<strong>02</strong>1<br />
This and other reports on renewable carbon are available at<br />
www.renewable-carbon.eu/publications<br />
Authors: Pia Skoczinski, Michael Carus, Doris de Guzman,<br />
Harald Käb, Raj Chinthapalli, Jan Ravenstijn, Wolfgang Baltus<br />
and Achim Raschka<br />
January 2<strong>02</strong>1<br />
This and other reports on renewable carbon are available at<br />
www.renewable-carbon.eu/publications<br />
Carbon Dioxide (CO 2) as Chemical<br />
Feedstock for Polymers<br />
Technologies, Polymers, Developers and Producers<br />
Chemical recycling – Status, Trends<br />
and Challenges<br />
Technologies, Sustainability, Policy and Key Players<br />
Plastic recycling and recovery routes<br />
Production of Cannabinoids via<br />
Extraction, Chemical Synthesis<br />
and Especially Biotechnology<br />
Current Technologies, Potential & Drawbacks and<br />
Future Development<br />
Virgin Feedstock<br />
Renewable Feedstock<br />
Plant extraction<br />
Chemical synthesis<br />
Monomer<br />
Secondary<br />
valuable<br />
materials<br />
Chemicals<br />
Fuels<br />
Others<br />
Cannabinoids<br />
Polymer<br />
Primary recycling<br />
(mechanical)<br />
Plastic<br />
Product<br />
Secondary recycling<br />
(mechanical)<br />
Tertiary recycling<br />
(chemical)<br />
CO 2 capture<br />
Genetic engineering<br />
Plant extraction<br />
Biotechnological production<br />
Product (end-of-use)<br />
Quaternary recycling<br />
(energy recovery)<br />
Energy<br />
Landfill<br />
Authors: Pauline Ruiz, Achim Raschka, Pia Skoczinski,<br />
Jan Ravenstijn and Michael Carus, nova-Institut GmbH, Germany<br />
January 2<strong>02</strong>1<br />
This and other reports on renewable carbon are available at<br />
www.renewable-carbon.eu/publications<br />
Author: Lars Krause, Florian Dietrich, Pia Skoczinski,<br />
Michael Carus, Pauline Ruiz, Lara Dammer, Achim Raschka,<br />
nova-Institut GmbH, Germany<br />
November 2<strong>02</strong>0<br />
This and other reports on the bio- and CO 2-based economy are<br />
available at www.renewable-carbon.eu/publications<br />
Authors: Pia Skoczinski, Franjo Grotenhermen, Bernhard Beitzke,<br />
Michael Carus and Achim Raschka<br />
January 2<strong>02</strong>1<br />
This and other reports on renewable carbon are available at<br />
www.renewable-carbon.eu/publications<br />
Commercialisation updates on<br />
bio-based building blocks<br />
Levulinic acid – A versatile platform<br />
chemical for a variety of market applications<br />
Global market dynamics, demand/supply, trends and<br />
market potential<br />
Succinic acid – From a promising<br />
building block to a slow seller<br />
What will a realistic future market look like?<br />
Production capacities (million tonnes)<br />
Bio-based building blocks<br />
Evolution of worldwide production capacities from 2011 to 2<strong>02</strong>4<br />
4<br />
3<br />
2<br />
1<br />
2011 2012 2013 2014 2015 2016 2017 2018 2019 2<strong>02</strong>4<br />
OH<br />
OH<br />
O<br />
HO<br />
diphenolic acid<br />
O<br />
H 2N<br />
OH<br />
O<br />
5-aminolevulinic acid<br />
O<br />
O<br />
OH<br />
O O<br />
levulinate ketal<br />
O<br />
OH<br />
O<br />
levulinic acid<br />
O<br />
OR<br />
O<br />
levulinic ester<br />
O<br />
O<br />
ɣ-valerolactone<br />
O<br />
HO<br />
OH<br />
O<br />
succinic acid<br />
H<br />
N<br />
O<br />
5-methyl-2-pyrrolidone<br />
Pharmaceutical/Cosmetic<br />
Acidic ingredient for denture cleaner/toothpaste<br />
Antidote<br />
Calcium-succinate is anticarcinogenic<br />
Efferescent tablets<br />
Intermediate for perfumes<br />
Pharmaceutical intermediates (sedatives,<br />
antiphlegm/-phogistics, antibacterial, disinfectant)<br />
Preservative for toiletries<br />
Removes fish odour<br />
Used in the preparation of vitamin A<br />
Food<br />
Bread-softening agent<br />
Flavour-enhancer<br />
Flavouring agent and acidic seasoning<br />
in beverages/food<br />
Microencapsulation of flavouring oils<br />
Preservative (chicken, dog food)<br />
Protein gelatinisation and in dry gelatine<br />
desserts/cake flavourings<br />
Used in synthesis of modified starch<br />
Succinic<br />
Acid<br />
Industrial<br />
De-icer<br />
Engineering plastics and epoxy curing<br />
agents/hardeners<br />
Herbicides, fungicides, regulators of plantgrowth<br />
Intermediate for lacquers + photographic chemicals<br />
Plasticizer (replaces phtalates, adipic acid)<br />
Polymers<br />
Solvents, lubricants<br />
Surface cleaning agent<br />
(metal-/electronic-/semiconductor-industry)<br />
Other<br />
Anodizing Aluminium<br />
Chemical metal plating, electroplating baths<br />
Coatings, inks, pigments (powder/radiation-curable<br />
coating, resins for water-based paint,<br />
dye intermediate, photocurable ink, toners)<br />
Fabric finish, dyeing aid for fibres<br />
Part of antismut-treatment for barley seeds<br />
Preservative for cut flowers<br />
Soil-chelating agent<br />
Author:<br />
Doris de Guzman, Tecnon OrbiChem, United Kingdom<br />
Updated Executive Summary and Market Review May 2<strong>02</strong>0 –<br />
Originally published February 2<strong>02</strong>0<br />
This and other reports on the bio- and CO 2-based economy are<br />
available at www.bio-based.eu/reports<br />
Authors: Achim Raschka, Pia Skoczinski, Raj Chinthapalli,<br />
Ángel Puente and Michael Carus, nova-Institut GmbH, Germany<br />
October 2019<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Authors: Raj Chinthapalli, Ángel Puente, Pia Skoczinski,<br />
Achim Raschka, Michael Carus, nova-Institut GmbH, Germany<br />
October 2019<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
renewable-carbon.eu/publications<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 9
ioplastics MAGAZINE presents:<br />
7 th PLA World Congress<br />
24 + 25 MAY 2<strong>02</strong>2 > MUNICH > GERMANY<br />
The PLA World Congress in Munich/Germany, organised by bioplastics MAGAZINE<br />
now for the 7 th time, is the must-attend conference for everyone interested in PLA,<br />
its benefits, and challenges. The global conference offers high-class presentations<br />
from top individuals in the industry from Europe, USA, Thailand, and more. There<br />
will also be excellent networking opportunities along with a table top exhibition.<br />
More details, programme updates and a registration form can be found on the<br />
conference website.<br />
Together with the Holiday Inn Munich City Centre we’ll elaborate a suitable<br />
hygiene concept for the conference. For those who cannot travel due to Corona<br />
restrictions, we’ll offer online access to the event. Stay tuned.<br />
7 th PLA World Congress, preliminary programme<br />
For updates vitis www.pla-world-congress.com<br />
www.pla-world-congress.com<br />
Remy Jongboom, Biotec<br />
Oliver Buchholz, European Bioplastics<br />
Udo Mühlbauer, Uhde Inventa-Fischer<br />
Sebastian Körber, Fraunhofer ICT<br />
Francois de Bie, TotalEnergies Corbion<br />
Andrew Gill, Floreon / Clariant<br />
Patrick Gerritsen, Bio4Pack<br />
Lien Van der Schueren, Centexbel<br />
Ramani Narayan<br />
Kevin Yang, Shenzhen Esun Industrial Co<br />
Keynote Speech: The fossil addiction and bioplastics (t.b.c.)<br />
Policy and market information<br />
Lactic Acid and Lactide Technology by Uhde Inventa-Fischer<br />
Development of High-Temperature Resistant Stereocomplex PLA<br />
for Injection Moulding<br />
PLA capacity and recycling (t.b.c.)<br />
Floreon: Redefining PLA<br />
Current market reaction on PLA<br />
PLA melt spinning, coating and printing for fully biobased clothing<br />
Reviewing the science around biodegradability and (home) compostability of PLA<br />
Application and Recycling of PLA<br />
Nopadol Suanprasert, Global Biopolymers Biocomposites of PLA/natural rubber/fiber<br />
Frédéric van Gansberghe, Galactic<br />
Gregory Coué, Kompuestos (t.b.c.)<br />
Zsolt Bodnar, Filaticum<br />
Kerstin Müller, Fraunhofer IVV<br />
Michael Thielen, bioplastics MAGAZINE<br />
Panel discussion<br />
Chemical Recycling of PLA<br />
Masterbatches for PLA (t.b.c.)<br />
Composite 3D printing filaments<br />
PLA in current Research Projects: Material Development -<br />
Packaging Applications – Recycling<br />
Plastic or no plastic — that's the question<br />
Market development of PLA<br />
Subject to changes. We still have a few speaking slots available.<br />
Especially if speakers cannot travel due to Corona restrictions, we might have to swap<br />
speakers due to time zone differences.<br />
Please visit the conference website regularly.<br />
10 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
한국포장협회로고.ps 2016.11.21 8:26 PM 페이지1 MAC-18<br />
Register now!<br />
7 th PLA World Congress<br />
24 + 25 MAY 2<strong>02</strong>2 > MUNICH > GERMANY<br />
HYBRID EVENT<br />
organized by<br />
www.pla-world-congress.com<br />
PLA is a versatile bioplastics raw material from renewable<br />
resources. It is being used for films and rigid packaging, for<br />
fibres in woven and non-woven applications. Automotive,<br />
consumer electronics, and other industries are thoroughly<br />
investigating and even already applying PLA. New methods<br />
of polymerizing, compounding, or blending of PLA have<br />
broadened the range of properties and thus the range of<br />
possible applications. That‘s why bioplastics MAGAZINE is<br />
now organizing the 7 th PLA World Congress on:<br />
24 + 25 May 2<strong>02</strong>2 in Munich / Germany<br />
Experts from all involved fields will share their knowledge<br />
and contribute to a comprehensive overview of today‘s<br />
opportunities and challenges and discuss the possibilities,<br />
limitations, and future prospects of PLA for all kinds<br />
of applications. Like the five previous congresses, the<br />
7 th PLA World Congress will also offer excellent networking<br />
opportunities for all delegates and speakers as well as<br />
exhibitors of the table-top exhibition. Based on the good<br />
experience with the hybrid format (bio!TOY and PHA World<br />
Congress 2<strong>02</strong>1) we will offer this format also for future<br />
conferences, hoping the pandemic does no longer force us<br />
to. So participation at the 7 th PLA World Congress will be<br />
possible on-site as well as online.<br />
Media Partner<br />
Gold Sponsor:<br />
organized by<br />
Silver Sponsor:<br />
KOREA PACKAGING ASSOCIATION INC.<br />
Supported by:<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 11
Automotive Events<br />
bio!PAC 2<strong>02</strong>2<br />
To unlock the potential of<br />
bioplastics recycling routes<br />
T<br />
he 4 th conference on bioplastics and packaging, the<br />
bio!PAC 2<strong>02</strong>2, had a strong focus on unlocking the<br />
potential of different routes for the recyclability of<br />
bioplastics. Next to that, preventing the accumulation of<br />
microplastics, the environmental benefits of biodegradable<br />
packaging, and the developments of new packaging<br />
applications were very prominent on the agenda.<br />
The international speakers’ line-up consisted of 27<br />
speakers from industry, knowledge institutions, and brand<br />
owners. About 100 participants from 18 countries from all<br />
over the world were represented. The presentations provided<br />
the participants with the most up-to-date information<br />
to be able to evaluate the possibilities and challenges of<br />
packaging based on bioplastics. The conference was held<br />
online on 15 th and 16 th March 2<strong>02</strong>2.<br />
Recycling routes<br />
“To process all our plastic waste, we need all the different<br />
end-of-life options”, said Erwin Vink from NatureWorks<br />
in his presentation ‘The compostables Project’. He<br />
demonstrated that the problems are much bigger than just<br />
handling plastic waste but also gave guidance for what is<br />
needed to implement a successful composting system. His<br />
arguments were also confirmed by other speakers such as<br />
expert Bruno de Wilde of Organic Waste Systems (OWS).<br />
A new technique of bioplastics recycling was presented<br />
by Jan Pels, senior scientist at TNO. He is the developer<br />
of Torwash and demonstrated that this technology enables<br />
selective removal of biodegradables like PLA or PHA from<br />
contaminated waste streams and multilayer packaging by<br />
depolymerizing them to their original monomers. These<br />
monomers can be used again to make food approved virgin<br />
plastics. This allows full recycling, not down-cycling.<br />
Political influence on bioplastics<br />
“Nature is much better at recycling than humans”,<br />
said Remy Jongboom from Biotec in his presentation on<br />
the added value of compostable materials in packaging<br />
applications. He also pointed out what the current war<br />
between Ukraine and Russia can mean for the supply of<br />
fossil resources and how we should consider using biogas<br />
through anaerobic digestion as a supplement. “Biogas can<br />
also provide secured energy supply in comparison with wind<br />
and solar”. His presentation was overall a strong argument<br />
for resource independence that biobased and biodegradable<br />
materials can offer (see also page 44).<br />
Microplastics & Packaging<br />
“Mechanical or chemical recycling will not prevent<br />
microplastic problems. It is therefore crucial that policy<br />
guidelines recognize the benefits of biodegradable and<br />
biobased materials and provide a level playing field for<br />
all sustainable forms of carbon, including organically and<br />
chemically recycled carbon”, said Heidi Koljonen from<br />
12 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
By:<br />
Caroli Buitenhuis<br />
Green Serendipity<br />
Amsterdam, The Netherlands<br />
Automotive<br />
Sulapac in Finland. Sulapac developed luxury jar lids<br />
for Chanel, based on FSC certified wood chips that are<br />
by-products of industrial side-streams combined, upon<br />
Chanel’s request, with upcycled camellia seed shells.<br />
Leaving no microplastics behind.<br />
Packaging developments<br />
In his presentation on barrier materials for food<br />
packaging, Peter Ragaert, director at Pack4Food<br />
and professor of food packaging technology at Ghent<br />
University, demonstrated the outcomes of bioplastics<br />
barrier and shelf life projects. There were some<br />
surprising outcomes like there is no significant<br />
difference between the PET tray for meat packaging and<br />
a tray based on PHA (PHBV). The first results showed<br />
that the gas barrier properties of the PHBV tray were<br />
even a bit higher than the PET tray. His conclusion was:<br />
“For meat packaging, PHBV performed in the tests the<br />
same as PET”.<br />
Johann Zimmermann of NaKu demonstrated an<br />
innovative cartridge based on PLA for a cosmetics<br />
packaging which allows very precise dispensing of<br />
cream per use. For this development Naku teamed<br />
up with a cosmetics company to develop the reusable<br />
packaging (see also page 41).<br />
A biobased multilayer packaging foil based on sidestream<br />
starches and biobased PE is developed by<br />
Rodenburg Biopolymers. It is a three layers foil with<br />
the possibility to regulate the OTR and WVTR to keep<br />
fruits and vegetables fresh, to expand their shelf life and<br />
prevent food losses. “Test results show that lettuce stays<br />
fresh longer, sugar snaps stay crunchy longer”, said<br />
Thijs Rodenburg, CEO of the company.<br />
The bio!PAC takes place every two years and is<br />
organized by bioplastics MAGAZINE in collaboration with<br />
Green Serendipity. This year’s bio!PAC was a 100 %<br />
digital event, hopefully soon live events will become<br />
the norm again, but as the recent postponement of the<br />
Chinaplas showed – corona is not over yet.<br />
And in case you missed the conference, you can still<br />
get access to all presentations via video on demand. Just<br />
contact mt@bioplasticsmagazine.com.<br />
www.bio-pac.info<br />
Join us at the<br />
17th European<br />
Bioplastics Conference<br />
– the leading business forum for the<br />
bioplastics industry.<br />
REGISTER<br />
NOW!<br />
6/7 December 2<strong>02</strong>2<br />
Maritim proArte Hotel<br />
Berlin, Germany<br />
@EUBioplastics #eubpconf2<strong>02</strong>2<br />
www.european-bioplastics.org/events<br />
For more information email:<br />
conference@european-bioplastics.org<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 13
CCU<br />
Melt spinning of CO 2<br />
-based<br />
thermoplastic polyurethanes<br />
An environmentally friendly approach for the production of elastic yarns<br />
T<br />
he market of elastic yarns has grown massively over<br />
the past years, mainly driven by applications in apparel,<br />
sports, and medical textiles. For example, approx. 80 %<br />
of all currently circulated apparel textiles contain elastic yarns<br />
to provide stretch and comfort. Most of these elastic yarns are<br />
produced by dry spinning of thermoset polyurethanes (PU)<br />
which causes specific challenges: Production is slow as well<br />
as expensive and potentially hazardous solvents have to be<br />
used. These challenges may be overcome by switching from<br />
dry to melt spinning processes. Thermoplastic polyurethanes<br />
(TPU) fulfil the needs of high elasticity and melt spinnability.<br />
Additionally, the greenhouse gas CO 2<br />
can be used as one of<br />
the resources for TPU production. By this, “Carbon Capture<br />
and Utilization” (CCU) can be applied to the textile industry.<br />
Motivation: CCU, High Economic Efficiency and<br />
Improved Processability<br />
TPU are linear and basically structured in hard and soft<br />
segments. Soft segments are typically polyols while hard<br />
segments are composed of isocyanates and a chain extender<br />
[1, 2]. There are three major categories of polyols being<br />
applied: polyether, polyester, and polycarbonate polyols [3].<br />
Specific polyols offer a huge potential for increasing the<br />
sustainability of TPU. Over the past years and decades, large<br />
efforts have been made to enable the use of renewable<br />
materials for (thermoplastic) PU production. For example,<br />
biobased polyols have been derived from vegetable oils [4, 5].<br />
Besides these biobased approaches, the incorporation of CO 2<br />
as a resource is eligible for the production of polyols. Covestro<br />
AG (Leverkusen, Germany) has developed a process for the<br />
production of polyether-polycarbonate PU, based on CO 2<br />
containing polyols. The technology involves the reaction of<br />
epoxide with CO 2<br />
under the application of selective catalysts. [6]<br />
Figure 1: Mission Statement of “CO2Tex”<br />
The approach of Carbon Capture and Utilization (CCU) does<br />
not only provide the opportunity for the circulation of CO 2<br />
with positive environmental aspects but also offers economic<br />
advantages. Allied Market Research (Portland, Oregon, USA),<br />
estimated the market volume of elastic filaments to be USD<br />
10.5 billion in 2<strong>02</strong>2, starting from USD 5.8 billion in 2015. This<br />
corresponds to a CAGR of 8.8 % over the past seven years. [7]<br />
Roughly 80 % of this market is currently being supplied by<br />
dry-spun yarns, whose production requires the use of solvents<br />
such as dimethylformamide (DMF) [8, 9]. Melt-spun CO 2<br />
-based<br />
TPU-filaments can be expected to be 50 to 60 % lower in price<br />
than conventional solution-spun PU filaments [10]. The main<br />
reasons for this economic advantage can be found in processes<br />
as well as facilities. Generally, lower winding speeds of 500 to<br />
2,000 m/min can be achieved in dry spinning in comparison<br />
to up to 6,000 m/min in melt spinning [11]. For TPU, melt<br />
spinning processes with a winding speed of 2,500 m/min<br />
have already been developed on pilot scale [10]. Additionally,<br />
solvent evaporation in dry spinning processes is energyintensive<br />
but does not need to be applied for melt spinning<br />
processes [11].<br />
The main obstacle to the wide use of melt-spun TPU is the<br />
strong tackiness of these yarns which especially hampers<br />
the unwinding from spools and transport through the<br />
machines for fabric production. To reduce this tackiness,<br />
different approaches are being developed, investigated, and<br />
evaluated in the research project CO2Tex.<br />
The Research Project CO2Tex<br />
RWTH Aachen Institut für Textiltechnik (ITA) (Aachen,<br />
Germany) is currently conducting the publicly funded<br />
research project CO2Tex in cooperation with the funded<br />
partners W. Zimmermann (Weiler-Simmerberg, Germany),<br />
medi (Bayreuth, Germany), Schill+Seilacher (Böblingen,<br />
Germany), Oerlikon Textile (Remscheid, Germany), Carbon<br />
Minds (Köln, Germany) and adidas (Herzogenaurach,<br />
Germany).<br />
The Target of this project is the establishment of<br />
commercially viable elastic filament yarns made from<br />
CO 2<br />
-containing TPU. At the end of the project, these yarns<br />
should be processed as easily as possible in existing<br />
industrial plants into textile pre- and end products. For<br />
the development of at least one stable and reproducible<br />
melt spinning process, modifications are made to spinning<br />
plants. These modifications include the investigation of<br />
spinnerets, filament cooling, godet surfaces, as well as<br />
winding technology. Additionally, spin finishes are adapted<br />
to the process and tested. All developments are scaled up<br />
from pilot to industrial scale. If the production of suitable<br />
14 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
By<br />
Jan Thiel, Henning Löcken, Lukasz Debicki, and Thomas Gries<br />
RWTH Aachen Institut für Textiltechnik<br />
Aachen, Germany<br />
yarns is possible, the process chain for the production of<br />
sports and medical textiles is investigated and adapted.<br />
This includes the processes of covering, knitting, and<br />
finishing. Finally, the use of TPU yarns containing CO 2<br />
is evaluated ecologically as well as economically and<br />
compared to conventional dry-spun yarns. The mission<br />
statement of CO2Tex is displayed in Figure 1.<br />
After a first benchmark definition, first melt spinning<br />
trials are about to start at the ITA on pilot and technical<br />
scale before being upscaled to industrial scale at<br />
Oerlikon.<br />
Acknowledgement<br />
The authors would like to thank the German Federal<br />
Ministry of Education and Research for funding<br />
the research project within the innovation space<br />
BioTexFuture (funding code: 031B1207A).<br />
www.ita.rwth-aachen.de<br />
Bibliography<br />
[1] Fabricius, M.; Gries, T, Wulfhrost, B.: Fiber Tables: Elastane Fibers<br />
