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Bioplastics - CO 2<br />

-based Plastics - Advanced Recycling<br />

bioplastics MAGAZINE Vol. 17<br />

Basics<br />

Plastic or no plastic -<br />

that’s the question 47<br />

Highlights<br />

Thermoforming / Rigid packaging | 49<br />

Masterbatch / Additives | 30<br />

... is read in 92 countries<br />

... is read in 92 countries<br />

<strong>02</strong> / 2<strong>02</strong>2<br />

ISSN 1862-5258 March/April


What are<br />

bioplastics?


dear<br />

Editorial<br />

readers<br />

I recently read an essay in The New Yorker called ”In A World On Fire, Stop Burning<br />

Things” that resonated with me a lot. While the article did not touch on the <strong>issue</strong>s of<br />

our industry specifically (e.g. plastic pollution or bioplastics vs. fossil-plastics) it did<br />

touch on the <strong>issue</strong> that goes far beyond – climate change, or I should rather say<br />

the climate crisis. The key message that Bill McKibben, author of the essay, tries to<br />

bring across is that we can switch from fossil to renewable energy right now – and<br />

that it would be cheaper long term to boot.<br />

Current geopolitical developments are more than proof that such a switch<br />

would be advisable. The war in Ukraine has sent shock waves through our global<br />

community, especially in “the West”. The incredible dependency on imported<br />

fossil fuels turned out to have a couple of pitfalls that many politicians (especially<br />

in Germany) only seem to realize now. The “easy and cheap” solution is now<br />

neither easy nor cheap. And European leaders scramble to fill their gas tanks,<br />

by swapping the dependency on Russia with a dependency on one or another<br />

potentially questionable big fossil-fuel exporter.<br />

Yet, I remain hopeful, or rather my hope is reawakening. Hope that this horrible<br />

war will be a catalyst that finally pushes renewables to the forefront. We need more<br />

renewable energy and we need more renewable materials – two industries that<br />

are often complementary. Resource independence is something that we should<br />

thrive for, not just because renewables are better for the climate, but because<br />

they offer a stabler economic environment. And just like with renewable energy<br />

that has become cheaper and cheaper over the years I am sure the same will hold true<br />

with bioplastics, given the chance. And I am not alone with this view, on page 44 Remy<br />

Jongboom shares his opinion on the fossil-fuel addiction and how to overcome it.<br />

This is not an addiction we’ll be able to cold turkey on, and fossil fuels will still play an<br />

important role in the coming years – the degree of that role is up for us to decide.<br />

Of course, this <strong>issue</strong> is not only philosophical excursions on why we should finally<br />

“go green”. We also have plenty of articles under our focus point of Additives &<br />

Masterbatches and our first On-site report after quite a while. Furthermore, our very<br />

own Editor in Chief tackled the topic of “plastics or no plastics” in our Basics section,<br />

albeit it might as well carry the label “Opinion”. Last but not least we also have a<br />

review of the esteemed bio!PAC conference (with the 7 th PLA World Congress already<br />

on the horizon), and many more stories big and small all around our little corner of the<br />

bioeconomy.<br />

And until we meet again in person, stay safe, fight the good fight, and cling to the<br />

hope that tomorrow will change for the better.<br />

Yours sincerely<br />

EcoComunicazione.it<br />

WWW.MATERBI.COM<br />

as orange peel<br />

adv arancia_bioplasticmagazine_01_<strong>02</strong>.2<strong>02</strong>0_210x297.indd 1 24/01/20 10:26<br />

r1_01.2<strong>02</strong>0<br />

bioplastics MAGAZINE Vol. 17<br />

Bioplastics - CO 2 -based Plastics - Advanced Recycling<br />

Basics<br />

Plastic or no plastic -<br />

that’s the question 50<br />

Highlights<br />

Thermoforming / Rigid packaging | 45<br />

Masterbatch / Additives | 24<br />

... is read in 92 countries<br />

... is read in 92 countries<br />

Follow us on twitter!<br />

www.twitter.com/bioplasticsmag<br />

<strong>02</strong> / 2<strong>02</strong>2<br />

ISSN 1862-5258 March/April<br />

Like us on Facebook!<br />

www.facebook.com/bioplasticsmagazine<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 3


Imprint<br />

Content<br />

34 Porsche launches cars with biocomposites<br />

32 Bacteriostatic PLA compound for 3D printingz<br />

Mar/Apr <strong>02</strong>|2<strong>02</strong>2<br />

Materials<br />

26 A new packaging solution for aerosols<br />

3 Editorial<br />

5 News<br />

38 Application News<br />

47 Basics<br />

48 Brand Owner<br />

49 10 years ago<br />

50 Suppliers Guide<br />

54 Companies in this <strong>issue</strong><br />

Publisher / Editorial<br />

Dr. Michael Thielen (MT)<br />

Alex Thielen (AT)<br />

Samuel Brangenberg (SB)<br />

Head Office<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach, Germany<br />

phone: +49 (0)2161 6884469<br />

fax: +49 (0)2161 6884468<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Media Adviser<br />

Samsales (German language)<br />

phone: +49(0)2161-6884467<br />

fax: +49(0)2161 6884468<br />

sb@bioplasticsmagazine.com<br />

Michael Thielen (English Language)<br />

(see head office)<br />

Layout/Production<br />

Michael Thielen<br />

Events<br />

10 7 th PLA World Congress<br />

12 4 th bio!PAC - Review<br />

CCU<br />

14 Melt spinning of CO 2<br />

-based<br />

thermoplastic polyurethanes<br />

16 Engineered bacteria upcycle<br />

carbon waste into commodity chemicals<br />

Advanced Recycling<br />

17 Enzymatic recycling technology for<br />

textile circularity<br />

18 Protective furniture packaging from<br />

pyrolysis oil<br />

19 Converting plastic waste into<br />

performance products<br />

Materials<br />

20 When Zero-Waste Meets 3D Printing<br />

22 There are no silver bullets<br />

but this one has a pretty shine<br />

24 100 % biobased surfactants and<br />

polyethylene glycols (PEGs)<br />

26 Plastics as CO 2<br />

sinks<br />

From Science & Research<br />

28 Self-cleaning bioplastics – the lotus effect<br />

Masterbatch / Additives<br />

30 Making the leap into a new era<br />

31 Let’s adopt the right BioHaviour<br />

32 Breakthrough for biobased HMDA<br />

33 New compostable mineral fillers<br />

& black masterbatches<br />

34 Unique antistatic ingredient for bioplastics<br />

36 Masterbatches for soil improvement<br />

Applications<br />

37 Home compostable<br />

3D printing filament<br />

On-Site<br />

42 Tecnaro<br />

Methodology<br />

46 Bioplastic Feedstock Alliance (BFA)<br />

– new guidance<br />

Opinion<br />

44 About reducing the fossil<br />

fuel addiction via compostables<br />

47 Plastic or nor plastic - that’s the question<br />

Print<br />

Poligrāfijas grupa Mūkusala Ltd.<br />

1004 Riga, Latvia<br />

bioplastics MAGAZINE is printed on<br />

chlorine-free FSC certified paper.<br />

bioplastics magazine<br />

Volume 17 - 2<strong>02</strong>2<br />

ISSN 1862-5258<br />

bM is published 6 times a year.<br />

This publication is sent to qualified subscribers<br />

(169 Euro for 6 <strong>issue</strong>s).<br />

bioplastics MAGAZINE is read in<br />

92 countries.<br />

Every effort is made to verify all Information<br />

published, but Polymedia Publisher<br />

cannot accept responsibility for any errors<br />

or omissions or for any losses that may<br />

arise as a result.<br />

All articles appearing in<br />

bioplastics MAGAZINE, or on the website<br />

www.bioplasticsmagazine.com are strictly<br />

covered by copyright. No part of this<br />

publication may be reproduced, copied,<br />

scanned, photographed and/or stored<br />

in any form, including electronic format,<br />

without the prior consent of the publisher.<br />

Opinions expressed in articles do not necessarily<br />

reflect those of Polymedia Publisher.<br />

bioplastics MAGAZINE welcomes contributions<br />

for publication. Submissions are<br />

accepted on the basis of full assignment<br />

of copyright to Polymedia Publisher GmbH<br />

unless otherwise agreed in advance and in<br />

writing. We reserve the right to edit items<br />

for reasons of space, clarity or legality.<br />

Please contact the editorial office via<br />

mt@bioplasticsmagazine.com.<br />

The fact that product names may not be<br />

identified in our editorial as trade marks<br />

is not an indication that such names are<br />

not registered trade marks.<br />

bioplastics MAGAZINE tries to use British<br />

spelling. However, in articles based on<br />

information from the USA, American<br />

spelling may also be used.<br />

Envelopes<br />

A part of this print run is mailed to the<br />

readers wrapped bioplastic envelopes<br />

sponsored by Sidaplax/Plastic Suppliers<br />

(Belgium/USA). Another part is sponsored<br />

by Minima Technology,Taiwan.<br />

Cover<br />

Shutterstock/AboutLife<br />

Follow us on twitter:<br />

http://twitter.com/bioplasticsmag<br />

Like us on Facebook:<br />

https://www.facebook.com/bioplasticsmagazine


TerraVerdae Bioworks<br />

to acquire PolyFerm<br />

Canada<br />

TerraVerdae Bioworks (Edmonton, AL, Canada)<br />

announced that it has signed a binding letter of<br />

intent to acquire 100 % of the equity of PolyFerm<br />

Canada.<br />

TerraVerdae is a world-leading performance<br />

biopolymers company.<br />

PolyFerm (Harrowsmith, ON, Canada) has<br />

a unique technology portfolio of biobased and<br />

biodegradable elastomeric polymers known as mcl<br />

PHAs. The addition of PolyFerm will strengthen<br />

TerraVerdae’s core capabilities and enhance the<br />

Company’s ability to produce biopolymers and<br />

resins for a wider range of applications, including<br />

for films, coatings, and adhesives.<br />

“The addition of PolyFerm’s capabilities and<br />

know-how represents a significant opportunity for<br />

TerraVerdae to advance new and valuable solutions<br />

to help the world develop sustainable plastic<br />

solutions that can reduce its carbon footprint”,<br />

said William Bardosh, CEO of TerraVerdae.<br />

As part of the acquisition, Bruce Ramsay,<br />

President of PolyFerm, will join the TerraVerdae<br />

team to help expand its PHA technology<br />

development programs. Ramsay is a recognized<br />

leader in the field of biobased elastomeric PHA<br />

technologies. With over 30 years of significant<br />

achievements, he has developed a unique<br />

intellectual property portfolio in medium chain<br />

length (mcl) PHA technologies.<br />

“I am very pleased to be joining one of the<br />

biopolymer industry’s leading product development<br />

teams”, said Bruce Ramsay. “And, I look forward to<br />

accelerating TerraVerdae’s development process<br />

with the exceptional resources available at the<br />

Company”.<br />

The transaction is anticipated to close in the<br />

second quarter of 2<strong>02</strong>2. AT/MT<br />

www.terraverdae.com | www.polyfermcanada.com<br />

Chinaplas postponed<br />

Trade fair organizer Adsale announced on March 18 that the<br />

CHINAPLAS, one of the world's leading plastics and rubber<br />

trade fairs and widely recognized by the industry as the most<br />

influential exhibitions next to the K fair, will be postponed.<br />

In view of the latest COVID development and the further<br />

tightening of the pandemic control measures in Shanghai and<br />

other provinces of China, and to protect the health and safety of<br />

all show participants as well as to ensure the best participation<br />

result for the exhibitors, it was decided that the 35 th Chinaplas,<br />

International Exhibition on Plastics and Rubber Industries,<br />

scheduled to be held from 25-28 April 2<strong>02</strong>2 at National Exhibition<br />

and Convention Center in Shanghai will be postponed. New dates<br />

and other details of the exhibition are not known yet but will be<br />

announced soon.<br />

The World Health Organization (WHO), announced that China<br />

had nearly 16,000 new cases within 24 hours around the date<br />

of Adsale’s announcement. The daily total number of cases has<br />

dropped by more than 50% though over a week's time. Other<br />

news reported the big industrial cities of Shenzhen, Changchun,<br />

Dongguan, Jilin City, and Langfang were completely shut down.<br />

Although the 35 th Chinaplas cannot be held as scheduled, the<br />

organisers assure that the promotion of companies and their<br />

products via their different online channels will continue. “CPS+<br />

eMarketplace” is ready and positioned to connect interested<br />

parties with buyers from China and overseas. AT<br />

https://www.chinaplasonline.com<br />

News<br />

daily updated News at<br />

www.bioplasticsmagazine.com<br />

Picks & clicks<br />

Most frequently clicked news<br />

Here’s a look at our most popular online content of the past two months.<br />

The story that got the most clicks from the visitors to bioplasticsmagazine.com was:<br />

tinyurl.com/news-2<strong>02</strong>20128<br />

Huntsman develops biobased polyurethane for<br />

Keen's plant-based soles<br />

(28 January 2<strong>02</strong>2)<br />

Footwear experts at Huntsman have helped Keen develop a breakthrough<br />

production innovation – a range of sneakers with plant-based soles. The<br />

Field to Foot (F2F) sneakers were created by Keen’s Advanced Concepts<br />

Team, utilizing a specially developed biobased polyurethane system from<br />

Huntsman that contains a by-product from agricultural processing.<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 5


News<br />

daily updated News at<br />

www.bioplasticsmagazine.com<br />

Sulzer PLA technology<br />

for China<br />

Sulzer has been awarded by Yangzhou Huitong<br />

Biological New Material to supply technology and key<br />

equipment for its polylactic acid (PLA) production facility<br />

in Jiangsu Province, China. The facility will have a<br />

production capacity of 30,000 tonnes per year.<br />

The plant will be able to produce a large portfolio<br />

of PLA grades serving a broad range of end-use<br />

applications from food packaging to kitchen utensils or<br />

toys. Replacing traditional plastics with non-fossil based<br />

plastics directly contributes to an improved carbon<br />

footprint.<br />

The versatility of Sulzer’s PLA technology allows the<br />

production of a large range of molecular weights and<br />

stereoisomer ratios while meeting product high-quality<br />

standards.<br />

To meet Yangzhou Huitong Biological New Material’s<br />

requirements, Sulzer Chemtech will design and provide<br />

its lactide purification, polymerization, devolatilization<br />

and post-reaction proprietary technologies. The<br />

licensing agreement framework also includes extensive<br />

service support from engineering to technical assistance<br />

and field services. Sulzer Chemtech was selected for its<br />

proven track record as market leader, delivering scalable<br />

production solutions with both improved efficiency and<br />

quality for the production of PLA.<br />

Zhang JianGang, President of Yangzhou Huitong<br />

Biological New Material, adds: “This new facility will<br />

allow us to enter the fast-growing bioplastic market.<br />

We consider Sulzer an extremely valuable partner in<br />

this project. The company’s comprehensive technical<br />

services and cutting-edge production technologies<br />

for PLA will help us to effectively produce sustainable<br />

plastics and meet our customers’ strategic demands”.<br />

Torsten Wintergerste, Division President of Sulzer<br />

Chemtech, comments: “We are excited to support<br />

Yangzhou Huitong Biological New Material in their<br />

flagship project. Our PLA technologies are currently used<br />

in most PLA facilities worldwide. We couldn’t be prouder<br />

to be supporting customers with monomer purification<br />

and polymer production units that are helping advance<br />

the sustainable and circular plastics sector”. MT<br />

www.sulzer.com<br />

The Bioplastics Award<br />

is facing new<br />

horizons<br />

After 15 editions of the Global<br />

Bioplastics Award, the last 11<br />

hosted by bioplastics MAGAZINE,<br />

this prestigious prize is now<br />

facing new horizons.<br />

bioplastics MAGAZINE decided to<br />

discontinue this award. Instead,<br />

after pausing for one year,<br />

European Bioplastics will come<br />

up with a new edition of the<br />

award in 2<strong>02</strong>3.<br />

Of course, bioplastics MAGAZINE<br />

will continue to report about<br />

nominees and winners. So stay<br />

tuned. MT<br />

Plant-derived<br />

ethylene & propylene<br />

Mitsubishi Chemical Corporation (Tokyo, Japan) and<br />

Toyota Tsusho Corporation (Nagoya, Japan) have begun<br />

a joint consideration to manufacture and sale ethylene,<br />

propylene, and their derivatives using bioethanol as raw<br />

material, with an aim to commence operation in 2<strong>02</strong>5.<br />

There is a growing need for plastic reuse and recycling to<br />

achieve the realization of a sustainable recycling-oriented<br />

society. There are also strong expectations for realizing a<br />

sustainable life cycle by using plant-derived materials.<br />

MCC and Toyota Tsusho are working on the<br />

commercialization of various recycling processes and<br />

aim to realize a recycling-oriented society by switching<br />

from raw materials derived from fossil fuels to plantderived<br />

materials.<br />

In order to make a wide range of products more<br />

sustainable, including products that are generally difficult<br />

to collect and recycle among packaging/containers and<br />

sanitary goods, both companies have decided to examine<br />

how to commercialize the manufacture and sale of<br />

ethylene, propylene, and their derivatives made from<br />

plant-derived raw materials.<br />

MCC and Toyota Tsusho will evaluate the manufacture<br />

of 100 % plant-derived ethylene (bioethylene) and<br />

its derivatives using bioethanol as raw material,<br />

and the manufacture and sale of the first plantderived<br />

propylene in Japan (biopropylene) and its<br />

derivatives using bioethylene as its raw material. AT<br />

www.m-chemical.co.jp | www.toyota-tsusho.com/english/<br />

6 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


Global treaty targeting plastic pollution<br />

Heads of State, Ministers of environment and other representatives from 175 nations endorsed a historic resolution at the UN<br />

Environment Assembly (UNEA-5) on the 2 nd of March 2<strong>02</strong>2 in Nairobi (Kenia) to End Plastic Pollution and forge an international legally<br />

binding agreement by 2<strong>02</strong>4. The resolution addresses the full lifecycle of plastic, including its production, design, and disposal.<br />

The resolution, based on three initial draft resolutions from various nations, establishes an Intergovernmental Negotiating<br />

Committee (INC), which will begin its work in 2<strong>02</strong>2, with the ambition of completing a draft global legally binding agreement by the<br />

end of 2<strong>02</strong>4. It is expected to present a legally binding instrument, which would reflect diverse alternatives to address the full lifecycle<br />

of plastics, the design of reusable and recyclable products and materials, and the need for enhanced international collaboration to<br />

facilitate access to technology, capacity building and scientific and technical cooperation.<br />

The UN Environment Programme (UNEP) will convene a forum by the end of 2<strong>02</strong>2 that is open to all stakeholders in conjunction<br />

with the first session of the INC, to share knowledge and best practices in different parts of the world. It will facilitate open discussions<br />

and ensure they are informed by science, reporting on progress throughout the next two years. Finally, upon completion of the INC’s<br />

work, UNEP will convene a diplomatic conference to adopt its outcome and open it for signatures.<br />

“Today marks a triumph by planet earth over single-use plastics. This is the most significant environmental multilateral deal since<br />

the Paris accord. It is an insurance policy for this generation and future ones, so they may live with plastic and not be doomed by it”.<br />

“Let it be clear that the INC’s mandate does not grant any stakeholder a two-year pause. In parallel to negotiations over an<br />

internationally binding agreement, UNEP will work with any willing government and business across the value chain to shift away<br />

from single-use plastics, as well as to mobilise private finance and remove barriers to investments in research and in a new circular<br />

economy”, said Inger Andersen, Executive Director of UNEP.<br />

Plastic production soared from 2 million tonnes in 1950 to 348 million tonnes in 2017, becoming a global industry valued at USD<br />

522.6 billion, and it is expected to double in capacity by 2040. The impacts of plastic production and pollution on the triple planetary<br />

crisis of climate change, nature loss and pollution are a catastrophe in the making.<br />

The historic resolution, titled “End Plastic Pollution: Towards an internationally legally binding instrument” was adopted with the<br />

conclusion of the three-day UNEA-5.2 meeting, attended by more than 3,400 in-person and 1,500 online participants from 175 UN<br />

Member States, including 79 ministers and 17 high-level officials. AT<br />

https://www.unep.org<br />

News<br />

daily updated News at<br />

www.bioplasticsmagazine.com<br />

We design colors with a purpose to allow our<br />

planet to remain as colorful today and tomorrow.<br />

Our SUKANO® PHA color Portfolio, designed for direct food contact, available for industrially<br />

and home compostable applications and allows soil and marine biodegradability.<br />

Formulated to your needs and requirements.<br />

www.sukano.com<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 7


News<br />

daily updated News at<br />

www.bioplasticsmagazine.com<br />

PHA production capacity to increase tenfold<br />

A new market report “Mimicking Nature – The PHA Industry Landscape. Latest trends and 28 producer profiles” was recently<br />

published by GO!PHA and nova-Institute.<br />

Natural PHAs are a class of materials that exist in nature for millions of years. These materials are both biobased and<br />

biodegradable, similar to other natural materials such as cellulose, proteins, and starch. Natural PHAs are produced by<br />

an extensive variety of microorganisms through bacterial fermentation. Due to its high performance, biocompatibility,<br />

biodegradability, and green credentials, the PHA family has a large design space and accommodates a wide range of market<br />

applications, as a broad variety of different polymers can be produced and blended. The potential of PHAs is enormous.<br />

Natural PHAs have been intensively researched for many years and many hopes for more environmentally friendly polymers<br />

are based on these PHAs. There have been highs and lows over the last 20 years, several expansions and scale-up plans have<br />

been postponed or even cancelled. A few reasons for that were the challenges of technology scale-up, product and application<br />

development needs, an underestimation of how much time it takes for a new polymer-platform to penetrate the market, and<br />

the time it takes for previously unconnected disciplines to understand each other for the benefit of successfully addressing all<br />

opportunities. But now, the momentum for this new polymer platform is rapidly changing for the better.<br />

At the end of 2<strong>02</strong>1, there was an installed manufacturing capacity of about 48,000 tonnes per up and running, based on the<br />

information from the companies described in the market report “Mimicking Nature – The PHA Industry Landscape. Latest<br />

trends and 28 producer profiles”. Capacity expansions have been announced and there are numerous plants under construction.<br />

Together, the manufacturers aim for a manufacturing capacity of about 570,000 tonnes per annum by 2<strong>02</strong>7.<br />

Developing new products to create a sustainable future for polymers, respecting the environment and our future generations<br />

is the motivation for most parties working on this new materials platform. They are in tune with a rapidly changing plastics<br />

industry. Most companies portrayed in the market report are/were start-ups when they began their natural PHA activities. Only<br />

six companies are already established in the market. The report is a must-read for all those interested in the very latest in<br />

PHAs, as developers, producers or, above all, users. The information on the companies described has been checked with each<br />

of them and is state-of-the-art for February 2<strong>02</strong>2.<br />

The Author of “Mimicking Nature” is Jan Ravenstijn, who has been working intensively on the topic of PHAs for 20 years,<br />

is the author of numerous publications and co-founder of the Global Organization for PHA, GO!PHA. The report is a joint<br />

publication of GO!PHA and nova-Institute.<br />

“Mimicking Nature – The PHA Industry Landscape. Latest trends and 28 producer profiles” is available at www.renewablecarbon.eu/publications<br />

starting at EUR 1,500” (see also p. 9). AT<br />

www.nova-institute.eu | www.gopha.org<br />

ECO profile of PLA available to product designers<br />

To support designers TotalEnergies Corbion (Gorinchem,<br />

The Netherlands) has enabled Sphera’s Product<br />

Sustainability (formerly GaBi) database users to access the<br />

Luminy ® PLA ecological product profile. The ECO profile<br />

allows designers to quantify the environmental impact of<br />

PLA in product design and production choosing Luminy PLA.<br />

Sphera’s Product Sustainability software is the world's<br />

leading Life Cycle Assessment (LCA) modelling and<br />

reporting software with intuitive data collection and result<br />

analytics. LCA is a scientific-based technique that allows<br />

optimizing the environmental impact of a product, through a<br />

comprehensive assessment of its lifecycle. From extraction<br />

of a raw material to its disposal or preparation for reuse,<br />

all relevant environmental impacts are considered, as far<br />

as quantifiable. Sphera’s Product Sustainability database<br />

has by far the largest Lifecycle Inventory (LCI) data industry<br />

coverage worldwide. Also, regionalized water and land use<br />

data are included throughout.<br />

“The detailed analysis of scenarios in the production and<br />

end-of-life phase enables our customers to choose the<br />

most sustainable solution for their products. Making our<br />

LCA data available in the leading databases will give access<br />

to our data to every Sphera LCA Software user globally. All<br />

users will be able to add our data to their own modelling to<br />

complete their view on the environmental impacts of their<br />

supply chain”, says François de Bie, Senior Marketing and<br />

Supply Chain Director at TotalEnergies Corbion. He adds<br />

“now producers and brand owners are quickly able to quantify<br />

the Green House Gas emissions saving that a conversion<br />

to biobased Luminy PLA will bring for their products. Such<br />

‘cradle to grave’ analyses are helpful to comply with the<br />

latest EU Taxonomy regulations and allow brand owners to<br />

make credible claims about the CO 2<br />

reductions”.<br />

Informed decision-making in production, setup and<br />

design will contribute to achieving sustainability goals<br />

across industries. Sphera’s Product Sustainability<br />

databases provide explicit knowledge of the product’s<br />

environmental performance through scenario analysis. This<br />

is an important tool to meet today’s market expectations<br />

and for the contribution of product designers to tackling<br />

environmental concerns. TotalEnergies Corbion believes in<br />

an unbiased and transparent reporting of the environmental<br />

impact of its PLA resins. MT<br />

www.totalenergies-corbion.com | www.sphera.com<br />

8 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


All figures available at www.bio-based.eu/markets<br />

Adipic acid (AA)<br />

11-Aminoundecanoic acid (11-AA)<br />

1,4-Butanediol (1,4-BDO)<br />

Dodecanedioic acid (DDDA)<br />

Epichlorohydrin (ECH)<br />

Ethylene<br />

Furan derivatives<br />

D-lactic acid (D-LA)<br />

L-lactic acid (L-LA)<br />

Lactide<br />

Monoethylene glycol (MEG)<br />

Monopropylene glycol (MPG)<br />

Naphtha<br />

1,5-Pentametylenediamine (DN5)<br />

1,3-Propanediol (1,3-PDO)<br />

Sebacic acid<br />

Succinic acid (SA)<br />

© -Institute.eu | 2<strong>02</strong>0<br />

fossil<br />

available at www.renewable-carbon.eu/graphics<br />

Refining<br />

Polymerisation<br />

Formulation<br />

Processing<br />

Use<br />

renewable<br />

Depolymerisation<br />

Solvolysis<br />

Thermal depolymerisation<br />

Enzymolysis<br />

Purification<br />

Dissolution<br />

Recycling<br />

Conversion<br />

Pyrolysis<br />

Gasification<br />

allocated<br />

Recovery<br />

Recovery<br />

Recovery<br />

conventional<br />

© -Institute.eu | 2<strong>02</strong>1<br />

© -Institute.eu | 2<strong>02</strong>0<br />

PVC<br />

EPDM<br />

PP<br />

PMMA<br />

PE<br />

Vinyl chloride<br />

Propylene<br />

Unsaturated polyester resins<br />

Methyl methacrylate<br />

PEF<br />

Polyurethanes<br />

MEG<br />

Building blocks<br />

Natural rubber<br />

Aniline Ethylene<br />

for UPR<br />

Cellulose-based<br />

2,5-FDCA<br />

polymers<br />

Building blocks<br />

for polyurethanes<br />

Levulinic<br />

acid<br />

Lignin-based polymers<br />

Naphtha<br />

Ethanol<br />

PET<br />

PFA<br />

5-HMF/5-CMF FDME<br />

Furfuryl alcohol<br />

Waste oils<br />

Casein polymers<br />

Furfural<br />

Natural rubber<br />

Saccharose<br />

PTF<br />

Starch-containing<br />

Hemicellulose<br />

Lignocellulose<br />

1,3 Propanediol<br />

polymer compounds<br />

Casein<br />

Fructose<br />

PTT<br />

Terephthalic<br />

Non-edible milk<br />

acid<br />

MPG NOPs<br />

Starch<br />

ECH<br />

Glycerol<br />

p-Xylene<br />

SBR<br />

Plant oils<br />

Fatty acids<br />

Castor oil<br />

11-AA<br />

Glucose Isobutanol<br />

THF<br />

Sebacic<br />

Lysine<br />

PBT<br />

acid<br />

1,4-Butanediol<br />

Succinic<br />

acid<br />

DDDA<br />

PBAT<br />

Caprolactame<br />

Adipic<br />

acid<br />

HMDA DN5<br />

Sorbitol<br />

3-HP<br />

Lactic<br />

acid<br />

Itaconic<br />

Acrylic<br />

PBS(x)<br />

acid<br />

acid<br />

Isosorbide<br />

PA<br />

Lactide<br />

Superabsorbent polymers<br />

Epoxy resins<br />

ABS<br />

PHA<br />

APC<br />

PLA<br />

available at www.renewable-carbon.eu/graphics<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

