SAFETY DATA SHEET OBJET Vero Black Plus ... - Laser Lines Ltd.

SAFETY DATA SHEETBased on Regulation (EC) No. 1907/2006 (REACH) Article 31 and Annex IIOBJET Vero Black Plus RGD8751. Identification of the substance/preparation and of the company/undertaking1.1 Identification of the substance or preparation:Product nameOBJET Vero Black Plus RGD875Product type REACHSpecial container containing a substance/preparationUnder normal conditions of use the substance is released from a cartridge only inside an appropriate printingsystemThe information refers to the substance/preparation1.2 Use of the substance/preparation:Ink cartridgeProfessional use1.3 Company/undertaking identification:Objet GMBHAirport Boulevard B 21077836 Rheinmünster, GermanyTel: +49 722 97 77 20Fax: +49 722 97 77 29 90info@objet.com, www.objet.com1.4 24H Emergency telephone service:+49 722 97772280 - Europe - Multi-lingual response+1 978 495 5580 - USA - Multi-lingual response+85 2 975 70887 - Asia Pacific - Multi-lingual response+61 2 8011 4763 - Australia - Multi-lingual response+86 15626070595 - China - Chinese response+49 722 97772281 – Global – English Language response2. Hazards identificationDSD/DPDClassified as dangerous in accordance with the criteria of Directives 67/548/EEC and 1999/45/ECHarmful if swallowedIrritating to respiratory system and skinRisk of serious damage to eyesMay cause sensitization by skin contactHarmful: danger of serious damage to health by prolonged exposure if swallowedHarmful to aquatic organisms, may cause long-term adverse effects in the aquatic environmentOther hazardsIn case of damage, the hazardous contents may be releasedThe contents are combustibleExposure is limited because of the form in which the product is placed on the marketCreated by: Objet Ltd. Publication date: 28‐12‐2011Reason for revision:DOC‐06142_A11/11

7. Handling and storage7.1 Handling:Keep away from naked flames/heatKeep container tightly closedAccidental release of the contents:observe very strict hygiene - avoid contactDo not discharge the waste into the drainSAFETY DATA SHEETBased on Regulation (EC) No. 1907/2006 (REACH) Article 31 and Annex IIOBJET Vero Black Plus RGD875Exposure is limited because of the form in which the product is placed on the marketIn case of damage, the hazardous contents may be released7.2 Storage:Safe storage requirements:Store in a dry area Storein a dark areaVentilation at floor levelStore at room temperatureKeep out of direct sunlightMeet the legal requirementsStorage temperature: 15 - 25 °CShipment temperature- up to 5 weeks: -20 to 50°CKeep away from:No data available7.3 Specific use(s):See information supplied by the manufacturer for the identified use(s)8. Exposure controls/Personal protection8.1 Exposure limit values:8.1.1 Occupational exposure:If limit values are applicable and available these will be listed below.8.2 Exposure controls:8.2.1 Occupational exposure controls:Accidental release of the contents: carry operations in the open/under local exhaust/ventilation or with respiratory protectionPersonal protective equipment:a) Respiratory protection:Not required for normal conditions of useAccidental release of the contents:Insufficient ventilation: wear respiratory protectionb) Hand protection:Not required for normal conditions of useAccidental release of the contents:GlovesDOC‐06142_A14/11

c) Eye protection:SAFETY DATA SHEETBased on Regulation (EC) No. 1907/2006 (REACH) Article 31 and Annex IIOBJET Vero Black Plus RGD875Not required for normal conditions of useAccidental release of the contents:Face shieldd) Skin protection:Not required for normal conditions of useAccidental release of the contents:Protective clothing8.2.2 Environmental exposure controls:See headings 6.2, 6.3 and 139. Physical and chemical properties9.1 General information:Physical formink cartridgeThe contents are: liquidOdourColourThe contents: characteristic odourThe contents: black9.2 Important health, safety and environmental information:Flashpoint > 100 °C9.3 Other information:10. Stability and reactivity10.1 Conditions to avoid:Possible fire hazardheat sourcesStabilityUnstable on exposure to heatUnstable on exposure to lightReactionsAfter destruction: polymerizes on exposure to UV light10.2 Materials to avoid:No data available10.3 Hazardous decomposition products:On burning: release of toxic and corrosive gases/vapors (nitrous vapors, carbon monoxide - carbon dioxide) and formation of small quantities ofphosphorus oxidesDOC‐06142_A15/11

