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HAZARD CLASSIFICATION SYSTEM The hazard class of dangerous goods is indicated either by its class (or division) number or name. Placards are used to identify the class or division of a material. The hazard class or division number must be displayed in the lower corner of a placard and is required for both primary and subsidiary hazard classes and divisions, if applicable. For other than Class 7 or the OXYGEN placard, text indicating a hazard (for example, “CORROSIVE”) is not required. Text is shown only in the U.S. The hazard class or division number and subsidiary hazard classes or division numbers placed in parentheses (when applicable), must appear on the shipping document after each proper shipping name. Class 1 - Explosives Division 1.1 Explosives with a mass explosion hazard Division 1.2 Explosives with a projection hazard Division 1.3 Explosives with predominantly a fire hazard Division 1.4 Explosives with no significant blast hazard Division 1.5 Very insensitive explosives with a mass explosion hazard Division 1.6 Extremely insensitive articles Class 2 - Gases Division 2.1 Flammable gases Division 2.2 Non-flammable, non-toxic* gases Division 2.3 Toxic* gases Class 3 - Flammable liquids (and Combustible liquids [U.S.]) Class 4 - Flammable solids; Spontaneously combustible materials; and Dangerous when wet materials/Water-reactive substances Division 4.1 Flammable solids Division 4.2 Spontaneously combustible materials Division 4.3 Water-reactive substances/Dangerous when wet materials Class 5 - Oxidizing substances and Organic peroxides Division 5.1 Oxidizing substances Division 5.2 Organic peroxides Class 6 - Toxic* substances and Infectious substances Division 6.1 Toxic*substances Division 6.2 Infectious substances Class 7 - Radioactive materials Class 8 - Corrosive substances Class 9 - Miscellaneous hazardous materials/Products, Substances or Organisms * The words “poison” or “poisonous” are synonymous with the word “toxic”. Page 4
INTRODUCTION TO THE TABLE OF PLACARDS USE THE TABLE OF PLACARDS ONLY WHEN THE ID NUMBER OR PROPER SHIPPING NAME IS NOT AVAILABLE. The next two pages display the placards used on transport vehicles carrying dangerous goods with the applicable reference GUIDE circled. Follow these steps: 1. Approach scene from upwind, uphill or upstream at a safe distance to safely identify and/or read the placard or orange panel. Use binoculars if available. 2. Match the vehicle placard(s) with one of the placards displayed on the next two pages. 3. Consult the circled guide number associated with the placard. Use that guide information for now. For example: • Use GUIDE for a FLAMMABLE (Class 3) placard • Use GUIDE for a CORROSIVE (Class 8) placard • Use GUIDE when the DANGER/DANGEROUS placard is displayed or the nature of the spilled, leaking or burning material is not known. Also use this GUIDE when the presence of dangerous goods is suspected but no placards can be seen. If multiple placards point to more than one guide, initially use the most conservative guide (i.e., the guide requiring the greatest degree of protective actions). 4. Guides associated with the placards provide the most significant risk and/or hazard information. 5. When specific information, such as ID number or proper shipping name, becomes available, the more specific Guide recommended for that material must be consulted. 6. Asterisks (*) on orange placards represent explosives “Compatibility Group” letters; refer to the Glossary (page 375). 7. Double asterisks (**) on orange placards represent the division of the explosive. Page 5
Page 1 and 2: A Guidebook for First Responders Du
Page 3 and 4: HOW TO USE THIS GUIDEBOOK RESIST RU
Page 5: NOTIFICATION AND REQUEST FOR TECHNI
Page 9 and 10: RESPONSE GUIDE TO USE ON-SCENE USIN
Page 11 and 12: ROAD TRAILER IDENTIFICATION CHART*
Page 13 and 14: HAZARD IDENTIFICATION NUMBERS DISPL
Page 15 and 16: HAZARD IDENTIFICATION NUMBERS DISPL
Page 17 and 18: Markers - Often appear at road, rai
Page 19 and 20: Liquids Pipelines Petroleum and Haz
Page 21 and 22: • Nearby building construction ma
Page 23 and 24: ID Guide No. No. Name of Material I
Page 27 and 28: ID Guide No. No. 1173 129 Ethyl ace
Page 29 and 30: ID Guide No. No. 1287 127 Rubber so
Page 31 and 32: ID Guide No. No. 1364 133 Cotton wa
Page 49 and 50: ID Guide No. No. 2076 153 Cresols,
Page 53 and 54: ID Guide No. No. 2368 128 Pinene (a
Page 55 and 56: ID Guide No. No. 2469 140 Zinc brom
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ID Guide No. No. Name of Material I
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ID Guide No. No. 2657 153 Selenium
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ID Guide No. No. 2810 153 HN-1 2810
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ID Guide No. No. 3163 126 Liquefied
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Name of Material Guide No. ID No. A
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Name of Material Guide No. ID No. B
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Name of Material Guide No. ID No. n
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Name of Material Guide No. ID No. C
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Name of Material Guide No. Compress
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Name of Material Guide No. ID No. D
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Name of Material Guide No. ID No. D
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Name of Material Guide No. ID No. E
