Fundamental Safety Testing and Analysis of Hydrogen Storage ...

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Task 2 Plans • Evaluate theoretical thermodynamics for water and air exposures initially of NH 3 BH 3 , 2LiBH 4 +MgH 2 , 2LiH+Mg(NH 2 ) 2 & AlH 3 followed by NaAlH 4 , Mg 2 NiH 4 & LaNiH 6 . • Perform calorimetric experiments for water exposure at 0
Task 3: Risk Mitigation System risk analyses will be performed and methods of mitigating these risks including exposure to air and humidity will be investigated. These mitigation methods may take the form of either materials modifications or system level methods which would lessen the probability or effects of environmental exposure. Proposed methods for inhibiting reactions include the application of thin film coatings or the use of liquid film inhibitors. The fundamental effectiveness of these mitigations methods will be determined with identification of the most successful identified. No Mitigation With Mitigation
Page 1 and 2: Fundamental Safety Testing and Anal
Page 3 and 4: DoE Technical Targets Target 2007 2
Page 5 and 6: Task Plan • Task 1: Risk Assessme
Page 7 and 8: Task 1: Standard Tests DOT/UN Doc.,
Page 9 and 10: Task 1 Plans • Synthesize/acquire
Page 11 and 12: Calorimetric Experimental Procedure
Page 13 and 14: Thermo-chemical Analysis of Water C
Page 15 and 16: Thermodynamics of Air Exposure Air
Page 17: XRD Analysis of Dry Air Exposure 30
Page 21 and 22: Evaluation tests on risk mitigation
Page 23 and 24: SRNL FYs ’07 & ‘08 Work • Coo

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