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Proiect nr.: 72‐172 / 01.10.2008<br />

Domeniul 7: Materiale, procese <strong>si</strong> produse <strong>in</strong>ovative<br />

Acronim: TIPSARMER<br />

TEHNICI DE INALTA PRECIZIE SI SENSIBILITATE<br />

APLICATE IN RETELE DE BIOMONITORIZARE A<br />

POLUARII MEDIULUI CU FACTORI POLUANTI DIN<br />

ZONELE DE DEZVOLTARE DE SUD, SUD-EST SI<br />

CENTRALA ALE ROMANIEI<br />

Coordonator:<br />

Univer<strong>si</strong>tatea Valahia d<strong>in</strong> Targoviste<br />

Director proiect:<br />

Prof. univ. dr. Ion V. POPESCU<br />

Coordonator sti<strong>in</strong>tific proiect:<br />

Conf.univ.dr.Claudia STIHI


Parteneri <strong>in</strong><br />

consortiu<br />

• P1: Univer<strong>si</strong>tatea “Dunarea <strong>de</strong> Jos”, Galati- UDJG;<br />

• P2: Institutul <strong>de</strong> Fizica <strong>si</strong> Ing<strong>in</strong>erie Nucleara – Horia Hulubei,, Magurele-<br />

IFIN-HH;<br />

• P3: Institutul National <strong>de</strong> Cercetare Dezvoltare pentru Ing<strong>in</strong>erie Electrica<br />

– Cercetari Avansate, Bucuresti- INCDIE-ICPE-CA;<br />

• P4: Univer<strong>si</strong>tatea Tran<strong>si</strong>lvania, Brasov- UTBV<br />

Buget<br />

Parteneri<br />

proiect<br />

Numele<br />

abreviat<br />

al<br />

organizatiei<br />

Tipul<br />

organizatiei<br />

Buget<br />

contractare<br />

<strong>in</strong>itiala<br />

2008 2009 2010 2011<br />

F<strong>in</strong>antare<br />

primita<br />

Buget<br />

contractare<br />

<strong>in</strong>itiala<br />

F<strong>in</strong>antare<br />

primita<br />

Buget<br />

contractare<br />

<strong>in</strong>itiala<br />

F<strong>in</strong>antare<br />

primita<br />

Buget<br />

contractare<br />

<strong>in</strong>itiala<br />

F<strong>in</strong>antare<br />

ramasa<br />

cf.<br />

contract<br />

<strong>in</strong>itial<br />

CO UVT UNI 68.065 0 320.427 109.720 781.508 256.270 130.000 934.010<br />

P1 UDJG UNI 15.707 0 73.945 25.320 18.0348 59.139 30.000 215.541<br />

P2 IFIN-HH INCD 10.472 0 49.296 16.881 120.232 39.426 20.000 143.693<br />

P3<br />

INCDIE INCD 5.236 0 24.648 8.440 60.116 19.713 10.000 71.847<br />

ICPE-CA<br />

P4 UTBV UNI 5.236 0 24.648 8.440 60.116 19.713 10.000 71.847<br />

Total proiect 104.716 0 492.964 168.801 1.202.320 394.261 200.000 1.436.938<br />

Total proiect contractare <strong>in</strong>itiala: 2.000.000<br />

Adresa WEB<br />

http://icstm.valahia.ro/tipsarmer


Obiectivele<br />

proiectului<br />

Proceduri/adaptare <strong>si</strong> implementare tehnici analitice <strong>de</strong> laborator /monitorizare<br />

mediu/mo<strong>de</strong>l experimental <strong>de</strong> biomonitorizare/cresterea vizibilitatii cercetarii <strong>in</strong>stitutiilor<br />

partenere <strong>in</strong> proiect<br />

1. Adaptarea, optimizarea <strong>si</strong> implementarea tehnicilor analitice <strong>de</strong> <strong><strong>in</strong>alta</strong> <strong>precizie</strong> <strong>si</strong><br />

sen<strong>si</strong>bilitate - atomice <strong>si</strong> nucleare, spectroscopice optice, electrochimice <strong>si</strong> fizico-chimice -<br />

pentru analiza probelor <strong>de</strong> mediu;<br />

2. Realizarea unui mo<strong>de</strong>l experimental <strong>de</strong> biomonitorizare a poluarii aerului, solului cu<br />

metale grele;<br />

3. Realizarea unor diagrame regionale <strong>de</strong> utilitate publica, cu <strong>in</strong>dici <strong>de</strong> poluare a mediului<br />

pr<strong>in</strong> metale grele;<br />

4. Disem<strong>in</strong>area pe scara larga a rezultatelor pr<strong>in</strong> comunicarea <strong>si</strong> publicarea nationala <strong>si</strong><br />

<strong>in</strong>ternationala a rezultatelor.<br />

Elemente <strong>de</strong><br />

noutate;<br />

orig<strong>in</strong>alitate<br />

A. Utilizarea <strong>in</strong> mod complementar a tehnicilor analitice <strong>de</strong> <strong><strong>in</strong>alta</strong><br />

sen<strong>si</strong>bilitate cu tehnica bio<strong>in</strong>dicatorilor;<br />

B. Realizarea diagramelor/hartilor <strong>de</strong> distributie a metalelor grele <strong>in</strong> zonele<br />

<strong>de</strong> sud, sud-est <strong>si</strong> centrale ale Romaniei<br />

Beneficiari/<br />

Potential <strong>de</strong><br />

aplicabilitate<br />

Potentiali beneficiari* :<br />

A. M<strong>in</strong>isterul Mediului <strong>si</strong> Padurilor‐ Agentiile regionale pentru protectia mediului – Galati,<br />

Targoviste;<br />

B. Firma specializate pentru <strong>in</strong>tocmirea studiilor <strong>de</strong> impact asupra mediului (EIM) <strong>si</strong> a<br />

bilanturilor <strong>de</strong> mediu (BM)‐ SC Rock‐Star Service SRL, Targoviste;<br />

