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Contents<br />

9 Parabolic Mirror–Assisted Gap-Mode Optical<br />

Ultramicroscopy 355<br />

D. Zhang and A. J. Meixner<br />

9.1 Introduction 355<br />

9.2 Principles 356<br />

9.2.1 Instrumentation 359<br />

9.2.1.1 Optics layout 359<br />

9.2.2 PM Optics 361<br />

9.2.3 Tip-Sample Distance Control and Image<br />

Recording 365<br />

9.3 Different Types of Gap-Modes 367<br />

9.3.1 Gap-Mode of Metallic System 367<br />

9.3.1.1 Au tip and Au substrate 367<br />

9.3.1.2 Au tip and monolayer adsorbates/Au<br />

substrate 372<br />

9.3.1.3 Au tip and single molecule/Au<br />

substrate 377<br />

9.3.2 Gap-Mode of Metal-Organic Semiconductor<br />

System 379<br />

9.3.2.1 Au tip and diindenoperylene molecule 379<br />

9.3.2.2 Au tip and organic solar cell blends 379<br />

9.3.2.3 Gap-mode of metal-inorganic<br />

semiconductor system 381<br />

9.4 Conclusion 387<br />

10 Wet-Chemical Synthesis Techniques for Colloidal Plasmonic<br />

Nanostructures Assisted by Convective or Microwave<br />

Dielectric Heating 395<br />

L. Carbone<br />

10.1 Introduction 395<br />

10.1.1 Wet-Chemical Synthesis: Basic Principles 397<br />

10.1.1.1 Hybrid nanoarchitecture<br />

formation 401<br />

10.2 Synthesis under Conventional Convective Heating 402<br />

10.2.1 Hard-Templated Growth 402<br />

10.2.2 Precipitation-Promoted Growth 403<br />

10.2.3 Electrochemical and Shape-Controlled<br />

Growth 405

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