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X423 Solid which reacts dangerously with water, emitting flammable gas, or flammable solid which reacts dangerously with water, emitting flammable gas, or self-heating solid which reacts dangerously with water, emitting flammable gas 43 Spontaneously flammable (pyrophoric) solid X432 Spontaneously flammable (pyrophoric) solid which reacts dangerously with water, emitting flammable gas 44 Flammable solid, in the molten state at an elevated temperature 446 Flammable solid, toxic, in the molten state at an elevated temperature 46 Flammable solid, toxic, or self-heating solid, toxic 462 Toxic solid which reacts with water, emitting flammable gas X462 Solid which reacts dangerously with water, emitting toxic gas 48 Flammable or self-heating solid, corrosive 482 Corrosive solid which reacts with water, emitting flammable gas X482 Solid which reacts dangerously with water, emitting corrosive gas 50 Oxidizing (fire-intensifying) substance 539 Flammable organic peroxide 55 Strongly oxidizing (fire-intensifying) substance 556 Strongly oxidizing (fire-intensifying) substance, toxic 558 Strongly oxidizing (fire-intensifying) substance, corrosive 559 Strongly oxidizing (fire-intensifying) substance which can spontaneously lead to violent reaction 56 Oxidizing (fire-intensifying) substance, toxic 568 Oxidizing (fire-intensifying) substance, toxic, corrosive 58 Oxidizing (fire-intensifying) substance, corrosive 59 Oxidizing (fire intensifying) substance which can spontaneously lead to violent reaction 60 Toxic substance 606 Infectious substance 623 Toxic liquid which reacts with water, emitting flammable gas 63 Toxic substance, flammable 638 Toxic substance, flammable, corrosive 639 Toxic substance, flammable, which can spontaneously lead to violent reaction 64 Toxic solid, flammable or self-heating 642 Toxic solid which reacts with water, emitting flammable gas 65 Toxic substance, oxidizing (fire-intensifying) 66 Highly toxic substance 663 Highly toxic substance, flammable 664 Highly toxic solid, flammable or self-heating Page 12 HAZARD IDENTIFICATION NUMBERS DISPLAYED ON SOME INTERMODAL CONTAINERS
HAZARD IDENTIFICATION NUMBERS DISPLAYED ON SOME INTERMODAL CONTAINERS 665 Highly toxic substance, oxidizing (fire-intensifying) 668 Highly toxic substance, corrosive X668 Highly toxic substance, corrosive, which reacts dangerously with water 669 Highly toxic substance which can spontaneously lead to violent reaction 68 Toxic substance, corrosive 69 Toxic substance which can spontaneously lead to violent reaction 70 Radioactive material 78 Radioactive material, corrosive 80 Corrosive substance X80 Corrosive substance which reacts dangerously with water 823 Corrosive liquid which reacts with water, emitting flammable gas 83 Corrosive substance, flammable X83 Corrosive substance, flammable, which reacts dangerously with water 839 Corrosive substance, flammable, which can spontaneously lead to violent reaction X839 Corrosive substance, flammable, which can spontaneously lead to violent reaction and which reacts dangerously with water 84 Corrosive solid, flammable or self-heating 842 Corrosive solid which reacts with water, emitting flammable gas 85 Corrosive substance, oxidizing (fire-intensifying) 856 Corrosive substance, oxidizing (fire-intensifying) and toxic 86 Corrosive substance, toxic 88 Highly corrosive substance X88 Highly corrosive substance which reacts dangerously with water 883 Highly corrosive substance, flammable 884 Highly corrosive solid, flammable or self-heating 885 Highly corrosive substance, oxidizing (fire-intensifying) 886 Highly corrosive substance, toxic X886 Highly corrosive substance, toxic, which reacts dangerously with water 89 Corrosive substance which can spontaneously lead to violent reaction 90 Miscellaneous dangerous substance; environmentally hazardous substance 99 Miscellaneous dangerous substance transported at an elevated temperature Page 13
Page 1 and 2: A Guidebook for First Responders Du
Page 3 and 4: HOW TO USE THIS GUIDEBOOK RESIST RU
Page 5 and 6: NOTIFICATION AND REQUEST FOR TECHNI
Page 7 and 8: INTRODUCTION TO THE TABLE OF PLACAR
Page 9 and 10: RESPONSE GUIDE TO USE ON-SCENE USIN
Page 11 and 12: ROAD TRAILER IDENTIFICATION CHART*
Page 13: HAZARD IDENTIFICATION NUMBERS DISPL
Page 17 and 18: Markers - Often appear at road, rai
Page 19 and 20: Liquids Pipelines Petroleum and Haz
Page 21 and 22: • Nearby building construction ma
Page 23 and 24: ID Guide No. No. Name of Material I
Page 27 and 28: ID Guide No. No. 1173 129 Ethyl ace
Page 29 and 30: ID Guide No. No. 1287 127 Rubber so
Page 31 and 32: ID Guide No. No. 1364 133 Cotton wa
Page 49 and 50: ID Guide No. No. 2076 153 Cresols,
Page 53 and 54: ID Guide No. No. 2368 128 Pinene (a
Page 55 and 56: ID Guide No. No. 2469 140 Zinc brom
Page 59 and 60: ID Guide No. No. 2657 153 Selenium
Page 63 and 64: ID Guide No. No. 2810 153 HN-1 2810
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ID Guide No. No. Name of Material I
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ID Guide No. No. 3163 126 Liquefied
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Name of Material Guide No. ID No. A
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Name of Material Guide No. ID No. B
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Name of Material Guide No. ID No. n
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Name of Material Guide No. ID No. C
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Name of Material Guide No. Compress
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Name of Material Guide No. ID No. D
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Name of Material Guide No. ID No. D
