PEROXAN CU-80 L - Pergan GmbH

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35.0.33 Page 4/8 Printing date 16.10.2012 Safety data sheet according to 1907/2006/EC, Article 31 Version: 3 Revision: 16.03.2010 Trade name: PEROXAN CU-80 L (Contd. of page 3) Prevent any seepage into the ground. Use only receptacles specifically permitted for this substance/product. · Information about storage in one common storage facility: Do not store or park organic peroxide together with heavy metal compounds and amines. Store away from foodstuffs, drinks and feeding stuffs. · Further information about storage conditions: Keep container tightly sealed. Store in cool, dry conditions in well sealed receptacles. Protect from heat and direct sunlight. Protect from contamination. Store under lock and key and out of the reach of children. Store in a cool place. · Recommended storage temperature (To maintain quality): 0 .... +30°C · Storage class: 5.2 "Organic Peroxides" (VCI Guideline) · Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see item 7. · Control parameters · Ingredients with limit values that require monitoring at the workplace: 98-82-8 cumene WEL (Great Britain) Short-term value: 250 mg/m³, 50 ppm Long-term value: 125 mg/m³, 25 ppm Sk IOELV (EU) Short-term value: 250 mg/m³, 50 ppm Long-term value: 100 mg/m³, 20 ppm · Additional information: The lists valid during the making were used as basis. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes and skin. Do not eat, drink, smoke or sniff while working. Use skin protection cream for skin protection. Be sure to clean skin thoroughly after work and before breaks. · Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device. Use suitable respiratory protective device in case of insufficient ventilation. `Q Filter A2 · Protection of hands: Only use chemical-protective gloves with CE-labelling of category III. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation `S Protective gloves · Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Butyl rubber, BR Fluorocarbon rubber (Viton) · Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Tightly sealed goggles `R Face protection (Contd. on page 5) GB
35.0.33 Page 5/8 Printing date 16.10.2012 Safety data sheet according to 1907/2006/EC, Article 31 Version: 3 Revision: 16.03.2010 Trade name: PEROXAN CU-80 L · Body protection: 9 Physical and chemical properties Protective work clothing · Information on basic physical and chemical properties · General Information · Appearance: · Form: Fluid · Colour: Light yellow · Odour: Characteristic · pH-value (13 g/l) at 20°C: >5 · Change in condition · Melting point/Melting range: Undetermined. · Boiling point/Boiling range: Undetermined. · Flash point: 60°C · Decomposition temperature: +80°C (SADT) · Self-igniting: Product is not selfigniting. · Danger of explosion: Product is not explosive. However, formation of explosive air/vapour mixtures are possible. · Vapour pressure at 20°C: 4 hPa · Density at 20°C: 1.034 g/cm³ · Solubility in / Miscibility with · water at 20°C: 13 g/l · Partition coefficient (n-octanol/water): 2.16 log POW · Viscosity: · Dynamic at 20°C: 15 mPas · Other information No further relevant information available. · Active oxygen 8,3 - 8,7 % 10 Stability and reactivity (Contd. of page 4) · Reactivity · Chemical stability · Thermal decomposition / conditions to be avoided: SADT (Self Accelerating Decomposition Temperature) is the lowest temperature at which self accelerating decomposition may occur with substance in the packaging as used in transport. A dangerous self-accelerating decomposition reaction and, under certain circumstances, explosion or fire can be cause decomposition at and above the temperature. Contact with incompatible substances can cause decomposition at or below the SADT. No decomposition if used and stored according to specifications. To avoid thermal decomposition do not overheat. · Possibility of hazardous reactions Self-accelerating decomposition at SADT. · Conditions to avoid No further relevant information available. · Incompatible materials: Rapid decomposition by dirt, rust, chemicals in particular concentrated acids, alkalis and accelerators (e. g. heavy-metal compounds and amines). · Hazardous decomposition products: Hydrocarbons, carbondioxide and -monoxid. No hazardous decomposition products if used and stored according to specifications. · Additional information: Emergency procedures will vary depending on conditions. The customer should have an emergency response plane in place. 11 Toxicological information · Information on toxicological effects · Acute toxicity: · LD/LC50 values relevant for classification: 80-15-9 alpha,alpha-dimethylbenzyl hydroperoxide Oral LD50 200-2000 mg/kg (rattus) (Contd. on page 6) GB
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PEROXAN CU-80 L - Pergan GmbH

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