*pe baza acordurilor <strong>de</strong> colaborare existente


STADIUL DE REALIZARE A PROIECTULUI<br />

(conform planului <strong>de</strong> realizare d<strong>in</strong><br />

Actul aditional 3/11.05.2010<br />

Etapa III<br />

16.12.2009-<br />

15.11.2010<br />

Titlul etapei:<br />

Studii experimentale pr<strong>in</strong> implementarea meto<strong>de</strong>lor fizico-chimice, optice,<br />

electrochimice <strong>si</strong> <strong>de</strong> spectroscopie atomica <strong>si</strong> nucleara <strong>de</strong> <strong><strong>in</strong>alta</strong> sen<strong>si</strong>bilitate a<br />

probelor <strong>de</strong> aerosol, apa, vegetatie, fauna acvatica, sol colectate d<strong>in</strong> zone <strong>de</strong> sud,<br />

sud-est <strong>si</strong> centrale ale Romaniei <strong>in</strong> ve<strong>de</strong>rea stabilirii gradului <strong>de</strong> poluare cu<br />

factori poluanti.<br />

72‐172 Buget <strong>de</strong> stat Cof<strong>in</strong>antare<br />

Buget Et. III/ 2010 394.261 lei*<br />

* la contractarea <strong>in</strong>itiala<br />

suma prevazuta a fost <strong>de</strong><br />

1.202.320<br />

‐<br />

Achizitii realizate conform actului aditional nr. 3/11.05.2010<br />

‐ au fost achizitionate: materiale consumabile pentru cercetare, reactivi , obiecte <strong>de</strong><br />

<strong>in</strong>ventar<br />

‐ nu au fost achizitionate echipamente pentru cercetare, mobilier


Etapa III<br />

STADIUL DE REALIZARE A PROIECTULUI<br />

(conform planului <strong>de</strong> realizare d<strong>in</strong><br />

Actul aditional 3/11.05.2010<br />

16.12.2009-<br />

15.11.2010<br />

Activitatea 3.1<br />

Activitati efectuate*<br />

Colectarea probelor <strong>de</strong> aerosol, apa, vegetatie, sol d<strong>in</strong> zonele monitorizate pr<strong>in</strong> program<br />

- au participat coordonatorul <strong>si</strong> toti partenerii implicati <strong>in</strong> proiect: Co, P1, P2, P3 <strong>si</strong> P4.<br />

Activitatea 3.2<br />

Masuratori PIXE, AAS, EDXRF, SEM-EDX <strong>si</strong> NAA ale probelor colectate pentru <strong>de</strong>term<strong>in</strong>area gradului <strong>de</strong><br />

poluare cu metale grele a probelor colectate<br />

-au participat coordonatorul - Co <strong>si</strong> partenerii : P1, P2 <strong>si</strong> P3.<br />

Activitatea 3.3.<br />

Masuratori electrochimice (biosenzori electrochimici) ale probelor, complementar cu masuratori<br />

spectrofotometrice <strong>de</strong> imagistica SEM<br />

- au participat partenerii P1<strong>si</strong> P4.<br />

Activitatea 3.4.<br />

Masuratori fizico-chimice (CL <strong>si</strong> FTIR) pentru <strong>de</strong>term<strong>in</strong>area gradului <strong>de</strong> poluare cu poluanti macromoleculari<br />

per<strong>si</strong>stenti<br />

- au participat coordonatorul- Co <strong>si</strong> partenerul P3<br />

Activitatea 3.5<br />

Prelucrarea datelor <strong>si</strong> analiza statistica a rezultatelor experimentale obt<strong>in</strong>ute<br />

- au participat coordonatorul - Co <strong>si</strong> partenerii : P1, P2, P3 <strong>si</strong> P4<br />

*Aceste activitati au fost realizate pr<strong>in</strong> contributia coordonatorului <strong>si</strong> a tuturor partenerilor d<strong>in</strong> proiect, <strong>in</strong> conformitate cu planul <strong>de</strong><br />

realizare al proiectului dupa actul aditional 3/11.05.2010 la contractul <strong>de</strong> f<strong>in</strong>antare pentru executie proiecte nr. 72-172/01.10.2008


2008‐2010<br />

STADIUL DE REALIZARE A PROIECTULUI<br />

(conform planului <strong>de</strong> realizare d<strong>in</strong><br />

Actul aditional 3/11.05.2010<br />

Rezultate obt<strong>in</strong>ute – pr<strong>in</strong> realizarea tuturor activitatilor d<strong>in</strong> etapele I, II <strong>si</strong> III<br />

•Pentru unele elemente concentratiile <strong>de</strong>term<strong>in</strong>ate <strong>in</strong> probele <strong>de</strong> apa potabila au <strong>de</strong>pa<strong>si</strong>t normele admise, la Turnu<br />

Magurele <strong>si</strong> Bucuresti; Ca, la Copsa Mica; Cr, la Turnu Magurele;<br />

•In cazul raului Ialomita se constata o <strong>de</strong>pa<strong>si</strong>re a concentratiei maxim admise a elementului Zn pe <strong>in</strong>treaga arie<br />

monitorizata;<br />

• Concentratiile <strong>de</strong>term<strong>in</strong>ate ale Fe au cla<strong>si</strong>ficat raul Ialomita d<strong>in</strong> aria monitorizata ca fi<strong>in</strong>d <strong>de</strong>:<br />

- categoria II (conform STAS 4706/88 ape ce pot fi utilizate în <strong>in</strong>dustrie, pentru piscicultură (exceptând<br />

salmoni<strong>de</strong>le), pentru agrement şi nevoi urbanistice) <strong>in</strong> zonele: Moroieni, Pietro<strong>si</strong>ta, Fieni, Pucioasa, Branesti<br />

-categoria III (conform STAS 4706/88 ape pot fi utilizate pentru irigaţii, alimentarea hidrocentralelor, răcirea<br />

agregatelor, alimentarea staţiilor <strong>de</strong> spălare) <strong>si</strong> chiar <strong>de</strong>pa<strong>si</strong>ri ale CMA <strong>si</strong> pentru aceasta categorie <strong>in</strong> zonele:<br />

