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Weygand/Hilgetag Preparative Organic Chemistry

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Aldehyde nitrates, 423<br />

Aldehydes, addition of alcohols, 294<br />

—, addition of phosphines, 701<br />

—, addition of thiols, 609<br />

—, alkylation by, 952<br />

—, amino, reduction, 53<br />

—, aromatic, direct synthesis, 942<br />

—, —, from imidoyl chlorides, 68<br />

—, —, reduction of, 53<br />

—, autoxidation, 310<br />

— bisulfite compounds, 519, 610<br />

—, bromination, 187, 188<br />

-,bromo, 171, 187, 188, 189<br />

—, by dehydrogenation of alcohols, 321<br />

—, by oxidation of methyl groups, 311<br />

—, by oxidative cleavage of olefins, 1035,<br />

1036<br />

—, by telomerization, 850<br />

—, chlorination, 185<br />

—, 2-chloro, vinylic, 976<br />

—, conversion into a-halo ethers, 232<br />

—, decarbonylation, 1024<br />

—, dialkoxy, 362<br />

—, dimerization, 335<br />

—, from -l-acyl-2-(benzenesulfonyl)hydrazides,<br />

82<br />

—, from l-acyl-3,5-dimethylpyrazoles, 82<br />

—, from 1-acylimidazoles, 82<br />

—, from aldimines, 346, 347<br />

—, from aliphatic nitro compounds, 340<br />

— ,from amides, 82<br />

—, from amidines, 1012<br />

—, from amines, 347, 348<br />

—, from benzylidene halides, 159<br />

—, from carbonyl chlorides, 66<br />

—, from carboxylic esters, 79<br />

—, from gem-dihahdcs, 338<br />

—, from 2,4-dinitrophenylhydrazones, 349<br />

—, from formic esters, 881<br />

—, from glycide esters, 1019<br />

—, from lactones, 79<br />

—, from iV-methylanilides, 347<br />

—, from JV-methyl-carboxyanilides, 82<br />

—, from monohalides, 339<br />

—, from nitriles, 346<br />

—, from nitronic acids, 348<br />

—, from oximes, 349<br />

—, from a-oxo carboxylic acids, 1018<br />

—, from ozonides, 1039<br />

—, from Schiff bases, 348<br />

—, from semicarbazones, 349, 350<br />

—, gas-phase oxidation, 333<br />

—, Gattermann-Koch synthesis, 942<br />

—, heterocyclic, reduction of, 53<br />

-,hydroxy, 79, 33}<br />

—, reduction of, 45, 48, 52, 56<br />

—, a-oxo, 341<br />

-,^-oxo, 927<br />

—,y-oxo-, 959<br />

—,polyene, 988<br />

—, Reimer-Tiemann synthesis, 944<br />

Subject index 1133<br />

Aldehydes, replacement of CO by CX2, 252<br />

—, Sommelet synthesis, 339, 340, 347<br />

— ,a-sulfo, 612<br />

—, unsaturated, reduction of, 17<br />

-,

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