Combustion and Sustainable Development - Italian Section of the ...

Combustion and Sustainable Development 

25 th Event of the Italian Section of the Combustion Institute 

9.30-9.45 Opening 

9.45-10.30 Opening Lecture 

Sala del Tempio di Adriano 

June 3-5, 2002 

PROVISIONAL PROGRAM 

Monday, 3 

Ultrafine Particles from Combustion: Scientific and Environmental Issues 

A. D’Alessio 

Dipartimento di Ingegneria Chimica, Università di Napoli "Federico II", Napoli, Italy 

10.30-12.30 Session I: Novel Fuels and Processes 

I.1 Preliminary Kinetic Analysis of Biogas Combustion under Diluted Condition 

G. Calchetti, V. Visentin, S. Giammartini 

ENEA - C. R. Casaccia, Sec. ING-TECO, Roma, Italy 

I.2 Mathematical Modelling of Electric Field-Activated Combustion Reactions 

M. Pisu*, A. Cincotti**, A. M. Locci**, R. Orrù*, and G. Cao** 

* CRS4, UTA , Cagliari, Italy 

** Dipartimento di Ingegneria Chimica e Materiali, Università degli Studi di Cagliari, Italy 

I.3 Mild Combustion in a Laboratory - Scale Apparatus 

A. Effuggi, D. Gelosa, R. Rota 

Dip. CMIC / CIIRCO, Politecnico di Milano, Italy 

I.4 Extinction of N2 Diluted N-Heptane Non-Premixed Counterflow Flames 

P. Berta*, I.K. Puri*, S. Granata**, T. Faravelli**, E. Ranzi** 

* University of Illinois at Chicago, USA 

** Dipartimento di Chimica, Materiali e Ingegneria Chimica, Politecnico di Milano, Italy 

I.5 Flameless Combustion: from Furnaces to New Applications 

A. Milani, J.G. Wünning 

WS GmbH, Germany 

I.6 Experimental Identification of Bifurcation Points in Methane Oxidation 

M. de Joannon*, A. Tregrossi*, A. Cavaliere** 

* Istituto di Ricerche sulla Combustione - CNR, Napoli, Italy 

** Dipartimento di Ingegneria Chimica, Università di Napoli "Federico II", Napoli, Italy 

I.7 Numerical Simulation of a H2/Air Turbulent Non-Premixed Flame 

R. Malagnino *, E. Giacomazzi**, C. Bruno*, G. Calchetti**, M. Rufoloni** 

* Department of Mechanics and Aeronautics - Università "La Sapienza", Rom, Italy 

** ENEA - C. R. Casaccia, Sec. ING-TECO, Roma, Italy 

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I.8 Study of the Stabilising Effect of Hydrogen in Lean Premixed Combustors 

A. Di Benedetto 

Istituto di Ricerche sulla Combustione - CNR, Napoli, Italy 

12.30-13.30 Session II/1: Combustion in Practical Systems 

II.1 Kinetic Modelling of Liquid Fuel Combustion 

S. Granata, R. Del Rosso, T. Faravelli, E. Ranzi 

Dipartimento di Chimica, Materiali e Ingegneria Chimica, Politecnico di Milano, Italy 

II.2 Validation of a Discrete Ordinate Flux Method for Design and Performance Prediction 

of Cylindrical Combustors 

M. Filla 

Dipartimento di Processi Chimici dell'Ingegneria, Universita' di Padova, Italy 

II.3 Cooling Control of Hot Exhaust Gases for Low NO2 Emissions 

E. Baraldi, G. Fogliani 

Worgas Bruciatori, Formigine (MO), Italy 

II.4 Characterization of Chemical Compounds Produced in a Steam Generator Tested in 

Reburning Conditions 

E. Ricci*, G. Giammartini*, C. Benedetti*, F. Di Carlo*, A. L'Insalata**, A. Saponaro**, L. Fortunato** 

* ENEA - C. R. Casaccia, Roma, Italy 

** ANSALDO CALDAIE - Centro Combustione Ambiente, Gioia del Colle, Italy 

13.30-15.15 Brunch Break 


II.5 LES of an Industrial Burner 

E. Giacomazzi, G. Calchetti, M. Rufoloni 

ENEA - C. R. Casaccia, Sec. ING-TECO, Roma, Italy 

II.6 Numerical Simulation of Strong Swirling Confined Flame by CFD Calculation 

A. Frassoldati*, S. Frigerio*, T. Faravelli*, E. Colombo**, F. Inzoli** 

* Dipartimento di Chimica, Materiali e Ingegneria Chimica, Politecnico di Milano, Italy 

