Nomenclature-Solution-for-WEB

Solution of Nomenclature
Hydrocarbon
1 2,2,4-Trimethylpentane
2 3-Ethyl-2-methylpentane
3 3,3-Dimethylbutene
4 2-Methylbuta-1,3-diene
5 2-Ethyl-3-methylbuta-1,3-diene
6 Hex – 1 – ene – 4 – yne
7 3-Methylbutyne
8 2,2,4,4-Tetramethylpentane
9 2,2 – Dimethylpropane
10 3,3-Diethylpentane
11 But-1-en-3-yne
12 Hex-4-enyne
13 Hex-1-en-4-yne
14 Penta-2,3-diene
15 2-Methylbuta-1,3-diene
16 2 – Methylpenta – 1, 4 – diene
17 3-Methylhepta-1,3,5-triene
18 3-Methylhexa1,5-diyne
Hydrocarbon Branch in
Branch
1 2, 3, 5 – Trimethyl – 4 - propylheptane
2 5–(1, 1–Dimethylpropyl)–5–(2–methyl–
propyl)nonane
3 4-Ethyl-3,5,6-trimethyloctane
4 2,3-Dimethyl-4-propyloctane
5 4-(1,2-Dimethyl)-3-ethyl-4,7-dimethyldecane
6 4,4-bis-(1-Methylethyl)heptane
7 3-(1,1-Dimethylethyl)-7-(2-methylpropyl)decane
8 3, 7 – Diethyl – 2, 2 – dimethyl – 4 –
propylnonane
9 2, 2 – Dimethyl – 5 – (1, 1, 2 – trimethylpropyl)
nonane
Compounds With One
Functional Group
1 2,2-Dichlorobutane
2 1-Bromo-3-chloro-2-iodopropane
3 1,2-Dichlorobutane
4 2 – Methylpropan – 1 – ol
5 3 – Methylbutan – 2 – ol
6 2-Methylpropan-2-ol
7 2-Methyl-propane1,3-diol
8 Propane-1,2,3-triol
9 Methoxymethane
10 Methoxyethane
11 2 – Methoxybutane
12 2-Methoxypropane
13 2-Ethoxy-3-methoxybutane
14 1,2-Dimethoxyethane
15 2-Methylbutanal
`16 Ethane1,2-dial
17 Propan2-one
18 Butan-2-one
19 Pentane – 2, 4 – dione
20 2-Methylpentane-2,3-dione
21 2 – Methylpropanoic acid
22 2-Methylbutanoic acid
23 2,2-Dimethylpropanoic acid
24 2,4-Dimethylhexanoic acid
25 Ethane-1,2-dioic acid
26 Butane-1,4-dioic acid
27 Butane-1,2-dinitrile
28 Butane-1,4-diamide
29 2-Methylbutane-1,4-dial
30 N,N-Dimethylmethanamine
31 3-Methylpropanamine
32 N-Methylethanamine
33 Bis-(N-methyl)methanamine
34 N,N-dimethybutan-2-amine
35 2-Methylpropanthiol
36 Ethanoic anhydride
37 Ethanoicpropanoic anhydride
38 Ethylethanoate
39 Methylmethanoate
40 Methylethanoate
41 Ethylmethanoate
42 Isopropyl-3-methylbutanoate
Polyfunctional Group
1 3-Bromopropanal
2 But – 3 – enoic acid
3 3 - Hydroxybutanal
4 3 - Chlorobutanamide
5 1-Chloropropan-2-one
6 3-Hydroxybutanoic acid
7 4-Ketopentanal
8 3- Bromopropanoylbromide
9 Ethyl-3-ketobutanoate
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Solution of Nomenclature
10 Ethyl-3-aminobutanoate
11 3-Formylbutanoic acid
12 Ethylbut-2-enoate
13 1 – Hydroxy – 4 – methylpentan – 3 – one
14 4 – Hydroxy – 2 – methylbutanoic acid
