7 - Air Mobility Command Administrative Record

1 7 7 5 0 

FILE: Table 32-1 Rule 16 

M.C. 

FAIRCHILD AFB 

WASHINGTON 

ADMINISTRATIVE RECORD 

COVERSHEET 

AR File Number 1-4 4 5 -

1 7 7 5 

77*

Section Tab 

I S Q)wxo, 

1 7 7 5 2

ww-1 

Optimization, Operations, and Maintenance 

First Quarter 2000 Report 

Fairchild Air Force Base 

June 2000 

1 7 7 5

ww-1 


First Quarter 2000 Report 

ww-1 


Preparedfor: 

Air Force Center for Environmental Excellence 

Environmental Restoration Division (AFCEE/ERD) 

Brooks Air Force Base, Texas 78235-5328 

AFCEE Contract Number F41624-97-D-8019, Delivery Order 27 

Prepared by: 

CH2M HILL 

9 South Washington, Suite 400 

Spokane, WA 99201 

June 2000 

1 7 7 5

1 7 7 5 5 

Copyright 2000 by CH2M HILL, Inc. 

Reproduction in whole or in part without the 

written consent of CH2M HILL is prohibited. 

146680.92.94 

MDH/BMF

Notice 

1 7 75 

This report has been prepared for the United States Air Force by CH2M HILL to aid in the 

implementation of a final remedial action plan under the Air Force Installation Restoration 

Program (IRP). The limited objectives of this report and the ongoing nature of the IRP, 

along with the evolving knowledge of site conditions and chemical effects on the 

environment and health, must be considered when evaluating this report because 

subsequent facts may become known which may make this report premature or inaccurate. 

Acceptance does not mean that the United States Air Force adopts the conclusions, 

recommendations, or other views expressed herein, which are those of the contractor only, 

and do not necessarily reflect the official position of the United States Air Force. 

Government agencies and their contractors registered with the Defense Technical 

Information Center (DTIC) should direct requests for copies of this report to: DTIC, 

Cameron Station, Alexandria, VA 99304-6145. 

Non-Government agencies may purchase copies of this document from National Technical 

Information Service (NTIS), 5285 Port Royal Road, Springfield, VA 22161. 

NOTICE&PREFACE DDC IN 

146680

1 7 

Preface 

This report presents findings obtained from the first quarter 2000 opfin-dzation, operation 

and maintenance for the groundwater extraction and treatment system located at the WW-1 

site, Fairchild Air Force Base near Spokane, Washington. 

Mr. Jon Haliscak, Air Force Center for Environmental Excellence, Environmental 

Restoration Division (AFCEE/ERD) was the ERD COR. 

Approval: 

R4 att 

Mark Henry 

Project Manager 

CH2M HILL 

N NOTICEVREFAC DOC 

146680

Contents 

1 7 75 

Section Page 

Notice III 

Preface ................................................................................................................................................ IV 

List of A cronym s ............................................................................................................................ V II 

1.0 Introduction ........................................................................................................................ 1-1 

1.1 Authorization 

1.2 Purpose and Objectives ............................................................................................ 1-1 

1.3 Background ................................................................................................................ 1-1 

2.0 First Q uarter 2000 G TP O perations ................................................................................ 2-1 

2.1 Perform ance M onitoring .......................................................................................... 2-1 

2.1.1 Liquid Phase Analytical Results .................................................................. 2-1 

2.1.2 A ir Phase Analytical Results ........................................................................ 2-2 

2.1.3 Regulatory Com pliance ................................................................................ 2-2 

2.2 Volum e of W ater Treated ......................................................................................... 2-3 

2.2.1 Flow M easurem ent System .......................................................................... 2-3 

2.2.2 Volum e of W ater Treated ............................................................................. 2-3 

2.3 TCE and DCE Rem ovals ........................................................................................... 2-3 

2.4 Plant O perations ........................................................................................................ 2-4 

2.4.1 O perational Param eters ................................................................................ 2-4 

2.4.2 H ours of Operation ........................................................................................ 2-4 

2.4.3 Incidental W ater Treatm ent ......................................................................... 2-4 

2.4.4 System Shutdow ns/A larm Conditions ...................................................... 2-4 

2.4.5 Site Events/Repairs ....................................................................................... 2-4 

3.0 Recom m endations .............................................................................................................. 3-1 

3.1 W W -1 Plant O ptim ization ....................................................................................... 3-1 

4.0 References ............................................................................................................................ 4-1 

Appendix 

A Operation and Maintenance Forms 

B Flow Summary 

C LTO Analytical Data 

Tables 

2-1 WW-1 Liquid Phase Analytical Results, First Quarter 2000 ......................................... 2-2 

2-2 W W -1 A ir Phase Analytical Results, First Q uarter 2000 ............................................... 2-2 

