Handbook for the Chemical Analysis of Plastic and Polymer Additives

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Antioxidants 101 Mass Spectrum for Irganox ® 259 - PLAS-AX-045 Abundance Abundance Average of 44.034 of 44.034 to 44.263 to 44.263 min.: min.: PLAS-AX-045.D 219 219 95 95 MW=638.92 90 90 85 85 m/z Abundance 80 80 219 100 75 75 70 57 51 70 65 65 304 42 60 60 203 40 55 55 638 38 57 50 57 50 45 45 304 203 304 40 203 40 638 638 35 35 30 259 30 378 259 163 378 25 163 25 20 20 83 322 15 83 322 15 10 470 10 149 232245 455 189 360 470 526 5 149 176 232245 345 455 582 107 135 189 290 360 437 526 5 176 276 345 414 493 511 549 582 0 107 135 290 437 276 414 493 511 549 m/z--> 0 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420 440 460 480 500 520 540 560 580 600 620 640 660 680 700 m/z--> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420 440 460 480 500 520 540 560 580 600 620 640 660 680 700 For Chromatogram See Appendix A - PLAS-AX-045 - page 366
102 Irganox ® 3114 FF Handbook for the Chemical Analysis of Plastic and Polymer Additives Brand Names & Manufacturers Physical Properties Ciba Specialty Chemicals CAS Number 27676-62-6 RTECS Number Not available Abbreviation Formula C48H69N3O6 Molecular Weight 784.08 OH Chemical Name 1,3,5-tris(3,5-di-tert-butyl-4-hydroxybenzyl)-1,3,5-triazine-2,4,6-(1H,3H,5H)-trione Synonyms 1,3,5-tris((3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl)methyl)-1,3,5-triazine-2,4,6(1H,3H,5H)-trione; Tris(3,5-di-t-butyl-4-hydroxybenzyl) isocyanurate Cyanox ® 1741 Ethanox ® 314 Vanox ® GT HO O N N N O O Cytec Technology Corp. Albemarle Corporation R.T. Vanderbilt Company, Inc. Appearance Stability Solubility (g/100mL 20 Application, Regulatory & Environmental Information ° White crystalline powder. Melting Point 218-220 °C Boiling Point 961 °C Stable under normal conditions of use. C) Water 5000 mg/kg [Rat], Acute dermal toxicity (LD50): >2000 mg/kg [Rat], Acute toxicity of the dust (LC50): 270000 mg/m 3 4 hour(s) [Rat].
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HANDBOOK FOR THE CHEMICAL ANALYSIS
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CRC Press Taylor & Francis Group 60
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vi Handbook for the Chemical Analys
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ABOUT THE AUTHORS Jack Hubball, Ph.
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Importance of Polymers PREFACE Poly
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Preface xiii Polymers have undoubte
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xvi Handbook for the Chemical Analy
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2 Overview of Polymeric Compounds H
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4 Handbook for the Chemical Analysi
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10 Handbook for the Chemical Analys
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Introduction CHAPTER 2 Extraction a
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Extraction and Analysis 21 Figure 2
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Extraction and Analysis 23 Ethanox
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Extraction and Analysis 25 4. Pfaen
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28 Accelerator MBT, MBT/MG Handbook
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30 Accelerator ETU-22 PM S Handbook
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32 Accelerator BBTS Handbook for th
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34 Cure-Rite ® IBT IUPAC Name tetr
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36 Activator OT Urea IUPAC Name ure
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38 Accelerator EZ & EZ-SP N S Handb
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CHAPTER 4 Antidegradants Antidegrad
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Antidegradants 43 Mass Spectrum for
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Page 79 and 80: 62 Alkanox ® P27 O O P Handbook fo
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Page 83 and 84: 66 Mass Spectrum for Alkanox ® TNP
Page 85 and 86: 68 Antioxidant 60 Handbook for the
Page 87 and 88: 70 Cyanox ® 1790 HO Handbook for t
Page 89 and 90: 72 Mass Spectrum for Cyanox ® 1790
Page 91 and 92: 74 Cyanox ® 2246 Handbook for the
Page 93 and 94: 76 Cyanox ® 425 OH Chemical Name 2
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Page 99 and 100: 82 Ethanox ® 310 OH O Handbook for
Page 101 and 102: 84 Ethanox ® 330 Handbook for the
Page 103 and 104: 86 Mass Spectrum for Ethanox ® 330
Page 105 and 106: 88 Antioxidants Ethanox ® 376 OH H
Page 107 and 108: 90 Ethanox ® 702 Chemical Name 4,4
Page 109 and 110: 92 Ethanox ® 703 Handbook for the
Page 111 and 112: 94 Ethaphos ® 368 Chemical Name tr
Page 113 and 114: 96 Irganox ® 1035 HO (CH 2) 2 C Ha
Page 115 and 116: 98 Irganox ® 1081 OH Handbook for
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Page 121 and 122: 104 Irganox ® E 201 HO O Handbook
Page 123 and 124: 106 Irganox ® MD 1024 HO Handbook
Page 125 and 126: 108 Isonox ® 132 Chemical Name 2,6
Page 127 and 128: 110 Isonox ® 232 Chemical Name 2,6
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Page 131 and 132: Antioxidants 114 Lowinox ® AH25 O
Page 133 and 134: 116 Lowinox ® TBM-6 HO Handbook fo
Page 135 and 136: 118 Naugard ® 445 Handbook for the
Page 137 and 138: 120 Naugard ® A Chemical Name acet
Page 139 and 140: 122 Naugard ® B-25 OH Handbook for
Page 141 and 142: 124 Naugard ® BHT Chemical Name 2,
Page 143 and 144: 126 Naugard ® HM-22 CH3 C CH 3 Han
Page 145 and 146: 128 Naugard ® J H N Chemical Name
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Page 149 and 150: 132 Naugard ® PANA H N Chemical Na
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Page 153 and 154: 136 Mass Spectrum for Naugard ® PH
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Page 157 and 158: 140 Mass Spectrum for Naugard ® PS
Page 159 and 160: 142 Naugard ® PS-35 Chemical Name
Page 161 and 162: Antioxidants 144 Naugard ® Q Extra
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152 Naugard ® XL-1 HO Handbook for
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154 Santicizer ® 278 Handbook for
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156 Ultranox ® 626 O O P O Handboo
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CHAPTER 6 Coupling Agents Coupling
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Coupling Agents 161 Mass Spectrum f
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172 2,2',4,4'-Tetrabromodiphenyl et
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174 2,2',4,4',6-Pentabromodiphenyl
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176 2,2',4,4',5,6'-Hexabromodipheny