OH<br />

O<br />

OH<br />

HO<br />

OH<br />

HO<br />

OH<br />

O<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

■<br />

OH<br />

HO<br />

OH<br />

O<br />

OH<br />

O<br />

© -Institute.eu | 2<strong>02</strong>1<br />

nova Market and Trend Reports<br />

on Renewable Carbon<br />

The Best Available on Bio- and CO2-based Polymers<br />

& Building Blocks and Chemical Recycling<br />

Mimicking Nature –<br />

The PHA Industry Landscape<br />

Latest trends and 28 producer profiles<br />

Bio-based Naphtha<br />

and Mass Balance Approach<br />

Status & Outlook, Standards &<br />

Certification Schemes<br />

Bio-based Building Blocks and<br />

Polymers – Global Capacities,<br />

Production and Trends 2<strong>02</strong>0–2<strong>02</strong>5<br />

Polymers<br />

News<br />

daily updated News at<br />

www.bioplasticsmagazine.com<br />

Principle of Mass Balance Approach<br />

Feedstock<br />

Process<br />

Products<br />

Use of renewable feedstock<br />

in very first steps of<br />

chemical production<br />

(e.g. steam cracker)<br />

Utilisation of existing<br />

integrated production for<br />

all production steps<br />

Allocation of the<br />

renewable share to<br />

selected products<br />

Author: Jan Ravenstijn<br />

March 2<strong>02</strong>2<br />

This and other reports on renewable carbon are available at<br />

www.renewable-carbon.eu/publications<br />

Authors: Michael Carus, Doris de Guzman and Harald Käb<br />

March 2<strong>02</strong>1<br />

This and other reports on renewable carbon are available at<br />

www.renewable-carbon.eu/publications<br />

Authors: Pia Skoczinski, Michael Carus, Doris de Guzman,<br />

Harald Käb, Raj Chinthapalli, Jan Ravenstijn, Wolfgang Baltus<br />

and Achim Raschka<br />

January 2<strong>02</strong>1<br />

This and other reports on renewable carbon are available at<br />

www.renewable-carbon.eu/publications<br />

Carbon Dioxide (CO 2) as Chemical<br />

Feedstock for Polymers<br />

Technologies, Polymers, Developers and Producers<br />

Chemical recycling – Status, Trends<br />

and Challenges<br />

Technologies, Sustainability, Policy and Key Players<br />

Plastic recycling and recovery routes<br />

Production of Cannabinoids via<br />

Extraction, Chemical Synthesis<br />

and Especially Biotechnology<br />

Current Technologies, Potential & Drawbacks and<br />

Future Development<br />

Virgin Feedstock<br />

Renewable Feedstock<br />

Plant extraction<br />

Chemical synthesis<br />

Monomer<br />

Secondary<br />

valuable<br />

materials<br />

Chemicals<br />

Fuels<br />

Others<br />

Cannabinoids<br />

Polymer<br />

Primary recycling<br />

(mechanical)<br />

Plastic<br />

Product<br />

Secondary recycling<br />

(mechanical)<br />

Tertiary recycling<br />

(chemical)<br />

CO 2 capture<br />

Genetic engineering<br />

Plant extraction<br />

Biotechnological production<br />

Product (end-of-use)<br />

Quaternary recycling<br />

(energy recovery)<br />

Energy<br />

Landfill<br />

Authors: Pauline Ruiz, Achim Raschka, Pia Skoczinski,<br />

Jan Ravenstijn and Michael Carus, nova-Institut GmbH, Germany<br />

January 2<strong>02</strong>1<br />

This and other reports on renewable carbon are available at<br />

www.renewable-carbon.eu/publications<br />

Author: Lars Krause, Florian Dietrich, Pia Skoczinski,<br />

Michael Carus, Pauline Ruiz, Lara Dammer, Achim Raschka,<br />

nova-Institut GmbH, Germany<br />

November 2<strong>02</strong>0<br />

This and other reports on the bio- and CO 2-based economy are<br />

available at www.renewable-carbon.eu/publications<br />

Authors: Pia Skoczinski, Franjo Grotenhermen, Bernhard Beitzke,<br />

Michael Carus and Achim Raschka<br />

January 2<strong>02</strong>1<br />

This and other reports on renewable carbon are available at<br />

www.renewable-carbon.eu/publications<br />

Commercialisation updates on<br />

bio-based building blocks<br />

Levulinic acid – A versatile platform<br />

chemical for a variety of market applications<br />

Global market dynamics, demand/supply, trends and<br />

market potential<br />

Succinic acid – From a promising<br />

building block to a slow seller<br />

What will a realistic future market look like?<br />

Production capacities (million tonnes)<br />

Bio-based building blocks<br />

Evolution of worldwide production capacities from 2011 to 2<strong>02</strong>4<br />

4<br />

3<br />

2<br />

1<br />

2011 2012 2013 2014 2015 2016 2017 2018 2019 2<strong>02</strong>4<br />

OH<br />

OH<br />

O<br />

HO<br />

diphenolic acid<br />

O<br />

H 2N<br />

OH<br />

O<br />

5-aminolevulinic acid<br />

O<br />

O<br />

OH<br />

O O<br />

levulinate ketal<br />

O<br />

OH<br />

O<br />

levulinic acid<br />

O<br />

OR<br />

O<br />

levulinic ester<br />

O<br />

O<br />

ɣ-valerolactone<br />

O<br />

HO<br />

OH<br />

O<br />

succinic acid<br />

H<br />

N<br />

O<br />

5-methyl-2-pyrrolidone<br />

Pharmaceutical/Cosmetic<br />

Acidic ingredient for denture cleaner/toothpaste<br />

Antidote<br />

Calcium-succinate is anticarcinogenic<br />

Efferescent tablets<br />

Intermediate for perfumes<br />

Pharmaceutical intermediates (sedatives,<br />

antiphlegm/-phogistics, antibacterial, disinfectant)<br />

Preservative for toiletries<br />

Removes fish odour<br />

Used in the preparation of vitamin A<br />

Food<br />

Bread-softening agent<br />

Flavour-enhancer<br />

Flavouring agent and acidic seasoning<br />

in beverages/food<br />

Microencapsulation of flavouring oils<br />

Preservative (chicken, dog food)<br />

Protein gelatinisation and in dry gelatine<br />

desserts/cake flavourings<br />

Used in synthesis of modified starch<br />

Succinic<br />

Acid<br />

Industrial<br />

De-icer<br />

Engineering plastics and epoxy curing<br />

agents/hardeners<br />

Herbicides, fungicides, regulators of plantgrowth<br />

Intermediate for lacquers + photographic chemicals<br />

Plasticizer (replaces phtalates, adipic acid)<br />

Polymers<br />

Solvents, lubricants<br />

Surface cleaning agent<br />

(metal-/electronic-/semiconductor-industry)<br />

Other<br />

Anodizing Aluminium<br />

Chemical metal plating, electroplating baths<br />

Coatings, inks, pigments (powder/radiation-curable<br />

coating, resins for water-based paint,<br />

dye intermediate, photocurable ink, toners)<br />

Fabric finish, dyeing aid for fibres<br />

Part of antismut-treatment for barley seeds<br />

Preservative for cut flowers<br />

Soil-chelating agent<br />

Author:<br />

Doris de Guzman, Tecnon OrbiChem, United Kingdom<br />

Updated Executive Summary and Market Review May 2<strong>02</strong>0 –<br />

Originally published February 2<strong>02</strong>0<br />

This and other reports on the bio- and CO 2-based economy are<br />

available at www.bio-based.eu/reports<br />

Authors: Achim Raschka, Pia Skoczinski, Raj Chinthapalli,<br />

Ángel Puente and Michael Carus, nova-Institut GmbH, Germany<br />

October 2019<br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Authors: Raj Chinthapalli, Ángel Puente, Pia Skoczinski,<br />

Achim Raschka, Michael Carus, nova-Institut GmbH, Germany<br />

October 2019<br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

renewable-carbon.eu/publications<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 9


ioplastics MAGAZINE presents:<br />

7 th PLA World Congress<br />

24 + 25 MAY 2<strong>02</strong>2 > MUNICH > GERMANY<br />

The PLA World Congress in Munich/Germany, organised by bioplastics MAGAZINE<br />

now for the 7 th time, is the must-attend conference for everyone interested in PLA,<br />

its benefits, and challenges. The global conference offers high-class presentations<br />

from top individuals in the industry from Europe, USA, Thailand, and more. There<br />

will also be excellent networking opportunities along with a table top exhibition.<br />

More details, programme updates and a registration form can be found on the<br />

conference website.<br />

Together with the Holiday Inn Munich City Centre we’ll elaborate a suitable<br />

hygiene concept for the conference. For those who cannot travel due to Corona<br />

restrictions, we’ll offer online access to the event. Stay tuned.<br />

7 th PLA World Congress, preliminary programme<br />

For updates vitis www.pla-world-congress.com<br />

www.pla-world-congress.com<br />

Remy Jongboom, Biotec<br />

Oliver Buchholz, European Bioplastics<br />

Udo Mühlbauer, Uhde Inventa-Fischer<br />

Sebastian Körber, Fraunhofer ICT<br />

Francois de Bie, TotalEnergies Corbion<br />

Andrew Gill, Floreon / Clariant<br />

Patrick Gerritsen, Bio4Pack<br />

Lien Van der Schueren, Centexbel<br />

Ramani Narayan<br />

Kevin Yang, Shenzhen Esun Industrial Co<br />

Keynote Speech: The fossil addiction and bioplastics (t.b.c.)<br />

Policy and market information<br />

Lactic Acid and Lactide Technology by Uhde Inventa-Fischer<br />

Development of High-Temperature Resistant Stereocomplex PLA<br />

for Injection Moulding<br />

PLA capacity and recycling (t.b.c.)<br />

Floreon: Redefining PLA<br />

Current market reaction on PLA<br />

PLA melt spinning, coating and printing for fully biobased clothing<br />

Reviewing the science around biodegradability and (home) compostability of PLA<br />

Application and Recycling of PLA<br />

Nopadol Suanprasert, Global Biopolymers Biocomposites of PLA/natural rubber/fiber<br />

Frédéric van Gansberghe, Galactic<br />

Gregory Coué, Kompuestos (t.b.c.)<br />

Zsolt Bodnar, Filaticum<br />

Kerstin Müller, Fraunhofer IVV<br />

Michael Thielen, bioplastics MAGAZINE<br />

Panel discussion<br />

Chemical Recycling of PLA<br />

Masterbatches for PLA (t.b.c.)<br />

Composite 3D printing filaments<br />

PLA in current Research Projects: Material Development -<br />

Packaging Applications – Recycling<br />

Plastic or no plastic — that's the question<br />

Market development of PLA<br />

Subject to changes. We still have a few speaking slots available.<br />

Especially if speakers cannot travel due to Corona restrictions, we might have to swap<br />

speakers due to time zone differences.<br />

Please visit the conference website regularly.<br />

10 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


한국포장협회로고.ps 2016.11.21 8:26 PM 페이지1 MAC-18<br />

Register now!<br />

7 th PLA World Congress<br />

24 + 25 MAY 2<strong>02</strong>2 > MUNICH > GERMANY<br />

HYBRID EVENT<br />

organized by<br />

www.pla-world-congress.com<br />

PLA is a versatile bioplastics raw material from renewable<br />

resources. It is being used for films and rigid packaging, for<br />

fibres in woven and non-woven applications. Automotive,<br />

consumer electronics, and other industries are thoroughly<br />

investigating and even already applying PLA. New methods<br />

of polymerizing, compounding, or blending of PLA have<br />

broadened the range of properties and thus the range of<br />

possible applications. That‘s why bioplastics MAGAZINE is<br />

now organizing the 7 th PLA World Congress on:<br />

24 + 25 May 2<strong>02</strong>2 in Munich / Germany<br />

Experts from all involved fields will share their knowledge<br />

and contribute to a comprehensive overview of today‘s<br />

opportunities and challenges and discuss the possibilities,<br />

limitations, and future prospects of PLA for all kinds<br />

of applications. Like the five previous congresses, the<br />

7 th PLA World Congress will also offer excellent networking<br />

opportunities for all delegates and speakers as well as<br />

exhibitors of the table-top exhibition. Based on the good<br />

experience with the hybrid format (bio!TOY and PHA World<br />

Congress 2<strong>02</strong>1) we will offer this format also for future<br />

conferences, hoping the pandemic does no longer force us<br />

to. So participation at the 7 th PLA World Congress will be<br />

possible on-site as well as online.<br />

Media Partner<br />

Gold Sponsor:<br />

organized by<br />

Silver Sponsor:<br />

KOREA PACKAGING ASSOCIATION INC.<br />

Supported by:<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 11


Automotive Events<br />

bio!PAC 2<strong>02</strong>2<br />

To unlock the potential of<br />

bioplastics recycling routes<br />

T<br />

he 4 th conference on bioplastics and packaging, the<br />

bio!PAC 2<strong>02</strong>2, had a strong focus on unlocking the<br />

potential of different routes for the recyclability of<br />

bioplastics. Next to that, preventing the accumulation of<br />

microplastics, the environmental benefits of biodegradable<br />

packaging, and the developments of new packaging<br />

applications were very prominent on the agenda.<br />

The international speakers’ line-up consisted of 27<br />

speakers from industry, knowledge institutions, and brand<br />

owners. About 100 participants from 18 countries from all<br />

over the world were represented. The presentations provided<br />

the participants with the most up-to-date information<br />

to be able to evaluate the possibilities and challenges of<br />

packaging based on bioplastics. The conference was held<br />

online on 15 th and 16 th March 2<strong>02</strong>2.<br />

Recycling routes<br />

“To process all our plastic waste, we need all the different<br />

end-of-life options”, said Erwin Vink from NatureWorks<br />

in his presentation ‘The compostables Project’. He<br />

demonstrated that the problems are much bigger than just<br />

handling plastic waste but also gave guidance for what is<br />

needed to implement a successful composting system. His<br />

arguments were also confirmed by other speakers such as<br />

expert Bruno de Wilde of Organic Waste Systems (OWS).<br />

A new technique of bioplastics recycling was presented<br />

by Jan Pels, senior scientist at TNO. He is the developer<br />

of Torwash and demonstrated that this technology enables<br />

selective removal of biodegradables like PLA or PHA from<br />

contaminated waste streams and multilayer packaging by<br />

depolymerizing them to their original monomers. These<br />

monomers can be used again to make food approved virgin<br />

plastics. This allows full recycling, not down-cycling.<br />

Political influence on bioplastics<br />

“Nature is much better at recycling than humans”,<br />

said Remy Jongboom from Biotec in his presentation on<br />

the added value of compostable materials in packaging<br />

applications. He also pointed out what the current war<br />

between Ukraine and Russia can mean for the supply of<br />

fossil resources and how we should consider using biogas<br />

through anaerobic digestion as a supplement. “Biogas can<br />

also provide secured energy supply in comparison with wind<br />

and solar”. His presentation was overall a strong argument<br />

for resource independence that biobased and biodegradable<br />

materials can offer (see also page 44).<br />

Microplastics & Packaging<br />

“Mechanical or chemical recycling will not prevent<br />

microplastic problems. It is therefore crucial that policy<br />

guidelines recognize the benefits of biodegradable and<br />

biobased materials and provide a level playing field for<br />

all sustainable forms of carbon, including organically and<br />

chemically recycled carbon”, said Heidi Koljonen from<br />

12 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


By:<br />

Caroli Buitenhuis<br />

Green Serendipity<br />

Amsterdam, The Netherlands<br />

Automotive<br />

Sulapac in Finland. Sulapac developed luxury jar lids<br />

for Chanel, based on FSC certified wood chips that are<br />

by-products of industrial side-streams combined, upon<br />

Chanel’s request, with upcycled camellia seed shells.<br />

Leaving no microplastics behind.<br />

Packaging developments<br />

In his presentation on barrier materials for food<br />

packaging, Peter Ragaert, director at Pack4Food<br />

and professor of food packaging technology at Ghent<br />

University, demonstrated the outcomes of bioplastics<br />

barrier and shelf life projects. There were some<br />

surprising outcomes like there is no significant<br />

difference between the PET tray for meat packaging and<br />

a tray based on PHA (PHBV). The first results showed<br />

that the gas barrier properties of the PHBV tray were<br />

even a bit higher than the PET tray. His conclusion was:<br />

“For meat packaging, PHBV performed in the tests the<br />

same as PET”.<br />

Johann Zimmermann of NaKu demonstrated an<br />

innovative cartridge based on PLA for a cosmetics<br />

packaging which allows very precise dispensing of<br />

cream per use. For this development Naku teamed<br />

up with a cosmetics company to develop the reusable<br />

packaging (see also page 41).<br />

A biobased multilayer packaging foil based on sidestream<br />

starches and biobased PE is developed by<br />

Rodenburg Biopolymers. It is a three layers foil with<br />

the possibility to regulate the OTR and WVTR to keep<br />

fruits and vegetables fresh, to expand their shelf life and<br />

prevent food losses. “Test results show that lettuce stays<br />

fresh longer, sugar snaps stay crunchy longer”, said<br />

Thijs Rodenburg, CEO of the company.<br />

The bio!PAC takes place every two years and is<br />

organized by bioplastics MAGAZINE in collaboration with<br />

Green Serendipity. This year’s bio!PAC was a 100 %<br />

digital event, hopefully soon live events will become<br />

the norm again, but as the recent postponement of the<br />

Chinaplas showed – corona is not over yet.<br />

And in case you missed the conference, you can still<br />

get access to all presentations via video on demand. Just<br />

contact mt@bioplasticsmagazine.com.<br />

www.bio-pac.info<br />

Join us at the<br />

17th European<br />

Bioplastics Conference<br />

– the leading business forum for the<br />

bioplastics industry.<br />

REGISTER<br />

NOW!<br />

6/7 December 2<strong>02</strong>2<br />

Maritim proArte Hotel<br />

Berlin, Germany<br />

@EUBioplastics #eubpconf2<strong>02</strong>2<br />

www.european-bioplastics.org/events<br />

For more information email:<br />

conference@european-bioplastics.org<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 13


CCU<br />

Melt spinning of CO 2<br />

-based<br />

thermoplastic polyurethanes<br />

An environmentally friendly approach for the production of elastic yarns<br />

T<br />

he market of elastic yarns has grown massively over<br />

the past years, mainly driven by applications in apparel,<br />

sports, and medical textiles. For example, approx. 80 %<br />

of all currently circulated apparel textiles contain elastic yarns<br />

to provide stretch and comfort. Most of these elastic yarns are<br />

produced by dry spinning of thermoset polyurethanes (PU)<br />

which causes specific challenges: Production is slow as well<br />

as expensive and potentially hazardous solvents have to be<br />

used. These challenges may be overcome by switching from<br />

dry to melt spinning processes. Thermoplastic polyurethanes<br />

(TPU) fulfil the needs of high elasticity and melt spinnability.<br />

Additionally, the greenhouse gas CO 2<br />

can be used as one of<br />

the resources for TPU production. By this, “Carbon Capture<br />

and Utilization” (CCU) can be applied to the textile industry.<br />

Motivation: CCU, High Economic Efficiency and<br />

Improved Processability<br />

TPU are linear and basically structured in hard and soft<br />

segments. Soft segments are typically polyols while hard<br />

segments are composed of isocyanates and a chain extender<br />

[1, 2]. There are three major categories of polyols being<br />

applied: polyether, polyester, and polycarbonate polyols [3].<br />

Specific polyols offer a huge potential for increasing the<br />

sustainability of TPU. Over the past years and decades, large<br />

efforts have been made to enable the use of renewable<br />

materials for (thermoplastic) PU production. For example,<br />

biobased polyols have been derived from vegetable oils [4, 5].<br />

Besides these biobased approaches, the incorporation of CO 2<br />

as a resource is eligible for the production of polyols. Covestro<br />

AG (Leverkusen, Germany) has developed a process for the<br />

production of polyether-polycarbonate PU, based on CO 2<br />

containing polyols. The technology involves the reaction of<br />

epoxide with CO 2<br />

under the application of selective catalysts. [6]<br />

Figure 1: Mission Statement of “CO2Tex”<br />

The approach of Carbon Capture and Utilization (CCU) does<br />

not only provide the opportunity for the circulation of CO 2<br />

with positive environmental aspects but also offers economic<br />

advantages. Allied Market Research (Portland, Oregon, USA),<br />

estimated the market volume of elastic filaments to be USD<br />

10.5 billion in 2<strong>02</strong>2, starting from USD 5.8 billion in 2015. This<br />

corresponds to a CAGR of 8.8 % over the past seven years. [7]<br />

Roughly 80 % of this market is currently being supplied by<br />

dry-spun yarns, whose production requires the use of solvents<br />

such as dimethylformamide (DMF) [8, 9]. Melt-spun CO 2<br />

-based<br />

TPU-filaments can be expected to be 50 to 60 % lower in price<br />

than conventional solution-spun PU filaments [10]. The main<br />

reasons for this economic advantage can be found in processes<br />

as well as facilities. Generally, lower winding speeds of 500 to<br />

2,000 m/min can be achieved in dry spinning in comparison<br />

to up to 6,000 m/min in melt spinning [11]. For TPU, melt<br />

spinning processes with a winding speed of 2,500 m/min<br />

have already been developed on pilot scale [10]. Additionally,<br />

solvent evaporation in dry spinning processes is energyintensive<br />

but does not need to be applied for melt spinning<br />

processes [11].<br />

The main obstacle to the wide use of melt-spun TPU is the<br />

strong tackiness of these yarns which especially hampers<br />

the unwinding from spools and transport through the<br />

machines for fabric production. To reduce this tackiness,<br />

different approaches are being developed, investigated, and<br />

evaluated in the research project CO2Tex.<br />

The Research Project CO2Tex<br />

RWTH Aachen Institut für Textiltechnik (ITA) (Aachen,<br />

Germany) is currently conducting the publicly funded<br />

research project CO2Tex in cooperation with the funded<br />

partners W. Zimmermann (Weiler-Simmerberg, Germany),<br />

medi (Bayreuth, Germany), Schill+Seilacher (Böblingen,<br />

Germany), Oerlikon Textile (Remscheid, Germany), Carbon<br />

Minds (Köln, Germany) and adidas (Herzogenaurach,<br />

Germany).<br />

The Target of this project is the establishment of<br />

commercially viable elastic filament yarns made from<br />

CO 2<br />

-containing TPU. At the end of the project, these yarns<br />

should be processed as easily as possible in existing<br />

industrial plants into textile pre- and end products. For<br />

the development of at least one stable and reproducible<br />

melt spinning process, modifications are made to spinning<br />

plants. These modifications include the investigation of<br />

spinnerets, filament cooling, godet surfaces, as well as<br />

winding technology. Additionally, spin finishes are adapted<br />

to the process and tested. All developments are scaled up<br />

from pilot to industrial scale. If the production of suitable<br />

14 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


By<br />

Jan Thiel, Henning Löcken, Lukasz Debicki, and Thomas Gries<br />

RWTH Aachen Institut für Textiltechnik<br />

Aachen, Germany<br />

yarns is possible, the process chain for the production of<br />

sports and medical textiles is investigated and adapted.<br />

This includes the processes of covering, knitting, and<br />

finishing. Finally, the use of TPU yarns containing CO 2<br />

is evaluated ecologically as well as economically and<br />

compared to conventional dry-spun yarns. The mission<br />

statement of CO2Tex is displayed in Figure 1.<br />

After a first benchmark definition, first melt spinning<br />

trials are about to start at the ITA on pilot and technical<br />

scale before being upscaled to industrial scale at<br />

Oerlikon.<br />

Acknowledgement<br />

The authors would like to thank the German Federal<br />

Ministry of Education and Research for funding<br />

the research project within the innovation space<br />

BioTexFuture (funding code: 031B1207A).<br />

www.ita.rwth-aachen.de<br />

Bibliography<br />

[1] Fabricius, M.; Gries, T, Wulfhrost, B.: Fiber Tables: Elastane Fibers<br />

(spandex) Frankfurt am Main, Schwenk & Co. GmbH, 1995<br />

[2] Prisacariu, C.: Polyurethane elastomers: From morphology to mechanical<br />

aspects. Wien [a.o.]: Springer, 2011<br />

[3] Zhu, R.; Wang, Y.; Zhang, Z.; Ma, D.; Wang, X.: Synthesis of polycarbonate<br />

urethane elastomers and effects of the chemical structures on their thermal,<br />

mechanical and biocompatibility properties. Heliyon 2 (2016), pp. 1-17<br />

[4] Javni, I.; Petrović, Z.S.; Guo, A.; Fuller, R.: Thermal stability of<br />

polyurethanes based on vegetable oils. Journal of Applied Polymer Science<br />

77 (2000), No. 8, pp. 1723-1734<br />

[5] Lligadas, G.; Ronda, J.C.; Galià, M.; Cádiz, V.: Oleic and undecylenic acids<br />

as renewable feedstocks in the synthesis of polyols and polyurethanes.<br />

Polymers 2 (2010), No. 4, pp. 440-453, doi:10.3390/polym2040440<br />

[6] Gürtler, C.: “Dream production” : CO2 as raw material for polyurethanes.<br />

