Acros Organics & Maybridge - N
Acros Organics & Maybridge - N
Acros Organics & Maybridge - N
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1-Nitroso-2-naphthol, 98%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
151530250 Glass bottle 25 g INR 710<br />
151531000 Glass bottle 100 g INR 1,910<br />
151535000 Glass bottle 500 g INR 7,570<br />
R33<br />
S45<br />
C10H7NO2 CAS: 131-91-9<br />
MFCD00003884<br />
ONC 10 H 6 OH<br />
FW: 173.17<br />
mp: 104-108 °C (d)<br />
1-Nitroso-2-naphthol-3,6-disulfonic acid, disodium salt hydrate<br />
pure<br />
indicator grade<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
346550250 Glass bottle 25 g INR 1,450<br />
346551000 Glass bottle 100 g INR 3,980<br />
346555000 Glass bottle 500 g INR 15,720<br />
R20/21/22 R36/37/<br />
38<br />
S26 S36/37/39<br />
C10H5NNa2O8S2 .xH2O CAS: 525-05-3 FW: 377.25<br />
MFCD00149246 mp: >300 °C<br />
Loss on drying ................ 5 % (1 g, 105°C)<br />
Nitrosonium hexafluorophosphate, 95%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
383730050 Plastic bottle 5 g INR 5,930<br />
383730250 Plastic bottle 25 g INR 9,660<br />
R34<br />
S26 S36/37/39 S45<br />
Moisture sensitive<br />
F6NOP CAS: 16921-91-8 MFCD00040324 FW: 174.97<br />
Nitrosonium tetrafluoroborate<br />
APPLICATION GUIDE<br />
Aromatic electrophilic substitution<br />
*Nitrosation Used for electrophilic nitrosation of electron rich aromatics. JOC 1994, 59, 5573<br />
Deprotecting Group Chemistry<br />
* Deprotection of dithianes Used as an oxidant to unmask carbonyl groups. S 1979, 273<br />
Fluorination<br />
* Diazonium tetrafluoroborate to fluoro Decomposition of the diazonium tetrafluoroborate produces<br />
fluoroarenes.<br />
Interconversion of functional groups<br />
* Alcohol to nitrite Alcohols are nitrosated to give alkyl nitrites. CB 1956, 89, 2374<br />
* Amide to carboxylic acid Primary amides can be converted to acids via diazotization and subsequent<br />
hydrolysis. JOC 1965, 30, 2386<br />
* Amine to diazonium salt WilliamS D. L. H, Nitrosation; Cambridge University Press: Cambridge, 1988<br />
* Amine to nitrosamine Secondary amines are converted to nitrosamine. Pyridines are nitrosated to Nnitrosopyridinium<br />
tetrafluoroborates. CB 1984, 117, 1965; JOC 1965, 30, 3373<br />
Ring Synthesis<br />
* Imidazole In the presence of MeCN, alkenes react with this reagent to give imidazoles after<br />
reduction. TL 1971, 2205<br />
*Isoxazole Superior nitrosating agent for reaction with allenylsilanes in MeCN - forms isoxazole<br />
derivatives via ¢3 + 2! annulations.<br />
Nitrosonium tetrafluoroborate, 97%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
174390050 Plastic bottle 5 g INR 2,400<br />
174390250 Plastic bottle 25 g INR 6,270<br />
174391000 Plastic bottle 100 g INR 19,760<br />
R34<br />
S26 S36/37/39 S45<br />
Moisture sensitive<br />
Store below +4ºC<br />
BF 4 NO NOBF 4<br />
CAS: 14635-75-7<br />
MFCD00011433<br />
FW: 116.81<br />
mp: 250 °C (S)<br />
http://www.acros.com Nitrosonapht<br />
N-Nitroso-N-phenylhydroxyamine ammonium salt , see Cupferron on page 642<br />
Nitroso-R salt , see 1-Nitroso-2-naphthol-3,6-disulfonic acid, disodium salt hydrate on page 1631<br />
5-Nitroso-2,4,6-triaminopyrimidine, 98%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
186480250 Glass bottle 25 g INR 3,210<br />
S24/25 C4H6N6O CAS: 1006-23-1<br />
MFCD00006096<br />
FW: 154.13<br />
mp: >300 °C<br />
trans--Nitrostyrene, 97+%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
386530050 Glass bottle 5 g INR 710<br />
386530250 Glass bottle 25 g INR 2,560<br />
386531000 Glass bottle 100 g INR 8,380<br />
R20/21/22 R36/37/<br />
38<br />
S26 S36/37/39<br />
Store below +4ºC<br />
C 8 H 7 NO 2<br />
CAS: 5153-67-3<br />
FW: 149.15<br />
mp: 56-58 °C<br />
bp: 250-260 °C<br />
3-Nitrostyrene, 97%<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
128992500 Glass bottle 250 mg INR 660<br />
128990025 Glass bottle 2.5 g INR 1,720<br />
128990100 Glass bottle 10 g INR 6,870<br />
R36/37/38<br />
S24/25<br />
Store below +4ºC<br />
C8H7NO2 CAS: 586-39-0<br />
MFCD00007276<br />
FW: 149.15<br />
H 2 C=CHC 6 H 4 NO 2<br />
mp: -5 °C<br />
Fp: 107 °C<br />
d: 1.070<br />
Nitrosyl hexafluorophosphate , see Nitrosonium hexafluorophosphate on page 1631<br />
Nitrosyl sulfate , see Nitrosylsulfuric acid (40% in sulfuric acid) on page 1631<br />
Nitrosylsulfuric acid (40% in sulfuric acid)<br />
APPLICATION GUIDE<br />
Interconversion of functional groups<br />
* Amine to diazonium salt Will diazotise weakly basic amines. CJC 1991, 69, 1183<br />
* Amine to nitrosation N-Acylarylamines to NNO. CJC 1967, 45, 1539<br />
* Hydrazines to azides As a solution in sulphuric acid. TL 1987, 28, 5091<br />
Nitrosylsulfuric acid<br />
40% in sulfuric acid<br />
Nitrosyl tetrafluoroborate , see Nitrosonium tetrafluoroborate on page 1631<br />
n 20<br />
D : 1.582 -1.584<br />
<strong>Acros</strong> <strong>Organics</strong> Product code Packaging Pack size Price<br />
416215000 Glass bottle 500 g INR 1,870<br />
R8 R14 R29 R35<br />
S8 S26 S36/37/39<br />
S45<br />
Moisture sensitive<br />
Store below +4ºC<br />
HNO5S HOSO2NO2 CAS: 7782-78-7 FW: 127.08<br />
MFCD00011495 mp: -10 °C<br />
Please enquire for bulk quantities 1631<br />
O<br />
N<br />
N<br />
H 2<br />
NH 2<br />
N<br />
N<br />
O<br />
N +<br />
d: 1.900<br />
NH 2<br />
O<br />
N
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