** Dipartimento di Energetica, Politecnico di Milano, Italy 

II.7 Comparison between PIV Measurements and CFD Simulation on a Model of GT Annular 

Burner 

D. Giordano, S. Giammartini, M. Rufoloni, G. Calchetti, F. Manfredi, E. Giacomazzi 

ENEA - Engineering Division CR Casaccia, Roma, Italy 

II.8 Fluid Dynamic and Thermal Analysis of an Industrial Natural Gas Burner 

P. Gennaro*, G. Scribano**, L. Galfetti**, A. Coghe**, G. Solero** 

* C.I.T.T. Impianti Srl , Bollate MI, Italy 

** Dipartimento di Energetica, CIIRCO, Politecnico di Milano, Italy 

16.15-16.30 Coffee Break 

16.30-18.00 Session III: Internal Combustion Engines 

III.2 CFD Modelling of a Lean-Lean-Premixed-Staged Combustion Chamber 

D. Valentini*, A. Barresi*, E. Carrea** 

* Politecnico di Torino, Italy 

** Alstom Power Technology Center, Baden-Daettwil, Switzerland 

III.3 NOx Formation in the Rich Quench Lean Combustion Mode: Chemical Kinetic Modelling 

L. Miccoli*, A. Barresi*, E. Carrea** 

* Politecnico di Torino, Italy 

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** Alstom Power Technology Center, Baden-Daettwil, Switzerland 

III.1 Modeling of Spark Ignition Engines with Tumble Swirl 

U. Martin*, R. Rota*, S. Carrà*, A. Dominici** 

* Dip. CMIC / CIIRCO, Politecnico di Milano, Italy 

** Ferrari Spa, Italy 

III.4 Combustion Control by Multiple Injection in Common Rail D.I. Engines 

C. Beatrice*, P. Belardini*, C. Bertoli*, M.na Migliaccio*, C. Guido** 

* Istituto Motori - CNR Napoli, Italy 

** DIME Università Federico II, Napoli, Italy 

III.5 Further Knowledge on the Effect of Fuel Formulation on Diesel Combustion 

C. Beatrice*, C. Bertoli*, N. Del Giacomo*, M. Lazzaro*, C. Guido** 

* Istituto Motori - CNR Napoli, Italy 

** DIME Università Federico II, Napoli, Italy 

III.6 DEAL : A New Concept For Diesel Combustion 

C. Beatrice, C. Bertoli, N. del Giacomo, M. Migliaccio 

Istituto Motori - CNR Napoli, Italy 

8.30-9.15 Invited Lecture 

Tuesday, 4 

Life Cycle Assessment: science, philosophy or divination? 

U. Arena 

Dipartimento di Scienze Ambientali, II Università di Napoli, Italy 

9.15-10.45 Session IV/1: Coal, Biomass and Waste 

IV.1 Modeling of Molecular Weight Distribution of Tars from Coal Pyrolysis 

G. Migliavacca*, E. Parodi*, L. Bonfanti**, T. Faravelli***, E. Ranzi*** 

* Stazione Sperimentale dei Combustibili. S. Donato Milanese, Italy 

** ENEL Produzione-Ricerca, Pisa, Italy 

*** Dipartimento di Chimica, Materiali e Ingegneria Chimica, Politecnico di Milano, Italy 

IV.2 Kinetic Modelling of Emissions from Liquid Fuel FBC 

A. Frassoldati*, T. Faravelli*, E. Ranzi*, M. Miccio**, F. Miccio*** 

* Dipartimento di Chimica, Materiali e Ingegneria Chimica, Politecnico di Milano, Italy 

** Dipartimento di Ingegneria Chimica ed Alimentare, Università di Salerno, Italy 

*** Istituto di Ricerche sulla Combustione - CNR Napoli, Italy 

IV.3 Sound Assisted Fluidized Bed Combustion 

A. Cammarota, M. Urciuolo, R. Chirone 


IV.4 Loss of Gasification Reactivity towards O2 and CO2 upon Heat Treatment of Carbons 

O. Senneca*, P. Salatino** 


** Dipartimento di Ingegneria Chimica, Università di Napoli “Federico II”, Napoli, Italy 

IV.5 Puff Production during Incineration of Sewage Sludge Spiked with Chlorinated 

Hydrocarbons 

G. Mininni*, G. Mascolo** 

* Istituto di Ricerca sulle Acque, CNR, Roma, Italy 

** Istituto di Ricerca sulle Acque, CNR, Bari, Italy 

IV.6 Metal Enrichment in Solid Residues Produced in Sludge Incineration by a Fluidized-Bed 