15 Hex – 3 – ene – 1,2 – dioic acid
16 6-Amino-5-chloro-4-oxoheptanoic acid
17 Methyl-6-cyano-4-methoxyhexanoate
18 2-Amino-3-hydroxy-4-oxopentanoic acid
19 5-Formyl-3-oxopentanoic acid
20 3-Hydroxy-N,N-dimethylbutanamide
21 4 – Bromo – 3 – chloro – 6 – nitro octane
22 3 – (1 – Chloroethyl) – 4 – methyl – 4 –
phenylpentan – 2 – one
23 Ethyl – 3 – hydroxybutanoate
24 3 – Methoxypentanoylchloride
25 4 – (2– Butenyl) – non – 6 – enoic acid
26 (1 – Methylethyl) propanoate or
Isopropylpropanoate
27 1-Formylmethanoic acid
BondLine
1 3-Methylhexane
2 3,3,4-Trimethyloctane
3 2,2,6,6-Tetramethyloctane
4 1-Cyclopropyl-3-methylpentene
5 3, 3 – Diethylpentane
6 5-(1,2-Dimethylpropyl)decane
7 5-Butyldec-3-ene
8 4-(1-Methylethyl)-oct-2-ene
9 5 – (1, 2 – Dimethyl propyl) nonane
10 5-Ethyl-4,6-dimethylocta-1,4-diene
11 3,4-Dipropylhepta-1,3,5-triene
12 5,6-Diethyl-3-methyldec-4-ene
13 7 – Ethyl – 2, 4, 5, 6 – tetramethyldec – 1, 8 –
diene
14 3,7-Dimethylocta-1,3,6-triene
15 3-Methylhexa-1,3,5-triene
16 Hexa-2,4-diyne
17 3,3-Dimethylpent-1-ene-4-yne
18 Oct-1-en-4-yne
19 4-Ethyl-2-cyclopropylhexene
20 4-Ethyl-hex-4-ene-2-ol
21 2-(2-Chloropropyl)hexa-1,3,5-triene
22 1-Chloro-3-ethyl-2-pentanone
23 3,4-Dimethylpent-1-en-3-ol
24 3-Hydroxy-3-methyl-butanoic acid
25 3,3,5-Trimethyl-hex-1-en-2-ol
26 Ethane-1,2-dioic acid
27 Propanoic Anhydride
28 2 – Ethyl – 3 – methyl pent – 2 – en – 1 – al
29 5 – Ethyl – 4 – methyl non – 4 – enoic acid
30 5 – Ethyl – 3 – methyl octanoic acid
31 3-Hydroxy-5-ketohexanoic acid
32 5 – Methyl – 3, 6 – octadien – 4 – ol
33 3,7-Dimethylocta-2,6-dienal
34 2,6-Dimethylhepta-2,5-dienoic acid
35 Ethyl-2-cyanopropanoate
36 N-Ethyl-N-methyl-2-aminopropane
37 3(N,N-Dimethyl)-3-ethylpentanamine
38 N,N-Diemethylbutanamide
AliCyclic Compound
1 Cyclododecane
2 Methylcyclohexane
3 Ethylcyclopentane
4 1-Ethyl-5-methylcyclohexane
5 (2-Propyl)cyclohexane
6 1, 3, 5 – Tris (hexyl) cyclohexane
7 1-Ethyl-2-methyl-5-propylcyclohexane
8 Cyclohexylcyclohexane
9 1,2-Dicyclohexylethane
10 Cyclopropylpropane
11 Cyclobutylbutane
12 1 – Cyclobutylpentane
13 2 – Cyclopropylbutane
14 3 – Cyclobutylpentane
15 (2 – Butyl) cyclopentane
16 1, 3 – Dicyclohexylpropane
17 Dicyclopropyl methane
18 1, 1, 2, 4 – Tetraethyl – 3 – methyl cyclobutane
19 3-Methyl-1-cyclohexyne
20 1-Cyclohexylethene
21 3-Ethylcyclopent-1-ene
22 4 – Cyclobutylbut – 1 – ene
23 2-Ethenyl-3-methylcyclohexa-1,3-diene
