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Otto H. Zinke - University of Arkansas Physics Department

Otto H. Zinke - University of Arkansas Physics Department

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TRANSIENTS IN OSCILLATOR SYSTEMS 2351 K. Denbigh, The Principles <strong>of</strong> Chemical Equilibrium(Cambridge U~~iversity Press, Cambridge, England, 1968),p. 397 et seq.ST. L. Hill, Introduction to Stalistieal ThRllnodynamics(Addison-IVesley Publ. Co., Inc., &ding, Mm., 19GO),p. 86 et seq.8 See Ref. 2, p. 490 et seq.W. Born and T. von Karman, Physik. Z. 13,297 (1912).6 L. B. W, Jolley, Summation <strong>of</strong> Series (Dover Fublications,Inc., New York, 1961), p. 78.OH. Wergeland in Proceedings <strong>of</strong> the nTUFFIC InternationalSumm Course in Science, compiled by E. G. D.Cohen (North-Holland Publ. Co., Amsterdam), p. 58.Webster's New I&rnationaE Dictioaary (G. & C.hlerriam Co., Springfield, Mass.), 2nd ed., unabridged(scnles) .Lord lbyleigh, Theory <strong>of</strong> Sound (Dover Publications,Inc., New York, 1945), p. 16.M. Born, Proc. Phys. Soc. (London) 64,382 (1942).ANERICAN JOURNAL OF PHYSICS VOLUME 38. PiTjMBER 2 FEBRU.4RY 1970Bose-Einstein Condensation <strong>of</strong> Noninteracting ParticlesOTTO HENRY ZINEE<strong>Department</strong> <strong>of</strong> <strong>Physics</strong>, <strong>University</strong> <strong>of</strong> <strong>Arkansas</strong>, Fayetteuille, <strong>Arkansas</strong> 797'01(Received 12 June 1969; revision received 8 August 1969)Tlie cbemical potential is determined for a, Bose-Eiwtein gas <strong>of</strong> noninteracting particles in aclosed system. The calculation is done in a manner which shows dependence on an energy gap(a-a), limits <strong>of</strong> application <strong>of</strong> the results, and behavior through the transition temperature.The usual approaches to Bose-Einstein condensationfor noninteracting particles are typifiedby those <strong>of</strong> London,' Wilson,= Landau andLifschit~,~ &nd Jackson.4 The chemical potential isobtained from an expression involving a summation[see Eq. (2) below] which must be dividedfor evaluation into a single term involving thelowest energy level and a new summation [seeEq. (9) below]. London' has shown the dominantrole <strong>of</strong> the lowest energy level which leads rathernaturally to this divhion. Objections can be madewith respect t.o the evaluation <strong>of</strong> the new summation,which is inevitably integrated [see, e.g.,Eq. (4) <strong>of</strong> Ref. 1 or Eq. (6.42.4) <strong>of</strong> Ref. 21 in sucha way that the limits <strong>of</strong> application <strong>of</strong> the resultwith respect to temperature variation are notimmdately apparent. In particular, it is notapparent whether the derived expression isapplicable through the transition ternperdure. Itwill be shown below that the limits <strong>of</strong> application<strong>of</strong> the result are also dependent on the energydifference (a-Q). This dependence is not shownin existing derivations. Since the s term must beseparated from the series <strong>of</strong> energies representingthe levels for the noninteracting particles in a box,in principle, the eo level need not be such a level,and the energy difference (el- a) could have anyvalue. For this reason, the energy differencebetween the lowest and the next level is called a"gap" here.The approach below seems to meet the aboveob,jections. The calculations are started from theirbeginning to avoid the difficulty <strong>of</strong> correlationwith the various energy normalizations used byother authors.The average population <strong>of</strong> the jth level <strong>of</strong> acollection <strong>of</strong> noninteracting Bose-Einstein particlesisvhere gj is the statistical weight <strong>of</strong> the energystate Ej; r is the chemical potential; and all othersymbols have their usual meanings. The chemicalpotential is found as a function <strong>of</strong> N, V, T fromN= l/[exp( (ej-{)/kT] -1.1. (2)j20However, the range <strong>of</strong> values available to thechemical potential are restricted. If ei 5 T < ei+lfor some set <strong>of</strong> the macroscopic variables and somevalue <strong>of</strong> j=i, then for every jsi we have (Nj)

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