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Muribrom raticida cebo fresco - dafnagro.gr

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MATERIAL SAFETY DATA SHEET<br />

According to Spanish Royal Decree 255/2003 (Directive 2001/58/CE)<br />

Date / Updated 7th February 2005.<br />

1. Product and Company names<br />

MURIBROM RATICIDA CEBO FRESCO (MURIBROM RODENTICIDE FRESH BAIT)<br />

Comercial use: Rodenticide<br />

Company:<br />

Química de Munguia, S.A.<br />

Zabalondo, 44<br />

48100 Munguia (Vizcaya)<br />

Telf: (94) 6741985<br />

2. Composition/Indications of the in<strong>gr</strong>edients<br />

Chemical description<br />

Nº<br />

EINECS<br />

Bromadiolone 249-205-9 28772-56-7 0.005<br />

3. Product Hazards Identification<br />

Nº CAS % w/w Risk phrases Symbol<br />

1 / 5<br />

R28,R48/25,<br />

R50/53<br />

This product should be handled in accordance with the legislation in force referring to Safety<br />

and Higiene in work.<br />

3.1. Main hazards: HARMFUL. Xn.<br />

3.2. Risk phrases:<br />

R 48/22 Harmful: danger of serious damage to health by prolonged exposure if<br />

swallowed.<br />

4. First Aid Measures.<br />

4.1 Poisoning symptoms<br />

Poisoned victims may show evidence of excessive blood loss. The lengthened protrombin<br />

time is usually apparent within 24 hours and reaches a maximum of 36-72 hours after<br />

exposure.<br />

4.2 First Aid Measures<br />

Remove victim from the contaminated area.<br />

Remove immediately contaminated clothing.<br />

Flood ayes with plenty of water for at least 15 minutes.<br />

Skin should be washed of with plenty of water and soap. Do not scrub the skin.<br />

Do not give anything orally.<br />

If swallowed and the subject is conscious: provoke vomit.<br />

Subject should be resting. Corporal temperature must be observed.<br />

Respiration should be controlled, if necessary apply artificial respiration.<br />

T+, N


If the person is unconscious, lay the person on his/her side with the head in a lower position<br />

than the rest of the body, flexing knees to a half position.<br />

Immediately get medical attention and show the label or the container where possible.<br />

DO NOT LEAVE THE SUBJET ALONE<br />

4.3 Notes to a Physician<br />

If ingested, perform gastric decontamination depending on the stage of conscience.<br />

Administer a water solution of activated charcoal and a saline cathartic (sodium sulphate)<br />

Antidote: Vitamin K1<br />

Symptomatically treatment<br />

IN CASE OF POSOINING CALL TO POISON AND HAZARDOUS CHEMICALS<br />

NATIONAL INFORMATION CENTRE.<br />

5. Fire fighting measures<br />

Extinguishing Media: Use media suitable for the surrounding fire.<br />

Fire Fighting Instruction: Not applicable.<br />

Fire Fighting Equipment: Self-contained breathing apparatus (full face piece) and<br />

protective clothing.<br />

6. Accidental release measures<br />

Personal precautions: Manipulate in accordance with industrial hygiene cautions and taking<br />

into account the security practices.<br />

Methods for cleaning up: Collect in containers; collect the rest in absorbent material and<br />

eliminate according to the regional regulations.<br />

Wash small quantities with water. Eliminate the used water according to the<br />

regional regulations in force.<br />

7. Handling and storage<br />

7.1 Handling<br />

Read carefully the label before using.<br />

Keep away from people and/or domestic animals.<br />

Do not eat, drink or smoke at the workplace.<br />

7.2. Almacenamiento:<br />

Keep away from food and drink. Store in the original container tightly closed,<br />

below 30ºC.<br />

8. Exposure controls / Personal protection<br />

Ventilation: General ventilation is appropriate.<br />

Protective Clothing/Equipment: No special requirements.<br />

Respirator: None required under normal conditions of use<br />

Contaminated Equipment: Practice good personal hygiene.<br />

Comments: Never eat, drink or smoke in working areas. Practice good personal<br />

