Slickgone NS - Australian Maritime Safety Authority

National Plan to Combat the Pollution 

of the Sea by Oil and Other Noxious 

and Hazardous Substances 

OIL SPILL RESPONSE 

OCCUPATIONAL HEALTH AND SAFETY 

MANUAL 

ANNEX 4 

MATERIAL SAFETY DATA SHEETS 

90

ANNEX 4 - MATERIAL SAFETY DATA SHEETS 

Material Safety Data Sheet 

Page 1 of 4 Issue date: March 2008 

ARDROX 6120LT 

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER 

Product Name: ARDROX 6120LT 

Use: OIL SPILL DISPERSANT 

CHEMETALL (AUSTRALASIA) PTY LTD 

17 TURBO DRIVE, BAYSWATER NORTH, VICTORIA 3153, AUSTRALIA. 

ACN. 074 869 015 

PH: 03 9729 6253 FAX: 03 9720 1711 

CHEMETALL (NZ) LTD 

BOX 82-286 HIGHLAND PARK, AUCKLAND, NEW ZEALAND. 

PH 64-9-579 2888 FAX 64-9-579 0888 

Emergency Advice All Hours: 

Technical manager ph 61(03) 9729 6253 (business hours) fx 61(03) 9720 1711 

pager (all hours) 61(03) 9625 0722 

(In New Zealand ph 9579 2888 in business hours) 

2. HAZARDS IDENTIFICATION 

CLASSIFIED AS HAZARDOUS ACCORDING TO THE CRITERIA OF NOHSC AUSTRALIA 

Hazard Category: Irritant (Xi) 

Hazard Classification: HAZARDOUS SUBSTANCE, NON-DANGEROUS GOOD 

RISK PHRASES 

R36/38 Irritating to eyes and skin. 

SAFETY PHRASES 

S24/25 Avoid contact with skin and eyes. 

S26 In case of contact with eyes, rinse immediately with plenty of water and contact a doctor or Poisons Information 

Centre. 

S37/39 Wear suitable gloves and eye/face protection. 

Poison Schedule: S5 [Aust] 

This material is a Scheduled S5 Poison and must be stored, handled and used according to the appropriate regulations. 

3. COMPOSITION / INFORMATION ON INGREDIENTS 

SUBSTANCE NAME Proportion CAS Number 

BUTYL DIGLYCOL 10 to 30% 112-34-5 

SURFACTANTS-ANIONIC (INC SOAPS) 10 to 30% Mixture 

All other ingredients not hazardous according to NOHSC Criteria. 

4. FIRST AID MEASURES 

Swallowed: 

If swallowed, DO NOT induce vomiting. If victim is conscious give water. If sickness persists transport to hospital or 

doctor. 

Eye: 

If material is splashed into eyes, immediately, flush with plenty of water for 15 minutes, ensuring eye lids are held 

open. If irritation persists transport to hospital or doctor. 

92



ARDROX 6120LT 

Skin: 

If material is splashed onto the skin, remove any contaminated clothing and wash skin thoroughly with water and soap 

if available. If irritation persists transport to hospital or doctor. 

Inhaled: 

Move victim to fresh air. Apply resuscitation if victim is not breathing. 

First Aid Facilities: 

Eye wash fountain, safety shower and normal wash room facilities. 

Advice to Doctor: 

Treat symptomatically. 

In case of poisoning, contact Poisons Information Centre 

In Australia call Tel: 131126 

In New Zealand Tel: 03 474 7000 

5. FIRE-FIGHTING MEASURES 

Fire/Explosion Hazard 

If safe to do so, move undamaged containers from fire area. 

Hazardous Decomposition Products: Nil 

Extinguishing Media: Use extinguishing media suitable for surrounding fire situation. 

HAZCHEM CODE: None allocated [Aust] 

FLAMMABILITY 

This material is not a flammable or combustible liquid. 

6. ACCIDENTAL RELEASE MEASURES 

Material may be slippery when spilt. Walk cautiously 

7. HANDLING AND STORAGE 

Store in a cool place and out of direct sunlight. Keep containers closed, when not using the product. Store in original 

packages as approved by manufacturer. 

8. EXPOSURE CONTROLS / PERSONAL PROTECTION 

Exposure Standards 

No exposure standards have been assigned by [NOHSC] for this product or any of the components. 

Engineering Controls 

Maintain adequate ventilation at all times. In most circumstances natural ventilation systems are adequate unless the 

material is heated, reacted or otherwise changed in some type of chemical reaction, then the use of a local exhaust 

ventilation system is recommended. 

Personal Protection Equipment 

CLOTHING: PVC or natural rubber apron or splash suit. 

GLOVES: PVC or natural rubber. 

EYES: Chemical goggles or faceshield to protect eyes. 

9. PHYSICAL AND CHEMICAL PROPERTIES 

Appearance: Clear Amber liquid 

Specific Gravity: 1.03 

Flash Point: Not determined 

Solubility in Water: Soluble 

93



10. STABILITY AND REACTIVITY 

STABILITY: 

Stable under normal conditions of use. 

HAZARDOUS DECOMPOSITION PRODUCTS: 

Emits smoke and fumes when heated to decomposition. 