Brussels, 07.06.2013<br />

[7] Allied Market Research: Spandex fiber market by type of production<br />

method and application – global opportunity analysis and industry forecast,<br />

2014-2<strong>02</strong>2. Pune, India, 2016: URL www.alliedmarketresearch.com/spandexfiber-market<br />

, Accessed on March the 09th, 2<strong>02</strong>2<br />

[8] Koslowski, H.-J.: Chemiefaser-Lexikon. Begriffe – Zahlen –<br />

Handelsnamen. 12. erw. Auflg.: Frankfurt am Main: Deutscher Fachverlag<br />

GmbH, 2008<br />

[9] Gries, T.; Veit, D.;Wulfhorst, B.: Textile Fertigungsverfahren: Eine<br />

Einführung. München: Carl Hanser Verlag, 2014<br />

[10] Manvi, P.: Melt spinning of carbon di-oxide based thermoplastic<br />

polyurethane. Aachen [Diss.], Shaker, 2018<br />

[11] Gupta, V.B., Kothari, V.K. (Eds.): Manufactured fibre technology London<br />

[u.a.]: Chapman & Hall, 1997<br />

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bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 15


CCU<br />

Engineered bacteria<br />

upcycle carbon waste into<br />

commodity chemicals<br />

You might not recognize the words acetone and isopropanol<br />

(IPA), but the chances are that you use them. While these<br />

chemicals are beneficial – serving as the building blocks<br />

for thousands of products, including fuels, materials, acrylic<br />

glass, fabrics, and even cosmetics – they are generated from<br />

fossil inputs, leading to emissions of climate-warming CO 2<br />

into the air.<br />

Researchers led by LanzaTech (Skokie, Illinois, USA),<br />

Northwestern University (Evanston, Illinois, USA), and Oak<br />

Ridge National Lab (Oak Ridge, Tennessee, USA) have<br />

developed an efficient new process to convert waste gases,<br />

such as emissions from heavy industry or syngas generated<br />

from any biomass source, into either acetone or IPA. The<br />

secret to the new platform is Clostridium autoethanogenum,<br />

or C. auto, a bacterium engineered at LanzaTech that can<br />

convert waste carbon selectively into either ethanol, acetone,<br />

or IPA.<br />

Their methods, including a pilot-scale demonstration<br />

and life cycle analysis (LCA) showing the economic viability,<br />

are published in the journal Nature Biotechnology. The new<br />

technology actually uses greenhouse gas (GHG) emissions<br />

destined for the atmosphere, avoids burning fossil fuels and<br />

removes CO 2<br />

from the air. According to LCA, this carbonnegative<br />

platform could reduce GHG by over 160 %, playing<br />

a critical role in helping the USA reach a net-zero emissions<br />

economy.<br />

“This discovery is a major step forward in avoiding a climate<br />

catastrophe”, said Jennifer Holmgren, LanzaTech CEO. “Today,<br />

most of our commodity chemicals are derived exclusively<br />

from new fossil resources such as oil, natural gas, or coal.<br />

Acetone and IPA are two examples with a combined global<br />

market of USD 10 billion. The acetone and IPA pathways and<br />

tools developed will accelerate the development of other new<br />

products by closing the carbon cycle for their use in multiple<br />

industries”.<br />

Acetone and IPA are necessary industrial bulk and platform<br />

chemicals. For example, acetone is used as a solvent for<br />

many plastics and synthetic fibres, thinning polyester resin,<br />

cleaning tools, and nail polish remover. IPA is a chemical<br />

used in antiseptics, disinfectants, and detergents and can be<br />

a pathway to commercial plastics such as polypropylene, used<br />

in both the medical and automotive sectors. Both are used in<br />

acrylic glass. IPA also is a widely used disinfectant, serving as<br />

the basis for one of the two World Health Organization (WHO)<br />

-recommended sanitiser formulations, which are highly<br />

effective against SARS-CoV-2.<br />

The collaborators developed a gas fermentation process<br />

for carbon-negative production of either acetone or IPA by<br />

reprogramming LanzaTech’s commercial ethanol-producing<br />

bacterial strain through cutting-edge synthetic biology<br />

tools, including combinatorial DNA libraries and cell-free<br />

prototyping advanced modelling, and omics. The scientists<br />

relied on a three-pronged approach that comprised innovations<br />

in pathway refactoring, strain optimization, and process<br />

development to achieve the observed level of performance.<br />

“These innovations, led by cell-free strategies that guided<br />

both strain engineering and optimization of pathway enzymes,<br />

accelerated time to production by more than a year”, said<br />

Michael Jewett, the Walter. P Murphy Professor in Chemical<br />

and Biological Engineering in Northwestern’s McCormick<br />

School of Engineering and director of the Center of Synthetic<br />

Biology.<br />

The optimized process was scaled up to the pilot plant, and<br />

LCA showed significant GHG savings. “Conversion pathways<br />

for the production of any biofuel or bioproduct, including<br />

acetone and IPA, inevitably involve chemical byproducts<br />

that can cause or be the result of major bottlenecks”, said<br />

ORNL’s Tim Tschaplinski. “We used advanced proteomics and<br />

metabolomics to identify and overcome these bottlenecks for<br />

a highly efficient pathway. This approach can be applied to<br />

create streamlined processes for other chemicals of interest”.<br />

By proving scalable and economically viable bulk<br />

chemical production, the researchers have set the stage<br />

for implementation of a circular economic model in which<br />

the carbon from agriculture, industrial and societal waste<br />

streams can be recycled into a chemical synthesis value<br />

chain to perpetually displace ever-increasing volumes of<br />

products made from virgin fossil resources. Thereby, chemical<br />

synthesis would become a path to capturing, recycling, and<br />

utilizing waste carbon resources.<br />

The acetone strain and process development, genomescale<br />

modeling, life cycle analysis, and initial pilot runs<br />

were supported by the Bioenergy Technologies Office in<br />

DOE’s Office of Energy Efficiency and Renewable Energy.<br />

The cell-free prototyping and omics analyses were funded<br />

by the Biological and Environmental Research program in<br />

DOE’s Office of Science. DNA sequencing and synthesis was<br />

supported by the Joint Genome Institute, a DOE Office of<br />

Science User Facility. AT<br />

The journal article can be found at<br />

https://www.nature.com/articles/s41587-<strong>02</strong>1-01195-w.<br />

www.lanzatech.com | www.northwestern.edu | www.ornl.gov<br />

Genome<br />

Mining<br />

Pathway<br />

optimization<br />

Engineered<br />

enzymes<br />

Combinatorial library<br />

Strain<br />

optimization<br />

Cell-free prototyping<br />

Omics<br />

m/z<br />

Metabolic modeling<br />

Process<br />

optimization<br />

Fermentation<br />

development<br />

& scale-up<br />

Life cycle analysis<br />

How it works: the team took a three-pronged optimization approach<br />

to increase fermentation efficiency and output. (Courtesy: FE Liewet<br />

al/Nature Biotechnology)<br />

LCA<br />

16 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


Enzymatic recycling technology<br />

for textile circularity<br />

Carbios (Saint-Beauzire, France), a pioneer in the<br />

development of enzymatic solutions dedicated to the endof-life<br />

of plastic and textile polymers, recently announced<br />

the validation of the 3 rd and final technical step of the CE-PET<br />

research project, co-funded by ADEME (France’s Environment<br />

and Energy Management Agency), for which Carbios is the<br />

lead partner alongside its academic partner Toulouse White<br />

Biotechnology (Toulouse, France). This achievement confirms,<br />

once again, the full potential and breadth of Carbios’ enzymatic<br />

recycling process, C-ZYME. This breakthrough innovation<br />

makes it possible to produce a wide variety of products of<br />

equivalent quality to those of petro-sourced origin from any<br />

PET waste, including textiles.<br />

The first white PET fibre recycled enzymatically<br />

from coloured textile waste<br />

Worldwide, around 90 million tonnes of PET are produced<br />

each year, more than 2/3 of which are used to manufacture<br />

fibres. However, only 13 % of textile waste is currently recycled,<br />

mainly for downcycling, i.e. for lower quality applications (such<br />

as padding, insulators, or rags). By successfully manufacturing<br />

at pilot scale a white PET fibre that is 100 % enzymatically<br />

recycled from coloured textile waste, Carbios is paving the way<br />

for the circular economy in the textile industry. C-ZYME is now<br />

on the doorstep of industrialization and will soon enable the<br />

biggest brands to move closer to their sustainability goals.<br />

“Thanks to our breakthrough process, it will soon be<br />

possible to manufacture, on a large scale, t-shirts or bottles<br />

using polyester textile waste as raw material”, said Emmanuel<br />

Ladent, CEO of Carbios. “This is a major breakthrough that<br />

gives value to waste that currently has little or no value. It is a<br />

concrete solution that opens up a global market of 60 million<br />

tonnes per year of potential raw materials and will help to<br />

reduce the use of fossil resources”.<br />

Textile waste that can also be used to<br />

manufacture food contact packaging<br />

In November 2<strong>02</strong>0, Carbios had already produced the first<br />

transparent bottles from textile waste. These 100 % recycled<br />

PET bottles have now passed the food contact validation<br />

tests. This is an important step that paves the way for the use<br />

of a new waste source for the production of biorecycled PET<br />

food packaging.<br />

Separate collection of textile waste soon to be<br />

mandatory in Europe<br />

From 1 January 2<strong>02</strong>5 the separate collection of textile waste,<br />

which is already in place in some countries, will be mandatory<br />

for all EU Member States (European Directive 2018/851 on<br />

waste). Carbios’ process will be one of the solutions that will<br />

enable this waste to be sustainably recovered and included<br />

in a truly circular economy model. These technological<br />

validations were carried out as part of the CE-PET research<br />

project, co-funded by ADEME. In particular, the project<br />

aimed to develop Carbios’ enzymatic PET recycling process<br />

on textile waste. The C-ZYME technology is complementary<br />

to thermomechanical recycling and will make it possible to<br />

process plastic and textile waste deposits that are currently<br />

not or poorly recovered. For the validation of this stage of<br />

the project, Carbios received EUR 827,200 (EUR 206,800 in<br />

grants and EUR 620,400 in repayable advances). AT<br />

www.carbios.com/en<br />

Advanced Recycling<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 17


Advanced Recycling<br />

Protective furniture packaging<br />

from pyrolysis oil<br />

As of November 2<strong>02</strong>1, Ekornes, a Norwegian (Ikornnes)<br />

manufacturer of high-end design furniture uses EPS<br />

(expandable polystyrene) protective packaging that has a<br />

lower carbon footprint than virgin material by safeguarding<br />

the same properties. This is achieved by replacing fossil<br />

resources with recycled raw materials at the beginning<br />

of production. BASF (Ludwigshafen, Germany) supplies<br />

Styropor ® Ccycled to VARTDAL PLAST (Vartdal, Norway),<br />

who converts the material into moulded packaging parts for<br />

Stressless ® furniture made by Ekornes.<br />

“We are really proud to be the first company to launch<br />

this project together with Vartdal Plast and BASF with<br />

regards to design furniture. We always strive to have the<br />

best packaging solution to protect our quality furniture,<br />

and Styropor Ccycled offers exactly what we want: same<br />

properties as virgin material but at the same time meeting<br />

the needs to reduce our carbon footprint, a perfect fit<br />

into our sustainability strategy”, says Solveig Gaundal,<br />

Compliance and CSR Manager at Ekornes.<br />

Virgin-quality packaging – smaller carbon<br />

footprint<br />

Due to its manufacturing process, Styropor Ccycled has<br />

the same properties as conventional Styropor. Maintaining<br />

excellent packaging properties such as outstanding<br />

impact absorption and high compressive strength, which<br />

are essential for the protection of sophisticated design<br />

furniture. In the production of the packaging foams that<br />

have become so well-known over the last 70 years, pyrolysis<br />

oil replaces fossil raw materials. BASF sources this oil from<br />

technology partners who use a thermochemical process<br />

called pyrolysis to transform post-consumer plastic waste<br />

that would otherwise be used for energy recovery or go to<br />

landfill into this secondary raw material. BASF then uses the<br />

oil at the very beginning of the value chain to manufacture<br />

new plastics and other products.<br />

Since recycled and fossil raw materials are mixed in<br />

production and cannot be distinguished from each other,<br />

the recycled portion is allocated to Styropor Ccycled using<br />

a mass balance approach. Both the allocation process and<br />

the product itself, have been certified by an independent<br />

auditor. Compared with conventional Styropor, at least 50 %<br />

of CO 2<br />

is saved in the production of Styropor Ccycled.<br />

Also, for the converter Vartdal Plast Styropor Ccycled<br />

brings a lot of advantages as the product is identical to<br />

virgin material. Therefore, the production process does not<br />

have to be adjusted. The company and their products are<br />

certified according to the ecoloop certification programme,<br />

confirming that for the products 100 % recycled material<br />

was used as feedstock. “We are thrilled to be working<br />

together with BASF and Ekornes on this project. This is<br />

a testament of our mutual commitment towards a more<br />

sustainable future”, says Mounir El’Mourabit, product<br />

manager at Vartdal Plast.<br />

Contributing to the circularity of plastics<br />

“Current environmental policy focuses on reducing<br />

greenhouse gas emissions, conserving fossil resources,<br />

and avoiding or using waste. By using products from our<br />

ChemCycling project, our partner Ekornes is actively<br />

contributing to the recovery of plastics after their use phase<br />

and feeding them back into the materials loop”, says Klaus<br />

Ries, head of BASF’s Styrenics business in Europe. AT<br />

www.basf.com | www.vartdalplast.no | www.ekornes.com<br />

18 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


Converting plastic waste into<br />

performance products<br />

The Advanced upcycling start-up Novoloop (Menlo Park,<br />

CA, USA) is pioneering the chemical transformation of plastic<br />

waste into high-performance chemicals and materials.<br />

The company’s proprietary process technology, ATOD<br />

(Accelerated Thermal Oxidative Decomposition), breaks<br />

down polyethylene into chemical building blocks that can<br />

be synthesized into high-value products. Polyethylene is the<br />

most widely used plastic today yet only 9 % is recycled and<br />

virtually none is upcycled.<br />

The start-up has raised USD 11 million in Series A<br />

financing led by Envisioning Partners (Seoul, South Korea)<br />

with participation from Valo Ventures (Palo Alto, CA, USA)<br />

and Bemis Associates (Shirley, MA, USA); earlier investors<br />

who joined the round included SOSV (Princeton, NJ, USA),<br />

Mistletoe (Tokyo, Japan), and TIME Ventures (San Francisco,<br />

CA, USA).<br />

The first product based on Novoloop’s ATOD process is<br />

Oistre, a thermoplastic polyurethane (TPU) for use in highperformance<br />

applications such as footwear, apparel, sporting<br />

goods, automotive, and electronics. Oistre is the first TPU<br />

made from post-consumer polyethylene waste that matches<br />

the performance characteristics of virgin TPUs made from<br />

petrochemicals. At the same time, Oistre’s carbon footprint is<br />

up to 46 % smaller than conventional TPUs and uses up to 50 %<br />

upcycled content from post-consumer plastic waste and.<br />

“What really compelled us to lead the investment round is<br />

that Novoloop has found product-market fit,” said June Cha,<br />

Partner of Envisioning Partners. “Novoloop has proven that<br />

Oistre has a wide range of applications in the market even at<br />

their early stage”.<br />

Novoloop’s technology can upcycle carbon content found<br />

in common plastic waste like grocery bags, packaging, and<br />

agricultural plastics that is too low value for material recovery<br />

facilities to bale and sell. Instead, the plastics go into landfills<br />

or incinerators today. Novoloop’s ATOD technology aims to<br />

increase commercial demand for waste polyethylene.<br />

“Plastics are not going away anytime soon, so we need to<br />

innovate to close the gap between what is produced and what<br />

is repurposed. After years of technology development, we’re<br />

thrilled to announce backing by high-calibre investors and<br />

partners to commercialize this much-needed technology”,<br />

said Novoloop Co-founder and CEO Miranda Wang.<br />

“With this funding, we look forward to completing crucial<br />

pilot scale-ups and commercializing our process technology<br />

to make a lasting impact. Our team is excited to lead the<br />

circular economy revolution for plastics”, said Novoloop Cofounder<br />

and COO Jeanny Yao.<br />

Novoloop is also announcing the company’s new<br />

partnership with Bemis Associates, the leader in apparel<br />

bonding solutions such as seam tapes, which can be found<br />

in high-performance outerwear. Together, the companies<br />

will introduce Oistre into the Bemis product portfolio as a<br />

first step to replace virgin petroleum-based thermoplastic<br />

polyurethane.<br />

“We are extremely excited to partner with Novoloop”, said<br />

Bemis Director of Sustainability Ben Howard. “Novoloop’s<br />

technology is a major breakthrough for our supply chain.<br />

Scaling it will be a huge step in shifting away from virgin<br />

petroleum sources and reducing our products’ carbon<br />

footprints”.<br />

Novoloop is currently sampling and taking pre-orders for<br />

Oistre 65A, a soft grade polyester TPU for injection moulding<br />

especially suitable for footwear applications. Higher<br />

durometer grades of Oistre TPU will be introduced soon. AT<br />

www.novoloop.com<br />

All photos courtesy Novoloop Inc.<br />

Advanced Recycling<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 19


Materials<br />

When Zero-Waste<br />

meets 3D printing<br />

GREENFILL3D – a Polish start-up (located in Łódź)<br />

operating on the edge of ecological, biodegradable<br />

materials, and 3D printing, announces the premiere<br />

of its unique filament based on wheat bran – GF3D<br />

Branfill3d. The material was created in accordance with<br />

the modern concepts of zero-waste and circular economy<br />

in mind – the wheat bran is a waste product of pasta and<br />

noodles production.<br />

From the material, the start-up 3D printed proprietary<br />

advertising stands (so-called POS – point of sales), on<br />

which ready-made pasta will be presented. The<br />

project is being developed in cooperation with<br />

the MASPEX Group (Wadowice, Poland) – one of<br />

the largest food producers in Europe.<br />

The GF3D Branfill3d material is a composite<br />

of wheat bran, polylactic acid (PLA) – a<br />

popular bioplastic used in 3D printing,<br />

and other fully biodegradable ingredients<br />

that together give GF3D Branfill3d unique<br />

properties. “The material has fantastic and<br />

surprising properties. Initially, we were afraid<br />

that it would be brittle – a typical problem in<br />

composite materials based on e.g., wood.<br />

However, it turned out that because wheat<br />

bran is fibrous, the fibres connect with each<br />

other in finished 3D prints in such a way that<br />

they are flexible (but not elastic!)”, commented<br />

Paweł Ślusarczyk, Senior Marketing Manager<br />

at Greenfill3d. “If the printout has thick walls<br />

(more than 1 cm), the model is very durable and<br />

has internal elasticity, which greatly increases<br />

the impact toughness. Thin elements (1–5 mm)<br />

can be bent to some extent without the risk of<br />

breaking”.<br />

What’s more, during the 3D printing process,<br />

the material offers the scent of baked bread,<br />

which stays on the 3D printed parts for a long<br />

time.<br />

Greenfill3d prints POS stands with its 3D<br />

printer farm of over 40 machines. Each stand<br />

consists of 34 elements – assembly is quick<br />

and easy. In addition, the structure of the stand<br />

is modular, which may allow for its further expansion with<br />

additional modules. And it is sturdier than conventional<br />

stands. “The stand was assembled and loaded with noodles<br />

in mid-January – today (mid-March), the lowest side<br />

walls began to slightly deform, but nothing threatens the<br />

stability of the structure. It should also be remembered that<br />

traditional advertising stands (e.g. made of cardboard) are<br />

designed to survive only for 3–4 weeks after which they are<br />

disposed of. Ours has been in operation for over 8 weeks<br />

and apart from the delicate visual aspect, there are no signs<br />

of wear”, says Ślusarczyk.<br />

The result is an advertising stand presenting food<br />

products, which was created based on the remains of the<br />

same food material. Production wastes – instead of being<br />

thrown away or disposed of, were used to produce common<br />

tools to support sales.<br />

“3D printing that has its obvious limitations and will<br />

always lose to injection moulding in terms of quantities. A<br />

cardboard or PVC stand will always win to a stand made<br />

on a 3D printer in terms of quantities and prices. This is<br />

why we are looking for applications where personalization<br />

or uniqueness of the product is a factor”, so<br />

Ślusarczyk.<br />

The project perfectly fits the assumptions of<br />

the Zero-Waste and Circular Economy ideas and<br />

can be scaled to other areas. The properties of<br />

wheat bran material allow performing a number<br />

of different applications – everyday use items,<br />

decorative items but also industrial. Currently,<br />

the Greenfill3d team is conducting the first<br />

tests of the use of applications made of GF3D<br />

Branfill3d for a customer representing the<br />

automotive industry and intends to successively<br />

test it in other industries.<br />

“The world is changing before our eyes<br />

and so is the approach to production. In the<br />

world of typical industrial manufacturing (e.g.,<br />

automotive), the standard was to produce<br />

hundreds of thousands of spare parts for<br />

stock. For several years, thanks to the greater<br />

efficiency of 3D printers, these parts can now<br />

be produced on-demand – only when they are<br />

needed,” Ślusarczyk elaborates. “We view our<br />

business in the same way. 3D printing allows you<br />

to change from a mass-production approach to<br />

a more personalized, targeted one. Fewer things<br />

reaching specific people”.<br />

So far, the material has not been tested for<br />

its CO 2<br />

savings or biodegradability rate, which<br />

is mainly due to the fact that it’s still quite new.<br />

“This year, we plan to commission our<br />

scientific partner – the Polish Academy of<br />

Science (Warsaw, Polen) with a series of tests examining<br />

the material in this respect. However, we’re still thinking<br />

about changing the current chemical blend. What will<br />

stay untouched for sure is wheat bran, but the rest of the<br />

components may be completely changed. As for the current<br />

chemical blend, all ingredients are biodegradable, so there<br />

is no physical or chemical chance of them not biodegrading<br />

– we just don’t know how fast yet,” explained Ślusarczyk.<br />

Cooperation with the MASPEX Group<br />

MASPEX is the largest private Polish company in the<br />

food industry and one of the largest in Central and Eastern<br />

20 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


COMPEO<br />

Automotive<br />

Europe. Greenfill3d was selected as part of the<br />

ScaleUp Program organized by PARP (Polish Agency<br />

for Enterprise Development) to implement a joint<br />

project with the MASPEX Group for one of its main<br />

brands – the leader in the pasta category in Poland<br />

(Lublin) – the Lubella brand.<br />

Leading compounding technology<br />

for heat- and shear-sensitive plastics<br />

Joint work on the project began on July 1, 2<strong>02</strong>1, and<br />

on December 15, 2<strong>02</strong>1, the first prototype was ready for<br />

logistic trials. The final POS display was made of 20 %<br />

wheat bran filament, using shelf connectors made of<br />

PLA polymer, mounted on a pedestal made of 100 %<br />

recyclable cardboard, with the print of Greenguard ®<br />

certified paints.<br />

The innovative “ecoPOS” will soon be delivered to<br />

selected retail outlets, but Greenfill3d has quite big<br />

ambitions.<br />

“What we have achieved so far is quite extraordinary.<br />

However, at the moment we are working on something<br />

other – a certain technological solution in the field of<br />

post-processing, which will make our products not<br />

only natural and biodegradable but also very visually<br />

attractive. What we are going to do will be, to some<br />

extent, a breakthrough for 3D printing itself. I have<br />

no idea why no one has figured it out before, but I’m<br />

glad it’s us”, says Ślusarczyk not without pride. “We<br />

have already carried out a few tests and the effects<br />

are amazing. I hope that by the summer holidays we<br />

will manage to create something so intriguing that we<br />

will be able to share it with the world. We will strive to<br />

expand the boundaries in the field of natural materials<br />

and find the perfect bridge between biodegradability<br />

and usability”. AT<br />

https://greenfill3d.com<br />

Uniquely efficient. Incredibly versatile. Amazingly flexible.<br />

With its new COMPEO Kneader series, BUSS continues<br />

to offer continuous compounding solutions that set the<br />

standard for heat- and shear-sensitive applications, in all<br />

industries, including for biopolymers.<br />

Info:<br />

On March 14, 2<strong>02</strong>2, representatives of the Polish 3D<br />

Printing Industry met to sign a joint statement on Russia’s<br />

aggression against Ukraine. Representatives of 13 companies<br />

submitted their signatures in person, and 5 others signed<br />

them electronically. The statement condemned the actions<br />

of the Russian Federation towards the Ukrainian Nation<br />

and declared the suspension of any economic activity in<br />

the markets of the Russian Federation and the Republic of<br />

Belarus.<br />

Greenfill3d was one of the signatories of the statement.<br />

• Moderate, uniform shear rates<br />

• Extremely low temperature profile<br />

• Efficient injection of liquid components<br />

• Precise temperature control<br />

• High filler loadings<br />

www.busscorp.com<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 21


Materials<br />

There are no silver bullets<br />

Since I joined bioplastics MAGAZINE in a bigger capacity<br />

about two years ago I came across one material that just<br />

sounded too good to be true – the UBQ material. The<br />

premise of taking mixed municipality waste (or municipality<br />

solid waste – MSW) and turning it into plastic material<br />

without the need for separation lies somewhere between<br />

an oil sheikhs’ fever dream and an environmentalist’s wet<br />

dream. I was quite sceptical for a long time, as things that<br />

sound too good to be true often aren’t good at all. But UBQ<br />

kept popping up, be it collaboration with McDonald’s, or the<br />

use of UBQ material in the first Zero-Waste Car Luca (bM<br />

01/21), and the announcement of PepsiCo (Harrison, NY,<br />

USA) just a couple of weeks ago. UBQ was even featured<br />

in the last <strong>issue</strong> of bioplastics MAGAZINE in the context of<br />

