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Temperature (1) - Oxford University Press

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102<br />

THERMAL T<br />

EFFECTS<br />

ice<br />

point<br />

0 °C<br />

pure<br />

melting<br />

ice<br />

5.03<br />

� Finding the lower fixed point<br />

steam<br />

point<br />

100 °C<br />

boiling<br />

water<br />

� Finding the upper fixed point<br />

<strong>Temperature</strong> (2)<br />

Fixing a temperature scale<br />

To create a temperature scale, two standard temperatures must be chosen<br />

against which others can be judged. These fixed points need to be defined so<br />

that they can be reproduced in laboratories anywhere in the world:<br />

On the Celsius scale:<br />

0 degrees Celsius (0 �C) is defined as the melting point of pure ice. This is<br />

the lower fixed point, known as the ice point.<br />

100 degrees Celsius (100 �C) is defined as the boiling point of pure water,<br />

where the water is boiling under standard atmospheric pressure (101 325 Pa).<br />

This is the upper fixed point, known as the steam point.<br />

Putting a scale on an instrument, so that it gives accurate readings, is called<br />

calibrating the instrument. The diagrams on the left show how the fixed<br />

points can be used to calibrate an unmarked thermometer.<br />

To find the 0 �C point, the unmarked thermometer is placed in pure, melting<br />

ice, as in the upper diagram on the left. The ice needs to be pure because its<br />

melting point is lowered if any impurities are present.<br />

To find the 100 �C point, the thermometer is placed in steam above boiling<br />

water, as in the lower diagram on the left. Boiling must take place under<br />

standard atmospheric pressure because a change in pressure alters the boiling<br />

point of the water. Impurities also affect the boiling point but, in most cases,<br />

they do not affect the temperature of the steam just above the water.<br />

ice<br />

point<br />

steam<br />

point<br />

0 °C if end of ’thread‘<br />

is half way between<br />

0 °C and 100 °C,<br />

temperature is 50 °C<br />

100 °C<br />

Once the 0 �C and 100 �C points have been fixed, the rest of the scale is made<br />

by dividing the distance between them into 100 equal divisions, or degrees<br />

(‘centigrade’ means ‘one hundred divisions’). The idea can can be extended<br />

to produce a scale going above 100 �C and below 0 �C, although for some<br />

thermometers, additional fixed points are used (see the top of the next page).<br />

Putting equal divisions on a thermometer defines the temperature scale for that<br />

particular type of thermometer. For example, if the end of the ‘thread’ is exactly<br />

half way between the ice points and the steam points, as in the diagram above,<br />

then by definition, the temperature is exactly half way between 0 �C and 100 �C.<br />

So the temperature is 50 �C. If a scale has equal divisions, it is described as a<br />

linear scale.

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