HAZARDOUS POLYMERIZATION: 

Will not occur. 

INCOMPATIBILITIES: 

Oxidizing agents. 

CONDITIONS TO AVOID: 

Heat, flames, ignition sources and incompatibles. 

ARDROX 6120LT 

11. TOXICOLOGICAL INFORMATION 

No adverse health effects are expected, if the product is handled in accordance with this Material Safety Data Sheet and 

the product label. Symptoms and effects that may arise if the product is mishandled and overexposure occurs are: 

ACUTE HEALTH EFFECTS: 

Swallowed: 

May cause irritation to mouth, throat and stomach with effects including mucous build up, irritation to the tongue and 

lips and pains in the stomach, which may lead to nausea, vomiting and diarrhoea. 

Eye: 

Will cause irritation to the eyes, with effects including: tearing, pain, stinging and blurred vision. Depending upon 

duration of exposure, eye damage may occur. 

Skin: 

Will cause irritation to the skin, with effects including; Redness, itchiness, and possible dermatitis. 

Inhaled: 

May cause irritation to the nose, throat and respiratory system with effects including: Dizziness, headache and loss of 

co-ordination. 

Chronic: 

Prolonged or repeated skin contact may lead to dermatitis. 

Prolonged contact may cause severe eye irritation and some form of permanent eye damage may occur. 

Toxicological Data: 

There is no other toxicological information available for this product. 

12. ECOLOGICAL INFORMATION 

There is no ecological information available for this product, however, large quantities should not be discharged into 

drains, sewers or waterways. 

13. DISPOSAL CONSIDERATIONS 

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste by an approved waste 

agency. Processing, use or contamination of this product may change the waste management options. Dispose of 

container and unused contents in accordance with federal, state and local requirements. 

94



ARDROX 6120LT 

14. TRANSPORT INFORMATION 

UN Number: None allocated 

Proper Shipping Name: NONE ALLOCATED 

Dangerous Goods Class: None allocated 

Packing Group: None allocated 

Label: Irritant (Xi) 

Hazchem Code: None allocated 

Not classified as a Dangerous Good according to the Australian Code for the Transport of Dangerous Goods by Road 

and Rail (ADG Code) 6th Edition. Not classified as a Dangerous Good according to the UN, DOT(US), IACO(IATA) 

or IMO(IMDG). 

15. REGULATORY INFORMATION 

Poison Schedule: S5 [Aust] 

Inventory Status: 

Australia (AICS) All ingredients are on the inventory. 

16. OTHER INFORMATION 

Contact Point 

Technical manager ph 61(03) 9729 6253 fx 61(03) 97201711 Emergency Pager 61(03) 96250722. (A.H.) 

In New Zealand ph 9579 2888 

Disclaimer 

The information herein is to the best of our knowledge, correct and complete. It describes the safety requirements for 

this product and should not be construed as guaranteeing specific properties. Since methods and conditions are beyond 

our control Chemetall (Australasia) Pty Ltd and its associated companies does not accept liability for any damages 

resulting from the use of, or reliance on, this information in inappropriate contexts. 

------------------ 

Revision Date: March 2008 

------------------ 

Reason for Revision : 

First Issue 

END OF MSDS 

95

SAFETY DATA SHEET 

PRODUCT 

COREXIT (R) EC9500A 

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

PRODUCT NAME : COREXIT (R) EC9500A 

COMPANY IDENTIFICATION : Nalco Australia Pty Ltd 

2 Anderson Street 

Botany N.S.W. 2019, 

Australia 

A.B.N. 41 000 424 788 

TEL: +61 2 9316 3000 

FAX: +61 2 9666 5292 

EMERGENCY TELEPHONE NUMBER(S) 

+800 2537 8747 (free call) or +65 6542 9595 (Singapore) 

EMERGENCY TELEPHONE NUMBER(S) : +800 2537 8747 (free call) or +65 6542 9595 (Singapore) 

Date issued : 26.10.2008 

Version Number : 1.3 


HAZARD CLASSIFICATION : 

Not classified as hazardous according to the criteria of the National Occupational Health and Safety Commission 

(NOHSC). This product is not classified as a dangerous good according to national or international regulations. 


S24/25 - Avoid contact with skin and eyes. 

S37/39 - Wear suitable gloves and eye/face protection. 

3. COMPOSITION/INFORMATION ON INGREDIENTS 

CHEMICAL NAME CAS NO % (w/w) 

Distillates, petroleum, hydrotreated light 64742-47-8 10 - 30 

Propylene Glycol 57-55-6 1 - 30 

Di(2-Ethylhexyl) Sodium Sulfosuccinate 577-11-7 10 - 30 

The balance of the substances in this product are not classified as hazardous or 

are present below hazard cut-off limits 


EYE CONTACT : 

Get medical attention. Immediately flush eye with water for at least 15 minutes while holding eyelids open. 

SKIN CONTACT : 

Immediately wash with plenty of soap and water. If symptoms develop, seek medical advice. 

INGESTION : 

Get medical attention. Do not induce vomiting: contains petroleum distillates and/or aromatic solvents. If 

conscious, washout mouth and give water to drink. 