Targoviste, Comisani, Bilciuresti, Dobra.<br />

•Studiul variatiei concentratiilor elementale <strong>in</strong> probele <strong>de</strong> sol analizate a evi<strong>de</strong>ntiat urmatoarele: valori<br />

maxime pentru Zn, As <strong>si</strong> Ca, la Copsa Mica, iar pentru Ni <strong>si</strong> Fe, la Deva; valori m<strong>in</strong>ime pentru Br, K <strong>si</strong> Rb la<br />

Copsa Mica, iar pentru As, Cr <strong>si</strong> Zr la Fundata.<br />

•Valoarea concentratiei <strong>de</strong> Zn <strong>in</strong> solul prelevat la Copsa Mica (sol necultivat), <strong>de</strong>paseste <strong>de</strong> 2 ori pragul <strong>de</strong> alerta<br />

maxima al standardului national <strong>in</strong> vigoare;<br />

•Pentru unele elemente valorile concentratiilor <strong>in</strong> sol <strong>de</strong>pasesc normele admise. Astfel, pentru Zn <strong>in</strong> sol la<br />

Magurele, pragul m<strong>in</strong>im <strong>de</strong> alerta este <strong>de</strong>pa<strong>si</strong>t <strong>de</strong> 2 ori, iar pentru Zn <strong>in</strong> sol la la Copsa Mica, pragurile m<strong>in</strong>im<br />

<strong>si</strong> maxim <strong>de</strong> alerta sunt <strong>de</strong>pa<strong>si</strong>te 4,7 <strong>si</strong> 2 ori, respectiv. Elementul Ni <strong>in</strong> proba <strong>de</strong> sol colectata la Deva<br />

<strong>de</strong>paseste pragul m<strong>in</strong>im <strong>de</strong> alerta, fi<strong>in</strong>d la nivelul acestei limite <strong>in</strong> proba <strong>de</strong> sol <strong>de</strong> la Magurele . Elementul Cr<br />

este apropiat <strong>de</strong> limita m<strong>in</strong>ima <strong>de</strong> alerta <strong>in</strong> probele <strong>de</strong> sol <strong>de</strong> la Afumati, Magurele, Galati <strong>si</strong> Deva. Elementul<br />

As este la nivelul limitei m<strong>in</strong>ime <strong>de</strong> alerta <strong>in</strong> probele <strong>de</strong> sol la Copsa Mica <strong>si</strong> Deva


2008‐2010<br />

STADIUL DE REALIZARE A PROIECTULUI<br />

(conform planului <strong>de</strong> realizare d<strong>in</strong><br />

Actul aditional 3/11.05.2010<br />

Rezultate obt<strong>in</strong>ute – pr<strong>in</strong> realizarea tuturor activitatilor d<strong>in</strong> etapele I, II <strong>si</strong> III<br />

•Concentratiile <strong>de</strong> As <strong>si</strong> Ni <strong>in</strong> sol sunt mai mari <strong>de</strong>cat valorile normale <strong>in</strong> toate probele analizate d<strong>in</strong> zonele<br />

d<strong>in</strong> jurul comb<strong>in</strong>atului <strong>si</strong><strong>de</strong>rurgic Galati, <strong>in</strong>clu<strong>si</strong>v <strong>in</strong> proba <strong>de</strong> control. Plumbul se afla peste valorile normale<br />

<strong>in</strong> proba colectata d<strong>in</strong> orasul Galati <strong>si</strong> Movileni. Zn a <strong>de</strong>pa<strong>si</strong>t valorile normale <strong>in</strong> Va<strong>de</strong>ni iar concentratiile <strong>de</strong><br />

Cu <strong>de</strong>pasesc valorile normale <strong>in</strong> toate punctele mai put<strong>in</strong> <strong>in</strong> comuna Adam;<br />

•valorile concentratiilor elementelor Cd, Cu, Se, Cr <strong>si</strong> Fe <strong>in</strong> solul speciilor <strong>de</strong> ciuperci - bio<strong>in</strong>dicatori, <strong>in</strong><br />

toate zonele <strong>de</strong> colectare, au <strong>de</strong>pa<strong>si</strong>t valorile pragului <strong>de</strong> <strong>in</strong>terventie. De asemenea s-a constatat o <strong>de</strong>pa<strong>si</strong>re<br />

a valorilor admise recomandate <strong>de</strong> EU pentru elementele Pb, Cd <strong>si</strong> Cr <strong>in</strong> anumite speciile <strong>de</strong> ciupercibio<strong>in</strong>dicatori<br />

•<strong>de</strong>şeurile polimerice studiate care prov<strong>in</strong> d<strong>in</strong> unităţile chimice <strong>de</strong> acoperiri <strong>de</strong> suprafaţă, pot per<strong>si</strong>sta un<br />

timp în<strong>de</strong>lungat, fără a se <strong>de</strong>scompune. Referitor la diferitele componente <strong>de</strong> mediu s-a constatat ca:<br />

sărurile accelerează <strong>de</strong>gradarea; mediul umed produce, <strong>de</strong> prepon<strong>de</strong>renţă funcţiuni hidroxil, ale căror<br />

structuri se regăsesc în mediu ca urmare a <strong>de</strong>gradării materialelor macromoleculare; lum<strong>in</strong>a solară este<br />

un factor distructiv major, ea <strong>in</strong>ducănd un proces <strong>de</strong> <strong>de</strong>gradare fotochimică cu consec<strong>in</strong>ţe directe asupra<br />

acumularilor <strong>de</strong> produ<strong>si</strong> <strong>de</strong> <strong>de</strong>scompunere şi a aditivilor toxici;<br />

•s-a putut remarca disponibilitatea materialelor polimerice <strong>de</strong> a se <strong>de</strong>grada pe cale oxidativă, viteza <strong>de</strong><br />

proces fi<strong>in</strong>d în funcţie <strong>de</strong> structura materialului, <strong>de</strong> <strong>in</strong>ten<strong>si</strong>tatea şi <strong>de</strong> durataacţiunii factorului energetic<br />

<strong>de</strong> <strong>de</strong>gradare (căldura sau radiaţiile ionizante) în prezenţa oxigenului, în diferite circumstanţe (aer sau<br />

apă).