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Name of Material Guide No. ID No. E
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Name of Material Guide No. ID No. F
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Name of Material Guide No. Hexafluo
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Name of Material Guide No. Hypochlo
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Name of Material Guide No. ID No. L
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Name of Material Guide No. ID No. L
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Name of Material Guide No. Mercapta
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Name of Material Guide No. ID No. N
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Name of Material Guide No. Nitrates
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Name of Material Guide No. ID No. N
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Name of Material Guide No. ID No. O
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Name of Material Guide No. ID No. P
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Name of Material Guide No. Picric a
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Name of Material Guide No. Poisonou
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Name of Material Guide No. ID No. n
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Name of Material Guide No. Rare gas
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Name of Material Guide No. Self-hea
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Name of Material Guide No. ID No. S
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Name of Material Guide No. ID No. T
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Name of Material Guide No. ID No. T
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Name of Material Guide No. Trifluor
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Name of Material Guide No. ID No. Y
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ERG2012 GUIDES Page 159
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ERG2012 Mixed Load/Unidentified Car
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ERG2012 expLosives* - division 1.1,
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ERG2012 fLaMMabLe soLids - toxiC (W
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ERG2012 expLosives* - division 1.4
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ERG2012 gases - fLaMMabLe (inCLUdin
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ERG2012 gases - fLaMMabLe (UnstabLe
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ERG2012 gases - toxiC - fLaMMabLe (
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ERG2012 gases - fLaMMabLe - Corrosi
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ERG2012 gases - toxiC - fLaMMabLe G
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ERG2012 gases - inert (inCLUding re
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ERG2012 gases - inert GUIDE 121 EME
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ERG2012 gases - oxidizing (inCLUdin
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ERG2012 gases - toxiC and/or Corros
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ERG2012 gases - toxiC and/or Corros
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ERG2012 gases - Corrosive GUIDE 125
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ERG2012 gases - CoMpressed or LiqUe
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ERG2012 fLaMMabLe LiqUids (poLar/Wa
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ERG2012 fLaMMabLe LiqUids (non-poLa
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ERG2012 fLaMMabLe LiqUids (poLar/Wa
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ERG2012 fLaMMabLe LiqUids (non-poLa
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ERG2012 fLaMMabLe LiqUids - toxiC G
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ERG2012 fLaMMabLe LiqUids - Corrosi
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ERG2012 EMERGENCY RESPONSE fLaMMabL
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ERG2012 fLaMMabLe soLids - toxiC an
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ERG2012 sUbstanCes - spontaneoUsLy
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ERG2012 sUbstanCes - spontaneoUsLy
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ERG2012 sUbstanCes - Water-reaCtive
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ERG2012 oxidizers GUIDE 140 EMERGEN
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ERG2012 oxidizers - toxiC GUIDE 141
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ERG2012 oxidizers - toxiC (LiqUid)
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ERG2012 oxidizers (UnstabLe) GUIDE
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ERG2012 oxidizers (Water-reaCtive)
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ERG2012 organiC peroxides (heat and
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ERG2012 organiC peroxides (heat, Co
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ERG2012 LithiUM ion batteries GUIDE
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ERG2012 organiC peroxides (heat and
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ERG2012 sUbstanCes (seLf-reaCtive)
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ERG2012 sUbstanCes (seLf-reaCtive/
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ERG2012 sUbstanCes - toxiC (non-CoM
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ERG2012 sUbstanCes - toxiC (CoMbUst
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ERG2012 sUbstanCes - toxiC and/or C