Nalco Australia Pty Ltd 2 Anderson Street • Botany N.S.W. 2019, Australia 

TEL: +61 2 9316 3000 FAX: +61 2 9666 5292 

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96


PRODUCT 




INHALATION : 

Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice. 

NOTE TO PHYSICIAN : 

Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms 

and clinical condition. 

5. FIRE FIGHTING MEASURES 

FLASH POINT : 83 °C PMCC 

EXTINGUISHING MEDIA : 

Foam, Carbon dioxide, Dry powder, Other extinguishing agent suitable for Class B fires, For large fires, use water 

spray or fog, thoroughly drenching the burning material. 

Water mist may be used to cool closed containers. 

UNSUITABLE EXTINGUISHING MEDIA : 

Do not use water unless flooding amounts are available. 

FIRE AND EXPLOSION HAZARD : 

Combustible Liquid; may form combustible mixtures at or above the flash point. Empty product containers may 

contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of 

ignition. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of sulfur (SOx) under fire 

conditions. 

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING : 

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit. 

SENSITIVITY TO STATIC DISCHARGE : 

Vapors in the flammable range may be ignited by a static discharge. 


PERSONAL PRECAUTIONS : 

Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment 

recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so. 

Ventilate spill area if possible. Remove sources of ignition. Notify appropriate government, occupational health 

and safety and environmental authorities. 

METHODS FOR CLEANING UP : 

SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled 

container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or 

by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaces 

with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated recovered 

material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). 

ENVIRONMENTAL PRECAUTIONS : 

Prevent material from entering sewers or waterways. 


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PRODUCT 




HANDLING : 

Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Do not breathe 

vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, 

leaks, etc.) readily available. Ensure all containers are labeled. Do not use, store, spill or pour near heat, sparks or 

open flame. 

STORAGE CONDITIONS : 

Store separately from oxidizers. Store the containers tightly closed. Store away from heat and sources of ignition. 

Have appropriate fire extinguishers available in and near the storage area. Connections must be grounded to 

avoid electrical charges. 

SUITABLE CONSTRUCTION MATERIAL : 

Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use., 

Stainless Steel 304, Stainless Steel 316L, Aluminum, Hastelloy C-276, MDPE (medium density polyethylene), 

HDPE (high density polyethylene), PVC, Plexiglass, Teflon, Kalrez, Perfluoroelastomer, PTFE, TFE, FEP 

(encapsulated) 

UNSUITABLE CONSTRUCTION MATERIAL : 

Mild steel, Carbon steel, Buna-N, Brass, Copper, Natural rubber, Polyethylene, Polypropylene, Ethylene 

propylene, EPDM, Neoprene, Nitrile, Polyurethane, Viton, Alfax, Hypalon 

8. EXPOSURE CONTROLS/PERSONAL PROTECTION 

OCCUPATIONAL EXPOSURE LIMITS 

This product does not contain any substance that has an established exposure limit. 

ENGINEERING MEASURES : 

General ventilation is recommended. The use of local exhaust ventilation is recommended to control emissions 

near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of 

confined spaces. 

PERSONAL PROTECTION 

GENERAL ADVICE : 

The use and choice of personal protection equipment is related to the hazard of the product, the workplace and the 

way the product is handled. In general, we recommend as a minimum precaution that safety glasses with 

side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area 

where this product is handled should at least wear safety glasses with side-shields. 

RESPIRATORY PROTECTION : 

Respiratory protection is not normally needed. If significant mists, vapors or aerosols are generated an approved 

respirator is recommended. An organic vapor cartridge with dust/mist prefilter or supplied air may be used. If 

respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, 

training, maintenance and inspection. 


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98

HAND PROTECTION : 

Nitrile gloves PVC gloves 

SKIN PROTECTION : 

Wear standard protective clothing. 

EYE PROTECTION : 

Wear safety glasses with side-shields. 


PRODUCT 




HYGIENE RECOMMENDATIONS : 

Use good work and personal hygiene practices to avoid exposure. Consider the provision in the work area of a 

safety shower and eyewash. Always wash thoroughly after handling chemicals. When handling this product never 

eat, drink or smoke. 


PHYSICAL STATE Liquid 

APPEARANCE Clear Light Amber 

ODOR Hydrocarbon 

pH (100 %) 6.2 

VAPOR PRESSURE 2.06 kPa (37.8 °C) 

VAPOR DENSITY No data available. 

SPECIFIC GRAVITY 0.95 (15.6 °C) 

DENSITY No data available. 

SOLUBILITY IN WATER Complete 

VISCOSITY 177 cst (0 °C) 

VISCOSITY 70 cst (15.6 °C) 

VISCOSITY 22.5 cst (40 °C) 

POUR POINT < -57.1 °C 

BOILING POINT 146.7 °C 

FLASH POINT 83 °C PMCC 

LOWER EXPLOSION LIMIT No data available. 

UPPER EXPLOSION LIMIT No data available. 

AUTOIGNITION TEMPERATURE No data available. 

Note: These physical properties are typical values for this product and are subject to change. 


STABILITY : 

Stable under normal conditions. 

CONDITIONS TO AVOID : 

Heat and sources of ignition including static discharges. 

INCOMPATIBLE MATERIALS : 

Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, 

permanganate) may generate heat, fires, explosions and/or toxic vapors. 