24 4-Cyclohexylbut-3-en-2-ol
25 3-Methylcyclopentan-1-ol
26 3-Aminocyclohexanone
27 4-Oxocyclohexan-1-carboxylic acid
28 5-Ethyl-6-methylcyclohex-2-en-1-one
29 2 – Cyclohexyl ethanoic acid
30 3 – Cyclohexyl butan – 2 – ol
31 Ethyl cyclohexyl methanoate
32 5, 6 – Dimethyl cyclohex – 2 – en – 1 – one
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Solution of Nomenclature
33 2, 3 – Dimethyl cyclohexanone
34 3 – Cyclopropyl – prop – 2 – enoic acid
35 1 – Cyclohexyl pent – 1 – en – 3 – one
36 N – Cyclohexyl Propanamide
37 3-Cyclopropyl-3-methylbutanal
38 2-Carboxy-5-formyl-cyclohexanone
39 3-Bromo-4,4-dimethylcyclohexanol
40 Propylcyclopentylmethanoate
41 2-Bromo-6-methylcyclohexanecarbaldehyde
42 3 – Ethoxy carbonyl cyclohexane carboxylic
acid
43 5 – Bromo – 2, 2 – dimethyl cyclohexanone
44 2 – Isopropyl – 4 – methyl cyclohexanol
45 1 – (2 – Butenyl) cyclohexane
46 Methyl (2 – hydroxyl cyclopentane) carboxylate
47 1-(4-Hydroxycyclohexyl)butane-1,4-diol
48 Isopropyl – 3 – hydroxycyclohexane
carboxylate
Aromatic
1 Ethoxybenzene
2 Phenoxybenzene
3 4-Hydroxybenzaldehyde
4 3-Phenylpropanal
5 1-Phenylethan-1-one (Acetophenone)
6 2,4-Dinitrophenol
7 2,4,6-Trinitrophenol
8 1,3,5-Trinitrobenzene
9 2,4,6-Trinitrotoluene
10 1,2-Benzenedicarboxylic acid
11 N-Methylbenzenamine
N-Methylaniline
12 2-Phenylethanamine
13 Benzoic anhydride
14 4-Methylbenzenesulphonic acid
OR, 4-toluenesulphonic acid
15 N-Methylbenzanamide
16 2-Chloro-4-methoxytoluene
17 4-Ethyl-1-fluoro-2-nitrobenzene
18 4-Hydroxy-3-methylbenzaldehyde
19 2,3-Dibromo-1-phenylpentane
20 Methyl – 2(chlorocarbonyl) benzoate
21 1, 3 – bis(Bromomethyl) benzene
22 N – Ethyl – N – phenyl butanamide
23 3-Phenylbutanal
24 3-Phenylprop-2-enoic acid
25 2 – ( 4 – chlorophenyl) Propanoic acid
26 Ethyl – 2 – bromo – 2(3 – nitrophenyl)
propanoate
Bicyclo compund
1 Bicyclo[3.1.0]hexane
2 Bicyclo[3.3.0]octane
3 Bicyclo[4.2.0]octane
4 8-Methylbicyclo[3.2.1]octane
5 Bicyclo[2.2.2]octane
6 Bicyclo[1.1.1]pentane
8 Bicyclo[2.2.1]heptane
9 Bicyclo[2.1.1]hexane
10 Bicyclo[2.1.1]hept-2-ene
11 Bicyclo[3.1.1]hept-2-ene
12 1,7,7-Trimethylbicyclo[2.1.1]hept-2-one
13 Bicyclo [3.2.2] nonane
14 Bicyclo [2.2.2] octa – 2, 6 – dione
15 Bicyclo [2.2.2] oct – 5 – ene – 2 – nitrile
16 7, 7 – Dimethyl bicycle [2.2.1] heptanes
17 2, 7, 7 – Trimethylbicylo [3.1..1] hept – 2 – ene
18 4-Chloro-3-ethyl-1,8-
dimethylbicyclo[3.2.1]octane