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178 Decabromodiphenyl ether Br Br C
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180 (Cl) x Chemical Name Not applic
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182 Firemaster BP4A HO Br Br Chemic
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184 Halowax 1051 Handbook for the C
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186 2-Butanone peroxide (in DMP) HO
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188 Adimoll DO O O Handbook for the
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190 Benzoflex ® 2-45 O O Handbook
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192 Bisphenol A Handbook for the Ch
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194 Butyl ricinoleate HO Chemical N
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196 Celogen ® SD-125 O H 2N N N NH
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198 Mass Spectrum for Celogen ® SD
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200 Citroflex ® 2 Chemical Name 2-
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202 Citroflex ® 4 O O Handbook for
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204 Citroflex ® A-2 Chemical Name
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206 Citroflex ® A-4 O O Handbook f
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208 Citroflex ® B-6 O O O O Handbo
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210 Dibutyl phthalate O Chemical Na
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212 Diethyl adipate O O Chemical Na
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214 Plasticizers Diethyl phthalate
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216 Diethyl succinate Handbook for
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218 Diisononyl adipate O O Handbook
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220 Handbook for the Chemical Analy
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222 Dioctyl maleate O O O O Chemica
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224 Dioctyl phthalate (DOP) O Chemi
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226 Epoxidized linseed oil O Chemic
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230 Flexol ® EP-8 Handbook for the
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232 Mass Spectrum for Flexol ® EP-
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234 Hercoflex ® 900 HO Handbook fo
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236 Mass Spectrum for Hercoflex ®
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238 Hi-Point ® PD-1 Handbook for t
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240 Imol S-140 H 3C Handbook for th
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242 Mass Spectrum for Abundance Ave
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244 Jayflex ® 77 O O O O Chemical
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246 Mass Spectrum for Jayflex ® 77
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248 Jayflex ® DIDP O O O Handbook
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250 Jayflex ® DINP O O O O Chemica
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252 Mass Spectrum for Jayflex ® DI
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254 Jayflex ® DTDP O Chemical Name
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256 Jayflex ® L11P-E O O O O Handb
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258 Plasticizers Kesscoflex TRA O C
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260 Laurex ® Chemical Name zinc sa
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262 Markstat ® 51 Handbook for the
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264 Mass Spectrum for Markstat ® 5
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266 Morflex ® 150 Handbook for the
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268 Morflex ® 190 O O Handbook for
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270 Morflex ® 310 O O Handbook for
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272 Morflex ® 560 O O Chemical Nam
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274 Morflex ® x-1125 O O O O Chemi
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276 Paraplex ® G-30 Chemical Name
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278 Plasthall ® DOZ O Chemical Nam
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280 Plastolein 9050 O O Chemical Na
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282 Polycizer ® 162 O Handbook for
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284 Polycizer ® 632 C 10H 21 O O H
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286 Polycizer ® butyl oleate C 4H
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288 Polycizer ® DP 500 Chemical Na
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292 Polycizer ® W 260 O Chemical N
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294 Santicizer ® 141 Handbook for
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296 Plasticizers Santicizer ® 160
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298 Vinsol ® resin Chemical Name g
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300 Witamol 500 O Handbook for the
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CHAPTER 9 Other Compounds of Intere
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Other Compounds of Interest 305 Mas
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326 Case Study #2: Peeling Labels H
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336 Analytical Conditions Summary H
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Chromatogram 342 Handbook for the C
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Chromatogram 396 Analytical Conditi
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404 Chromatogram for Aroclor 1254 -
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408 Chromatogram for Halowax 1051 -
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Chromatogram 410 Analytical Conditi
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412 Chromatogram for Bisphenol A -
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ABS Acrylonitrile butadiene styrene
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A Accelerated Soxhlet Extraction, 2
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Subject Index 467 Isonox ® , 112-1
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Subject Index 469 Uvinul ® 3040, 5
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MASS TO CHARGE RATIOS M.W. INTENSIT
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57-11-4 . . . . . . 312 57-13-6 . .
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