odstranjevanje acetamiprida s fentonovo oksidacijo

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znano, da v okolju hitro razpade oziroma se hitro razgradi, je potrebno raziskati in ugotoviti ali se razgradi ali mineralizira, oziroma kateri produkti pri tem nastanejo. 36
6 VIRI Abramović B.F., Banić N.D., Šojić D.V. 2010. Degradation of thiacloprid in aqueos solution by UV and UV/H 2 O 2 treatments. Chemosphere. 81: 114 119. Agencija Republike Slovenije za okolje http://kazalci.arso.gov.si/?data=indicator&ind_id=37 (pregledano 28. marec 2010). http://kazalci.arso.gov.si/?data=indicator&ind_id=282 (pregledano 28. marec 2010). Baird C. 2003. Evironmental Chemistry. 2nd Edition. USA. W.H. Freeman and Company: str. 492. Bourgin M., Violleau F., Debrauwer L., Albet J. 2011. Ozonation of imidacloprid in aqueous solutions: Reaction monitoring and identification of degradation products. Journal of Hazardous Materials. Članek v tisku. Cox C. Insecticide factsheet Imidacloprid. Journal of Pesticide Reform 21. 1 (2001): 15 21. Černigoj U., Štangar U.L., Trebše P. 2007. Degradation of neonicotinoid insecticides by different advanced oxidation processes and studying the effect of ozone on TiO 2 photocatalysis. Applied Catalysis B: Environmental. 75: 229 238. Di Muccio A., Fidente P., Barbini D. A., Dommarco R., Seccia S., Morrica P. 2006. Application of solid-phase extraction and liquid chromatography-mass spectrometry to the determination of neonicotinoid pesticide residues in fruit and vegetables. Journal of Chromatography. 1108: 1 6. EC, Health & Consumer protection directorate. 2004 http://ec.europa.eu/food/plant/protection/evaluation/newactive/acetamiprid.pdf (pregledano 12. marec 2011). Fan H.J., Huang S.T., Chung W.H., Jan J.L., Lin W.Y., Chen C.C. 2009. Degradation pathways of crystal violet by Fenton and Fenton-like systems: Condition optimization and intermediate seperation and identification. Journal of Hazardous Metarials. 171: 1032 1044. Fitosanitarna uprava Republike Slovenije http://spletni2.furs.gov.si/FFS/REGSR/index.htm (pregledano 14. marec 2011). Food Safety-From the Farm to the Fork http://ec.europa.eu/food/plant/protection/index_en.htm (pregledano 4. maj 2011). Guohong X., Guoguang L., Dezhi S., Liqing Z. 2009. Kinetics of Acetamiprid Photolysis in Solution. Bull Environ Contam Toxicol. 82: 129 132. Gupta S., Gajbhiye V.T., Gupta R.K. 2008. Effect of Light on the Degradation of Two Neonicotinoids viz Acetamiprid and Thiacloprid in soil. Bull Environ Contam Toxicol. 81: 185 189. 37
Page 1: UNIVERZA V NOVI GORICI FAKULTETA ZA
Page 5: ZAHVALA Iskreno se zahvaljujem prof
Page 8 and 9: VIII
Page 10 and 11: SEZNAM PREGLEDNIC Preglednica 1: Re
Page 12 and 13: SEZNAM OKRAJŠAV FFS = fitofarmacev
Page 14 and 15: obremenjen je SV ravninski del (Dra
Page 16 and 17: Acetamiprid Tiakloprid Klotianidin
Page 18 and 19: Topnost v vodi (destilirana voda, 2
Page 20 and 21: Preglednica 1: Redoks potencial nek
Page 22 and 23: R - R * + O 2 R - R + + O 2 (Litte
Page 24 and 25: R + Fe 3+ R + + Fe 2+ (10) R + Fe
Page 26 and 27: 2.3.7 Uporaba NOM za razgradnjo neo
Page 28 and 29: 3 EKSPERIMENTALNI DEL 3.1 Uporablje
Page 30 and 31: Slika 4: Instrument za določanje s
Page 32 and 33: 3.1.5 Izvedba foto-Fentonove oksida
Page 34 and 35: 4 REZULTATI IN RAZPRAVA 4.1 Analiza
Page 36 and 37: tem razmerju s Fentonovo oksidacijo
Page 38 and 39: Slika 12: Kinetika razpada acetamip
Page 40 and 41: Preglednica 7: Koncentracije ogljik
Page 42 and 43: Preglednica 9: Delež koncentracije
Page 44 and 45: Slika 18: Kromatografski vrh produk
Page 46 and 47: Slika 24: Kromatografski vrh spojin
Page 50 and 51: Guzsvány V.J., Csanádi J.J., Lazi
Page 53 and 54: PRILOGA Preglednica A: Površine kr
Page 55 and 56: Preglednica E: Koncentracije ogljik

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