2-3 Approximate Flow Measurement Information at WW-1, First Quarter 2000 ........... 2-3 

2-4 WW-1 System Shutdowns/Alarms, First Quarter 2000 ................................................ 2-4 

2-5 W W -I Site A ctivities, First Q uarter 2000 ......................................................................... 2-5 

2-6 W W -l Site Repairs, First Q uarter 2000 ............................................................................. 2-5 

2000 1 ST QUARTER DOC V

-List of Acronyms 

AFCEE Air Force Center for Environmental Excellence 

AS air stripper 

CAS Columbia Analytical Services 

cis-DCE cis-1,2-Dichloroethene 

COC Contan-dnant of Concern 

DTW depth to water 

EA EA Engineering, Science, and Technology, Inc. 

Ecology Washington State Department of Ecology 

EPA United States Environmental Protection Agency 

ERD Environmental Restoration Division 

EW extraction well 

FAFB Fairchild Air Force Base 

FSP Field Sampling Plan 

GAC granular activated carbon 

gpm gallons per minute 

GTP Groundwater Treatment Plant 

IDW investigation-derived waste 

LTO long-term operation and maintenance 

fLg/L micrograms per liter 

MDL Method Detection Limit 

Ms matrix spike 

MSD matrix spike duplicate 

MW monitoring well 

NA not applicable 

NM not measured 

O&M operation and maintenance 

ppbv parts per billion volume 

PPE personal protective equipment 

PVC polyvinyl chloride 

RI remedial investigation 

ROD Record of Decision 

SAP Sampling and Analysis Plan 

TCE trichloroethene 

USAF United States Air Force 

VC vinyl chloride 

VOCS volatile organic compounds 

Weston Roy F. Weston Corporation 

WW-1 Wastewater Lagoon site 

1 7 7 

ACRONYM&DOC VII 

146680

1.0 Introduction 


1 7 75 1 0 

CH2M HILL has prepared this document as authorized by Delivery Order 27 (dated 19 

February 1998) of Contract Number F41624-97-D-8019, issued by the Department of the Air 

Force, Air Force Center for Environmental Excellence (AFCEE), Brooks Air Force Base, 

Texas. Specifically, this work was performed at the WW-1 site located at the eastern end of 

the Fairchild Air Force Base runway. Fairchild AFB is located west of Spokane, Washington. 

1.2 PurposeandO active 

This report presents and summarizes data collected during the first quarter of 2000 for the 

optimization and long-term operation and maintenance (LTO) of the groundwater 

extraction and treatment system at the WW-l site. 

1.3 Background 

The WW-1 site consists of two interconnected industrial wastewater lagoons, a skimming 

lagoon and a holding lagoon, which were used to remove petroleum contamination from 

stormwater and industrial wastewater generated on the Base. Trichloroethene (TCE) is the 

primary contaminant of concern (COC) at WW-1. Based on historical data, potential sources 

of TCE likely include long-term direct disposal of TCE (via industrial wastewater) into the 

lagoons and residual TCE in the stormwater sewer system from flightline oil/water 

separators (Weston, 1997). 

The Record of Decision (ROD) for WW-1 specified groundwater extraction and treatment 

using air stripping and/or carbon adsorption for rernediation of affected groundwater 

(Halliburton, June 1993). Construction of a pump-and-treat system, consisting of two 

extraction wells and a shallow-tray air stripper system with activated carbon adsorption, 

was completed in February 1996. During the first year of operation, the system was 

operated by Roy F. Weston Inc. and their operations subcontractor, Budinger and 

Associates. 

On March 1, 1997, CH2M HILL assumed primary responsibility for the optimization, 

operations, and maintenance of the WW-1 groundwater treatment plant (GTP). In 

December 1997, the pump-and-treat system was modified to enhance groundwater 

extraction with the addition of a well-point eductor system. 

2000 1 ST OUARTER DOC 

14V.80

.2.0 First Quarter 2000 GTP Operations 

This section presents and discusses data collected during LTO of the groundwater purnpand-treat 

system at WW-l for the first quarter of 2000. 

1 7 75 

The site was visited by operational staff routinely, except for weekends and some federal 

holidays. Normal operational activities included data recording, systems checks, treatment 

system flow rate monitoring, maintenance, and sampling in accordance with the with the 

Work Plan (CH2M HILL, March 1999b) and Sampling and Analysis Plan (CH2M HILL, 

March 1999a). 

Appendix A contains the following operational documentation: 

• Appendix A-1 Inspection/Maintenance Forms 

• Appendix A-2 Extraction Wells Data Summaries 

• Appendix A-3 Operational Data Summaries 

• Appendix A-4 Incidental Water Treatment Forms 

• Appendix A-5 Sampling Documentation Forms 

• Appendix A-6 Event/Repair Forms 

• Appendix A-7 Alarm Response Forms 

Appendix B provides a detail of treatment flows. Appendix C provides laboratory 

analytical data packages for samples collected during this quarter. 