Modul <strong>de</strong> implicare a t<strong>in</strong>erilor cercetatori<br />

Un doctorat f<strong>in</strong>alizat – 2009 :<br />

Etapa proiectului Nr. persoane sub 35<br />

ani<br />

Etapa I:<br />

8<br />

20.01.2009<br />

Etapa II:<br />

15.12.2009<br />

6<br />

Etapa III:<br />

6<br />

15.11.2010<br />

Anca Gheboianu (Co-UVT) – doctorand la Univer<strong>si</strong>tatea d<strong>in</strong> Bucuresti<br />

Titlul tezei:<br />

Meto<strong>de</strong> spectrometrice <strong>de</strong> analiza, atomice <strong>si</strong> nucleare, utilizate <strong>in</strong> caracterizarea gradului <strong>de</strong> poluare a mediului<br />

<strong>in</strong>conjurator<br />

Coordonator sti<strong>in</strong>tific: Prof. univ. dr. Ion V. Popescu<br />

Un doctorat <strong>in</strong> curs <strong>de</strong> f<strong>in</strong>alizare –<br />

ianuarie 2011 :<br />

teza sust<strong>in</strong>uta <strong>in</strong> sem<strong>in</strong>arul <strong>de</strong> catedra , cu recomandarea sust<strong>in</strong>erii publice a tezei<br />

Gabriel State (Co-UVT) – doctorand la Univer<strong>si</strong>tatea d<strong>in</strong> Bucuresti<br />

Titlul tezei: Studiul comparativ al meto<strong>de</strong>lor <strong>de</strong> analiză atomice <strong>si</strong> nucleare <strong>aplicate</strong> <strong>in</strong> <strong>in</strong>vestigarea urmelor <strong>de</strong> elemente<br />

poluante d<strong>in</strong> probe <strong>de</strong> mediu <strong>in</strong>conjurător<br />

Coordonator sti<strong>in</strong>tific: Prof. univ. dr. Ion V. Popescu


Modul <strong>de</strong> implicare a t<strong>in</strong>erilor cercetatori<br />

Un doctorand <strong>in</strong>scris <strong>in</strong> anul 2008 :<br />

Ioana Daniela Dulama (Co-UVT) - doctorand la Univer<strong>si</strong>tatea d<strong>in</strong> Bucuresti<br />

Titlul tezei: Studii analitice <strong>de</strong> optimizare a meto<strong>de</strong>lor <strong>de</strong> analiza <strong>de</strong> <strong><strong>in</strong>alta</strong> sen<strong>si</strong>bilitate <strong>si</strong> <strong>precizie</strong> bazate pe <strong>in</strong>teractia<br />

radiatiei electromagnetice <strong>si</strong> a particulelor cu substanta aplicata <strong>in</strong> studiul factorilor poluanti ai mediului <strong>in</strong>conjurator<br />

Coordonator sti<strong>in</strong>tific: Prof. univ. dr. Ion V. Popescu<br />

Un doctorand <strong>in</strong>scris <strong>in</strong> anul 2009 :<br />

Bosneaga Al<strong>in</strong>a (P1-UDJG)* - doctorand la Univer<strong>si</strong>tatea Dunarea <strong>de</strong> Jos, Galati<br />

Titlul tezei: Cuantificarea gradului <strong>de</strong> poluare a solului<br />

Coordonator sti<strong>in</strong>tific: Prof. univ. dr. Lucian Petrescu<br />

*(<strong>in</strong> 2008-2009 masterand la UDJG, specializarea "Meto<strong>de</strong> fizico-chimice <strong>de</strong> analiza <strong>si</strong> control",<br />

titlul lucrarii <strong>de</strong> disertatie: "Aplicatii ale fluorescentei <strong>de</strong> raze X“ – coordonator sti<strong>in</strong>tific – Conf. univ. dr. Antoaneta Ene).<br />

D<strong>in</strong> colectivul <strong>de</strong> cercetare fac parte stu<strong>de</strong>nti masteranzi la urmatoarele specializari:<br />

• “Meto<strong>de</strong> fizico-chimice pentru studiul calitatii vietii <strong>si</strong> mediului” – Co-UVT<br />

• "Analize fizico-chimice d<strong>in</strong> Sti<strong>in</strong>ta Materialelor <strong>si</strong> Mediu“- P1- UGJG


Indicatori <strong>de</strong> rezultat realizati<br />

1. Meto<strong>de</strong> analitice <strong>de</strong> <strong><strong>in</strong>alta</strong> sen<strong>si</strong>bilitate, adaptate <strong>si</strong> optimizate pentru analiza probelor <strong>de</strong><br />

mediu: AAS, EDXRF, PIXE, NAA, SEM, UV-VIS, electrochimice cu biosenzori, CL, FTIR;<br />

2. Retete <strong>de</strong> preparare probe;<br />

3. Studii:<br />

- priv<strong>in</strong>d cont<strong>in</strong>utul <strong>de</strong> metale grele al diferitelor probe <strong>de</strong> mediu: sol, apa, vegetatie;<br />

- priv<strong>in</strong>d capacitatea <strong>de</strong> acumulare a metalelor grele <strong>de</strong> catre bio<strong>in</strong>dicatori:<br />

muschi – bio<strong>in</strong>dicatori <strong>de</strong> aer <strong>si</strong> ciuperci – bio<strong>in</strong>dicatori <strong>de</strong> sol;<br />

- studiu comparativ al rezultatelor analizelor elementale ale probelor <strong>de</strong> mediu;<br />

- <strong>de</strong> <strong>de</strong>gradare a <strong>de</strong>seurilor polimerice.<br />