19 1 – Ethylbicyclo [2.2.1] heptane
20 3, 3 – Dimethylbicyclohept – 6 – ene
21 2, 2, 4, 4 – Tetramethyl bicyclo [1.1.0] butane
22 1 – Methylbicyclo [2.2.1] hept – 5 – en – 2 – ol
23 6, 6 – Dimethylbricyclo [3.1.1] hept – 3 – en – 2
–one
Spiro
1 Spiro[3.3]heptane
2 Spiro[2.4]heptane
3 Spiro[3.5]nonane
4 Spiro [4.5] deca – 1, 6 – diene
5 2 – Methyl spiro [4.5] deca -1, 6 – diene
6 1 – Chloro spiro[3.4] octene
Tercyclo
1 1, 1’, 2’, 1’’- Tercyclobutane
2 1, 1’, 4’, 1’’ – Terphenyl
3 1, 1’, 2’, 1’’ – Tercyclopropane
Special Case
1 Butane-1,2,4-tricarbonitrile
2 Pentane-1,3,5-tricarboxylic acid
3 Propane-1,2,3-tricarbaldehyde
4 3-(Cyanomethyl)hexane-1,6-dinitrile
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Solution of Nomenclature
5 3-(Carboxymethyl)hexane-1,6-dioic acid
6 3,3-bis(Formyl methyl)hexane-1,6-dial
7 3,3-bis(Carbamoyl methyl)pentane-1,5-diamide
8 2-Hydroxy-1,2,3-propane tricarboxylic acid
9 1, 3 – Dichloro – 2, 2 – bis (chloromethyl)
propane
Harder Problems
1 2-Chloromethyl-5-formyl-3-hydroxymethyl-2-
N,N-dimethylamino-6-methoxy-4-nitrosonon-8-
en-1-nitrile
2 1,3,5-Tridecylcyclohexane
3 Ethyl – 2 – cyano – 3 – oxo – 4, 6 – dimethyl – 5
– cyclopropylhept – 5 – ene – 1 – oate
4 2 – Amido – 2 – chlorocarbonyl – 5 – (N – ethyl,
N – methyl) amino - 6 – methylene – 9 –
propoxycarbonyldec -4, 7 – diene – 1 – oic acid
5 2,2-bis(2-Hydroxyethoxy)ethanoic acid
6 2,2-bis(4-Chlorophenyl)-1,1,1-trichloroethane
7 1, 1, 1 – Trichloro – 2, 2 – diphenylethane
Write the structure of the
following compounds whose
IUPAC names are given as
under
Soln. 1
But – 2 – ene
CH3-CH=CH-CH3
Soln. 2
1, 2, 3 – Propanetriol
Soln. 3
Ethanoyl chloride
CH 3 COCl
Soln. 4
2, 3 - Pentadione
CH 3
-C-C-CH 2
-CH 3
|| ||
O O
Soln. 5
Octa – 3, 5 – diene
CH 3 -CH 2 -CH=CH-CH=CH-CH 2 -CH 3
Soln. 6
4 – Hydroxyl – 3 – pentenoic acid
CH 3
-C=CH-CH-COOH
|
OH
Soln. 7
2, 3 – Dimethylbutan – 2 – ol
OH
|
CH 3
-CH-C-CH
| | 3
CH 3 CH 3
Soln. 8
2, 2 – Dimethylpentanal
CH 3
|
CH 3
-CH 2
-CH 2
-C-CHO
|
CH 3
Soln. 9
2, 7 – Dimethylocta – 2, 4, 6 – triene
CH 3
C=CH-CH=CH-CH=C-CH | 3
|
CH 3
CH 3
Give the IUPAC name of the
following compounds
Soln. 1
Acetylene
CHCH
Ethyne
Soln. 2
Methylacetylene
CH 3 CCH
Propyne
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|
|
Solution of Nomenclature
Soln. 3
Dimethylacetylene
CH 3 CCCH 3
Soln. 4
Isobutane
CH 3
|
CH 3
CHCH 3
2-Methylpropane
Soln. 5
Isopentane
CH 3
