Prothioconazole/Trifloxystrobin

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Ms. Karen Cain 10. (MRID 46246523 supplemental) Prothioconazole dissipated in paddy water with a calculated half-life of 4.8 days. The half-life in the sediment/soil could not be determined due to too few detections. (MRID 46246524 supplemental) Prothioconazole dissipated in paddy water with a calculated half-life of 0.6 days. The half-life in the sediment/soil could not be determined due to too few detections. TRANSFORMATION PRODUCTS: Solubility JAU6476-desthio: The solubility of JAU6476-desthio is 22 ppm. Hydrolysis JAU6476-desthio: (MRID 46246506 supplemental) JAU6476-desthio was stable at pH 5, 7, and 9. Aerobic Metabolism JAU6476-desthio: (MRID 46246513 supplemental). No major transformation products found. Soil Silt loam Silt loam Sandy loam Silty clay pH 7.3 7.9 7.2 6.3 % OC T 2 JAU6476-desthio linear/nonlinear/empirical 1.55 55.5/29.4/3-7 days 0.98 45.3/29.0/14-30 days 1.02 22.6/6.8/3-7 days 1.46 30.3/18.6/7-14 days T 2 JAU6476-desthio and bound residues linear/nonlinear/empirical 165.0/144.4/
Ms. Karen Cain 11. Aerobic Metabolism JAU6476-S-methyl: (MRID 46246514 supplemental). Soil Silt loam Silt loam Sandy loam pH 7.3 7.9 7.2 % OC T 2 JAU6476-S-methyl linear/nonlinear/empirical 1.55 25.1/5.6/1-3 days 0.98 47.5/26.1/14 days 1.02 28.4/7.5/3 days T 2 JAU6476-S-methyl and bound residues linear/nonlinear/empirical 86.6/74.5/7-14 days 173.3/154/>125 days 123.8/92.4/14 days Silty clay* 6.3 1.46 55.0/44.4/14-30 days 128.4/111.8/125 days *Major transformation products found only in silty clay were M2 at 10.0% and M6 24.7%. Adsorption/Desorption Transformation Product JAU6476-S-methyl: (MRID 462464501 acceptable) Soil type Sandy loam Silt Silty clay loam Loamy sand pH %OC Adsorption Koc 7.2 2.02 2772 7.1 2.14 2995 5.9 1.66 2484 6.8 0.79 1973 Desorption Koc 3124 3358 2926 2532 Label statements: AProthioconazole-desthio (a degradate of prothioconazole) is known to leach through soil into groundwater under certain conditions as a result of labeled use. Use of this chemical in areas where soils are permeable, particularly where the water table is shallow, may result in ground-water contamination. Drift and runoff are hazardous to aquatic organisms in water adjacent to treated areas. This product has a high potential for runoff for several months or more after application. Poorly draining soils and soils with shallow water tables are more prone to produce runoff that contains this product. A level, well maintained vegetative buffer strip between areas to which this product is applied and surface water features such as ponds, streams, and springs will reduce the potential for contamination of water from rainfall-runoff. Runoff of this product will be reduced by avoiding applications when rainfall is forecasted to occur within 48 hours.@ Environmental Fate Summary: Given that the use rates for this product are less than those already allowed for use in NYS, and neither active ingredient was found to be a groundwater concern in past reviews, staff do not object to the use of this product on sweet corn, field corn and soybeans.
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Prothioconazole/Trifloxystrobin

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