4. Articole publicate/ acceptate pentru publicare:<br />

- 18 lucrari publicate <strong>in</strong> reviste ISI;<br />

- 20 lucrari publicate <strong>in</strong> reviste BDI sau B+;<br />

- 4 articole acceptate pentru publicare <strong>in</strong> reviste ISI<br />

5. Articol premiat la confer<strong>in</strong>ta <strong>in</strong>ternationala


Indicatori <strong>de</strong> rezultat realizati<br />

Articole publicate <strong>in</strong> reviste ISI – etapa I <strong>si</strong> etapa II/2009: 4<br />

1. I.V.Popescu, C.Stihi, Gh.V.Cimpoca, G.Dima, Gh.Vlaicu, A.Gheboianu, I.Bancuta, V.Ghisa, G.State, Environmental Samples<br />

Analy<strong>si</strong>s by Atomic Absorption Spectrometry (AAS) and Inductively Coupled Plasma-Optical Emis<strong>si</strong>on Spectroscopy (ICP-AES),<br />

Rom. Journ. Phys., 2009, Vol. 54, Nos. 7–8, P. 741–746,<br />

2. M. Ba<strong>de</strong>a, M. Florescu, Gh. Coman, A. Chesca, J.-L. Marty, Comparative Studies for Pollutants Detection U<strong>si</strong>ng Electrochemical<br />

Sensors and Enzyme-Based Biosensors, Sen<strong>si</strong>ng <strong>in</strong> Electroanaly<strong>si</strong>s, Vol. 4, Eds: K. Vytras, K. Ka;lcher, I. Svancara, Univer<strong>si</strong>ty of<br />

Pardubice, 2009. ISBN 978-80-7395-9.<br />

3. T. Zaharescu, S. Jipa, E.D. Poescu, W. Kappel, G. Samoilescu, Effects of -irradiation on PVC/mica electrical <strong>in</strong>sulation, Journal<br />

of Optoelectronics and advanced materials- sympo<strong>si</strong>a, 2009, Vol1., N0.5, p.963-966<br />

4. S. Jipa, T. Zaharescu, R. Setnescu, E.S. Dragan, M.V. D<strong>in</strong>u, Thermal and radiochemical <strong>de</strong>gradation of some PAN copolymers,<br />

Materials Chemistry and Phy<strong>si</strong>cs, 112, 612-618, 2008<br />

Articole publicate <strong>in</strong> reviste ISI – etapa III/2010: 14 articole<br />

1. Ion V. Popescu, Mar<strong>in</strong>a Frontasyeva, Claudia Stihi, Gh. V. Cimpoca, Cristiana Radulescu, Anca Gheboianu, Cal<strong>in</strong> Oros, Gh. Vlaicu,<br />

Marian Petre, Iulian Bancuta, Ioana Dulama, Nuclear and Nuclear Related Analytical Methods Applied <strong>in</strong> Environmental<br />

Research, Romanian. Journal of Phy<strong>si</strong>cs, Vol. 55, No 7-8 , p. 821-830, 2010<br />

2. Antoaneta Ene, Ion V. Popescu, Claudia Stihi, Anca Gheboianu, Ana Pantelicã, Carmelia Petre, PIXE Analy<strong>si</strong>s of Multielemental<br />

Samples, Romanian. Journal of Phy<strong>si</strong>cs, Vol. 55, No. 7-8, p.806-815, 2010<br />

3. Cristiana Radulescu, Claudia Stihi, Gabriela Busuioc, Anca Ir<strong>in</strong>a Gheboianu, Ion V. Popescu, Studies Concern<strong>in</strong>g Heavy Metals<br />

Bioaccumulation of Wild Edible Mushrooms from Industrial Area by U<strong>si</strong>ng Spectrometric Techniques, Bullet<strong>in</strong> of Environmental<br />

Contam<strong>in</strong>ation and Toxicology 84:641–646 (2010)


Indicatori <strong>de</strong> rezultat realizati<br />

4. Radulescu, C., Stihi, C., Busuioc, G., Popescu, I.V., Gheboianu, A., Cimpoca, Gh.V, Evaluation of essential elements and heavy<br />

metal levels <strong>in</strong> fruit<strong>in</strong>g bodies of wild mushrooms and their substrate by EDXRF spectrometry and FAA spectrometry, Romanian<br />

Biotechnological Letters, Vol. 15, No. 4, pp. 5444-5456, 2010<br />

5. Antoaneta Ene, Al<strong>in</strong>a Bosneaga, L.Georgescu , Determ<strong>in</strong>ation of Heavy Metals <strong>in</strong> Soils U<strong>si</strong>ng XRF Technique, Romanian Journal of<br />

Phy<strong>si</strong>cs, Vol. 55, Nr 7-8, p.815-820, 2010<br />

6. S. Jipa, T. Zaharescu, W. Kappel, L. M. Gorghiu, R. Setnescu, Thermolum<strong>in</strong>escence of rare earths activated potas<strong>si</strong>um tetraborate,<br />

Rev. Chim. 61, nr. 3, p. 300 – 302, 2010<br />

7. H. C. Popa, S. Jipa, T. Zaharescu, Panagiotis Kefalas, K<strong>in</strong>etic approach of natural antioxidant <strong>de</strong>pletion dur<strong>in</strong>g thermal oxidation,<br />

OAM – RC, vol 4, No 2, p 223 – 227, 2010<br />

8. M. G. Ne<strong>de</strong>lcu, C. Pod<strong>in</strong>a, S. Jipa, T. Zaharescu, L. M. Gorghiu, Boracite Thermolum<strong>in</strong>escence, Rev. Chim. 61, nr. 8, p. 770 – 773,<br />

2010<br />

9. T. Zaharescu, L.G. A. Silva, S. Jipa, W. Kappel, Post – irradiation thermal <strong>de</strong>gradation of Pa6 and PA6,6, Rev. Rad. Phys. Chem. ,79,<br />

p. 388 – 391, 2010<br />

10. Maria Maris, Dan a. Maris, S. Jipa, T. Zaharescu, L. M. Gorghiu, Radioprotective Potential of Rosemary ( Rosmar<strong>in</strong>us Offic<strong>in</strong>alis)<br />