(spandex) Frankfurt am Main, Schwenk & Co. GmbH, 1995<br />
[2] Prisacariu, C.: Polyurethane elastomers: From morphology to mechanical<br />
aspects. Wien [a.o.]: Springer, 2011<br />
[3] Zhu, R.; Wang, Y.; Zhang, Z.; Ma, D.; Wang, X.: Synthesis of polycarbonate<br />
urethane elastomers and effects of the chemical structures on their thermal,<br />
mechanical and biocompatibility properties. Heliyon 2 (2016), pp. 1-17<br />
[4] Javni, I.; Petrović, Z.S.; Guo, A.; Fuller, R.: Thermal stability of<br />
polyurethanes based on vegetable oils. Journal of Applied Polymer Science<br />
77 (2000), No. 8, pp. 1723-1734<br />
[5] Lligadas, G.; Ronda, J.C.; Galià, M.; Cádiz, V.: Oleic and undecylenic acids<br />
as renewable feedstocks in the synthesis of polyols and polyurethanes.<br />
Polymers 2 (2010), No. 4, pp. 440-453, doi:10.3390/polym2040440<br />
[6] Gürtler, C.: “Dream production” : CO2 as raw material for polyurethanes.<br />
Brussels, 07.06.2013<br />
[7] Allied Market Research: Spandex fiber market by type of production<br />
method and application – global opportunity analysis and industry forecast,<br />
2014-2<strong>02</strong>2. Pune, India, 2016: URL www.alliedmarketresearch.com/spandexfiber-market<br />
, Accessed on March the 09th, 2<strong>02</strong>2<br />
[8] Koslowski, H.-J.: Chemiefaser-Lexikon. Begriffe – Zahlen –<br />
Handelsnamen. 12. erw. Auflg.: Frankfurt am Main: Deutscher Fachverlag<br />
GmbH, 2008<br />
[9] Gries, T.; Veit, D.;Wulfhorst, B.: Textile Fertigungsverfahren: Eine<br />
Einführung. München: Carl Hanser Verlag, 2014<br />
[10] Manvi, P.: Melt spinning of carbon di-oxide based thermoplastic<br />
polyurethane. Aachen [Diss.], Shaker, 2018<br />
[11] Gupta, V.B., Kothari, V.K. (Eds.): Manufactured fibre technology London<br />
[u.a.]: Chapman & Hall, 1997<br />
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bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 15
CCU<br />
Engineered bacteria<br />
upcycle carbon waste into<br />
commodity chemicals<br />
You might not recognize the words acetone and isopropanol<br />
(IPA), but the chances are that you use them. While these<br />
chemicals are beneficial – serving as the building blocks<br />
for thousands of products, including fuels, materials, acrylic<br />
glass, fabrics, and even cosmetics – they are generated from<br />
fossil inputs, leading to emissions of climate-warming CO 2<br />
into the air.<br />
Researchers led by LanzaTech (Skokie, Illinois, USA),<br />
Northwestern University (Evanston, Illinois, USA), and Oak<br />
Ridge National Lab (Oak Ridge, Tennessee, USA) have<br />
developed an efficient new process to convert waste gases,<br />
such as emissions from heavy industry or syngas generated<br />
from any biomass source, into either acetone or IPA. The<br />
secret to the new platform is Clostridium autoethanogenum,<br />
or C. auto, a bacterium engineered at LanzaTech that can<br />
convert waste carbon selectively into either ethanol, acetone,<br />
or IPA.<br />
Their methods, including a pilot-scale demonstration<br />
and life cycle analysis (LCA) showing the economic viability,<br />
are published in the journal Nature Biotechnology. The new<br />
technology actually uses greenhouse gas (GHG) emissions<br />
destined for the atmosphere, avoids burning fossil fuels and<br />
removes CO 2<br />
from the air. According to LCA, this carbonnegative<br />
platform could reduce GHG by over 160 %, playing<br />
a critical role in helping the USA reach a net-zero emissions<br />
economy.<br />
“This discovery is a major step forward in avoiding a climate<br />
catastrophe”, said Jennifer Holmgren, LanzaTech CEO. “Today,<br />
most of our commodity chemicals are derived exclusively<br />
from new fossil resources such as oil, natural gas, or coal.<br />
Acetone and IPA are two examples with a combined global<br />
market of USD 10 billion. The acetone and IPA pathways and<br />
tools developed will accelerate the development of other new<br />
products by closing the carbon cycle for their use in multiple<br />
industries”.<br />
Acetone and IPA are necessary industrial bulk and platform<br />
chemicals. For example, acetone is used as a solvent for<br />
many plastics and synthetic fibres, thinning polyester resin,<br />
cleaning tools, and nail polish remover. IPA is a chemical<br />
used in antiseptics, disinfectants, and detergents and can be<br />
a pathway to commercial plastics such as polypropylene, used<br />
in both the medical and automotive sectors. Both are used in<br />
acrylic glass. IPA also is a widely used disinfectant, serving as<br />
the basis for one of the two World Health Organization (WHO)<br />
-recommended sanitiser formulations, which are highly<br />
effective against SARS-CoV-2.<br />
The collaborators developed a gas fermentation process<br />
for carbon-negative production of either acetone or IPA by<br />
reprogramming LanzaTech’s commercial ethanol-producing<br />
bacterial strain through cutting-edge synthetic biology<br />
tools, including combinatorial DNA libraries and cell-free<br />
prototyping advanced modelling, and omics. The scientists<br />
relied on a three-pronged approach that comprised innovations<br />
in pathway refactoring, strain optimization, and process<br />
development to achieve the observed level of performance.<br />
“These innovations, led by cell-free strategies that guided<br />
both strain engineering and optimization of pathway enzymes,<br />
accelerated time to production by more than a year”, said<br />
Michael Jewett, the Walter. P Murphy Professor in Chemical<br />
and Biological Engineering in Northwestern’s McCormick<br />
School of Engineering and director of the Center of Synthetic<br />
Biology.<br />
The optimized process was scaled up to the pilot plant, and<br />
LCA showed significant GHG savings. “Conversion pathways<br />
for the production of any biofuel or bioproduct, including<br />
acetone and IPA, inevitably involve chemical byproducts<br />
that can cause or be the result of major bottlenecks”, said<br />
ORNL’s Tim Tschaplinski. “We used advanced proteomics and<br />
metabolomics to identify and overcome these bottlenecks for<br />
a highly efficient pathway. This approach can be applied to<br />
create streamlined processes for other chemicals of interest”.<br />
By proving scalable and economically viable bulk<br />
chemical production, the researchers have set the stage<br />
for implementation of a circular economic model in which<br />
the carbon from agriculture, industrial and societal waste<br />
streams can be recycled into a chemical synthesis value<br />
chain to perpetually displace ever-increasing volumes of<br />
products made from virgin fossil resources. Thereby, chemical<br />
synthesis would become a path to capturing, recycling, and<br />
utilizing waste carbon resources.<br />
The acetone strain and process development, genomescale<br />
modeling, life cycle analysis, and initial pilot runs<br />
were supported by the Bioenergy Technologies Office in<br />
DOE’s Office of Energy Efficiency and Renewable Energy.<br />
The cell-free prototyping and omics analyses were funded<br />
by the Biological and Environmental Research program in<br />
DOE’s Office of Science. DNA sequencing and synthesis was<br />
supported by the Joint Genome Institute, a DOE Office of<br />
Science User Facility. AT<br />
The journal article can be found at<br />
https://www.nature.com/articles/s41587-<strong>02</strong>1-01195-w.<br />
www.lanzatech.com | www.northwestern.edu | www.ornl.gov<br />
Genome<br />
Mining<br />
Pathway<br />
optimization<br />
Engineered<br />
enzymes<br />
Combinatorial library<br />
Strain<br />
optimization<br />
Cell-free prototyping<br />
Omics<br />
m/z<br />
Metabolic modeling<br />
Process<br />
optimization<br />
Fermentation<br />
development<br />
& scale-up<br />
Life cycle analysis<br />
How it works: the team took a three-pronged optimization approach<br />
to increase fermentation efficiency and output. (Courtesy: FE Liewet<br />
al/Nature Biotechnology)<br />
LCA<br />
16 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
Enzymatic recycling technology<br />
for textile circularity<br />
Carbios (Saint-Beauzire, France), a pioneer in the<br />
development of enzymatic solutions dedicated to the endof-life<br />
of plastic and textile polymers, recently announced<br />
the validation of the 3 rd and final technical step of the CE-PET<br />
research project, co-funded by ADEME (France’s Environment<br />
and Energy Management Agency), for which Carbios is the<br />
lead partner alongside its academic partner Toulouse White<br />
Biotechnology (Toulouse, France). This achievement confirms,<br />
once again, the full potential and breadth of Carbios’ enzymatic<br />
recycling process, C-ZYME. This breakthrough innovation<br />
makes it possible to produce a wide variety of products of<br />
equivalent quality to those of petro-sourced origin from any<br />
PET waste, including textiles.<br />
The first white PET fibre recycled enzymatically<br />
from coloured textile waste<br />
Worldwide, around 90 million tonnes of PET are produced<br />
each year, more than 2/3 of which are used to manufacture<br />
fibres. However, only 13 % of textile waste is currently recycled,<br />
mainly for downcycling, i.e. for lower quality applications (such<br />
as padding, insulators, or rags). By successfully manufacturing<br />
at pilot scale a white PET fibre that is 100 % enzymatically<br />
recycled from coloured textile waste, Carbios is paving the way<br />
for the circular economy in the textile industry. C-ZYME is now<br />
on the doorstep of industrialization and will soon enable the<br />
biggest brands to move closer to their sustainability goals.<br />
“Thanks to our breakthrough process, it will soon be<br />
possible to manufacture, on a large scale, t-shirts or bottles<br />
using polyester textile waste as raw material”, said Emmanuel<br />
Ladent, CEO of Carbios. “This is a major breakthrough that<br />
gives value to waste that currently has little or no value. It is a<br />
concrete solution that opens up a global market of 60 million<br />
tonnes per year of potential raw materials and will help to<br />
reduce the use of fossil resources”.<br />
Textile waste that can also be used to<br />
manufacture food contact packaging<br />
In November 2<strong>02</strong>0, Carbios had already produced the first<br />
transparent bottles from textile waste. These 100 % recycled<br />
PET bottles have now passed the food contact validation<br />
tests. This is an important step that paves the way for the use<br />
of a new waste source for the production of biorecycled PET<br />
food packaging.<br />
Separate collection of textile waste soon to be<br />
mandatory in Europe<br />
From 1 January 2<strong>02</strong>5 the separate collection of textile waste,<br />
which is already in place in some countries, will be mandatory<br />
for all EU Member States (European Directive 2018/851 on<br />
waste). Carbios’ process will be one of the solutions that will<br />
enable this waste to be sustainably recovered and included<br />
in a truly circular economy model. These technological<br />
validations were carried out as part of the CE-PET research<br />
project, co-funded by ADEME. In particular, the project<br />
aimed to develop Carbios’ enzymatic PET recycling process<br />
on textile waste. The C-ZYME technology is complementary<br />
to thermomechanical recycling and will make it possible to<br />
process plastic and textile waste deposits that are currently<br />
not or poorly recovered. For the validation of this stage of<br />
the project, Carbios received EUR 827,200 (EUR 206,800 in<br />
grants and EUR 620,400 in repayable advances). AT<br />
www.carbios.com/en<br />
Advanced Recycling<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 17
Advanced Recycling<br />
Protective furniture packaging<br />
from pyrolysis oil<br />
As of November 2<strong>02</strong>1, Ekornes, a Norwegian (Ikornnes)<br />
manufacturer of high-end design furniture uses EPS<br />
(expandable polystyrene) protective packaging that has a<br />
lower carbon footprint than virgin material by safeguarding<br />
the same properties. This is achieved by replacing fossil<br />
resources with recycled raw materials at the beginning<br />
of production. BASF (Ludwigshafen, Germany) supplies<br />
Styropor ® Ccycled to VARTDAL PLAST (Vartdal, Norway),<br />
who converts the material into moulded packaging parts for<br />
Stressless ® furniture made by Ekornes.<br />
“We are really proud to be the first company to launch<br />
this project together with Vartdal Plast and BASF with<br />
regards to design furniture. We always strive to have the<br />
best packaging solution to protect our quality furniture,<br />
and Styropor Ccycled offers exactly what we want: same<br />
properties as virgin material but at the same time meeting<br />
the needs to reduce our carbon footprint, a perfect fit<br />
into our sustainability strategy”, says Solveig Gaundal,<br />
Compliance and CSR Manager at Ekornes.<br />
Virgin-quality packaging – smaller carbon<br />
footprint<br />
Due to its manufacturing process, Styropor Ccycled has<br />
the same properties as conventional Styropor. Maintaining<br />
excellent packaging properties such as outstanding<br />
impact absorption and high compressive strength, which<br />
are essential for the protection of sophisticated design<br />
furniture. In the production of the packaging foams that<br />
have become so well-known over the last 70 years, pyrolysis<br />
oil replaces fossil raw materials. BASF sources this oil from<br />
technology partners who use a thermochemical process<br />
called pyrolysis to transform post-consumer plastic waste<br />
that would otherwise be used for energy recovery or go to<br />
landfill into this secondary raw material. BASF then uses the<br />
oil at the very beginning of the value chain to manufacture<br />
new plastics and other products.<br />
Since recycled and fossil raw materials are mixed in<br />
production and cannot be distinguished from each other,<br />
the recycled portion is allocated to Styropor Ccycled using<br />
a mass balance approach. Both the allocation process and<br />
the product itself, have been certified by an independent<br />
auditor. Compared with conventional Styropor, at least 50 %<br />
of CO 2<br />
is saved in the production of Styropor Ccycled.<br />
Also, for the converter Vartdal Plast Styropor Ccycled<br />
brings a lot of advantages as the product is identical to<br />
virgin material. Therefore, the production process does not<br />
have to be adjusted. The company and their products are<br />
certified according to the ecoloop certification programme,<br />
confirming that for the products 100 % recycled material<br />
was used as feedstock. “We are thrilled to be working<br />
together with BASF and Ekornes on this project. This is<br />
a testament of our mutual commitment towards a more<br />
sustainable future”, says Mounir El’Mourabit, product<br />
manager at Vartdal Plast.<br />
Contributing to the circularity of plastics<br />
“Current environmental policy focuses on reducing<br />
greenhouse gas emissions, conserving fossil resources,<br />
and avoiding or using waste. By using products from our<br />
ChemCycling project, our partner Ekornes is actively<br />
contributing to the recovery of plastics after their use phase<br />
and feeding them back into the materials loop”, says Klaus<br />
Ries, head of BASF’s Styrenics business in Europe. AT<br />
www.basf.com | www.vartdalplast.no | www.ekornes.com<br />
18 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
Converting plastic waste into<br />
performance products<br />
The Advanced upcycling start-up Novoloop (Menlo Park,<br />
CA, USA) is pioneering the chemical transformation of plastic<br />
waste into high-performance chemicals and materials.<br />
The company’s proprietary process technology, ATOD<br />
(Accelerated Thermal Oxidative Decomposition), breaks<br />
down polyethylene into chemical building blocks that can<br />
be synthesized into high-value products. Polyethylene is the<br />
most widely used plastic today yet only 9 % is recycled and<br />
virtually none is upcycled.<br />
The start-up has raised USD 11 million in Series A<br />
financing led by Envisioning Partners (Seoul, South Korea)<br />
with participation from Valo Ventures (Palo Alto, CA, USA)<br />
and Bemis Associates (Shirley, MA, USA); earlier investors<br />
who joined the round included SOSV (Princeton, NJ, USA),<br />
Mistletoe (Tokyo, Japan), and TIME Ventures (San Francisco,<br />
CA, USA).<br />
The first product based on Novoloop’s ATOD process is<br />
Oistre, a thermoplastic polyurethane (TPU) for use in highperformance<br />
applications such as footwear, apparel, sporting<br />
goods, automotive, and electronics. Oistre is the first TPU<br />
made from post-consumer polyethylene waste that matches<br />
the performance characteristics of virgin TPUs made from<br />
petrochemicals. At the same time, Oistre’s carbon footprint is<br />
up to 46 % smaller than conventional TPUs and uses up to 50 %<br />
upcycled content from post-consumer plastic waste and.<br />
“What really compelled us to lead the investment round is<br />
that Novoloop has found product-market fit,” said June Cha,<br />
Partner of Envisioning Partners. “Novoloop has proven that<br />
Oistre has a wide range of applications in the market even at<br />
their early stage”.<br />
Novoloop’s technology can upcycle carbon content found<br />
in common plastic waste like grocery bags, packaging, and<br />
agricultural plastics that is too low value for material recovery<br />
facilities to bale and sell. Instead, the plastics go into landfills<br />
or incinerators today. Novoloop’s ATOD technology aims to<br />
increase commercial demand for waste polyethylene.<br />
“Plastics are not going away anytime soon, so we need to<br />
innovate to close the gap between what is produced and what<br />
is repurposed. After years of technology development, we’re<br />
thrilled to announce backing by high-calibre investors and<br />
partners to commercialize this much-needed technology”,<br />
said Novoloop Co-founder and CEO Miranda Wang.<br />
“With this funding, we look forward to completing crucial<br />
pilot scale-ups and commercializing our process technology<br />
to make a lasting impact. Our team is excited to lead the<br />
circular economy revolution for plastics”, said Novoloop Cofounder<br />
and COO Jeanny Yao.<br />
Novoloop is also announcing the company’s new<br />
partnership with Bemis Associates, the leader in apparel<br />
bonding solutions such as seam tapes, which can be found<br />
in high-performance outerwear. Together, the companies<br />
will introduce Oistre into the Bemis product portfolio as a<br />
first step to replace virgin petroleum-based thermoplastic<br />
polyurethane.<br />
“We are extremely excited to partner with Novoloop”, said<br />
Bemis Director of Sustainability Ben Howard. “Novoloop’s<br />
technology is a major breakthrough for our supply chain.<br />
Scaling it will be a huge step in shifting away from virgin<br />
petroleum sources and reducing our products’ carbon<br />
footprints”.<br />
Novoloop is currently sampling and taking pre-orders for<br />
Oistre 65A, a soft grade polyester TPU for injection moulding<br />
especially suitable for footwear applications. Higher<br />
durometer grades of Oistre TPU will be introduced soon. AT<br />
www.novoloop.com<br />
All photos courtesy Novoloop Inc.<br />
Advanced Recycling<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 19
Materials<br />
When Zero-Waste<br />
meets 3D printing<br />
GREENFILL3D – a Polish start-up (located in Łódź)<br />
operating on the edge of ecological, biodegradable<br />
materials, and 3D printing, announces the premiere<br />
of its unique filament based on wheat bran – GF3D<br />
Branfill3d. The material was created in accordance with<br />
the modern concepts of zero-waste and circular economy<br />
in mind – the wheat bran is a waste product of pasta and<br />
noodles production.<br />
From the material, the start-up 3D printed proprietary<br />
advertising stands (so-called POS – point of sales), on<br />
which ready-made pasta will be presented. The<br />
project is being developed in cooperation with<br />
the MASPEX Group (Wadowice, Poland) – one of<br />
the largest food producers in Europe.<br />
The GF3D Branfill3d material is a composite<br />
of wheat bran, polylactic acid (PLA) – a<br />
popular bioplastic used in 3D printing,<br />
and other fully biodegradable ingredients<br />
that together give GF3D Branfill3d unique<br />
properties. “The material has fantastic and<br />
surprising properties. Initially, we were afraid<br />
that it would be brittle – a typical problem in<br />
composite materials based on e.g., wood.<br />
However, it turned out that because wheat<br />
bran is fibrous, the fibres connect with each<br />
other in finished 3D prints in such a way that<br />
they are flexible (but not elastic!)”, commented<br />
Paweł Ślusarczyk, Senior Marketing Manager<br />
at Greenfill3d. “If the printout has thick walls<br />
(more than 1 cm), the model is very durable and<br />
has internal elasticity, which greatly increases<br />
the impact toughness. Thin elements (1–5 mm)<br />
can be bent to some extent without the risk of<br />
breaking”.<br />
What’s more, during the 3D printing process,<br />
the material offers the scent of baked bread,<br />
which stays on the 3D printed parts for a long<br />
time.<br />
Greenfill3d prints POS stands with its 3D<br />
printer farm of over 40 machines. Each stand<br />
consists of 34 elements – assembly is quick<br />
and easy. In addition, the structure of the stand<br />
is modular, which may allow for its further expansion with<br />
additional modules. And it is sturdier than conventional<br />
stands. “The stand was assembled and loaded with noodles<br />
in mid-January – today (mid-March), the lowest side<br />
walls began to slightly deform, but nothing threatens the<br />
stability of the structure. It should also be remembered that<br />
traditional advertising stands (e.g. made of cardboard) are<br />
designed to survive only for 3–4 weeks after which they are<br />
disposed of. Ours has been in operation for over 8 weeks<br />
and apart from the delicate visual aspect, there are no signs<br />
of wear”, says Ślusarczyk.<br />
The result is an advertising stand presenting food<br />
products, which was created based on the remains of the<br />
same food material. Production wastes – instead of being<br />
thrown away or disposed of, were used to produce common<br />
tools to support sales.<br />