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Name of Material Guide No. ID No. F
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Name of Material Guide No. Hexafluo
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Name of Material Guide No. Hypochlo
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Name of Material Guide No. ID No. L
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Name of Material Guide No. ID No. L
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Name of Material Guide No. Mercapta
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Name of Material Guide No. ID No. N
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Name of Material Guide No. Nitrates
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Name of Material Guide No. ID No. N
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Name of Material Guide No. ID No. O
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Name of Material Guide No. ID No. P
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Name of Material Guide No. Picric a
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Name of Material Guide No. Poisonou
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Name of Material Guide No. ID No. n
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Name of Material Guide No. Rare gas
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Name of Material Guide No. Self-hea
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Name of Material Guide No. ID No. S
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Name of Material Guide No. ID No. T
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Name of Material Guide No. ID No. T
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Name of Material Guide No. Trifluor
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Name of Material Guide No. ID No. Y
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ERG2012 GUIDES Page 159
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ERG2012 Mixed Load/Unidentified Car
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ERG2012 expLosives* - division 1.1,
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ERG2012 fLaMMabLe soLids - toxiC (W
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ERG2012 expLosives* - division 1.4
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ERG2012 gases - fLaMMabLe (inCLUdin
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ERG2012 gases - fLaMMabLe (UnstabLe
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ERG2012 gases - toxiC - fLaMMabLe (
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ERG2012 gases - fLaMMabLe - Corrosi
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ERG2012 gases - toxiC - fLaMMabLe G
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ERG2012 gases - inert (inCLUding re
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ERG2012 gases - inert GUIDE 121 EME
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ERG2012 gases - oxidizing (inCLUdin
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ERG2012 gases - toxiC and/or Corros
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ERG2012 gases - toxiC and/or Corros
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ERG2012 gases - Corrosive GUIDE 125
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ERG2012 gases - CoMpressed or LiqUe
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ERG2012 fLaMMabLe LiqUids (poLar/Wa
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ERG2012 fLaMMabLe LiqUids (non-poLa
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ERG2012 fLaMMabLe LiqUids (poLar/Wa
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ERG2012 fLaMMabLe LiqUids (non-poLa
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ERG2012 fLaMMabLe LiqUids - toxiC G
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ERG2012 fLaMMabLe LiqUids - Corrosi
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ERG2012 EMERGENCY RESPONSE fLaMMabL
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ERG2012 fLaMMabLe soLids - toxiC an
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ERG2012 sUbstanCes - spontaneoUsLy
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ERG2012 sUbstanCes - spontaneoUsLy
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ERG2012 sUbstanCes - Water-reaCtive
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ERG2012 oxidizers GUIDE 140 EMERGEN
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ERG2012 oxidizers - toxiC GUIDE 141
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ERG2012 oxidizers - toxiC (LiqUid)
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ERG2012 oxidizers (UnstabLe) GUIDE
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ERG2012 oxidizers (Water-reaCtive)
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ERG2012 organiC peroxides (heat and
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ERG2012 organiC peroxides (heat, Co
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ERG2012 LithiUM ion batteries GUIDE
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ERG2012 organiC peroxides (heat and
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ERG2012 sUbstanCes (seLf-reaCtive)
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ERG2012 sUbstanCes (seLf-reaCtive/
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ERG2012 sUbstanCes - toxiC (non-CoM
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ERG2012 sUbstanCes - toxiC (CoMbUst
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ERG2012 sUbstanCes - toxiC and/or C
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ERG2012 infeCtioUs sUbstanCes GUIDE
