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Corrosion protection by Metal Cladding Technology ... - Fleming gulf

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<strong>Corrosion</strong> <strong>protection</strong> <strong>by</strong> <strong>Metal</strong> <strong>Cladding</strong><br />

<strong>Technology</strong>, Case Studies<br />

and Turnaround Incorporation<br />

Iain Hall, Chief <strong>Technology</strong> Officer<br />

United States<br />

Japan<br />

Kazakhstan<br />

China India<br />

Gulf States<br />

South Africa<br />

0<br />

Strictly Confidential


Presentation Overview<br />

1. Short Company Introduction<br />

2. <strong>Metal</strong> <strong>Cladding</strong> <strong>Technology</strong><br />

3. Case Studies<br />

4. Turnaround Implementation<br />

1<br />

Strictly Confidential


Important IGS Milestones<br />

<strong>Metal</strong>spray is<br />

established,<br />

serving the pulp<br />

and paper industry<br />

with thermal spray<br />

protective coatings<br />

The Company<br />

acquires Department<br />

of Energy high<br />

temperature erosion<br />

testing facility<br />

Adds mechanical<br />

service capabilities<br />

IGS acquires<br />

UTT on-site<br />

experience<br />

O&G - Sasol<br />

1980 1991 1994 1995 2000 2003 2007 2007 2011<br />

2<br />

Begins service<br />

agreement<br />

with Tengiz<br />

Chevroil in KZ<br />

The<br />

Company<br />

adds weld<br />

overlay<br />

capabilities<br />

IGS is the most experienced, longest tenured integrated provider of in situ surface <strong>protection</strong><br />

