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Determination of Contact Angle from Contact Area of Liquid Droplet ...

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<strong>Determination</strong> <strong>of</strong> <strong>Contact</strong> <strong>Angle</strong> <strong>from</strong> <strong>Contact</strong> <strong>Area</strong> <strong>of</strong> <strong>Liquid</strong> <strong>Droplet</strong> Spreading on Solid Substrate<br />

Derrick O. NJOBUENWU, Esio O. OBOHO, Rhoda H. GUMUS<br />

4<br />

Figure 3. Experimental setup to measure contact angle <strong>from</strong> contact area: 1, Flat solid<br />

substrate; 2, Optical screen; 3, Microlitre screen; 4, Micromanipulator; 5, CCD video<br />

camera; 6, VHS recorder; 7, Light source; 8, Personal computer with frame grabber; 9<br />

spreading drop<br />

Results and Discussion<br />

1<br />

2<br />

5<br />

9<br />

3<br />

6<br />

The spreading <strong>of</strong> liquid droplets over glass, polystyrene and PMMA substrates were<br />

investigated. Typical image frame acquired by the image analysis system described in the<br />

experimental procedure is displayed in Figure 4. The figure shows a printout <strong>of</strong> the plan view<br />

<strong>of</strong> a sample <strong>of</strong> experimental measurement for silicone oil spreading on glass substrate.<br />

Similar images (frames) were grabbed by the image analyser for glycerine and hexadecane<br />

drops on glass, polystyrene and PMMA substrate. The radius <strong>of</strong> spread was determined by the<br />

plan view and the contact angle for spreading <strong>of</strong> liquid droplets was determined <strong>from</strong> the side<br />

view. These data were digitalised and measured using the s<strong>of</strong>tware as a function <strong>of</strong> time. The<br />

omissions <strong>of</strong> the other images were deliberate to avoid redundancy <strong>of</strong> images. Furthermore, a<br />

surface plot <strong>of</strong> a frame for Glycerine on Polystyrene is shown in Figure 5 to elucidate the<br />

understanding on surface geometry <strong>of</strong> liquid droplet undergoing partial wetting on solid<br />

substrate surface.<br />

5<br />

7<br />

8

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