assist EMAP with recruitment. Project results should be instrumental in increasing the success ofEMAP.Kendall Smith, Department of Modern Languages and ClassicsFaculty Mentor: Dr. Aida Toledo, Department of Modern Languages and ClassicsNicanor Parra, the Creator of Anti Poetry<strong>The</strong> Chilean poet Nicanor Parra created the idea of Anti Poetry, from which he has gainedworldwide fame. What distinguishes Parra's "Anti Poetry" from other genres of writing? Whatrole does Parra play in the development of Latin American poetry in South America, especiallyChile? How has Chile's political, economical and social background and history affected Parra asa person and as a Poet? What does the Nobel Prize mean for Parra & why has he yet to receiveit?M. Quentin Sonnier, Jr., Department of ChemistryFaculty Mentor: Dr. Kevin Shaughnessy, Department of ChemistryPalladium Catalyzed Suzuki Coupling with Water-soluble phosphine ligands to PromoteActivation of aryl halides<strong>The</strong> development of new reaction conditions for Suzuki a coupling reactions has become an areaof interest over the past several years. Previous studies have been undertaken with moderate togood yields under relatively benign reaction conditions. Our motivation is to utilize watersolublephosphine derivatives to improve on these reaction conditions, improve yields, reactiontime, allow for reactions to be carried out at ambient temperature, and lower catalyst loading. Itis thought that increasing electronic donation into the palladium metal center from the phosphinewill aide in oxidative addition into the aryl halide bond. Additionally it is thought that stericallydemanding groups on the phosphine ligand increase subsequent reductive elimination ormigratory insertion steps. Water-soluble phosphines have been developed to be electronicreleasing and sterically demanding, while offering potential for recyclability due to watersolubility. Moreover, the water-soluble ligands we have developed are phosphonium salts,which are easily deprotonated, that offer greater stability when shipping or in open atmosphere.<strong>The</strong> use of the water-soluble ligand, 3-(di-tert-butylphosphino)propanesulfonate (DTBPSP) hasdemonstrated good activity towards Suzuki coupling of electron rich and deficient aryl bromideswith 73-84% yields at room temperature. <strong>The</strong> water-soluble ligand 3-(diadamantylphosphino)propanesulfonate (DAPSP) has demonstrated activitation of electronrich and deficient aryl bromides with 64-92% yield at room temperature. Future work willinclude expanding these ligands to aryl chlorides. We also will be to expand these ligands toother coupling reactions and into generating palladium-ligand complexes.Jarrod Stanley, New College, and McNair Scholars ProgramFaculty Mentor: Dr. Celia Lo, Department of Criminal Justice<strong>School</strong>-Related Factors and Methamphetamine Use: A Study of High <strong>School</strong> SeniorsThis study sought to identify the factors that influence a high school senior's decision to trymethamphetamine. Using data from the 2005 Monitoring the Future survey, a model was developed andtested using logistic regression techniques. Social bonding variables, including absenteeism, cognitiveconfidence, educational efficacy, and goals were first entered into the model with the control variables,race and gender. Social learning variables, including peer use, perceived risk, and prior marijuana usewere entered in the model in a second step. <strong>The</strong> results showed that while absenteeism and educational63
efficacy had some impact on the likelihood of methamphetamine use, these effects were mediated by themore proximal role of the social learning variables. Policy implications are briefly discussed.Regan Stevens, Department of <strong>The</strong>atre and DanceFaculty Mentor: Professor Seth Panitch, Department of <strong>The</strong>atre and Dance<strong>The</strong> Necessity of the Arts in EducationIn today’s education system, as budget cuts are prevalent in public schools, arts education mustremain a facet of the K-12 education system. Art is an important aspect of an effective educationdue to its unequaled capacity to instill positive cultural values. Art teaches tolerance throughexposure to the arts of many different cultures, creativity through the realization of one’spotential to formulate and manifest an idea, and socialization through learning a variety of modesfor personal expression.Jackson Switzer, Department of Chemistry, and Computer-Based Honors ProgramFaculty Mentor: Dr. David Dixon, Department of ChemistryEnergetics Relevant to the Atmospheric Decomposition of Chemical WeaponsHigh level molecular orbital theory has been used to predict the electronic structure andenergetics for the decomposition of sarin, tabun, and soman (chemical weapons of massdestruction) in the environment. Very high accuracy methods on model compounds were used tobenchmark the calculated results leading to new ideas about bond energies. We are predicting:(1) how quickly these compounds can decompose in the atmosphere; (2) what gases could beadded in a region where they have been dispersed to enhance their decomposition; and (3) theirdestruction by chemical means.Laughlin Tagg, New CollegeFaculty Mentor: Dr. Janeann Dill, New CollegeInterdisciplinary Art: Deep Research and Experimental Animation<strong>The</strong> critical point of view I am arguing is that we as a culture lack a strong social consciousness.Our perceptions are distorted, primarily because of cultural dependence on mass media andtechnology. Exploring how media dependency affects American cultural perception, <strong>The</strong>Simpsons and the animated sitcom are relevant entertainment to the public. <strong>The</strong> creator, MattGroening’s personal background and central concept provide full understanding of hisinterdisciplinary approach to sending the American public a message, as well as the role of artand experimental animation in contemporary American culture.Russ Terry, Department of ChemistryFaculty Mentor: Dr. Silas Blackstock, Department of ChemistryLooking for Isomorphs of Tetramethylpyrazinedioxide to tune Barrier to DA CoCrystal LatticeIsomerizationI am attempting to synthesize isomorphs of tetramethylpyrazinedioxide (TMPDO) as part of alarger effort to create a CoCrystal between it (my product, the isomorph) and tetracyanoethylene(TCNE). This work is important because CoCrystals exhibit unique properties that are distinctfrom any other type of crystals—particularly in regard to the way they share electrons—and weare hoping in the future to delve more deeply into this interesting property through the use of myisomorphs.64
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THE UNIVERISTY OF ALABAMAFirst Annu
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Office of the Provostand Vice Presi
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