Recommended Liquid–Liquid Equilibrium Data. Part 4. 1-Alkanol ...

TABLE 10. 1-Hexanol–water
Components References
1 1-Hexanol; C6H14O; 111-27-3
4
L. Erichsen, Brennst.-Chem. 33, 166 1952.
2 Water; H2O; 7732-18-5
6
H. Fühner, Ber. Dtsch. Chem. Ges. 57, 510 1924.
24
D. J. Donahue and F. E. Bartell, J. Phys. Chem. 56, 480 1952.
37 K. Kinoshita, H. Ishikawa, and K. Shinoda, Bull. Chem. Soc. Jpn. 31, 10811958.
89 R. Stephenson, J. Stuart, and M. Tabak, J. Chem. Eng. Data 29, 287 1984
126 C. A. Chandy and M. R. Rao, J. Chem. Eng. Data 7, 473 1962.
127 M. A. Fahim, S. A. Al-Muhtaseb, and I. M. Al-Nashef, J. Chem. Eng. Data 42, 1831997.
128 D. J. T. Hill and L. R. White, Aust. J. Chem. 27, 1905 1974.
129 H.-M. Lin, G.-B. Hong, C.-E. Yeh, and M.-J. Lee, J. Chem. Eng. Data 48, 587 2003.
130 V. P. Sazonov, N. P. Markuzin, and V. V. Filippov, Zh. Prikl. Khim. Leningrad 49, 784 1976.
Reference liquid–liquid equilibrium data
Water rich phase Alcohol rich phase
T K x 1,exp x 1,calc T K x 2,exp x 2,calc
273.15 1.4010−3 Ref. 4 1.4810−3 273.15 0.283 Ref. 89 0.283
278.66 1.4010−3 Ref. 128 1.3310−3 283.15 0.280 Ref. 129 0.288
280.00 1.3610−3 Ref. 128 1.3010−3 283.35 0.289 Ref. 89 0.288
283.15 1.2010−3 Ref. 4 1.2410−3 293.15 0.293 Ref. 89 0.295
284.15 1.2510−3 Ref. 128 1.2210−3 298.15 0.288 Ref. 24 0.299
286.09 1.2110−3 Ref. 128 1.1910−3 302.85 0.297 Ref. 89 0.303
287.83 1.1810−3 Ref. 128 1.1610−3 303.15 0.299 Ref. 126 0.303
290.19 1.1410−3 Ref. 128 1.1310−3 308.15 0.305 Ref. 129 0.308
293.15 1.1010−3 Ref. 4 1.1010−3 312.95 0.312 Ref. 89 0.313
296.14 1.0610−3 Ref. 128 1.0610−3 313.15 0.289 Ref. 4 0.313
298.15 1.0610−3 Ref. 37 1.0510−3 323.15 0.318 Ref. 89 0.325
300.14 1.0210−3 Ref. 128 1.0310−3 333.15 0.334 Ref. 89 0.338
302.85 1.0010−3 Ref. 89 1.0110−3 343.15 0.354 Ref. 4 0.352
304.07 9.9910−4 Ref. 128 1.0110−3 343.45 0.351 Ref. 89 0.353
306.24 9.8510−4 Ref. 128 9.9610−4 353.15 0.377 Ref. 4 0.369
308.00 9.0010−4 Ref. 127 9.8910−4 353.45 0.365 Ref. 89 0.369
312.95 9.0010−4 Ref. 89 9.7410−4 363.15 0.398 Ref. 4 0.386
313.10 1.0010−3 Ref. 130 9.7410−4 363.45 0.374 Ref. 89 0.387
318.00 9.0010−4 Ref. 127 9.6810−4 373.15 0.419 Ref. 4 0.406
323.15 9.1010−4 Ref. 6 9.7010−4 383.15 0.442 Ref. 4 0.426
333.15 9.4010−4 Ref. 6 9.9710−4 393.15 0.465 Ref. 4 0.449
343.15 1.0010−3 Ref. 6 1.0510−3 403.15 0.490 Ref. 4 0.474
353.15 1.1010−3 Ref. 6 1.1410−3 413.15 0.516 Ref. 4 0.501
353.45 1.1010−3 Ref. 89 1.1410−3 423.15 0.546 Ref. 4 0.530
363.15 1.2110−3 Ref. 6 1.2610−3 433.15 0.576 Ref. 4 0.562
373.15 1.4010−3 Ref. 4 1.4210−3 443.15 0.608 Ref. 4 0.597
383.15 1.6010−3 Ref. 4 1.6310−3 453.15 0.647 Ref. 4 0.637
393.15 1.9010−3 Ref. 4 1.9110−3 463.15 0.690 Ref. 4 0.682
403.15 2.1010−3 Ref. 4 2.2610−3 473.15 0.740 Ref. 4 0.736
443.15 5.0010−3 Ref. 4 5.2510−3 483.15 0.799 Ref. 4 0.803
453.15 6.6010−3 Ref. 4 6.8310−3 493.15 0.876 Ref. 4 0.888
463.15 9.0010−3 Ref. 4 9.1810−3 473.15 1.2810 −2 Ref. 4 1.2910 −2
483.15 1.8910 −2 Ref. 4 1.9310 −2
493.15 3.4210 −2 Ref. 4 3.1910 −2
Other references:
2 J. A. V. Butler, D. W. Thomson, and W. H. Maclennan, J. Chem. Soc. 1933, 674 1933.
20 V. Ababi and A. Popa, An. Stiint. Univ. “Al. I. Cuza” Iasi 6, 929 1960.
26 L. Erichsen, Naturwissenschaften, 39, 411952.
LIQUID–LIQUID EQUILBRIUM. 4 1405
J. Phys. Chem. Ref. Data, Vol. 35, No. 3, 2006