“3D printing that has its obvious limitations and will<br />
always lose to injection moulding in terms of quantities. A<br />
cardboard or PVC stand will always win to a stand made<br />
on a 3D printer in terms of quantities and prices. This is<br />
why we are looking for applications where personalization<br />
or uniqueness of the product is a factor”, so<br />
Ślusarczyk.<br />
The project perfectly fits the assumptions of<br />
the Zero-Waste and Circular Economy ideas and<br />
can be scaled to other areas. The properties of<br />
wheat bran material allow performing a number<br />
of different applications – everyday use items,<br />
decorative items but also industrial. Currently,<br />
the Greenfill3d team is conducting the first<br />
tests of the use of applications made of GF3D<br />
Branfill3d for a customer representing the<br />
automotive industry and intends to successively<br />
test it in other industries.<br />
“The world is changing before our eyes<br />
and so is the approach to production. In the<br />
world of typical industrial manufacturing (e.g.,<br />
automotive), the standard was to produce<br />
hundreds of thousands of spare parts for<br />
stock. For several years, thanks to the greater<br />
efficiency of 3D printers, these parts can now<br />
be produced on-demand – only when they are<br />
needed,” Ślusarczyk elaborates. “We view our<br />
business in the same way. 3D printing allows you<br />
to change from a mass-production approach to<br />
a more personalized, targeted one. Fewer things<br />
reaching specific people”.<br />
So far, the material has not been tested for<br />
its CO 2<br />
savings or biodegradability rate, which<br />
is mainly due to the fact that it’s still quite new.<br />
“This year, we plan to commission our<br />
scientific partner – the Polish Academy of<br />
Science (Warsaw, Polen) with a series of tests examining<br />
the material in this respect. However, we’re still thinking<br />
about changing the current chemical blend. What will<br />
stay untouched for sure is wheat bran, but the rest of the<br />
components may be completely changed. As for the current<br />
chemical blend, all ingredients are biodegradable, so there<br />
is no physical or chemical chance of them not biodegrading<br />
– we just don’t know how fast yet,” explained Ślusarczyk.<br />
Cooperation with the MASPEX Group<br />
MASPEX is the largest private Polish company in the<br />
food industry and one of the largest in Central and Eastern<br />
20 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
COMPEO<br />
Automotive<br />
Europe. Greenfill3d was selected as part of the<br />
ScaleUp Program organized by PARP (Polish Agency<br />
for Enterprise Development) to implement a joint<br />
project with the MASPEX Group for one of its main<br />
brands – the leader in the pasta category in Poland<br />
(Lublin) – the Lubella brand.<br />
Leading compounding technology<br />
for heat- and shear-sensitive plastics<br />
Joint work on the project began on July 1, 2<strong>02</strong>1, and<br />
on December 15, 2<strong>02</strong>1, the first prototype was ready for<br />
logistic trials. The final POS display was made of 20 %<br />
wheat bran filament, using shelf connectors made of<br />
PLA polymer, mounted on a pedestal made of 100 %<br />
recyclable cardboard, with the print of Greenguard ®<br />
certified paints.<br />
The innovative “ecoPOS” will soon be delivered to<br />
selected retail outlets, but Greenfill3d has quite big<br />
ambitions.<br />
“What we have achieved so far is quite extraordinary.<br />
However, at the moment we are working on something<br />
other – a certain technological solution in the field of<br />
post-processing, which will make our products not<br />
only natural and biodegradable but also very visually<br />
attractive. What we are going to do will be, to some<br />
extent, a breakthrough for 3D printing itself. I have<br />
no idea why no one has figured it out before, but I’m<br />
glad it’s us”, says Ślusarczyk not without pride. “We<br />
have already carried out a few tests and the effects<br />
are amazing. I hope that by the summer holidays we<br />
will manage to create something so intriguing that we<br />
will be able to share it with the world. We will strive to<br />
expand the boundaries in the field of natural materials<br />
and find the perfect bridge between biodegradability<br />
and usability”. AT<br />
https://greenfill3d.com<br />
Uniquely efficient. Incredibly versatile. Amazingly flexible.<br />
With its new COMPEO Kneader series, BUSS continues<br />
to offer continuous compounding solutions that set the<br />
standard for heat- and shear-sensitive applications, in all<br />
industries, including for biopolymers.<br />
Info:<br />
On March 14, 2<strong>02</strong>2, representatives of the Polish 3D<br />
Printing Industry met to sign a joint statement on Russia’s<br />
aggression against Ukraine. Representatives of 13 companies<br />
submitted their signatures in person, and 5 others signed<br />
them electronically. The statement condemned the actions<br />
of the Russian Federation towards the Ukrainian Nation<br />
and declared the suspension of any economic activity in<br />
the markets of the Russian Federation and the Republic of<br />
Belarus.<br />
Greenfill3d was one of the signatories of the statement.<br />
• Moderate, uniform shear rates<br />
• Extremely low temperature profile<br />
• Efficient injection of liquid components<br />
• Precise temperature control<br />
• High filler loadings<br />
www.busscorp.com<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 21
Materials<br />
There are no silver bullets<br />
Since I joined bioplastics MAGAZINE in a bigger capacity<br />
about two years ago I came across one material that just<br />
sounded too good to be true – the UBQ material. The<br />
premise of taking mixed municipality waste (or municipality<br />
solid waste – MSW) and turning it into plastic material<br />
without the need for separation lies somewhere between<br />
an oil sheikhs’ fever dream and an environmentalist’s wet<br />
dream. I was quite sceptical for a long time, as things that<br />
sound too good to be true often aren’t good at all. But UBQ<br />
kept popping up, be it collaboration with McDonald’s, or the<br />
use of UBQ material in the first Zero-Waste Car Luca (bM<br />
01/21), and the announcement of PepsiCo (Harrison, NY,<br />
USA) just a couple of weeks ago. UBQ was even featured<br />
in the last <strong>issue</strong> of bioplastics MAGAZINE in the context of<br />
Mercedes-Benz’s VISION EQXX (bM 01/22). This story was<br />
the kick-off to a closer examination of UBQ and I sat down<br />
(digitally) with Jack “Tato” Bigio, Co-CEO & Co-Founder<br />
at UBQ Materials. So, what is UBQ? Where does it come<br />
from? Where does it go? And is Tato secretly Cotton-Eye<br />
Joe? As with most things in life the answers are not always<br />
as straightforward as we’d like.<br />
Same-same, but different<br />
The purpose of UBQ is to substitute fossil-based plastics.<br />
From injection moulding through to extrusion and 3D<br />
printing anything is possible. It is compatible with most<br />
common resins on the market, but mainly in combination<br />
with PP, PE, PLA, PS and PVC. It can be compounded with<br />
additives commonly used in the industry to tune properties<br />
like any other polymer, while not being a polymer itself.<br />
“UBQ is a new member of the thermoplastics’ family,<br />
however, it is not a polymer, it is a composite thermoplastic<br />
material. The beauty of UBQ is that it performs very<br />
similar to other members of this family of polymers like<br />
e.g., polypropylene or polyethylene. Of course, all these<br />
materials have different mechanical properties, some are<br />
more rigid, some more flexible etc. UBQ falls into its own<br />
range of properties, which is within the range of all these<br />
other plastic materials. The incredible thing about UBQ, the<br />
‘too good to be true’ part, is that it can bond with all these<br />
other materials. If it bonds with polypropylene it becomes<br />
polypropylene, and this works also with PS, PVC, or PE.<br />
UBQ takes on the properties of the material it is bonded to.<br />
It can therefore do things that other thermoplastic can’t”,<br />
Tato explained. In general, UBQ’s substitution rates lie<br />
between 20 % and 60 %, depending on the application. The<br />
real difference of UBQ is its origin.<br />
Recycling, waste, and value<br />
UBQ starts where most other processes stop, with the<br />
unrecyclable that usually ends up in incineration or landfill.<br />
While waste management is different in different regions<br />
the average household waste (MSW) is a mix of about 85 %<br />
organic material and 15 % plastic materials. These waste<br />
streams have one common problem – contamination.<br />
The plastic materials are dirty, wet, and often multilayer<br />
applications – things that make them difficult to recycle<br />
and not that useful for incineration (wet materials need<br />
extra energy input). All these shortcomings are properties<br />
UBQ needs, or rather UBQ was designed to make these<br />
mixed and contaminated waste streams into a feedstock.<br />
“Society is obsessed with the recycling of plastics, but the<br />
large majority of the waste is overlooked. Plastics are only<br />
about 15–16 % of waste and you cannot recycle about half<br />
of them in the best of the cases”, says Tato. “The problem<br />
of waste cannot be solved by recycling plastics alone – it<br />
is a good thing to try to increase recycling rates from<br />
household waste, but nobody is talking about that 85 % that<br />
we happily sent to landfills and decompose into GHG gases<br />
like methane and CO 2<br />
”.<br />
So UBQ tries to tackle these overlooked 85 % in a process<br />
that is very different from chemical recycling, which<br />
needs very clean plastic material streams and very high<br />
temperatures. UBQ is created at low temperatures that<br />
range within 200 °C as higher temperatures would destroy<br />
all the organic particles that are necessary for the process.<br />
The process, therefore, needs comparatively little energy<br />
and no added water as the base material – waste – tends to<br />
be rather wet anyways.<br />
“In a first step metals and minerals that are highly<br />
recyclable are filtered out, they are valuable materials<br />
but don’t have any added value for our material. After the<br />
removal, we send these to recyclers and are left with the<br />
food residues, trimmings, cardboard, paper, mixed plastics,<br />
and diapers. All those materials together without the need<br />
for separation will be converted into UBQ – so UBQ is not<br />
a recycling technology. We’re converting these streams<br />
of materials, which are very heterogeneous and different,<br />
into one homogeneous, consistent material“, so Tato. “The<br />
problem for most recycling processes is the dirtiness of the<br />
material, but the dirtiness in trash – it’s organic matter –<br />
UBQ actually loves that ‘dirtiness.’ Luckily organic matter<br />
has a number of common particles that create the building<br />
blocks that we use to create this new bonding matrix. The<br />
mixed plastics that are part of the waste, those that are<br />
recyclable and unrecyclable then melt into the matrix, bond<br />
with it, and become part of the matrix. So, at the end of the<br />
day, you have a composite material where all these previous<br />
heterogeneous materials disappear into one material that<br />
has thermoplastic properties. These novel and unique<br />
properties enabled us to get patents on UBQ material<br />
worldwide”.<br />
One of the main goals of UBQ is to give waste value, if<br />
MSW has intrinsic value then the likelihood of it ending up<br />
in uncontrolled landfills (which are still the norm in many<br />
parts of the world) decreases. Due to the high GHG potential<br />
of waste in such landfills (as they lead to the development<br />
of methane which is 86 times more potent than CO 2<br />
) UBQ<br />
has a huge impact on materials’ carbon footprint. To put<br />
things in perspective, every tonne of fossil-based plastics<br />
22 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
ut this one has a pretty shine<br />
By Alex Thielen<br />
Materials<br />
emits between 2–5 tonnes of CO 2<br />
eq. Replacing one tonne of<br />
polypropylene (+2.7 tonnes CO 2<br />
eq/tonne) with UBQ (-11.7 CO 2<br />
eq/<br />
tonne), a total amount of +14.4 tonnes CO 2<br />
eq/tonne can be<br />
avoided.<br />
“The development of this discovery took us very, very many<br />
years because we needed to understand the chemistry of each<br />
and every step on the conversion process to then reach one<br />
consistent and homogenous material is not a simple thing.<br />
The fact that we got patents all over the world on UBQ material<br />
is because we created a new composition of matter – a novel<br />
thermoplastic that didn’t exist before us. A material to replace<br />
common resins that are scarce, expensive, and polluting”.<br />
UBQ has not been in the spotlight of the plastic world for long,<br />
as they started marketing the material in early 2019, but they<br />
have already made some waves. It is a USDA Certified Biobased<br />
material, EU and UK REACH compliant (the 100 % UBQ powder)<br />
and IFTA compliant. UBQ Materials is also a Certified B Corp<br />
company, among other things.<br />
“We are not a huge company yet, but the people already<br />
involved here are really remarkable. Our Board of Directors is<br />
really AAA and the International Advisory Board we put together<br />
is quite remarkable. We have Roget Kornberg of Stanford, Nobel<br />
Prize winner in chemistry in 2006, and Connie Hedegaard who is<br />
the former European Commissioner for climate action in Europe<br />
that led the Paris Accord. John Elkington who is considered one<br />
of the godfathers of sustainability in the world and all these,<br />
all these incredible people are around us since 5–7 years ago,<br />
helping us develop this idea – this technology, the network, the<br />
certifications, the validations, the permitting, and policy matters.<br />
And internally, we have a really remarkable team”.<br />
As Tato said UBQ is still rather small with a pilot plant just<br />
out of Tse’elim (Israel) with an annual capacity of 7,000 tonnes.<br />
However, a new large-scale facility with an annual capacity of<br />
80,000 tonnes is planned to start production this year – and many<br />
more are planned.<br />
While there are no silver bullets for our problems, and<br />
probably never will be, the technology behind UBQ might be able<br />
to make a dent in the climate/plastic pollution crisis, with a price<br />
competitive and highly valuable sustainable material that is also<br />
highly recyclable, thus supporting a truly circular economy.<br />
www.ubqmaterials.com<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 23
Masterbacth / Additives<br />
100 % biobased surfactants<br />
& polyethylene glycols (PEGs)<br />
Clariant (Muttenz, Switzerland) recently unveiled its<br />
new Vita 100 % biobased surfactants and polyethylene<br />
glycols (PEGs) to help directly address climate change<br />
by helping remove fossil carbon from the value chain.<br />
As our climate gives us increasing and alarming signals<br />
of change, individuals and industries are looking for ways to<br />
reduce their environmental footprints, and the demand for<br />
biobased chemicals is set to grow strongly in the coming<br />
years. Clariant is committed to fostering the transition to a<br />
more sustainable bioeconomy and has a growing share of<br />
biobased products and processing aids in its portfolio.<br />
The introduction of 100 % biobased surfactants and PEGs<br />
significantly expands Clariant’s Vita designated ingredients.<br />
Vita products are based on renewable feedstocks and have<br />
at least 98 % Renewable Carbon Index (RCI). It is just one<br />
example of its commitment to provide low carbon footprint<br />
solutions to customers and to Greater Chemistry – between<br />
people and planet.<br />
“From the packaging to the many ingredients, a typical<br />
consumer product in coatings, personal care, home<br />
care, industrial, and agricultural applications still uses<br />
petrochemicals and therefore fossil carbon”, said Christian<br />
Vang, Global Head of Business Unit Industrial & Consumer<br />
Specialties, Clariant. “Switching to biobased carbon<br />
chemistry remains a big challenge for manufacturers and<br />
by launching the Vita surfactant and PEG range we are<br />
offering them an important new solution to achieve this”.<br />
Designed for natural formulations targeting a high<br />
Renewable Carbon Index (RCI), the new Vita products<br />
support manufacturers in maximizing the biobased carbon<br />
content of consumer goods such as detergents, hair and<br />
body shampoo, paint, industrial lubricants, and crop<br />
formulations.<br />
Clariant uses 100 % bioethanol derived from sugar<br />
cane or corn to create ethylene oxide for its innovative<br />
new surfactants and PEGs. The biobased material is fully<br />
segregated along the value chain from the field to the final<br />
consumer product.<br />
Because only biobased feedstocks are used, the<br />
ingredients have significantly lower carbon footprints than<br />
their fossil-based counterparts. The Vita surfactants are<br />
CO 2<br />
emissions savers: they can help save up to 85 % of CO 2<br />
emissions compared to their fossil analogues (based on EO<br />
estimative).<br />
Importantly, in addition to setting the standard in a greener<br />
production, these new solutions are chemically equivalent<br />
to Clariant’s fossil versions, offering the same performance<br />
and efficiency to formulators and brand owners. Customers<br />
can currently benefit from more than 70 biobased products,<br />
and the range will continue to be expanded to meet evolving<br />
market needs. In Q1 2<strong>02</strong>2, double-digit kilotonnes of the<br />
biobased surfactants and PEGs will be available for the<br />
worldwide business segments from Clariant IGL Specialty<br />
Chemicals (CISC), a Clariant joint venture.<br />
As one of the global leaders in specialty chemicals, and<br />
a member of the UN Global Compact, Clariant is at the<br />
forefront of advanced carbon solutions with a unique level<br />
of expertise, know-how and industry knowledge. AT<br />
www.clariant.com<br />
24 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
ioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 25
Materials<br />
Plastics as CO 2<br />
sinks<br />
Building a carbon-negative plastics industry with<br />
low-CO 2<br />
compounds and masterbatches<br />
Plastics can become a permanent CO 2<br />
sink and contribute<br />
to the de-fossilisation of the plastics industry. As a<br />
division of carbonauten GmbH based in Giengen an der<br />
Brenz (Germany), carbonauten polymers has developed the<br />
so-called carbonauten NET Materials ® (Negative Emission<br />
Technology), which consist of a combination of biopolymers<br />
or polymers and CO 2<br />
-negative biocarbons. carbonauten<br />
NET Materials describe a new category of compounds and<br />
masterbatches that are used for a wide range of applications<br />
such as construction, infrastructure, packaging, automotive,<br />
agriculture, engineering, housing, and others. The effect:<br />
the more CO 2<br />
-negative plastics are used, the better for the<br />
environment, people, and the economy.<br />
The aim of carbonauten polymers is to become a global<br />
catalyst for change in reducing the carbon footprint while<br />
creating innovative plastic products with added value.<br />
The business model is based on maximising the material<br />
and energy use of woody (carbonaceous) biomass residues.<br />
These come from agriculture, forestry, and the wood and<br />
food industries. Thus, for companies, cities, municipalities,<br />
and local authorities, their waste becomes a valuable<br />
material and thus an important resource. These biomass<br />
residues are pyrolytically carbonised in an industrial process<br />
at temperatures between 400 °C and 700 °C in the absence<br />
of oxygen. Subsequently, the biocarbons are cooled down to<br />
be anhydrous and, depending on the specification, ground<br />
up in the range of nanometres and micrometres. In further<br />
processes, the polarity of the biocarbons can be influenced.<br />
Depending on the carbon content of the biomass residues<br />
used, each tonne of biocarbon permanently stores between 2.5<br />
tonnes and 3.3 tonnes of CO 2<br />
. This is because the biocarbons<br />
are long-chain and therefore stable even after hundreds<br />
of years. Only through thermal utilisation would the carbon<br />
return to the atmosphere as natural CO 2<br />
that the plants had<br />
From waste to recyclable material: biomass residues are turned into<br />
high-quality and sustainable minus CO 2<br />
plastics<br />
previously absorbed through photosynthesis and used the<br />
carbon fraction for structural building.<br />
Another special feature of the decentralised carbonautenprocess<br />
is that pyrolysis requires only 5 % of the energy<br />
stored in the biomass for carbonisation and 90 % is used as<br />
green electricity for preparation, compounding, and further<br />
processing.<br />
The polymeric carriers for the carbonauten NET Materials<br />
are polypropylene (PP), polyethylene (PE), polycarbonate<br />
(PC), acrylonitrile butadiene styrene (ABS), polyamide (PA6,<br />
PA66, PA12), and others. Thanks to the wide viscosity range<br />
from (MFI) 0.5 g/10 min to 40 g/10 min, the compounds and<br />
masterbatches are suitable for processing from extrusion to<br />
injection moulding.<br />
By using biopolymers such as polylactic acid (PLA) or<br />
polybutylene succinate (PBS) as a carrier material, the<br />
company has also developed innovative compounds and<br />
masterbatches that can be used to produce biodegradable<br />
and compostable plastic products with improved functions.<br />
In agricultural films, such as bio-mulch films, the biocarbon<br />
contained in the carbonauten polymers and carbonauten<br />
masterbatches acts as a soil conditioner and water reservoir<br />
during degradation, contributing to sustainable farming<br />
carbonauten minus CO2 polymers will be used in many industries and<br />
sectors in the future<br />
26 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
By:<br />
Torsten Becker, Dreamer + Innovator<br />
and Cristian Hedesiu, CFO<br />
Carbonauten<br />
Giengen, Germany<br />
Materials<br />
