EPA Nanotechnology and the Environment ... - Mechatronics
EPA Nanotechnology and the Environment ... - Mechatronics
EPA Nanotechnology and the Environment ... - Mechatronics
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<strong>Nanotechnology</strong> <strong>and</strong> <strong>the</strong> <strong>Environment</strong>: Applications <strong>and</strong> Implications STAR Progress Review Workshop<br />
Development of High Surface Area Material <strong>and</strong> Filter Media<br />
Jayesh Doshi<br />
eSpin Technologies, Inc., Chattanooga, TN<br />
Abstract<br />
The 21st Century has begun with <strong>the</strong> promise of<br />
nanotechnology, which is expected to harness novel properties<br />
of materials <strong>and</strong> unique features of phenomena at<br />
<strong>the</strong> nanometer scale. This is likely to lead to significant<br />
breakthroughs that will have major implications for environmental<br />
protection. Nanotechnologies developed in <strong>the</strong><br />
coming years will form <strong>the</strong> foundation of significant<br />
commercial platforms. This project focuses on providing<br />
a feasibility demonstration of producing nonwoven<br />
webs of electrospun nanofibers at a commercial scale<br />
for specific environmental applications. The applications<br />
targeted are those that require <strong>the</strong> use of webs such as<br />
high surface area material or filtration media. These applications<br />
are well suited to address <strong>the</strong> problems of<br />
adsorbing gaseous pollutants (where high surface area<br />
of nanowebs is very attractive) or filtering particles<br />
smaller than 3 microns from effluent gases or liquids<br />
economically (where superior efficiency of nanowebs<br />
in capturing submicron particles is very attractive). Alternatively,<br />
such filters will increase <strong>the</strong> particle-loading<br />
capacity of <strong>the</strong> filters, or reduce <strong>the</strong> pressure drop for a<br />
variety of filtration end uses.<br />
Initially, <strong>the</strong> nanofibers will be electrospun from a<br />
solution of polyacrylonitrile in dimethylformamide in <strong>the</strong><br />
form of a nonwoven mat. This mat will be fur<strong>the</strong>r processed<br />
to convert it into activated carbon fiber NanoFilter<br />
media. The web architecture will be tailored to achieve<br />
<strong>the</strong> desired filter performance <strong>and</strong> gas adsorption by varying<br />
fiber diameter, fiber orientation, fiber-packing fraction<br />
within <strong>the</strong> nanoweb, activation level, <strong>and</strong> nanoweb<br />
thickness.<br />
This project will be carried out by eSpin Technologies—a<br />
small, high-technology startup company based<br />
in Chattanooga, TN, that specializes in providing custom-made<br />
electrospun nanofibers—in collaboration with<br />
academic centers <strong>and</strong> major corporations. Toge<strong>the</strong>r, this<br />
group possesses <strong>the</strong> skills <strong>and</strong> facilities needed to successfully<br />
conduct <strong>the</strong> work under this project.<br />
At <strong>the</strong> end of <strong>the</strong> Phase I <strong>and</strong> Phase II efforts, eSpin<br />
will have successfully developed nanofiber-based high<br />
surface area NanoFilters made from activated carbon<br />
for <strong>the</strong> removal of gaseous pollutants. With <strong>the</strong> active<br />
collaboration of eSpin’s partners, <strong>the</strong>se products will be<br />
commercialized in <strong>the</strong> United States <strong>and</strong> in <strong>the</strong> international<br />
marketplace. Apart from providing technology leadership<br />
to U.S. companies, <strong>the</strong> proposed effort also will<br />
help fulfill <strong>the</strong> mission of <strong>the</strong> U.S. <strong>Environment</strong>al Protection<br />
Agency to improve <strong>the</strong> quality of air <strong>and</strong> water.<br />
The Office of Research <strong>and</strong> Development’s National Center for <strong>Environment</strong>al Research 67