DK Eyewitness - Astronomy
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Kirchhoff and bunsen<br />
Following the invention of<br />
the clean-flame burner by the<br />
German chemist Robert Bunsen<br />
(1811–1899), it was possible to<br />
study the effect of different<br />
chemical vapors on the known<br />
pattern of spectral lines. Together,<br />
Gustav Kirchhoff and Bunsen<br />
invented a new instrument<br />
called the spectroscope to<br />
measure these effects. Within<br />
a few years, they had managed<br />
to isolate the spectra for many<br />
known substances, as well<br />
as to discover a few<br />
unknown elements.<br />
Eyepiece<br />
Continuous<br />
spectrum<br />
Absorbing color<br />
To prove his laws<br />
of spectral analysis,<br />
Kirchhoff used sodium<br />
gas to show that when<br />
white light is directed<br />
through the gas, the<br />
characteristic color<br />
of the sodium is<br />
absorbed and the spectrum shows black lines where the sodium should<br />
have appeared. In the experiment shown above, a continuous spectrum (top)<br />
is produced by shining white light through a lens. When a petri dish of the<br />
chemical potassium permanganate in solution is placed between the lens<br />
and the light, some of the color of the spectrum is absorbed.<br />
Spectrum of the stars<br />
By closely examining the spectral lines<br />
in the light received from a distant star, the<br />
astronomer can detect these “fingerprints” and<br />
uncover the chemical composition of the object<br />
being viewed. Furthermore, the heat of the<br />
source can also be discovered by studying the<br />
spectral lines. Temperature can be measured<br />
by the intensities of individual lines in their<br />
spectra. The width of the line provides<br />
information about temperature, movement,<br />
and presence of magnetic fields. With<br />
magnification, each of these spectra<br />
can be analyzed in more detail.<br />
The spectrum<br />
of potassium<br />
permanganate<br />
Micrometer (p.25)<br />
Latticework frame<br />
Prisms<br />
Eyepiece<br />
Norman lockyer (1836–1920)<br />
During the solar eclipse of 1868, a<br />
number of astronomers picked up a<br />
new spectral line in the upper surface of<br />
the Sun, the chromosphere (p.39). The English<br />
astronomer Lockyer realized that the line did not coincide with<br />
any of the known elements. The newly discovered element was<br />
named helium (Helios is Greek for the sun god). It was not until<br />
1895, however, that helium was discovered on Earth.<br />
The spectroscope<br />
A spectroscope uses a series of<br />
prisms or a diffraction grating—a device<br />
that diffracts light through fine lines to form<br />
a spectrum—to split light into its constituent<br />
wavelengths (pp.32–33). Before the era of<br />
photography, an astronomer would view the<br />
spectrum produced with the eye, but now it is<br />
mostly recorded with an electronic detector<br />
called a CCD (p.37). This 19th-century spectroscope<br />
uses a prism to split the light.<br />
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