Method 300.0, Rev. 2.1 - Water - US Environmental Protection Agency

More documents

Recommendations

Info

METHOD 300.0 DETERMINATION OF INORGANIC ANIONS BY ION CHROMATOGRAPHY 1.0 SCOPE AND APPLICATION 1.1 This method covers the determination of the following inorganic anions: PART A. Bromide Nitrite Chloride Ortho-Phosphate-P Fluoride Sulfate Nitrate PART B. Bromate Chlorite Chlorate 1.2 The matrices applicable to each method are shown below: 1.2.1 Drinking water, surface water, mixed domestic and industrial wastewaters, groundwater, reagent waters, solids (after extraction 11.7), leachates (when no acetic acid is used). 1.2.2 Drinking water and reagent waters 1.3 The single laboratory Method Detection Limit (MDL defined in Section 3.2) for the above analytes is listed in Tables 1A and 1B. The MDL for a specific matrix may differ from those listed, depending upon the nature of the sample. 1.4 Method A is recommended for drinking and wastewaters. The multilaboratory ranges tested for each anion are as follows: Analyte mg/L Bromide 0.63 - 21.0 Chloride 0.78 - 26.0 Fluoride 0.26 - 8.49 Nitrate-N 0.42 - 14.0 Nitrite-N 0.36 - 12.0 Otho-Phosphate-P 0.69 - 23.1 Sulfate 2.85 - 95.0 1.5 This method is recommended for use only by or under the supervision of analysts experienced in the use of ion chromatography and in the interpretation of the resulting ion chromatograms.
1.6 When this method is used to analyze unfamiliar samples for any of the above anions, anion identification should be supported by the use of a fortified sample matrix covering the anions of interest. The fortification procedure is described in Section 11.6. 1.7 Users of the method data should state the data-quality objectives prior to analysis. Users of the method must demonstrate the ability to generate acceptable results with this method, using the procedures described in Section 9.0. 2.0 SUMMARY OF METHOD 2.1 A small volume of sample, typically 2-3 mL, is introduced into an ion chromatograph. The anions of interest are separated and measured, using a system comprised of a guard column, analytical column, suppressor device, and conductivity detector. 2.2 The main differences between Parts A and B are the separator columns and guard columns. Sections 6.0 and 7.0 will elicit the differences. 2.3 An extraction procedure must be performed to use this method for solids (See Section 11.7). 2.4 Limited performance-based method modifications may be acceptable provided they are fully documented and meet or exceed requirements expressed in Section 9.0, Quality Control. 3.0 DEFINITIONS 3.1 Calibration Blank (CB) -- A volume of reagent water fortified with the same matrix as the calibration standards, but without the analytes, internal standards, or surrogate analytes. 3.2 Calibration Standard (CAL) -- A solution prepared from the primary dilution standard solution or stock standard solutions and the internal standards and surrogate analytes. The CAL solutions are used to calibrate the instrument response with respect to analyte concentration. 3.3 Field Duplicates (FD) -- Two separate samples collected at the same time and placed under identical circumstances and treated exactly the same throughout field and laboratory procedures. Analyses of field duplicates indicate the precision associated with sample collection, preservation and storage, as well as with laboratory procedures. 3.4 Instrument Performance Check Solution (IPC) -- A solution of one or more method analytes, surrogates, internal standards, or other test substances used to evaluate the performance of the instrument system with respect to a defined set of criteria.
Page 1: METHOD 300.0 DETERMINATION OF INORG
Page 5 and 6: 3.13 Stock Standard Solution (SSS)
Page 7 and 8: 6.3 The Dionex AI-450 Data Chromato
Page 9 and 10: e cooled to 4°C and held for no lo
Page 11 and 12: e used to establish an on-going pre
Page 13 and 14: to volume with reagent water. If a
Page 15 and 16: 13.2 Tables 2A and 2B give the sing
Page 17 and 18: 17.0 TABLES, DIAGRAMS, FLOWCHARTS A
Page 19 and 20: TABLE 2A. SINGLE-OPERATOR ACCURACY
Page 21 and 22: TABLE 3. MULTIPLE LABORATORY (n=19)
Page 27: TABLE 9. MULTIPLE LABORATORY (n=19)

Method 300.0, Rev. 2.1 - Water - US Environmental Protection Agency

Create successful ePaper yourself

Delete template?

Save as template?