11. Toxicological information11.1 Acute toxicity:Acrylic monomerSAFETY DATA SHEETBased on Regulation (EC) No. 1907/2006 (REACH) Article 31 and Annex IIOBJET Vero Black Plus RGD875LD50 oral (rat)LD50 dermal (rat)588 mg/kg> 2000 mg/kgexo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylateLD50 oral (rat)LD50 dermal (rabbit)4890 mg/kg> 5000 mg/kgPhotoinitiatorLD50 oral (rat)> 2000 mg/kg11.2 Chronic toxicity:Prolonged exposure: danger of damage to health if swallowedNot listed in carcinogenicity class (IARC,EC,TLV,MAK)Not listed in mutagenicity class (EC,MAK)Not classified as toxic to reproduction (EC)diphenyl(2,4,6-trimethylbenzoyl)phosphine oxideEC repr cat 3CLP repr cat category 211.3 Acute effects/symptoms:Inhalation:Irritation of the respiratory tractIrritation of the nasal mucous membranesSkin contact:Tingling/irritation of the skinEye contact:Irritation of the eye tissueInflammation/damage of the eye tissueIngestion:No effects known11.4 Chronic effects:ON CONTINUOUS/REPEATED EXPOSURE/CONTACT:Skin rash/inflammationDOC‐06142_A16/11

12. Ecological information12.1 Ecotoxicity:PhotoinitiatorLC50 fishesSAFETY DATA SHEETBased on Regulation (EC) No. 1907/2006 (REACH) Article 31 and Annex IIOBJET Vero Black Plus RGD875species value duration (h) remarksOryzias latipes 1 - 10 mg/l 48 hThreshold limit algaespecies value duration (h) remarksAlgae >10/100 mg/l 72 hAcute toxicity invertebratesspecies value duration remarksDaphnia magna 10 - 100 mg/l 48 h12.2 Mobility:12.3 Persistence and degradability:12.4 Bioaccumulative potential:12.5 Results of PBT assessment:Not applicable, based on available data12.6 Other adverse effects:Not dangerous for the ozone layer (1999/45/EC)13. Disposal considerations13.1 Provisions relating to waste:Waste material code (Directive 2008/98/EC, decision 2001/118/EC)08 03 12* : waste ink containing dangerous substancesDepending on branch of industry and production process, also other EURAL codes may be applicableHazardous waste according to Directive 2008/98/EC13.2 Disposal methods:Refer to manufacturer/supplier for information on recovery/ recyclingDo not landfillRemove waste in accordance with local and/or national regulationsHazardous waste shall not be mixed together with other waste. Different types of hazardous waste shall not be mixed together if this may entail a riskof pollution or create problems for the further management of the wasteHazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures toprevent risks of pollution or damage to people or animalsDo not discharge into drains or the environmentDOC‐06142_A17/11

13.3 Packaging/Container:No data availableSAFETY DATA SHEETBased on Regulation (EC) No. 1907/2006 (REACH) Article 31 and Annex IIOBJET Vero Black Plus RGD87514. Transport informationADRTransportNot subjectUN number -ClassPacking groupHazard identification numberClassification codeLabelsEnvironmentally hazardous substance markRIDnoTransportNot subjectUN number -ClassPacking groupClassification codeLabelsEnvironmentally hazardous substance markANDnoTransportNot subjectUN number -ClassPacking groupClassification codeLabelsEnvironmentally hazardous substance markIMOnoTransportNot subjectUN number -Class -LabelsMarine pollutant -Environmentally hazardous substance marknoDOC‐06142_A18/11

