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Fluid treatment in the aluminium industry Membrane ... - Membratec

Fluid treatment in the aluminium industry Membrane ... - Membratec

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THE TECHNIQUE OF MEMBRANE SEPARATION<br />

<strong>Membrane</strong> separation makes use of a<br />

physical barrier, <strong>the</strong> membrane, to<br />

separate <strong>the</strong> constituents of a fluid<br />

accord<strong>in</strong>g to <strong>the</strong>ir size.<br />

The degree of separation of <strong>the</strong><br />

constituents is determ<strong>in</strong>ed by <strong>the</strong> choice<br />

of <strong>the</strong> membrane’s cut-off, def<strong>in</strong>ed as <strong>the</strong><br />

size of <strong>the</strong> smallest elements (ions,<br />

molecules or particles) of which it will<br />

reta<strong>in</strong> 90% or more.<br />

In most applications <strong>the</strong> driv<strong>in</strong>g force<br />

beh<strong>in</strong>d <strong>the</strong> separation is <strong>the</strong> pressure<br />

gradient across <strong>the</strong> membrane.<br />

The technique performs well because:<br />

<strong>the</strong> asymmetrical structure of <strong>the</strong><br />

material ensures that separation occurs<br />

at its surface and not throughout its<br />

depth,<br />

<strong>the</strong> fluid flow is tangential to <strong>the</strong><br />

surface, ensur<strong>in</strong>g a cont<strong>in</strong>uous clean<strong>in</strong>g<br />

effect.<br />

The <strong>the</strong>rmal resistance and chemical<br />

compatibility of <strong>the</strong> membranes<br />

Examples of membrane<br />

materials<br />

Cellulose acetate<br />

Polyamide<br />

Polye<strong>the</strong>rsulphone<br />

Ceramic<br />

T max.<br />

(°C)<br />

35<br />

50<br />

80<br />

350<br />

pH<br />

3-8<br />

3-11<br />

2-12<br />

0-14<br />

THE VARIOUS MEMBRANE<br />

SEPARATION PROCESSES<br />

The processes and <strong>the</strong>ir characteristics<br />

The same basic pr<strong>in</strong>ciple of operation<br />

applies over a range of four orders of magnitude<br />

of pore size, for microfiltration,<br />

ultrafiltration, nanofiltration and reverse<br />

osmosis.<br />

The filtration spectrum<br />

The figure opposite shows <strong>the</strong> sizes of<br />

some common materials and <strong>the</strong> work<strong>in</strong>g<br />

pressures used for filter<strong>in</strong>g <strong>the</strong>m.<br />

<strong>Membrane</strong> separation processes

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