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2.3. Results<br />

2.3.1. Destruction of trichloroethylene<br />

Capítulo 2<br />

The trichloroethylene <strong>de</strong>struction process was studied in a helium <strong>plasma</strong> <strong>un</strong><strong>de</strong>r<br />

variable conditions as regards applied microwave power, gas flow-rate, inner diameter of<br />

the coupler tip and C2HCl3 concentration.<br />

2.3.1.1. Influence of the applied microwave power<br />

The principal mechanism for the <strong>de</strong>composition of residual molecules in non-<br />

equilibrium <strong>plasma</strong>s is via electron collisions. The efficiency of which increases when<br />

the amo<strong>un</strong>t of energy released to free electrons in the <strong>plasma</strong> increases. As a result, the<br />

electronic <strong>de</strong>nsity and temperature of the <strong>plasma</strong> have a direct impact on the efficiency<br />

with which contaminants can be <strong>de</strong>stroyed since the microwave energy supplied to the<br />

torch via the wavegui<strong>de</strong> is used to reach optimum efficiency [19, 20]; therefore,<br />

increasing the applied power increases the electron <strong>de</strong>nsity and temperature of the<br />

<strong>plasma</strong>, and the efficiency with which the compo<strong>un</strong>ds introduced in the main gas flow<br />

are <strong>de</strong>stroyed.<br />

C 2 HCl 3 concentration (ppb)<br />

60<br />

55<br />

50<br />

45<br />

40<br />

35<br />

30<br />

25<br />

20<br />

15<br />

10<br />

5<br />

0<br />

Total flow rate: 1.0 L/min<br />

C 2 HCl 3 : 1000 ppm<br />

Helium<br />

300 400 500 600 700 800 900 1000 1100 1200 1300 1400 1500<br />

Microwave Power (W)<br />

Figure 2.2: Variation of the C 2HCl 3 concentration in the helium <strong>plasma</strong> as a f<strong>un</strong>ction of the<br />

applied microwave power.<br />

53

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