in international critical process markets.<br />

Strictly Confidential<br />

IGS continues engagement<br />

with TengizChevroil in a 7<br />

year maintenance contract.<br />

Is actively engaged in<br />

Equipment Maintenance with<br />

Qatar Petroleum, Total (Off-<br />

Shore), Oryx, Dolphin Energy,<br />

ADGAS (2012/3)<br />

2013


IGS Global Presence – Qatar / UAE and soon KSR Base<br />

Projects Completed <strong>by</strong> IGS to Date<br />

Near-Term Expansion Opportunities<br />

3<br />

QP<br />

ORYX<br />

DOLPHIN<br />

TOTAL<br />

ADGAS<br />

Strictly Confidential


2. What is <strong>Metal</strong> <strong>Cladding</strong>/Coating ?<br />

4<br />

Strictly Confidential


What it is not !<br />

5<br />

Strictly Confidential


<strong>Metal</strong> <strong>Cladding</strong> Protection<br />

6<br />

Strictly Confidential


Thermal Spray Process<br />

7<br />

Strictly Confidential


Reliable <strong>Corrosion</strong> Resistance<br />

with High Velocity Thermal Spray<br />

8<br />

Strictly Confidential


Coating Application – Wire Feedstock<br />

Low Velocity Arc Spray<br />

(TWAS)<br />

• High Oxide content<br />

• Interconnected oxides<br />

and porosity<br />

(Only good for Al,Zn)<br />

9<br />

High Velocity Arc Spray<br />

(HVAS)<br />

• Higher Density<br />

• Higher Bond strength<br />

• More Homogenous<br />

Microstructure<br />

Strictly Confidential


Coating Application – Powder Feedstock<br />

High Velocity Oxy Fuel (HVOF)<br />

compressed<br />

airoxy/propa compressed ne<br />

air high alloy<br />

compressed<br />

powder<br />

airoxy/propa<br />

compressed ne<br />

air<br />

10<br />

air<br />

envelope<br />

substr<br />

ate<br />

Strictly Confidential


Coating Base <strong>Metal</strong> Interface<br />

<strong>Metal</strong> <strong>Cladding</strong><br />

11<br />

Strictly Confidential<br />

Base <strong>Metal</strong> – Acid Etched


Surface Profile<br />

Interface – 50MPa Bond Strength<br />

No Heat Affected Zone (HAZ)<br />

12<br />

Strictly Confidential


<strong>Corrosion</strong> Mechanism<br />

Coating<br />

Particles<br />

Substrate<br />

Permeation <strong>by</strong><br />

corrosive media<br />

Low Velocity<br />

High Velocity<br />

13<br />

Strictly Confidential


Base Alloy Selection<br />

14<br />

Strictly Confidential


Process and Material <strong>Technology</strong><br />

Material Development<br />

We customize solutions to meet<br />

applications across end markets.<br />

Process Design and<br />

Optimization<br />

15<br />

Strictly Confidential<br />

UTEx 5-420 + 5-620(Chevron Spec)<br />

Specified for corrosion <strong>protection</strong><br />

H2S and Cl service<br />

•High Velocity Application<br />

•Low stress, low permeability<br />

•High Bond Strength<br />

•Independent qualification through:<br />

Chevron, Total, TWI


Material performance testing<br />

16<br />

Strictly Confidential


Coating Resistance - Permeability<br />

<strong>Corrosion</strong> Rate (mpy)<br />

1200<br />

1000<br />

800<br />

600<br />

400<br />

200<br />

High Velocity Coating<br />

<strong>Corrosion</strong> Rate of High and Low Velocity<br />

Alloy 625 Coatings v s Thickne ss<br />

Low Velocity Coating<br />

0<br />

0 20 40 60 80 100<br />

Coating Thickness (mils)<br />

High Velocity Low Velocity<br />

Low Velocity Trend High Velocity Trend<br />

17<br />

Strictly Confidential


UTEx 5-420 Low Stress – Low Oxide HVAS Coating<br />

Characteristics<br />

Porosity < 1 %<br />

Total Oxides < 5 %<br />

Bond Strength 46 MPa<br />

Nominal Material Composition<br />

18<br />

Strictly Confidential


Strictly Confidential<br />

UTEx 5-620(Chevron) Low Stress – Low Oxide HVAS Coating<br />

Characteristics<br />

Porosity < 1 %<br />

Total Oxides < 5 %<br />

Bond Strength 47 MPa<br />

Nominal Composition<br />

19


Automated Weld Overlay - CRO<br />

20<br />

Strictly Confidential


Weld Overlay <strong>Technology</strong><br />

21<br />

IGS - Pulsed MIG<br />

Spray Transfer<br />

Strictly Confidential<br />

• Strong magnetic field from rapid high current<br />

pulsing initiates rotary spray transfer<br />

• Droplet size much less than electrode<br />

diameter<br />

• Higher current results in less heat, less<br />

distortion, less dilution<br />

• Reduced heat affected zone<br />

• Better weld chemistry


Weld Overlay <strong>Technology</strong><br />

22<br />

• NBIC R-Stamp<br />

• ASME Sec IX<br />

PQR/WPS<br />

Strictly Confidential<br />

Flexible on-site, in-situ field<br />

application – shell and nozzles


3. Case Studies<br />

23<br />

Strictly Confidential


Alloy Selection for Slug Catcher Application<br />

Total ABK – Slug Catcher (2 units):<br />

Substrate /Base:<br />

Carbon Steel – 316 strip clad WO<br />

<strong>Corrosion</strong> Mechanism :<br />

Pitting in 316L initiating due to Chlorides<br />

Shell and Nozzles :<br />

Thermal Spray / Weld Overlay<br />

