58An increased frequency of chromosomal aberrations in peripheral lymphocytes inprinting workers exposed to inter alia toluene was found in two studies, but not intwo other studies. In one study, an increased frequency of chromosomal aberrationswas found in workers exposed to toluene and benzene. In one study of a groupexposed to toluene, an increased frequency of sister chromatid exchange was found,but not in two other studies.In one study of printers exposed to lead, increased frequencies of chromosomalaberrations and sister chromatid exchange were found.In one study, an increased frequency of micronuclei was observed in printingworkers exposed to toluene. In one study of volunteers exposed to toluene, noincrease in sister chromatid exchange was observed in lymphocytes.As we can see that there is a clear relationship between hazardous chemicals usedin printing and illnesses. It is undeniable realism.3.7 Minimization of Health Impacts of Printing Chemicals3.7.1 UV PrintingNowadays there are innovations in printing like other sectors, and UV printing,UV cured inks and even UV cationic inks and lacquers have been developed.The implementation of the 1990 Clean Air Act (CAA) has had a major effect onthe coatings industry in terms of reducing Volatile Organic Compounds (VOCs).Ultraviolet (UV) curing coatings have emerged as one of the efficient vehicles tochallenge the VOC limits in organic coatings . In addition, UV coatings also offer theadvantages of fast curing speed, high energy efficiency, and low capital investmentand space requirement. These coatings are especially suitable for the wood(furniture) or plastics coating, metal decorating, and paper printing industries. This isa consequence of an ambient temperature cure . There are two principle mechanismsin which the UV coatings polymerize on the substrates, free radical and cationic(Wua, Searsa, Souceka& Simonsickb, 1999). The most widely used in UV-radiation
59curing: acrylates, which polymerize by a radical mechanism, and epoxides, whichpolymerize by a cationic mechanism.In free radical initiated polymerization, free radicals are generated using eitherunimolecular photoinitiators (benzoylketals) or bimolecular photoinitiators(thioxanthones). Multi-functional acrylate esters are used with acrylatefunctionalized oligomers to form highly crosslinked films. The functionality of themonomers can range from one to six functionality. To balance the reactivity andoverall performance, a mixture of mono, di, and tri/higher functional monomers arecommonly used. Free radical polymerization, however, exhibits oxygen inhibition ofpropagating radicals. In addition, acrylate monomers also represent odor problems,and more importantly, health hazards (Wua, Searsa, Souceka, & Simonsickb, 1999).Acrylic UV-systems contain high molecular oligomers or prepolimers and alsophotoinitiators (i.e. benzophenon).Although UV light drying technologies have already been in use for over 30 yearsin the printing industry, it is still considered as a new technology in comparison withconventional printing. Before UV-curing technologies, hazardous chemicalscontaining VOC’s and heavy metal pigments are used in printing, causing healthproblems on workers. Furthermore for 30 years chemical substances such asbenzophenols, amines and acryclic acids have been used in conventional UV curingand these were also harmful for the people and environment.In Turkey, since 1980, UV inks and lacquers are in use and some of thesechemicals have hazardous characteristics. It is estimated that about 60-85 tons ofUV-lacquers, 20-30 tons auxilary materials and 40-60 tons of cleaning solvents areused per month in Turkey. These figures indicate the importance of the problem. Onthe other hand, UV printing within the concept of cationic system with newlydeveloped inks and lacquers are much more environmental friendly and theapplication of this technique is increasing in time. (Türkman, Akgün, Onuş, &Özman, 2005).
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4ACKNOWLEDGMENTSI would like to exp
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102.2.3.1 Pigments ................
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125.1.4 Conformity of Foodstuff Pac
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2On the other hand OSHA gives diffe
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4The environment has a certain capa
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6as dynamite or black powder, that
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- Page 29 and 30: 17surface of the substrate is press
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- Page 33 and 34: 212.2.2.1 Solvent-based InkThese in
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- Page 37 and 38: 25Table 2.4 The most common types o
- Page 39 and 40: 27-Precipitation. Excess water (usu
- Page 41 and 42: 29The chemicals used in each ink sy
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- Page 45 and 46: 33Polybrominated bi-or terphenylsPo
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- Page 51 and 52: 39CHAPTER THREEHEALTH AND SAFETY IN
- Page 53 and 54: 41H-Compensation, rehabilitation an
- Page 55 and 56: 43Occupational injury is any such i
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- Page 63 and 64: 51Exposure to solvents may cause co
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- Page 85 and 86: 73(substances and preparations acco
- Page 87 and 88: 75As a result of the compromise, us
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- Page 91 and 92: 79It identifies the hazards and off
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- Page 99 and 100: 87Table 4.2 Occupatıonal Exposure
- Page 101 and 102: 89Regulations on OHS in National Le
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- Page 105 and 106: 93Monitoring exposure to these chem
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109harmonized legislation, the dire
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111The most important general requi
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113-Communication No :2005/34 Commu
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115CHAPTER SIXEXPERĐMENTAL STUDY6.
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117CHAPTER SEVENCONCLUSIONAn estima
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119Ultraviolet (UV) curing coatings
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121hazards make On 13 November 2004
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123Buser, H. R. (2001). The Seveso
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125Herlihy, S.L., Rowatt B., & Davi
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127Pocas, M.F. & Hogg, T. (2007). E
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129United States of. Department of
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131Yang Hu, C., & J. Raymond, D. J.