2.1 Performance Monitoring 

Performance monitoring is conducted to monitor the effectiveness of several essential 

treatment plant components and confirm that the plant is meeting performance and 

permitted standards. Quarterly performance monitoring is performed in compliance with 

the Sampling and Analysis Plan (CH2M HILL, March 1999a)and includes: 

• Water samples collected from the plant influent and plant effluent 

• Air samples collected from the influent to the lead GAC unit, intermediate (influent into 

the lag GAC unit), and effluent from the lag GAC unit 

Laboratory analytical results (data reports) for water and air samples collected during this 

quarter are presented in Appendix C. 

2.1.1 Liquid Phase Analytical Results 

Influent and effluent water samples were collected on March 30,2000, and analyzed for 

volatile organic compounds (VOCs) using EPA Method 8260, in accordance with the 

AFCEE Quality Assurance Project Plan (QAPP) version 3.0 (AFCEE, March 1498). Table 2-1 

summarizes the results for TCE, cis-1,2-dichloroethene (cis-DCE), and vinyl chloride (VC). 

Complete analytical data packages are included in Appendix C. 

2ODD 1ST QUARTER DOC 2-1

7 7 5 12 

TABLE 2-1 

WW-11 Liquid Phase Analytical Results, First Quarter 2000 

WW-1 FIRST QUARTER 2000 REPORT 

TCE cis-DICE VIC 

Sample Location 4411-) (pg/L) (Rg/L) 

Plant Influent 9.8 20.5 1.16 

Plant Effluent 0.12 U 0.12 U 0.13 U 

Qualifiers: 

U = The analyte was analyzed for, but not detected. The associated numerical value is at or below the method 

detection limit (MDL). 

2.1.2 Air Phase Analytical Results 

Air samples were collected on March 30, 2000, using 6-liter Summa canisters and were 

analyzed using Method TO-14 by CH2M HILL's Applied Sciences Laboratory as specified 

in the Sampling and Analysis Plan (CH2M HILL, March 1999a).Ihe results for TICE, cis- 

DCE, and VC are shown in Table 2-2. Additional analytes were detected; complete 

analytical data packages are included in Appendix C. 

TABLE 2-2 

WW-1 Air Phase Analytical Results, First Quarter 2000 

TCE ci&-DCE VIC 

Sample Location (ppbv) (ppbv) (ppbv) 

GAC Influent 6.6 16.4 1.1 

Intermediate 0.5 L1 4.3 0.7 F 

GAC Effluent 0.5 F 6.2 1.2 

Qualifier: 

F = The analyte was positively identified but the associated numerical value is at or below the reporting limit. 

U = The analyte was not detected; the associated numerical value is the method detection limit. 

TCE was detected in the effluent sample at a concentration less than the method detection 

limit (MDL) of 0.5 ppbv for this quarter. The presence of cis-DCE in the GAC effluent 

indicates that cis-DICE breakthrough continues to occur in both the lead and lag GAC units. 

Quarterly results indicate that cis-DCE concentrations are greater in the effluent than in the 

intermediate. This likely is a result of the displacement of cis-DCE by the incon-dng TCE on 

the activated carbon adsorption sites (that is, TCE has a greater affinity for activated carbon 

than cis-DICE). 

2.1.3 Regulatory Compliance 

'Ihe WW-1 GTP operated within regulatory compliance limits for the first quarter of 2000. 

Trichloroethene was not detected in liquid discharge samples (the liquid discharge limit for 

TCE is 5 gg/L). Trichloroethene was detected in the effluent offgas samples at a 

concentration below the MDL (0.5 ppbv). 

2-2 2000 1ST QUARTERDOC

2.2 Volume of Water Treated 

2.2.1 Flow Measurement System 

1 7 75 13 

WW-1 FIRST OUARTERM REPORT 

Water flow rates are measured at EW-1 and at the plant discharge (P-5). The EW-1 flow 

meter measures the flow coming from that well. Flow meter (P-5) measures the combined 

flow of EW-1 and the Well Point System after being processed by the GTP air stripper. 

There are no flow monitors for the Well Point System, which includes water from EW-3, 

WP-1, WP-2, and WP-3. Because of this, the flow from the Well Point System is estimated 

by assuming it to equal the difference in flow between the total plant discharge and EW-1. 

2.2.2 Vol u me of Water Treated 

Table 2-3 shows the estimated volume of water treated at WW-1 during the quarter. The 

total volume of water treated during the first quarter of 2000 was approximately 1.3 million 

gallons. The average flow rate of extracted groundwater through the GTP during the 

quarter was approximately 9.6 gallons per minute (gpm). The total amount of groundwater 

treated at the WW-1 GTP from March 1, 1997, through the end of this quarter is 

approximately 19.4 million gallons. A more detailed description of the flows and readings 

are included in Appendix B as Tables B-1 and B-2. 