- CH - CH 2
- CH 3
|
CH 3
2-Methylbutnae
Soln. 6
Neopentane
CH 3
|
CH 3
C CH 3
|
CH 3
Soln. 9
Ethylidene bromide
CH 3
CH
Br
Br
1,1-Dibromoethane
Soln. 10
Vinyl chloride
CH 2 =CH-Cl
Chloroethene
Soln. 11
Allyl bromide
CH 2 = CH – CH 2 - Br
3-Bromopropene
Soln. 12
Benzyl alcohol
C 6 H 5 CH 2 OH
Phenylmethanol
Soln. 13
Benzylidene chloride
C 6
H 5
CH
Br
Br
1,1-Dibromophenylmethane
2,2-Dimethylpropane
Soln. 7
Neohexane
CH 3
CH 3
- C - CH 2
CH 3
CH 3
2,2-demethylbutane
Soln. 8
Ethylene bromide
CH 2
-CH | | 2
Br Br
1,2-Dibromoethane
Soln. 14
Glycol
CH 2
-CH 2 | |
OH OH
Ethane-1,2-diol
Soln. 15
Glycerol
H - C - C - C - H
OH OH OH
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H
H H
Propane – 1,2,3 - triol

Solution of Nomenclature
Soln. 16
ter-butyl alcohol
CH 3
|
CH 3
-C-CH
| 3
OH
2-Methypropan-2-ol
Soln. 17
sec-Butyl alcohol
CH 3
-CH-CH 2
CH 3
|
OH
Butan-2-ol
Soln. 18
Formaldehyde
HCHO
Methanal
Soln. 19
Acetaldehyde
CH 3 CHO
Ethanal
Soln. 20
Acetone
CH 3 COCH 3
Propan-2-one
Soln. 21
Glyoxal
O = C - C = O
| |
H H
Ethane-1,2-dial
Soln. 22
Methyl glyoxal
CH 3 COCHO
2-Ketopropanal
Soln. 23
Mesitylene
CH 3
H 3 C
CH 3
1,3,5-trimethybenzene
Soln. 24
Formic acid
HCOOH
Methanoic acid
Soln. 25
Acetic acid
CH 3 COOH
Ethanoic Acid
Soln. 26
Oxalic acid
HO - C - C - OH
|| ||
O O
Ethane-1,2-dioic acid
Soln. 27
Formamide
HCONH 2
Methanamide
Soln. 28
Acetamide
CH 3 CONH 2
Ethanamide
Soln. 29
Ethylacetate
CH 3 COOC 2 H 5
Ethylethanoate
Soln. 30
Acetyl chloride
CH 3 COCl
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Solution of Nomenclature
Ethanoyl Chloride
Soln. 2(b)
Soln. 31
TNT
O
O -
N +
CH 3 O
N + O -
2-bromo-5-hydroxy benzonitrile (as CN – group gets
the top priority).
Soln. 3(c)
COCl
|
O -
2,4,6-Trinitrotoluene
N +
O
IUPAC name of is
chloride
Soln. 4(d)
benzene carbonyl
Soln. 32
DDT
Cl CH - CCl 3
CH 3
- CH - CH 2
- CH 2
- CH 3
|
CH isopropyl group
3
Soln. 5(b)
Cl
2,2-bis(4-Chlorophenyl)-1,1,1-trichloroethane
Soln. 33
Isobutyric acid
CH 3
CHCOOH
|
CH 3
2-Methylpropanoic acid
Soln. 34
Methy vinyl ketone
CH 3 COCH=CH 2
But-3-en-2-one
IIT Advanced
Soln. 1
Butane dioic acid or 1, 4-Butane dioic acid
H
|
H 2
C = CH - C - CH 3
1
3
2 | 4
CH 3
3-methyl-1-butene
Soln. 6(c)
CH 3
|
H 3
C - C - CH = CH 2
| 2
4
3 1
CH 3
3, 3-dimethyl-1-butene
Soln. 7
(i) Pent-2-en-1 oic acid or 2-pentenoic acid
(ii) 3-(N, N-dimethyl amino) 3-methyl pentane or 3-
(N, N-Dimethyl)-3 methyl-3-pentamine.