Mercedes-Benz’s VISION EQXX (bM 01/22). This story was<br />

the kick-off to a closer examination of UBQ and I sat down<br />

(digitally) with Jack “Tato” Bigio, Co-CEO & Co-Founder<br />

at UBQ Materials. So, what is UBQ? Where does it come<br />

from? Where does it go? And is Tato secretly Cotton-Eye<br />

Joe? As with most things in life the answers are not always<br />

as straightforward as we’d like.<br />

Same-same, but different<br />

The purpose of UBQ is to substitute fossil-based plastics.<br />

From injection moulding through to extrusion and 3D<br />

printing anything is possible. It is compatible with most<br />

common resins on the market, but mainly in combination<br />

with PP, PE, PLA, PS and PVC. It can be compounded with<br />

additives commonly used in the industry to tune properties<br />

like any other polymer, while not being a polymer itself.<br />

“UBQ is a new member of the thermoplastics’ family,<br />

however, it is not a polymer, it is a composite thermoplastic<br />

material. The beauty of UBQ is that it performs very<br />

similar to other members of this family of polymers like<br />

e.g., polypropylene or polyethylene. Of course, all these<br />

materials have different mechanical properties, some are<br />

more rigid, some more flexible etc. UBQ falls into its own<br />

range of properties, which is within the range of all these<br />

other plastic materials. The incredible thing about UBQ, the<br />

‘too good to be true’ part, is that it can bond with all these<br />

other materials. If it bonds with polypropylene it becomes<br />

polypropylene, and this works also with PS, PVC, or PE.<br />

UBQ takes on the properties of the material it is bonded to.<br />

It can therefore do things that other thermoplastic can’t”,<br />

Tato explained. In general, UBQ’s substitution rates lie<br />

between 20 % and 60 %, depending on the application. The<br />

real difference of UBQ is its origin.<br />

Recycling, waste, and value<br />

UBQ starts where most other processes stop, with the<br />

unrecyclable that usually ends up in incineration or landfill.<br />

While waste management is different in different regions<br />

the average household waste (MSW) is a mix of about 85 %<br />

organic material and 15 % plastic materials. These waste<br />

streams have one common problem – contamination.<br />

The plastic materials are dirty, wet, and often multilayer<br />

applications – things that make them difficult to recycle<br />

and not that useful for incineration (wet materials need<br />

extra energy input). All these shortcomings are properties<br />

UBQ needs, or rather UBQ was designed to make these<br />

mixed and contaminated waste streams into a feedstock.<br />

“Society is obsessed with the recycling of plastics, but the<br />

large majority of the waste is overlooked. Plastics are only<br />

about 15–16 % of waste and you cannot recycle about half<br />

of them in the best of the cases”, says Tato. “The problem<br />

of waste cannot be solved by recycling plastics alone – it<br />

is a good thing to try to increase recycling rates from<br />

household waste, but nobody is talking about that 85 % that<br />

we happily sent to landfills and decompose into GHG gases<br />

like methane and CO 2<br />

”.<br />

So UBQ tries to tackle these overlooked 85 % in a process<br />

that is very different from chemical recycling, which<br />

needs very clean plastic material streams and very high<br />

temperatures. UBQ is created at low temperatures that<br />

range within 200 °C as higher temperatures would destroy<br />

all the organic particles that are necessary for the process.<br />

The process, therefore, needs comparatively little energy<br />

and no added water as the base material – waste – tends to<br />

be rather wet anyways.<br />

“In a first step metals and minerals that are highly<br />

recyclable are filtered out, they are valuable materials<br />

but don’t have any added value for our material. After the<br />

removal, we send these to recyclers and are left with the<br />

food residues, trimmings, cardboard, paper, mixed plastics,<br />

and diapers. All those materials together without the need<br />

for separation will be converted into UBQ – so UBQ is not<br />

a recycling technology. We’re converting these streams<br />

of materials, which are very heterogeneous and different,<br />

into one homogeneous, consistent material“, so Tato. “The<br />

problem for most recycling processes is the dirtiness of the<br />

material, but the dirtiness in trash – it’s organic matter –<br />

UBQ actually loves that ‘dirtiness.’ Luckily organic matter<br />

has a number of common particles that create the building<br />

blocks that we use to create this new bonding matrix. The<br />

mixed plastics that are part of the waste, those that are<br />

recyclable and unrecyclable then melt into the matrix, bond<br />

with it, and become part of the matrix. So, at the end of the<br />

day, you have a composite material where all these previous<br />

heterogeneous materials disappear into one material that<br />

has thermoplastic properties. These novel and unique<br />

properties enabled us to get patents on UBQ material<br />

worldwide”.<br />

One of the main goals of UBQ is to give waste value, if<br />

MSW has intrinsic value then the likelihood of it ending up<br />

in uncontrolled landfills (which are still the norm in many<br />

parts of the world) decreases. Due to the high GHG potential<br />

of waste in such landfills (as they lead to the development<br />

of methane which is 86 times more potent than CO 2<br />

) UBQ<br />

has a huge impact on materials’ carbon footprint. To put<br />

things in perspective, every tonne of fossil-based plastics<br />

22 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


ut this one has a pretty shine<br />

By Alex Thielen<br />

Materials<br />

emits between 2–5 tonnes of CO 2<br />

eq. Replacing one tonne of<br />

polypropylene (+2.7 tonnes CO 2<br />

eq/tonne) with UBQ (-11.7 CO 2<br />

eq/<br />

tonne), a total amount of +14.4 tonnes CO 2<br />

eq/tonne can be<br />

avoided.<br />

“The development of this discovery took us very, very many<br />

years because we needed to understand the chemistry of each<br />

and every step on the conversion process to then reach one<br />

consistent and homogenous material is not a simple thing.<br />

The fact that we got patents all over the world on UBQ material<br />

is because we created a new composition of matter – a novel<br />

thermoplastic that didn’t exist before us. A material to replace<br />

common resins that are scarce, expensive, and polluting”.<br />

UBQ has not been in the spotlight of the plastic world for long,<br />

as they started marketing the material in early 2019, but they<br />

have already made some waves. It is a USDA Certified Biobased<br />

material, EU and UK REACH compliant (the 100 % UBQ powder)<br />

and IFTA compliant. UBQ Materials is also a Certified B Corp<br />

company, among other things.<br />

“We are not a huge company yet, but the people already<br />

involved here are really remarkable. Our Board of Directors is<br />

really AAA and the International Advisory Board we put together<br />

is quite remarkable. We have Roget Kornberg of Stanford, Nobel<br />

Prize winner in chemistry in 2006, and Connie Hedegaard who is<br />

the former European Commissioner for climate action in Europe<br />

that led the Paris Accord. John Elkington who is considered one<br />

of the godfathers of sustainability in the world and all these,<br />

all these incredible people are around us since 5–7 years ago,<br />

helping us develop this idea – this technology, the network, the<br />

certifications, the validations, the permitting, and policy matters.<br />

And internally, we have a really remarkable team”.<br />

As Tato said UBQ is still rather small with a pilot plant just<br />

out of Tse’elim (Israel) with an annual capacity of 7,000 tonnes.<br />

However, a new large-scale facility with an annual capacity of<br />

80,000 tonnes is planned to start production this year – and many<br />

more are planned.<br />

While there are no silver bullets for our problems, and<br />

probably never will be, the technology behind UBQ might be able<br />

to make a dent in the climate/plastic pollution crisis, with a price<br />

competitive and highly valuable sustainable material that is also<br />

highly recyclable, thus supporting a truly circular economy.<br />

www.ubqmaterials.com<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 23


Masterbacth / Additives<br />

100 % biobased surfactants<br />

& polyethylene glycols (PEGs)<br />

Clariant (Muttenz, Switzerland) recently unveiled its<br />

new Vita 100 % biobased surfactants and polyethylene<br />

glycols (PEGs) to help directly address climate change<br />

by helping remove fossil carbon from the value chain.<br />

As our climate gives us increasing and alarming signals<br />

of change, individuals and industries are looking for ways to<br />

reduce their environmental footprints, and the demand for<br />

biobased chemicals is set to grow strongly in the coming<br />

years. Clariant is committed to fostering the transition to a<br />

more sustainable bioeconomy and has a growing share of<br />

biobased products and processing aids in its portfolio.<br />

The introduction of 100 % biobased surfactants and PEGs<br />

significantly expands Clariant’s Vita designated ingredients.<br />

Vita products are based on renewable feedstocks and have<br />

at least 98 % Renewable Carbon Index (RCI). It is just one<br />

example of its commitment to provide low carbon footprint<br />

solutions to customers and to Greater Chemistry – between<br />

people and planet.<br />

“From the packaging to the many ingredients, a typical<br />

consumer product in coatings, personal care, home<br />

care, industrial, and agricultural applications still uses<br />

petrochemicals and therefore fossil carbon”, said Christian<br />

Vang, Global Head of Business Unit Industrial & Consumer<br />

Specialties, Clariant. “Switching to biobased carbon<br />

chemistry remains a big challenge for manufacturers and<br />

by launching the Vita surfactant and PEG range we are<br />

offering them an important new solution to achieve this”.<br />

Designed for natural formulations targeting a high<br />

Renewable Carbon Index (RCI), the new Vita products<br />

support manufacturers in maximizing the biobased carbon<br />

content of consumer goods such as detergents, hair and<br />

body shampoo, paint, industrial lubricants, and crop<br />

formulations.<br />

Clariant uses 100 % bioethanol derived from sugar<br />

cane or corn to create ethylene oxide for its innovative<br />

new surfactants and PEGs. The biobased material is fully<br />

segregated along the value chain from the field to the final<br />

consumer product.<br />

Because only biobased feedstocks are used, the<br />

ingredients have significantly lower carbon footprints than<br />

their fossil-based counterparts. The Vita surfactants are<br />

CO 2<br />

emissions savers: they can help save up to 85 % of CO 2<br />

emissions compared to their fossil analogues (based on EO<br />

estimative).<br />

Importantly, in addition to setting the standard in a greener<br />

production, these new solutions are chemically equivalent<br />

to Clariant’s fossil versions, offering the same performance<br />

and efficiency to formulators and brand owners. Customers<br />

can currently benefit from more than 70 biobased products,<br />

and the range will continue to be expanded to meet evolving<br />

market needs. In Q1 2<strong>02</strong>2, double-digit kilotonnes of the<br />

biobased surfactants and PEGs will be available for the<br />

worldwide business segments from Clariant IGL Specialty<br />

Chemicals (CISC), a Clariant joint venture.<br />

As one of the global leaders in specialty chemicals, and<br />

a member of the UN Global Compact, Clariant is at the<br />

forefront of advanced carbon solutions with a unique level<br />

of expertise, know-how and industry knowledge. AT<br />

www.clariant.com<br />

24 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


ioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 25


Materials<br />

Plastics as CO 2<br />

sinks<br />

Building a carbon-negative plastics industry with<br />

low-CO 2<br />

compounds and masterbatches<br />

Plastics can become a permanent CO 2<br />

sink and contribute<br />

to the de-fossilisation of the plastics industry. As a<br />

division of carbonauten GmbH based in Giengen an der<br />

Brenz (Germany), carbonauten polymers has developed the<br />

so-called carbonauten NET Materials ® (Negative Emission<br />

Technology), which consist of a combination of biopolymers<br />

or polymers and CO 2<br />

-negative biocarbons. carbonauten<br />

NET Materials describe a new category of compounds and<br />

masterbatches that are used for a wide range of applications<br />

such as construction, infrastructure, packaging, automotive,<br />

agriculture, engineering, housing, and others. The effect:<br />

the more CO 2<br />

-negative plastics are used, the better for the<br />

environment, people, and the economy.<br />

The aim of carbonauten polymers is to become a global<br />

catalyst for change in reducing the carbon footprint while<br />

creating innovative plastic products with added value.<br />

The business model is based on maximising the material<br />

and energy use of woody (carbonaceous) biomass residues.<br />

These come from agriculture, forestry, and the wood and<br />

food industries. Thus, for companies, cities, municipalities,<br />

and local authorities, their waste becomes a valuable<br />

material and thus an important resource. These biomass<br />

residues are pyrolytically carbonised in an industrial process<br />

at temperatures between 400 °C and 700 °C in the absence<br />

of oxygen. Subsequently, the biocarbons are cooled down to<br />

be anhydrous and, depending on the specification, ground<br />

up in the range of nanometres and micrometres. In further<br />

processes, the polarity of the biocarbons can be influenced.<br />

Depending on the carbon content of the biomass residues<br />

used, each tonne of biocarbon permanently stores between 2.5<br />

tonnes and 3.3 tonnes of CO 2<br />

. This is because the biocarbons<br />

are long-chain and therefore stable even after hundreds<br />

of years. Only through thermal utilisation would the carbon<br />

return to the atmosphere as natural CO 2<br />

that the plants had<br />

From waste to recyclable material: biomass residues are turned into<br />

high-quality and sustainable minus CO 2<br />

plastics<br />

previously absorbed through photosynthesis and used the<br />

carbon fraction for structural building.<br />

Another special feature of the decentralised carbonautenprocess<br />

is that pyrolysis requires only 5 % of the energy<br />

stored in the biomass for carbonisation and 90 % is used as<br />

green electricity for preparation, compounding, and further<br />

processing.<br />

The polymeric carriers for the carbonauten NET Materials<br />

are polypropylene (PP), polyethylene (PE), polycarbonate<br />

(PC), acrylonitrile butadiene styrene (ABS), polyamide (PA6,<br />

PA66, PA12), and others. Thanks to the wide viscosity range<br />

from (MFI) 0.5 g/10 min to 40 g/10 min, the compounds and<br />

masterbatches are suitable for processing from extrusion to<br />

injection moulding.<br />

By using biopolymers such as polylactic acid (PLA) or<br />

polybutylene succinate (PBS) as a carrier material, the<br />

company has also developed innovative compounds and<br />

masterbatches that can be used to produce biodegradable<br />

and compostable plastic products with improved functions.<br />

In agricultural films, such as bio-mulch films, the biocarbon<br />

contained in the carbonauten polymers and carbonauten<br />

masterbatches acts as a soil conditioner and water reservoir<br />

during degradation, contributing to sustainable farming<br />

carbonauten minus CO2 polymers will be used in many industries and<br />

sectors in the future<br />

26 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


By:<br />

Torsten Becker, Dreamer + Innovator<br />

and Cristian Hedesiu, CFO<br />

Carbonauten<br />

Giengen, Germany<br />

Materials<br />

methods, plant growth, and avoidance of agrochemicals (the<br />

popular German TV-Scientist Prof Harald Lesch says: “Super<br />

Fertiliser Terra Preta”).<br />

In addition to reducing the carbon footprint, carbonauten<br />

compounds and masterbatches offer a number of advantages<br />

for the plastic products, such as:<br />

• Improved product performance, e.g. the ratio of stiffness<br />

to impact strength, which can lead to longer durability or<br />

material savings for the same performance<br />

• excellent UV resistance<br />

• improved temperature resistance<br />

• improved dimensional stability CLTE (coefficient of linear<br />

thermal expansion)<br />

• weight reduction in automotive parts compared to talcfilled<br />

compounds<br />

• natural black pigment<br />

• 100 % recyclability<br />

Currently, carbonauten polymers is working with major<br />

brands in the automotive, packaging, and construction<br />

industries on numerous R&D projects to develop tailor-made<br />

minus CO 2<br />

plastic products that meet pressing environmental<br />

and economic demands and needs.<br />

A further and decisive advantage lies in economic efficiency.<br />

This is because the optimised processes mean that the<br />

carbonauten compounds and masterbatches are no more<br />

expensive than petroleum-based plastics. And they replace<br />

between 10 % and 70 % of expensive petroleum-based<br />

polymers.<br />

Due to the future decentralised production sites worldwide,<br />

large quantities will be produced regionally. In the smallest<br />

version, the modular plants produce over 6,000 tonnes of<br />

biocarbons annually. The carbonauten compounds and<br />

masterbatches contain between 10 % and 70 % biocarbon.<br />

From this, an average of 10,000–20,000 tonnes of carbonauten<br />

compounds and masterbatches can be produced.<br />

The carbonauten minus CO 2<br />

factory 1 is located in<br />

Eberswalde (Germany) and will start industrial operation this<br />

June. In the course of the year, the first tonnes of carbonauten<br />

compounds and masterbatches will be delivered.<br />

The next development step is the material use of the biooils<br />

that are produced during the pyrolysis of the biomass<br />

residues. These complex molecules serve as basic chemicals<br />

for the production of biobased polymers. This is old<br />

knowledge rediscovered: Until 1928, Germany was the world<br />

market leader with an annual production of 100,000 tonnes of<br />

pyrolysis oils, until after the Second World War, when cheap<br />

crude oil displaced this sustainable resource.<br />

www.carbonauten.com<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 27


From Science & Research<br />

Self-cleaning bioplastics<br />

The innovative plastic developed at RMIT University<br />

(Melbourne, Australia) repels liquids and dirt – just<br />

like a lotus leaf – then breaks down rapidly once in soil.<br />

RMIT researcher Mehran Ghasemlou, lead author of the study<br />

published in Science of the Total Environment [1] said the new<br />

bioplastic was ideal for fresh food and takeaway packaging.<br />

“Plastic waste is one of our biggest environmental<br />

challenges but the alternatives we develop need to be<br />

both eco-friendly and cost-effective, to have a chance of<br />

widespread use”, Ghasemlou said. “We designed this new<br />

bioplastic with large-scale fabrication in mind, ensuring it was<br />

simple to make and could easily be integrated with industrial<br />

manufacturing processes”.<br />

Ghasemlou said nature was full of ingeniously-designed<br />

structures that could inspire researchers striving to develop<br />

new high-performance and multifunctional materials. “We’ve<br />

replicated the phenomenally water-repellent structure of<br />

lotus leaves to deliver a unique type of bioplastic that precisely<br />

combines both strength and degradability”, he said.<br />

The bioplastic is made from cheap and widely-available<br />

raw materials – starch and cellulose – to keep production<br />

costs low and support rapid biodegradability. The fabrication<br />

process does not require heating or complicated equipment<br />

and would be simple to upscale to a roll-to-roll production<br />

line, Ghasemlou said.<br />

Naturally compostable<br />

While biodegradable plastics are a growing market, not all<br />

bioplastics are equal. Most biodegradable or compostable<br />

plastics require industrial processes and high temperatures<br />

to break them down. The new bioplastic does not need<br />

industrial intervention to biodegrade, with trials showing it<br />

breaks down naturally and quickly in soil. “Our ultimate aim<br />

is to deliver packaging that could be added to your backyard<br />

compost or thrown into a green bin alongside other organic<br />

waste, so that food waste can be composted together with the<br />

container it came in, to help prevent food contamination of<br />

recycling”, said Ghasemlou.<br />

Lotus-inspired structures<br />

Lotus leaves are renowned for having some of the most<br />

water-repellent surfaces on earth and are almost impossible<br />

to get dirty. The secret lies in the leaf’s surface structure,<br />

which is composed of tiny pillars topped with a waxy layer.<br />

Any water that lands on the leaf remains a droplet, simply<br />

rolling off with the help of gravity or wind. The droplets sweep<br />

The lotus effect<br />

up dirt as they slide down, keeping the leaf clean. To make<br />

their lotus-inspired material, the RMIT team of science and<br />

engineering researchers first synthetically engineered a<br />

plastic made of starch and cellulosic nanoparticles. The<br />

surface of this bioplastic was imprinted with a pattern that<br />

mimics the structure of lotus leaves, then coated with a<br />

protective layer of PDMS, a silicon-based organic polymer.<br />

Tests show the bioplastic not only repels liquids and dirt<br />

effectively, but also retains its self-cleaning properties after<br />

being scratched with abrasives and exposed to heat, acid, and<br />

ethanol. Corresponding author, Benu Adhikari, said the design<br />

overcomes key challenges of starch-based materials. “Starch<br />

is one of the most promising and versatile natural polymers,<br />

but it is relatively fragile and highly susceptible to moisture”,<br />

Adhikari said. “Through our bio-inspired engineering that<br />

mimics the ‘lotus effect’, we have delivered a highly-effective<br />

starch-based biodegradable plastic”.<br />

Ghasemlou is currently working with a bioplastic company,<br />

which is evaluating further development of these novel<br />

water repellent materials. The RMIT research team is keen<br />

to collaborate with other potential partners on commercial<br />

applications for the bioplastic.<br />

A study describing the lotus leaf-inspired structure of<br />

the bioplastic was published in ACS Applied Materials and<br />

Interfaces [2]. AT<br />

[1] Ghasemlou et al: Biodegradation of novel bioplastics made of starch,<br />

polyhydroxyurethanes and cellulose nanocrystals in soil environment. https://<br />

doi.org/10.1016/j.scitotenv.2<strong>02</strong>1.152684<br />

[2] Ghasemlou et al: Robust and Eco-Friendly Superhydrophobic Starch<br />

Nanohybrid Materials with Engineered Lotus Leaf Mimetic Multiscale<br />

Hierarchical Structures. https://pubs.acs.org/doi/10.1<strong>02</strong>1/acsami.1c09959<br />

www.rmit.edu.au<br />

Magnified image showing the pillared structure of a lotus leaf<br />

(left) and the new bioplastic (right). Images magnified 2,000 times.<br />

28 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


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bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 29