HAZARDOUS DECOMPOSITION PRODUCTS : 

Under fire conditions: Oxides of carbon, Oxides of sulfur 


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99

HAZARDOUS REACTIONS : 

Hazardous polymerization will not occur. 


OVERVIEW OF HEALTH HAZARDS 

ACUTE HAZARDS - EYE CONTACT 

Can cause mild irritation. 

ACUTE HAZARDS - SKIN CONTACT 

May cause irritation with prolonged contact. 


PRODUCT 




ACUTE HAZARDS - INGESTION 

Not a likely route of exposure. May cause nausea and vomiting. Can cause chemical pneumonia if aspirated into 

lungs following ingestion. 

ACUTE HAZARDS - INHALATION 

Repeated or prolonged exposure may irritate the respiratory tract. 

CHRONIC HAZARDS : 

Repeated or prolonged exposure may cause skin irritation and rash (dermatitis). 

SUMMARY OF TOXICITY INFORMATION 

ACUTE TOXICITY DATA : 

No toxicity studies have been conducted on this product. 

SENSITIZATION : 

This product is not expected to be a sensitizer. 

CARCINOGENICITY : 

None of the substances in this product are listed as carcinogens by the International Agency for Research on 

Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial 

Hygienists (ACGIH). 

For additional information on the hazard of the preparation, please consult section 2 and 12. 

HUMAN HAZARD CHARACTERIZATION 

Based on our hazard characterization, the potential human hazard is: Low 


ECOTOXICOLOGICAL EFFECTS : 

The following results are for the product. 


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100


PRODUCT 




ACUTE INVERTEBRATE RESULTS : 

Species Exposure LC50 EC50 Test Descriptor 

Acartia tonsa 48 hrs 34 mg/l Product 

Artemia 48 hrs 20.7 mg/l Product 

MOBILITY AND BIOACCUMULATION POTENTIAL : 

The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program 

interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input 

and output. The level III model does not require equilibrium between the defined media. The information provided 

is intended to give the user a general estimate of the environmental fate of this product under the defined 

conditions of the models. 

If released into the environment this material is expected to distribute to the air, water and soil/sediment in the 

approximate respective percentages; 

Air Water Soil/Sediment 


PRODUCT 




TRANSPORTATION 

AIR TRANSPORT (ICAO/IATA) 

Proper Shipping Name : PRODUCT IS NOT REGULATED DURING 


MARINE TRANSPORT (IMDG/IMO) 

Proper Shipping Name : PRODUCT IS NOT REGULATED DURING 


15. REGULATORY INFORMATION 

AUSTRALIA : 

NICNAS 

All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme 

(NICNAS). 

SUSDP SCHEDULE : Not Listed 

INTERNATIONAL CHEMICAL CONTROL LAWS 

UNITED STATES : 

The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) 

CANADA : 

The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL). 

EUROPE 

The substance(s) in this preparation are included in or exempted from the EINECS or ELINCS inventories 

JAPAN 

All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical 

Substances and are listed on the Ministry of International Trade & industry List (MITI). 

CHINA 

All substances in this product comply with the Chemical Control Law and are listed on the Inventory of Existing 

Chemical Substances China (IECSC). 

KOREA 

All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing 

Chemicals List (ECL) 

PHILIPPINES 

All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines 

Inventory of Chemicals & Chemical Substances (PICCS). 



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PRODUCT 




This product material safety data sheet provides health and safety information. The product is to be used in 

applications consistent with our product literature. Individuals handling this product should be informed of the 

recommended safety precautions and should have access to this information. For any other uses, exposures 

should be evaluated so that appropriate handling practices and training programs can be established to insure 

safe workplace operations. Please consult your local sales representative for any further information. 

REFERENCES 

Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American 

Conference of Governmental Industrial Hygienists, OH., (Ariel Insight CD-ROM Version), Ariel Research Corp., 

Bethesda, MD. 

Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS CD-ROM 

Version), Micromedex, Inc., Englewood, CO. 

IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health 

Organization, International Agency for Research on Cancer. 

Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS 

CD-ROM Version), Micromedex, Inc., Englewood, CO. 

Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, 

Public Health Service. 

Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational 

Safety and Health Administration (OSHA), (Ariel Insight CD-ROM Version), Ariel Research Corp., Bethesda, MD. 

Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, 

Cincinnati, OH, (TOMES CPS CD-ROM Version), Micromedex, Inc., Englewood, CO. 

Ariel Insight (An integrated guide to industrial chemicals covered under major regulatory and advisory programs), 

North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel 

Insight CD-ROM Version), Ariel Research Corp., Bethesda, MD. 

The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS CD-ROM Version), 

Micromedex, Inc., Englewood, CO. 

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a 

bar in the left-hand margin of the MSDS. 

