A system of physical chemistry - Index of

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A system of physical chemistry - Index of

io8 A SYSTEM OF PHYSICAL CHEMISTRY

Using the numerical values already employed for the hydrogen atom we

see that—

Wo = 2'0 X ID -11

erg.

-8

^0 = °*55 ^ i°~° cm.

0)0 = 6 "2 X lo^^ revolutions per second,

and therefore, for the system containing n electrons and charge Nc on

the nucleus—

W = 2-0 X io~^^ X «Fo2 . . . .

a = 2-0 X IO~^^ X «Fo^

0-55 X io-8/Fo

fc) = 6-2 X lO^^Fo^

In order to use these expressions in actual calculation it is necessary to

know Fo, i.e. (N - s„). Bohr gives the following table of values for $»

for various values of « up to « = 1 6. For n = i , ^„ is of course zero :—

n.

(i)

(ii)

(iii)

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