Masterbatch / Additives<br />

Making the leap into a new era<br />

According to the industry association European<br />

Bioplastics (EUBP), Berlin Germany, global<br />

production capabilities for bioplastics will almost<br />

double in 2<strong>02</strong>2 and are estimated to reach 2 % of global<br />

plastic production by 2<strong>02</strong>6. Both the market and end<br />

consumers are increasingly demanding more sophisticated<br />

material and end applications. As a result, bioplastics<br />

are and will continue to play an important role in the<br />

development of a circular economy and a decisive role in<br />

reaching the Green Deal objectives. That is why bioplastics<br />

are definitely part of the solution.<br />

At Sukano, Schindellegi, Switzerland, it is clear that only<br />

by joining forces along the whole value chain can we achieve<br />

a holistic and impactful change for the environment, society<br />

and, in the end, for each one of us. This is why Sukano<br />

embarked on this journey from the very beginning, over 15<br />

years ago. Initially focusing on PLA, followed by PBS(A) and<br />

finally, in 2<strong>02</strong>1, leading the way into a new era, offering PHA<br />

colour masterbatches.<br />

The concept of PHA foresees two main areas of use.<br />

The first is organic recycling. This includes applications<br />

where it is difficult to separate the polymers from the<br />

organic material, such as coffee capsules or tea bags.<br />

Applications made from PHA can go directly to organic<br />

recycling, increasing organic waste collection and therefore<br />

supporting recycling. Of course, this is presuming that<br />

policy-makers can offer such collection systems and that<br />

recyclers accept such fast-degrading organic materials<br />

in their incoming stream. The second area of use for PHA<br />

as a polymer is in applications where it is challenging or<br />

prohibitively expensive to avoid fragments ending up in the<br />

open environment or to remove them after use, such as<br />

mulch films in agriculture. With PHA, even if there is a leak<br />

to the open environment, there is no risk. This is because<br />

PHA is degradable in soil (according to ASTM D6400, and<br />

anaerobically digestible under ISO 15985 standards), open<br />

water (UV Marine Biodegradable OK Certification), and<br />

home composting conditions, following the certifications<br />

ASTM D6400 and TÜV Home Compost OK Certification.<br />

Sukano has recently launched a dedicated PHA<br />

colour portfolio, which is formulated for direct food<br />

contact applications, available for industrially and home<br />

compostable applications up to soil/marine biodegradable<br />

applications and fully tailored to the properties and<br />

performance requirements of the final application. Of<br />

course, it is up to 100 % biobased with a fully compatible<br />

PHA carrier.<br />

“At Sukano we design colours with a purpose. Everything<br />

we put on the market is designed and tailored according<br />

to specific end-of-lives depending on the end article and<br />

the local market where it will be sold“, states Alessandra<br />

Funcia, Head of Sales and Marketing. ”We want to make<br />

sure that our planet remains as colourful as it is and always<br />

has been”, she adds.<br />

The Sukano PHA colour portfolio is inspired by the planet,<br />

nature, and the people that live on it. The colours, shades,<br />

and effects allow responsible innovation and freedom<br />

in design while ensuring compostability compliance.<br />

All masterbatches are formulated and certified for<br />

compostability.<br />

“For every biopolymer masterbatch, Sukano <strong>issue</strong>s<br />

a so-called compostability letter disclosing all relevant<br />

and critical information according to the compostability<br />

schemes required by the certifying bodies”, Daniel Ganz,<br />

Global Product Manager Bioplastics confirms.<br />

In addition to the PHA colour palette, Sukano offers the<br />

technical background expertise used to formulate these<br />

products to achieve the critical polymer properties and<br />

end applications that PHA stands for. When it comes to<br />

processing PHA, Sukano offers an established three-step<br />

processing guide and provides technical on-site service<br />

whenever needed.<br />

Sukano takes action to be part of the solution. Are you<br />

ready to join them and build back stronger? MT<br />

www.sukano.com<br />

30 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


Let’s all adopt the<br />

right biohaviour now!<br />

It is the slogan of the last digital marketing campaign of<br />

CABAMIX, launched in 2<strong>02</strong>1.<br />

It underlines how Cabamix, a family-owned company<br />

producing bio and recycled mineral compounds in southern<br />

France (Cabannes), is acting concretely towards the urgency<br />

of changing the game for preserving our planet through a<br />

cleaner and more responsible industry (but now!)<br />

It is above all a question of global change in our behaviour:<br />

change in our way of consuming (3R) and in our way of<br />

producing also (3R again), so that we can really adopt the right<br />

Biohaviour. Cabamix’s responsible contribution is tangibly<br />

translated into their range of products Carbomax ® Bio.<br />

Carbomax Bio is a compound based on CaCO 3<br />

, compostable,<br />

biodegradable, partially biobased and certified by TÜV Austria<br />

(OK Compost Industrial, OK Compost Home, OK Compost<br />

Soil). Carbomax Bio is suitable for different materials such<br />

as PBAT, PLA, PBS, PHA, and their compounds, or in starch<br />

based compounds.<br />

Carbomax Bio is successfully used all around the globe<br />

in film extrusion, injection, thermoforming, and 3D printing.<br />

Carbomax Bio gives 3 main advantages: process optimization<br />

(like significantly reduced cycle times in injection), improved<br />

finished product performances and the possibility of reducing<br />

formulation costs.<br />

A recent European study has highlighted the use of<br />

biodegradable mulch film as a perfect solution for a greener<br />

agriculture. This is one of the core applications where<br />

Carbomax Bio is used.<br />

In 3D printing, converters can reach higher productivity and<br />

better look of printed parts thanks to the addition of Carbomax<br />

Bio in PLA filaments.<br />

There are many other applications where Carbomax Bio is<br />

now commonly used like biobags (fruit and vegetable bags,<br />

garbage bags for the selective collection of organics, etc.),<br />

flexible packaging, horticulture, coffee capsules, and many<br />

more. In collaboration with their customers and partners, they<br />

constantly discover new possibilities to introduce Carbomax<br />

Bio in applications where compostability makes sense and is<br />

an added value.<br />

The company will continue to launch new products to<br />

support the needs of their customers and soon they will offer<br />

a 100 % recycled revolutionary solution.<br />

From 2<strong>02</strong>3, Cabamix aims to manufacture 100 % of their<br />

products based on bio-sourced, compostable, or recycled raw<br />

materials. AT<br />

www.carbomaxbio.com<br />

Masterbatch / Additives<br />

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bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 31


Masterbatch / Additives<br />

Breakthrough for<br />

biobased HMDA<br />

Material manufacturer Covestro (Leverkusen, Germany)<br />

and biotechnology pioneer Genomatica (San Diego,<br />

California, USA) announced an important industry<br />

milestone to advance sustainability resulting from their<br />

partnership. The two companies have teamed to be the<br />

first to successfully produce significant volumes of a 100 %<br />

plant-based version of the chemical raw material HMDA<br />

(hexamethylene diamine).<br />

HMDA, with a worldwide market of 2 million tonnes<br />

per year, is a key ingredient for the widely-used nylon-6,6<br />

(with a USD 6.4 billion market), as well as an important<br />

component for raw materials for coatings and adhesives<br />

from Covestro. Up to now, HMDA has been manufactured<br />

from fossil feedstocks. Coatings and adhesives can be<br />

produced more sustainably thanks to biobased HMDA,<br />

made from renewable feedstocks – Genomatica utilizes<br />

plant- or waste-based feedstocks for its sustainable<br />

materials, generally consisting of the sugars from starchy<br />

plants like industrial corn, sugar beets, or cassava. Areas<br />

of application include automotive, construction, furniture,<br />

textiles, and fibres. The automotive industry alone uses<br />

500,000 tonnes of polyurethane coating based on HMDA<br />

annually.<br />

Teams from Genomatica and Covestro have been working<br />

together to develop a commercial process technology for<br />

biobased HMDA. The companies expect to produce tonne<br />

quantities of high-quality material over the course of<br />

multiple production campaigns. Both partners are already<br />

processing and testing material from their initial production<br />

campaigns, and the resulting bio-HMDA is of high purity<br />

and quality. The companies plan to advance the program to<br />

full commercial scale, and Covestro has secured an option<br />

from Genomatica to license the resulting integrated GENO<br />

HMD process technology for commercial production.<br />

Genomatica develops widely-used ingredients and<br />

materials using biotechnology and renewable, plant-based<br />

feedstocks rather than fossil feedstocks and their associated<br />

extractive processing methods. These materials are used<br />

by brands and their suppliers in popular goods ranging<br />

from apparel to cosmetics. Covestro brings extensive<br />

know-how in the field of research, chemical process<br />

technology and application development. The cooperation<br />

for the development of alternative raw materials based<br />

on biotechnology advances Covestro’s global program to<br />

achieve the circular economy.<br />

Covestro established an R&D Competence Center for<br />

biotechnology to further strengthen its overall know-how in<br />

this field. Biobased raw materials and biotechnology have<br />

also been identified as one of five focus areas at Covestro´s<br />

Venture Capital (COVeC) approach.<br />

“The increased use of alternative raw materials, including<br />

the utilization of biotechnology, is an important pillar of<br />

our approach to fully embrace the circular economy and<br />

help make it a global guiding principle”, says Covestro<br />

CEO Markus Steilemann. “Our program with Genomatica,<br />

which complements our internal R&D, is one of our<br />

largest external funding of biotechnology R&D to date, and<br />

underscores both the field’s importance to Covestro and the<br />

results it can deliver”. AT<br />

https://www.covestro.com | www.genomatica.com<br />

32 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


New compostable mineral<br />

fillers & black masterbatches<br />

Committed to sustainable innovation and circular economy<br />

By:<br />

Grégory Coué<br />

Technical Manager<br />

Masterbatch / Additives<br />

Kompuestos<br />

Palau Solità i Plegamans, Spain<br />

Bioexfill: mineral fillers for a lower carbon<br />

footprint<br />

Kompuestos is a Spanish company based in Palau Solità<br />

i Plegamans near Barcelona in Spain. Over the past<br />

three decades, Kompuestos has both acquired an indepth<br />

knowledge of the plastic industry, as well as gained<br />

market recognition. With a production capacity of over<br />

230,000 tonnes per year, Kompuestos has acquired a wealth<br />

of knowledge. Due to its pioneering activities and the quality<br />

and efficiency of its materials, it is today one of the leading<br />

suppliers within the plastic transforming industries, while<br />

still seeking to expand its business horizons. To answer the<br />

demand for greener products, Kompuestos has developed<br />

a whole range of biodegradable and compostable resins<br />

made of starches and other biologically sourced polymers.<br />

Several grades for film and extrusion applications have<br />

already been certified as compostable by TÜV Austria.<br />

A new range of compostable masterbatches<br />

Kompuestos has combined its know-how in masterbatches<br />

with the benefits offered by compostable resins to bring<br />

on a whole new range of eco-friendly masterbatches. The<br />

ingredients of this new range of products are carefully<br />

chosen to meet industrial and legislative requirements.<br />

Several of these grades have been certified by TÜV Austria<br />

as OK Compost INDUSTRIAL and/or OK Compost HOME.<br />

These easy-to-use compostable masterbatches ensure<br />

a dust-free and healthy production, eliminating the health<br />

risk that is involved in using powder additives, especially at<br />

their ultrafine state. Unlike using powder additives, these<br />

concentrates can easily achieve the desired final properties<br />

with complete safety at low addition levels.<br />

Using these concentrates in biodegradable packaging or<br />

other plastic products can help avoid the significant costs<br />

and time required to test products for compostability. These<br />

concentrates are available to improve the performance of a<br />

wide range of compostable resins including, but not limited<br />

to, PLA, PBAT, PBS, thermoplastic starch, and PHA.<br />

Mineral concentrates play a key role in compounding,<br />

as they are used in polymers not only as lower-cost<br />

fillers but increasingly as modifiers to improve properties<br />

such as stiffness, heat deflection temperature, and creep<br />

resistance. The mineral particle size, shape, surface area,<br />

matrix compatibility, and dispersion are all important factors<br />

affecting performance. It is also critical to understand<br />

mineral chemistry to choose the best products for each<br />

polymer.<br />

Bioexfill is a unique combination of 100 % treated and<br />

ultrafine minerals together with compostable polymer<br />

resins. Thanks to its excellent dispersion and homogeneity,<br />

high amounts of Bioexfill can be added to the final article.<br />

Bioexfill reduces costs as well as carbon footprint while<br />

maintaining the mechanical properties of the final article. In<br />

a typical example for blown film extrusion applications, with<br />

the addition of up to 25 wt% Bioexfill, similar mechanical<br />

properties can be achieved compared to the neat resin, both<br />

in machine and transverse directions. Additional benefits<br />

include lower cost, lower carbon footprint, and increased<br />

productivity. On the finished product, Bioexfill can be used<br />

as an opacifier or to colour white while reducing the amount<br />

of titanium dioxide needed.<br />

BK325: black and compostable<br />

The compostable black masterbatch BK325 ensures<br />

an excellent dispersion enabling converters to produce<br />

compostable films & bags, as well as packaging articles<br />

with very high opacity.<br />

Mulch films are used to cover the soil in order to suppress<br />

weeds and to promote crop growth. The compostable black<br />

masterbatch BK325 can be used for mulch films meant<br />

to biodegrade in soil. BK325 has been shown to avoid the<br />

penetration of light through these mulch films to eliminate<br />

the development to weeds under the film. BK325 is also<br />

compatible with the formulation of any compostable plastic<br />

article, for which black colour is desired.<br />

www.kompuestos.com<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 33


Masterbatch / Additives<br />

Unique antistatic ingredient<br />

for bioplastics<br />

There are different types of static charge control<br />

additives for polymers: these are permanent,<br />

internally added, and externally applied, depending<br />

on the level of performance and application. Croda Smart<br />

Materials ((Snaith, UK) offers all three of them.<br />

When antistatic performance is required in synthetic<br />

plastics or bioplastics, such as PLA and its blends, Atmer<br />

190 is a fantastic option. The advantage of Atmer 190 is that<br />

it can be added either directly or via masterbatch during<br />

extrusion or injection moulding, without the need for extra<br />

steps for external application methods, which increase<br />

costs. The recommended dosage is 2–3 %. The surface<br />

resistivity which can be achieved is in the order of 10 10 Ω.<br />

Atmer 190 is an internally incorporated additive that can<br />

be dispersed evenly through the polymer in the melt phase.<br />

It migrates to the surface of the polymer where it interacts<br />

with atmospheric moisture, reducing surface resistivity, and<br />

allowing dissipation of static charge over a long period of<br />

time.<br />

Alternatively, Atmer 190 can be applied externally to the<br />

surface of a polymer giving an immediate but temporary<br />

effect. Atmer 190 has FDA approvals.<br />

Additive Type What are they? How do they work? Why choose this type?<br />

Permanent<br />

Short & medium<br />

term<br />

Externally coated<br />

Internally incorporated,<br />

non-migrating static<br />

dissipative polymers<br />

Internally incorporated low<br />

molecular weight migrating<br />

anti-static additives<br />

Externally applied antistatic<br />

additives<br />

They reduce the resistivity of the<br />

plastic by forming a co-continuous<br />

ion conductive phase within the host<br />

polymer<br />

They are incorporated via a masterbatch<br />

and migrate to the surface after<br />

extrusion where they pick up moisture<br />

They are dissolved in an appropriate<br />

solvent and are then applied by spraying<br />

a wet coating onto the surface, or by<br />

dipping<br />

For applications where permanent and<br />

humidity independent static control is needed.<br />

Applications include EX, EPA and ESA.<br />

For short- or medium-term performance for<br />

example in packaging or where wide ranging<br />

food contact approval is needed<br />

When internal additives can’t be used, where<br />

clarity is affected too much or no internal<br />

additive is available, for example, PET<br />

Atmer TM<br />

Migrating anti-static<br />

additives<br />

Electromagnetic Interference<br />

(EMI) 10 1 - 10 4<br />

Anti-static 10 10 - 10 12<br />

Metals 10 -5 - 10 -1 Conductive 10 1 - 10 6 Static Dissipative 10 6 - 10 12 Plastics ≥ 10 12<br />

Surface resistivity (Ω)<br />

Additionally, Atmer 190 does not have any adverse effect<br />

on the optical properties of PLA or PLA blends. This is<br />

clearly illustrated in the Figure below<br />

By conducting tensile tests using the ASTM D638, Croda<br />

clearly demonstrates in the figures (right page) that Young’s<br />

modulus tensile strength & strain at break are not influenced<br />

by Atmer 190, i.e. the additive does not behave as a plasticizer.<br />

Material Charge decay half-life (s) Surface resistivity<br />

PLA +2 %<br />

Atmer 190<br />

a) b) c) d) e)<br />

PLA +3 %<br />

Atmer 190<br />

a) control cast extruded PLA film, b) PLA+ 2 % Atmer 190, c)<br />

PLA+ 3 % Atmer 190, d) control PLA/PBS/PCL cast extruded film<br />

and e) PLA/PBS/PCL +2 % Atmer 190<br />

More importantly, Atmer 190 does not have any adverse<br />

effect on the mechanical properties of PLA or PLA blends.<br />

PLA/PBT/PCL<br />

(Ω)<br />

Internally incorporated,<br />

non-migrating static<br />

dissipative polymers<br />

They reduce the resistivity of the<br />

plastic by forming a co-continuous<br />

ion conductive phase within the<br />

host polymer<br />

Base PLA (2500HP) > 40 7x10 14<br />

PLA + 2% Atmer 190 3 2x10 11<br />

PLA + 3% Atmer 190 3 3x10 10<br />

PLA/PBT/PCL* > 40 2x10 14<br />

PLA/PBT/PCL* + 2%<br />

Atmer 190<br />

PLA/PBT/PCL<br />

+2 % Atmer 190<br />

1 1x10 11<br />

Charge Decay and Surface Resistivity Change with Concentration level<br />

* PLA/PBS/PCL f‌ilms supplied by Floreon TM<br />

34 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


Young‘s modulus, E (GPa)<br />

2.5 —<br />

2 —<br />

1.5 —<br />

1 —<br />

0.5 —<br />

0 —<br />

Control 2% Atmer 190<br />

Young‘s modulus, E (GPa)<br />

2.5 —<br />

2 —<br />

1.5 —<br />

1 —<br />

0.5 —<br />

0 —<br />

Control 2% Atmer 190<br />

By<br />

Dimitris Vgenopoulos and Emile Homsi<br />

Croda Smart Materials<br />

Snaith, UK<br />

Masterbacth Automotive Additives<br />

PLA<br />

PLA/PBS/PCL<br />

Young’s modulus, E, of PLA (left) and PLA/PBS/PCL (right); comparison between control vs. 2 % Atmer 190<br />

Tensile strenght, UTS (MPa)<br />

70 —<br />

60 —<br />

50 —<br />

40 —<br />

30 —<br />

20 —<br />

10 —<br />

0 —<br />

Control 2% Atmer 190<br />

PLA<br />

Tensile strenght, UTS (MPa)<br />

60 —<br />

50 —<br />

40 —<br />

30 —<br />

20 —<br />

10 —<br />

0 —<br />

Control 2% Atmer 190<br />

PLA/PBS/PCL<br />

Tensile strength, UTS, of PLA (left) and PLA/PBS/PCL (right); comparison between control vs. 2 % Atmer 190<br />

250 —<br />

500 —<br />

Strain at break, ε (%)<br />

200 —<br />

150 —<br />

100 —<br />

50 —<br />

Strain at break, ε (%)<br />

400 —<br />

300 —<br />

200 —<br />

100 —<br />

0 —<br />

Control 2% Atmer 190<br />

0 —<br />

Control 2% Atmer 190<br />

PLA<br />

PLA/PBS/PCL<br />

Strain at break, ε, of PLA (left) and PLA/PBS/PCL (right); comparison between control vs. 2 % Atmer 190<br />

Summary<br />

Atmer 190 is an ideal antistatic additive for PLA & PLA blends because it combines the following benefits:<br />

• Good antistatic performance with a surface resistivity of 10 10<br />

• Internally added either via direct addition or via MB<br />

• No adverse effect on optical properties<br />

• No adverse effect on mechanical properties<br />

www.croda.com<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 35


Masterbacth / Additives<br />

Masterbatches with<br />

soil improving pigments<br />

Colouring plastics is a standard procedure throughout<br />

the industry, but what if instead of simply getting the<br />

desired colour of an application a colour masterbatch<br />

could have an added value on its own?<br />

CAPROWAX P (Frankfurt am Main, Germany) recently<br />

developed a new line of masterbatches for universal<br />

colouration aimed at biodegradable plastics that does<br />

just that. Next to colouring they have the added value of<br />

containing soil-improving pigments. The soil-improving<br />

properties fall in general into two categories: pigments that<br />

improve the water retention capacity of soil, and pigments<br />

that have acid-binding capacity and are soil similar.<br />

Water retention capacity is the ability for soil to hold<br />

water and is, therefore an important factor for agricultural<br />

purposes, it reduces the need for irrigation as well as the<br />

risk of drought or desert desertification. Pigments that<br />

increase water retention capacity are vegetable carbon or<br />

lava rock flour from the Volcanic Eifel.<br />

Acid-binding capacity can help to reduce acidity levels of<br />

soil. Acidic soils are less productive as they contain fewer<br />

nutrients important for plant growth, high acidity levels also<br />

hinder root growth and many plants have difficulty growing<br />

in soil with high acidity levels.<br />

Soil similar pigments with acid-binding properties include<br />

biomineral natural calcite, calcined Kaolin (a brightening<br />

pigment without the addition of titanium dioxide.<br />

The carrier material Caprowax P is compostable and<br />

waterproof, and complies with the specification of DIN<br />

EN 13432. Caprowax P masterbatches are suitable for<br />

universal colouration of bioplastics, blends, biocomposites,<br />

and filaments including: PLA, PBS, PHA, PCL, Caprowax P/<br />

Blends / BioMineralComposites, Polysaccharide/Derivates,<br />

PVAc/Bioplastic-Blends, PVOH, Bio-NFC/WPC, Bio-UPR,<br />

Bio-TPE, and NIPU.<br />

The masterbatches can be used translucent, covering,<br />

chromatic/achromatic and pearlescent colouration.<br />

They are lightfast, non-migratory, temperature stable,<br />

insoluble in water, comparable with natural, mineral<br />

pigments, and already mineralised. Masterbatch pellets are<br />

added to different bioplastics in a range of 0,5–6 %. They<br />

have a processing range of 90–200 °C, and for a short time<br />

up 220 °C. The content of each separate pigment in the<br />

coloured final products is ≤1 %.<br />

In the course of composting the brown to black colour of<br />

compost or humus change over to the coloured bioplastic<br />

and the colourful appearance disappears. Colourations with<br />

natural, biomineral calcite support biogenic weathering in<br />

soil and waters.<br />

After the biological degradation of the coloured biopolymer,<br />

the used pigments are able to regenerate acidic soil, improve<br />

plant fertilization, and increase water retention capacity. AT<br />

www.caprowax-p.eu<br />

Examples of masterbatches for soil improvement QX<br />

CAPROWAX P TM Shade Description<br />

Lava Red 134 QX LP lava rock f‌lour, Volcanic Eifel / iron oxide red<br />

Yellow 314 BM QX LP natural calcite / iron oxide yellow<br />

White C 004 BM QX<br />

natural Calcite<br />

Green 444 BM QX LP natural Calcite / iron oxide yellow / ultramarin blue<br />

Blue G 545 BM QX LP natural calcite / ultramarin blue<br />

Violet B 636 BM QX LP natural calcite / mangan violet, bluish<br />

Lava Brown 715 QX LP lava rock f‌lour Volcanic Eifel / iron oxides red / black<br />

Lava Brown 717 QX LP lava rock flour Volcanic Eifel / iron oxides red / black<br />

Lava-Grey FK 833 QX LP lava rock flour Volc. Eifel / iron oxide black / kaolin calcined<br />

Grey 821 BM wcb QX<br />

natural calcite / iron oxide black<br />

Grey FK V 827 bb QX LP kaolin calcined / vegetable carbon<br />

Black V 804 bb QX<br />

vegetable carbon<br />

Lava-Black 806 QX LP lava rock flour Volcanic Eifel / iron oxide black<br />

V: vegetable carbon, bb: biobased , wcb: without carbon black , LP: laboratory prototype<br />

QX: biobased carbon black and lava rock f‌lour from Volcanic Eifel are soil improver with water retention capacity<br />

BM: biomineral, natural calcite, acid-binding, FK: calcined kaolin, compost friendly<br />

36 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


Within its work on the European<br />

Nenu2phar project, Elixance (Elven,<br />

France), a company specialized in the<br />

elaboration and production of masterbatches<br />

and compounds, has developed a compostable<br />

3D printing filament based on PHA. The R&D<br />

department formulated two types of filaments<br />

to cover a large field of applications: a rigid<br />

filament, and a more flexible one. The objective<br />

was to develop a fully biodegradable filament<br />

without losing the performance of a petroleumbased<br />

plastic like, e.g. TPE, ABS.<br />

The company already has a large range of green<br />

products under its brand Elixbio and acquired<br />

a strong knowledge in the use of naturals<br />

fillers blend with biopolymers. By applying<br />

this knowledge to the 3D printing area with its<br />

partner Nanovia (Louargat, France), they made<br />

printable formulations based on biodegradable<br />

raw materials. These formulations include<br />

PHA, a compostable polymer that comes from<br />

renewable resources, and natural fillers, such as<br />

hemp or oyster powder.<br />

In the exploration of their mechanical<br />

performance, the formulations were extruded<br />

and printed into test bars for mechanical<br />

characterization. These properties were<br />

compared to properties of non-compostable<br />

3D filaments. The formulations with the most<br />

interesting performances were then used to print<br />

different complex geometry parts.<br />

The rigid filament is a blend of PHB, PHBV,<br />

and incorporated hemp fibres and achieves<br />

mechanical properties close to a filament made<br />

of PLA: high tensile modulus and good impact<br />

resistance. The flexible filament is a blend of PHB<br />

and PBAT with oyster powder, with a low tensile<br />

modulus and a high elongation at break (around<br />

300 % according to ISO 527-1). These properties<br />

are similar to those of TPE.<br />

For several years, Elixance has been developing<br />

bioplastics with a circular economy philosophy,<br />

using natural fillers and fibres (oyster and scallop<br />

shells, flax, hemp, etc.) from local resources. By<br />

working with natural fillers, they find a way to<br />

convert by-products into valuable materials and<br />

to naturally colourize the filaments, even though<br />

these compostable filaments could be colourized<br />

with vegetable or mineral pigments.<br />

These new home-compostable filaments open<br />

up the field of external applications for 3D printer<br />

owners with a sustainable management of the<br />

end-of-life.<br />

The NENU2PHAR project has received funding<br />

from the Bio-Based Industries Joint Undertaking<br />

(BBI-JU) under grant agreement No 887474. The<br />

JU receives support from the European Union’s<br />

Horizon 2<strong>02</strong>0 research and innovation programme<br />

and the Bio-Based Industries Consortium. AT<br />

https://www.elixbio.com/<br />

https://nenu2phar.eu/<br />

Home<br />

compostable<br />

3D printing<br />

filament<br />

Applications<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 37


Application News<br />

Ballpoint pens<br />

Mitsubishi Chemical Corpora- tion (Tokyo,<br />

Japan) recently announced that their<br />

biobased engineering plas- tic DURABIO<br />

has been adopted as the main body part<br />

(rear shaft) of Pilot Corporation’s (Tokyo,<br />

Japan) ballpoint<br />

pen Acroball T Series<br />

Biomass Plastic and FRIXION Ball Knock<br />

05 Biomass Plastic. These products<br />

have been of- fered for sale by Pilot since 3<br />

February<br />

2<strong>02</strong>2 (These products are currently<br />

only available for novelty items).<br />

Durabio is a biobased engineering plastic<br />

made from the renewable plant-derived<br />

raw material isosorbide, a highly durable<br />

material. In addition, the plastic can be applied<br />

to various design parts because it has excellent colour<br />

development during colouring and mouldability during<br />

processing. These excellent characteristics have been<br />

highly evaluated, which has led to its adoption. This is the<br />

first case for using Durabio in a stationery application. AT<br />

wwwmitsubishi-chemical.com<br />

www.pilot.co.jp<br />

Carbon negative<br />

composites<br />

Mitsubishi Chemical Holdings Corporation (MCHC,<br />

Chiyoda-ku, Tokyo) announced in February that Diamond<br />

Edge Ventures, Inc. (DEV, a wholly-owned subsidiary of<br />

MCHC”) has invested in Lingrove, Inc. (San Francisco,<br />

California, USA).<br />

Lingrove – whose high-performance, carbon-negative<br />

composite technology can replace wood, high-pressure<br />

laminates, and plastics with its less expensive, cleanchemistry<br />

product Ekoa ® – has secured its Series A<br />

funding with lead investor Diamond Edge Ventures<br />

(DEV).<br />

Ekoa, developed from plant fiber, delivers a higher<br />

strength-to-weight ratio than steel. Ekoa is already<br />

being used to replace mainstream materials such as<br />

wood in musical instruments and designer furniture.<br />

Upcoming uses in late-stage testing include instrument<br />

consoles in electric vehicles, kitchen & bath products,<br />

and acoustic panels. Ekoa, with its extreme<br />

endurance, moldability, and<br />

general<br />

performance,<br />

provides a<br />

sustainable<br />

alternative to<br />

other composites<br />

and incumbent<br />

materials, with a<br />

luxurious and natural<br />

aesthetic.MT<br />

www.mitsubishichem-hd.co.jp/english<br />

www.diamondedgeventures.com<br />

https://lingrove.com<br />

Beauty joins<br />

PEFerence consortium<br />

Avantium (Amsterdam, The Netherlands), a leading<br />

technology company in renewable chemistry, announces<br />

that world luxury goods leader LVMH Group (Moët Hennessy<br />

Louis Vuitton – Paris, France) and Avantium have agreed<br />

to further explore the potential of Avantium’s 100 % plantbased,<br />

recyclable polymer PEF (polyethylene furanoate),<br />

as a sustainable packaging solution for LVMH beauty<br />

brands. To this end, LVMH Beauty will be the first luxury<br />

cosmetic company to join the PEFerence consortium,<br />

further enabling the commercial introduction of PEF to the<br />

Cosmetics market.<br />

The PEFerence consortium, coordinated by Avantium,<br />

aims to replace a significant share of fossil-based<br />

polyesters with the novel, sustainable polymer PEF. PEF<br />

is a plant-based, highly recyclable plastic, with superior<br />

performance properties compared to today’s widely<br />

used petroleum-based packaging materials. Joining the<br />

PEFerence consortium supports the ambitions of LVMH<br />

Group’s social and environmental strategy LIFE 360 (LVMH<br />

Initiative for the Environment), and the company’s target of<br />

zero plastic from virgin fossil feedstock.<br />

“LVMH Beauty is always looking for sustainable materials<br />

with superior performance for our luxury products as part of<br />

our sustainability strategy,” says Claude Martinez Executive<br />

President and Managing Director, Beauty Division of LVMH<br />

Group. “The environmental and performance features of<br />

PEF are unique and very promising to meet our sustainable<br />

packaging goals, which is why LVMH Beauty decided to<br />

join the PEFerence consortium. Together, with the other<br />

PEFerence consortium partners, we aim to shape this<br />

next-generation, fully circular and sustainable packaging<br />

material”.<br />

Avantium CEO Tom van Aken comments: “We are pleased<br />

with the decision of LVMH to join the PEFerence consortium,<br />

demonstrating the importance of our mutual work to develop<br />

packaging solutions for a circular and sustainable future. We<br />

look forward to continuing and expanding our collaboration<br />

with LVMH Beauty for many years to come”. AT<br />

www.lvmh.com | www.avantium.com<br />

38 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


Biomaterial pendant<br />

Visitors walking into New Zealand’s Expo Restaurant Tiaki in Dubai (United Arab Emirates) will be in awe of the David<br />