Prepared By: Nalco Asia Pacific, Safety, Health and Environment (SHE) Specialist, (02) 9316 3162 


TEL: +61 2 9316 3000 FAX: +61 2 9666 5292 

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103


PRODUCT 

COREXIT(R) EC9527A 

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

PRODUCT NAME : COREXIT(R) EC9527A 

COMPANY IDENTIFICATION : Nalco Australia Pty Ltd 

2 Anderson Street 

Botany N.S.W. 2019 

Australia 

A.B.N. 41 000 424 788 

TEL: +61 2 9316 3000 

FAX: +61 2 9666 5292 



EMERGENCY TELEPHONE NUMBER(S) : +800 2537 8747 (free call) or +65 6542 9595 (Singapore) 

Date issued : 16.10.2008 

Version Number : 1.3 


HAZARD CLASSIFICATION : HARMFUL, IRRITANT 

Hazardous according to the criteria of the National Occupational Health and Safety Commission (NOHSC). This 

product is classified as a combustible liquid according to the Australian Dangerous Goods Code when transported 

in bulk by road or rail. 

RISK PHRASES 

R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. 

R36/38 - Irritating to eyes and skin. 


S23 - Do not breathe .. (gas/fumes/vapor/spray). 

S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 

S28 - After contact with skin, wash immediately with plenty of water. 

S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. 

S46 - If swallowed, seek medical advice immediately and show this container or label. 

3. COMPOSITION/INFORMATION ON INGREDIENTS 

CHEMICAL NAME CAS NO % (w/w) 

2-Butoxyethanol 111-76-2 30 - 60 

Di(2-Ethylhexyl) Sodium Sulfosuccinate 577-11-7 10 - 30 

The balance of the substances in this product are not classified as hazardous or 

are present below hazard cut-off limits 


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104



PRODUCT 




EYE CONTACT : 

Immediately flush eye with water for at least 15 minutes while holding eyelids open. If symptoms develop, seek 

medical advice. 

SKIN CONTACT : 

Remove contaminated clothing. Wash off affected area immediately with plenty of water. Get medical attention. 

INGESTION : 

Do not induce vomiting without medical advice. If conscious, washout mouth and give water to drink. If reflexive 

vomiting occurs, rinse mouth and repeat administration of water. Get medical attention. For advice, contact the 

Poisons Information Centre (eg Australia 13 1126; New Zealand 0800 764 766) or a doctor at once. 

INHALATION : 

Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice. 

NOTE TO PHYSICIAN : 

Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms 

and clinical condition. 

5. FIRE FIGHTING MEASURES 

FLASH POINT : 72.7 °C TCC 

EXTINGUISHING MEDIA : 

Foam, Carbon dioxide, Dry powder, Other extinguishing agent suitable for Class B fires, For large fires, use water 

spray or fog, thoroughly drenching the burning material. 

Water mist may be used to cool closed containers. 

FIRE AND EXPLOSION HAZARD : 

Combustible Liquid; may form combustible mixtures at or above the flash point. Empty product containers may 

contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of 

ignition. May evolve oxides of carbon (COx) under fire conditions. 

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING : 

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit. 

SENSITIVITY TO STATIC DISCHARGE : 

Vapors in the flammable range may be ignited by a static discharge. 


PERSONAL PRECAUTIONS : 

Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment 

recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so. 

Ventilate spill area if possible. Remove sources of ignition. Ensure clean-up is conducted by trained personnel 

only. Do not touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available. 

Notify appropriate government, occupational health and safety and environmental authorities. 


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105


PRODUCT 




METHODS FOR CLEANING UP : 

SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled 

container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or 

by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaces 

with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated recovered 

material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). 

ENVIRONMENTAL PRECAUTIONS : 

Harmful to aquatic organisms., Do not contaminate surface water. 


HANDLING : 

Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Avoid generating 

aerosols and mists. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, 

leaks, etc.) readily available. Ensure all containers are labeled. Do not use, store, spill or pour near heat, sparks or 

open flame. 

STORAGE CONDITIONS : 

Store in suitable labeled containers. Store the containers tightly closed. Store away from heat and sources of 

ignition. Have appropriate fire extinguishers available in and near the storage area. Connections must be 

grounded to avoid electrical charges. 

SUITABLE CONSTRUCTION MATERIAL : 

Stainless Steel 316L, Hastelloy C-276, MDPE (medium density polyethylene), Nitrile, Plexiglass, Kalrez, TFE, 

Alfax, Teflon, HDPE (high density polyethylene), Neoprene, Aluminum, Polypropylene, Polyethylene, Carbon 

Steel C1018, Stainless Steel 304, Compatibility with Plastic Materials can vary; we therefore recommend that 

compatibility is tested prior to use., FEP (encapsulated), Perfluoroelastomer, PVC 

UNSUITABLE CONSTRUCTION MATERIAL : 

Copper, Mild steel, Brass, Nylon, Buna-N, Natural rubber, Polyurethane, Hypalon, Viton, Ethylene propylene, 

EPDM 

8. EXPOSURE CONTROLS/PERSONAL PROTECTION 

OCCUPATIONAL EXPOSURE LIMITS 

The following component(s) have been assigned an exposure standard by NOHSC (Australia) and/or other 

Agencies: 

Country/Source Substance(s) Category: ppm mg/m3 

AUSTRALIA 2-Butoxyethanol TWA 20 96.9 

STEL 50 242 

Skin* 

USA 2-Butoxyethanol ACGIH/TWA 20 

OSHA Z1/PEL 50 240 

OSHA Z1/Skin* 


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106


PRODUCT 




* A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route, including 

mucous membranes and the eyes. 