TABLE 2-3 

Approximate Flow Measurement Information at W*11, First Quarter 2000 

Period of EW-11 Well Point SystemO Total Plant Discharge (P-5) 

Operation Total Total Total 

Flow Rateb Volume Flow Flateb Volume Flow Rateb Volume 

(gpm) (gallons)c (gpm) (gallons) WPM) (gallons) 

January 6.4 285,962 2.8 123,182 9.2 409,144 

February 6.4 261,760 2.6 108,472 9.0 370,232 

March 7.4 326,917 3.3 146,449 10.7 473,366 

First Quarter 6.7 874 378,104 9.6 1,252,742 

'Well Point System Flow Rate is not directly measured. It is assumed to be the difference between the Total Plant 

Discharge (P-5) and EW-1. 

bFlow Rate is calculated as a total monthly average by dividing the total flow by plant operating time. 

cEW-1 Total Volume is corrected by subtracting the amount of re-circulation volume during routine cleaning (see 

Appendix 8 for further details). 

2.3 TCE and cis-DCE Removals 

The estimated quantities of TCE and cis-DICE removed from the extracted groundwater 

during the first quarter of 2000 were calculated by multiplying quarterly concentrations by 

the total flow volume treated for the quarter. It is assumed that the air stripper had 100 

percent removal efficiencies for TCE and cis-DCE, since both these compounds were 

20DO 1 ST OUARTER DOC 2-3

1 7 7 5 1 4 

WWA FIRST QUARTER 2000 REPORT 

measured below the minimum detection limits in the laboratory. The estimated quantities 

of TCE and cis-DCE removed were 0.10 pound and 0.21 pound, respectively. 

2.4 Plant Operations 

2.4.1 Operational Parameters 

The WW-1 GTP operated in compliance with normal operating parameters set forth in the 

WW-1 Operations and Maintenance Manual (Weston, January 1997) and manufacturers' 

specifications. First quarter 2000 readings are included in Appendix A. 

2.4.2 Hours of Operation 

The WW-1 GTP operated for 2,161 hours during the first quarter of 2000. The GTP was 

shutdown for a total of 23 hours during the quarter as a result of a power failures. 

2.4.3 Incidental Water Treatment 

Approximately 115 gallons of incidental water were treated at the GTP. This water was 

generated by EA during their quarterly LTM sampling event, which commenced on 

March 17,2000, and ended on March 23,2000. The Water Treatment Approval Form is 

included in Appendix A-4. 

2.4.4 System Shutdowns/Alarm Conditions 

A system shutdown is defined as any alarm or maintenance issue that results in a plant 

down time of one hour or more. Table 2-4 summarizes the system shutdowns and alanns 

for this quarter. There were no Alarm responses during the first quarter of 2000. 

TABLE 2-4 

WWA System Shutdowns/Alarms, First Quarter 2000 

Date Hours of Plant Shutdown Alarm Reason 

01/16/00 3 No Power failure 




03103/00 4 No Power failure 

2.4.5 Site Events/Repairs 

Table 2-5 summarizes site activities for the first quarter. 

24 2000 ?ST QUARTER DOC

TABLE 2-6 

WW-11 Site Activities, First Quarter 2000 

Date(s) Event Description 

02123/00 - 02/24/00 Routine chlorinating and re-circulation of EW-11 (35,588 gallons circulated) 

3/20/00 Routine screen scrubbing of Well Point System wells. 

3/2a/oo Treated 1 1 5 gallons of incidental water from EA's quarterly sampling event. 

1 7 75 5 

WW-1 FIRSTGUARTERMAEPORT 

Repairs are corrective actions beyond normal operations that are independently tracked. 

Repair # 16, which was initiated during the fourth quarter 1999, is ongoing. Repair # 17 was 

initiated during this quarter and is also ongoing. Table 2-6 summarizes these repairs. The 

Event/Repair Forms are provided in Appendix A. 

TABLE 2-6 

WW-11 Site Repairs, First Quarter 2000 

Date 

Initiated Repair Status Reason 

10/20/99 1 6 Ongoing Small Miscellaneous Repairs, including flow meter calibration, fire 

alarm system repair, etc. 

03/06/00 1 7 Ongoing Miscellaneous work items, including reconnaissance for WW-1 

source investigation, etc. 

2000 I ST GUARTERDOC 2-5

3.0 Recommendations 

3.1 WW-1 Plant Optimization 

The following are recommended to further optimize WW-1 plant performance: 

• Evaluate extraction rates to determine if declining flows are resulting from regional or 

seasonal water level fluctuations, because of well mechanics, or a result of biofouling or 

inorganic precipitation that is reducing porosity in the aquifer 

• Modify the Well Point System to elin-dnate unnecessary valves, pipe, fittings, etc. to 

decrease head (friction) losses and thereby increase pumping volumes. 