Trubridge pendant lights suspended above their heads – one of those being made from a shimmering biomaterial formulation<br />

developed by Crown research institute Scion (Rotorua, New Zealand).<br />

Showcasing New Zealand’s innovative and sustainable spirit, the Navicula pendant light features a composite of sustainable<br />

biobased plastics and native pāua shells developed by Scion scientists with a beautiful iridescent sparkle.<br />

The Navicula design is inspired by microscopic diatoms which live in water and produce 50 % of the oxygen in the air we<br />

breathe. Designer David Trubridge is a recognised leader in sustainable design for his high-end lighting that is produced with<br />

minimal environmental impact.<br />

“Scion havs been experimenting with New Zealand materials to make biomaterial colour. They’ve used kiwifruit to make<br />

green, harakeke (flax) to make brown, the pāua added more of a glitter effect”, Trubridge said.<br />

“I love the pāua navicula pendant light they developed because it’s different – the light shines through, the colour works well.<br />

The whole way along we said it’s important to get a texture, as we didn’t want it to<br />

have a glossy shine that made it look like plastic. Scion achieved a rough texture which is<br />

important – it works really well, it’s quite different to our plywood lights and I like that”.<br />

Scion’s biomaterials technology platform takes biomass fillers, such as sander dust,<br />

kiwifruit hair and skin, seashells, grape marc, harakeke, bark, or casein and combines<br />

them with biobased polymers. Compounding the filler with the polymer creates a<br />

biocomposite which is then extruded or reshaped into a new form that can be used.<br />

“As kaitiaki (guardians), New Zealanders believe we have a responsibility to leave<br />

the world in a better place for future generations – and we can see this in the shared<br />

sustainability ethos of the design companies”, said Scion Materials, Engineering<br />

and Manufacturing Research Group Leader Marie Joo Le<br />

Guen.<br />

Trubridge adds, “it’s wonderful to be part of New<br />

Zealand’s creative community on exhibit in Dubai – to be<br />

there telling the story of our land and our people”. MT<br />

youtu.be/6h8yD98dZP8<br />

Photo: Stephen Parker<br />

www.scionresearch.com | https://davidtrubridge.com/nz<br />

Application News<br />

Wakeboards from bio-epoxy<br />

Sicomin Epoxy Systems (Châteauneuf-les-Martigues, France), the leading formulator of high-performance epoxy resin<br />

systems and the market-leading GreenPoxy bio-resin range, announces its new collaboration with sports equipment giant<br />

Decathlon (Villeneuve-d’Ascq, France).<br />

Sicomin will supply its GreenPoxy 33 resin to produce Decathlon’s new JIB and BLOCK wakeboards that will be manufactured<br />

at Meditec, the specialist composite board manufacturer based in Tunisia (Mornaguia).<br />

With a desire to produce products that are as sustainable as possible, GreenPoxy 33 resins will contribute to Decathlon’s<br />

environmental mission, deriving 28 % of its carbon content from plant sources, whilst also providing high mechanical properties<br />

and exceptional clarity in the finished laminates. Formulated with rapid processing in mind, GreenPoxy 33 has been seamlessly<br />

integrated into Meditec’s manufacturing process, allowing it to match Decathlon’s production demand and keep cure cycles as<br />

short as 10 minutes at 100˚C.<br />

Meditec combines GreenPoxy 33 with Forest Stewardship<br />

Council ® (FSC) accredited wood cores, further increasing<br />

the percentage of responsibly sourced materials in the new<br />

Jib and Block boards. Both models have been designed for<br />

intermediate wakeboarders looking for a rigid yet flexible<br />

board to be used at cable parks or when towed. The Block<br />

model also features a unidirectional carbon strip on the lower<br />

part to further increase its pop on the water.<br />

Decathlon closely monitors all factors that contribute to the<br />

ecological impact of its products, including the supply chains<br />

and transport miles incurred by both raw materials and<br />

finished products. Sicomin’s manufacturing site in Southern<br />

France combined with Meditec’s location close to Europe near<br />

Tunis also provides a reliable and low mileage supply chain<br />

that avoids extended shipping from East Asia. AT<br />

www.sicomin.com | www.decathlon.com |<br />

www.meditec-sports.com<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 39


Application News<br />

Casio’s new PRO TREK with biomass plastics<br />

The new PRW-61 is the first Casio watch to be made with<br />

biomass plastics sourced from renewable organic substances.<br />

Casio Computer (Tokyo, Japan) recently<br />

announced the latest addition to the PRO<br />

TREK line of outdoor watches. Produced<br />

from regenerable resources, biomass<br />

plastics are attracting attention as a material<br />

that can help reduce environmental impact<br />

by curbing CO 2<br />

emissions.<br />

For the first time in any Casio watch, the<br />

PRW-61 uses biomass plastics in the case,<br />

band, and case back. The environmentally<br />

friendly biomass plastics are produced using<br />

materials derived from castor seeds and<br />

corn, as well as other raw materials. Casio is<br />

proud of this new material application for its line of outdoor<br />

tools, Pro Trek, for nature lovers.<br />

Delivering on outdoor utility, the model is equipped with<br />

Triple Sensor (digital compass, barometer/altimeter, and<br />

thermometer), as well as Multi-Band 6 radio wave reception<br />

from 6 transmission stations around the world, and Tough<br />

Solar to provide stable power for these<br />

functions and more. For optimum readability,<br />

the design features thick bar indexes to<br />

check time, direction, and other indicators at<br />

a glance, as well as slits on the band above<br />

and below the dial that serve as guides to<br />

quickly read the compass direction indicated<br />

by the second hand.<br />

As part of its focus on the Sustainable<br />

Development Goals, Casio is pursuing<br />

a number of environmentally friendly<br />

initiatives, including a shift from plastic to<br />

recycled paper in packaging for the PRW-<br />

61. Moving forward, Casio will also contribute to efforts to<br />

build a circular economy by expanding its use of sustainable<br />

materials in the design of other watch models, as well. AT<br />

https://world.casio.com<br />

Cellulose-based heat-sealed sandwich bags<br />

St1’s HelmiSimpukka (Helsinki, Finland), in collaboration with Woodly (Helsinki, Finland) and Amerplast (Tampere, Finland),<br />

launches the Woodly heat-sealed take-away bag.<br />

The heat-sealed bag is 100 % carbon-neutral and recyclable wood-based packaging material. Consumers will recognize the<br />

new packaging from the Woodly logo and the sandwiches can be found in all St1 HelmiSimpukka outlets in Finland.<br />

Recognized as one of the biggest companies in Finland, St1 and their HelmiSimpukka outlets are known for comprehensive<br />

services and delicious foods. With the new environmentally friendly packaging solution, St1 aims to reduce food waste, increase<br />

consumer recycling, and improve the quality and shelf life of products.<br />

“Sandwiches packaged in the Woodly heat-sealed take-away bags retain freshness even longer than those packaged in<br />

a traditional plastic bag, which supports our goal of reducing food waste. In addition, the Woodly heat-sealed bag is made<br />

of renewable material and is suitable for recycling, which is in line with our responsibility thinking”, says Emil Huttunen,<br />

Marketing and Concept Manager of the HelmiSimpukka chain.<br />

The Woodly heat-sealed bags are manufactured by Amerplast, a company with extensive experience in manufacturing flexible<br />

packaging and strong expertise in food industry<br />

requirements and packaging materials.<br />

For Woodly, the collaboration with St1 and<br />

Amerplast can lead to extraordinary results with<br />

hopes of many more to follow suit in packaging<br />

products more environmentally friendly. “The<br />

development of the bag solution together with<br />

the HelmiSimpukka restaurant chain and bag<br />

manufacturer Amerplast has been exciting and<br />

inspiring. We see a lot of new opportunities here to<br />

expand similar Woodly heat-sealed take away bag<br />

solutions to other product categories as well”, says<br />

Jaakko Kaminen, CEO of Woodly Oy. AT<br />

www.woodly.com<br />

40 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


Renewable, aesthetically pleasing, and reusable<br />

Sensibly sustainable packaging is becoming increasingly important for high-priced products such as cosmetics. In the past, it was<br />

enough to simply have a beautiful design, now aesthetics need to be combined with sustainability and functionality. If you want to be a<br />

packaging trailblazer in the luxury segment, you cannot afford to make any compromises when it comes to sustainability. Half-baked<br />

ideas that are not properly thought through and only do lip service to the goals of the circular economy don’t give any added value in the<br />

best of cases and are plain greenwashing in the worst.<br />

If you are planning on becoming a pioneer with your sustainable packaging, you should first turn to experienced specialists in the<br />

bioplastics industry. Product requirements, material pairings, and design must be perfectly coordinated.<br />

NaKu (Vienna, Austria) is such a specialist. In close cooperation with freemee cosmetics (Scharnstein, Austria) they created a reusable<br />

packaging made of wood and glass containing a replaceable cartridge made of bioplastic, which optimally protects biocosmetics and<br />

can be emptied completely. As the ideals of the circular economy stand front and centre, only materials such as glass, sustainably grown<br />

wood, and renewable and compostable plastics were allowed to be used.<br />

The luxury segment has particularly high requirements for simple and reliable usability. The product design does not only require the<br />

end product to be aesthetically appealing, all individual parts must be ideally matched to each other so that everything is properly sealed<br />

while being easy to use at the same time. This is a particularly difficult challenge with bioplastics, many are still new and experience in<br />

their use are scarce, thus less data for design and simulations are available. A lot has to be considered, tried, and tested.<br />

What is already a challenge with conventional plastic can be a “make or break” scenario for projects<br />

utilizing bioplastics. Anyone who succeeds in combining reusable, compostable, and renewable<br />

materials takes on a clear pioneering role in sustainable packaging.<br />

Currently, many recycling and collection systems are not yet prepared for the newly emerging<br />

circular economy, yet NaKu doesn’t want to wait for these systems to be in place. This is why the<br />

refillable cartridges are both industrially compostable and chemically recyclable.<br />

NaKu invites both cosmetic brand owners who are interested in this packaging for their cream<br />

products, as well as companies who need similar packaging for their products in the future. AT<br />

www.naku.at/naku-freemee-cosmetics<br />

Application News<br />

10-12 May – Cologne, Germany<br />

renewable-materials.eu<br />

The stars of Renewable Materials meet in Cologne<br />

The unique concept of presenting all renewable material solutions at one event<br />

hits the mark: bio-based, CO2-based and recycled are the only alternatives to<br />

fossil-based chemicals and materials. Preliminary program available.<br />

First day<br />

• Bio- and CO2-based<br />

Refineries<br />

• Chemical Industry,<br />

New Refinery Concepts<br />

• Chemical Recycling<br />

Second day<br />

• Renewable Chemicals<br />

and Building Blocks<br />

• Renewable Polymers and<br />

Plastics – Technology<br />

and Markets<br />

• Fine Chemicals (parallel session)<br />

• Innovation Award<br />

Third day<br />

• Latest nova Research<br />

• The Policy & Brands View<br />

on Renewable Materials<br />

• Biodegradation<br />

• Renewable Plastics and<br />

Composites<br />

ORGANISED BY<br />

NOVA-INSTITUTE<br />

RENEWABLE<br />

MATERIAL<br />

OF THE<br />

YEAR 2<strong>02</strong>2<br />

1<br />

INNOVATION AWARD<br />

Call for Innovation<br />

Vote for the Innovation<br />

Award “Renewable<br />

Material of the Year 2<strong>02</strong>2”<br />

Organiser<br />

Premium<br />

Partner<br />

Innovation Award<br />

Sponsor<br />

Sponsors<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 41


On-Site<br />

Tecnaro<br />

W<br />

e are sure that many of our readers know<br />

TECNARO or have at least heard about the<br />

company from Isfeld, Germany. Who does not<br />

know the term ‘liquid wood’? Who has never<br />

seen the picture of the famous loudspeaker<br />

housing?<br />

However, we wanted to know<br />

more about the roots, the current<br />

status, and the future prospects<br />

of the innovative company<br />

that develops and produces<br />

its own bioplastics and<br />

biocomposites based on<br />

renewable raw materials<br />

and markets them<br />

worldwide. That’s<br />

why we visited<br />

Tecnaro in mid-<br />

February.<br />

Gucci high heel<br />

It all started back<br />

in 1998 when Helmut<br />

Nägele and Jürgen Pfitzer founded Tecnaro<br />

as a spin-off of the Fraunhofer Gesellschaft. Well, actually<br />

it started a little earlier…<br />

In 1996 the Technical Business Economist Jürgen Pfitzer<br />

and Chemical Engineer Helmut Nägele met for the first<br />

time at the Fraunhofer Institute for Chemical Technology<br />

(ICT), Pfinztal, Germany, by now the largest Institute of the<br />

Fraunhofer Society. Initially, Helmut Nägele wanted to PhDresearch<br />

online measurement of polymer melts. But then<br />

the newly upcoming topic of polymers based on renewable<br />

resources fascinated him much more, so he changed his<br />

mind. Initiated by the Climate Conference in Rio de Janeiro<br />

1992, Pfitzer and Nägele started discussing ways to reduce<br />

CO 2<br />

. “Not so many in the broad public in those days thought<br />

that carbon dioxide would become a topic as significant as<br />

it is today”, Nägele commented.<br />

The development of<br />

the Aquasolv paper<br />

pulping process at<br />

the ICT opened the<br />

door for Pfitzer<br />

and Nägele’s<br />

activities. The<br />

Aquasolv process<br />

uses heat and<br />

water (steam) to<br />

obtain cellulose<br />

fibres from wood,<br />

with lignin as a<br />

by-product. A patent<br />

search didn’t show any<br />

significant results. So, the<br />

Binabo by Tic Toys<br />

two sat down in Pfitzer’s backyard<br />

over beer and barbeque and wrote down some<br />

20 patent drafts. This was then followed by lots of<br />

experiments. Systematically the two researched and<br />

developed the conversion of lignin into a product family that<br />

would later become known as Arboform ® or liquid wood.<br />

The lignin content can be from 30 up to 70 %.<br />

Until then, and still today in many<br />

cases, the by-product lignin is just<br />

burnt to exploit the energy. “And<br />

we do not take away the lignin<br />

from the energetic use”, as<br />

Jürgen Pfitzer emphasised,<br />

“we add just one more<br />

value-added step. At the<br />

very end of its lifetime,<br />

after reuse and recycling,<br />

the lignin-based plastic can<br />

still be incinerated, and the<br />

energy used”.<br />

So, the much-used saying<br />

among representatives of the<br />

pulp and paper industries “One<br />

can make anything from lignin<br />

except money” proved not to be<br />

true for Pfitzer and Nägele.<br />

Urn made of Arboform<br />

This was the basement for the foundation of Tecnaro<br />

GmbH, the name abbreviating the German words for<br />

Technology Renewable Resources. It was the declared<br />

philosophy of the Fraunhofer Society to allow inventors to<br />

exploit their inventions themselves, as so many inventions<br />

in the Society ended up unused. This allowed for a very<br />

smooth spin-off. In 1998 the two started their own business<br />

without any venture capital and left the Fraunhofer Institute<br />

another two years later.<br />

After the first few years as a young start-up company, the<br />

head office was moved from Pfinztal in Baden-Württemberg<br />

to the government-funded start-up and innovation centre of<br />

Eisenach/Stedtfeld in Thuringia (one of the then so-called<br />

New Federal States) in May 2000.<br />

As a result of constantly growing<br />

demand, particularly in southern<br />

Germany, Tecnaro returned from<br />

Thuringia to Baden-Württemberg<br />

in August 2006 and moved into<br />

larger premises for production<br />

as well as research and<br />

development at the Ilsfeld-<br />

Auenstein location.<br />

The first product Arboform<br />

provides very good dampening<br />

properties and proved to<br />

be a very good material for<br />

acoustic applications, such as<br />

loudspeaker housings, but also<br />

musical instruments like bass guitars,<br />

recorders (flutes). But also for other Loudspeaker housing<br />

applications where you want a high level<br />

of design freedom for wooden products Arboform is the<br />

42 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


By: Michael Thielen<br />

On-site<br />

ideal material. This also includes automotive interior<br />

parts, where real wood veneer can be back-injected with<br />

Arboform, allowing the production of rigid “all-wood” parts<br />

in almost any design.<br />

An interesting application from the early days is a<br />

biodegradable urn. “In many so-called Friedwälder<br />

(cemetery forests) all over Europe and beyond the Tecnaro<br />

urns are the only allowed products”, Jürgen Pfitzer<br />

explained.<br />

Over the years the product family of Arboform (injection<br />

mouldable lignin-based bioplastics Liquid Wood) which are<br />

100 % biobased and biodegradable has been extended with<br />

further products for many different applications.<br />

Combined with other ingredients, such as PLA, PHA,<br />

waxes, minerals, and many more, the product family of<br />

Arboblend ® was created and the addition of fibres and<br />

fillers led to the Arbofill ® products.<br />

Today the material database of Tecnaro comprises<br />

about 6,000 recipes for tailormade resins for a plethora of<br />

applications “from fibres and yarns through to thick-walled<br />

parts”, as Pfitzer pointed out. From hard to soft (TPE)<br />

almost anything can be realised. 40-50 different grades are<br />

always on stock for immediate delivery.<br />

One example is the Eco Pump of Sergio Rossi (Gucci).<br />

Here the heels are made of Arboform the inner sole made<br />

of a soft Arboblend and the outer sole of a rigid type.<br />

Since 2005 Tecnaro is also a supplier to the automotive<br />

industry. “It started with a really spectacular product”,<br />

Pfitzer proudly said. “It is a lost core for high-performance<br />

carbon-ceramic brakes of cars like Porsche, Bentley,<br />

Lamborghini, Formula-1 cars, and others.” And Helmut<br />

Nägele added: “Due to the complex shape and very narrow<br />

tolerances the manufacture of these lost cores, that were<br />

initially made of machined plywood was very costly”.<br />

Injection moulding with Arboform showed significant<br />

advantages and outperformed high-performance plastics<br />

tin-bismuth alloys while simultaneously being a lot cheaper.<br />

The biobased origin and biodegradability were certainly of<br />

lesser importance. For the automotive industry once again,<br />

performance and cost are the key factors.<br />

Other remarkable applications areas include homecompostable<br />

organic coffee capsules, growth covers<br />

biodegradable under forest conditions for microplastic-free<br />

reforestation, a complete biobased range of household goods<br />

ranges, and many more. The company delivers resins to all<br />

market areas, including household, medical applications,<br />

consumer electronics, textile, toys, and many more. “All<br />

except aerospace”, as Nägele pointed out. Tecnaro grades<br />

can be processed in injection moulding, blow moulding,<br />

thermoforming, film blowing, and 3D printing.<br />

Today, Tecnaro is a company with 40 employees working<br />

in 3 shifts 24/7 compounding on four production lines about<br />

16,000 tonnes of material annually. The offive, production<br />

and storage area was recently doubled to 5,000 m 2 .<br />

To the last question, as in many of our interviews: “What<br />

are you particularly proud of?” Helmut Nägele said: “We<br />

started in 1996 and wanted to contribute our share to<br />

make the world a better place. And we are still there. With<br />

the same management, the same shareholder structure<br />

without any venture capital we are a successful player and<br />

have so many ideas for the future”. Jürgen Pitzer added,<br />

“and in times where everyone suffers from supply chain<br />

<strong>issue</strong>s we can proudly say ‘we can deliver’”.<br />

www.tecnaro.de<br />

From left: Helmut Nägele, Alex and Michael<br />

Thielen, Jürgen Pfitzer<br />

Jürgen Pfitzer explains the compounding line<br />

Alex Thielen is fascinated of the carbon-ceramic<br />

brake application<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 43


Opinion<br />

About reducing the fossil fuel<br />

addiction via compostables<br />

From a historical perspective, it is quite remarkable to<br />

see how geopolitical events can have an unexpected<br />

influence on the way we deal with our materials.<br />

During the American civil war, around the 1860s, a company<br />

in billiard supplies, called Phelan and Collender, faced a<br />

serious shortage in their supply of ivory as a direct result<br />

of the war. The company offered a USD 10,000 award for<br />

anyone who could offer an alternative material for making<br />

billiard balls. It led to the development of a cellulose-based<br />

material called Parkesine, which is often seen as the<br />

world’s first (semi)synthetic material that was ever made.<br />

Wallace Carothers – a Harvard professor in organic<br />

chemistry – only joined Dupont after significant pressure,<br />

to then further investigate the concept of macromolecules<br />

in 1928, which was formulated by Staudinger in 1920.<br />

Carothers patented numerous materials like Nylon<br />

(polyamide), various polyesters (incl. PLA), and Neoprene<br />

(synthetic rubber). When the United States got involved in<br />

WW2 in 1941 there was an urgent demand for lightweight<br />

materials in planes. As Japan had occupied the countries<br />

holding natural rubber plantations, it was good to have<br />

synthetic alternatives available. Nylon – promoted originally<br />

as artificial silk for lady’s stockings – came in handy as an<br />

alternative for regular silk for parachutes, as Japan was<br />

also in control of the global silk market.<br />

In 1973 the Yom Kippur war led to an oil and energy crisis<br />

in various western countries, when Arab countries decided<br />

to cut supplies to countries, who had chosen to side with<br />

Israel in this conflict. It is unlikely to be a coincidence that the<br />

first materials where starch was combined with synthetic<br />

polymers appeared in the market in the mid 1970s. Initially,<br />

it was only a cheap filler to reduce crude oil dependency, but<br />

was soon linked to biodegradable materials, e.g. in mulch<br />

film applications.<br />

Even at the grand opening of NatureWorks’ PLA facility in<br />

Blair (USA) in 20<strong>02</strong>, one of the key-note speakers asked the<br />