MONITORING MEASURES : 

A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be desorbed 

or removed and analyzed as referenced below: 

Substance(s) Method Analysis Absorbant 

2-Butoxyethanol US NIOSH: 1403 Gas chromatography Charcoal 

BIOLOGICAL EXPOSURE INDICES : 

2-Butoxyethanol A biological index of exposure to 

2-butoxyethanol (CAS 111-76-2) is the 

detection of butoxyacetic acid in the urine at 

the end of the work shift (UK, 240mmol/mol 

creatinine) or at the end of the last shift of the 

working week (Germany, 100mg/l). 

ENGINEERING MEASURES : 

General ventilation is recommended. The use of local exhaust ventilation is recommended to control emissions 

near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of 

confined spaces. 

PERSONAL PROTECTION 

GENERAL ADVICE : 

The use and choice of personal protection equipment is related to the hazard of the product, the workplace and the 

way the product is handled. In general, we recommend as a minimum precaution that safety glasses with 

side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area 

where this product is handled should at least wear safety glasses with side-shields. 

RESPIRATORY PROTECTION : 

Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air 

supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of 

chemicals being handled. Consider the use of filter type: Multi-contaminant cartridge. with a Particulate pre-filter. 

In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA 

should be used. If respiratory protection is required, institute a complete respiratory protection program including 

selection, fit testing, training, maintenance and inspection. 

HAND PROTECTION : 

PVC gloves Neoprene gloves Nitrile gloves Butyl gloves 

SKIN PROTECTION : 

Wear impervious apron and boots. 

EYE PROTECTION : 

Wear chemical splash goggles. 

HYGIENE RECOMMENDATIONS : 

Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a 

safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. 


TEL: +61 2 9316 3000 FAX: +61 2 9666 5292 

4 / 9 

107


PRODUCT 




Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling 

this product never eat, drink or smoke. 


PHYSICAL STATE Liquid 

APPEARANCE Amber 

ODOR Mild 

pH (100 %) 6.1 

VAPOR PRESSURE No data available. 

EVAPORATION RATE 0.1 

VAPOR DENSITY No data available. 

SPECIFIC GRAVITY 0.98 - 1.02 

DENSITY No data available. 

SOLUBILITY IN WATER Complete 

VISCOSITY 160 cst (0 °C) 

POUR POINT ASTM D-97 -55 °C 

POUR POINT < -40 °C 

BOILING POINT 171 °C 

FLASH POINT 72.7 °C TCC 

LOWER EXPLOSION LIMIT No data available. 

UPPER EXPLOSION LIMIT No data available. 

AUTOIGNITION TEMPERATURE No data available. 

Note: These physical properties are typical values for this product and are subject to change. 


STABILITY : 

Stable under normal conditions. 

CONDITIONS TO AVOID : 

Heat and sources of ignition including static discharges. 

INCOMPATIBLE MATERIALS : 

Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, 

permanganate) may generate heat, fires, explosions and/or toxic vapors. 

HAZARDOUS DECOMPOSITION PRODUCTS : 

Under fire conditions: Oxides of carbon 

HAZARDOUS REACTIONS : 

Hazardous polymerization will not occur. 


OVERVIEW OF HEALTH HAZARDS 

ACUTE HAZARDS - EYE CONTACT 

Can cause moderate irritation. 


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108

ACUTE HAZARDS - SKIN CONTACT 

Can cause moderate irritation. Harmful if absorbed through skin. 


PRODUCT 




ACUTE HAZARDS - INGESTION 

May be harmful if swallowed. May cause liver and kidney effects and/or damage. There may be irritation to the 

gastro-intestinal tract. 

ACUTE HAZARDS - INHALATION 

Harmful by inhalation. Repeated or prolonged exposure may irritate the respiratory tract. 

CHRONIC HAZARDS : 

Contains ethylene glycol monobutyl ether (butoxyethanol). Prolonged and/or repeated exposure through 

inhalation or extensive skin contact with EGBE may result in damage to the blood and kidneys. 

SUMMARY OF TOXICITY INFORMATION 

ACUTE TOXICITY DATA : 


SENSITIZATION : 

This product is not expected to be a sensitizer. 

CARCINOGENICITY : 

None of the substances in this product are listed as carcinogens by the International Agency for Research on 

Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial 

Hygienists (ACGIH). 

For additional information on the hazard of the preparation, please consult section 2 and 12. 

HUMAN HAZARD CHARACTERIZATION 

Based on our hazard characterization, the potential human hazard is: Moderate 


ECOTOXICOLOGICAL EFFECTS : 


MOBILITY AND BIOACCUMULATION POTENTIAL : 

The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program 

interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input 

and output. The level III model does not require equilibrium between the defined media. The information provided 

is intended to give the user a general estimate of the environmental fate of this product under the defined 

conditions of the models. 

If released into the environment this material is expected to distribute to the air, water and soil/sediment in the 

approximate respective percentages; 

Air Water Soil/Sediment 


TEL: +61 2 9316 3000 FAX: +61 2 9666 5292 

6 / 9 

109


PRODUCT 


SUSDP SCHEDULE : S6 

INTERNATIONAL CHEMICAL CONTROL LAWS 


PRODUCT 




UNITED STATES : 

The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) 

CANADA : 

The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been 

reported in accordance with the New Substances Notification Regulations. 

