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2008 Annual Report Vol.36 - 中研院物理研究所 - Academia Sinica

2008 Annual Report Vol.36 - 中研院物理研究所 - Academia Sinica

2008 Annual Report Vol.36 - 中研院物理研究所 - Academia Sinica

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• We have observed several interesting quantum-size effects on the magnetisim<br />

and superconductivity in nanomaterials of heavy fermion systems.<br />

• We have developed the new methods for the production of high quality<br />

magnetic/superconducting nanoparticles and thin films<br />

• We have developed a new wide-range low temperature sensor for calorimeter<br />

application using transition metal oxides.<br />

• We have observed the coexistence of magnetic order and superconductivity in<br />

Ru-based double perovskite oxides.<br />

Major research achievements:<br />

• The evolution of Kondo interactions and magnetic correlation with size variation<br />

and Core (magnetic)- shell (nonmagnetic) model in CePt 2<br />

The evolution of the Kondo effect and antiferromagnetic correlations with size<br />

reduction in CePt 2 nanoparticles (3.1-26 nm) is studied by analysis of the<br />

temperature-dependent specific heat and magnetic susceptibility. The<br />

antiferromagnetic correlations diminish with size reduction. The Kondo effect<br />

predominates at small particle size with trivalent, small Kondo temperature<br />

magnetic regions coexisting with strongly mixed valent, large T K nonmagnetic<br />

regions. From the data of specific heat of bulk and nanoparticles, the integrated<br />

entropy S M =∫(C M /T)dT is close to 100 % of Rln2 for bulk CePt 2 , however we find<br />

n M =0.86, 0.69 and 0.25 for d = 26, 22 and 3.1 nm, respectively. The distribution<br />

configuration of magnetic and nonmagnetic Ce ions can be sketched by a core<br />

(magnetic)- shell (nonmagnetic) model (Phys. Rev. Lett, 98, 157206, 2007).<br />

• Room temepature ferromagnetism in capped CdSe nanocrystals<br />

We demonstrated the synthesis of nanocrystals of a nominally non magnetic<br />

semiconductor that exhibit ferromagnetism at several degrees above room<br />

temperature. The nanocrystals are capped by TOPO (Tri-n-octylphosphine)<br />

which is also nonmagnetic. The RTFM arises from electronic effects at the crystal<br />

surfaces due to the presence of the TOPO. The importance of the work is that with<br />

appropriate surface modification, i.e., capping with TOPO for our case, the<br />

semiconductor quantum dots exhibit RTFM with no need of magnetic dopants.<br />

The work was published in advanced materials and also selected by Nature<br />

Publishing Group (NPG) Asia Materials website for the best research published in<br />

the Asia-Pacific region. (Advanced Materials, 20, 1656-1660, <strong>2008</strong>).<br />

• Electrical and thermal transport in single nickel nanowire<br />

The thermal conductivity and electrical resistivity of a single suspended nickel<br />

nanowire have been measured in the temperature range 15- 300 K by means of the<br />

18

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