audience if they “want their raw materials to come from the<br />

Midwest or the Middle East”, referring to the attacks of 11 th<br />

September 2001.<br />

The recent geopolitical developments have been putting<br />

pressure on the situation related to energy supply. If we<br />

want to have a situation in Western Europe where the gas<br />

supply is re-evaluated, the short-term solution will be in<br />

shifting energy sources, away from natural gas towards<br />

oil, coal, lignite, and even nuclear energy. The side effects<br />

that are likely to occur in such situations are often ignored.<br />

Uncertainties for the future may influence the stock market,<br />

inflation might rise (significantly), and interest rates are<br />

likely to go through the roof in the upcoming months as well<br />

– even if a peaceful settlement can be reached soon.<br />

Have we learnt nothing from the oil and energy crisis of<br />

1973? Unpredicted changes in the price and availability of<br />

crude oil and raw materials (like plastics) have been the<br />

start of a strong recession that lasted for almost a decade.<br />

Which in turn lead to high unemployment rates and strong<br />

increases in prices. Yet the consumption of energy and<br />

plastics did not change. There seems therefore to be a<br />

direct connection between economic growth (GDP) and the<br />

consumption of plastics. Before 1973 there was a direct<br />

correlation between energy use and the development of<br />

the GDP in Europe. After 1973 there was a clear separation<br />

visible, with a growth of the GDP and a diversification in<br />

energy supply.<br />

For around 30 years the bioplastic industry has been<br />

developing new materials and processes, especially in<br />

the area of compostable materials. Initially, the driving<br />

force (in the early 90s of the previous century) was linked<br />

to agriculture. Creating added value for farmers was the<br />

focus of almost all starch producing companies – only a<br />

few companies from that pioneering phase managed to<br />

make the translation from starch to the world of plastics<br />

and packaging. Since these days, the bioplastic industry<br />

has been sending out different signals to the industry.<br />

Environmental benefits had to be clarified, separate waste<br />

separation was promoted as an approach to reduce landfills,<br />

climate change was addressed, and being biobased received<br />

attention. We have seen various hypes like agrification, the<br />

cradle-to-cradle approach, and currently, we are in the<br />

middle of the circular economy mantra.<br />

The plastic industry has kept on growing, and as<br />

environmental impacts become more and more visible to the<br />

general public (like the Plastic Soup), the communication<br />

on plastic recycling has been intensified. Unfortunately, it<br />

becomes increasingly eminent that mechanical recycling is<br />

simply not the holy grail that the plastic industry and big<br />

brand owners are trying to make it out to be. The European<br />

Plastics Pact had the ambition that the industry would<br />

reduce the consumption of plastics and increase recycling.<br />

Ambitious targets and voluntary agreements have been<br />

presented to the general public. How close to achieving<br />

these targets are we, and is it even realistic that we will<br />

reach them at all? Consumption of plastic has increased<br />

instead of decreasing, and the use of recycled plastics in<br />

packaging is still at embarrassingly low levels compared<br />

to glass, metal, and paper. The industry is kicking the can<br />

down the road with a new magical solution called chemical<br />

recycling. The processes that are being investigated are<br />

44 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


Opinion<br />

(with the exception of chemical<br />

recycling of PLA) far more<br />

expensive than using virgin<br />

materials like PE or PP, can be<br />

quite energy-intensive, and are<br />

overall rather controversial.<br />

What is missing to reach the<br />

necessary transition is a proper<br />

driving force. For companies<br />

that are using regular plastics,<br />

making a shift is expensive<br />

and risky. And as long as<br />

consumers believe that there<br />

are realistic environmental<br />

solutions in place - which<br />

help to reduce their guilty conscience – it will be difficult<br />

to achieve breakthrough changes. Yes, some brands and<br />

retailers have made enormous propaganda for their green<br />

solutions, but if you look at the relative numbers they were<br />

rather homeopathic in nature. And many positive initiatives<br />

have been stopped as soon as the actual target, creating<br />

brand value and a positive image, was achieved. Multibillion<br />

companies have marketing departments that can<br />

easily spend large amounts of money on communication<br />

to influence public opinion. That is their job. But as soon<br />

as the shareholder value comes under pressure and the<br />

competition is not following, environmental aspirations are<br />

thrown out the window again – quietly.<br />

In this context, it is also interesting to analyse the waste<br />

processing companies. There is an overcapacity of waste<br />

incineration plants in various regions in Western Europe.<br />

Coincidence or not: these are also the regions with the<br />

highest resistance against the use of compostable materials.<br />

Waste incineration plants earn more money if they run at<br />

full capacity. Considering that a waste incineration plant<br />

costs around EUR 1 billion to build, with a technical life<br />

expectancy of at least 30 years, it is not surprising that<br />

such companies try to protect their shareholders’ value.<br />

Municipalities that have difficulties dealing with low budgets<br />

easily fall into the hands of a company with overcapacity in<br />

incineration. There is no proper environmental driving force<br />

to change the status quo that can compete with this strong<br />

financial motivation to make ends meet.<br />

What do the considerations as described above mean<br />

for the bioplastic industry? The recent geopolitical<br />

developments might be a breaking point. We cannot take<br />

cheap energy and oil supply for granted anymore and<br />

we might be forced to reconsider how we deal with our<br />

resources and waste. Most compostable plastics are<br />

Remy Jongboom<br />

Director Business Development & Product Innovation<br />

Biotec<br />

Emmerich, Germany<br />

(partially) biobased. Examples like<br />

PLA and PHA are 100 % biobased, and<br />

starch blends have increased their<br />

biobased share over the last 5 years<br />

from 25 % up to more than 60 %. A<br />

silent revolution or a rapid evolution?<br />

Biobased monomers like butanediol<br />

or succinic acid can be produced at<br />

competitive prices compared with<br />

their fossil-based alternatives.<br />

So far, mainly feedstocks like starch<br />

and sugar have been considered as<br />

primary sources. However, we could, or<br />

should, also consider other feedstock<br />

like side streams of the food processing<br />

industry. Even wastewater plants can<br />

be used to produce new raw materials like PHA. While<br />

technically possible, they were often too expensive in the<br />

reality of yesterday. Mainly due to the relatively low costs<br />

of fossil energy and its abundant supply. This has recently<br />

changed, and it is not clear yet if these days will ever<br />

come back again, for better or worse. Compost can help<br />

to improve the structure of the soil and contains a certain<br />

amount of nutrients. Using more compost not only has a<br />

climate-friendly carbon binding potential but also reduces<br />

the need for energy-intensive mineral fertilizers. And if<br />

renewable energy sources like solar and wind energy keep<br />

on increasing in importance, then the conversion of organic<br />

waste, including compostable plastics, towards biogas may<br />

help to secure our energy supply when the sun is not shining<br />

and the winds are not blowing.<br />

Hopefully, the acts of war in Ukraine will soon come to an<br />

end. And maybe in 5 or 10, years we will look back at the<br />

current events as the big catalyst that led to major changes<br />

in the Western World on how we will look at and deal with<br />

our resources and waste streams. The cleaner technologies<br />

are available and getting cheaper – lucrative opportunities<br />

that bring change are there, with environmental benefits as<br />

positive side effects. The driving force for change is a new<br />

and unpredictable one. Only the future will tell us if we will<br />

manage to maintain and improve our current standards<br />

of living and freedom even further, by kicking our fossil<br />

resources addiction.<br />

www.biotec.de<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 45


Methodology<br />

Bioplastic Feedstock Alliance<br />

new guidance<br />

T<br />

he Bioplastic Feedstock Alliance, the World Wildlife<br />

Fund (WWF) (Gland, Switzerland) led initiative<br />

to advance thought leadership on responsible<br />

biobased plastic, released an updated methodology for<br />

guiding responsible sourcing decisions.<br />

Responsibly sourced biobased plastic is one of the many<br />

circularity solutions that WWF is championing in its pursuit<br />

of No Plastic in Nature by 2030. The global environmental<br />

NGO launched the Bioplastic Feedstock Alliance (BFA) in<br />

2013 to advance thought leadership on biobased plastic’s<br />

role in creating a more sustainable and circular material<br />

system. The group’s focus has been on building the<br />

knowledge around the responsible sourcing of feedstocks,<br />

which are key to realizing biobased plastic’s potential for<br />

both people and planet.<br />

In this pursuit, the BFA convenes to address the significant<br />

gap in guidance for decision making regarding biobased<br />

plastic sourcing, including the crucial first step of assessing<br />

the risks and benefits of different feedstocks from different<br />

places. The BFA created this methodology, BFA Methodology<br />

for the Assessment of Bioplastic Feedstocks, to serve as<br />

a tool to start the journey to responsible sourcing and its<br />

environmental and social benefits.<br />

The methodology defines 13 indicators that users explore<br />

to build their understanding of the relative benefits, tradeoffs,<br />

and risks of different feedstocks. The 2<strong>02</strong>2 update<br />

integrates the latest science and guidance into this existing<br />

framework, as well as simplifying the user experience.<br />

The BFA methodology serves as a guide to help companies<br />

and producers navigate complex decision-making based on<br />

consistent and comprehensive criteria. Further, it provides<br />

guidance and resources across a broad range of sourcing<br />

topics in one place, helping users build a comprehensive<br />

understanding across environmental and social indicators<br />

as well as identify what <strong>issue</strong>s require further due diligence<br />

or external expertise.<br />

The goal is to ensure that bioplastic purchasers and<br />

producers are asking the important questions that ultimately<br />

drive the entire industry toward sourcing decisions that do<br />

more good, resulting in better environmental and social<br />

outcomes.<br />

As science in both the bioplastic and conservation spaces<br />

are constantly advancing, it is important to update this<br />

guide to reflect the latest thinking.<br />

Since the BFA methodology was first developed in 2014,<br />

new guidance has been developed by many organizations<br />

on a range of topics, including water stewardship, climate<br />

resilience and mitigation, land-use change, and food<br />

security. This 2<strong>02</strong>2 update to the BFA methodology brings<br />

these learnings together to create a central point for the<br />

latest research and developments in conservation science<br />

related to biobased plastic.<br />

Here’s what’s new in the 2<strong>02</strong>2 BFA Methodology for the<br />

Assessment of Bioplastic Feedstocks, and what it means<br />

for the industry:<br />

• Integrating a climate resilience lens across the<br />

methodology. To successfully integrate biobased plastics<br />

into the circular economy at scale, their production<br />

must support climate resilience at the landscape level.<br />

The methodology now includes guidance to help users<br />

understand this complex topic and how their decisions<br />

can affect landscape resilience.<br />

• Widening the lens to adapt to novel feedstocks. As<br />

feedstocks such as algae, residues from crop harvesting,<br />

tall oil, CO 2<br />

capture and utilization, and used cooking<br />

oil come to market, it is crucial that they are assessed<br />

against consistent criteria. In this update, content<br />

is adapted to account for the broad range of <strong>issue</strong>s<br />

associated with the expanding categories of feedstock<br />

options.<br />

• Simplifying user experience. The 2<strong>02</strong>2 update includes<br />

updated research guidance and resources to help users<br />

navigate this complex topic, find external expertise<br />

when needed, and prioritize specific <strong>issue</strong>s for further<br />

investigation. An updated scoring system makes it<br />

simpler to understand and communicate results.<br />

Together, the suite of updates included in the 2<strong>02</strong>2<br />

Methodology for the Assessment of Bioplastic Feedstocks<br />

combines the most up-to-date guidance from experts<br />

across a wide range of disciplines. The updated Methodology<br />

will guide producers and purchasers of biobased plastic<br />

towards decisions that support a more sustainable future.<br />

www.bioplasticfeedstockalliance.org<br />

Info:<br />

The new BFA guidance can be<br />

downloaded from<br />

https://tinyurl.com/wwf-bfa<br />

By<br />

Kori Goldberg<br />

Plastic Waste Specialist<br />

World Wildlife Fund US<br />

Washington, DC, USA<br />

46 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


Plastic or no plastic –<br />

that‘s the question<br />

By Michael Thielen<br />

Basics<br />

Initially announced as a Basics article, this turns out to be<br />

more an opinion article. However, this article shall serve<br />

as food for thought. I explicitly encourage stakeholders<br />

in this topic to share their opinion with us. Maybe we can<br />

publish a kind of “Pro – Con” article in one of the upcoming<br />

<strong>issue</strong>s.<br />

The motivation for this article is the fact that we see an<br />

increasing number of publications and products on the<br />

market, stating their products made of biobased and/or<br />

biodegradable/compostable plastics were “plastic-free” or<br />

“no-plastic”. A plastic planet is even starting a discussion<br />

about what they call “Plastic Free Standards” [1]. This not<br />

only confuses experts and consumers alike – in my opinion<br />

,it is simply wrong.<br />

I’d like to start with my personal opinion or definition of<br />

what plastics and what polymers are.<br />

Polymers<br />

A polymer (from the Greek terms poly-, “many” and<br />

-mer, “part”) is a substance or material consisting of very<br />

large molecules, or macromolecules, composed of many<br />

repeating subunits [2]. Polymers can be polymerized<br />

industrially from monomers (such as combining ethylene<br />

(C 2<br />

H 4<br />

) to long chains (C 2<br />

H 4<br />

) n<br />

= polyethylene). But polymers<br />

also exit in natural substances, for example, cellulose,<br />

lignin, in the exoskeleton of crustaceans (chitin) and many<br />

more.<br />

Plastic<br />

Since polymers, as they come from the reactor (e.g. pure<br />

polyethylene), cannot be processed into useful everyday<br />

products by injection moulding, blow moulding, film<br />

blowing, etc, they need to be compounded, i.e. combined<br />

with additives.<br />

Bioplastic<br />

The same holds true for bioplastics (plastics that are<br />

made from renewable resources, that are biodegradable or<br />

that are both). Biobased polymers, whether they are, e.g.<br />

polymerized from monomers obtained from fermentation<br />

processes from sugar sources (e.g. lactic acid to polylactic<br />

acid PLA) or otherwise obtained from natural sources<br />

(PHAs being natural polymers in the body of certain<br />

bacteria, chitin/chitosan from crustaceans, or many other<br />

possible sources), need to be compounded before they can<br />

be processed.<br />

Bioplastics are plastics<br />

Bioplastics are plastics: Materials, compounded from<br />

polymers that can be processed into useful products. This<br />

is what all definitions of the plastic industry, the European<br />

Commission or the industry association European<br />

Bioplastics confirm. According to the REACH regulations,<br />

for example (Article 3(5) Regulation 1907/2006), “plastics are<br />

polymers that include various additives making it possible<br />

to obtain materials that can be cast, shaped, generally<br />

under heat and pressure, in order to obtain market-ready<br />

final articles”.<br />

So, if a manufacturer of biobased plastic products wants<br />

to make a claim, it should not say “plastic-free”, or “noplastic”.<br />

It should rather read “free from conventional<br />

plastic” or “free from fossil-based plastic” or “no petroleumbased<br />

plastic” or the like.<br />

Potential pitfalls<br />

Talking about “no-plastic” or “plastic-free” can be a pitfall<br />

when marketing products made of biobased plastics. The<br />

abovementioned REACH regulation also states that all<br />

so-called “bio-sourced” and/or “biodegradable” materials<br />

are included in this definition and regarded as plastics<br />

in the same way as all the others, often referred to as<br />

“conventional plastics”.<br />

The Single-Use Plastic (SUP) directive of the European<br />

Commission includes all plastics, under the meaning of<br />

the REACH definition, with no distinction, and hence de<br />

facto including biodegradable and/or bio-sourced plastics,<br />

irrespective of their means of biodegradation (compost, soil,<br />

river or seawater). I think we all agree that this directive<br />

is not a good directive. But this topic shall be discussed<br />

separately.<br />

Pro and Con<br />

So, what is your opinion? Plastic or no plastic? Please let<br />

us know. We’d like to publish different opinions on this in<br />

one of our next <strong>issue</strong>s.<br />

Source: aplasticplanet.com/trust-marks/<br />

Courtesy: Naku<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 47


Brand Owner<br />

Brand-Owner’s perspective<br />

on bioplastics and how to<br />

unleash its full potential<br />

What does fischer as a brand owner expect from<br />

the bioplastics industry?<br />

Moving away from a finite resource such as oil towards a<br />

renewable and therefore infinite resource is precisely the right<br />

approach. We have the same quality requirements we have for<br />

conventional resources in this respect. In addition to this, we<br />

also ensure that raw materials don’t compete with main food<br />

crops and that they have a neutral impact on the environment.<br />

Providing transparent information on ingredients and<br />

manufacturing methods is also of key importance. As such,<br />

the material must meet high recyclability requirements. As<br />

part of our comprehensive approach, we also emphasise<br />

compliance with CSR standards ranging from mining to<br />

further processing and logistics.<br />

Christian Ziegler<br />

Head of Department<br />

Sustainability, Environment and Energy,<br />

fischer group<br />

What does fischer think the bioplastics industry<br />

needs to do?<br />

The production of bioplastics would need to be optimised<br />

to the point that sustainable raw materials are available at a<br />

similar price as conventional ones. Furthermore, sustainable<br />

resources should be competitive in terms of quality, availability<br />

,and planning security.<br />

Under what circumstances would fischer use<br />

(more) bioplastics, what are the requirements?<br />

If the quality requirements for bioplastics are similarly high<br />

as they are for conventional resources, then from this aspect<br />

nothing speaks against using them more frequently. And the<br />

price has to be right, too. The purchasing price for bioplastics<br />

must be at a similar level as regular plastics. At the moment,<br />

bioplastics tend to be significantly more expensive and<br />

sometimes aren’t available as required.<br />

What is fischer already doing in this respect?<br />

fischer is the world’s first manufacturer to produce<br />

plugs made of primarily renewable resources with its<br />

GreenLine, which was honoured with a Green Brand<br />

award last year. The award and its corresponding quality<br />

seal recognises brands with a proven commitment to<br />

climate conservation, sustainability, and ecological<br />

responsibility. The regenerative market share of<br />

GreenLine has been confirmed by an independent testing<br />

and certification body by DIN CERTCO / TÜV Rheinland.<br />

We are continuously raising awareness of these products<br />

among our staff and customers to reduce reservations<br />

or concerns and demonstrate the advantages. One of<br />

our advantages from a production point of view is that<br />

we can use our existing manufacturing processes and<br />

tools regardless of the respective raw materials.<br />

www.fischer.de<br />

Magnetic<br />

for Plastics<br />

www.plasticker.com<br />

• International Trade<br />

in Raw Materials, Machinery & Products Free of Charge.<br />

• Daily News<br />

from the Industrial Sector and the Plastics Markets.<br />

• Current Market Prices<br />

for Plastics.<br />

• Buyer’s Guide<br />

for Plastics & Additives, Machinery & Equipment, Subcontractors<br />

and Services.<br />

• Job Market<br />

for Specialists and Executive Staff in the Plastics Industry.<br />

Up-to-date • Fast • Professional<br />

48 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


10<br />

Years ago<br />

Cover Application Story News<br />

the stadium’s visible demonstration of environmental awareness<br />

as promoter of new and fair-play solutions:<br />

The PLA cups offer a simple way of contributing to more<br />

sustainable environmental performance. Their PR appeal can<br />

rise an increased media interest. For sponsoring or advertising<br />

companies the cups can be used to improve the corporate and<br />

brand image and can help to differ from competition. And finally<br />

cups made from PLA offer a possibility for single waste stream.<br />

Moreover, the PLA beer cups are compostable and certified in<br />

accordance with EN 13432, European norm for compostability of<br />

packaging, meaning that they degrade completely in industrial<br />

composting facilities. The options for disposal are plentiful:<br />

incineration with energy recovery, composting and recycling. Apart<br />

from that, Huhtamaki and stadium operators are jointly working<br />

on a promising ‘from cradle to cradle’ project, planning to build a<br />

closed recycled PLA material loop for stadiums and arenas.<br />

Huhtamaki was the first to launch a complete range of<br />

compostable tableware. The BioWare family was launched in<br />

2004 and is continuously developed with new products. BioWare<br />

products are available in Europe and Oceania.<br />

Huhtamaki has maintained the Pass status in the Kempen SNS<br />

Socially Responsible Investing (SRI) Universe since 20<strong>02</strong>. Only<br />

those European companies that meet or exceed the strict business<br />

ethical, social and environmental performance standards set by<br />

Kempen Capital Management and SNS Asset Management qualify<br />

for inclusion.<br />

www.huhtamaki.de/foodservice<br />

Cover Story<br />

Fair play commitment<br />

to environment<br />

Our cover photo protagonists<br />

and their friends enjoy beer<br />

from PLA cups<br />

Huhtamaki’s PLA beer cup assortment emerges<br />

as a clear winner in stadiums and arenas<br />

S<br />

ustainable packaging is quite a new addition to the environmental<br />

considerations for packaging. With eco-friendly<br />

PLA cold drink cups for the catering market, Huhtamaki has<br />

since several years been promoting this aspect. Recently, more and<br />

more organizers of big events and football (soccer) games in stadiums<br />

decided to join the ranks.<br />

In 2009, the first Premier League arenas in Germany together<br />

with several Second League stadiums pioneered the concept<br />

of using biodegradable NatureWorks ® PLA beer cups for their<br />

big events. These were the early birds in recognising not only<br />

the positively practical benefits of these products, but also their<br />

sustainable aspects: PLA is made from annually renewable<br />

resources, is compostable and thus can be disposed of completely<br />

naturally. Other stadiums as well as various breweries were quick<br />

to follow, and soon both operators and visitors appreciated the<br />

evident advantages of this environmental-friendly solution for<br />

cups. Single use cups offer guaranteed hygiene, as each guest gets<br />

a new cup. There is no need for dishwashing as for reusable cups.<br />

This saves labour time, water, heating energy and detergents. The<br />

lightweight PLA cups are safe, as they do not break nor splinter.<br />

The cups are light to carry and easy to handle and in addition allow<br />

a faster and more focused customer service. Last but not least, the<br />

possibility for customised printing offers additional promotional<br />

opportunities.<br />

In terms of sustainability, the concept offers far more. Belonging<br />

to Huhtamaki’s future friendly BioWare packaging portfolio, PLA<br />

beer cups together with molded fibre strongholders stand out as<br />

In March 2<strong>02</strong>2,<br />

Hendrik Müller – General Manager<br />

Huhtamaki Foodservice Germany<br />

Sales GMBH & Co. KG<br />

Alf, Germany<br />

says:<br />

Packaging for good: for Huhtamaki it is<br />

not only an international slogan but also<br />

the demand to think ahead and to constantly<br />

develop. 10 years ago Huhtamaki<br />

had already outgrown its infancy in the<br />

field of disposable cups/products made of PLA<br />

and the raw material developed into a real alternative<br />

to oil-based plastics in the field of packaging<br />

and still is today.<br />

Huhtamaki in Alf played a pioneering role in<br />

terms of further developing the processability of<br />

PLA in the thermoforming process. Today, many<br />

different industries and production processes<br />

use the same sources of raw materials as we<br />

do because they too have recognized the advantages<br />

of PLA. In this market, in particular,<br />

tact and flexibility are currently<br />

in demand. Plastic packaging<br />

is a hotly debated topic, plastic<br />

and disposable bans in certain<br />

areas of application put crisis<br />

security to the test. Unfortunately,<br />

European legislation<br />

has (almost) completely<br />

disregarded the undisputed<br />

benefits of biobased plastics<br />

when formulating the SUPD,<br />

which has pushed the materials’<br />

advantages for use in<br />

service packaging more and<br />

more into the background.<br />

Personally, I believe that<br />

the potential and importance<br />

of PLA will continue<br />

to grow. This will certainly<br />

soon be supported by the<br />

possibility of resource-saving,<br />

chemical recycling. It<br />

remains to be seen whether<br />

this will be in time for<br />

our applications, but we in<br />

Alf are proud of the contribution<br />

we were allowed<br />

to make to the PLA success<br />

story and we still<br />

are today.<br />

www.foodservice.huhtamaki.de<br />

bioplastics MAGAZINE [<strong>02</strong>/12] Vol. 7 17<br />

https://tinyurl.com/2012-PLA-cups<br />

16 bioplastics MAGAZINE [<strong>02</strong>/12] Vol. 7<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 49


1. Raw materials<br />

Suppliers Guide<br />

AGRANA Starch<br />

Bioplastics<br />

Conrathstraße 7<br />

A-3950 Gmuend, Austria<br />

bioplastics.starch@agrana.com<br />

www.agrana.com<br />

Xinjiang Blue Ridge Tunhe<br />

Polyester Co., Ltd.<br />

No. 316, South Beijing Rd. Changji,<br />

Xinjiang, 831100, P.R.China<br />

Tel.: +86 994 22 90 90 9<br />

Mob: +86 187 99 283 100<br />

chenjianhui@lanshantunhe.com<br />

www.lanshantunhe.com<br />

PBAT & PBS resin supplier<br />

Kingfa Sci. & Tech. Co., Ltd.<br />

No.33 Kefeng Rd, Sc. City, Guangzhou<br />

Hi-Tech Ind. Development Zone,<br />

Guangdong, P.R. China. 510663<br />

Tel: +86 (0)20 6622 1696<br />

info@ecopond.com.cn<br />

www.kingfa.com<br />

BASF SE<br />

Ludwigshafen, Germany<br />

Tel: +49 621 60-99951<br />

martin.bussmann@basf.com<br />

www.ecovio.com<br />

Mixcycling Srl<br />

Via dell‘Innovazione, 2<br />

36042 Breganze (VI), Italy<br />

Phone: +39 04451911890<br />

info@mixcycling.it<br />

www.mixcycling.it<br />

FKuR Kunststoff GmbH<br />

Siemensring 79<br />

D - 47 877 Willich<br />

Tel. +49 2154 9251-0<br />

Tel.: +49 2154 9251-51<br />

sales@fkur.com<br />

www.fkur.com<br />

Simply contact:<br />

Tel.: +49 2161 6884467<br />

suppguide@bioplasticsmagazine.com<br />

Stay permanently listed in the<br />

Suppliers Guide with your company<br />

logo and contact information.<br />

For only 6,– EUR per mm, per <strong>issue</strong> you<br />

can be listed among top suppliers in the<br />

field of bioplastics.<br />

Gianeco S.r.l.<br />

Via Magenta 57 10128 Torino - Italy<br />

Tel.+390119370420<br />

info@gianeco.com<br />

www.gianeco.com<br />

Xiamen Changsu Industrial Co., Ltd<br />

Tel +86-592-6899303<br />

Mobile:+ 86 185 5920 1506<br />

Email: andy@chang-su.com.cn<br />

1.1 Biobased monomers<br />

1.2 Compounds<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

39 mm<br />

For Example:<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach<br />

Germany<br />

Tel. +49 2161 664864<br />

Fax +49 2161 631045<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Sample Charge:<br />

