<strong>NI</strong>-<strong>191</strong>-42. Hazards identificationOver-exposure signs/symptomsInhalationIngestionSkinEyesMedical conditionsaggravated by overexposureSee toxicological information (Section 11): Adverse symptoms may include the following:respiratory tract irritationcoughing: No specific data.: No specific data.: Adverse symptoms may include the following:irritationredness:Pre-existing disorders involving any target organs mentioned in this MSDS as being atrisk may be aggravated by over-exposure to this product.3. Composition/information on ingredientsName CAS number %Nickel 7440-02-0 20 - 50Cobalt 7440-48-4 20 - 50Chromium 7440-47-3 5 - 20Aluminium 7429-90-5 5 - 20Yttrium 7440-65-5
<strong>NI</strong>-<strong>191</strong>-45. Fire-fighting measuresSpecial exposure hazards :Hazardous thermaldecomposition productsSpecial protectiveequipment for fire-fighters6. Accidental release measuresPersonal precautions :Environmental precautionsMethods for cleaning upSmall spill :Large spill :7. Handling and storage:Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining.: Decomposition products may include the following materials:metal oxide/oxidesFire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Avoid breathing dust. Provideadequate ventilation. Wear appropriate respirator when ventilation is inadequate. Puton appropriate personal protective equipment (see Section 8).: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air).Move containers from spill area. Vacuum or sweep up material and place in adesignated, labeled waste container. Dispose of via a licensed waste disposalcontractor.Move containers from spill area. Approach release from upwind. Prevent entry intosewers, water courses, basements or confined areas. Vacuum or sweep up materialand place in a designated, labeled waste container. Avoid creating dusty conditions andprevent wind dispersal. Dispose of via a licensed waste disposal contractor. Note: seesection 1 for emergency contact information and section 13 for waste disposal.HandlingStorage::Put on appropriate personal protective equipment (see Section 8). Eating, drinking andsmoking should be prohibited in areas where this material is handled, stored andprocessed. Workers should wash hands and face before eating, drinking and smoking.Remove contaminated clothing and protective equipment before entering eating areas.Avoid exposure - obtain special instructions before use. Do not get in eyes or on skin orclothing. Do not ingest. Avoid breathing dust. If during normal use the materialpresents a respiratory hazard, use only with adequate ventilation or wear appropriaterespirator. Keep in the original container or an approved alternative made from acompatible material, kept tightly closed when not in use. Empty containers retainproduct residue and can be hazardous. Do not reuse container.Store in accordance with local regulations. Store in original container protected fromdirect sunlight in a dry, cool and well-ventilated area, away from incompatible materials(see section 10) and food and drink. Keep container tightly closed and sealed until readyfor use. Containers that have been opened must be carefully resealed and kept uprightto prevent leakage. Do not store in unlabeled containers. Use appropriate containmentto avoid environmental contamination.8. Exposure controls/personal protectionIngredientExposure limitsNickel ACGIH TLV (United States, 2/2010). Notes: Refers to Appendix A --Carcinogens. Inhalable fraction. See Appendix C, paragraph A.Inhalable Particulate Mass TLVs (IPM–TLVs) for those materialsthat are hazardous when deposited anywhere in the respiratorytract. 1998 Adoption.TWA: 1.5 mg/m³ 8 hour(s). Form: Inhalable fraction<strong>NI</strong>OSH REL (United States, 6/2009). Notes: as NiTWA: 0.015 mg/m³, (as Ni) 10 hour(s).OSHA PEL (United States, 6/2010). Notes: as NiTWA: 1 mg/m³, (as Ni) 8 hour(s).11/9/2012.Z<strong>NI</strong><strong>191</strong>-04103/9
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