1 7 7 5 6 

2ODD 1ST QUARTER DOC 3-1

4.0 References 

Air Force Center for Environmental Excellence (AFCEE). AFCEE Quality Analysis Project 

Plan, version 3.0, March 1998. 

CH2M HILL. Final Sampling and Analysis Plan Addendumfor Groundwater Monitoring and 

Pump and Treat Systems Operation, Craig Road Landfill and WW-1 Sites, March 1999a. 

CH2M HILL. Final Work Planfor Pump and Treat Systems Operation, Craig Road Landfill and 

WWA Sites, March 1999b. 

Halliburton N1JS (Halliburton NUS Environmental Corporation). Record of Decisionfor the 

On-Base Priority One Operable Units, June 1993. 

URS Consultants, Inc. WW-1 (AF Site WP-03) Treatment System Addenda, April 1995. 

WESTON (Roy F. Weston, Inc.). Remedial Action Report, August 1997. 

WESTON (Roy F. Weston, Inc.). Facility Assessment Report, August 1997 

WESTON (Roy F. Weston, Inc.). Operations and Maintenance Manual, January 1997. 

1 7 75 1 7 

2DDO IST QUARTER DOC 4-1

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1 7 75 2 4

WW-1 Routine Flow Measurements 


1 7 7 5 2 5 

xtraction Wells Air Stripper Effluent Pump 

EW-1 EW-3 P-5 

Flow Totalizer Flow Flow Totalizer Flow Flow Totalizer Flow 

Date Time Initials -(gpm) (gpm) (gallons) (gpm) (gallons) 

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Blower 

load, Vacuum Air 


Date Time Initials w.c.) (inches w.c.) (inches w.c.) (inches w.c.) (inches w.c.) (inches w.c.) Temp. (OF) 

6116a 's 0 940 "'Ye., /!r 6 J'Y & P4 /;. 4 9, O 0, a 7,Y 

741b 6 9,0 6 -f ie,- '14,_0 1q 10,0 f, I/.?- - O f"o -a, el 71Y 

10,60 *- If 5 , O C . /.I- O d,,o 1 7-; 

q qvo I4 ;, /), O. a/, /X, 0 X7 - 0 17Y 

Ille /0,0 /*O 4:C 61 'O'N /.O , /) 4- t5 go- tv 7 X 

011%0106 (J,7,40 4-a 6, o 4, /1, O ore O 0. 4) 73 

//16 lop 14 Al, .44V vf, /j /4f 4 12 _fn 0,0 61- &I 7,; 

Comments: 

WW-I Flow Masterxis i2/29/98 REVISED. NOV 1996

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Appendix Tab 

w 

JKo(liy- A-9 

lnaldeol4i vV& Frro.5 

1 7 75 3 0

FAIRCHILD AFB WW-I 

WATER TREATMENT APPROVAL FORM 

INFORMAno 

SOURCE(e.g..,wellpurgingetc.) wo.'A wj"14 

LOCATION OF SOURCE (e.g., monitoring Nvell number, etc.) KlaA-3d 5 

DATE OF GENERATION 

DATE OF SAMPLING 

DATE OF ANALYSIS (attach copy). e:21 

DATE OF APPROVAL TO DISCHARGE 

APPROVAL BY 

Eta &4;"&4;Am 16C 

NAME TAF9t TITLE 

TRANSFER INFORMATION 

DATEo TIME 0 fd 0 

ACCEPTING TANK T-100 T-101 

QUANTITY OF TRANSFER 

INDIVIDUAL RECEI dUG-WAUR 

NAME 

COMMENTS: 

1 7 75 4 0

Appendix Tab 

kFe rri k .X A-5 

&wh - Cb mlvv- vd-c o Yu 0-" is 

Ili 

1 7 7 5 4 1

FAIRCHILD AFB 

ENVIRONMENTAL MEDIA SAMPLING FORM 

SITE LOCATION (circle one): Craig Road Landfill 6) 

SAMPLING DATE: -va4z&C 

SAMPLE TEAM MEMBERS: 

SAMPLE MATRIX (circle one)(9Liquid Groundwater Other 

SAM SAMPLE ME ER ID PARAMETERS 

q! Af Z.IF-P- To -I+ 

LABORATORY:azm -CZ-. cp,& 

COMMENTS: 

COMPLETED BY: -TM Ls 'hz"o to 6 

(s n (date) 

4f/r. 

1 7 7 5 4 2

1 7 7 5 4 3 

FAIRCHILD AFB 


SITE LOCATION (circle one): Craig Road Landfill 

SAMPLING DATE: 

SAMPLETEAMMEMBERS: FILE( oc)R> WtQ-( 

SAMPLE MATRIX (circle one): Air (!) Groundwater Other. 