39mm x 6,00 €<br />

= 234,00 € per entry/per <strong>issue</strong><br />

Sample Charge for one year:<br />

6 <strong>issue</strong>s x 234,00 EUR = 1,404.00 €<br />

The entry in our Suppliers Guide is<br />

bookable for one year (6 <strong>issue</strong>s) and extends<br />

automatically if it’s not cancelled<br />

three month before expiry.<br />

PTT MCC Biochem Co., Ltd.<br />

info@pttmcc.com / www.pttmcc.com<br />

Tel: +66(0) 2 140-3563<br />

MCPP Germany GmbH<br />

+49 (0) 211 520 54 662<br />

Julian.Schmeling@mcpp-europe.com<br />

MCPP France SAS<br />

+33 (0)2 51 65 71 43<br />

fabien.resweber@mcpp-europe.com<br />

Microtec Srl<br />

Via Po’, 53/55<br />

30030, Mellaredo di Pianiga (VE),<br />

Italy<br />

Tel.: +39 041 5190621<br />

Fax.: +39 041 5194765<br />

info@microtecsrl.com<br />

www.biocomp.it<br />

Earth Renewable Technologies BR<br />

Estr. Velha do Barigui 10511, Brazil<br />

slink@earthrenewable.com<br />

www.earthrenewable.com<br />

Trinseo<br />

1000 Chesterbrook Blvd. Suite 300<br />

Berwyn, PA 19312<br />

+1 855 8746736<br />

www.trinseo.com<br />

BIO-FED<br />

Branch of AKRO-PLASTIC GmbH<br />

BioCampus Cologne<br />

Nattermannallee 1<br />

50829 Cologne, Germany<br />

Tel.: +49 221 88 88 94-00<br />

info@bio-fed.com<br />

www.bio-fed.com<br />

Green Dot Bioplastics<br />

527 Commercial St Suite 310<br />

Emporia, KS 66801<br />

Tel.: +1 620-273-8919<br />

info@greendotbioplastics.com<br />

www.greendotbioplastics.com<br />

Plásticos Compuestos S.A.<br />

C/ Basters 15<br />

08184 Palau Solità i Plegamans<br />

Barcelona, Spain<br />

Tel. +34 93 863 96 70<br />

info@kompuestos.com<br />

www.kompuestos.com<br />

NUREL Engineering Polymers<br />

Ctra. Barcelona, km 329<br />

50016 Zaragoza, Spain<br />

Tel: +34 976 465 579<br />

inzea@samca.com<br />

www.inzea-biopolymers.com<br />

www.facebook.com<br />

www.issuu.com<br />

www.twitter.com<br />

www.youtube.com<br />

Tel: +86 351-8689356<br />

Fax: +86 351-8689718<br />

www.jinhuizhaolong.com<br />

ecoworldsales@jinhuigroup.com<br />

Global Biopolymers Co., Ltd.<br />

Bioplastics compounds<br />

(PLA+starch, PLA+rubber)<br />

194 Lardproa80 yak 14<br />

Wangthonglang, Bangkok<br />

Thailand 10310<br />

info@globalbiopolymers.com<br />

www.globalbiopolymers.com<br />

Tel +66 81 9150446<br />

a brand of<br />

Helian Polymers BV<br />

Bremweg 7<br />

5951 DK Belfeld<br />

The Netherlands<br />

Tel. +31 77 398 09 09<br />

sales@helianpolymers.com<br />

https://pharadox.com<br />

50 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


1.5 PHA<br />

3. Semi-finished products<br />

Sukano AG<br />

Chaltenbodenstraße 23<br />

CH-8834 Schindellegi<br />

Tel. +41 44 787 57 77<br />

Fax +41 44 787 57 78<br />

www.sukano.com<br />

Biofibre GmbH<br />

Member of Steinl Group<br />

Sonnenring 35<br />

D-84032 Altdorf<br />

Fon: +49 (0)871 308-0<br />

Fax: +49 (0)871 308-183<br />

info@biofibre.de<br />

www.biofibre.de<br />

Zhejiang Hisun Biomaterials Co.,Ltd.<br />

No.97 Waisha Rd, Jiaojiang District,<br />

Taizhou City, Zhejiang Province, China<br />

Tel: +86-576-88827723<br />

pla@hisunpharm.com<br />

www.hisunplas.com<br />

ECO-GEHR PLA-HI®<br />

- Sheets 2 /3 /4 mm – 1 x 2 m -<br />

GEHR GmbH<br />

Mannheim / Germany<br />

Tel: +49-621-8789-127<br />

laudenklos@gehr.de<br />

www.gehr.de<br />

1.4 Starch-based bioplastics<br />

Kaneka Belgium N.V.<br />

Nijverheidsstraat 16<br />

2260 Westerlo-Oevel, Belgium<br />

Tel: +32 (0)14 25 78 36<br />

Fax: +32 (0)14 25 78 81<br />

info.biopolymer@kaneka.be<br />

TianAn Biopolymer<br />

No. 68 Dagang 6th Rd,<br />

Beilun, Ningbo, China, 315800<br />

Tel. +86-57 48 68 62 50 2<br />

Fax +86-57 48 68 77 98 0<br />

enquiry@tianan-enmat.com<br />

www.tianan-enmat.com<br />

1.6 Masterbatches<br />

3.1 Sheets<br />

Customised Sheet Xtrusion<br />

James Wattstraat 5<br />

7442 DC Nijverdal<br />

The Netherlands<br />

+31 (548) 626 111<br />

info@csx-nijverdal.nl<br />

www.csx-nijverdal.nl<br />

4. Bioplastics products<br />

Bio4Pack GmbH<br />

Marie-Curie-Straße 5<br />

48529 Nordhorn, Germany<br />

Tel. +49 (0)5921 818 37 00<br />

info@bio4pack.com<br />

www.bio4pack.com<br />

Suppliers Guide<br />

Natureplast – Biopolynov<br />

11 rue François Arago<br />

14123 IFS<br />

Tel: +33 (0)2 31 83 50 87<br />

www.natureplast.eu<br />

TECNARO GmbH<br />

Bustadt 40<br />

D-74360 Ilsfeld. Germany<br />

Tel: +49 (0)7062/97687-0<br />

www.tecnaro.de<br />

P O L i M E R<br />

GEMA POLIMER A.S.<br />

Ege Serbest Bolgesi, Koru Sk.,<br />

No.12, Gaziemir, Izmir 35410,<br />

Turkey<br />

+90 (232) 251 5041<br />

info@gemapolimer.com<br />

http://www.gemabio.com<br />

eli<br />

bio<br />

Elixance<br />

Tel +33 (0) 2 23 10 16 17<br />

Tel PA du +33 Gohélis, (0)2 56250 23 Elven, 10 16 France 17 - elixbio@elixbio.com<br />

elixbio@elixbio.com/www.elixbio.com<br />

www.elixance.com - www.elixbio.com<br />

1.3 PLA<br />

TotalEnergies Corbion bv<br />

Stadhuisplein 70<br />

4203 NS Gorinchem<br />

The Netherlands<br />

Tel.: +31 183 695 695<br />

www.totalenergies-corbion.com<br />

pla@total-corbion.com<br />

BIOTEC<br />

Biologische Naturverpackungen<br />

Werner-Heisenberg-Strasse 32<br />

46446 Emmerich/Germany<br />

Tel.: +49 (0) 2822 – 92510<br />

info@biotec.de<br />

www.biotec.de<br />

Plásticos Compuestos S.A.<br />

C/ Basters 15<br />

08184 Palau Solità i Plegamans<br />

Barcelona, Spain<br />

Tel. +34 93 863 96 70<br />

info@kompuestos.com<br />

www.kompuestos.com<br />

Sunar NP Biopolymers<br />

Turhan Cemat Beriker Bulvarı<br />

Yolgecen Mah. No: 565 01355<br />

Seyhan /Adana,TÜRKIYE<br />

info@sunarnp.com<br />

burc.oker@sunarnp.com.tr<br />

www. sunarnp.com<br />

Tel: +90 (322) 441 01 65<br />

UNITED BIOPOLYMERS S.A.<br />

Parque Industrial e Empresarial<br />

da Figueira da Foz<br />

Praça das Oliveiras, Lote 126<br />

3090-451 Figueira da Foz – Portugal<br />

Phone: +351 233 403 420<br />

info@unitedbiopolymers.com<br />

www.unitedbiopolymers.com<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

Albrecht Dinkelaker<br />

Polymer- and Product Development<br />

Talstrasse 83<br />

60437 Frankfurt am Main, Germany<br />

Tel.:+49 (0)69 76 89 39 10<br />

info@polyfea2.de<br />

www.caprowax-p.eu<br />

Treffert GmbH & Co. KG<br />

In der Weide 17<br />

55411 Bingen am Rhein; Germany<br />

+49 6721 403 0<br />

www.treffert.eu<br />

Treffert S.A.S.<br />

Rue de la Jontière<br />

57255 Sainte-Marie-aux-Chênes,<br />

France<br />

+33 3 87 31 84 84<br />

www.treffert.fr<br />

www.granula.eu<br />

2. Additives/Secondary raw materials<br />

Plant-based and Compostable PLA Cups and Lids<br />

Great River Plastic Manufacturer<br />

Company Limited<br />

Tel.: +852 95880794<br />

sam@shprema.com<br />

https://eco-greatriver.com/<br />

Minima Technology Co., Ltd.<br />

Esmy Huang, Vice president<br />

Yunlin, Taiwan(R.O.C)<br />

Mobile: (886) 0-982 829988<br />

Email: esmy@minima-tech.com<br />

Website: www.minima.com<br />

w OEM/ODM (B2B)<br />

w Direct Supply Branding (B2C)<br />

w Total Solution/Turnkey Project<br />

Naturabiomat<br />

AT: office@naturabiomat.at<br />

DE: office@naturabiomat.de<br />

NO: post@naturabiomat.no<br />

FI: info@naturabiomat.fi<br />

www.naturabiomat.com<br />

Natur-Tec ® - Northern Technologies<br />

4201 Woodland Road<br />

Circle Pines, MN 55014 USA<br />

Tel. +1 763.404.8700<br />

Fax +1 763.225.6645<br />

info@natur-tec.com<br />

www.natur-tec.com<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 51


9. Services<br />

10. Institutions<br />

10.1 Associations<br />

Suppliers Guide<br />

NOVAMONT S.p.A.<br />

Via Fauser , 8<br />

28100 Novara - ITALIA<br />

Fax +39.0321.699.601<br />

Tel. +39.0321.699.611<br />

www.novamont.com6. Equipment<br />

6.1 Machinery & moulds<br />

Buss AG<br />

Hohenrainstrasse 10<br />

4133 Pratteln / Switzerland<br />

Tel.: +41 61 825 66 00<br />

Fax: +41 61 825 68 58<br />

info@busscorp.com<br />

www.busscorp.com<br />

6.2 Degradability Analyzer<br />

MODA: Biodegradability Analyzer<br />

SAIDA FDS INC.<br />

143-10 Isshiki, Yaizu,<br />

Shizuoka,Japan<br />

Tel:+81-54-624-6155<br />

Fax: +81-54-623-8623<br />

info_fds@saidagroup.jp<br />

www.saidagroup.jp/fds_en/<br />

7. Plant engineering<br />

Osterfelder Str. 3<br />

46047 Oberhausen<br />

Tel.: +49 (0)208 8598 1227<br />

thomas.wodke@umsicht.fhg.de<br />

www.umsicht.fraunhofer.de<br />

Innovation Consulting Harald Kaeb<br />

narocon<br />

Dr. Harald Kaeb<br />

Tel.: +49 30-28096930<br />

kaeb@narocon.de<br />

www.narocon.de<br />

nova-Institut GmbH<br />

Chemiepark Knapsack<br />

Industriestrasse 300<br />

50354 Huerth, Germany<br />

Tel.: +49(0)2233-48-14 40<br />

E-Mail: contact@nova-institut.de<br />

www.biobased.eu<br />

Bioplastics Consulting<br />

Tel. +49 2161 664864<br />

info@polymediaconsult.com<br />

BPI - The Biodegradable<br />

Products Institute<br />

331 West 57th Street, Suite 415<br />

New York, NY 10019, USA<br />

Tel. +1-888-274-5646<br />

info@bpiworld.org<br />

European Bioplastics e.V.<br />

Marienstr. 19/20<br />

10117 Berlin, Germany<br />

Tel. +49 30 284 82 350<br />

Fax +49 30 284 84 359<br />

info@european-bioplastics.org<br />

www.european-bioplastics.org<br />

10.2 Universities<br />

Institut für Kunststofftechnik<br />

Universität Stuttgart<br />

Böblinger Straße 70<br />

70199 Stuttgart<br />

Tel +49 711/685-62831<br />

silvia.kliem@ikt.uni-stuttgart.de<br />

www.ikt.uni-stuttgart.de<br />

IfBB – Institute for Bioplastics<br />

and Biocomposites<br />

University of Applied Sciences<br />

and Arts Hanover<br />

Faculty II – Mechanical and<br />

Bioprocess Engineering<br />

Heisterbergallee 12<br />

30453 Hannover, Germany<br />

Tel.: +49 5 11 / 92 96 - 22 69<br />

Fax: +49 5 11 / 92 96 - 99 - 22 69<br />

lisa.mundzeck@hs-hannover.de<br />

www.ifbb-hannover.de/<br />

10.3 Other institutions<br />

GO!PHA<br />

Rick Passenier<br />

Oudebrugsteeg 9<br />

1012JN Amsterdam<br />

The Netherlands<br />

info@gopha.org<br />

www.gopha.org<br />

Green Serendipity<br />

Caroli Buitenhuis<br />

IJburglaan 836<br />

1087 EM Amsterdam<br />

The Netherlands<br />

Tel.: +31 6-24216733<br />

www.greenseredipity.nl<br />

EREMA Engineering Recycling<br />

Maschinen und Anlagen GmbH<br />

Unterfeldstrasse 3<br />

4052 Ansfelden, AUSTRIA<br />

Phone: +43 (0) 732 / 3190-0<br />

Fax: +43 (0) 732 / 3190-23<br />

erema@erema.at<br />

www.erema.at<br />

Michigan State University<br />

Dept. of Chem. Eng & Mat. Sc.<br />

Professor Ramani Narayan<br />

East Lansing MI 48824, USA<br />

Tel. +1 517 719 7163<br />

narayan@msu.edu<br />

Our new<br />

frame<br />

colours<br />

Bioplastics related topics, i.e.<br />

all topics around biobased<br />

and biodegradable plastics,<br />

come in the familiar<br />

green frame.<br />

All topics related to<br />

Advanced Recycling, such<br />

as chemical recycling<br />

or enzymatic degradation<br />

of mixed waste into building<br />

blocks for new plastics have<br />

this turquoise coloured<br />

frame.<br />

When it comes to plastics<br />

made of any kind of carbon<br />

source associated with<br />

Carbon Capture & Utilisation<br />

we use this frame colour.<br />

The familiar blue<br />

frame stands for rather<br />

administrative sections,<br />

such as the table of<br />

contents or the “Dear<br />

readers” on page 3.<br />

If a topic belongs to more<br />

than one group, we use<br />

crosshatched frames.<br />

Ochre/green stands for<br />

Carbon Capture &<br />

Bioplastics, e. g. PHA made<br />

from methane.<br />

Articles covering Recycling<br />

and Bioplastics ...<br />

Recycling & Carbon Capture<br />

We’re sure, you got it!<br />

As you may have already noticed, we are expanding our scope of topics. With the main target in focus – getting away from fossil resources – we are strongly<br />

supporting the idea of Renewable Carbon. So, in addition to our traditional bioplastics topics, about biobased and biodegradable plastics, we also started covering<br />

topics from the fields of Carbon Capture and Utilisation as well as Advanced Recycling.<br />

To better differentiate the different overarching topics in the magazine, we modified our layout.<br />

52 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


24/01/20 10:26<br />

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the next six <strong>issue</strong>s for €179.– 1)<br />

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young professionals<br />

1,2) € 99.-<br />

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Send a scan of your<br />

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or similar proof.<br />

Event Calendar<br />

Rethinking Materials<br />

04.05. - 05.05.2<strong>02</strong>2 - London, UK<br />

https://rethinkingmaterials.com/register<br />

The Renewable Materials Conference<br />

10.05. - 12.05.2<strong>02</strong>2 - Cologne, Germany<br />

https://renewable-materials.eu/<br />

7 th PLA World Congress<br />

by bioplastics MAGAZINE<br />

24.05. - 25.05.2<strong>02</strong>2 -Munich, Germany<br />

www.pla-world-congress.com<br />

2nd Annual Bioplastics Innovation Forum<br />

09.06. - 10.06.2<strong>02</strong>2 - Praque, Czech Republic<br />

www.interfoam.cn/en<br />

Interfoam 2<strong>02</strong>2<br />

15.06. - 17.06.2<strong>02</strong>2 - Shanghai, China<br />

www.interfoam.cn/en<br />

Plastics for Cleaner Planet - Conference<br />

26.06. - 28.06.2<strong>02</strong>2 - New York City Area, USA<br />

https://innoplastsolutions.com/conference<br />

You can meet us<br />

Events<br />

daily updated eventcalendar at<br />

www.bioplasticsmagazine.com<br />

Bioplastix India<br />

29.07. - 30.07.2<strong>02</strong>2 - Bangalore, India<br />

https://bioplastex.com/<br />

W.MATERBI.COM<br />

as orange peel<br />

Bioplastics - CO 2 -based Plastics - Advanced Recycling<br />

Bioplastics - CO 2 -based Plastics - Advanced Recycling<br />

Basics<br />

Plastic or no plastic -<br />

that’s the question 50<br />

Jan/Feb 01 / 2<strong>02</strong>2<br />

Highlights<br />

Thermoforming / Rigid packaging | 45<br />

Masterbatch / Additives | 24<br />

ISSN 1862-5258 March/April<br />

bioplastics MAGAZINE Vol. 17<br />

Vol. 17<br />

... is read in 92 countries<br />

... is read in 92 countries<br />

bioplastics MAGAZINE<br />

2007<br />

Highlights<br />

Automotive | 18<br />

Foam | 36<br />

Basics<br />

Biodegradation | 50<br />

rancia_bioplasticmagazine_01_<strong>02</strong>.2<strong>02</strong>0_210x297.indd 1 24/01/20 10:26<br />

... is read in 92 countries<br />

. is read in 92 countries<br />

ISSN 1862-5258<br />

Subject to changes.<br />

For up to date event-info visit https://www.bioplasticsmagazine.com/en/event-calendar/<br />

+<br />

or<br />

Use the promotion code ‘watch‘ or ‘book‘<br />

and you will get our watch or the book 3)<br />

Bioplastics Basics. Applications. Markets. for free<br />

(new subscribers only).<br />

1) Offer valid until 31 May 2<strong>02</strong>2.<br />

3) Gratis-Buch in Deutschland leider nicht möglich (Buchpreisbindung).<br />

Watch as long as supply lasts.<br />

bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17 53


Companies in this <strong>issue</strong><br />

Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />

ADEME 17<br />

Gema Polimers 51 Oak Ridge National Lab 16<br />

adidas 14<br />

Genomatica 32<br />

Oerlikon Textile 14<br />

Adsale 5 25 Ghent University 13<br />

Organic Waste Systems (OWS) 12<br />

Agrana Starch Bioplastics 50 Gianeco 50 Pack4Food 13<br />

Amerplast 41<br />

Global Biopolymers 10 50 PARP 21<br />

Avantium 38<br />

GO!PHA 8 52 PepsiCo 22<br />

BASF 18 50 Grafe 50,51 Phelan and Collender 44<br />

Bemis Associates 19<br />

Granula 51 Pilot Corporation 38<br />

Bentley 43<br />

Great River Plastic Manuf. 51 plasticker 48<br />

Bio4Pack 10 51 Green Dot Bioplastics 50 Polish Academy of Science 20<br />

Bio-Fed Branch of Akro-Plastic 50 Green Serendipity 13 52 PolyFerm 5<br />

Biofibre 51 GREENFILL3D 20, 21<br />

polymediaconsult 52<br />

Bioplastic Feedstock Alliance 46<br />

Gucci 43<br />

Porsche 43<br />

bioplastics MAGAZINE 6, 10, 11, 13, 22<br />

Helian Polymers 50 PTT/MCC 50<br />

Biotec 10, 12, 45 51,55 Huntsman 5<br />

RMIT University 28<br />

BMBF 15<br />

Inst. F. Bioplastics & Biocomposites 52 Rodenburg Biopolymers 13<br />

Borealis 8<br />

Institut f. Kunststofftechnik, Stuttgart 52 Institute für Textiltechnik (RWTH) 14, 15<br />

BPI 52 JinHui ZhaoLong High Technology 50 Saida 52<br />

Buss 21,52 K fair 5<br />

Schill+Seilacher 14<br />

CABAMIX 30<br />

Kaneka 51 Scion 39<br />

CAPROWAX P 36 51 Keen 5<br />

Shenzhen Esun Industrial 10<br />

Carbios 17<br />

Kingfa 50 Sicomin Epoxy Systems 39<br />

Carbon Minds 14<br />

Kompuestos 10, 33 50,51 SOSV 19<br />

carbonauten 26,27<br />

Lamborghini 43<br />

Sphera 8<br />

Casio Computer 40<br />

LanzaTech 16<br />

St1’s HelmiSimpukka 40<br />

Centexbel 10<br />

Lingrove 38<br />

Sukano 31 23,51<br />

Chanel 13<br />

Lubella 21<br />

Sulapac 12<br />

CHINAPLAS 5 25 LVMH Group 38<br />

Sulzer 6<br />

Clariant 24<br />

MASPEX 20, 21<br />

TECNARO 42, 43 51<br />

Covestro 14, 32<br />

McDonald's 22<br />

TerraVerdae Bioworks 5<br />

Croda Smart Materials 34, 35<br />

medi 14<br />

TianAn Biopolymer 51<br />

Customized Sheet Extrusion 51 Meditec, 39<br />

Tic Toys 42<br />

Decathlon 39<br />

Mercedes Benz 22<br />

TIME Ventures 19<br />

Diamond Edge Ventures 38<br />

Michigan State University 52 TNO 12<br />

Dr. Heinz Gupta Verlag 15 Microtec 50 TotalEnergies Corbion 8, 10 51<br />

Dupont 44<br />

Minima Technology 51 Toulouse White Biotechnology 17<br />

Earth Renewable Technologies 50 Mistletoe 19<br />

Toyota Tsusho Corporation 6<br />

Ekornes 18<br />

Mitsubishi Chemical Corporation 6, 38<br />

Treffert 51<br />

Elixance 37 51 Mixcycling 50 Trinseo 50<br />

Envisioning Partners 19<br />

NaKu 13, 41<br />

UBQ 22, 23<br />

Erema 52 Nanovia 37<br />

Uhde Inventa-Fischer 10<br />

European Bioplastics (EUBP) 6, 10, 31 52 narocon InnovationConsulting 52 United Biopolymers 51<br />

Filaticum 10<br />

Naturabiomat 51 Univ. Stuttgart (IKT) 52<br />

fischer group 48<br />

Natureplast-Biopolynov 51 Valo Ventures 19<br />

FKuR 10 2,5 NatureWorks 12, 44<br />

VARTDAL PLAST 18<br />

Floreon / Clariant 10<br />

Natur-Tec 51 W. Zimmermann 14<br />

Fraunhofer ICT 10, 42<br />

Neste 8<br />

WHO 5<br />

Fraunhofer IVV 10<br />

Northwestern University 16<br />

Woodly 41<br />

Fraunhofer UMSICHT 52 nova-institute 8 9,41,52 World Wildlife Fund 46<br />

freemee cosmetics 41<br />

Novamont 52,56 Xiamen Changsu Industries 50<br />

Galactic 10<br />

Novoloop 19<br />

Xinjiang Blue Ridge Tunhe Polyester 50<br />

Gehr 51 Nurel 50 Yangzhou Huitong Biological New Material 6<br />

Zeijiang Hisun Biomaterials 51<br />

Next <strong>issue</strong>s<br />

Issue<br />

Month<br />

Publ.<br />

Date<br />

edit/ad/<br />

Deadline<br />

Edit. Focus 1 Edit. Focus 2 Basics<br />

03/2<strong>02</strong>2 May/Jun 07.06.2<strong>02</strong>2 06.05.2<strong>02</strong>2 Injection moulding Beauty &<br />

Healthcare<br />

04/2<strong>02</strong>2 Jul/Aug 01.08.2<strong>02</strong>2 01.07.2<strong>02</strong>2 Blow Moulding Polyurethanes/<br />

Elastomers/Rubber<br />

05/2<strong>02</strong>2 Sep/Oct 04.10.2<strong>02</strong>2 <strong>02</strong>.09.2<strong>02</strong>2 Fiber / Textile /<br />

Nonwoven<br />

06/2<strong>02</strong>2 Nov/Dec 05.12.2<strong>02</strong>2 04.11.2<strong>02</strong>2 Films/Flexibles/<br />

Bags<br />

Building &<br />

Construction<br />

Consumer<br />

Electronics<br />

Biocompatability of PHA<br />

FDCA and PEF<br />

Feedstocks, different<br />

generations<br />

Chemical recycling<br />

Trade-Fair<br />

Specials<br />

Chinaplas Review<br />

K'2<strong>02</strong>2 Preview<br />

K'2<strong>02</strong>2 Review<br />

Subject to changes<br />

54 bioplastics MAGAZINE [<strong>02</strong>/22] Vol. 17


SMART<br />

SOLUTIONS<br />

FOR<br />

EVERYDAY<br />

PRODUCTS<br />

• Food contact grade<br />

• Odourless<br />

• Plasticizer free<br />

• Home and industrial<br />

compostable<br />

100%<br />

compostable<br />

(according to EN 13432)


WWW.MATERBI.COM<br />

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EcoComunicazione.it<br />

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