EUROPE 

The substance(s) in this preparation are included in or exempted from the EINECS or ELINCS inventories 

JAPAN 

All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical 

Substances and are listed on the Ministry of International Trade & industry List (MITI). 

CHINA 

All substances in this product comply with the Chemical Control Law and are listed on the Inventory of Existing 

Chemical Substances China (IECSC). 

KOREA 

All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing 

Chemicals List (ECL) 

PHILIPPINES 

All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines 

Inventory of Chemicals & Chemical Substances (PICCS). 


This product material safety data sheet provides health and safety information. The product is to be used in 

applications consistent with our product literature. Individuals handling this product should be informed of the 

recommended safety precautions and should have access to this information. For any other uses, exposures 

should be evaluated so that appropriate handling practices and training programs can be established to insure 

safe workplace operations. Please consult your local sales representative for any further information. 

REFERENCES 

Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American 

Conference of Governmental Industrial Hygienists, OH., (Ariel Insight CD-ROM Version), Ariel Research Corp., 

Bethesda, MD. 

Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS CD-ROM 

Version), Micromedex, Inc., Englewood, CO. 


TEL: +61 2 9316 3000 FAX: +61 2 9666 5292 

8 / 9 

111


PRODUCT 




IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health 

Organization, International Agency for Research on Cancer. 

Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS 

CD-ROM Version), Micromedex, Inc., Englewood, CO. 

Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, 

Public Health Service. 

Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational 

Safety and Health Administration (OSHA), (Ariel Insight CD-ROM Version), Ariel Research Corp., Bethesda, MD. 

Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, 

Cincinnati, OH, (TOMES CPS CD-ROM Version), Micromedex, Inc., Englewood, CO. 

Ariel Insight (An integrated guide to industrial chemicals covered under major regulatory and advisory programs), 

North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel 

Insight CD-ROM Version), Ariel Research Corp., Bethesda, MD. 

The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS CD-ROM Version), 

Micromedex, Inc., Englewood, CO. 

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a 

bar in the left-hand margin of the MSDS. 

Prepared By: Nalco Asia Pacific, Safety, Health and Environment (SHE) Specialist, (02) 9316 3162 


TEL: +61 2 9316 3000 FAX: +61 2 9666 5292 

9 / 9 

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�

SAFETY�DATA�SHEET� 

Section�1:�Chemical�Product�and�Company�Identification� 

Product�Name� Tergo�2�005� Contact�Details:� � 

Synonyms� Oil�Spill�dispersant�Type�III� Supplier� Tergo�Industries�Ltd� 

� � Address� 664�Rosebank�Rd,�Avondale� 

Recommended�Use� Dispersant�for�emergency�� Auckland�� 

� response�to�oil�spill� � New�Zealand� 

Date�of�Preparation� 21�April�2009� Telephone�No.� +64�9�820�3888� 

� � Emergency�No.� NZ�0800�POISON�(0800�764�766)� 

� � � AUS��131126�� 

� � � � 

� � � � 

Section�2:�Hazard�Identification� 

Hazard�Classification� 3.1D,��6.4A� 

� � � � 

Hazards�Statements� Warning:� 

Combustible�Liquid� 

Causes�eye�irritation.� 

� � � � 

Precautionary�Statements� Keep�away�from�heat/sparks/open�flame.� 

Wear�eye/face�protection� 

Store�in�well�ventilated�place� 

If�in�eyes�rinse�cautiously�with�water�for�several�minutes.�Remove�contact�lense�if� 

present�and�easy�to�do�so.�Continue�rinsing.� 

Wash�hands�after�handling.� 

� 

� 

� 

Section�3:�Composition/Information�On�Ingredients� 

Chemical� C.A.S�No.� Proportion�(low

� Inhalation� High�concentrations�may�cause�irritation�to�eyes�and�throat.� 

� � 

Workplace�Facilities� � Provide�safety�goggles� 

� � 

Treatment� Ingestion� Do�not�induce�vomiting.�Rinse�mouth�with�water.�Obtain�medical� 

attention.� 

� Eyes� If�in�eyes�rinse�cautiously�with�water�for�several�minutes.�Remove�contact� 

lense�if�present�and�easy�to�do�so.�Continue�rinsing.� 

� Skin� Remove�contaminated�clothing.�Flush�affected�area�with�running�water� 

Launder�contaminated�clothing�before�re�use.� 

� Inhalation� Remove�to�fresh�air.� 

Notes�For�Medical� 

Personnel� 

� 

� 

� Treat�symptomatically.�If�aspirated�into�the�lungs�during�ingestion,� 

or�from�vomiting,�chemical�pneumonitis�or�pulmonary� 

oedema�may�occur.� 

Section�5:�Fire�Fighting�Measures� 

Hazards� Flammable�after�moderate�preheating�and�therefore�will�support�combustion�under�extreme� 

conditions�of�a�fire.� 

Extinguishing�Media� Foam,�dry�chemical�powder,�Carbon�dioxide,�water�spray�or�fog�(large�fires�only)� 