Aga<strong>in</strong>st Effects of Ioni<strong>si</strong>ng Radiation, Rev. Chim, 61, nr. 3, p. 235 – 237, 2010<br />

11. T. Zaharescu, F. Buse, S. Jipa, I. Plesa, F. Ciupr<strong>in</strong>a , The Assessment on Insulation Behavior of Multilayer EPDM/ Paper<br />

Compo<strong>si</strong>te, Materiale Plastice, 47, nr. 2, p. 195 – 198, 2010.<br />

12. E.Craciun, I.Jitaru, T.Zaharescu, S.Jipa, Qualification of epoxy re<strong>si</strong>n by radiochemical age<strong>in</strong>g, OAM – RC, vol 4, No 11, p 1819-1822,<br />

2010<br />

13. R.Parvu, C.Pod<strong>in</strong>a, T.Zaharescu, S.Jipa, Stability evaluation of polyurethane coat<strong>in</strong>gs by gamma irradiation, OAM – RC, vol 4, No<br />

11, p 1815-1818, 2010<br />

14. Cristiana Radulescu, Claudia Stihi, Ion V.Popescu, Stefania Iordache, Cationic dyes removal from textile wastewaters by u<strong>si</strong>ng<br />

ecofriendly adsorbents, Rev. Chim, 61, nr. 11, 2010


Indicatori <strong>de</strong> rezultat realizati<br />

Articole publicate <strong>in</strong> reviste recunoscute CNCSIS BDI-B+ : 19 articole<br />

1. Cristiana Radulescu, Claudia Stihi, Ion V. Popescu, Gabriela Busuioc, Anca Ir<strong>in</strong>a Gheboianu, Valerica cimpoca, Ioana Dulama, Mihaela<br />

Diaconescu, Determ<strong>in</strong>ation of heavy metals content <strong>in</strong> wild mushrooms and soil by EDXRF and FAAS techniques, Analele Univer<strong>si</strong>tatii<br />

“Ovidius” Constanta, Seria Chimie, Vol. XXI, Nr. 1 ,9-14, 2010<br />

2. Radu Setnescu, Iulian Bancuta, Tanta Setnescu, Valerica Cimpoca, Silviu Jipa, Ion V. Popescu, Thermal Characterization of<br />

Semiconductor BI2TE3 Materials u<strong>si</strong>ng DSC, Journal Of Science And Arts , 10, nr. 1(12) , p. 95 – 102, 2010<br />

3. Madal<strong>in</strong>a Ne<strong>de</strong>lcu, Corneliu Pod<strong>in</strong>a, Silviu Jipa, Radu Setnescu, Tanta Setnescu, Laura Monica Gorghiu, Cr<strong>in</strong>ela Dumitrescu, Ion V.<br />

Popescu, Cal<strong>in</strong> Oros, Traian Zaharescu, Adrian Mantsch, Wilhelm Kappel, Do<strong>si</strong>metric features of natural Fluorite from Romania, Journal Of<br />

Science And Arts, 10, nr. 2(13), p. 287 – 292, 2010<br />

4. Flor<strong>in</strong> Ciupr<strong>in</strong>a, Traian Zaharescu, Silviu Jipa, Ilona Plesa, Petru V. Not<strong>in</strong>gher, Denis Panaitescu, Effects of ioniz<strong>in</strong>g radiation on the<br />

dielectric properties of LDPE – AL2O3 nanocompo<strong>si</strong>tes, U.P.B. Sci. Bull., Series C, Vol. 72, Iss. 3, 2010<br />

5. Antoaneta Ene, Al<strong>in</strong>a Bosneaga, Inter-element relationships for soils around a ferrous metallurgical plant, Journal of Sciences and<br />

Arts, Year 10, No. 2 (13), pp. 285-290, 2010<br />

6. Antoaneta Ene, Nicolae Tigau, Mirela Praisler, Lum<strong>in</strong>ita Moraru, Pr<strong>in</strong>cipal component analy<strong>si</strong>s of phy<strong>si</strong>co-chemical parameters of<br />

river water, Annals of the Univer<strong>si</strong>ty Dunarea <strong>de</strong> Jos of Galati, Fascicle II - Mathematics, Phy<strong>si</strong>cs, Theoretical Mechanics, Year II(XXXIII)<br />

2010, ISSN 2067 - 2071, p.130-135.<br />

7. Giancarlo Rennela, Loretta Landi, Al<strong>in</strong>a Bosneaga, Paola Arfaioli, Antoaneta Ene, Lucian P. Georgescu, Quantitative measurements of<br />

the heavy metal content u<strong>si</strong>ng sequential chemical extraction on cu polluted soils, Annals of the Univer<strong>si</strong>ty Dunarea <strong>de</strong> Jos of Galati, Fascicle<br />

II - Mathematics, Phy<strong>si</strong>cs, Theoretical Mechanics, Year II(XXXIII) 2010, ISSN 2067 - 2071, p.160-165.<br />

8. Giancarlo Rennela, Loretta Landi, Al<strong>in</strong>a Bosneaga, Paola Arfaioli, Antoaneta Ene, Lucian P. Georgescu, Determ<strong>in</strong>ation of the level of<br />

soil pollution from soil solution u<strong>si</strong>ng AAS technique, Annals of the Univer<strong>si</strong>ty Dunarea <strong>de</strong> Jos of Galati, Fascicle II - Mathematics, Phy<strong>si</strong>cs,<br />

Theoretical Mechanics, Year II(XXXIII) 2010, ISSN 2067 - 2071, p.172-175<br />

9. L. Moraru, A. Ene, M. Praisler, Image analy<strong>si</strong>s procedure for i<strong>de</strong>ntify<strong>in</strong>g ciliated protozoa and para<strong>si</strong>tes <strong>in</strong> water samples, Annals of<br />

the Univer<strong>si</strong>ty Dunarea <strong>de</strong> Jos of Galati, Fascicle II - Mathematics, Phy<strong>si</strong>cs, Theoretical Mechanics, Year II(XXXIII) 2010, ISSN 2067 - 2071,<br />

p.83-86.


