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A simple method for determining biochar condensation

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The output<br />

In the absence of ring currents, 13 C-benzene gives a peak at 128.7 ppm.<br />

Ring currents shift that peak to lower values when sorbed to <strong>biochar</strong><br />

Expressed as Δδ – i.e. the difference from 128.7 ppm<br />

Activated<br />

<strong>biochar</strong>s<br />

G<br />

Δδ ‐1.8<br />

Natural<br />

<strong>biochar</strong>s –from a<br />

bushfire<br />

Δδ ‐10.0<br />

Δδ ‐6.5<br />

Highly condensed<br />

structures (very<br />

negative Δδ values)<br />

Commercial<br />

activated carbon<br />

(AC1) more<br />

condensed than<br />

activated cow<br />

manure <strong>biochar</strong><br />

(AC2)<br />

OW<br />

Δδ ‐2.0<br />

PB<br />

Δδ ‐1.1<br />

EW1<br />

Δδ ‐2.0<br />

EW2<br />

Δδ ‐2.8<br />

Effect of starting<br />

material – wood<br />

<strong>biochar</strong>s (OW, EW)<br />

more condensed<br />

than grass <strong>biochar</strong><br />

(G) and bark<br />

<strong>biochar</strong> (PB)<br />

“Apparent”<br />

production<br />

temperature ~500-<br />

600°C <strong>for</strong> wood<br />

<strong>biochar</strong>s

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