methods, plant growth, and avoidance of agrochemicals (the<br />
popular German TV-Scientist Prof Harald Lesch says: “Super<br />
Fertiliser Terra Preta”).<br />
In addition to reducing the carbon footprint, carbonauten<br />
compounds and masterbatches offer a number of advantages<br />
for the plastic products, such as:<br />
• Improved product performance, e.g. the ratio of stiffness<br />
to impact strength, which can lead to longer durability or<br />
material savings for the same performance<br />
• excellent UV resistance<br />
• improved temperature resistance<br />
• improved dimensional stability CLTE (coefficient of linear<br />
thermal expansion)<br />
• weight reduction in automotive parts compared to talcfilled<br />
compounds<br />
• natural black pigment<br />
• 100 % recyclability<br />
Currently, carbonauten polymers is working with major<br />
brands in the automotive, packaging, and construction<br />
industries on numerous R&D projects to develop tailor-made<br />
minus CO 2<br />
plastic products that meet pressing environmental<br />
and economic demands and needs.<br />
A further and decisive advantage lies in economic efficiency.<br />
This is because the optimised processes mean that the<br />
carbonauten compounds and masterbatches are no more<br />
expensive than petroleum-based plastics. And they replace<br />
between 10 % and 70 % of expensive petroleum-based<br />
polymers.<br />
Due to the future decentralised production sites worldwide,<br />
large quantities will be produced regionally. In the smallest<br />
version, the modular plants produce over 6,000 tonnes of<br />
biocarbons annually. The carbonauten compounds and<br />
masterbatches contain between 10 % and 70 % biocarbon.<br />
From this, an average of 10,000–20,000 tonnes of carbonauten<br />
compounds and masterbatches can be produced.<br />
The carbonauten minus CO 2<br />
factory 1 is located in<br />
Eberswalde (Germany) and will start industrial operation this<br />
June. In the course of the year, the first tonnes of carbonauten<br />
compounds and masterbatches will be delivered.<br />
The next development step is the material use of the biooils<br />
that are produced during the pyrolysis of the biomass<br />
residues. These complex molecules serve as basic chemicals<br />
for the production of biobased polymers. This is old<br />
knowledge rediscovered: Until 1928, Germany was the world<br />
market leader with an annual production of 100,000 tonnes of<br />
pyrolysis oils, until after the Second World War, when cheap<br />
crude oil displaced this sustainable resource.<br />
www.carbonauten.com<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 27
From Science & Research<br />
Self-cleaning bioplastics<br />
The innovative plastic developed at RMIT University<br />
(Melbourne, Australia) repels liquids and dirt – just<br />
like a lotus leaf – then breaks down rapidly once in soil.<br />
RMIT researcher Mehran Ghasemlou, lead author of the study<br />
published in Science of the Total Environment [1] said the new<br />
bioplastic was ideal for fresh food and takeaway packaging.<br />
“Plastic waste is one of our biggest environmental<br />
challenges but the alternatives we develop need to be<br />
both eco-friendly and cost-effective, to have a chance of<br />
widespread use”, Ghasemlou said. “We designed this new<br />
bioplastic with large-scale fabrication in mind, ensuring it was<br />
simple to make and could easily be integrated with industrial<br />
manufacturing processes”.<br />
Ghasemlou said nature was full of ingeniously-designed<br />
structures that could inspire researchers striving to develop<br />
new high-performance and multifunctional materials. “We’ve<br />
replicated the phenomenally water-repellent structure of<br />
lotus leaves to deliver a unique type of bioplastic that precisely<br />
combines both strength and degradability”, he said.<br />
The bioplastic is made from cheap and widely-available<br />
raw materials – starch and cellulose – to keep production<br />
costs low and support rapid biodegradability. The fabrication<br />
process does not require heating or complicated equipment<br />
and would be simple to upscale to a roll-to-roll production<br />
line, Ghasemlou said.<br />
Naturally compostable<br />
While biodegradable plastics are a growing market, not all<br />
bioplastics are equal. Most biodegradable or compostable<br />
plastics require industrial processes and high temperatures<br />
to break them down. The new bioplastic does not need<br />
industrial intervention to biodegrade, with trials showing it<br />
breaks down naturally and quickly in soil. “Our ultimate aim<br />
is to deliver packaging that could be added to your backyard<br />
compost or thrown into a green bin alongside other organic<br />
waste, so that food waste can be composted together with the<br />
container it came in, to help prevent food contamination of<br />
recycling”, said Ghasemlou.<br />
Lotus-inspired structures<br />
Lotus leaves are renowned for having some of the most<br />
water-repellent surfaces on earth and are almost impossible<br />
to get dirty. The secret lies in the leaf’s surface structure,<br />
which is composed of tiny pillars topped with a waxy layer.<br />
Any water that lands on the leaf remains a droplet, simply<br />
rolling off with the help of gravity or wind. The droplets sweep<br />
The lotus effect<br />
up dirt as they slide down, keeping the leaf clean. To make<br />
their lotus-inspired material, the RMIT team of science and<br />
engineering researchers first synthetically engineered a<br />
plastic made of starch and cellulosic nanoparticles. The<br />
surface of this bioplastic was imprinted with a pattern that<br />
mimics the structure of lotus leaves, then coated with a<br />
protective layer of PDMS, a silicon-based organic polymer.<br />
Tests show the bioplastic not only repels liquids and dirt<br />
effectively, but also retains its self-cleaning properties after<br />
being scratched with abrasives and exposed to heat, acid, and<br />
ethanol. Corresponding author, Benu Adhikari, said the design<br />
overcomes key challenges of starch-based materials. “Starch<br />
is one of the most promising and versatile natural polymers,<br />
but it is relatively fragile and highly susceptible to moisture”,<br />
Adhikari said. “Through our bio-inspired engineering that<br />
mimics the ‘lotus effect’, we have delivered a highly-effective<br />
starch-based biodegradable plastic”.<br />
Ghasemlou is currently working with a bioplastic company,<br />
which is evaluating further development of these novel<br />
water repellent materials. The RMIT research team is keen<br />
to collaborate with other potential partners on commercial<br />
applications for the bioplastic.<br />
A study describing the lotus leaf-inspired structure of<br />
the bioplastic was published in ACS Applied Materials and<br />
Interfaces [2]. AT<br />
[1] Ghasemlou et al: Biodegradation of novel bioplastics made of starch,<br />
polyhydroxyurethanes and cellulose nanocrystals in soil environment. https://<br />
doi.org/10.1016/j.scitotenv.2<strong>02</strong>1.152684<br />
[2] Ghasemlou et al: Robust and Eco-Friendly Superhydrophobic Starch<br />
Nanohybrid Materials with Engineered Lotus Leaf Mimetic Multiscale<br />
Hierarchical Structures. https://pubs.acs.org/doi/10.1<strong>02</strong>1/acsami.1c09959<br />
www.rmit.edu.au<br />
Magnified image showing the pillared structure of a lotus leaf<br />
(left) and the new bioplastic (right). Images magnified 2,000 times.<br />
28 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
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bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 29
Masterbatch / Additives<br />
Making the leap into a new era<br />
According to the industry association European<br />
Bioplastics (EUBP), Berlin Germany, global<br />
production capabilities for bioplastics will almost<br />
double in 2<strong>02</strong>2 and are estimated to reach 2 % of global<br />
plastic production by 2<strong>02</strong>6. Both the market and end<br />
consumers are increasingly demanding more sophisticated<br />
material and end applications. As a result, bioplastics<br />
are and will continue to play an important role in the<br />
development of a circular economy and a decisive role in<br />
reaching the Green Deal objectives. That is why bioplastics<br />
are definitely part of the solution.<br />
At Sukano, Schindellegi, Switzerland, it is clear that only<br />
by joining forces along the whole value chain can we achieve<br />
a holistic and impactful change for the environment, society<br />
and, in the end, for each one of us. This is why Sukano<br />
embarked on this journey from the very beginning, over 15<br />
years ago. Initially focusing on PLA, followed by PBS(A) and<br />
finally, in 2<strong>02</strong>1, leading the way into a new era, offering PHA<br />
colour masterbatches.<br />
The concept of PHA foresees two main areas of use.<br />
The first is organic recycling. This includes applications<br />
where it is difficult to separate the polymers from the<br />
organic material, such as coffee capsules or tea bags.<br />
Applications made from PHA can go directly to organic<br />
recycling, increasing organic waste collection and therefore<br />
supporting recycling. Of course, this is presuming that<br />
policy-makers can offer such collection systems and that<br />
recyclers accept such fast-degrading organic materials<br />
in their incoming stream. The second area of use for PHA<br />
as a polymer is in applications where it is challenging or<br />
prohibitively expensive to avoid fragments ending up in the<br />
open environment or to remove them after use, such as<br />
mulch films in agriculture. With PHA, even if there is a leak<br />
to the open environment, there is no risk. This is because<br />
PHA is degradable in soil (according to ASTM D6400, and<br />
anaerobically digestible under ISO 15985 standards), open<br />
water (UV Marine Biodegradable OK Certification), and<br />
home composting conditions, following the certifications<br />
ASTM D6400 and TÜV Home Compost OK Certification.<br />
Sukano has recently launched a dedicated PHA<br />
colour portfolio, which is formulated for direct food<br />
contact applications, available for industrially and home<br />
compostable applications up to soil/marine biodegradable<br />
applications and fully tailored to the properties and<br />
performance requirements of the final application. Of<br />
course, it is up to 100 % biobased with a fully compatible<br />
PHA carrier.<br />
“At Sukano we design colours with a purpose. Everything<br />
we put on the market is designed and tailored according<br />
to specific end-of-lives depending on the end article and<br />
the local market where it will be sold“, states Alessandra<br />
Funcia, Head of Sales and Marketing. ”We want to make<br />
sure that our planet remains as colourful as it is and always<br />
has been”, she adds.<br />
The Sukano PHA colour portfolio is inspired by the planet,<br />
nature, and the people that live on it. The colours, shades,<br />
and effects allow responsible innovation and freedom<br />
in design while ensuring compostability compliance.<br />
All masterbatches are formulated and certified for<br />
compostability.<br />
“For every biopolymer masterbatch, Sukano <strong>issue</strong>s<br />
a so-called compostability letter disclosing all relevant<br />
and critical information according to the compostability<br />
schemes required by the certifying bodies”, Daniel Ganz,<br />
Global Product Manager Bioplastics confirms.<br />
In addition to the PHA colour palette, Sukano offers the<br />
technical background expertise used to formulate these<br />
products to achieve the critical polymer properties and<br />
end applications that PHA stands for. When it comes to<br />
processing PHA, Sukano offers an established three-step<br />
processing guide and provides technical on-site service<br />
whenever needed.<br />
Sukano takes action to be part of the solution. Are you<br />
ready to join them and build back stronger? MT<br />
www.sukano.com<br />
30 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
Let’s all adopt the<br />
right biohaviour now!<br />
It is the slogan of the last digital marketing campaign of<br />
CABAMIX, launched in 2<strong>02</strong>1.<br />
It underlines how Cabamix, a family-owned company<br />
producing bio and recycled mineral compounds in southern<br />
France (Cabannes), is acting concretely towards the urgency<br />
of changing the game for preserving our planet through a<br />
cleaner and more responsible industry (but now!)<br />
It is above all a question of global change in our behaviour:<br />
change in our way of consuming (3R) and in our way of<br />
producing also (3R again), so that we can really adopt the right<br />
Biohaviour. Cabamix’s responsible contribution is tangibly<br />
translated into their range of products Carbomax ® Bio.<br />
Carbomax Bio is a compound based on CaCO 3<br />
, compostable,<br />
biodegradable, partially biobased and certified by TÜV Austria<br />
(OK Compost Industrial, OK Compost Home, OK Compost<br />
Soil). Carbomax Bio is suitable for different materials such<br />
as PBAT, PLA, PBS, PHA, and their compounds, or in starch<br />
based compounds.<br />
Carbomax Bio is successfully used all around the globe<br />
in film extrusion, injection, thermoforming, and 3D printing.<br />
Carbomax Bio gives 3 main advantages: process optimization<br />
(like significantly reduced cycle times in injection), improved<br />
finished product performances and the possibility of reducing<br />
formulation costs.<br />
A recent European study has highlighted the use of<br />
biodegradable mulch film as a perfect solution for a greener<br />
agriculture. This is one of the core applications where<br />
Carbomax Bio is used.<br />
In 3D printing, converters can reach higher productivity and<br />
better look of printed parts thanks to the addition of Carbomax<br />
Bio in PLA filaments.<br />
There are many other applications where Carbomax Bio is<br />
now commonly used like biobags (fruit and vegetable bags,<br />
garbage bags for the selective collection of organics, etc.),<br />
flexible packaging, horticulture, coffee capsules, and many<br />
more. In collaboration with their customers and partners, they<br />
constantly discover new possibilities to introduce Carbomax<br />
Bio in applications where compostability makes sense and is<br />
an added value.<br />
The company will continue to launch new products to<br />
support the needs of their customers and soon they will offer<br />
a 100 % recycled revolutionary solution.<br />
From 2<strong>02</strong>3, Cabamix aims to manufacture 100 % of their<br />
products based on bio-sourced, compostable, or recycled raw<br />
materials. AT<br />
www.carbomaxbio.com<br />
Masterbatch / Additives<br />
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bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 31
Masterbatch / Additives<br />
Breakthrough for<br />
biobased HMDA<br />
Material manufacturer Covestro (Leverkusen, Germany)<br />
and biotechnology pioneer Genomatica (San Diego,<br />
California, USA) announced an important industry<br />
milestone to advance sustainability resulting from their<br />
partnership. The two companies have teamed to be the<br />
first to successfully produce significant volumes of a 100 %<br />
plant-based version of the chemical raw material HMDA<br />
(hexamethylene diamine).<br />
HMDA, with a worldwide market of 2 million tonnes<br />
per year, is a key ingredient for the widely-used nylon-6,6<br />
(with a USD 6.4 billion market), as well as an important<br />
component for raw materials for coatings and adhesives<br />
from Covestro. Up to now, HMDA has been manufactured<br />
from fossil feedstocks. Coatings and adhesives can be<br />
produced more sustainably thanks to biobased HMDA,<br />
made from renewable feedstocks – Genomatica utilizes<br />
plant- or waste-based feedstocks for its sustainable<br />
materials, generally consisting of the sugars from starchy<br />
plants like industrial corn, sugar beets, or cassava. Areas<br />
of application include automotive, construction, furniture,<br />
textiles, and fibres. The automotive industry alone uses<br />
500,000 tonnes of polyurethane coating based on HMDA<br />
annually.<br />
Teams from Genomatica and Covestro have been working<br />
together to develop a commercial process technology for<br />
biobased HMDA. The companies expect to produce tonne<br />
quantities of high-quality material over the course of<br />
multiple production campaigns. Both partners are already<br />
processing and testing material from their initial production<br />
campaigns, and the resulting bio-HMDA is of high purity<br />
and quality. The companies plan to advance the program to<br />
full commercial scale, and Covestro has secured an option<br />
from Genomatica to license the resulting integrated GENO<br />
HMD process technology for commercial production.<br />
Genomatica develops widely-used ingredients and<br />
materials using biotechnology and renewable, plant-based<br />
feedstocks rather than fossil feedstocks and their associated<br />
extractive processing methods. These materials are used<br />
by brands and their suppliers in popular goods ranging<br />
from apparel to cosmetics. Covestro brings extensive<br />
know-how in the field of research, chemical process<br />
technology and application development. The cooperation<br />
for the development of alternative raw materials based<br />
on biotechnology advances Covestro’s global program to<br />
achieve the circular economy.<br />
Covestro established an R&D Competence Center for<br />
biotechnology to further strengthen its overall know-how in<br />
this field. Biobased raw materials and biotechnology have<br />
also been identified as one of five focus areas at Covestro´s<br />
Venture Capital (COVeC) approach.<br />
“The increased use of alternative raw materials, including<br />
the utilization of biotechnology, is an important pillar of<br />
our approach to fully embrace the circular economy and<br />
help make it a global guiding principle”, says Covestro<br />
CEO Markus Steilemann. “Our program with Genomatica,<br />
which complements our internal R&D, is one of our<br />
largest external funding of biotechnology R&D to date, and<br />
underscores both the field’s importance to Covestro and the<br />
results it can deliver”. AT<br />
https://www.covestro.com | www.genomatica.com<br />
32 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
New compostable mineral<br />
fillers & black masterbatches<br />
Committed to sustainable innovation and circular economy<br />
By:<br />
Grégory Coué<br />
Technical Manager<br />
Masterbatch / Additives<br />
Kompuestos<br />
Palau Solità i Plegamans, Spain<br />
Bioexfill: mineral fillers for a lower carbon<br />
footprint<br />
Kompuestos is a Spanish company based in Palau Solità<br />
i Plegamans near Barcelona in Spain. Over the past<br />
three decades, Kompuestos has both acquired an indepth<br />
knowledge of the plastic industry, as well as gained<br />
market recognition. With a production capacity of over<br />
230,000 tonnes per year, Kompuestos has acquired a wealth<br />
of knowledge. Due to its pioneering activities and the quality<br />
and efficiency of its materials, it is today one of the leading<br />
suppliers within the plastic transforming industries, while<br />
still seeking to expand its business horizons. To answer the<br />
demand for greener products, Kompuestos has developed<br />
a whole range of biodegradable and compostable resins<br />
made of starches and other biologically sourced polymers.<br />
Several grades for film and extrusion applications have<br />
already been certified as compostable by TÜV Austria.<br />
A new range of compostable masterbatches<br />
Kompuestos has combined its know-how in masterbatches<br />
with the benefits offered by compostable resins to bring<br />
on a whole new range of eco-friendly masterbatches. The<br />
ingredients of this new range of products are carefully<br />
chosen to meet industrial and legislative requirements.<br />
Several of these grades have been certified by TÜV Austria<br />
as OK Compost INDUSTRIAL and/or OK Compost HOME.<br />
These easy-to-use compostable masterbatches ensure<br />
a dust-free and healthy production, eliminating the health<br />
risk that is involved in using powder additives, especially at<br />
their ultrafine state. Unlike using powder additives, these<br />
concentrates can easily achieve the desired final properties<br />
with complete safety at low addition levels.<br />
Using these concentrates in biodegradable packaging or<br />
other plastic products can help avoid the significant costs<br />
and time required to test products for compostability. These<br />
concentrates are available to improve the performance of a<br />
wide range of compostable resins including, but not limited<br />
to, PLA, PBAT, PBS, thermoplastic starch, and PHA.<br />
Mineral concentrates play a key role in compounding,<br />
as they are used in polymers not only as lower-cost<br />
fillers but increasingly as modifiers to improve properties<br />
such as stiffness, heat deflection temperature, and creep<br />
resistance. The mineral particle size, shape, surface area,<br />
matrix compatibility, and dispersion are all important factors<br />
affecting performance. It is also critical to understand<br />
mineral chemistry to choose the best products for each<br />
polymer.<br />
Bioexfill is a unique combination of 100 % treated and<br />
ultrafine minerals together with compostable polymer<br />
resins. Thanks to its excellent dispersion and homogeneity,<br />
high amounts of Bioexfill can be added to the final article.<br />
Bioexfill reduces costs as well as carbon footprint while<br />
maintaining the mechanical properties of the final article. In<br />
a typical example for blown film extrusion applications, with<br />
the addition of up to 25 wt% Bioexfill, similar mechanical<br />
properties can be achieved compared to the neat resin, both<br />
in machine and transverse directions. Additional benefits<br />
include lower cost, lower carbon footprint, and increased<br />
productivity. On the finished product, Bioexfill can be used<br />
as an opacifier or to colour white while reducing the amount<br />
of titanium dioxide needed.<br />
BK325: black and compostable<br />
The compostable black masterbatch BK325 ensures<br />
an excellent dispersion enabling converters to produce<br />
compostable films & bags, as well as packaging articles<br />
with very high opacity.<br />