ICAOTransportSAFETY DATA SHEETBased on Regulation (EC) No. 1907/2006 (REACH) Article 31 and Annex IIOBJET Vero Black Plus RGD875UN number -ClassPacking groupLabelsEnvironmentally hazardous substance mark15. Regulatory information15.1 EU Legislation:DSD/DPDClassification according to directives 67/548/EEC, 1999/45/EC and 2006/8/ECNot subjectnoHarmfulContains: Acrylic monomer, Acrylic OligomerR-phrases22 Harmful if swallowed37/38 Irritating to respiratory system and skin41 Risk of serious damage to eyes43 May cause sensitisation by skin contact48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environmentS-phrases24 Avoid contact with skin26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice35 This material and its container must be disposed of in a safe way37/39 Wear suitable gloves and eye/face protection61 Avoid release to the environment. Refer to special instructions/safety data sheets.15.2 National provisions:GermanyTA-Luftexo-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl acrylate: TA-Luft Klasse 5.2.5/IWGK 3Classification water polluting based on the components in compliance withVerwaltungsvorschrift wassergefährdender Stoffe (VwVwS) of 27 July 2005 (Anhang 4)DOC‐06142_A19/11

SAFETY DATA SHEETBased on Regulation (EC) No. 1907/2006 (REACH) Article 31 and Annex IIOBJET Vero Black Plus RGD87515.3 Specific community rules:REACH Annex XVII - Restriction16. Other informationContains component(s) included in Annex XVII of Regulation (EC) No. 1907/2006: restrictions onthe manufacture, placing on the market and use of certain dangerous substances, mixtures andarticlesThe information in this safety data sheet is based on data and samples provided to BIG. The sheet was written to the best of our ability and accordingto the state of knowledge at that time. The safety data sheet only constitutes a guideline for the safe handling, use, consumption, storage, transportand disposal of the substances/preparations/mixtures mentioned under point 1. New safety data sheets are written from time to time. Only the mostrecent versions may be used. Old versions must be destroyed. Unless indicated otherwise word for word on the safety data sheet, the informationdoes not apply to substances/preparations/mixtures in purer form, mixed with other substances or in processes. The safety data sheet offers noquality specification for the substances/preparations/mixtures in question.Compliance with the instructions in this safety data sheet does not release the user from the obligation to take all measures dictated by commonsense, regulations and recommendations or which are necessary and/or useful based on the real applicable circumstances. BIG does not guaranteethe accuracy or exhaustiveness of the information provided. Use of this safety data sheet is subject to the licence and liability limiting conditions asstated in your BIG licence agreement. All intellectual property rights to this sheet are the property of BIG and its distribution and reproduction arelimited. Consult your BIG licence agreement for details.(*) = INTERNAL CLASSIFICATION (NFPA)PBT-substances = persistent, bioaccumulative and toxic substancesDSDDPDCLP (EU-GHS)Dangerous Substance DirectiveDangerous Preparation DirectiveClassification, labelling and packaging (Globally Harmonised System in Europe)Full text of any R-phrases referred to under headings 2 and 3:R22Harmful if swallowedR36/37/38 Irritating to eyes, respiratory system and skinR36/38 Irritating to eyes and skinR37/38 Irritating to respiratory system and skinR41Risk of serious damage to eyesR43May cause sensitisation by skin contactR48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowedR51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environmentR52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environmentR62Possible risk of impaired fertilityFull text of any H‐statements referred to under headings 2 and 3:H302Harmful if swallowed.H315H317H318H319H335H361fH373Causes skin irritation.May cause an allergic skin reaction.Causes serious eye damage.Causes serious eye irritation.May cause respiratory irritation.Suspected of damaging fertility.May cause damage to organs through prolonged or repeated exposure if swallowed.DOC‐06142_A110/11

H411SAFETY DATA SHEETBased on Regulation (EC) No. 1907/2006 (REACH) Article 31 and Annex IIOBJET Vero Black Plus RGD875Toxic to aquatic life with long lasting effects.Full text of any classes referred to under headings 2 and 3:Acute Tox. Acute toxicityAquatic Chronic Hazardous to the aquatic environment - chronicEye Dam. Serious eye damageEye Irrit. Eye irritationRepr.Reproductive toxicitySkin Irrit. Skin irritationSkin Sens. Skin sensitizationSTOT RE Specific target organ toxicity - repeated exposureSTOT SE Specific target organ toxicity - single exposureDOC‐06142_A111/11