SPA No 31 juin 04

Unsuitable extinguishingmediaSpecific hazards arising fromthe chemicalSpecial protective equipmentand precautions for firefightersFire-fightingequipment/instructionsSpecific methods6. Accidental release measuresPersonal precautions,protective equipment andemergency proceduresMethods and materials forcontainment and cleaning upEnvironmental precautions7. Handling and storagePrecautions for safe handlingConditions for safe storage,including any incompatibilitiesDo not use a solid water stream as it may scatter and spread fire.Contents under pressure. Pressurized container may explode when exposed to heat or flame. Firemay produce irritating, corrosive and/or toxic gases.Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA. Firefighters should wear fullprotective clothing including self contained breathing apparatus. Structural firefighters protectiveclothing will only provide limited protection.In case of fire and/or explosion do not breathe fumes. Firefighters must use standard protectiveequipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and inenclosed spaces, SCBA. Move containers from fire area if you can do so without risk. Containersshould be cooled with water to prevent vapor pressure build up. For massive fire in cargo area,use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.Water runoff can cause environmental damage.In the event of fire and/or explosion do not breathe fumes. Self-contained breathing apparatusand full protective clothing must be worn in case of fire. Use standard firefighting procedures andconsider the hazards of other involved materials. Move container from fire area if it can be donewithout risk. Use water spray to cool unopened containers. Cool containers exposed to flameswith water until well after the fire is out.Immediately evacuate personnel to safe areas. Keep unnecessary personnel away. Localauthorities should be advised if significant spillages cannot be contained. Consider initialdownwind evacuation for at least 500 meters (1/3 mile). Wear appropriate protective equipmentand clothing during clean-up. Fully encapsulating, vapor protective clothing should be worn forspills and leaks with no fire. Do not touch damaged containers or spilled material unless wearingappropriate protective clothing. Do not touch or walk through spilled material. Keep people awayfrom and upwind of spill/leak. Keep upwind. Keep out of low areas. Pay attention to flashback.Ventilate closed spaces before entering them.ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keepcombustibles (wood, paper, oil, etc.) away from spilled material. The product is immiscible withwater and will spread on the water surface. Stop leak if you can do so without risk. Move thecylinder to a safe and open area if the leak is irreparable. Dike far ahead of spill for later disposal.Absorb spillage with non-combustible, absorbent material. Scoop up used absorbent into drumsor other appropriate container. Following product recovery, flush area with water. Prevent entryinto waterways, sewer, basements or confined areas.Avoid release to the environment. Contact local authorities in case of spillage to drain/aquaticenvironment. Prevent further leakage or spillage if safe to do so.Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Vapors may form explosive mixtures with air. Pressurized container: Do notpierce or burn, even after use. Do not spray on a naked flame or any other incandescent material.Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill,grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment usedwhen handling the product must be grounded. Ground and bond containers when transferringmaterial. Do not use if spray button is missing or defective. Do not re-use empty containers. Donot breathe dust/fume/gas/mist/vapors/spray. Do not taste or swallow. Avoid contact with skin.Avoid contact with eyes. Avoid contact during pregnancy/while nursing. Do not get this material onclothing. Wear personal protective equipment. Use only in well-ventilated areas. Avoid prolongedexposure. When using, do not eat, drink or smoke. Wash hands thoroughly after handling. Avoidrelease to the environment.Level 3 Aerosol.8. Exposure controls/personal protectionOccupational exposure limitsStore locked up. Contents under pressure. Pressurized container. Protect from sunlight and donot expose to temperatures exceeding 50°C/122 °F. Do not handle or store near an open flame,heat or other sources of ignition. Do not puncture, incinerate or crush. This material canaccumulate static charge which may cause spark and become an ignition source. Preventelectrostatic charge build-up by using common bonding and grounding techniques. Store in awell-ventilated place. Keep container tightly closed. Keep in an area equipped with sprinklers.Keep away from food, drink and animal feedingstuffs. Keep out of the reach of children.US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)ComponentsTypeN-hexane (CAS 110-54-3)Propane (CAS 74-98-6)PELPELValue1800 mg/m3500 ppm1800 mg/m3Material name: LPS® Food Grade Silicone626 Version #: 01 Issue date: 02-07-2013SDS US3 / 9