kimia-anorganik-taro-saito

02.04.2017 Views

Indeks 2-pusat 2-elektron ............................................ 15 3-pusat 2-elektron ............................................ 66 Adisi oksidatif ................................................ 178 Afinitas elektron............................................... 33 Air 76 alkil homoleptik.............................................. 149 aluminosilikat................................................... 79 Aluminum trikhlorida...................................... 105 Amonia 63 Anomali fluorin ............................................... 101 antiferomagnetik............................................ 144 antiikatan ......................................................... 37 arachno 67 Arsen pentafluorida........................................ 104 asam 53 Asam fosfat ...................................................... 85 Asam fosfit ....................................................... 85 asam heteropoli ............................................... 94 asam isopoli ..................................................... 94 asam konjugat.................................................. 53 Asam nitrat....................................................... 83 Asam sulfat ...................................................... 86 Asam tiosulfat .................................................. 86 aturan 18 elektron.......................................... 153 aturan Hund...................................................... 41 Aturan Hund ....................................................... 6 aturan oktet...................................................... 14 aturan Wade ..................................................... 69 basa 53 basa konjugat................................................... 53 Belerang dioksida ............................................ 85 Belerang trioksida............................................ 86 Berilium khlorida............................................ 106 Besi (II)khlorida.............................................. 108 Besi(III)khlorida.............................................. 108 bilangan akseptor ............................................ 57 bilangan donor.................................................. 57 bilangan koordinasi.................................. 18, 124 Bilangan oksidasi ............................................. 50 blok d 9 blok f 9 blok p 9 blok s 9 Cesium khlorida ............................................... 26 Closo 67 deret elektrokimia............................................ 50 deret spektrokimia......................................... 141 Diagram Latimer............................................... 51 Diagram Tanabe-Sugano ................................141 diamagnetik....................................................142 diboran 65 Dinitrogen monoksida ......................................81 Dinitrogen pentoksida ......................................83 Dinitrogen trioksida..........................................82 donasi balik ....................................................147 efek penyamarataan.........................................55 elektrode hidrogen standar..............................47 elektrode kalomel jenuh...................................47 elektron konduksi.............................................15 eliminasi reduktif ...........................................178 Emas iodida ....................................................106 Energi bebas Gibbs...........................................47 Energi ionisasi ..................................................31 energi pemasangan ........................................131 energi penstabilan medan ligan.....................131 Entalpi 46 Entalpi kisi........................................................18 Entalpi pembentukan standar ..........................46 Entropi 46 feromagnetik ..................................................144 Fosfin 63 Fosfor hitam .....................................................73 Fosfor merah ....................................................73 Fosfor pentakhlorida ......................................104 Fosfor pentoksida.............................................84 Fosfor putih ......................................................72 Fosfor trifluorida.............................................103 Fosfor trioksida ................................................84 Fuleren 70 fungsi keasaman Hammett ..............................56 Gas mulia........................................................110 gaya dispersi ....................................................20 Grafit 69 halogen 99 Haptisitas .......................................................148 heksagonal terjejal...........................................21 hidrida molekular kompleks.............................61 hidrida salin ......................................................61 Hidrogen fluorida..............................................63 Hidrogen peroksida ..........................................76 Hidrogen sulfida ...............................................63 hipervalensi ......................................................14 HOMO 38 Hukum Curie ...................................................142 ikatan 37 ikatan koordinat ...............................................15 191

