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DK Eyewitness - Astronomy

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Kirchhoff and bunsen<br />

Following the invention of<br />

the clean-flame burner by the<br />

German chemist Robert Bunsen<br />

(1811–1899), it was possible to<br />

study the effect of different<br />

chemical vapors on the known<br />

pattern of spectral lines. Together,<br />

Gustav Kirchhoff and Bunsen<br />

invented a new instrument<br />

called the spectroscope to<br />

measure these effects. Within<br />

a few years, they had managed<br />

to isolate the spectra for many<br />

known substances, as well<br />

as to discover a few<br />

unknown elements.<br />

Eyepiece<br />

Continuous<br />

spectrum<br />

Absorbing color<br />

To prove his laws<br />

of spectral analysis,<br />

Kirchhoff used sodium<br />

gas to show that when<br />

white light is directed<br />

through the gas, the<br />

characteristic color<br />

of the sodium is<br />

absorbed and the spectrum shows black lines where the sodium should<br />

have appeared. In the experiment shown above, a continuous spectrum (top)<br />

is produced by shining white light through a lens. When a petri dish of the<br />

chemical potassium permanganate in solution is placed between the lens<br />

and the light, some of the color of the spectrum is absorbed.<br />

Spectrum of the stars<br />

By closely examining the spectral lines<br />

in the light received from a distant star, the<br />

astronomer can detect these “fingerprints” and<br />

uncover the chemical composition of the object<br />

being viewed. Furthermore, the heat of the<br />

source can also be discovered by studying the<br />

spectral lines. Temperature can be measured<br />

by the intensities of individual lines in their<br />

spectra. The width of the line provides<br />

information about temperature, movement,<br />

and presence of magnetic fields. With<br />

magnification, each of these spectra<br />

can be analyzed in more detail.<br />

The spectrum<br />

of potassium<br />

permanganate<br />

Micrometer (p.25)<br />

Latticework frame<br />

Prisms<br />

Eyepiece<br />

Norman lockyer (1836–1920)<br />

During the solar eclipse of 1868, a<br />

number of astronomers picked up a<br />

new spectral line in the upper surface of<br />

the Sun, the chromosphere (p.39). The English<br />

astronomer Lockyer realized that the line did not coincide with<br />

any of the known elements. The newly discovered element was<br />

named helium (Helios is Greek for the sun god). It was not until<br />

1895, however, that helium was discovered on Earth.<br />

The spectroscope<br />

A spectroscope uses a series of<br />

prisms or a diffraction grating—a device<br />

that diffracts light through fine lines to form<br />

a spectrum—to split light into its constituent<br />

wavelengths (pp.32–33). Before the era of<br />

photography, an astronomer would view the<br />

spectrum produced with the eye, but now it is<br />

mostly recorded with an electronic detector<br />

called a CCD (p.37). This 19th-century spectroscope<br />

uses a prism to split the light.<br />

31

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