Author's personal copy - University of Brighton Repository

MgO CaO H 2O CO 2: an experimental spectroscopic study.
J. Geol. 116, 387–400.
Kazakov A. V., Tikhomirova M. M. and Plotnikova V. I. (1959)
The system of carbonate equilibria. Int. Geol. Rev. 1(10), 1–39.
Kim J.-M., Chang S.-M., Kim K.-S., Chung M.-K. and Kim W.-S.
(2011) Acoustic influence on aggregation and agglomeration of
crystals in reaction crystallization of cerium carbonate. Colloids
Surf. A 375, 193–199.
Kloprogge J. T., Martens W. N., Duong L. V. and Webb G. E.
(2003) Low temperature synthesis and characterisation of
nesquehonite. J. Mater. Sci. Lett. 22(11), 825–829.
Königsberger E., Königsberger L.-C. and Gamsjäger H. (1999)
Low temperature thermodynamic model for the system:
Na2CO3 MgCO3 CaCO3–H2O. Geochim. Cosmochim. Acta
63, 3105–3119.
Lanas J. and Alvarez J. I. (2004) Dolomitic lime: thermal
decomposition of nesquehonite. Thermochim. Acta 421, 123–
132.
Langmuir D. (1965) Stability of carbonates in the system
MgO CO 2–H 2O. J. Geol. 73, 730–754.
Last F. M., Last W. M. and Halden N. M. (2010) Carbonate
microbialites and hardgrounds from Manito Lake, an alkaline,
hypersaline lake in the north Great Plains of Canada. Sed. Geol.
225, 34–49.
Menzel H. and Brückner A. (1930) Studien an kohlensauren
Magnesiumsalzen. I. Basische Magnesiumcarbonate. Z. Elektrochem.
36, 63–87.
Morse J. W. and Casey W. H. (1988) Ostwald processes and
mineral paragenesis in sediments. Am. J. Sci. 288, 537–560.
Nashar B. (1965) Barringtonite – a new hydrous magnesium
carbonate from Barrington Tops, New South Wales, Australia.
Mineral. Mag. 34, 370–372.
Ostwald W. (1897) Studien über die Bildung und Umwandlung
fester Körper. Z. Phys. Chem. 22, 289–330.
Power I. M., Wilson S. A., Thom J. M., Dipple G. M. and
Southam G. (2007) Biologically induced mineralization of
dypingite by cyanobacteria from an alkaline wetland near Atlin,
British Columbia, Canada. Geochem. Trans. 8, 13.
Power I. M., Wilson S. A., Thom J. M., Dipple G. M., Gabites J.
E. and Southam G. (2009) The hydromagnesite playas of Atlin,
British Columbia, Canada: a biogeochemical model of CO2
sequestration. Chem. Geol. 260, 286–300.
Author's personal copy
Phase transitions in the system MgO–CO2–H2O 13
Raade G. (1970) Dypingite, a new hydrous basic carbonate of
magnesium, from Norway. Am. Mineral. 55, 1457–1465.
Russell M. J., Ingham J. K., Zedef V., Maktav D., Sumar F., Hall
A. J. and Fallick A. E. (1999) Search for signs of ancient life on
Mars: expectations from hydromagnesite microbialites, Salda
Lake, Turkey. J. Geol. Soc. London 156, 869–888.
Söhnel O. and Mullin J. W. (1978) A method for the determination
of precipitation induction periods. J. Cryst. Growth 44, 377–
382.
Stamatakis M. G. (1995) Occurrence and genesis of huntite–
hydromagnesite assemblages, Kozani, Greece: important new
white fillers and extenders. Trans. Inst. Mining Metal 104,
B179–185.
Stephan G. W. and MacGillavry C. H. (1972) The crystal structure
of nesquehonite, MgCO3 3H2O. Acta Crystallogr. B28, 1031–
1033.
Suzuki J. and Ito M. (1973) A new magnesium carbonate hydrate
mineral, Mg5(CO3)4(OH)2 8H2O, from Yoshikawa, Aichi Prefecture,
Japan. J. Jpn. Assoc. Mineral. Petrol. Econ. Geol. 68,
353–361.
Van Santen R. A. (1984) The Ostwald step rule. J. Phys. Chem. 88,
5768–5769.
Wells R. C. (1915) The solubility of magnesium carbonate in
natural waters. Am. Chem. Soc. J. 37, 1704–1707.
White W. B. (1971) Infrared characterisation of water and
hydroxyl ion in the basic magnesium carbonate minerals. Am.
Mineral. 56, 46–53.
White W. B. (1974) The carbonate minerals. In Mineralogical
Monograph 4. The Infrared Spectra of Minerals (ed V. C.
Farmer). Mineralogical Society. pp. 227–282.
Xiong Y. and Lord A. S. (2008) Experimental investigations of the
reaction path in the MgO–CO2–H2O system in solutions with
various ionic strengths, and their application to nuclear waste
isolation. Appl. Geochem. 23, 1634–1639.
Zeppenfeld K. (2006) Crystallization kinetics of strontianite from
Sr(HCO3)2 solutions. Chem. Erde 66, 319–323.
Zhang Z., Zheng Y., Ni Y., Liu Z., Chen J. and Liang X. (2006)
Temperature and pH dependent morphology and FT-IR
analysis of magnesium carbonate hydrates. J. Phys. Chem.
110, 12969–12973.
Associate editor: Alfonso Mucci