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Ksp Problem Set - Widener University

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.0.3295 g BaF 2 dissolves in 250.0 mL of water at 25 °C<br />

mass :=<br />

0.3295⋅gm<br />

V :=<br />

250.0⋅mL<br />

MW BaF2 := ( 137.329 + 18.998⋅2) ⋅gm⋅<br />

mole − 1<br />

mass<br />

mole BaF2 := mole BaF2 = 1.879 × 10 − 3 mol<br />

MW BaF2<br />

M<br />

mole BaF2<br />

:= M 7.517 10 − 3 − 1<br />

= × mole⋅liter<br />

V<br />

The molar solubility is simply the concentration of the solution at equlibrium:<br />

M 7.517 × 10 − 3 − 1<br />

=<br />

mole⋅liter<br />

Since BaF 2 --> Ba 2+ + 2 F -<br />

K sp_BaF2 := 4⋅M 3<br />

K sp_BaF2 = 1.699 × 10 − 6<br />

⎛<br />

⎜<br />

⎝<br />

mole<br />

liter<br />

⎞<br />

⎟<br />

⎠<br />

3<br />

ksp_a.mcd<br />

3/25/2004<br />

2 S.E. Van Bramer<br />

svanbram@science.widener.edu

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