Furnace 

D. Marani, C.M. Braguglia, G. Mininni 

Istituto di Ricerca sulle Acque, CNR, Roma, Italy 

3



IV.7 The Influence of the Hydration Time on Spent Sorbents Reactivation for Fluidized-Bed 

Desulphurization Processes 

F. Montagnaro*, P. Salatino*, S. Russo**, F. Scala**, C. Zucchini** 

* Dipartimento di Ingegneria Chimica, Università di Napoli “Federico II”, Napoli, Italy 

** Istituto di Ricerche sulla Combustione - CNR, Napoli, Italy 

IV.8 Selective Depolymerization of Polyethylene 

D. Pedol, P. Canu 

Dipartimento di Principi e Impianti di Ingegneria Chimica, Università di Padova, Italy 

IV.9 Fuels and Combustible Wastes 

G. Mininni*, R. Chirone** 

* Istituto di Ricerca sulle Acque, CNR, Roma, Italy 


IV.10 Characterization of Biomass Residue after Devolatilization in Different Operative 

Conditions 

E. Biagini*, L. Tognotti** 

* Dipartimento di Ingegneria Chimica, Università di Pisa, Italy 

** ENEL Produzione S.p.A. - Ricerca, Pisa, Italy 

IV.11 Sub-Models for the Devolatilization of Biomass Fuels 

E. Biagini, C. Grassi, L. Tognotti 

Dipartimento di Ingegneria Chimica, Università di Pisa, Italy 

IV.12 Deposit Prediction from Coal-Biomass Co-Combustion 

A.Bianchi, M. Cioni, N. Pintus 

ENEL Produzione S.p.A. - Ricerca, Pisa, Italy 

IV.13 Combustion Behaviour of Fast Pyrolysed Coal, Biomasses and Their Blends 

P. Ciambelli, V. Palma, P. Russo, S. Vaccaro, V. Vaiano 

Dipartimento di Ingegneria Chimica e Alimentare, Università di Salerno, Fisciano, Italy 

IV.14 The Environmental Performance of Alternative Solid Waste Management Options: A 

Life-Cycle Assessment Approach to the Study 

U. Arena, M.L. Mastellone, F. Perugini. 

Dipartimento di Scienze Ambientali, II Università di Napoli, Italy 

13.00-14.00 Lunch Break 


IV.15 Chemical Characterization of Liquids Products from Wood Pyrolysis 

C. Branca 

Dipartimento di Ingegneria Chimica, Università "Federico II", Napoli, Italy 

IV.16 Modelling the Combustion of Moist Wood 

A. Galgano 

Dipartimento di Ingegneria Chimica, Università "Federico II", Napoli, Italy 

IV.17 Development of a Commercial FB Boiler for Combustion of Renewable Fuels at Small 

Scale 

A. Cante*, A. De Riccardis**, C. Liccardi*, F. Miccio*, A. Silvestre* 


** Tekne srl, Galatina LE, Italy 

4

IV.18 Char Combustion Ketics of Biomasses: a Database for Industries 

N. Rossi*, M. Falcitelli**, P. Ghetti* 

* ENEL S.p.A. Produzione Ricerca, Pisa, Italy 

** Consorzio Pisa Ricerche, Pisa, Italy 

15.00-16.00 Session V: Catalytic Combustion and Combustion 

Synthesis of Materials 

V.1 Detailed Surface Chemistry and CFD Simulation of CO Catalytic Combustion 

S. Segato*, M. Perini*, H. Kusar**, P. Canu* 

* Dipartimento di Principi e Impianti di Ingegneria Chimica, Università di Padova, Italy 

** Royal Institute of Technology, Dept. of Chemical Engineering and Chemical Technology, 

Stockholm, Sweden 

V.2 Mechanisms and Kinetics of Catalytic Combustion of Diesel Soot 

D. Fino, P. Fino, G. Saracco, V. Specchia 

Dipartimento di Scienza dei Materiali ed Ingegneria Chimica, Politecnico di Torino, Italy 

V.3 Catalytic Combustion of Light Alkanes in a Fludized Bed Reactor under Fuel-Lean 

Conditions 

M. Iamarino*, R. Chirone**, R. Pirone**, P. Salatino***, G. Russo** 

* Dip. di Ingegneria e Fisica dell'Ambiente, Università della Basilicata, Potenza, Italy 


*** Dipartimento di Ingegneria Chimica, Università "Federico II", Napoli, Italy 

V.4 Combustion Synthesis of Perovskite Catalysts 

S. Biamino, A. Civera, M. Pavese, P. Fino, G. Saracco, C. Badini 




II.9 A Swirl Natural Gas Flame as a Test-Case for Experimental Analysis and Numerical 

