Collodion USP - Mavidon

1. Product and Company Identification
Company Name: Mavidon® Medical Products Telephone: 561-585-2227
Address: 1820 2 ed Avenue North Transportation Emergency: Infotrac
Lake Worth, FL 33461 1-800-535-5053 Outside the US1-352-323-5000
USA (collect calls accepted)
Substance Name: Collodion USP E-mail: CS@MAVIDON.COM
Product: MD0002 Contact Person:
Special End Use: Medical Skin Coating Emergency Contact:
Acute
Toxicity:
Skin / Eye
Irritation:
Collodion MD0002
2. Hazards Identification
Health Environmental Physical
Acute Oral Toxicity
Category 4
Acute Inhalation
Toxicity Category 4
Skin Irritant
Category 2
Eye Irritant
Category 2A
STOT-SE Specific Target Organ
Toxicity Single
Exposure Category 3
(CNS)
Signal word: Danger
Acute
Toxicity:
Chronic
Toxicity:
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NA Fire: Flammable
liquid and
vapor
Category 2
Hazard Statements/Category Precautionary Statements:
-Highly Flammable Liquid and Vapor
-Harmful if Swallowed
-Harmful if Inhaled
-Causes Skin and Eye Irritation
-May cause drowsiness or dizziness
NA
- Keep away for heat, sparks and open
flames.
-Keep container tightly closed.
-Use explosion proof ventilating / lighting
equipment.
-Use only non-sparking tools.
-Take precautionary measures against static
discharge.
-Wash hands thoroughly after handing.
-Do not eat, drink or smoke when using
this product.
-Avoid breathing vapors.
-Use only outdoors or in a well ventilated
area.
-Wear protective gloves and face
protection.

Symbols:
Response:
Rinse mouth.
If swallowed: Call poison control (1-800-535-5053-INFOTRAC) if you feel unwell.
If inhaled: Remove person to fresh air and keep comfortable for breathing.
Call poison control (1-800-535-5053-INFOTRAC) if you feel unwell.
If on skin: Wash with plenty of water. When dried may be pealed off. Use acetone or
collodion remover to facilitate removal.
If skin irritation occurs: Get medical attention.
Take off contaminated clothing and wash it before use.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
If eye irritation persists: get medical attention.
Storage:
Store in a well ventilated place. Keep container tightly closed.
Store in Approved Flammable Cabinet. Store locked up.
Keep cool.
3. Composition/Information on Ingredients
Chemical Name Cas # ENCIS # Reach Registered Concentration
% Weight
Ethyl Ether (a,b) 60-29-7 200-467-2 Yes 65-75
Ethanol (denatured) 64-17-5 200-578-6 Yes 20-30
Nitrocellulose,
colloided, granular
(d)
Collodion MD0002
9004-70-0 603-037-01-3 NA 3-7
4. First Aid Measures
Inhalation: Move from the exposed area immediately, supply artificial respiration
if necessary. If symptoms persist seek medical attention.
Skin Contact: If still liquid wipe of with disposable towel. Once dried, nitrocellulose
film can be removed by pealing off. Use acetone or collodion remover
to help with removal if needed.
Eye Contact: Rinse cautiously with water for several minutes. Remove contact lens,
if present and easy to do. Continue rinsing. (P305+P351+P338) If eye
irritation persists get medical attention. (P337+P313)
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Ingestion: If swallowed, drink two glasses of water to dilute. DO NOT INDUCE
VOMITING. Never give anything by mouth to an unconscious person.
Notes for
Doctor:
Extinguishing
Media:
Special
Hazards:
Hazardous
Combustion
Products:
Collodion MD0002
There are no antidotes for this material, treatment is based on
symptoms.
5. Fire Fighting Measures
In case of fire: Use Dry Chemical or CO2 for extinguishing.
(P370+P378) For surrounding fire such as dry chemical for small fire,
use carbon dioxide, water fog and dry chemical.
Closed containers can explode due to buildup of pressure when
exposed to extreme heat. Do not use direct stream of water on pool
fires as product may re-ignite on water surface. Caution - Material is
extremely flammable!
Smoke, fumes, hydrocarbons and oxides of carbon.
6. Accidental Release Measures
Personal Protection Wear protective gloves/eye protection/face protection. (P280) If
Equipment:
misting occurs, use appropriate respiratory protection.
Non Emergency Leave the immediate area; prevent smoking or open flames,
Personnel:
turnoff all electrical equipment without generating sparks. Use
natural ventilation (open doors or window) avoid sparks and
ignition sources.