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Solution of Nomenclature
Soln. 1(d)
IIT Mains/AIEEE
CH 3
CHCHCH 3
H 3
C
OH
Correct IUPAC
3 – methyl – 2 – butanol
Soln. 2(b)
The IUPAC name of CH 3 COCH(CH 3 ) 2 is
3 – methyl butan – 2 – one
Soln. 3(c)
Soln. 7(b)
As about the double bond, two geometrical isomers
are possible and the compound is having one chiral
carbon. So there are four stereo isomers.
Soln. 1(b)
1
3 4
CH 3
- C = CH - CH
2
3
|
CH 3
2-Methyl-2-butene
Soln. 2(b)
AIPMT
The IUPAC name
HO
is
5
3
4
2 1
CH 3
- CH - CH = C - CHO
| |
OH CH 3
3, 3 – dimethyl – 1 – cyclohexanol
Soln. 4(c)
Cl
4-Hydroxy-2-methylpent-2-en-1-al
Soln. 3(b)
When many substituents are present, the numbering
is done from the end where the sum of locants is the
lowest (lowest sum rule)
The IUPAC name
Br
is
7 6 5 4 3 2 1
H 3
C - CH - CH - CH 2
- CH 2
- CH - CH 3
| |
|
CH 3
CH 3
CH 3
3 – bromo – 1 – chlorocyclohexane
Soln. 5(c)
The IUPAC name of
Is
3 – ethyl – 4, 4 – dimethyl heptane
Soln. 6(b)
– SO 3 H, - COOH, - CONH 2 , - CHO
2, 5, 6-trimethylheptane
2 + 5 +6 = 13
1
2 3 4 5 6 7
H 3
C - CH - CH - CH 2
- CH 2
- CH - CH 3
| |
|
CH 3
CH 3
CH 3
2 + 3 + 6 = 11
2, 3, 6-trimethylheptane
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|||
|||
Solution of Nomenclature
Soln. 4(c)
Soln. 7(b)
Cl
H 3
C
|
|
C = C
|
|
CH 2
CH 3
I
H 3 C
4
1
CH 3
2
H 3 C
3
5
6
7
As in this compound the common groups i.e. highly
electronegative halogen atoms are on opposite side,
hence it is a trans isomer. Thus its name is trans-2-
chloro-3-iodo-2-pentene
Soln. 5(a)
CH 3
4-ethyl-3-methyloctane
Soln. 8(a)
Correct IUPAC name of
1 2 3 4
CH 3
- C - CH - CH 3
|| |
O CH 3
2-Methyl-3-butanone
CH 3
|
CH 3
- CH 2
- CH 2
- CH - CH - CH 2
CH 3
|
CH 2
CH 3
1 2 3
CH 3
- CH - CH - CH 3
| | 4 5
CH 3 CH 2
CH 3
2,3-Dimethylpentane
is 4-Ethyl-3-methyl heptane.
Soln. 9(c)
4 3 2 1
CH 3
- CH - CH - CH 3
|
Cl
|
Br
2-Bromo-3-chlorobutane
5
4
3 2 1
C
O
Cl
1 2 3 4 |
CH 3
- C
5
CH 3
C - CH
|
CH 3
4-Methyl-2-pentyne
Soln. 6(b)
The IUPAC name of
1 2 3
4 5 6
CH 2 = CH - CH 2 - CH 2 - C
CH
is Hex-1-en-5-yne or 1-hexene-5-yne.
It is 2, 3-dimethylpentanoyl chloride
Soln. 10(a)
The given compound is
2 1
CH = CH 2
|
CH 3
- CH 2
- CH 2
- C - C - CH 2
- CH 3
3
| 4
CH 2
- CH 3
5 6
4-Ethyl-3-propyl hex-1-ene
The lowest number is given to the C = C double
bond.
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Solution of Nomenclature
Soln. 11(a)
CH 3
1
Cl
C = C
2
3
4 5
CH 2
CH 3
I
Correct IUPAC name of above compound is trans-2-
chloro-3-iodo-2-pentene
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