Simulation 

A. Frassoldati, G. Solero, A. Coghe, T. Faravelli, 

CIIRCO - Centro Interdipartimentale di Ricerche sulla Combustione, Politecnico di Milano, Italy 

II.10 Analysis and Prediction of Flash-Back in Premix Porous Burners for Domestic Appliances 

M. Bizzi, G. Saracco, V. Specchia 


II.11 DME Combustion in Domestic Cooking Appliances: Comparison with LPG 

G. Migliavacca*, E. Parodi*, M. Marchionna**, L. Pellegrini*** 

* Stazione Sperimentale per i Combustibili, San Donato Milanese MI, Italy 

** SNAM Progetti SpA, San Donato Milanese MI, Italy 

*** Agip Petroli SpA, San Donato Milanese MI, Italy 

II.12 Prediction of Flammabile Limits of Mixtures in Non Standard Conditions. 

M. Milli, M. De Lucca, R. Rota 

Dip. CMIC / CIIRCO, Politecnico di Milano, Italy 

II.13 Effects of Different Fuels in a Trapped Vortex Combustor 

M. Losurdo*, C. Bruno*, G. Calchetti**, E. Giacomazzi**, M. Rufoloni** 

* Department of Mechanics and Aeronautics - Università "La Sapienza", Roma, Italy 

** ENEA - C. R. Casaccia, Sec. ING-TECO, Roma, Italy 

II.14 Turbulent Structures Characterization in a Bluff-Body Premixed Flame 

E. Giacomazzi*, V. Battaglia**, C. Bruno*** 

* ENEA - C. R. Casaccia, Sec. ING-TECO, Roma, Italy 

** CRS4 - Cagliari, Italy 

*** Department of Mechanics and Aeronautics - University "La Sapienza", Roma, Italy 

5

II.15 Interaction of Combustion and Atomization Processes in Electrosprays Burning 

R. Ragucci*, A. Cavaliere**, O. Campagna** 



II.16 Mathematical and Modelling of Flameless Combustion for Micro-CHP System 

Development 

M. Malfa*, M. Venturino*, V. Tota** 

* ABB Service Srl – Research Division - Sesto San Giovanni, Milano, Italy 

** Dipartimento di Energetica –Politecnico di Milano, Milano, Italy 

18.15 Meeting of the Members of the Italian Section of The 

Combustion Institute 

9.00-9.45 Invited Lecture 

title to be defined 

A.G. Federico 

ENEA, Italy 

Wednesday, 5 

9.45-10.45 Session VI/1: Combustion Diagnostics 

VI.1 Absolute Concentrations of Radical C2 in Atmospheric Pressure Hydrocarbon Flames 

M. Marrocco*, M. D'Apice*, S. Giammartini*, M. Magaldi**, G. P. Romano** 

* ENEA - Engineering Division CR Casaccia, Roma, Italy 

** Department of Mechanics and Aeronautics - Università "La Sapienza", Roma, Italy 

VI.2 Optical Emission Spectroscopy On a Mild Combustor 

M. Marrocco, V. Visentin, M. D'Apice, S. Giammartini 

ENEA - Engineering Division CR Casaccia, Roma, Italy 

VI.3 PIV Post Processing Methods Applied on High Turbulent GT Burners Flames 

D. Giordano*, C. Willert**, S. Giammartini*, R. Gallodoro*** 

* ENEA - Engineering Division CR Casaccia, Roma, Italy 

** DLR, Köln, Germany 

*** Department of Mechanics and Aeronautics - Università "La Sapienza", Roma, Italy 

VI.4 Multiangular Light Scattering Measurements from Soot Fractal Aggregates in Laminar 

Diffusion Flames 

S. De Iuliis, F. Cignoli, and G. Zizak 

Istituto per l'Energetica e le Interfasi - CNR Sez. Milano, Italy 


11.00-12.30 Session VI/2: Combustion Diagnostics 

VI.5 Extra Situ-DLS Measurements on Nanoparticles Produced in Laminar Premixed Flames 

D. Cecere*, P. Minutolo**, A. D'Alessio* 

* Dipartimento di Ingegneria Chimica, Università "Federico II", Napoli, Italy 


VI.6 Characterization of Combustion Produced Nanoparticles by Atomic Force Microscopy 

C. Barone, A. D'Alessio, A. D'Anna 


6

VI.7 Matrix-Assisted Laser Desorption/Ionization Time-of-Flight (MALDI-TOF) Mass 

Spectrometry in the Analysis of Fuel-Rich Combustion Products: a Preliminary Study 