ikatan logam..................................................... 15 ikatan logam-logam.......................................... 15 intan 70 interaksi agostik ............................................ 150 interaksi London .............................................. 20 interaksi van der Waals ................................... 15 ion berkonfigurasi d n ...................................... 123 ion oksonium .................................................... 53 ion pseudohalida ............................................ 102 isomer optik ................................................... 127 jari-jari atomik.................................................. 18 jari-jari ionik ..................................................... 17 Kadmium iodida ............................................. 107 Kalsium fluorida ............................................. 109 Kalsium hidrida ................................................ 62 Kalsium khlorida ............................................ 109 katalis heterogen ........................................... 180 katalis Wilkinson............................................ 177 Katenasi ........................................................... 96 kation dioksigen............................................... 75 keadaan singlet................................................ 61 Keadaan standar .............................................. 47 keadaan triplet................................................. 61 Ke-elektronegativan......................................... 34 kekerasan dan kelunakan................................ 57 keramik maju.................................................... 91 kompleks ligan campuran.............................. 126 kompleks mono-inti.......................................... 11 konfigurasi elektron spin rendah ................... 132 konfigurasi elektron spin tinggi ..................... 132 konstanta kestabilan ..................................... 166 konstanta perisai ............................................. 31 kontraksi lantanida ........................................ 173 Kontraksi lantanoid.......................................... 18 korundum ......................................................... 91 Kromium(II) khlorida ...................................... 109 Kromium(III) khlorida ..................................... 109 kubus berpusat muka....................................... 22 kubus terjejal ................................................... 21 ligan khelat..................................................... 124 ligan monodentat ........................................... 124 ligan polidentat .............................................. 124 Litium hidrida ................................................... 62 Litium tetrahidridoaluminat ............................. 62 logam 10 logam alkali.................................................... 113 logam alkali tanah.......................................... 115 logam transisi awal........................................ 123 LUMO 38 medan kuat..................................................... 132 medan lemah.................................................. 132 medan ligan.................................................... 130 Mekanisme asosiatif ...................................... 167 Mekanisme disosiatif .....................................168 mekanisme koordinasi dalam ........................170 mekanisme koordinasi luar ............................170 Mekanisme pertukaran...................................167 Merkuri(II) khlorida.........................................105 molekul kecil ..................................................155 muatan inti efektif............................................31 Natrium tetrahidroborat ...................................62 nido 67 Nitrogen dioksida .............................................82 Nitrogen oksida ................................................81 nomor atom ........................................................4 nomor massa ......................................................4 non-ikatan.........................................................37 oksidasi 50 oksidator...........................................................50 oksigen singlet .................................................75 oksigen triplet ..................................................75 orbital molekul .................................................37 orbital terdepan................................................38 orto-hidrogen ....................................................61 Ozon 76 Paladium khlorida...........................................107 para-hidrogen ...................................................61 paramegnetisme.............................................142 penyaring molekular.........................................80 perbatasan........................................................57 peroksida..........................................................75 pi 38 Polihalogen .....................................................102 Polimorfisme.....................................................12 potensial reduksi standar ................................49 Prinsip kenetralan lisrik Pauling ......................15 Prinsip Pauli........................................................6 pseudorotasi Berry .........................................126 reaksi sisipan .................................................179 Reaksi sisipan ................................................178 reduksi 50 reduktor 50 sel satuan .........................................................12 senyawa Berthollida.........................................12 senyawa Daltonida. ..........................................12 Senyawa fasa Chevrel......................................99 senyawa non-stoikiometrik ..............................12 senyawa valensi campuran............................120 sigma 38 Silan 63 Spinel 92 spinel inversi ....................................................93 spinel normal ....................................................92 Struktur fluorit..................................................27 Struktur garam dapur .......................................25 struktur Keggin, ...............................................94 192