SAMPLE ID SAMPLE TIME CONTAINER ID PARAMETERS 

W)) I LU V04!; Ar3ce6jPIL0 

it 

LABORATORY:&.um&,4 &AyT7CAt--1;C"X,4&.5 

COMMENTS: (2A?-TE-ay 4:TP CZ&FLAROCL SNONO- 

COMPLETED BY: 30 IZ-000 

(date)

Appendix Tab 

krevljl4 A-o 

F-VV)4-18epal'r VovMS 

1 

1 7 75 4 4

WW-1, Fairchild Air Force Base 

Event/Repair Form 

Small Miscellaneous Repairs 

Project No.: 146680.96.93 Repair Number: # 16 

Initial Date: October 20, 1999 Completion Date: Ongoin 

Employee Responsible: Bob Wort Title: Treatment Plant Qperato 

Estimated Repair Cost: S 1,200 Final Repair Cost: Ongoin 

Est. CH2M HELL Level of Effort (LOE): 2 hrs; Final CH2M HILL LOE: Ongoing 

Equipment Purchased: - Yes - No AS-Built Updated _Yes - No 

Nature of the Problem: Miscellaneous small repairs completed at the direction/request of Fairchild 

AFB staff. 

Nature of Repairs (Ongoing): 

1. Function and calibration check of an industrial flow transmitter unit on October 20, 

1999, by Equipment Technology & Design Inc. 

2. Fire Alarm System repair on March 22, 2000, by General Fire 

ITUMBAftoLKLIENT PROJECT DELIVERYTAIRCHILMCONTRACT 8019 REPA1RS\WW-1\REPA1R 16,DOC 

1 7 75 4 5

7 7 5 4 6 



Miscellaneous Work Items 


Initial Date: March 6. 2000 Completion Date: Ongoin 

Employee Responsible: Bob Worl Title: Treatment Plant Operator 

Estimated Repair Cost: $ Z000 Final Repair Cost: Ongoin 

Est. C112M HILL Level of Effort (LOE): 20 hrs Final C112M HILL LOE: Ongoin 

Equipment Purchased: -Yes - No AS-Built Updated Y es -No 

Nature of the Problem: Miscellaneous work items identified by CH2M HILL and miscellaneous 

small repairs completed at the direction/request of Fairchild AFB personnel. 


1. ReconnaissanceforWW-Isourceinvestigation 

\TUMSAANVOLMLIENT PROJECT DELNERAFAIRCHILMONTRACT 8019 REPA1RSMW-1%REPfiR 17.ooc

Appendix Tab 

ApPeM 1 x A - - 

4(oorm Hesporicz 

1 7 75 4 7 

TUvc vvev-e k. 0,10,jMS 6(k_rj Vlj q/u- pi Or 2000.

Appendix Tab 

Ap(t vqd i -Y, B 

Pc)w Uwmar 

1 7 75 4 8

WI Site Flow Summary (Table B-1) 

1 7 75 4 9 

Water flow rates are measured at EW-1 and at the GTP total plant discharge (P-5). The EW-1 

flow meter measures the flow coming from that well. The total flow discharged by the GTP, 

which is a combination of flow from EW-1 and the Well Point System, is measured by the 

P-5 flow meter. There are no flow monitoring systems for the Well Point System, which 

includes EW-3, WP-1, WP-2, and WP-3. As a result, flow generated by the Well Point 

System is estimated by calculating the difference between the P-5 and EW-1 flow meter 

values. 

Average flow rates are also calculated for each system by dividing the daily flow volumes 

by the operating time in minutes for each month. 

As reported in Table B-1, the calculated average flow rate value for EW-1 on 24 February 

2000 is zero. This value is a result of re-circulating EW-1 during routine maintenance 

beginning on 23 February 2000. During the maintenance of EW-1, the discharge line is 

connected in a circuit to flush chlorinated water through the system for about a 24-hour 

period. The flow meter for EW-1 registers the circulating flow, which creates a false influent 

flow reading at the GTP. The only flow into the GTP during this time is from the Well Point 

System. Consequently, the average calculated flow rate for P-5 is equal to the average 

calculated flow rate for the Well Point System. 

2000 WI Site Flow Summary (Table B-2) 

Table B-2 provides a monthly summary of flow volumes and flow rates for EW-1, the Well 

Point System, and P-5 through the first quarter of 2000. The flow rates are calculated by 

dividing the volume of water treated by the operating time for each month. The total 

monthly volumes for EW-1 have been corrected by subtracting the volume of circulated 

water that is registered by the flow meter during routine maintenance of EW-1, as specified 

above. 