B. Apicella*, M. Millan**, A.A. Herod**, R. Kandiyoti** 


** Department of Chemical Engineering, Imperial College, London, United Kingdom 

VI.8 Diagnostics of Gas Mixing in Bubbling Fluidized Beds 

R. Solimene*, A. Telesca*, A. Marzocchella*, R. Ragucci**, P. Salatino* 

* Dipartimento di Ingegneria Chimica – Università di Napoli “Federico II”, Napoli, Italy 


VI.9 Identification of Average "Hidden" Features of Multiphase Flows Through High Order 

Statistical Momenta of Quantitative Images 

R. Ragucci*, A. Cavaliere**, A. Sgambati** 



VI.10 Ultraviolet Light Absorption in Flame, Engine Exhausts and Urban Atmosphere 

A. Borghese*, G. Basile**, A. D’Alessio** 

* Istituto Motori - CNR, Napoli, Italy 


12.30-13.30 Session VII/1: Pollutant Formation and Control 

VII.1 Dry Flue Gas Desulphurization: Adsorption Mechanism and Sorbent Reactivation 

M. Derudi*, M. Suardi*, D. Gelosa*, R. Rota*, S. Malloggi**, E. Sani** 

* Dip. CMIC / CIIRCO, Politecnico di Milano, Italy 

** ENEL DP / Ricerca, Pisa, Italy 

VII.2 Kinetic Scheme of Thermal Decomposition of Polyvinylchloride 

A. Marongiu, F. Robecchi, T. Faravelli, G. Bozzano, M. Dente, E. Ranzi 

Dipartimento di Chimica, Materiali e Ingegneria Chimica, Politecnico di Milano, Italy 

VII.3 Wall-Flow Catalytic Traps for Diesel Particulate Abatement from Mobile Sources 

E. Cauda, D. Fino, N. Russo, G. Saracco, V. Specchia 


VII.4 Emissions from Light Oil Fluidized Combustion: Preliminary Application of an optical 

technique 

C. Allouis*, F. Beretta*, F. Miccio*, M. Miccio**, G. Olivieri** 


** Dipartimento di Ingegneria Chimica ed Alimentare, Università di Salerno, Italy 

13.30-14.30 Lunch Break 

14.30-16.45 Session VII/2: Pollutant Formation and Control 

VII.5 Carbonisation Rates of Carbonaceous Particles in Premixed Laminar Flames of Ethylene- 

Air 

A. Rolando*, G. Basile*, P. Minutolo**, A. D'Anna*, A. D'Alessio * 

* Dipartimento di Ingegneria Chimica, Università degli Studi di Napoli "Federico II", Napoli, Italy 


VII.6 Aspetti Ambientali della Combustione Stazionaria 

F. Beretta*, A. Borghese*, G. Cascio***, A. D'Alessio****, A. Pini*** 


** Istituto Motori - CNR, Napoli, Italy 

*** Agenzia Nazionale per la Protezione dell'Ambiente 

**** Dipartimento di Ingegneria Chimica, Università degli Studi di Napoli "Federico II", Napoli, Italy 

VII.7 Self-Propagating Reactions for Environmental Protection: State of the Art 

D. Carta, R. Orrù, G. Cao 

Dipartimento di Ingegneria Chimica e Materiali, Università di Cagliari, Italy 

7

VII.8 Modelling In-Duct Mercury Removal by Activated Carbon Injection in Coal-Fired Power 

Plants Flue Gas 

F. Scala 


VII.9 Pilot-Scale Tests of Mercury Removal in Coal Flue Gas through Sorbent Injection 

N. Pintus*, A. Bianchi*, V. Borghini** 

* ENEL Produzione S.p.A. - Ricerca, Pisa, Italy 

** Università degli Studi di Pisa, Italy 

VII.10 Size-Dependent Coagulation of Small Carbonaceous Particles at High Temperature. 

M. Mancini Tortora, A. D'Anna, A. D'Alessio 


VII.11 Optical and Spectroscopic Characterization of a Coflow Ethylene/Air Flame 

C. Allouis*, F. Beretta*, A. D'Alessio**, A. D'Anna**, P. Minutolo* 



VII.12 Molecular Weight Evaluation of Combustion Related Materials 

B. Apicella, R. Barbella, R. Ciajolo, A. Tregrossi 


VII.13 Co and Ag Exchanged Zeolites in NOx Lean CH4-SCR 

P. Ciambelli, D. Sannino, M.C. Gaudino, I. Buonomo 

Dipartimento di Ingegneria Chimica e Alimentare, Università di Salerno, Fisciano, Italy 

16.45 Concluding Remarks 

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