Mulch films are used to cover the soil in order to suppress<br />
weeds and to promote crop growth. The compostable black<br />
masterbatch BK325 can be used for mulch films meant<br />
to biodegrade in soil. BK325 has been shown to avoid the<br />
penetration of light through these mulch films to eliminate<br />
the development to weeds under the film. BK325 is also<br />
compatible with the formulation of any compostable plastic<br />
article, for which black colour is desired.<br />
www.kompuestos.com<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 33
Masterbatch / Additives<br />
Unique antistatic ingredient<br />
for bioplastics<br />
There are different types of static charge control<br />
additives for polymers: these are permanent,<br />
internally added, and externally applied, depending<br />
on the level of performance and application. Croda Smart<br />
Materials ((Snaith, UK) offers all three of them.<br />
When antistatic performance is required in synthetic<br />
plastics or bioplastics, such as PLA and its blends, Atmer<br />
190 is a fantastic option. The advantage of Atmer 190 is that<br />
it can be added either directly or via masterbatch during<br />
extrusion or injection moulding, without the need for extra<br />
steps for external application methods, which increase<br />
costs. The recommended dosage is 2–3 %. The surface<br />
resistivity which can be achieved is in the order of 10 10 Ω.<br />
Atmer 190 is an internally incorporated additive that can<br />
be dispersed evenly through the polymer in the melt phase.<br />
It migrates to the surface of the polymer where it interacts<br />
with atmospheric moisture, reducing surface resistivity, and<br />
allowing dissipation of static charge over a long period of<br />
time.<br />
Alternatively, Atmer 190 can be applied externally to the<br />
surface of a polymer giving an immediate but temporary<br />
effect. Atmer 190 has FDA approvals.<br />
Additive Type What are they? How do they work? Why choose this type?<br />
Permanent<br />
Short & medium<br />
term<br />
Externally coated<br />
Internally incorporated,<br />
non-migrating static<br />
dissipative polymers<br />
Internally incorporated low<br />
molecular weight migrating<br />
anti-static additives<br />
Externally applied antistatic<br />
additives<br />
They reduce the resistivity of the<br />
plastic by forming a co-continuous<br />
ion conductive phase within the host<br />
polymer<br />
They are incorporated via a masterbatch<br />
and migrate to the surface after<br />
extrusion where they pick up moisture<br />
They are dissolved in an appropriate<br />
solvent and are then applied by spraying<br />
a wet coating onto the surface, or by<br />
dipping<br />
For applications where permanent and<br />
humidity independent static control is needed.<br />
Applications include EX, EPA and ESA.<br />
For short- or medium-term performance for<br />
example in packaging or where wide ranging<br />
food contact approval is needed<br />
When internal additives can’t be used, where<br />
clarity is affected too much or no internal<br />
additive is available, for example, PET<br />
Atmer TM<br />
Migrating anti-static<br />
additives<br />
Electromagnetic Interference<br />
(EMI) 10 1 - 10 4<br />
Anti-static 10 10 - 10 12<br />
Metals 10 -5 - 10 -1 Conductive 10 1 - 10 6 Static Dissipative 10 6 - 10 12 Plastics ≥ 10 12<br />
Surface resistivity (Ω)<br />
Additionally, Atmer 190 does not have any adverse effect<br />
on the optical properties of PLA or PLA blends. This is<br />
clearly illustrated in the Figure below<br />
By conducting tensile tests using the ASTM D638, Croda<br />
clearly demonstrates in the figures (right page) that Young’s<br />
modulus tensile strength & strain at break are not influenced<br />
by Atmer 190, i.e. the additive does not behave as a plasticizer.<br />
Material Charge decay half-life (s) Surface resistivity<br />
PLA +2 %<br />
Atmer 190<br />
a) b) c) d) e)<br />
PLA +3 %<br />
Atmer 190<br />
a) control cast extruded PLA film, b) PLA+ 2 % Atmer 190, c)<br />
PLA+ 3 % Atmer 190, d) control PLA/PBS/PCL cast extruded film<br />
and e) PLA/PBS/PCL +2 % Atmer 190<br />
More importantly, Atmer 190 does not have any adverse<br />
effect on the mechanical properties of PLA or PLA blends.<br />
PLA/PBT/PCL<br />
(Ω)<br />
Internally incorporated,<br />
non-migrating static<br />
dissipative polymers<br />
They reduce the resistivity of the<br />
plastic by forming a co-continuous<br />
ion conductive phase within the<br />
host polymer<br />
Base PLA (2500HP) > 40 7x10 14<br />
PLA + 2% Atmer 190 3 2x10 11<br />
PLA + 3% Atmer 190 3 3x10 10<br />
PLA/PBT/PCL* > 40 2x10 14<br />
PLA/PBT/PCL* + 2%<br />
Atmer 190<br />
PLA/PBT/PCL<br />
+2 % Atmer 190<br />
1 1x10 11<br />
Charge Decay and Surface Resistivity Change with Concentration level<br />
* PLA/PBS/PCL films supplied by Floreon TM<br />
34 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
Young‘s modulus, E (GPa)<br />
2.5 —<br />
2 —<br />
1.5 —<br />
1 —<br />
0.5 —<br />
0 —<br />
Control 2% Atmer 190<br />
Young‘s modulus, E (GPa)<br />
2.5 —<br />
2 —<br />
1.5 —<br />
1 —<br />
0.5 —<br />
0 —<br />
Control 2% Atmer 190<br />
By<br />
Dimitris Vgenopoulos and Emile Homsi<br />
Croda Smart Materials<br />
Snaith, UK<br />
Masterbacth Automotive Additives<br />
PLA<br />
PLA/PBS/PCL<br />
Young’s modulus, E, of PLA (left) and PLA/PBS/PCL (right); comparison between control vs. 2 % Atmer 190<br />
Tensile strenght, UTS (MPa)<br />
70 —<br />
60 —<br />
50 —<br />
40 —<br />
30 —<br />
20 —<br />
10 —<br />
0 —<br />
Control 2% Atmer 190<br />
PLA<br />
Tensile strenght, UTS (MPa)<br />
60 —<br />
50 —<br />
40 —<br />
30 —<br />
20 —<br />
10 —<br />
0 —<br />
Control 2% Atmer 190<br />
PLA/PBS/PCL<br />
Tensile strength, UTS, of PLA (left) and PLA/PBS/PCL (right); comparison between control vs. 2 % Atmer 190<br />
250 —<br />
500 —<br />
Strain at break, ε (%)<br />
200 —<br />
150 —<br />
100 —<br />
50 —<br />
Strain at break, ε (%)<br />
400 —<br />
300 —<br />
200 —<br />
100 —<br />
0 —<br />
Control 2% Atmer 190<br />
0 —<br />
Control 2% Atmer 190<br />
PLA<br />
PLA/PBS/PCL<br />
Strain at break, ε, of PLA (left) and PLA/PBS/PCL (right); comparison between control vs. 2 % Atmer 190<br />
Summary<br />
Atmer 190 is an ideal antistatic additive for PLA & PLA blends because it combines the following benefits:<br />
• Good antistatic performance with a surface resistivity of 10 10<br />
• Internally added either via direct addition or via MB<br />
• No adverse effect on optical properties<br />
• No adverse effect on mechanical properties<br />
www.croda.com<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 35
Masterbacth / Additives<br />
Masterbatches with<br />
soil improving pigments<br />
Colouring plastics is a standard procedure throughout<br />
the industry, but what if instead of simply getting the<br />
desired colour of an application a colour masterbatch<br />
could have an added value on its own?<br />
CAPROWAX P (Frankfurt am Main, Germany) recently<br />
developed a new line of masterbatches for universal<br />
colouration aimed at biodegradable plastics that does<br />
just that. Next to colouring they have the added value of<br />
containing soil-improving pigments. The soil-improving<br />
properties fall in general into two categories: pigments that<br />
improve the water retention capacity of soil, and pigments<br />
that have acid-binding capacity and are soil similar.<br />
Water retention capacity is the ability for soil to hold<br />
water and is, therefore an important factor for agricultural<br />
purposes, it reduces the need for irrigation as well as the<br />
risk of drought or desert desertification. Pigments that<br />
increase water retention capacity are vegetable carbon or<br />
lava rock flour from the Volcanic Eifel.<br />
Acid-binding capacity can help to reduce acidity levels of<br />
soil. Acidic soils are less productive as they contain fewer<br />
nutrients important for plant growth, high acidity levels also<br />
hinder root growth and many plants have difficulty growing<br />
in soil with high acidity levels.<br />
Soil similar pigments with acid-binding properties include<br />
biomineral natural calcite, calcined Kaolin (a brightening<br />
pigment without the addition of titanium dioxide.<br />
The carrier material Caprowax P is compostable and<br />
waterproof, and complies with the specification of DIN<br />
EN 13432. Caprowax P masterbatches are suitable for<br />
universal colouration of bioplastics, blends, biocomposites,<br />
and filaments including: PLA, PBS, PHA, PCL, Caprowax P/<br />
Blends / BioMineralComposites, Polysaccharide/Derivates,<br />
PVAc/Bioplastic-Blends, PVOH, Bio-NFC/WPC, Bio-UPR,<br />
Bio-TPE, and NIPU.<br />
The masterbatches can be used translucent, covering,<br />
chromatic/achromatic and pearlescent colouration.<br />
They are lightfast, non-migratory, temperature stable,<br />
insoluble in water, comparable with natural, mineral<br />
pigments, and already mineralised. Masterbatch pellets are<br />
added to different bioplastics in a range of 0,5–6 %. They<br />
have a processing range of 90–200 °C, and for a short time<br />
up 220 °C. The content of each separate pigment in the<br />
coloured final products is ≤1 %.<br />
In the course of composting the brown to black colour of<br />
compost or humus change over to the coloured bioplastic<br />
and the colourful appearance disappears. Colourations with<br />
natural, biomineral calcite support biogenic weathering in<br />
soil and waters.<br />
After the biological degradation of the coloured biopolymer,<br />
the used pigments are able to regenerate acidic soil, improve<br />
plant fertilization, and increase water retention capacity. AT<br />
www.caprowax-p.eu<br />
Examples of masterbatches for soil improvement QX<br />
CAPROWAX P TM Shade Description<br />
Lava Red 134 QX LP lava rock flour, Volcanic Eifel / iron oxide red<br />
Yellow 314 BM QX LP natural calcite / iron oxide yellow<br />
White C 004 BM QX<br />
natural Calcite<br />
Green 444 BM QX LP natural Calcite / iron oxide yellow / ultramarin blue<br />
Blue G 545 BM QX LP natural calcite / ultramarin blue<br />
Violet B 636 BM QX LP natural calcite / mangan violet, bluish<br />
Lava Brown 715 QX LP lava rock flour Volcanic Eifel / iron oxides red / black<br />
Lava Brown 717 QX LP lava rock flour Volcanic Eifel / iron oxides red / black<br />
Lava-Grey FK 833 QX LP lava rock flour Volc. Eifel / iron oxide black / kaolin calcined<br />
Grey 821 BM wcb QX<br />
natural calcite / iron oxide black<br />
Grey FK V 827 bb QX LP kaolin calcined / vegetable carbon<br />
Black V 804 bb QX<br />
vegetable carbon<br />
Lava-Black 806 QX LP lava rock flour Volcanic Eifel / iron oxide black<br />
V: vegetable carbon, bb: biobased , wcb: without carbon black , LP: laboratory prototype<br />
QX: biobased carbon black and lava rock flour from Volcanic Eifel are soil improver with water retention capacity<br />
BM: biomineral, natural calcite, acid-binding, FK: calcined kaolin, compost friendly<br />
36 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
Within its work on the European<br />
Nenu2phar project, Elixance (Elven,<br />
France), a company specialized in the<br />
elaboration and production of masterbatches<br />
and compounds, has developed a compostable<br />
3D printing filament based on PHA. The R&D<br />
department formulated two types of filaments<br />
to cover a large field of applications: a rigid<br />
filament, and a more flexible one. The objective<br />
was to develop a fully biodegradable filament<br />
without losing the performance of a petroleumbased<br />
plastic like, e.g. TPE, ABS.<br />
The company already has a large range of green<br />
products under its brand Elixbio and acquired<br />
a strong knowledge in the use of naturals<br />
fillers blend with biopolymers. By applying<br />
this knowledge to the 3D printing area with its<br />
partner Nanovia (Louargat, France), they made<br />
printable formulations based on biodegradable<br />
raw materials. These formulations include<br />
PHA, a compostable polymer that comes from<br />
renewable resources, and natural fillers, such as<br />
hemp or oyster powder.<br />
In the exploration of their mechanical<br />
performance, the formulations were extruded<br />
and printed into test bars for mechanical<br />
characterization. These properties were<br />
compared to properties of non-compostable<br />
3D filaments. The formulations with the most<br />
interesting performances were then used to print<br />
different complex geometry parts.<br />
The rigid filament is a blend of PHB, PHBV,<br />
and incorporated hemp fibres and achieves<br />
mechanical properties close to a filament made<br />
of PLA: high tensile modulus and good impact<br />
resistance. The flexible filament is a blend of PHB<br />
and PBAT with oyster powder, with a low tensile<br />
modulus and a high elongation at break (around<br />
300 % according to ISO 527-1). These properties<br />
are similar to those of TPE.<br />
For several years, Elixance has been developing<br />
bioplastics with a circular economy philosophy,<br />
using natural fillers and fibres (oyster and scallop<br />
shells, flax, hemp, etc.) from local resources. By<br />
working with natural fillers, they find a way to<br />
convert by-products into valuable materials and<br />
to naturally colourize the filaments, even though<br />
these compostable filaments could be colourized<br />
with vegetable or mineral pigments.<br />
These new home-compostable filaments open<br />
up the field of external applications for 3D printer<br />
owners with a sustainable management of the<br />
end-of-life.<br />
The NENU2PHAR project has received funding<br />
from the Bio-Based Industries Joint Undertaking<br />
(BBI-JU) under grant agreement No 887474. The<br />
JU receives support from the European Union’s<br />
Horizon 2<strong>02</strong>0 research and innovation programme<br />
and the Bio-Based Industries Consortium. AT<br />
https://www.elixbio.com/<br />
https://nenu2phar.eu/<br />
Home<br />
compostable<br />
3D printing<br />
filament<br />
Applications<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 37
Application News<br />
Ballpoint pens<br />
Mitsubishi Chemical Corpora- tion (Tokyo,<br />
Japan) recently announced that their<br />
biobased engineering plas- tic DURABIO<br />
has been adopted as the main body part<br />
(rear shaft) of Pilot Corporation’s (Tokyo,<br />
Japan) ballpoint<br />
pen Acroball T Series<br />
Biomass Plastic and FRIXION Ball Knock<br />
05 Biomass Plastic. These products<br />
have been of- fered for sale by Pilot since 3<br />
February<br />
2<strong>02</strong>2 (These products are currently<br />
only available for novelty items).<br />
Durabio is a biobased engineering plastic<br />
made from the renewable plant-derived<br />
raw material isosorbide, a highly durable<br />
material. In addition, the plastic can be applied<br />
to various design parts because it has excellent colour<br />
development during colouring and mouldability during<br />
processing. These excellent characteristics have been<br />
highly evaluated, which has led to its adoption. This is the<br />
first case for using Durabio in a stationery application. AT<br />
wwwmitsubishi-chemical.com<br />
www.pilot.co.jp<br />
Carbon negative<br />
composites<br />
Mitsubishi Chemical Holdings Corporation (MCHC,<br />
Chiyoda-ku, Tokyo) announced in February that Diamond<br />
Edge Ventures, Inc. (DEV, a wholly-owned subsidiary of<br />
MCHC”) has invested in Lingrove, Inc. (San Francisco,<br />
California, USA).<br />
Lingrove – whose high-performance, carbon-negative<br />
composite technology can replace wood, high-pressure<br />
laminates, and plastics with its less expensive, cleanchemistry<br />
product Ekoa ® – has secured its Series A<br />
funding with lead investor Diamond Edge Ventures<br />
(DEV).<br />
Ekoa, developed from plant fiber, delivers a higher<br />
strength-to-weight ratio than steel. Ekoa is already<br />
being used to replace mainstream materials such as<br />
wood in musical instruments and designer furniture.<br />
Upcoming uses in late-stage testing include instrument<br />
consoles in electric vehicles, kitchen & bath products,<br />
and acoustic panels. Ekoa, with its extreme<br />
endurance, moldability, and<br />
general<br />
performance,<br />
provides a<br />
sustainable<br />
alternative to<br />
other composites<br />
and incumbent<br />
materials, with a<br />
luxurious and natural<br />
aesthetic.MT<br />
www.mitsubishichem-hd.co.jp/english<br />
www.diamondedgeventures.com<br />
https://lingrove.com<br />
Beauty joins<br />
PEFerence consortium<br />
Avantium (Amsterdam, The Netherlands), a leading<br />
technology company in renewable chemistry, announces<br />
that world luxury goods leader LVMH Group (Moët Hennessy<br />
Louis Vuitton – Paris, France) and Avantium have agreed<br />
to further explore the potential of Avantium’s 100 % plantbased,<br />
recyclable polymer PEF (polyethylene furanoate),<br />
as a sustainable packaging solution for LVMH beauty<br />
brands. To this end, LVMH Beauty will be the first luxury<br />
cosmetic company to join the PEFerence consortium,<br />
further enabling the commercial introduction of PEF to the<br />
Cosmetics market.<br />
The PEFerence consortium, coordinated by Avantium,<br />
aims to replace a significant share of fossil-based<br />
polyesters with the novel, sustainable polymer PEF. PEF<br />
is a plant-based, highly recyclable plastic, with superior<br />
performance properties compared to today’s widely<br />
used petroleum-based packaging materials. Joining the<br />
PEFerence consortium supports the ambitions of LVMH<br />
Group’s social and environmental strategy LIFE 360 (LVMH<br />
Initiative for the Environment), and the company’s target of<br />
zero plastic from virgin fossil feedstock.<br />
“LVMH Beauty is always looking for sustainable materials<br />
with superior performance for our luxury products as part of<br />
our sustainability strategy,” says Claude Martinez Executive<br />
President and Managing Director, Beauty Division of LVMH<br />
Group. “The environmental and performance features of<br />
PEF are unique and very promising to meet our sustainable<br />
packaging goals, which is why LVMH Beauty decided to<br />
join the PEFerence consortium. Together, with the other<br />
PEFerence consortium partners, we aim to shape this<br />
next-generation, fully circular and sustainable packaging<br />
material”.<br />
Avantium CEO Tom van Aken comments: “We are pleased<br />
with the decision of LVMH to join the PEFerence consortium,<br />
demonstrating the importance of our mutual work to develop<br />
packaging solutions for a circular and sustainable future. We<br />
look forward to continuing and expanding our collaboration<br />
with LVMH Beauty for many years to come”. AT<br />
www.lvmh.com | www.avantium.com<br />
38 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
Biomaterial pendant<br />
Visitors walking into New Zealand’s Expo Restaurant Tiaki in Dubai (United Arab Emirates) will be in awe of the David<br />
Trubridge pendant lights suspended above their heads – one of those being made from a shimmering biomaterial formulation<br />
developed by Crown research institute Scion (Rotorua, New Zealand).<br />
Showcasing New Zealand’s innovative and sustainable spirit, the Navicula pendant light features a composite of sustainable<br />
biobased plastics and native pāua shells developed by Scion scientists with a beautiful iridescent sparkle.<br />
The Navicula design is inspired by microscopic diatoms which live in water and produce 50 % of the oxygen in the air we<br />
breathe. Designer David Trubridge is a recognised leader in sustainable design for his high-end lighting that is produced with<br />
minimal environmental impact.<br />
“Scion havs been experimenting with New Zealand materials to make biomaterial colour. They’ve used kiwifruit to make<br />
green, harakeke (flax) to make brown, the pāua added more of a glitter effect”, Trubridge said.<br />
“I love the pāua navicula pendant light they developed because it’s different – the light shines through, the colour works well.<br />
The whole way along we said it’s important to get a texture, as we didn’t want it to<br />
have a glossy shine that made it look like plastic. Scion achieved a rough texture which is<br />
important – it works really well, it’s quite different to our plywood lights and I like that”.<br />
Scion’s biomaterials technology platform takes biomass fillers, such as sander dust,<br />
kiwifruit hair and skin, seashells, grape marc, harakeke, bark, or casein and combines<br />
them with biobased polymers. Compounding the filler with the polymer creates a<br />
biocomposite which is then extruded or reshaped into a new form that can be used.<br />
“As kaitiaki (guardians), New Zealanders believe we have a responsibility to leave<br />
the world in a better place for future generations – and we can see this in the shared<br />
sustainability ethos of the design companies”, said Scion Materials, Engineering<br />
and Manufacturing Research Group Leader Marie Joo Le<br />
Guen.<br />
Trubridge adds, “it’s wonderful to be part of New<br />
Zealand’s creative community on exhibit in Dubai – to be<br />
there telling the story of our land and our people”. MT<br />
youtu.be/6h8yD98dZP8<br />
Photo: Stephen Parker<br />
www.scionresearch.com | https://davidtrubridge.com/nz<br />
Application News<br />
Wakeboards from bio-epoxy<br />
Sicomin Epoxy Systems (Châteauneuf-les-Martigues, France), the leading formulator of high-performance epoxy resin<br />
systems and the market-leading GreenPoxy bio-resin range, announces its new collaboration with sports equipment giant<br />
Decathlon (Villeneuve-d’Ascq, France).<br />
Sicomin will supply its GreenPoxy 33 resin to produce Decathlon’s new JIB and BLOCK wakeboards that will be manufactured<br />
at Meditec, the specialist composite board manufacturer based in Tunisia (Mornaguia).<br />
With a desire to produce products that are as sustainable as possible, GreenPoxy 33 resins will contribute to Decathlon’s<br />
environmental mission, deriving 28 % of its carbon content from plant sources, whilst also providing high mechanical properties<br />
and exceptional clarity in the finished laminates. Formulated with rapid processing in mind, GreenPoxy 33 has been seamlessly<br />
integrated into Meditec’s manufacturing process, allowing it to match Decathlon’s production demand and keep cure cycles as<br />
short as 10 minutes at 100˚C.<br />
Meditec combines GreenPoxy 33 with Forest Stewardship<br />
Council ® (FSC) accredited wood cores, further increasing<br />
