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QuEChERS Validation Method for Acidic Pesticides - EURL ...

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<strong>QuEChERS</strong> – alkaline hydrolysis<br />

Example 2,4-D<br />

Acids are often covalently bound to matrix components<br />

and thus their concentration underestimated!<br />

CRL-SRM<br />

CRL Workshop Valencia Spain<br />

26. – 29. September 2007<br />

Selective systemic herbicide<br />

Control of broad leaved weed<br />

Plant growth regulator used to prevent premature fruit drop<br />

Formulations include free acid, acid,<br />

salts, salts,<br />

esters<br />

May <strong>for</strong>m conjugates<br />

<strong>Method</strong> designed to convert all possible residues to free acid<br />

Community Reference Laboratory<br />

<strong>for</strong> Pesticide Residues<br />

using Single Residue <strong>Method</strong>s

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