gas-phase photocatalytic oxidation of volatile organic ... - Doria

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Table 3.4.1 Arrhenius equation parameters for the PCO of VOCs on TiO2
MTBE TBA Ethanethiol MA DMA
Temperature range Temperature range Temperature range Temperature range Temperature range
(333 to 373 K) (333 to 373 K) (373 to 453 K) (353 to 413 K) (353 to 413 K)
Parameter
-38 ± 1 -15 ± 2 -45 ± 1 -14 ± 1 -42 ± 1
� H, kJ mol -1
1.5 ± 0.5 1.25 · 10 -4
0.003 ± 0.002 4.0 ± 0.5 2.2 x 10 -4
Aads, m 3 mol -1
27 ± 1 11 ± 2 42 ± 1 13 ± 1 42.1±1
E, kJ mol -1
3.0 ± 0.1 0.07 ± 0.01 272 ± 1 0.5 ± 0.5 0.35 · 10 4
Ar, mol m -3 s -1