the percentage of responsibly sourced materials in the new<br />
Jib and Block boards. Both models have been designed for<br />
intermediate wakeboarders looking for a rigid yet flexible<br />
board to be used at cable parks or when towed. The Block<br />
model also features a unidirectional carbon strip on the lower<br />
part to further increase its pop on the water.<br />
Decathlon closely monitors all factors that contribute to the<br />
ecological impact of its products, including the supply chains<br />
and transport miles incurred by both raw materials and<br />
finished products. Sicomin’s manufacturing site in Southern<br />
France combined with Meditec’s location close to Europe near<br />
Tunis also provides a reliable and low mileage supply chain<br />
that avoids extended shipping from East Asia. AT<br />
www.sicomin.com | www.decathlon.com |<br />
www.meditec-sports.com<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 39
Application News<br />
Casio’s new PRO TREK with biomass plastics<br />
The new PRW-61 is the first Casio watch to be made with<br />
biomass plastics sourced from renewable organic substances.<br />
Casio Computer (Tokyo, Japan) recently<br />
announced the latest addition to the PRO<br />
TREK line of outdoor watches. Produced<br />
from regenerable resources, biomass<br />
plastics are attracting attention as a material<br />
that can help reduce environmental impact<br />
by curbing CO 2<br />
emissions.<br />
For the first time in any Casio watch, the<br />
PRW-61 uses biomass plastics in the case,<br />
band, and case back. The environmentally<br />
friendly biomass plastics are produced using<br />
materials derived from castor seeds and<br />
corn, as well as other raw materials. Casio is<br />
proud of this new material application for its line of outdoor<br />
tools, Pro Trek, for nature lovers.<br />
Delivering on outdoor utility, the model is equipped with<br />
Triple Sensor (digital compass, barometer/altimeter, and<br />
thermometer), as well as Multi-Band 6 radio wave reception<br />
from 6 transmission stations around the world, and Tough<br />
Solar to provide stable power for these<br />
functions and more. For optimum readability,<br />
the design features thick bar indexes to<br />
check time, direction, and other indicators at<br />
a glance, as well as slits on the band above<br />
and below the dial that serve as guides to<br />
quickly read the compass direction indicated<br />
by the second hand.<br />
As part of its focus on the Sustainable<br />
Development Goals, Casio is pursuing<br />
a number of environmentally friendly<br />
initiatives, including a shift from plastic to<br />
recycled paper in packaging for the PRW-<br />
61. Moving forward, Casio will also contribute to efforts to<br />
build a circular economy by expanding its use of sustainable<br />
materials in the design of other watch models, as well. AT<br />
https://world.casio.com<br />
Cellulose-based heat-sealed sandwich bags<br />
St1’s HelmiSimpukka (Helsinki, Finland), in collaboration with Woodly (Helsinki, Finland) and Amerplast (Tampere, Finland),<br />
launches the Woodly heat-sealed take-away bag.<br />
The heat-sealed bag is 100 % carbon-neutral and recyclable wood-based packaging material. Consumers will recognize the<br />
new packaging from the Woodly logo and the sandwiches can be found in all St1 HelmiSimpukka outlets in Finland.<br />
Recognized as one of the biggest companies in Finland, St1 and their HelmiSimpukka outlets are known for comprehensive<br />
services and delicious foods. With the new environmentally friendly packaging solution, St1 aims to reduce food waste, increase<br />
consumer recycling, and improve the quality and shelf life of products.<br />
“Sandwiches packaged in the Woodly heat-sealed take-away bags retain freshness even longer than those packaged in<br />
a traditional plastic bag, which supports our goal of reducing food waste. In addition, the Woodly heat-sealed bag is made<br />
of renewable material and is suitable for recycling, which is in line with our responsibility thinking”, says Emil Huttunen,<br />
Marketing and Concept Manager of the HelmiSimpukka chain.<br />
The Woodly heat-sealed bags are manufactured by Amerplast, a company with extensive experience in manufacturing flexible<br />
packaging and strong expertise in food industry<br />
requirements and packaging materials.<br />
For Woodly, the collaboration with St1 and<br />
Amerplast can lead to extraordinary results with<br />
hopes of many more to follow suit in packaging<br />
products more environmentally friendly. “The<br />
development of the bag solution together with<br />
the HelmiSimpukka restaurant chain and bag<br />
manufacturer Amerplast has been exciting and<br />
inspiring. We see a lot of new opportunities here to<br />
expand similar Woodly heat-sealed take away bag<br />
solutions to other product categories as well”, says<br />
Jaakko Kaminen, CEO of Woodly Oy. AT<br />
www.woodly.com<br />
40 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
Renewable, aesthetically pleasing, and reusable<br />
Sensibly sustainable packaging is becoming increasingly important for high-priced products such as cosmetics. In the past, it was<br />
enough to simply have a beautiful design, now aesthetics need to be combined with sustainability and functionality. If you want to be a<br />
packaging trailblazer in the luxury segment, you cannot afford to make any compromises when it comes to sustainability. Half-baked<br />
ideas that are not properly thought through and only do lip service to the goals of the circular economy don’t give any added value in the<br />
best of cases and are plain greenwashing in the worst.<br />
If you are planning on becoming a pioneer with your sustainable packaging, you should first turn to experienced specialists in the<br />
bioplastics industry. Product requirements, material pairings, and design must be perfectly coordinated.<br />
NaKu (Vienna, Austria) is such a specialist. In close cooperation with freemee cosmetics (Scharnstein, Austria) they created a reusable<br />
packaging made of wood and glass containing a replaceable cartridge made of bioplastic, which optimally protects biocosmetics and<br />
can be emptied completely. As the ideals of the circular economy stand front and centre, only materials such as glass, sustainably grown<br />
wood, and renewable and compostable plastics were allowed to be used.<br />
The luxury segment has particularly high requirements for simple and reliable usability. The product design does not only require the<br />
end product to be aesthetically appealing, all individual parts must be ideally matched to each other so that everything is properly sealed<br />
while being easy to use at the same time. This is a particularly difficult challenge with bioplastics, many are still new and experience in<br />
their use are scarce, thus less data for design and simulations are available. A lot has to be considered, tried, and tested.<br />
What is already a challenge with conventional plastic can be a “make or break” scenario for projects<br />
utilizing bioplastics. Anyone who succeeds in combining reusable, compostable, and renewable<br />
materials takes on a clear pioneering role in sustainable packaging.<br />
Currently, many recycling and collection systems are not yet prepared for the newly emerging<br />
circular economy, yet NaKu doesn’t want to wait for these systems to be in place. This is why the<br />
refillable cartridges are both industrially compostable and chemically recyclable.<br />
NaKu invites both cosmetic brand owners who are interested in this packaging for their cream<br />
products, as well as companies who need similar packaging for their products in the future. AT<br />
www.naku.at/naku-freemee-cosmetics<br />
Application News<br />
10-12 May – Cologne, Germany<br />
renewable-materials.eu<br />
The stars of Renewable Materials meet in Cologne<br />
The unique concept of presenting all renewable material solutions at one event<br />
hits the mark: bio-based, CO2-based and recycled are the only alternatives to<br />
fossil-based chemicals and materials. Preliminary program available.<br />
First day<br />
• Bio- and CO2-based<br />
Refineries<br />
• Chemical Industry,<br />
New Refinery Concepts<br />
• Chemical Recycling<br />
Second day<br />
• Renewable Chemicals<br />
and Building Blocks<br />
• Renewable Polymers and<br />
Plastics – Technology<br />
and Markets<br />
• Fine Chemicals (parallel session)<br />
• Innovation Award<br />
Third day<br />
• Latest nova Research<br />
• The Policy & Brands View<br />
on Renewable Materials<br />
• Biodegradation<br />
• Renewable Plastics and<br />
Composites<br />
ORGANISED BY<br />
NOVA-INSTITUTE<br />
RENEWABLE<br />
MATERIAL<br />
OF THE<br />
YEAR 2<strong>02</strong>2<br />
1<br />
INNOVATION AWARD<br />
Call for Innovation<br />
Vote for the Innovation<br />
Award “Renewable<br />
Material of the Year 2<strong>02</strong>2”<br />
Organiser<br />
Premium<br />
Partner<br />
Innovation Award<br />
Sponsor<br />
Sponsors<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 41
On-Site<br />
Tecnaro<br />
W<br />
e are sure that many of our readers know<br />
TECNARO or have at least heard about the<br />
company from Isfeld, Germany. Who does not<br />
know the term ‘liquid wood’? Who has never<br />
seen the picture of the famous loudspeaker<br />
housing?<br />
However, we wanted to know<br />
more about the roots, the current<br />
status, and the future prospects<br />
of the innovative company<br />
that develops and produces<br />
its own bioplastics and<br />
biocomposites based on<br />
renewable raw materials<br />
and markets them<br />
worldwide. That’s<br />
why we visited<br />
Tecnaro in mid-<br />
February.<br />
Gucci high heel<br />
It all started back<br />
in 1998 when Helmut<br />
Nägele and Jürgen Pfitzer founded Tecnaro<br />
as a spin-off of the Fraunhofer Gesellschaft. Well, actually<br />
it started a little earlier…<br />
In 1996 the Technical Business Economist Jürgen Pfitzer<br />
and Chemical Engineer Helmut Nägele met for the first<br />
time at the Fraunhofer Institute for Chemical Technology<br />
(ICT), Pfinztal, Germany, by now the largest Institute of the<br />
Fraunhofer Society. Initially, Helmut Nägele wanted to PhDresearch<br />
online measurement of polymer melts. But then<br />
the newly upcoming topic of polymers based on renewable<br />
resources fascinated him much more, so he changed his<br />
mind. Initiated by the Climate Conference in Rio de Janeiro<br />
1992, Pfitzer and Nägele started discussing ways to reduce<br />
CO 2<br />
. “Not so many in the broad public in those days thought<br />
that carbon dioxide would become a topic as significant as<br />
it is today”, Nägele commented.<br />
The development of<br />
the Aquasolv paper<br />
pulping process at<br />
the ICT opened the<br />
door for Pfitzer<br />
and Nägele’s<br />
activities. The<br />
Aquasolv process<br />
uses heat and<br />
water (steam) to<br />
obtain cellulose<br />
fibres from wood,<br />
with lignin as a<br />
by-product. A patent<br />
search didn’t show any<br />
significant results. So, the<br />
Binabo by Tic Toys<br />
two sat down in Pfitzer’s backyard<br />
over beer and barbeque and wrote down some<br />
20 patent drafts. This was then followed by lots of<br />
experiments. Systematically the two researched and<br />
developed the conversion of lignin into a product family that<br />
would later become known as Arboform ® or liquid wood.<br />
The lignin content can be from 30 up to 70 %.<br />
Until then, and still today in many<br />
cases, the by-product lignin is just<br />
burnt to exploit the energy. “And<br />
we do not take away the lignin<br />
from the energetic use”, as<br />
Jürgen Pfitzer emphasised,<br />
“we add just one more<br />
value-added step. At the<br />
very end of its lifetime,<br />
after reuse and recycling,<br />
the lignin-based plastic can<br />
still be incinerated, and the<br />
energy used”.<br />
So, the much-used saying<br />
among representatives of the<br />
pulp and paper industries “One<br />
can make anything from lignin<br />
except money” proved not to be<br />
true for Pfitzer and Nägele.<br />
Urn made of Arboform<br />
This was the basement for the foundation of Tecnaro<br />
GmbH, the name abbreviating the German words for<br />
Technology Renewable Resources. It was the declared<br />
philosophy of the Fraunhofer Society to allow inventors to<br />
exploit their inventions themselves, as so many inventions<br />
in the Society ended up unused. This allowed for a very<br />
smooth spin-off. In 1998 the two started their own business<br />
without any venture capital and left the Fraunhofer Institute<br />
another two years later.<br />
After the first few years as a young start-up company, the<br />
head office was moved from Pfinztal in Baden-Württemberg<br />
to the government-funded start-up and innovation centre of<br />
Eisenach/Stedtfeld in Thuringia (one of the then so-called<br />
New Federal States) in May 2000.<br />
As a result of constantly growing<br />
demand, particularly in southern<br />
Germany, Tecnaro returned from<br />
Thuringia to Baden-Württemberg<br />
in August 2006 and moved into<br />
larger premises for production<br />
as well as research and<br />
development at the Ilsfeld-<br />
Auenstein location.<br />
The first product Arboform<br />
provides very good dampening<br />
properties and proved to<br />
be a very good material for<br />
acoustic applications, such as<br />
loudspeaker housings, but also<br />
musical instruments like bass guitars,<br />
recorders (flutes). But also for other Loudspeaker housing<br />
applications where you want a high level<br />
of design freedom for wooden products Arboform is the<br />
42 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
By: Michael Thielen<br />
On-site<br />
ideal material. This also includes automotive interior<br />
parts, where real wood veneer can be back-injected with<br />
Arboform, allowing the production of rigid “all-wood” parts<br />
in almost any design.<br />
An interesting application from the early days is a<br />
biodegradable urn. “In many so-called Friedwälder<br />
(cemetery forests) all over Europe and beyond the Tecnaro<br />
urns are the only allowed products”, Jürgen Pfitzer<br />
explained.<br />
Over the years the product family of Arboform (injection<br />
mouldable lignin-based bioplastics Liquid Wood) which are<br />
100 % biobased and biodegradable has been extended with<br />
further products for many different applications.<br />
Combined with other ingredients, such as PLA, PHA,<br />
waxes, minerals, and many more, the product family of<br />
Arboblend ® was created and the addition of fibres and<br />
fillers led to the Arbofill ® products.<br />
Today the material database of Tecnaro comprises<br />
about 6,000 recipes for tailormade resins for a plethora of<br />
applications “from fibres and yarns through to thick-walled<br />
parts”, as Pfitzer pointed out. From hard to soft (TPE)<br />
almost anything can be realised. 40-50 different grades are<br />
always on stock for immediate delivery.<br />
One example is the Eco Pump of Sergio Rossi (Gucci).<br />
Here the heels are made of Arboform the inner sole made<br />
of a soft Arboblend and the outer sole of a rigid type.<br />
Since 2005 Tecnaro is also a supplier to the automotive<br />
industry. “It started with a really spectacular product”,<br />
Pfitzer proudly said. “It is a lost core for high-performance<br />
carbon-ceramic brakes of cars like Porsche, Bentley,<br />
Lamborghini, Formula-1 cars, and others.” And Helmut<br />
Nägele added: “Due to the complex shape and very narrow<br />
tolerances the manufacture of these lost cores, that were<br />
initially made of machined plywood was very costly”.<br />
Injection moulding with Arboform showed significant<br />
advantages and outperformed high-performance plastics<br />
tin-bismuth alloys while simultaneously being a lot cheaper.<br />
The biobased origin and biodegradability were certainly of<br />
lesser importance. For the automotive industry once again,<br />
performance and cost are the key factors.<br />
Other remarkable applications areas include homecompostable<br />
organic coffee capsules, growth covers<br />
biodegradable under forest conditions for microplastic-free<br />
reforestation, a complete biobased range of household goods<br />
ranges, and many more. The company delivers resins to all<br />
market areas, including household, medical applications,<br />
consumer electronics, textile, toys, and many more. “All<br />
except aerospace”, as Nägele pointed out. Tecnaro grades<br />
can be processed in injection moulding, blow moulding,<br />
thermoforming, film blowing, and 3D printing.<br />
Today, Tecnaro is a company with 40 employees working<br />
in 3 shifts 24/7 compounding on four production lines about<br />
16,000 tonnes of material annually. The offive, production<br />
and storage area was recently doubled to 5,000 m 2 .<br />
To the last question, as in many of our interviews: “What<br />
are you particularly proud of?” Helmut Nägele said: “We<br />
started in 1996 and wanted to contribute our share to<br />
make the world a better place. And we are still there. With<br />
the same management, the same shareholder structure<br />
without any venture capital we are a successful player and<br />
have so many ideas for the future”. Jürgen Pitzer added,<br />
“and in times where everyone suffers from supply chain<br />
<strong>issue</strong>s we can proudly say ‘we can deliver’”.<br />
www.tecnaro.de<br />
From left: Helmut Nägele, Alex and Michael<br />
Thielen, Jürgen Pfitzer<br />
Jürgen Pfitzer explains the compounding line<br />
Alex Thielen is fascinated of the carbon-ceramic<br />
brake application<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 43
Opinion<br />
About reducing the fossil fuel<br />
addiction via compostables<br />
From a historical perspective, it is quite remarkable to<br />
see how geopolitical events can have an unexpected<br />
influence on the way we deal with our materials.<br />
During the American civil war, around the 1860s, a company<br />
in billiard supplies, called Phelan and Collender, faced a<br />
serious shortage in their supply of ivory as a direct result<br />
of the war. The company offered a USD 10,000 award for<br />
anyone who could offer an alternative material for making<br />
billiard balls. It led to the development of a cellulose-based<br />
material called Parkesine, which is often seen as the<br />
world’s first (semi)synthetic material that was ever made.<br />
Wallace Carothers – a Harvard professor in organic<br />
chemistry – only joined Dupont after significant pressure,<br />
to then further investigate the concept of macromolecules<br />
in 1928, which was formulated by Staudinger in 1920.<br />
Carothers patented numerous materials like Nylon<br />
(polyamide), various polyesters (incl. PLA), and Neoprene<br />
(synthetic rubber). When the United States got involved in<br />
WW2 in 1941 there was an urgent demand for lightweight<br />
materials in planes. As Japan had occupied the countries<br />
holding natural rubber plantations, it was good to have<br />
synthetic alternatives available. Nylon – promoted originally<br />
as artificial silk for lady’s stockings – came in handy as an<br />
alternative for regular silk for parachutes, as Japan was<br />
also in control of the global silk market.<br />
In 1973 the Yom Kippur war led to an oil and energy crisis<br />
in various western countries, when Arab countries decided<br />
to cut supplies to countries, who had chosen to side with<br />
Israel in this conflict. It is unlikely to be a coincidence that the<br />
first materials where starch was combined with synthetic<br />
polymers appeared in the market in the mid 1970s. Initially,<br />
it was only a cheap filler to reduce crude oil dependency, but<br />
was soon linked to biodegradable materials, e.g. in mulch<br />
film applications.<br />
Even at the grand opening of NatureWorks’ PLA facility in<br />
Blair (USA) in 20<strong>02</strong>, one of the key-note speakers asked the<br />
audience if they “want their raw materials to come from the<br />
Midwest or the Middle East”, referring to the attacks of 11 th<br />
September 2001.<br />
The recent geopolitical developments have been putting<br />
pressure on the situation related to energy supply. If we<br />
want to have a situation in Western Europe where the gas<br />
supply is re-evaluated, the short-term solution will be in<br />
shifting energy sources, away from natural gas towards<br />
oil, coal, lignite, and even nuclear energy. The side effects<br />
that are likely to occur in such situations are often ignored.<br />
Uncertainties for the future may influence the stock market,<br />
inflation might rise (significantly), and interest rates are<br />
likely to go through the roof in the upcoming months as well<br />
– even if a peaceful settlement can be reached soon.<br />
Have we learnt nothing from the oil and energy crisis of<br />
1973? Unpredicted changes in the price and availability of<br />
crude oil and raw materials (like plastics) have been the<br />
start of a strong recession that lasted for almost a decade.<br />
Which in turn lead to high unemployment rates and strong<br />
increases in prices. Yet the consumption of energy and<br />
plastics did not change. There seems therefore to be a<br />
direct connection between economic growth (GDP) and the<br />
consumption of plastics. Before 1973 there was a direct<br />
correlation between energy use and the development of<br />
the GDP in Europe. After 1973 there was a clear separation<br />
visible, with a growth of the GDP and a diversification in<br />
energy supply.<br />
For around 30 years the bioplastic industry has been<br />
developing new materials and processes, especially in<br />
the area of compostable materials. Initially, the driving<br />
force (in the early 90s of the previous century) was linked<br />
to agriculture. Creating added value for farmers was the<br />
focus of almost all starch producing companies – only a<br />
few companies from that pioneering phase managed to<br />
make the translation from starch to the world of plastics<br />
and packaging. Since these days, the bioplastic industry<br />
has been sending out different signals to the industry.<br />
Environmental benefits had to be clarified, separate waste<br />
separation was promoted as an approach to reduce landfills,<br />
climate change was addressed, and being biobased received<br />
attention. We have seen various hypes like agrification, the<br />
cradle-to-cradle approach, and currently, we are in the<br />