Indicatori <strong>de</strong> rezultat realizati<br />

Articole publicate <strong>in</strong> reviste recunoscute CNCSIS BDI-B+ : 19 articole<br />

11. Antoaneta Ene, Oleg Bog<strong>de</strong>vich, Al<strong>in</strong>a Bosneaga, Determ<strong>in</strong>ation of pestici<strong>de</strong>s and polycyclic aromatic hydrocarbons <strong>in</strong> soils from Eastern<br />

part of Romania u<strong>si</strong>ng GC and GC/MS techniques, Annals of the Univer<strong>si</strong>ty Dunarea <strong>de</strong> Jos of Galati, Fascicle II - Mathematics, Phy<strong>si</strong>cs,<br />

Theoretical Mechanics, Year II(XXXIII) 2010, ISSN 2067 - 2071, p.124-129.<br />

12. Antoaneta Ene, Ion V. Popescu, Claudia Stihi, Applications of proton-<strong>in</strong>duced X-ray emis<strong>si</strong>on technique <strong>in</strong> materials and<br />

environmental science, Ovidius Univer<strong>si</strong>ty Annals of Chemistry, Volume 20, Number 1, pp. 35-39, 2009.<br />

13. Cristiana Rădulescu , Ionica Ioniţă, Elena Ir<strong>in</strong>a Moater, Claudia Stihi, Decolourization of textile wastewater conta<strong>in</strong><strong>in</strong>g green cationic<br />

dye by AOPs, Ovidius Univer<strong>si</strong>ty Annals of Chemistry, Volume 20, Number 1, pp. 66-71, 2009<br />

14. Gheboianu, I.V. Popescu, C. Stihi, I. Bancuta, I. Dulama, AAS and TDS mesurements for water quality analy<strong>si</strong>s, Journal of Science and<br />

Arts, No.1(10), p.93-100 2009<br />

15. A. Bosneaga, A. Ene, L. Georgescu, XRF multi-elemental analy<strong>si</strong>s of topsoil near an <strong>in</strong>dustrial plant, The Annals of the Univer<strong>si</strong>ty<br />

Dunarea <strong>de</strong> Jos of Galati, Fascicle II - Mathematics, Phy<strong>si</strong>cs, Chemistry, Informatics, Supplement, Year III(XXXII), ISSN 1842-6506, p. 33-40,<br />

2009<br />

16. A. Bosneaga, L. Georgescu, A. Ene, Soil pollution with heavy metals <strong>in</strong> Galati region, The Annals of the Univer<strong>si</strong>ty Dunarea <strong>de</strong> Jos of<br />

Galati, Fascicle II - Mathematics, Phy<strong>si</strong>cs, Chemistry, Informatics, Supplement, Year III(XXXII), ISSN 1842-6506, p. 41-48, 2009<br />

17. Antoaneta Ene, Claudia Stihi, I.V. Popescu, Anca Gheboianu, Al<strong>in</strong>a Bosneaga, I. Bancuta,, Comparative studies on heavy metal content<br />

of soils u<strong>si</strong>ng AAS and EDXRF atomic spectrometric techniques, Annals of the Univer<strong>si</strong>ty Dunarea <strong>de</strong> Jos of Galati, Fascicle II -<br />

Mathematics, Phy<strong>si</strong>cs, Theoretical Mechanics, Year I(XXXII), ISSN 2067 - 2071, p. 51-54, 2009<br />

18. Antoaneta Ene, Al<strong>in</strong>a Boşneagă, Lucian Georgescu, XRF analy<strong>si</strong>s of soils from Lower Prut Meadow, Annals of the Univer<strong>si</strong>ty Dunarea<br />

<strong>de</strong> Jos of Galati, Fascicle II - Mathematics, Phy<strong>si</strong>cs, Theoretical Mechanics, Year I(XXXII), ISSN 2067 - 2071, p. 55-58, 2009<br />

19. A. Gheboianu, C. Stihi, I.V. Popescu, A. Ene, I. Bancuta, Gh.V. Cimpoca, I. Dulama, Quality studies of Ialomita and Potop rivers from<br />

Dambovita County area by AAS and TDS measurements, Annals of the Univer<strong>si</strong>ty Dunarea <strong>de</strong> Jos of Galati, Fascicle II - Mathematics,<br />

Phy<strong>si</strong>cs, Theoretical Mechanics, Year I(XXXII), ISSN 2067 - 2071, p. 59-62, 2009


Indicatori <strong>de</strong> rezultat realizati<br />

Articole acceptate pentru publicare <strong>in</strong> reviste ISI – 4 articole<br />

1. C. Stihi , C. Radulescu, G. Busuioc, I. V. Popescu ,A. Gheboianu, A. Ene, Studies on Accumulation of Heavy Metals<br />

from Substrate to Edible Wild Mushrooms, Romanian. Journal of Phy<strong>si</strong>cs, Vol. 55, No.1-2, 2011<br />

2. I.A. Ivan, V. Stihi, M. Ivan, C. Stihi, M. Rakotondrabe, A .Jelea, Battery Powered Cost Effective TDS Logger<br />

Inten<strong>de</strong>d for Water Test<strong>in</strong>g, Romanian. Journal of Phy<strong>si</strong>cs, Vol. 56, No 3-4, 2011<br />

3. Gabriel State, Ion V. Popescu, Anca Gheboianu, Cristiana Radulescu, Ioana Dulama, Iulian Bancuta, Raluca Stirbescu,<br />

I<strong>de</strong>ntification of air pollution elements <strong>in</strong> lichens used as bio<strong>in</strong>dicators, by the XRF and AAS methods, Romanian.<br />

Journal of Phy<strong>si</strong>cs, Vol. 55, No.1-2, 2011<br />

4. Ene, A., Bosneaga A., Georgescu L., Evaluation of soils pollution with heavy metals u<strong>si</strong>ng XRF technique, Journal of<br />

environmental Protection and Ecology 12 (2011), Manuscript No 1636A/07.07.09 acceptata pentru publicare – Nr. 12<br />

(2011).