SPMPPENDIX B DOC

Table B-I 

WW-I Site Flow Summary, Third Quarter 1999 

1775 5o 

EW-1 Well Po! Svstem Total lant Dischame (P-5) 

(measured) (measured) (calculated) (calculated) (calculated) (measured) (calculated) (measured) 

Date Time Flow Rate Flow Average Flow Average Flow Rate Average Flow 

WPM) Volume Flow Rate Volume Flow Rate WPM) Flow Rate Volume 

(gallons) WPM) (gallons) (gpm) (gpm) (gallons) 

01/01/00 9:00 F.77- 12,486,973 6.7 3,957,310 3.1 26 9.8 18,167,002 

01/04/00 9:00 6.6 12,515.932 6.7 3,970,686 3.1 26 9.8 18,209,337 

01/07/00 9:00 6.5 12,544,281 6.6 3,981,699 2.5 26 9.1 18,248,699 

01/10/00 10:00 6.5 12,572,971 6.6 3,990,296 2.0 25 8.5 18,285,985 

01/13/00 9:30 6.6 12,601,023 6.5 4.004,646 3.3 25 9.9 18,328,388 

01/16/00 14:00 6.8 12,629,601 6.5 4,005.544 0.2 25 6.7 18,357,864 

01/20/00 9:00 6.5 12.665,045 6.5 4,026,805 3.9 25 10.4 18,414,569 

01/26/00 10:00 6.3 12,720,326 6.4 4,053,409 3.1 27 9.4 18,496,454 

02/01/00 9:30 6.2 12,772,935 6.1 4,080,492 3.1 27 9.3 18,576,146 

02/04/00 10:00 6.7 12,801,196 6.5 4.095,858 3.5 27 10.0 18.619,773 

02/09/00 9:30 6.9 12,840,762 6.0 4,115,630 3.0 27 9.0 18,679,111 

02/16/00 8:30 6.9 12.909,195 6.8 4,151,916 3.6 26 10.5 18,783,830 

02/18/00 9:00 6.8 12,928,542 6.6 4,159,855 2.7 27 9.4 18,811,116 

02/23/00 9:15 6.9 12,976,705 6.7 4,174,388 2.0 27 8.7 18,873,812 

VWN-1-00 --6.-30 '-f3-.01-,293 _A. 

43,L31 --- ill 2i _J-T :E8 8:7:8,-4e 

03/01/00 9:00 8.1 -1i.OT0,283 7.0 4,153,376 1.2 26 8.2 18,946,378 _ 

03/03/00 9:30 8.0 13,083,677 5.0 4,161,473 3.0 27 8.0 18,967,869 

03/06/00 9:00 7.7 13,117.161 7.8 4,182,425 49 26 12.7 19,022,305 

03/09/00 10:00 7.8 13,150,199 7.5 4,202,288 4.5 26 12.1 19,075,206 

03/14/00 8:00 7.5 13.204,816 7.7 4,230,541 4.0 27 11.7 19,158,076 

03/17/00 8:30 7.3 13,237,763 7.6 4,244,419 3.2 27 10.8 19,204,901 

03120/00 8:30 7.5 13,269,984 7.5 4,255,333 2.5 27 10.0 19,248,036 

03/22/00 8:00 7.5 13,291,476 7.5 4,261,224 2.1 27 9.6 19,275,419 

03/28/00 9:00 7.5 13,355,512 7.4 4,284,345 2.7 26 10.0 19,362,576 

03/30/00 8:50 7.2 13,376,316 7.2 4,292,139 2.7 27 10.0 19,391,174 

04104/00 11:00 7.2 13,428,525 7.1 4,311,355 2.6 27 9.7 19,462,599 

04/01/00 8:50 1 7.2 1 13,397,200 1 7.3 1 4,299.825 1 2.7 1 27 9.9 19,419.7AA I 

Not-eThe zero value in the EW-1 column is a result of recirculating EW-1 for routine maintenan 

SPK/Appendix Table B-1.xls 146680.92.94

1 7 75 5 1 

Table B-2 

2000 WWA Site Flow Summary 

EW-1 -Well Point m P-5 EW-1 Re-circ 

Period of Total Volume Flow Rate Total Volume Flow Rate Total Volume Flow Rate Volume 

Operation (gallons) (gpm) (gallons) (gpm) (gallons) (gpm) (gallons) 

January 285,962 6.4 123,182 2.8 409,144 9.2 0 

February 261,760 6.4 108,472 2.6 370.232 9.0 35,588 

March 326,917 7.4 146,449 3.3 473,366 10.7 0 

Ist Quarter 874,639 6.7 378,104 2.9 9.6 35.600 

SM/Flow Cal.Yft 146680.92 94

Appendix Tab 

L42: Nice ) Y- 

6 

L.M Mlj v fi. ca, Octhq- 

1 7 75 5 2

Appendix Tab 

I 

Pe VI di X L- I 

Air SMple- Fesu(4-5 

1 7 75 5 3

1 7 75 5 Appled SdOMW G=P 

2300 NW Wahut Blvd 

Corvdh& CR 

97330-3&38 

CH2M HILL P.O. Box 428 

Applied Sciences Group Corvaft OR 

97339-=8 

Tel 541.752.4271 

April 25, 2000 Fax 541.752 0276 

Fairchild AFB-LTO 

156470.02.08.03 

RE: Analytical Data for Fairchild AFB-LTO 

Applied Sciences Group Reference No. 3806 

Mark Henry/SPK: 

On March 31, 2000, CH2M HILL Applied Sciences Group received six samples with a 

request for analysis of selected parameters. 