middle of the circular economy mantra.<br />
The plastic industry has kept on growing, and as<br />
environmental impacts become more and more visible to the<br />
general public (like the Plastic Soup), the communication<br />
on plastic recycling has been intensified. Unfortunately, it<br />
becomes increasingly eminent that mechanical recycling is<br />
simply not the holy grail that the plastic industry and big<br />
brand owners are trying to make it out to be. The European<br />
Plastics Pact had the ambition that the industry would<br />
reduce the consumption of plastics and increase recycling.<br />
Ambitious targets and voluntary agreements have been<br />
presented to the general public. How close to achieving<br />
these targets are we, and is it even realistic that we will<br />
reach them at all? Consumption of plastic has increased<br />
instead of decreasing, and the use of recycled plastics in<br />
packaging is still at embarrassingly low levels compared<br />
to glass, metal, and paper. The industry is kicking the can<br />
down the road with a new magical solution called chemical<br />
recycling. The processes that are being investigated are<br />
44 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
Opinion<br />
(with the exception of chemical<br />
recycling of PLA) far more<br />
expensive than using virgin<br />
materials like PE or PP, can be<br />
quite energy-intensive, and are<br />
overall rather controversial.<br />
What is missing to reach the<br />
necessary transition is a proper<br />
driving force. For companies<br />
that are using regular plastics,<br />
making a shift is expensive<br />
and risky. And as long as<br />
consumers believe that there<br />
are realistic environmental<br />
solutions in place - which<br />
help to reduce their guilty conscience – it will be difficult<br />
to achieve breakthrough changes. Yes, some brands and<br />
retailers have made enormous propaganda for their green<br />
solutions, but if you look at the relative numbers they were<br />
rather homeopathic in nature. And many positive initiatives<br />
have been stopped as soon as the actual target, creating<br />
brand value and a positive image, was achieved. Multibillion<br />
companies have marketing departments that can<br />
easily spend large amounts of money on communication<br />
to influence public opinion. That is their job. But as soon<br />
as the shareholder value comes under pressure and the<br />
competition is not following, environmental aspirations are<br />
thrown out the window again – quietly.<br />
In this context, it is also interesting to analyse the waste<br />
processing companies. There is an overcapacity of waste<br />
incineration plants in various regions in Western Europe.<br />
Coincidence or not: these are also the regions with the<br />
highest resistance against the use of compostable materials.<br />
Waste incineration plants earn more money if they run at<br />
full capacity. Considering that a waste incineration plant<br />
costs around EUR 1 billion to build, with a technical life<br />
expectancy of at least 30 years, it is not surprising that<br />
such companies try to protect their shareholders’ value.<br />
Municipalities that have difficulties dealing with low budgets<br />
easily fall into the hands of a company with overcapacity in<br />
incineration. There is no proper environmental driving force<br />
to change the status quo that can compete with this strong<br />
financial motivation to make ends meet.<br />
What do the considerations as described above mean<br />
for the bioplastic industry? The recent geopolitical<br />
developments might be a breaking point. We cannot take<br />
cheap energy and oil supply for granted anymore and<br />
we might be forced to reconsider how we deal with our<br />
resources and waste. Most compostable plastics are<br />
Remy Jongboom<br />
Director Business Development & Product Innovation<br />
Biotec<br />
Emmerich, Germany<br />
(partially) biobased. Examples like<br />
PLA and PHA are 100 % biobased, and<br />
starch blends have increased their<br />
biobased share over the last 5 years<br />
from 25 % up to more than 60 %. A<br />
silent revolution or a rapid evolution?<br />
Biobased monomers like butanediol<br />
or succinic acid can be produced at<br />
competitive prices compared with<br />
their fossil-based alternatives.<br />
So far, mainly feedstocks like starch<br />
and sugar have been considered as<br />
primary sources. However, we could, or<br />
should, also consider other feedstock<br />
like side streams of the food processing<br />
industry. Even wastewater plants can<br />
be used to produce new raw materials like PHA. While<br />
technically possible, they were often too expensive in the<br />
reality of yesterday. Mainly due to the relatively low costs<br />
of fossil energy and its abundant supply. This has recently<br />
changed, and it is not clear yet if these days will ever<br />
come back again, for better or worse. Compost can help<br />
to improve the structure of the soil and contains a certain<br />
amount of nutrients. Using more compost not only has a<br />
climate-friendly carbon binding potential but also reduces<br />
the need for energy-intensive mineral fertilizers. And if<br />
renewable energy sources like solar and wind energy keep<br />
on increasing in importance, then the conversion of organic<br />
waste, including compostable plastics, towards biogas may<br />
help to secure our energy supply when the sun is not shining<br />
and the winds are not blowing.<br />
Hopefully, the acts of war in Ukraine will soon come to an<br />
end. And maybe in 5 or 10, years we will look back at the<br />
current events as the big catalyst that led to major changes<br />
in the Western World on how we will look at and deal with<br />
our resources and waste streams. The cleaner technologies<br />
are available and getting cheaper – lucrative opportunities<br />
that bring change are there, with environmental benefits as<br />
positive side effects. The driving force for change is a new<br />
and unpredictable one. Only the future will tell us if we will<br />
manage to maintain and improve our current standards<br />
of living and freedom even further, by kicking our fossil<br />
resources addiction.<br />
www.biotec.de<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 45
Methodology<br />
Bioplastic Feedstock Alliance<br />
new guidance<br />
T<br />
he Bioplastic Feedstock Alliance, the World Wildlife<br />
Fund (WWF) (Gland, Switzerland) led initiative<br />
to advance thought leadership on responsible<br />
biobased plastic, released an updated methodology for<br />
guiding responsible sourcing decisions.<br />
Responsibly sourced biobased plastic is one of the many<br />
circularity solutions that WWF is championing in its pursuit<br />
of No Plastic in Nature by 2030. The global environmental<br />
NGO launched the Bioplastic Feedstock Alliance (BFA) in<br />
2013 to advance thought leadership on biobased plastic’s<br />
role in creating a more sustainable and circular material<br />
system. The group’s focus has been on building the<br />
knowledge around the responsible sourcing of feedstocks,<br />
which are key to realizing biobased plastic’s potential for<br />
both people and planet.<br />
In this pursuit, the BFA convenes to address the significant<br />
gap in guidance for decision making regarding biobased<br />
plastic sourcing, including the crucial first step of assessing<br />
the risks and benefits of different feedstocks from different<br />
places. The BFA created this methodology, BFA Methodology<br />
for the Assessment of Bioplastic Feedstocks, to serve as<br />
a tool to start the journey to responsible sourcing and its<br />
environmental and social benefits.<br />
The methodology defines 13 indicators that users explore<br />
to build their understanding of the relative benefits, tradeoffs,<br />
and risks of different feedstocks. The 2<strong>02</strong>2 update<br />
integrates the latest science and guidance into this existing<br />
framework, as well as simplifying the user experience.<br />
The BFA methodology serves as a guide to help companies<br />
and producers navigate complex decision-making based on<br />
consistent and comprehensive criteria. Further, it provides<br />
guidance and resources across a broad range of sourcing<br />
topics in one place, helping users build a comprehensive<br />
understanding across environmental and social indicators<br />
as well as identify what <strong>issue</strong>s require further due diligence<br />
or external expertise.<br />
The goal is to ensure that bioplastic purchasers and<br />
producers are asking the important questions that ultimately<br />
drive the entire industry toward sourcing decisions that do<br />
more good, resulting in better environmental and social<br />
outcomes.<br />
As science in both the bioplastic and conservation spaces<br />
are constantly advancing, it is important to update this<br />
guide to reflect the latest thinking.<br />
Since the BFA methodology was first developed in 2014,<br />
new guidance has been developed by many organizations<br />
on a range of topics, including water stewardship, climate<br />
resilience and mitigation, land-use change, and food<br />
security. This 2<strong>02</strong>2 update to the BFA methodology brings<br />
these learnings together to create a central point for the<br />
latest research and developments in conservation science<br />
related to biobased plastic.<br />
Here’s what’s new in the 2<strong>02</strong>2 BFA Methodology for the<br />
Assessment of Bioplastic Feedstocks, and what it means<br />
for the industry:<br />
• Integrating a climate resilience lens across the<br />
methodology. To successfully integrate biobased plastics<br />
into the circular economy at scale, their production<br />
must support climate resilience at the landscape level.<br />
The methodology now includes guidance to help users<br />
understand this complex topic and how their decisions<br />
can affect landscape resilience.<br />
• Widening the lens to adapt to novel feedstocks. As<br />
feedstocks such as algae, residues from crop harvesting,<br />
tall oil, CO 2<br />
capture and utilization, and used cooking<br />
oil come to market, it is crucial that they are assessed<br />
against consistent criteria. In this update, content<br />
is adapted to account for the broad range of <strong>issue</strong>s<br />
associated with the expanding categories of feedstock<br />
options.<br />
• Simplifying user experience. The 2<strong>02</strong>2 update includes<br />
updated research guidance and resources to help users<br />
navigate this complex topic, find external expertise<br />
when needed, and prioritize specific <strong>issue</strong>s for further<br />
investigation. An updated scoring system makes it<br />
simpler to understand and communicate results.<br />
Together, the suite of updates included in the 2<strong>02</strong>2<br />
Methodology for the Assessment of Bioplastic Feedstocks<br />
combines the most up-to-date guidance from experts<br />
across a wide range of disciplines. The updated Methodology<br />
will guide producers and purchasers of biobased plastic<br />
towards decisions that support a more sustainable future.<br />
www.bioplasticfeedstockalliance.org<br />
Info:<br />
The new BFA guidance can be<br />
downloaded from<br />
https://tinyurl.com/wwf-bfa<br />
By<br />
Kori Goldberg<br />
Plastic Waste Specialist<br />
World Wildlife Fund US<br />
Washington, DC, USA<br />
46 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
Plastic or no plastic –<br />
that‘s the question<br />
By Michael Thielen<br />
Basics<br />
Initially announced as a Basics article, this turns out to be<br />
more an opinion article. However, this article shall serve<br />
as food for thought. I explicitly encourage stakeholders<br />
in this topic to share their opinion with us. Maybe we can<br />
publish a kind of “Pro – Con” article in one of the upcoming<br />
<strong>issue</strong>s.<br />
The motivation for this article is the fact that we see an<br />
increasing number of publications and products on the<br />
market, stating their products made of biobased and/or<br />
biodegradable/compostable plastics were “plastic-free” or<br />
“no-plastic”. A plastic planet is even starting a discussion<br />
about what they call “Plastic Free Standards” [1]. This not<br />
only confuses experts and consumers alike – in my opinion<br />
,it is simply wrong.<br />
I’d like to start with my personal opinion or definition of<br />
what plastics and what polymers are.<br />
Polymers<br />
A polymer (from the Greek terms poly-, “many” and<br />
-mer, “part”) is a substance or material consisting of very<br />
large molecules, or macromolecules, composed of many<br />
repeating subunits [2]. Polymers can be polymerized<br />
industrially from monomers (such as combining ethylene<br />
(C 2<br />
H 4<br />
) to long chains (C 2<br />
H 4<br />
) n<br />
= polyethylene). But polymers<br />
also exit in natural substances, for example, cellulose,<br />
lignin, in the exoskeleton of crustaceans (chitin) and many<br />
more.<br />
Plastic<br />
Since polymers, as they come from the reactor (e.g. pure<br />
polyethylene), cannot be processed into useful everyday<br />
products by injection moulding, blow moulding, film<br />
blowing, etc, they need to be compounded, i.e. combined<br />
with additives.<br />
Bioplastic<br />
The same holds true for bioplastics (plastics that are<br />
made from renewable resources, that are biodegradable or<br />
that are both). Biobased polymers, whether they are, e.g.<br />
polymerized from monomers obtained from fermentation<br />
processes from sugar sources (e.g. lactic acid to polylactic<br />
acid PLA) or otherwise obtained from natural sources<br />
(PHAs being natural polymers in the body of certain<br />
bacteria, chitin/chitosan from crustaceans, or many other<br />
possible sources), need to be compounded before they can<br />
be processed.<br />
Bioplastics are plastics<br />
Bioplastics are plastics: Materials, compounded from<br />
polymers that can be processed into useful products. This<br />
is what all definitions of the plastic industry, the European<br />
Commission or the industry association European<br />
Bioplastics confirm. According to the REACH regulations,<br />
for example (Article 3(5) Regulation 1907/2006), “plastics are<br />
polymers that include various additives making it possible<br />
to obtain materials that can be cast, shaped, generally<br />
under heat and pressure, in order to obtain market-ready<br />
final articles”.<br />
So, if a manufacturer of biobased plastic products wants<br />
to make a claim, it should not say “plastic-free”, or “noplastic”.<br />
It should rather read “free from conventional<br />
plastic” or “free from fossil-based plastic” or “no petroleumbased<br />
plastic” or the like.<br />
Potential pitfalls<br />
Talking about “no-plastic” or “plastic-free” can be a pitfall<br />
when marketing products made of biobased plastics. The<br />
abovementioned REACH regulation also states that all<br />
so-called “bio-sourced” and/or “biodegradable” materials<br />
are included in this definition and regarded as plastics<br />
in the same way as all the others, often referred to as<br />
“conventional plastics”.<br />
The Single-Use Plastic (SUP) directive of the European<br />
Commission includes all plastics, under the meaning of<br />
the REACH definition, with no distinction, and hence de<br />
facto including biodegradable and/or bio-sourced plastics,<br />
irrespective of their means of biodegradation (compost, soil,<br />
river or seawater). I think we all agree that this directive<br />
is not a good directive. But this topic shall be discussed<br />
separately.<br />
Pro and Con<br />
So, what is your opinion? Plastic or no plastic? Please let<br />
us know. We’d like to publish different opinions on this in<br />
one of our next <strong>issue</strong>s.<br />
Source: aplasticplanet.com/trust-marks/<br />
Courtesy: Naku<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 47
Brand Owner<br />
Brand-Owner’s perspective<br />
on bioplastics and how to<br />
unleash its full potential<br />
What does fischer as a brand owner expect from<br />
the bioplastics industry?<br />
Moving away from a finite resource such as oil towards a<br />
renewable and therefore infinite resource is precisely the right<br />
approach. We have the same quality requirements we have for<br />
conventional resources in this respect. In addition to this, we<br />
also ensure that raw materials don’t compete with main food<br />
crops and that they have a neutral impact on the environment.<br />
Providing transparent information on ingredients and<br />
manufacturing methods is also of key importance. As such,<br />
the material must meet high recyclability requirements. As<br />
part of our comprehensive approach, we also emphasise<br />
compliance with CSR standards ranging from mining to<br />
further processing and logistics.<br />
Christian Ziegler<br />
Head of Department<br />
Sustainability, Environment and Energy,<br />
fischer group<br />
What does fischer think the bioplastics industry<br />
needs to do?<br />
The production of bioplastics would need to be optimised<br />
to the point that sustainable raw materials are available at a<br />
similar price as conventional ones. Furthermore, sustainable<br />
resources should be competitive in terms of quality, availability<br />
,and planning security.<br />
Under what circumstances would fischer use<br />
(more) bioplastics, what are the requirements?<br />
If the quality requirements for bioplastics are similarly high<br />
as they are for conventional resources, then from this aspect<br />
nothing speaks against using them more frequently. And the<br />
price has to be right, too. The purchasing price for bioplastics<br />
must be at a similar level as regular plastics. At the moment,<br />
bioplastics tend to be significantly more expensive and<br />
sometimes aren’t available as required.<br />
What is fischer already doing in this respect?<br />
fischer is the world’s first manufacturer to produce<br />
plugs made of primarily renewable resources with its<br />
GreenLine, which was honoured with a Green Brand<br />
award last year. The award and its corresponding quality<br />
seal recognises brands with a proven commitment to<br />
climate conservation, sustainability, and ecological<br />
responsibility. The regenerative market share of<br />
GreenLine has been confirmed by an independent testing<br />
and certification body by DIN CERTCO / TÜV Rheinland.<br />
We are continuously raising awareness of these products<br />
among our staff and customers to reduce reservations<br />
or concerns and demonstrate the advantages. One of<br />
our advantages from a production point of view is that<br />
we can use our existing manufacturing processes and<br />
tools regardless of the respective raw materials.<br />
www.fischer.de<br />
Magnetic<br />
for Plastics<br />
www.plasticker.com<br />
• International Trade<br />
in Raw Materials, Machinery & Products Free of Charge.<br />
• Daily News<br />
from the Industrial Sector and the Plastics Markets.<br />
• Current Market Prices<br />
for Plastics.<br />
• Buyer’s Guide<br />
for Plastics & Additives, Machinery & Equipment, Subcontractors<br />
and Services.<br />
• Job Market<br />
for Specialists and Executive Staff in the Plastics Industry.<br />
Up-to-date • Fast • Professional<br />
48 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
10<br />
Years ago<br />
Cover Application Story News<br />
the stadium’s visible demonstration of environmental awareness<br />
as promoter of new and fair-play solutions:<br />
The PLA cups offer a simple way of contributing to more<br />
sustainable environmental performance. Their PR appeal can<br />
rise an increased media interest. For sponsoring or advertising<br />
companies the cups can be used to improve the corporate and<br />
brand image and can help to differ from competition. And finally<br />
cups made from PLA offer a possibility for single waste stream.<br />
Moreover, the PLA beer cups are compostable and certified in<br />
accordance with EN 13432, European norm for compostability of<br />
packaging, meaning that they degrade completely in industrial<br />
composting facilities. The options for disposal are plentiful:<br />
incineration with energy recovery, composting and recycling. Apart<br />
from that, Huhtamaki and stadium operators are jointly working<br />
on a promising ‘from cradle to cradle’ project, planning to build a<br />
closed recycled PLA material loop for stadiums and arenas.<br />
Huhtamaki was the first to launch a complete range of<br />
compostable tableware. The BioWare family was launched in<br />
2004 and is continuously developed with new products. BioWare<br />
products are available in Europe and Oceania.<br />
Huhtamaki has maintained the Pass status in the Kempen SNS<br />
Socially Responsible Investing (SRI) Universe since 20<strong>02</strong>. Only<br />
those European companies that meet or exceed the strict business<br />
ethical, social and environmental performance standards set by<br />
Kempen Capital Management and SNS Asset Management qualify<br />
for inclusion.<br />
www.huhtamaki.de/foodservice<br />
Cover Story<br />
Fair play commitment<br />
to environment<br />
Our cover photo protagonists<br />
and their friends enjoy beer<br />
from PLA cups<br />
Huhtamaki’s PLA beer cup assortment emerges<br />
as a clear winner in stadiums and arenas<br />
S<br />
ustainable packaging is quite a new addition to the environmental<br />
considerations for packaging. With eco-friendly<br />
PLA cold drink cups for the catering market, Huhtamaki has<br />
since several years been promoting this aspect. Recently, more and<br />
more organizers of big events and football (soccer) games in stadiums<br />
decided to join the ranks.<br />
In 2009, the first Premier League arenas in Germany together<br />
with several Second League stadiums pioneered the concept<br />
of using biodegradable NatureWorks ® PLA beer cups for their<br />
big events. These were the early birds in recognising not only<br />
the positively practical benefits of these products, but also their<br />
sustainable aspects: PLA is made from annually renewable<br />
resources, is compostable and thus can be disposed of completely<br />
naturally. Other stadiums as well as various breweries were quick<br />
to follow, and soon both operators and visitors appreciated the<br />
evident advantages of this environmental-friendly solution for<br />
cups. Single use cups offer guaranteed hygiene, as each guest gets<br />
a new cup. There is no need for dishwashing as for reusable cups.<br />