Indicatori <strong>de</strong> rezultat realizati<br />

1.Articol premiat – Best Poster Award<br />

The workshop “Challenges <strong>in</strong> food chemistry”, 28-29 May, 2010,<br />

Constanta, Romania:<br />

Cristiana Radulescu, Claudia Stihi, Ion. V. Popescu, Valerica Gh.<br />

Cimpoca, Gabriela Busuioc, Anca Gheboianu, Mihaela<br />

Diaconescu (ROMANIA),<br />

Determ<strong>in</strong>ation of heavy metal contents <strong>in</strong> wild mushrooms and soil by<br />

EDXRF and FAA spectrometries<br />

http://www.univ-ovidius.ro/cfc2010/BestPosterAward.htm<br />

2. A II-a Confer<strong>in</strong>tă Sti<strong>in</strong>ifică Natională<br />

„Sti<strong>in</strong>te <strong>aplicate</strong> în studiul mediului înconjurător <strong>si</strong> materialelor ”,<br />

28-30 aprilie 2010,Targoviste


Activitati prevazute a se realiza <strong>in</strong> 2011‐ 9 activitati<br />

conform actului aditional 3/11.05.2010<br />

Activitate 4.1 Colectarea probelor <strong>de</strong> apa, vegetatie, sol d<strong>in</strong> zonele monitorizate pr<strong>in</strong> program.<br />

Activitate 4.2 Masuratori PIXE, AAS, EDXRF, SEM-EDX <strong>si</strong> NAA ale probelor colectate pentru<br />

<strong>de</strong>tern<strong>in</strong>area gradului <strong>de</strong> poluare cu metale grele.<br />

Activitate 4.3 Masuratori optice (senzori optici, turbidimetrie, nefelometrie, flamfotometrie) ale<br />

probelor, complementar cu masuratori spectrofotometrice <strong>si</strong> <strong>de</strong> imagistica SEM.<br />

Activitate 4.4 Masuratori fizico-chimice (CL <strong>si</strong> FTIR, s.a) pentru <strong>de</strong>term<strong>in</strong>area gradului <strong>de</strong> poluare<br />

cu poluanti macromoleculari per<strong>si</strong>stenti.<br />

Activitate 4.5 Prelucrarea datelor <strong>si</strong> analiza statistica a rezultatelor experimnentale obt<strong>in</strong>ute.<br />

Activitate 4.6 Realizarea diagramelor <strong>de</strong> distribuite a factorilor poluanti monitorizati <strong>in</strong> proiect.<br />

Activitate 4.7 Actualizarea pag<strong>in</strong>ii web cu rezultatele experimentale obt<strong>in</strong>ute<br />

Activitate 4.8 Comunicarea <strong>in</strong> mediul sti<strong>in</strong>tific a rezultatelor experimentale obt<strong>in</strong>ute; organizarea<br />

unei se<strong>si</strong>uni <strong>de</strong> comunicari sti<strong>in</strong>tifice <strong>de</strong> nivel national <strong>in</strong> domeniul tehnicilor <strong>aplicate</strong> <strong>in</strong> studiul<br />

mediului.<br />

Activitate 4.9 Elaborarea materialelor didactice pentru nivel masterat <strong>si</strong> doctorat cu tematica -<br />

tehnici <strong>de</strong> <strong><strong>in</strong>alta</strong> <strong>precizie</strong> <strong>si</strong> sen<strong>si</strong>bilitate utilizate pentru studiul poluarii mediului.


Obiective ce vor fi at<strong>in</strong>se, rezultate preconizate <strong>in</strong> 2011<br />

• Realizarea unui mo<strong>de</strong>l experimental <strong>de</strong> biomonitorizare a poluarii aerului <strong>si</strong> solului cu<br />

metale grele - element <strong>de</strong> orig<strong>in</strong>alitate;<br />

• Realizarea diagramelor/hartilor regionale <strong>de</strong> utilitate publica, cu <strong>in</strong>dici <strong>de</strong> poluare a<br />

mediului pr<strong>in</strong> metale grele;<br />

• Elaborarea elementelor <strong>de</strong> tehnologie pentru recuperarea materialelor polimerice;<br />

• Disem<strong>in</strong>area pe scara larga a rezultatelor pr<strong>in</strong> comunicarea la confer<strong>in</strong>te<br />

<strong>in</strong>ternationale <strong>si</strong> publicarea <strong>in</strong> reviste cotate ISI ; organizarea unei se<strong>si</strong>uni <strong>de</strong><br />

comunicari sti<strong>in</strong>tifice <strong>de</strong> nivel national <strong>in</strong> domeniul tehnicilor <strong>aplicate</strong> <strong>in</strong> studiul<br />

mediului;<br />

• Transferul rezultatelor catre agentiile regionale <strong>de</strong> protecta mediului, catre firmele cu<br />

activitate specifica <strong>in</strong> domeniul monitorizarii mediului, <strong>in</strong> scopul <strong>in</strong>formarii <strong>si</strong> educarii<br />

populatiei asupra factorilor <strong>de</strong> risc <strong>si</strong> a modurilor <strong>de</strong> actiune<br />

Estimarea necesarului <strong>de</strong> f<strong>in</strong>antare pentru ultimul an <strong>de</strong> implementare 2011<br />

Proiect 72-172<br />

Buget contractare <strong>in</strong>itiala<br />

(lei)<br />

F<strong>in</strong>antare primita<br />

(lei)<br />

F<strong>in</strong>antare<br />

primita %<br />

2011- ultimul an <strong>de</strong> implementare proiect<br />

Buget 2011 F<strong>in</strong>antare F<strong>in</strong>antare<br />

contractare ramasa conform solicitata<br />

<strong>in</strong>itiala contractului<br />

<strong>in</strong>itial<br />

2.000.000 563.062 31,3% 200.000 1.436.938 1.436.938

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