ikatan logam..................................................... 15<br />

ikatan logam-logam.......................................... 15<br />

intan 70<br />

interaksi agostik ............................................ 150<br />

interaksi London .............................................. 20<br />

interaksi van der Waals ................................... 15<br />

ion berkonfigurasi d n ...................................... 123<br />

ion oksonium .................................................... 53<br />

ion pseudohalida ............................................ 102<br />

isomer optik ................................................... 127<br />

jari-jari atomik.................................................. 18<br />

jari-jari ionik ..................................................... 17<br />

Kadmium iodida ............................................. 107<br />

Kalsium fluorida ............................................. 109<br />

Kalsium hidrida ................................................ 62<br />

Kalsium khlorida ............................................ 109<br />

katalis heterogen ........................................... 180<br />

katalis Wilkinson............................................ 177<br />

Katenasi ........................................................... 96<br />

kation dioksigen............................................... 75<br />

keadaan singlet................................................ 61<br />

Keadaan standar .............................................. 47<br />

keadaan triplet................................................. 61<br />

Ke-elektronegativan......................................... 34<br />

kekerasan dan kelunakan................................ 57<br />

keramik maju.................................................... 91<br />

kompleks ligan campuran.............................. 126<br />

kompleks mono-inti.......................................... 11<br />

konfigurasi elektron spin rendah ................... 132<br />

konfigurasi elektron spin tinggi ..................... 132<br />

konstanta kestabilan ..................................... 166<br />

konstanta perisai ............................................. 31<br />

kontraksi lantanida ........................................ 173<br />

Kontraksi lantanoid.......................................... 18<br />

korundum ......................................................... 91<br />

Kromium(II) khlorida ...................................... 109<br />

Kromium(III) khlorida ..................................... 109<br />

kubus berpusat muka....................................... 22<br />

kubus terjejal ................................................... 21<br />

ligan khelat..................................................... 124<br />

ligan monodentat ........................................... 124<br />

ligan polidentat .............................................. 124<br />

Litium hidrida ................................................... 62<br />

Litium tetrahidridoaluminat ............................. 62<br />

logam 10<br />

logam alkali.................................................... 113<br />

logam alkali tanah.......................................... 115<br />

logam transisi awal........................................ 123<br />

LUMO 38<br />

medan kuat..................................................... 132<br />

medan lemah.................................................. 132<br />

medan ligan.................................................... 130<br />

Mekanisme asosiatif ...................................... 167<br />

Mekanisme disosiatif .....................................168<br />

mekanisme koordinasi dalam ........................170<br />

mekanisme koordinasi luar ............................170<br />

Mekanisme pertukaran...................................167<br />

Merkuri(II) khlorida.........................................105<br />

molekul kecil ..................................................155<br />

muatan inti efektif............................................31<br />

Natrium tetrahidroborat ...................................62<br />

nido 67<br />

Nitrogen dioksida .............................................82<br />

Nitrogen oksida ................................................81<br />

nomor atom ........................................................4<br />

nomor massa ......................................................4<br />

non-ikatan.........................................................37<br />

oksidasi 50<br />

oksidator...........................................................50<br />

oksigen singlet .................................................75<br />

oksigen triplet ..................................................75<br />

orbital molekul .................................................37<br />

orbital terdepan................................................38<br />

orto-hidrogen ....................................................61<br />

Ozon 76<br />

Paladium khlorida...........................................107<br />

para-hidrogen ...................................................61<br />

paramegnetisme.............................................142<br />

penyaring molekular.........................................80<br />

perbatasan........................................................57<br />

peroksida..........................................................75<br />

pi 38<br />

Polihalogen .....................................................102<br />

Polimorfisme.....................................................12<br />

potensial reduksi standar ................................49<br />

Prinsip kenetralan lisrik Pauling ......................15<br />

Prinsip Pauli........................................................6<br />

pseudorotasi Berry .........................................126<br />

reaksi sisipan .................................................179<br />

Reaksi sisipan ................................................178<br />

reduksi 50<br />

reduktor 50<br />

sel satuan .........................................................12<br />

senyawa Berthollida.........................................12<br />

senyawa Daltonida. ..........................................12<br />

Senyawa fasa Chevrel......................................99<br />

senyawa non-stoikiometrik ..............................12<br />

senyawa valensi campuran............................120<br />

sigma 38<br />

Silan 63<br />

Spinel 92<br />

spinel inversi ....................................................93<br />

spinel normal ....................................................92<br />

Struktur fluorit..................................................27<br />

Struktur garam dapur .......................................25<br />

struktur Keggin, ...............................................94<br />

192

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