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NAMED ORGANIC REAGENTS (PART 1)

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Dr. John Andraos, http://www.careerchem.com/<strong>NAMED</strong>/Structures(A-K).pdf 8<br />

Cornforth reagent (1962)<br />

(chromium trioxide/ pyridine/water)<br />

Crabtree's catalyst (1977)<br />

((1,5-cyclooctadiene)bis(methyldiphenyl-<br />

phosphine)iridium(I)hexafluoro- phosphate) or<br />

((1,5-cyclooctadiene)tricyclohexyl<br />

phosphine pyridinioiridium(I)<br />

hexafluorophosphate)<br />

Creutz-Taube complex or ion (1969)<br />

(decaammine-μ-(pyrazine-<br />

N 1 :N 4 )diruthenium(5+) or<br />

μ-pyrazine-<br />

bis[pentaammineruthenium(III,II)]<br />

Dahl acids<br />

6-amino-1-naphthalenesulfonic acid<br />

4-amino-1,7-naphthalenedisulfonic acid<br />

or Dahl's acid II<br />

4-amino-1,6-naphthalenedisulfonic acid<br />

or Dahl's acid III<br />

110-86-1<br />

1333-82-0<br />

1333-74-0<br />

35599-57-6<br />

81-05-0<br />

85-74-5<br />

85-75-6<br />

N<br />

CrO 3 H 2 O<br />

Ir[(COD)(P(CH3)Ph2)2)] + PF6 - / H2<br />

Ir[(COD)(PCy3)(pyr)] + PF6 - / H2<br />

(H 3N) 5Ru<br />

H 2N<br />

HO 3S<br />

HO 3S<br />

N N Ru(NH3) 5<br />

SO 3H<br />

SO 3H<br />

NH 2<br />

SO 3H<br />

NH 2<br />

+

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