This saves labour time, water, heating energy and detergents. The<br />
lightweight PLA cups are safe, as they do not break nor splinter.<br />
The cups are light to carry and easy to handle and in addition allow<br />
a faster and more focused customer service. Last but not least, the<br />
possibility for customised printing offers additional promotional<br />
opportunities.<br />
In terms of sustainability, the concept offers far more. Belonging<br />
to Huhtamaki’s future friendly BioWare packaging portfolio, PLA<br />
beer cups together with molded fibre strongholders stand out as<br />
In March 2<strong>02</strong>2,<br />
Hendrik Müller – General Manager<br />
Huhtamaki Foodservice Germany<br />
Sales GMBH & Co. KG<br />
Alf, Germany<br />
says:<br />
Packaging for good: for Huhtamaki it is<br />
not only an international slogan but also<br />
the demand to think ahead and to constantly<br />
develop. 10 years ago Huhtamaki<br />
had already outgrown its infancy in the<br />
field of disposable cups/products made of PLA<br />
and the raw material developed into a real alternative<br />
to oil-based plastics in the field of packaging<br />
and still is today.<br />
Huhtamaki in Alf played a pioneering role in<br />
terms of further developing the processability of<br />
PLA in the thermoforming process. Today, many<br />
different industries and production processes<br />
use the same sources of raw materials as we<br />
do because they too have recognized the advantages<br />
of PLA. In this market, in particular,<br />
tact and flexibility are currently<br />
in demand. Plastic packaging<br />
is a hotly debated topic, plastic<br />
and disposable bans in certain<br />
areas of application put crisis<br />
security to the test. Unfortunately,<br />
European legislation<br />
has (almost) completely<br />
disregarded the undisputed<br />
benefits of biobased plastics<br />
when formulating the SUPD,<br />
which has pushed the materials’<br />
advantages for use in<br />
service packaging more and<br />
more into the background.<br />
Personally, I believe that<br />
the potential and importance<br />
of PLA will continue<br />
to grow. This will certainly<br />
soon be supported by the<br />
possibility of resource-saving,<br />
chemical recycling. It<br />
remains to be seen whether<br />
this will be in time for<br />
our applications, but we in<br />
Alf are proud of the contribution<br />
we were allowed<br />
to make to the PLA success<br />
story and we still<br />
are today.<br />
www.foodservice.huhtamaki.de<br />
bioplastics MAGAZINE [<strong>02</strong>/12] Vol. 7 17<br />
https://tinyurl.com/2012-PLA-cups<br />
16 bioplastics MAGAZINE [<strong>02</strong>/12] Vol. 7<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 49
1. Raw materials<br />
Suppliers Guide<br />
AGRANA Starch<br />
Bioplastics<br />
Conrathstraße 7<br />
A-3950 Gmuend, Austria<br />
bioplastics.starch@agrana.com<br />
www.agrana.com<br />
Xinjiang Blue Ridge Tunhe<br />
Polyester Co., Ltd.<br />
No. 316, South Beijing Rd. Changji,<br />
Xinjiang, 831100, P.R.China<br />
Tel.: +86 994 22 90 90 9<br />
Mob: +86 187 99 283 100<br />
chenjianhui@lanshantunhe.com<br />
www.lanshantunhe.com<br />
PBAT & PBS resin supplier<br />
Kingfa Sci. & Tech. Co., Ltd.<br />
No.33 Kefeng Rd, Sc. City, Guangzhou<br />
Hi-Tech Ind. Development Zone,<br />
Guangdong, P.R. China. 510663<br />
Tel: +86 (0)20 6622 1696<br />
info@ecopond.com.cn<br />
www.kingfa.com<br />
BASF SE<br />
Ludwigshafen, Germany<br />
Tel: +49 621 60-99951<br />
martin.bussmann@basf.com<br />
www.ecovio.com<br />
Mixcycling Srl<br />
Via dell‘Innovazione, 2<br />
36042 Breganze (VI), Italy<br />
Phone: +39 04451911890<br />
info@mixcycling.it<br />
www.mixcycling.it<br />
FKuR Kunststoff GmbH<br />
Siemensring 79<br />
D - 47 877 Willich<br />
Tel. +49 2154 9251-0<br />
Tel.: +49 2154 9251-51<br />
sales@fkur.com<br />
www.fkur.com<br />
Simply contact:<br />
Tel.: +49 2161 6884467<br />
suppguide@bioplasticsmagazine.com<br />
Stay permanently listed in the<br />
Suppliers Guide with your company<br />
logo and contact information.<br />
For only 6,– EUR per mm, per <strong>issue</strong> you<br />
can be listed among top suppliers in the<br />
field of bioplastics.<br />
Gianeco S.r.l.<br />
Via Magenta 57 10128 Torino - Italy<br />
Tel.+390119370420<br />
info@gianeco.com<br />
www.gianeco.com<br />
Xiamen Changsu Industrial Co., Ltd<br />
Tel +86-592-6899303<br />
Mobile:+ 86 185 5920 1506<br />
Email: andy@chang-su.com.cn<br />
1.1 Biobased monomers<br />
1.2 Compounds<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
39 mm<br />
For Example:<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
41066 Mönchengladbach<br />
Germany<br />
Tel. +49 2161 664864<br />
Fax +49 2161 631045<br />
info@bioplasticsmagazine.com<br />
www.bioplasticsmagazine.com<br />
Sample Charge:<br />
39mm x 6,00 €<br />
= 234,00 € per entry/per <strong>issue</strong><br />
Sample Charge for one year:<br />
6 <strong>issue</strong>s x 234,00 EUR = 1,404.00 €<br />
The entry in our Suppliers Guide is<br />
bookable for one year (6 <strong>issue</strong>s) and extends<br />
automatically if it’s not cancelled<br />
three month before expiry.<br />
PTT MCC Biochem Co., Ltd.<br />
info@pttmcc.com / www.pttmcc.com<br />
Tel: +66(0) 2 140-3563<br />
MCPP Germany GmbH<br />
+49 (0) 211 520 54 662<br />
Julian.Schmeling@mcpp-europe.com<br />
MCPP France SAS<br />
+33 (0)2 51 65 71 43<br />
fabien.resweber@mcpp-europe.com<br />
Microtec Srl<br />
Via Po’, 53/55<br />
30030, Mellaredo di Pianiga (VE),<br />
Italy<br />
Tel.: +39 041 5190621<br />
Fax.: +39 041 5194765<br />
info@microtecsrl.com<br />
www.biocomp.it<br />
Earth Renewable Technologies BR<br />
Estr. Velha do Barigui 10511, Brazil<br />
slink@earthrenewable.com<br />
www.earthrenewable.com<br />
Trinseo<br />
1000 Chesterbrook Blvd. Suite 300<br />
Berwyn, PA 19312<br />
+1 855 8746736<br />
www.trinseo.com<br />
BIO-FED<br />
Branch of AKRO-PLASTIC GmbH<br />
BioCampus Cologne<br />
Nattermannallee 1<br />
50829 Cologne, Germany<br />
Tel.: +49 221 88 88 94-00<br />
info@bio-fed.com<br />
www.bio-fed.com<br />
Green Dot Bioplastics<br />
527 Commercial St Suite 310<br />
Emporia, KS 66801<br />
Tel.: +1 620-273-8919<br />
info@greendotbioplastics.com<br />
www.greendotbioplastics.com<br />
Plásticos Compuestos S.A.<br />
C/ Basters 15<br />
08184 Palau Solità i Plegamans<br />
Barcelona, Spain<br />
Tel. +34 93 863 96 70<br />
info@kompuestos.com<br />
www.kompuestos.com<br />
NUREL Engineering Polymers<br />
Ctra. Barcelona, km 329<br />
50016 Zaragoza, Spain<br />
Tel: +34 976 465 579<br />
inzea@samca.com<br />
www.inzea-biopolymers.com<br />
www.facebook.com<br />
www.issuu.com<br />
www.twitter.com<br />
www.youtube.com<br />
Tel: +86 351-8689356<br />
Fax: +86 351-8689718<br />
www.jinhuizhaolong.com<br />
ecoworldsales@jinhuigroup.com<br />
Global Biopolymers Co., Ltd.<br />
Bioplastics compounds<br />
(PLA+starch, PLA+rubber)<br />
194 Lardproa80 yak 14<br />
Wangthonglang, Bangkok<br />
Thailand 10310<br />
info@globalbiopolymers.com<br />
www.globalbiopolymers.com<br />
Tel +66 81 9150446<br />
a brand of<br />
Helian Polymers BV<br />
Bremweg 7<br />
5951 DK Belfeld<br />
The Netherlands<br />
Tel. +31 77 398 09 09<br />
sales@helianpolymers.com<br />
https://pharadox.com<br />
50 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
1.5 PHA<br />
3. Semi-finished products<br />
Sukano AG<br />
Chaltenbodenstraße 23<br />
CH-8834 Schindellegi<br />
Tel. +41 44 787 57 77<br />
Fax +41 44 787 57 78<br />
www.sukano.com<br />
Biofibre GmbH<br />
Member of Steinl Group<br />
Sonnenring 35<br />
D-84032 Altdorf<br />
Fon: +49 (0)871 308-0<br />
Fax: +49 (0)871 308-183<br />
info@biofibre.de<br />
www.biofibre.de<br />
Zhejiang Hisun Biomaterials Co.,Ltd.<br />
No.97 Waisha Rd, Jiaojiang District,<br />
Taizhou City, Zhejiang Province, China<br />
Tel: +86-576-88827723<br />
pla@hisunpharm.com<br />
www.hisunplas.com<br />
ECO-GEHR PLA-HI®<br />
- Sheets 2 /3 /4 mm – 1 x 2 m -<br />
GEHR GmbH<br />
Mannheim / Germany<br />
Tel: +49-621-8789-127<br />
laudenklos@gehr.de<br />
www.gehr.de<br />
1.4 Starch-based bioplastics<br />
Kaneka Belgium N.V.<br />
Nijverheidsstraat 16<br />
2260 Westerlo-Oevel, Belgium<br />
Tel: +32 (0)14 25 78 36<br />
Fax: +32 (0)14 25 78 81<br />
info.biopolymer@kaneka.be<br />
TianAn Biopolymer<br />
No. 68 Dagang 6th Rd,<br />
Beilun, Ningbo, China, 315800<br />
Tel. +86-57 48 68 62 50 2<br />
Fax +86-57 48 68 77 98 0<br />
enquiry@tianan-enmat.com<br />
www.tianan-enmat.com<br />
1.6 Masterbatches<br />
3.1 Sheets<br />
Customised Sheet Xtrusion<br />
James Wattstraat 5<br />
7442 DC Nijverdal<br />
The Netherlands<br />
+31 (548) 626 111<br />
info@csx-nijverdal.nl<br />
www.csx-nijverdal.nl<br />
4. Bioplastics products<br />
Bio4Pack GmbH<br />
Marie-Curie-Straße 5<br />
48529 Nordhorn, Germany<br />
Tel. +49 (0)5921 818 37 00<br />
info@bio4pack.com<br />
www.bio4pack.com<br />
Suppliers Guide<br />
Natureplast – Biopolynov<br />
11 rue François Arago<br />
14123 IFS<br />
Tel: +33 (0)2 31 83 50 87<br />
www.natureplast.eu<br />
TECNARO GmbH<br />
Bustadt 40<br />
D-74360 Ilsfeld. Germany<br />
Tel: +49 (0)7062/97687-0<br />
www.tecnaro.de<br />
P O L i M E R<br />
GEMA POLIMER A.S.<br />
Ege Serbest Bolgesi, Koru Sk.,<br />
No.12, Gaziemir, Izmir 35410,<br />
Turkey<br />
+90 (232) 251 5041<br />
info@gemapolimer.com<br />
http://www.gemabio.com<br />
eli<br />
bio<br />
Elixance<br />
Tel +33 (0) 2 23 10 16 17<br />
Tel PA du +33 Gohélis, (0)2 56250 23 Elven, 10 16 France 17 - elixbio@elixbio.com<br />
elixbio@elixbio.com/www.elixbio.com<br />
www.elixance.com - www.elixbio.com<br />
1.3 PLA<br />
TotalEnergies Corbion bv<br />
Stadhuisplein 70<br />
4203 NS Gorinchem<br />
The Netherlands<br />
Tel.: +31 183 695 695<br />
www.totalenergies-corbion.com<br />
pla@total-corbion.com<br />
BIOTEC<br />
Biologische Naturverpackungen<br />
Werner-Heisenberg-Strasse 32<br />
46446 Emmerich/Germany<br />
Tel.: +49 (0) 2822 – 92510<br />
info@biotec.de<br />
www.biotec.de<br />
Plásticos Compuestos S.A.<br />
C/ Basters 15<br />
08184 Palau Solità i Plegamans<br />
Barcelona, Spain<br />
Tel. +34 93 863 96 70<br />
info@kompuestos.com<br />
www.kompuestos.com<br />
Sunar NP Biopolymers<br />
Turhan Cemat Beriker Bulvarı<br />
Yolgecen Mah. No: 565 01355<br />
Seyhan /Adana,TÜRKIYE<br />
info@sunarnp.com<br />
burc.oker@sunarnp.com.tr<br />
www. sunarnp.com<br />
Tel: +90 (322) 441 01 65<br />
UNITED BIOPOLYMERS S.A.<br />
Parque Industrial e Empresarial<br />
da Figueira da Foz<br />
Praça das Oliveiras, Lote 126<br />
3090-451 Figueira da Foz – Portugal<br />
Phone: +351 233 403 420<br />
info@unitedbiopolymers.com<br />
www.unitedbiopolymers.com<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
Albrecht Dinkelaker<br />
Polymer- and Product Development<br />
Talstrasse 83<br />
60437 Frankfurt am Main, Germany<br />
Tel.:+49 (0)69 76 89 39 10<br />
info@polyfea2.de<br />
www.caprowax-p.eu<br />
Treffert GmbH & Co. KG<br />
In der Weide 17<br />
55411 Bingen am Rhein; Germany<br />
+49 6721 403 0<br />
www.treffert.eu<br />
Treffert S.A.S.<br />
Rue de la Jontière<br />
57255 Sainte-Marie-aux-Chênes,<br />
France<br />
+33 3 87 31 84 84<br />
www.treffert.fr<br />
www.granula.eu<br />
2. Additives/Secondary raw materials<br />
Plant-based and Compostable PLA Cups and Lids<br />
Great River Plastic Manufacturer<br />
Company Limited<br />
Tel.: +852 95880794<br />
sam@shprema.com<br />
https://eco-greatriver.com/<br />
Minima Technology Co., Ltd.<br />
Esmy Huang, Vice president<br />
Yunlin, Taiwan(R.O.C)<br />
Mobile: (886) 0-982 829988<br />
Email: esmy@minima-tech.com<br />
Website: www.minima.com<br />
w OEM/ODM (B2B)<br />
w Direct Supply Branding (B2C)<br />
w Total Solution/Turnkey Project<br />
Naturabiomat<br />
AT: office@naturabiomat.at<br />
DE: office@naturabiomat.de<br />
NO: post@naturabiomat.no<br />
FI: info@naturabiomat.fi<br />
www.naturabiomat.com<br />
Natur-Tec ® - Northern Technologies<br />
4201 Woodland Road<br />
Circle Pines, MN 55014 USA<br />
Tel. +1 763.404.8700<br />
Fax +1 763.225.6645<br />
info@natur-tec.com<br />
www.natur-tec.com<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 51
9. Services<br />
10. Institutions<br />
10.1 Associations<br />
Suppliers Guide<br />
NOVAMONT S.p.A.<br />
Via Fauser , 8<br />
28100 Novara - ITALIA<br />
Fax +39.0321.699.601<br />
Tel. +39.0321.699.611<br />
www.novamont.com6. Equipment<br />
6.1 Machinery & moulds<br />
Buss AG<br />
Hohenrainstrasse 10<br />
4133 Pratteln / Switzerland<br />
Tel.: +41 61 825 66 00<br />
Fax: +41 61 825 68 58<br />
info@busscorp.com<br />
www.busscorp.com<br />
6.2 Degradability Analyzer<br />
MODA: Biodegradability Analyzer<br />
SAIDA FDS INC.<br />
143-10 Isshiki, Yaizu,<br />
Shizuoka,Japan<br />
Tel:+81-54-624-6155<br />
Fax: +81-54-623-8623<br />
info_fds@saidagroup.jp<br />
www.saidagroup.jp/fds_en/<br />
7. Plant engineering<br />
Osterfelder Str. 3<br />
46047 Oberhausen<br />
Tel.: +49 (0)208 8598 1227<br />
thomas.wodke@umsicht.fhg.de<br />
www.umsicht.fraunhofer.de<br />
Innovation Consulting Harald Kaeb<br />
narocon<br />
Dr. Harald Kaeb<br />
Tel.: +49 30-28096930<br />
kaeb@narocon.de<br />
www.narocon.de<br />
nova-Institut GmbH<br />
Chemiepark Knapsack<br />
Industriestrasse 300<br />
50354 Huerth, Germany<br />
Tel.: +49(0)2233-48-14 40<br />
E-Mail: contact@nova-institut.de<br />
www.biobased.eu<br />
Bioplastics Consulting<br />
Tel. +49 2161 664864<br />
info@polymediaconsult.com<br />
BPI - The Biodegradable<br />
Products Institute<br />
331 West 57th Street, Suite 415<br />
New York, NY 10019, USA<br />
Tel. +1-888-274-5646<br />
info@bpiworld.org<br />
European Bioplastics e.V.<br />
Marienstr. 19/20<br />
10117 Berlin, Germany<br />
Tel. +49 30 284 82 350<br />
Fax +49 30 284 84 359<br />
info@european-bioplastics.org<br />
www.european-bioplastics.org<br />
10.2 Universities<br />
Institut für Kunststofftechnik<br />
Universität Stuttgart<br />
Böblinger Straße 70<br />
70199 Stuttgart<br />
Tel +49 711/685-62831<br />
silvia.kliem@ikt.uni-stuttgart.de<br />
www.ikt.uni-stuttgart.de<br />
IfBB – Institute for Bioplastics<br />
and Biocomposites<br />
University of Applied Sciences<br />
and Arts Hanover<br />
Faculty II – Mechanical and<br />
Bioprocess Engineering<br />
Heisterbergallee 12<br />
30453 Hannover, Germany<br />
Tel.: +49 5 11 / 92 96 - 22 69<br />
Fax: +49 5 11 / 92 96 - 99 - 22 69<br />
lisa.mundzeck@hs-hannover.de<br />
www.ifbb-hannover.de/<br />
10.3 Other institutions<br />
GO!PHA<br />
Rick Passenier<br />
Oudebrugsteeg 9<br />
1012JN Amsterdam<br />
The Netherlands<br />
info@gopha.org<br />
www.gopha.org<br />
Green Serendipity<br />
Caroli Buitenhuis<br />
IJburglaan 836<br />
1087 EM Amsterdam<br />
The Netherlands<br />
Tel.: +31 6-24216733<br />
www.greenseredipity.nl<br />
EREMA Engineering Recycling<br />
Maschinen und Anlagen GmbH<br />
Unterfeldstrasse 3<br />
4052 Ansfelden, AUSTRIA<br />
Phone: +43 (0) 732 / 3190-0<br />
Fax: +43 (0) 732 / 3190-23<br />
erema@erema.at<br />
www.erema.at<br />
Michigan State University<br />
Dept. of Chem. Eng & Mat. Sc.<br />
Professor Ramani Narayan<br />
East Lansing MI 48824, USA<br />
Tel. +1 517 719 7163<br />
narayan@msu.edu<br />
Our new<br />
frame<br />
colours<br />
Bioplastics related topics, i.e.<br />
all topics around biobased<br />
and biodegradable plastics,<br />
come in the familiar<br />
green frame.<br />
All topics related to<br />
Advanced Recycling, such<br />
as chemical recycling<br />
or enzymatic degradation<br />
of mixed waste into building<br />
blocks for new plastics have<br />
this turquoise coloured<br />
frame.<br />
When it comes to plastics<br />
made of any kind of carbon<br />
source associated with<br />
Carbon Capture & Utilisation<br />
we use this frame colour.<br />
The familiar blue<br />
frame stands for rather<br />
administrative sections,<br />
such as the table of<br />
contents or the “Dear<br />
readers” on page 3.<br />
If a topic belongs to more<br />
than one group, we use<br />
crosshatched frames.<br />
Ochre/green stands for<br />
Carbon Capture &<br />
Bioplastics, e. g. PHA made<br />
from methane.<br />
Articles covering Recycling<br />
and Bioplastics ...<br />
Recycling & Carbon Capture<br />
We’re sure, you got it!<br />
As you may have already noticed, we are expanding our scope of topics. With the main target in focus – getting away from fossil resources – we are strongly<br />
supporting the idea of Renewable Carbon. So, in addition to our traditional bioplastics topics, about biobased and biodegradable plastics, we also started covering<br />
topics from the fields of Carbon Capture and Utilisation as well as Advanced Recycling.<br />
To better differentiate the different overarching topics in the magazine, we modified our layout.<br />
52 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
24/01/20 10:26<br />
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now at<br />
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Send a scan of your<br />
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Event Calendar<br />
Rethinking Materials<br />
04.05. - 05.05.2<strong>02</strong>2 - London, UK<br />
https://rethinkingmaterials.com/register<br />
The Renewable Materials Conference<br />
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ISSN 1862-5258 March/April<br />
bioplastics MAGAZINE Vol. 17<br />
Vol. 17<br />
... is read in 92 countries<br />
... is read in 92 countries<br />
bioplastics MAGAZINE<br />
2007<br />
Highlights<br />
Automotive | 18<br />
Foam | 36<br />
Basics<br />
Biodegradation | 50<br />
rancia_bioplasticmagazine_01_<strong>02</strong>.2<strong>02</strong>0_210x297.indd 1 24/01/20 10:26<br />
... is read in 92 countries<br />
. is read in 92 countries<br />
ISSN 1862-5258<br />
Subject to changes.<br />
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bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 53
Companies in this <strong>issue</strong><br />
Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />
ADEME 17<br />
Gema Polimers 51 Oak Ridge National Lab 16<br />
adidas 14<br />
Genomatica 32<br />
Oerlikon Textile 14<br />
Adsale 5 25 Ghent University 13<br />
Organic Waste Systems (OWS) 12<br />
Agrana Starch Bioplastics 50 Gianeco 50 Pack4Food 13<br />
Amerplast 41<br />
Global Biopolymers 10 50 PARP 21<br />
Avantium 38<br />
GO!PHA 8 52 PepsiCo 22<br />
BASF 18 50 Grafe 50,51 Phelan and Collender 44<br />
Bemis Associates 19<br />
Granula 51 Pilot Corporation 38<br />
Bentley 43<br />
Great River Plastic Manuf. 51 plasticker 48<br />
Bio4Pack 10 51 Green Dot Bioplastics 50 Polish Academy of Science 20<br />
Bio-Fed Branch of Akro-Plastic 50 Green Serendipity 13 52 PolyFerm 5<br />
Biofibre 51 GREENFILL3D 20, 21<br />
polymediaconsult 52<br />
Bioplastic Feedstock Alliance 46<br />
Gucci 43<br />
Porsche 43<br />
bioplastics MAGAZINE 6, 10, 11, 13, 22<br />
Helian Polymers 50 PTT/MCC 50<br />
Biotec 10, 12, 45 51,55 Huntsman 5<br />
RMIT University 28<br />
BMBF 15<br />
Inst. F. Bioplastics & Biocomposites 52 Rodenburg Biopolymers 13<br />
Borealis 8<br />
Institut f. Kunststofftechnik, Stuttgart 52 Institute für Textiltechnik (RWTH) 14, 15<br />
BPI 52 JinHui ZhaoLong High Technology 50 Saida 52<br />
Buss 21,52 K fair 5<br />
Schill+Seilacher 14<br />
CABAMIX 30<br />
Kaneka 51 Scion 39<br />
CAPROWAX P 36 51 Keen 5<br />
Shenzhen Esun Industrial 10<br />
Carbios 17<br />
Kingfa 50 Sicomin Epoxy Systems 39<br />
Carbon Minds 14<br />
Kompuestos 10, 33 50,51 SOSV 19<br />
carbonauten 26,27<br />
Lamborghini 43<br />
Sphera 8<br />
Casio Computer 40<br />
LanzaTech 16<br />
St1’s HelmiSimpukka 40<br />
Centexbel 10<br />
Lingrove 38<br />
Sukano 31 23,51<br />
Chanel 13<br />
Lubella 21<br />
Sulapac 12<br />
CHINAPLAS 5 25 LVMH Group 38<br />
Sulzer 6<br />
Clariant 24<br />
MASPEX 20, 21<br />
TECNARO 42, 43 51<br />
Covestro 14, 32<br />
McDonald's 22<br />
TerraVerdae Bioworks 5<br />
Croda Smart Materials 34, 35<br />
medi 14<br />
TianAn Biopolymer 51<br />
Customized Sheet Extrusion 51 Meditec, 39<br />
Tic Toys 42<br />
Decathlon 39<br />
Mercedes Benz 22<br />
TIME Ventures 19<br />
Diamond Edge Ventures 38<br />
Michigan State University 52 TNO 12<br />
Dr. Heinz Gupta Verlag 15 Microtec 50 TotalEnergies Corbion 8, 10 51<br />
Dupont 44<br />
Minima Technology 51 Toulouse White Biotechnology 17<br />
Earth Renewable Technologies 50 Mistletoe 19<br />
Toyota Tsusho Corporation 6<br />
Ekornes 18<br />
Mitsubishi Chemical Corporation 6, 38<br />
Treffert 51<br />
Elixance 37 51 Mixcycling 50 Trinseo 50<br />
Envisioning Partners 19<br />
NaKu 13, 41<br />
UBQ 22, 23<br />
Erema 52 Nanovia 37<br />
Uhde Inventa-Fischer 10<br />
European Bioplastics (EUBP) 6, 10, 31 52 narocon InnovationConsulting 52 United Biopolymers 51<br />
Filaticum 10<br />
Naturabiomat 51 Univ. Stuttgart (IKT) 52<br />
fischer group 48<br />
Natureplast-Biopolynov 51 Valo Ventures 19<br />
FKuR 10 2,5 NatureWorks 12, 44<br />
VARTDAL PLAST 18<br />
Floreon / Clariant 10<br />
Natur-Tec 51 W. Zimmermann 14<br />
Fraunhofer ICT 10, 42<br />
Neste 8<br />
WHO 5<br />
Fraunhofer IVV 10<br />
Northwestern University 16<br />
Woodly 41<br />
Fraunhofer UMSICHT 52 nova-institute 8 9,41,52 World Wildlife Fund 46<br />
freemee cosmetics 41<br />
Novamont 52,56 Xiamen Changsu Industries 50<br />
Galactic 10<br />
Novoloop 19<br />
Xinjiang Blue Ridge Tunhe Polyester 50<br />
Gehr 51 Nurel 50 Yangzhou Huitong Biological New Material 6<br />
Zeijiang Hisun Biomaterials 51<br />
Next <strong>issue</strong>s<br />
Issue<br />
Month<br />
Publ.<br />
Date<br />
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Deadline<br />
Edit. Focus 1 Edit. Focus 2 Basics<br />
03/2<strong>02</strong>2 May/Jun 07.06.2<strong>02</strong>2 06.05.2<strong>02</strong>2 Injection moulding Beauty &<br />
Healthcare<br />
04/2<strong>02</strong>2 Jul/Aug 01.08.2<strong>02</strong>2 01.07.2<strong>02</strong>2 Blow Moulding Polyurethanes/<br />
Elastomers/Rubber<br />
05/2<strong>02</strong>2 Sep/Oct 04.10.2<strong>02</strong>2 <strong>02</strong>.09.2<strong>02</strong>2 Fiber / Textile /<br />
Nonwoven<br />
06/2<strong>02</strong>2 Nov/Dec 05.12.2<strong>02</strong>2 04.11.2<strong>02</strong>2 Films/Flexibles/<br />
Bags<br />
Building &<br />
Construction<br />
Consumer<br />
Electronics<br />
Biocompatability of PHA<br />
FDCA and PEF<br />
Feedstocks, different<br />
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Chemical recycling<br />
Trade-Fair<br />
Specials<br />
Chinaplas Review<br />
K'2<strong>02</strong>2 Preview<br />
K'2<strong>02</strong>2 Review<br />
Subject to changes<br />
54 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17
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