Emergency
Carefully ventilate the area avoid sparks and ignition sources.
Responders:
Firefighters must wear full face piece self - contained breathing
apparatus in positive pressure mode. Do not use solid stream of
water since stream will scatter and spread fire. Fine water spray
can be used to keep fire - exposed containers cool.
Environmental Keep away for heat, sparks and open flames.
Precautions:
Methods & Materials Flush the area with water, ventilate with large volumes of
for
outside air, avoid generating sparks, heat or flames.
Containment/Cleanup:
Other information: Keep away from heat, sparks and flames.
Reference to other: See section 7 for safe handling precautions and personal
Sections:
protective equipment.
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7. Handling and Storage
Precautions for Safe Store in tightly closed containers. Store in a well ventilated area.
Handling:
Store in approved Flammable Liquid cabinet. Keep room
temperature 28ºC (82º F) or below. (P403+P235)
Protective Measures: Keep in room temperature 28ºC (82º F) or below and dry areas.
Fire Prevention: Keep away from flames and hot surfaces-No Smoking (P210)
Aerosol & Dust None applicable
Generation
Prevention:
Handling
Keep container tightly closed. (P233)
considerations: Ground/bond container and receiving equipment. (P240)
Use Proper air purification system to remove fumes, or Use
explosion proof electrical/ventilating/lighting equipment. (P241)
Use only non sparking tools. (P242)
Take precautionary measures against static discharge. (P243)
Safe Storage: Store in original labeled container. Keep in room temperature
28ºC (82º F) or below and in dry areas.
General Hazards: Product is extremely flammable. Products of combustion include:
smoke, fumes, hydrocarbons and oxides of carbon. Vapors may
cause a flash fire or ignite explosively. Vapors may travel a
considerable distance to a source of ignition and flash back.
Exposure Controls:
8. Exposure Controls/Personal Protection
Follow all manufactures instructions.
Engineering Use in well ventilated area, assess atmosphere for potential
Controls:
flammable levels.
Safety Equipment: Safety eye bath nearby.
Eye and Face
Protection:
Splash goggles with side shields.
Skin Protection: Neoprene or rubber gloves with cuffs.
Respiratory
Protection:
If misting occurs, use appropriate respiratory protection.
Thermal Hazards: Vapors may cause a flash fire or ignite explosively. Vapors may
travel a considerable distance to a source of ignition and flash
back.
Environmental
Exposure Controls:
Non applicable
Occupations
Exposure limits
Ethyl Ether 1200/1210 mg/m 3 OSHA PEL/ACGIH TLV
Ethanol (denatured) 1900/1900 mg/m 3 OSHA PEL/ACGIH TLV
Collodion MD0002
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Collodion MD0002
9. Physical and Chemical Properties
Component Collodion UPS
Appearance Viscous Colorless Liquid
Odor Ether Odor
Odor Threshold ND
PH ND
Melting Point/Freezing Point ND
Initial Boiling Point: ºC / ºF 36.1/97
Evaporation Rate Slower Than Ether
Flash point Closed Cup: ºC / ºF -45/-49
Upper/Lower Flammability/Explosive 1.90 % / 36.0 %
Vapor Pressure: 70º F 442 mm Hg
Vapor Density (Air =1) >1
Specific Gravity (H2O= 1 @ 20º C) 0.770
Density ND
Solubility In Water Slight
Auto-Ignition Temperature ND
Decomposition Temperature ND
Flammability (solid, gas) ND
Relative Density ND
Viscosity ND
Partition coefficient: n-octanol/water ND
10. Stability and Reactivity
Reactivity: Stable at ambient temperature and pressure.
Chemical Stability: Considered stable and under normal ambient temperatures.
Possibility of Hazardous Reactive with oxidizing materials and strong acids.
Reactions:
Conditions to
Extreme temperatures, open flames, sparks or hot surface.
Avoid:
Incompatible Materials: Reactive with oxidizing materials and strong acids.
Hazardous
Decomposition
Products:
In case of fire: smoke, fumes, hydrocarbons and oxides of
carbon.
Storage: Store in original labeled container. Store in approved
Flammable Liquid cabinet. Keep in cool and dry areas.
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Routes of exposure:
11. Toxicological Information
Oral, dermal, inhalation and eye.
Acute Toxicity: Dizziness and drowsiness.
Skin
Corrosion/Irritation:
May Cause Drying and Cracking
Serious Eye Damage: Irritating to eyes.