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ERG2012 sUbstanCes (irritating) GUI
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ERG2012 haLogenated soLvents GUIDE
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ERG2012 radioaCtive MateriaLs (LoW
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ERG2012 radioaCtive MateriaLs (speC
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ERG2012 radioaCtive MateriaLs (fiss
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ERG2012 radioaCtive MateriaLs - Cor
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ERG2012 fLUorine (refrigerated LiqU
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ERG2012 Carbon Monoxide (refrigerat
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ERG2012 aLUMinUM (MoLten) GUIDE 169
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ERG2012 MetaLs (poWders, dUsts, sha
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ERG2012 sUbstanCes (LoW to Moderate
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ERG2012 gaLLiUM and MerCUry GUIDE 1
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INTRODUCTION TO GREEN TABLES - INIT
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PROTECTIVE ACTION DECISION FACTORS
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BACKGROUND ON TABLE 1 - INITIAL ISO
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(6) Initiate Protective Actions to
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1051 117 Hydrocyanic acid, aqueous
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1251 131P Methyl vinyl ketone, stab
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1582 119 Chloropicrin and Methyl 30
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30 m (100 ft) 0.1 km (0.1 mi) 0.2 k
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30 m (100 ft) 0.1 km (0.1 mi) 0.3 k
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30 m (100 ft) 0.1 km (0.1 mi) 0.2 k
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100 m (300 ft) 1.1 km (0.7 mi) 3.0
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30 m (100 ft) 0.1 km (0.1 mi) 0.3 k
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30 m (100 ft) 0.1 km (0.1 mi) 0.2 k
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30 m (100 ft) 0.2 km (0.1 mi) 0.8 k
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2481 155 Ethyl isocyanate 150 m (50
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2810 153 GF (when used as a weapon)
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2845 135 Ethyl phosphonous dichlori
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60 m (200 ft) 0.8 km (0.5 mi) 1.7 k
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3049 138 Metal alkyl halides, 30 m
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30 m (100 ft) 0.2 km (0.1 mi) 0.2 k
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100 m (300 ft) 0.5 km (0.3 mi) 2.2
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60 m (200 ft) 0.6 km (0.4 mi) 2.0 k
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60 m (200 ft) 0.4 km (0.3 mi) 2.1 k
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30 m (100 ft) 0.1 km (0.1 mi) 0.3 k
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60 m (200 ft) 0.3 km (0.2 mi) 1.1 k
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100 m (300 ft) 0.5 km (0.4 mi) 2.6
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30 m (100 ft) 0.1 km (0.1 mi) 0.3 k
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30 m (100 ft) 0.2 km (0.1 mi) 0.2 k
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30 m (100 ft) 0.1 km (0.1 mi) 0.5 k
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9269 132 Trimethoxysilane 30 m (100
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TABLE 2 - WATER-REACTIVE MATERIALS
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NOTES Page 351
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TABLE 3 - INITIAL ISOLATION AND PRO
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UN1052 Hydrogen fluoride: Large Spi
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GUIDEBOOK CONTENTS 1-Yellow-bordere
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Table 2 lists, by ID number order,
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PROTECTIVE CLOTHING Street Clothing
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FIRE AND SPILL CONTROL FIRE CONTROL
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What are the main hazards from a BL
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BLEVE (USE WITH CAUTION) Cooling wa
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INDICATORS OF A POSSIBLE CHEMICAL I
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Initial actions to consider in a po
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NOTES Page 373
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Glossary Blood agents Substances th
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Glossary Decontamination The remova
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Glossary Mass explosion Explosion w
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Glossary Radiation Authority As ref
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PUBLICATION DATA The 2012 Emergency
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The Emergency Response Guidebook is
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NOTE: 1. The appropriate federal ag
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CANADA EMERGENCY RESPONSE TELEPHONE
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