Organic Reactions, Volume 2

3-Hydroxy-4-nitro
2-Hydroxy-3-allyl
2-Methoxy-4-allyl
2-Methoxy-4-propyl
2-Methoxy-4-0y-hydroxypropyl)
2-Allyloxy-3-allyl
3-Allyloxy-4,6-diaUyl
2,3-MethyIenedioxy
2-Allyloxy-3-methoxy
2-AHyloxy-3-hydroxy (
2-Fonnyl
4-Formyl
4-Acetyl
2-AUyl-4-formyl
2-Carbethoxy
2-Carbomethoxy
0.8
—
4
—
—
—
—
—'
5
—
1 *
185
Distillation
in
vacuum
200
190-200
Distillation
in
vacuum
Distillation
in
vacuum
220-240
200
200
220-230
250-270
200-210
250-310
230
(Inert atmosphere)
(Inert atmosphere)
* References 104-129 appear on p. 48.
t The mixture contained the 6-allyl and 4-allyl derivatives in the ratio 5 : 4.
t For products with boron fluoride-acetic acid (103a)t see p. 25.
§ The product was not isolated from the reaction mixture, which contained other substances also.
|| The yield based on ether not recovered was 52%.
6-Allyl-3-hydroxy-4-nitro
3,6-Diallyl-2-hydroxy
4,6-Diallyl-2-methoxy
6-Allyl-2-methoxy-4-propyl
6-AUyl-2-methoxy-4-(7-hydroxypropyl)
3,5,6-Triallyl-2-nydroxy
2,4,6-Triallyl-3-allyloxy
Mixture of 6-allyl-2,3-methylenedioxy
(80%) and 4-allyl-2,3-methylenedioxy
(20%)
6-Allyl-2-formyl
2-Allyl-4-formyl
2-Allyl-4-acetyl
2,6-Diallyl-4-formyl
6-Allyl-2-carbethoxy
6-Allyl-2-carbomethoxy
26%l|
70%
>85%
79%
>85%
66%
78%