Hygiene after using this product<br />

2 / 5


9. Physical and Chemical Properties<br />

Physical state: Oily paste.<br />

Color: Red.<br />

Odor: Odourless<br />

Density: 0.73 <strong>gr</strong>/cm3 a 20 ºC<br />

Melting point: N.A.<br />

Boiling point: N.A.<br />

Vapour pressure: N.A<br />

Decomposition temperature: N.A.<br />

Flash point: N.A<br />

Solubility in water: Practically insoluble.<br />

Solubility in organic solvent: Obtained with some organic solvents.<br />

Partition coefficient octanol/water: N.A.<br />

Acidity/ Alcalinity: N.A.<br />

No mix with: Strong acids and bases.<br />

10. Stability and Reactivity<br />

Stable under normal conditions of temperature and humidity<br />

10.1. Conditions to avoid<br />

Avoid contact with oxidizing agents, acids and mild alkalis.<br />

10.2. Hazardous decomposition products<br />

Toxic products may be produced by thermal decomposition as a result, in case of fire or<br />

combustion do not breath fumes produced<br />

11. Toxicological Information<br />

DL50 oral rats: 22.5 g/kg<br />

DL50 oral mouse: 35 g/kg<br />

12. Ecological information<br />

1.1. Avoid contact with fluvial water.<br />

1.2. Persistence/De<strong>gr</strong>adability<br />

Product is highly de<strong>gr</strong>aded by the biochemical action of the soil.<br />

Persistence time may vary depending on the chemical and physical characteristics of the soil.<br />

1.3. Bio-accumulation:<br />

There is nothing indicating bioaccumulation of the product.<br />

1.4. Aquatic toxicity<br />

LC 50 Rainbow trout 1.4 mg/l (96h)<br />

LC 50 Bluegill sunfish 3.0 mg/l (96h)<br />

LC 50 Daphnia 2.0 mg/l (48h)<br />

1.5. Toxicity to birds<br />

LD 50 Bobwhite quail 138 mg/kg<br />

LC 50 Mallard duck 110 ppm<br />

3 / 5


13. Disposal considerations<br />

The disposal of large quantity should be carried out by accredited companies.<br />

Product remains and its containers are disposed in a responsible way for the environment.<br />

Avoid spillage next to the rivers, seas, lakes, wells or drains.<br />

The washing water should be recovered and neutralized<br />

14. Transport information<br />

Non applicable ADR<br />

15. Regulatory Information<br />

Señalización según el R.D 255/2003<br />

Classification according to Spanish Royal Decree 255/2003 (Directive 2001/58/CE).<br />

The product should be labelled with the following data:<br />

HARMFUL (Xn)<br />

Risk Phrases:<br />

R 48/22 Harmful: danger of serious damage to health by prolonged<br />

exposure if swallowed.<br />

Safety phrases:<br />

S 2 Keep out of reach of children<br />

S 13 Keep away from food, drink and animal feed stuffs.<br />

S 37 Wear suitable gloves.<br />

S 45 In case of accident or if you feel unwell, seek medical advice<br />

immediately and show the label where possible.<br />

16. Other information<br />

The information contained in the safety data sheet is correct to the best of our knowledge and it<br />

relates only to the provided product. This Safety Data Sheet does not substitute either to the<br />

summary of the product characteristics or the regulations in force. As a result, an inappropriate<br />

or improper use is only a responsibility of the user.<br />

QUÍMICA DE MUNGUÍA, S.A<br />

C/ Zabalondo 44, 48100 Munguía<br />

Vizcaya, SPAIN<br />

Tel. 946 741 085<br />

Fax 946 744 829<br />

www.quimunsa.com<br />

info@quimunsa.com<br />

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