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ERG2012 infeCtioUs sUbstanCes GUIDE
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ERG2012 sUbstanCes (irritating) GUI
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ERG2012 haLogenated soLvents GUIDE
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ERG2012 radioaCtive MateriaLs (LoW
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ERG2012 radioaCtive MateriaLs (speC
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ERG2012 radioaCtive MateriaLs (fiss
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ERG2012 radioaCtive MateriaLs - Cor
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ERG2012 fLUorine (refrigerated LiqU
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ERG2012 Carbon Monoxide (refrigerat
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ERG2012 aLUMinUM (MoLten) GUIDE 169
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ERG2012 MetaLs (poWders, dUsts, sha
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ERG2012 sUbstanCes (LoW to Moderate
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ERG2012 gaLLiUM and MerCUry GUIDE 1
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INTRODUCTION TO GREEN TABLES - INIT
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PROTECTIVE ACTION DECISION FACTORS
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BACKGROUND ON TABLE 1 - INITIAL ISO
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(6) Initiate Protective Actions to
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1051 117 Hydrocyanic acid, aqueous
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1251 131P Methyl vinyl ketone, stab
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1582 119 Chloropicrin and Methyl 30
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30 m (100 ft) 0.1 km (0.1 mi) 0.2 k
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30 m (100 ft) 0.1 km (0.1 mi) 0.3 k
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30 m (100 ft) 0.1 km (0.1 mi) 0.2 k
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100 m (300 ft) 1.1 km (0.7 mi) 3.0
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30 m (100 ft) 0.1 km (0.1 mi) 0.3 k
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30 m (100 ft) 0.1 km (0.1 mi) 0.2 k
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30 m (100 ft) 0.2 km (0.1 mi) 0.8 k
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2481 155 Ethyl isocyanate 150 m (50
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2810 153 GF (when used as a weapon)
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2845 135 Ethyl phosphonous dichlori
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60 m (200 ft) 0.8 km (0.5 mi) 1.7 k
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3049 138 Metal alkyl halides, 30 m
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30 m (100 ft) 0.2 km (0.1 mi) 0.2 k
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100 m (300 ft) 0.5 km (0.3 mi) 2.2
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60 m (200 ft) 0.6 km (0.4 mi) 2.0 k
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60 m (200 ft) 0.4 km (0.3 mi) 2.1 k
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30 m (100 ft) 0.1 km (0.1 mi) 0.3 k
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60 m (200 ft) 0.3 km (0.2 mi) 1.1 k
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100 m (300 ft) 0.5 km (0.4 mi) 2.6
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30 m (100 ft) 0.1 km (0.1 mi) 0.3 k
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30 m (100 ft) 0.2 km (0.1 mi) 0.2 k
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30 m (100 ft) 0.1 km (0.1 mi) 0.5 k
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9269 132 Trimethoxysilane 30 m (100
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TABLE 2 - WATER-REACTIVE MATERIALS
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NOTES Page 351
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TABLE 3 - INITIAL ISOLATION AND PRO
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UN1052 Hydrogen fluoride: Large Spi
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GUIDEBOOK CONTENTS 1-Yellow-bordere
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Table 2 lists, by ID number order,
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PROTECTIVE CLOTHING Street Clothing
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FIRE AND SPILL CONTROL FIRE CONTROL
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What are the main hazards from a BL
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BLEVE (USE WITH CAUTION) Cooling wa
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INDICATORS OF A POSSIBLE CHEMICAL I
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Initial actions to consider in a po
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NOTES Page 373
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Glossary Blood agents Substances th
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Glossary Decontamination The remova
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Glossary Mass explosion Explosion w
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Glossary Radiation Authority As ref
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PUBLICATION DATA The 2012 Emergency
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The Emergency Response Guidebook is
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NOTE: 1. The appropriate federal ag
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CANADA EMERGENCY RESPONSE TELEPHONE
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