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sudoku Kinetics

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ter cat 1st AC 0<br />

2nd 0<br />

0 E a ter<br />

k ter AC<br />

0 ter AC 2nd 1st E a t 1/2<br />

2nd E a 1st<br />

AC ter 1st<br />

cat t 1/2<br />

1st k AC ter E a<br />

Chemistry SUDOKU: <strong>Kinetics</strong><br />

Place all nine symbols in empty squares so that each row, column, and 3X3 box<br />

contains the same symbol only once.<br />

k: Rate constant found in rate equation, rate=k[a] [b], etc.<br />

1st: First order rxns have a unit of k=t -1 and equation ln[R] t /[R] 0 =-kt<br />

2nd: Second order rxns have a unit of k=L/mol . t and equation 1/[R] t -1/[R] 0 =kt<br />

0: Zero order rxns have a unit of k=mol/L . t and equation [R] 0 -[R] t =kt<br />

t 1/2 : Half life equation t 1/2 =ln2/k<br />

E a : Activation nrg<br />

ter: A termolecular elementary step involves the collision of three molecules.<br />

AC: Activated Complex or transition state between reactants and products.<br />

cat: Catalysts lower E a , increase rxn rate, provide alternate rxn mechanism, are rxn<br />

specific, and are recycled.

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