Protective�Gear� Fire�fighters�must�use�recommended�protective�equipment�and�self�contained�breathing� 

apparatus.�Hazchem�Code�3[Y]�� 

� 

Section�6:�Accidental�Release�Measures� 

Small�Spills� Shut�off��ignition�sources.�Absorb�spill�with�inert��material�and�place�in�container�for�removal�by� 

approved�waste�management�facility.� 

Large�Spills� �Remove�all�ignition�sources.�Wear�protective�gloves�and�safety�glasses.��Increase�ventilation.� 

Contain�spill�with�sand,�earth�or�vermiculite.�Collect�recoverable�product�into�labelled�containers� 

for�removal�by�approved�waste�management�facility.� 

� 

Section�7:�Handling�and�Storage� 

Handling� � Use�good�occupational�work�practice.�Wear�recommended�Personal�Protective�Equipment� 

(PPE)�and�observe�precautions�in�section�two�of�this�safety�data�sheet.� 

Storage� Site� Store�away�from�heat�and�open�flames.�Store�at�ambient�temperatures.�Keep�containers� 

tightly�closed�and�in�a�well�ventilated�place.�� 

� Packaging� Where�possible�keep�in�manufacturer’s�original�container.�If�container�deteriorates�or� 

decanting�to�smaller�quantities�the�new�packaging�should�be�sturdy�polyethylene� 

/polypropylene� 

� 

Section�8:�Exposure�Controls/Personal�Protection� 

Workplace�Exposure�Standards� No�value�assigned�by�NZ�OSH�but�2000�mg/m 3�� TWA�recommended�based�on� 

generic�equivalents� 

Engineering�Controls� In�general,�dilution�ventilation�is�a�satisfactory�health�hazard�control�for�this� 

substance.� 

Personal�Protective�Equipment� No�special�equipment�needed�when�handling�small�quantities.�In�an�industrial� 

environment�with�large�quantities�involved,�safety�glasses,�PVC�gloves�and� 

Document�Control� File�Name:� Tergo�2�005_SDS.doc� Issue�Date 01/07/2009 Author: .TD� Formula�#:� 1 Page�2of�4 

� 

121

� 

� 

safety�footwear�are�recommended.� 

Section�9:�Physical�and�Chemical�Properties� 

Appearance:� Clear�to�slightly�hazy,�amber�liquid�with�characteristic��hydrocarbon� 

odour.� 

Boiling�Point�(°C):� 296� 

Vapour�Pressure�(kPa�@�20°C)� 200� 

Water�Solubility� Miscible� 

Plus�other�properties�if�applicable� � 

� 

Section�10:�Stability�and�Reactivity� 

Stability� Considered�stable�under�normal�conditions� 

Conditions/Materials�to�Avoid� Sources�of�heat�and�ignition,�open�flames.�Strong�oxidizing�substances.� 

Hazardous�Decomposition�Products� Thermal�decomposition�will�produce�Carbon�Dioxide,�and�Monoxide�and� 

oxides�of�sulphur� 

Hazardous�Polymerisation� Will�not�occur� 

� 

Section�11:�Toxicological�Information� 

Minimal�toxicity�and�irritation�potential.� 

CAUTION:�these�values�represent�established�data�on�individual�components�of�the�product�and�must�be�interpreted� 

in�conjunction�with�the�proportion�of�that�component�in�the�product.� 

� 

Component� %�by��wt� Value� End�Point� Route� Species� 

Hydrotreated�light�distillate� 10�60� 15000mg/kg� LD50� Oral� rat� 

� � � � � � 

� � � � � � 

Carcinogenicity� OSHA:�NO��IARC:�NO��NTP:�NO� 

� 

� 

� 

Section�12:�Ecological�Information� 

Species� Exposure�(hours)� End�Point� Value� 

Rock�oyster� 48� EC50� 15� 

Tiger�Prawn� 96� EC50� 15� 

Mysid�Shrimp� 96� LC50� >80� 

Sea�Urchin� 72� EC50� 15.96� 

Section�13:�Disposal�Consideration� 

Dispose�in�accordance�with�all�applicable�local�regulations.�Contact�a�licensed�waste�disposal�facility��to�assure� 

compliance� 

� 


� 

122

Section�14:�Transport�Information� 

Land�(NZS�5433� Proper�Shipping�Name� Nil� 

and�ADG)� Class� Nil� 

� UN�No.� Nil� 

� Packing�Group� n/a� 

� Hazchem�Code� n/a� 

Sea�(IMDG/IMO)� Proper�Shipping�Name� Nil� 

� Class� Nil� 




Air�(IATA)� Proper�Shipping�Name� Nil� 

� Class� Nil� 




� 

Section�15:�Regulatory�Information� 

HSNO�Approval�Code� � HSR002490� 

HSNO�Classifications� � 3.1D,6.4A� 

� � � 

HSNO�Controls� Trigger�Quantity� 

Approved�Handler� Not�required� 

Site�location�Certification� Not�Required� 

Hazardous�Atmosphere�Zone� Not�required� 

Signage�Required� 10,000L� 

Emergency�Plan�&�Secondary�Containment� 10,000L� 

Fire�Extinguishers� 500L� 

� 

� 

� 

� 

Section�16:�Other�Information� 


� 

123

Slickgone NS - Australian Maritime Safety Authority

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