2008 Annual Report Vol.36 - 中研院物理研究所 - Academia Sinica
2008 Annual Report Vol.36 - 中研院物理研究所 - Academia Sinica
2008 Annual Report Vol.36 - 中研院物理研究所 - Academia Sinica
Create successful ePaper yourself
Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.
• We have observed several interesting quantum-size effects on the magnetisim<br />
and superconductivity in nanomaterials of heavy fermion systems.<br />
• We have developed the new methods for the production of high quality<br />
magnetic/superconducting nanoparticles and thin films<br />
• We have developed a new wide-range low temperature sensor for calorimeter<br />
application using transition metal oxides.<br />
• We have observed the coexistence of magnetic order and superconductivity in<br />
Ru-based double perovskite oxides.<br />
Major research achievements:<br />
• The evolution of Kondo interactions and magnetic correlation with size variation<br />
and Core (magnetic)- shell (nonmagnetic) model in CePt 2<br />
The evolution of the Kondo effect and antiferromagnetic correlations with size<br />
reduction in CePt 2 nanoparticles (3.1-26 nm) is studied by analysis of the<br />
temperature-dependent specific heat and magnetic susceptibility. The<br />
antiferromagnetic correlations diminish with size reduction. The Kondo effect<br />
predominates at small particle size with trivalent, small Kondo temperature<br />
magnetic regions coexisting with strongly mixed valent, large T K nonmagnetic<br />
regions. From the data of specific heat of bulk and nanoparticles, the integrated<br />
entropy S M =∫(C M /T)dT is close to 100 % of Rln2 for bulk CePt 2 , however we find<br />
n M =0.86, 0.69 and 0.25 for d = 26, 22 and 3.1 nm, respectively. The distribution<br />
configuration of magnetic and nonmagnetic Ce ions can be sketched by a core<br />
(magnetic)- shell (nonmagnetic) model (Phys. Rev. Lett, 98, 157206, 2007).<br />
• Room temepature ferromagnetism in capped CdSe nanocrystals<br />
We demonstrated the synthesis of nanocrystals of a nominally non magnetic<br />
semiconductor that exhibit ferromagnetism at several degrees above room<br />
temperature. The nanocrystals are capped by TOPO (Tri-n-octylphosphine)<br />
which is also nonmagnetic. The RTFM arises from electronic effects at the crystal<br />
surfaces due to the presence of the TOPO. The importance of the work is that with<br />
appropriate surface modification, i.e., capping with TOPO for our case, the<br />
semiconductor quantum dots exhibit RTFM with no need of magnetic dopants.<br />
The work was published in advanced materials and also selected by Nature<br />
Publishing Group (NPG) Asia Materials website for the best research published in<br />
the Asia-Pacific region. (Advanced Materials, 20, 1656-1660, <strong>2008</strong>).<br />
• Electrical and thermal transport in single nickel nanowire<br />
The thermal conductivity and electrical resistivity of a single suspended nickel<br />
nanowire have been measured in the temperature range 15- 300 K by means of the<br />
18