PEROXAN PPV - Pergan GmbH

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35.0.33 Page 2/7 Printing date 16.10.2012 Safety data sheet according to 1907/2006/EC, Article 31 Version: 3 Revision: 02.03.2011 Trade name: PEROXAN PPV (Contd. of page 1) · Safety phrases: 7/47 Keep container tightly closed and at a temperature not exceeding 0 °C. 14 Keep away from dirt, rust, chemicals in particular concentrated acids, alkalis and accelerators (e. g. heavy metal compounds and amines). 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. 60 This material and its container must be disposed of as hazardous waste. 62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. · Other hazards · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. * 3 Composition/information on ingredients · Chemical characterization: Mixtures · Dangerous components: CAS: 927-07-1 tert-butyl peroxypivalate EINECS: 213-147-2 Xn R20; Xi R36/37/38; Xi R43; E R2; O R7 R52/53 Unst. Expl., H200; Acute Tox. 3, H331; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335; Org. Perox. CD, H242; Aquatic Chronic 3, H412 CAS: 31807-55-3 EINECS: 250-816-8 isododecane Xn R65 R10 Flam. Liq. 3, H226; Asp. Tox. 1, H304 · Additional information: For the wording of the listed risk phrases refer to section 16. 4 First aid measures 70-80% 20-25% · Description of first aid measures · General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. ?Z Take care of personal protection for the first aider. · After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. Take affected persons into fresh air and keep quiet. · After skin contact: Immediately wash with water and soap and rinse thoroughly. Immediately remove contaminated clothing. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: If symptoms persist consult doctor. · Information for doctor: · Most important symptoms and effects, both acute and delayed No further relevant information available. · Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Firefighting measures · Extinguishing media · Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Special hazards arising from the substance or mixture Under certain fire conditions, traces of other toxic gases cannot be excluded. Hydrocarbons, carbondioxide and -monoxid. · Advice for firefighters · Protective equipment: Mouth respiratory protective device. Do not inhale explosion gases or combustion gases. · Additional information Cool endangered receptacles with water spray. Self-protection first! GB (Contd. on page 3)
35.0.33 Page 3/7 Printing date 16.10.2012 Safety data sheet according to 1907/2006/EC, Article 31 Version: 3 Revision: 02.03.2011 Trade name: PEROXAN PPV 6 Accidental release measures (Contd. of page 2) · Personal precautions, protective equipment and emergency procedures Remove persons from danger area. Keep away from ignition sources. After exceeding the emergency temperature must be diluted with a suitable desentisation agent to < 10 %. In case of further temperature should be cooled with waterspray from a safe distance. Take precautionary measures against static discharges. Wear breathing apparatus with filter A during decomposition of materials. Wear protective equipment. Keep unprotected persons away. · Environmental precautions: Do not allow to enter sewers/ surface or ground water. ?K@JL · Methods and material for containment and cleaning up: Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Large quantities should be diluted with suitable desensitation agent to a concentration below 10 % before disposal. Soak up with absorbant material (e. g. Vermiculit) and dispose of in accordance with government regulations. · Reference to other sections In case of large spillage the environmental authority should be informed. 7 Handling and storage · Precautions for safe handling Keep receptacles tightly sealed. Keep away from heat and direct sunlight. Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Prevent formation of aerosols. Wear suitable respiratory protective device when decanting larger quantities without extractor facilities. Handle with care. Avoid jolting, friction and impact. Do not refill residue into storage receptacles. Restrict the quantity stored at the work place. Use only in well ventilated areas. Before break and at the end of work hands should be thoroughly washed. Only use tools made of suitable materials (e. g. polyethylene or stainless steel). The product must be preserved, stored and transported continously cool. Keep away from dirt, rust, chemicals in particular concentrated acids, alkalis and accelerators (e. g. heavy-metal compounds and amines). Oxidizing because of releasing oxygene. While using do not eat, drink or smoke. Do not generate flames or sparks. Keep product and emptied container away from heat and sources of ignition. Avoid shock and friction. Take precautionary measures against static discharges. `bW Do not smoke. · Information about fire - and explosion protection: Protect from heat. Protect against electrostatic charges. Prevent impact and friction. Use explosion-proof apparatus / fittings and spark-proof tools. Fumes can combine with air to form an explosive mixture. `bV Wear shoes with conductive soles. Formation of flammable or explosive gas/air-mixtures is possible. Avoid open flames, sparks, direct sunlight and other sources of ignition. Keep ignition sources away - Do not smoke. · Conditions for safe storage, including any incompatibilities · Storage: Pay attention to the special requirements of your local autorithies for storing dangerous goods. · Requirements to be met by storerooms and receptacles: Store only in the original receptacle. Prevent any seepage into the ground. Use only receptacles specifically permitted for this substance/product. (Contd. on page 4) GB
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PEROXAN PPV - Pergan GmbH

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