Respiratory or Skin
Sensitization:
Non applicable
Germ Cell
Mutagenicity:
Non applicable
Carcinogenicity: NTP Carcinogen: No, IARC Monographs: No, OSHA
Regulated No
Reproductive Toxicity: Not determined
STOT Single Exposure: Causes CNS depression.
STOT Repeated
Exposure:
Not determined
Aspiration Hazard: Not determined
Hazardous Components CAS #/ENICS# LD 50 of LC 50 of
ingredients ingredients
(Specify Species and (Specify Species)
Ethyl Ether (a,b) 60-29-7/200-467-2
route)
1215 mg / kg
Oral-rat
Ethanol (denatured) 64-17-5/200-578-6 7060/mg/kg
Oral-rat
Nitrocellulose, colloided, 9004-70-0/603-037-01-3 >5000 mg/kg
granular (d)
Oral rat
12. Ecological Information
Toxicity: No data available
Persistence and No data available
Degradability:
Bioaccumulative No data available
Potential:
Mobility in Soil: No data available
Results of PBT/vPvB No data available
Assessment:
Other Adverse effects: No data available
Waste Treatment
Methods:
Collodion MD0002
Page 6 of 8
6500 ppm / 99M
inhalation – mouse
20000 ppm / 10 H
inhalation – rat
Not established
13. Disposal Considerations
Dispose of contents/container in accordance with
local/regional/national/international regulations. (P501)
14. Transport Information
Air: Nitrocellulose, solution flammable, Class 3, Packaging Group

Collodion MD0002
II, UN 2059
Land: Nitrocellulose, solution flammable, Class 3, Packaging Group
II, UN 2059
Sea: Nitrocellulose, solution flammable, Class 3, Packaging Group
II, UN 2059
Notes Label: Flammable Liquid
Transportation information provided is for reference only.
Client is urged to consult DOT, IMDG, IATA, EU, United
Nations, TDG, and WHMIS (Canada) TDG information
manuals for detailed regulations and exceptions covering
specific container sizes, packaging materials and methods of
shipping.
Risk Phrases:
15. Regulatory Information
R1, 3, 11, 12, 19, 22, 66, 67
Safety Phrases: S9, 16, 29, 33
TSCA (USA - Toxic Substance
Control Act)
SARA TITLE III (USA -
Superfund Amendments and
Reauthorization Act)
CERCLA (USA -
Comprehensive Response
Compensation and Liability Act)
California Prop 65, Safe
Drinking Water and Toxic
Enforcement Act of 1986
CPR (Canadian Controlled
Products Regulations)
IDL (Canadian Ingredient
Disclosure List)
DSL / NDSL (Canadian
Domestic Substances List /
Non-Domestic Substances List)
EINECS (European Inventory of
Existing Commercial Chemical
Substances
All components of this product are listed on the U.S. Toxic Substances Control
Act Chemical Inventory (TSCA Inventory) or are exempted from listing because
a Low Volume or Polymer Exemption has been granted in accordance with 40
CFR 723.50.
WGK Water Quality Index: 1 VbK Index: A I
311/312 Hazard Categories: Immediate health, fire hazard
313 Reportable Ingredients: None
(a) The Comprehensive Environmental Response, Compensation, and Liability
Act (CERCLA) has notification requirements for releases or spills to the
environment of the Reportable Quantity (RQ for this mixture > 24,000 lbs) or
greater amounts, according to 40 CFR 302.
There are no reportable chemicals present known to the state of California to
cause cancer or reproductive toxicity.
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations and the MSDS contains all the information
required by the Controlled Products Regulations. WHMIS Classification: B2
Components of this product identified by CAS number and listed on the
Canadian Ingredient Disclosure List are shown in Section 2.
Components of this product identified by CAS number are listed on the DSL or
NDSL, or are otherwise in compliance with the New Substances Notification
(NSN) regulations. Only ingredients classified as "hazardous" are listed in
Section 2 unless otherwise indicate
Components of this product identified by CAS numbers are on the European
Inventory of Existing Commercial Chemical Substances.
16. Other Information
To the best of our knowledge, the information contained herein is accurate. However,
Mavidon® Medical Products assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of
any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist. NO
WARRANTY, EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS OR
OTHERWISE IS MADE. In no event shall Mavidon® Medical Products or any of its
subsidiaries be liable for any special, incidental or consequential damages.
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Creation Date: 8/03/2012 Replaces 9/09/2011
Collodion MD0002
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