24<br />

Strictly Confidential


Alloy Selection for Slug Catcher Application<br />

25<br />

Strictly Confidential


Alloy Selection for Slug Catcher Application<br />

Ideal Alloys<br />

Ni,Cr, high Mo – C276<br />

High Pitting <strong>Corrosion</strong><br />

Resistance<br />

Shell Internals<br />

Thermal Spray<br />

Nozzles:<br />

Thermal Spray and<br />

Weld Overlay<br />

26<br />

Strictly Confidential


Alloy Selection for Slug Catcher Application<br />

Nozzles:<br />

Weld Overlay qualified per<br />

ISO 15156 ASME IX<br />

27<br />

Strictly Confidential


Alloy Selection for Slug Catcher Application<br />

28<br />

Strictly Confidential


Amine Regeneration Column<br />

Substrate /Base:<br />

Carbon Steel<br />

<strong>Corrosion</strong> Mechanism :<br />

Large scale pitting and washing out<br />

Coating Used:<br />

UTEx 5-420 – UTEx 6-210 Sealant<br />

Desired Outcome:<br />

Protect shell for four years until<br />

replacement<br />

2 yr Inspection Outcome:<br />

Extend coating, cancel immediate<br />

vessel replacement<br />

29<br />

Strictly Confidential


Amine Regeneration Column<br />

30<br />

Strictly Confidential


Amine Regeneration Column<br />

31<br />

Strictly Confidential


Amine Regeneration Column<br />

32<br />

Strictly Confidential


Amine Regeneration Column<br />

Original Condition Condition after 2 yrs<br />

33<br />

Strictly Confidential


Other <strong>Corrosion</strong> Applications and<br />

Case History<br />

• General broad area metal loss<br />

• Aggressive pitting<br />

• Stress <strong>Corrosion</strong> Cracking<br />

• <strong>Metal</strong> Dusting<br />

• Fe Contamination<br />

• Belzona/Epoxy Permanent Replacement<br />

• Atmospheric / Marine <strong>Corrosion</strong><br />

34<br />

Strictly Confidential


Upstream, Downstream and other Petrochem applications<br />

Total<br />

Belgium<br />

Sasol Synthetic Fuels<br />

South Africa<br />

Tengizchevroil<br />

Kazahkstan<br />

Shell<br />

Canada<br />

BP<br />

Lima USA<br />

Caltex<br />

South Africa<br />

Chevron<br />

Canada<br />

Eneos<br />

Japan<br />

Oryx +<br />

QP<br />

Qatar<br />

35<br />

Amine<br />

Regenerator<br />

Flare KO Pot<br />

H2S Absorber<br />

Sulfinol Contactor<br />

Incinerator<br />

Oxygenate Removal<br />

Column<br />

Process Cooling Water<br />

Heat Exchanger<br />

Waste Heat Boiler<br />

Synthol Reactor<br />

Strictly Confidential<br />

Catalyst loading<br />

valves and piping<br />

Overhead Condenser<br />

Acid Gas<br />

Scrubber Column<br />

Buffer Drum Oxygen Intercooler<br />

Hot Quench Tower Storage Tanks<br />

Distillation Columns<br />

Amine Contactor


4. Turnaround Incorporation<br />

36<br />

Strictly Confidential


What is required from a First Class Contractor ?<br />

Surface<br />

Protection Broad Service<br />

Technologies:<br />

HVAS / HVOF<br />

WeldOverlay<br />

TWAS(Al)<br />

Monitoring<br />

Simulation<br />

Failure Analysis<br />

Testing<br />

0 LTI’s<br />

In last 3 years<br />

Proven<br />

Experience and<br />

Good Track<br />

Record<br />

37<br />

Ownership<br />

Of <strong>Technology</strong><br />

External<br />

Partnerships<br />

Project<br />

Management,<br />

Equipment,<br />

Labour, Materials<br />

and Deployability<br />

Strictly Confidential


Continuous Improvement Process Approach<br />

38<br />

Strictly Confidential


What is required from a First Class Customer ?<br />

• Pre - ”Request For Quotation” Collaboration<br />

• Primary Scope of Work<br />

• Battery Limits – (Supplemental in/out of scope)<br />

• Pricing Structure ( Fixed + Discovery Scope)<br />

( lump sum + unit priced scope)<br />

• Request for Quotation<br />

• Fixed and Flexible submission format<br />

• Post Bid Review<br />

• <strong>Technology</strong> / Efficiency gains / Pricing structure<br />

• Post Award Scope, Time and Resource Optimization<br />

• Inclusivity in Turnaround Planning<br />

39<br />

Strictly Confidential<br />

or $/m2 ?


What is required from a First Class Customer ?<br />

• Fast Efficient Communication Channels<br />

• Safety<br />

• Quality<br />

• Scope Completion / Change<br />

• Permit<br />

• Resource provision ( scaffold etc)<br />

• Contractual liason<br />

• Post Turn Around<br />

• Best Practices<br />

• Lessons Learned<br />

• Initiate Planning for Next Outage<br />

40<br />

Strictly Confidential


IGS Contact Details :<br />

Iain Hall, Chief <strong>Technology</strong> Officer<br />

iainhall@integratedglobal.com<br />

+1 804 314 5603<br />

Local Representation - Petro<strong>gulf</strong> :<br />

S.Y. Satish – Sr Sales and Marketing Manager<br />

satish@petro<strong>gulf</strong>.org<br />

+97455882314<br />

United States Japan<br />

Kazakhstan<br />

China India<br />

Gulf States<br />

South Africa<br />

41<br />

Strictly Confidential

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