The analytical results and associated quality control data are enclosed. Any unusual 

difficulties encountered during the analysis of your samples are discussed in the case 

narrative. 

Under CH2M HILL policy, your samples will be stored for 10 days after reporting. If you 

have not given us prior instructions for disposal, we will contact you if any samples require 

disposal as hazardous waste. 

C112M HELL Applied Sciences Group appreciates your business and looks forward to 

serving your analytical needs again. If you should have any questions concerning the data, or 

if you need additional information, please call Ms. Kathy McKinley at (541) 758-0235, 

extension 3120. 

Sincerely, 

'14 

Kelly Ensor 

Environmental Technologist 

Enclosures 

Cc: Artemis Antipas/SEA

55 

Table of Contents 

CH2M HILL Laboratory Reference No. 3806 

Page 

Volatile Organic Analysis ................................................................................ :............... I to 34 

Sample Data and QC Summary ............................................................................... 3 to 31 

Chain of Custody ................................................................................................... 32 to 34

AFCEE 

ORGANIC ANALYSIS DATA PACKAGE 

Analytical Method: TO-14 AAB#: 

Lab Name: QH2M HILL Applied Sciences Lab Contract C: 156470.02.08.03 

Base/Cormnand: Fairchild AFB-LTO Prime Contractor.: 

Field Sample ID Lab Sample H) 

0003LF02GAC(IN) 380601 

0003LF02GAC(UM 380602 

0003LF02GAC(OUT) 380603 

0003WWIGAC(N 380604 

0003WWIGAC( 380605 

0003WWIGAC(OUT) 380606 

1. Holding Times: 

All holding times were met for original sample analysis. Sample 380606RI was analyzed outside of 

acceptable holding times to provide lower reporting limits. 

11. Analysis: 

A Calibration: 

All acceptance criteria were met. 

B. Blanks: 


C. Duplicate Sarnole(s): 


D. Instrument rp6grraance Check-, 

,ept-ance criteria were met. 

E. Surrozate Recoveries: 


F. Internal Standards: 


G. Laboratory Control Spike(LCS) 


H. Analytical Exceptio 


1. Other: 

None 

Hi. SamWing EquiRment: 

None. 

AFCEE QRM 0-1 

1 7 75 5 6

17 75 5 7 

IV. Documentation Exceptions: 

None 

VOLATILE ORGANIC ANALYSIS 

V. I certify that this data package is in compliance with the terms and conditions agreed to by the client and CH2M 

HILL, both technically and for completeness, except for the conditions detailed above. Release of the data 

contained in this hardcopy data package has been authorized by the Laboratory Manager or designee, as verified 

by the following signature. 

Signature: Name: Ben Thomoson 

Date: Title: Air Toxics SUpervisor 

AFCEE ORM 0-1

AFCEE 

ORGANICS ANALYSES DATA SHEET 2 1 7 75 5 

RESULTS 

Anafytical Method: TO-14 Preparatory Method: NA SDG N 3806 

LabName: CH2MHILLASL Contract: 156470.02.08.03 

Field Sample ID: 0003LF02GAC(IN) Lab Sample ID: 380601 Matdx: Air 

% Solids NA Initial Calibration ID: 0410TO14 

Date Received: 03/31/00 Date Prepared: 04/13100 Date Analyzed: 04/13/00 13:42 

Concentration Units: ppbv 

Analyte MDL RL Concentration Dilution Confirm Qualifier 

bichlorodifluoromethane 0.8 1.7 0.8 1.7 U 

hioromethane 0.8 1.7 0.8 1.7 U 

1.2-Dichloro.1.1.2.2-tetrafluoroethane 0.8 1.7 0.8 1.7 U 

Vinyl chloride 0.8 1.7 0.8 1.7 U 

Bromomethane 0.8 1.7 0.8 1.7 U 

Chloroethane 0.8 1.7 0.8 1.7 U 

Trichlorofluoromethane 0.8 1.7 0.8 1.7 U 

11,11-Dichloroethene 0.8 1.7 0.8 1.7 U 

Mathylene chloride 0.8 1.7 0.8 1.7 U 

1.1,2-Trichloro-1.2.2-trifluoroethane 0.8 1.7 0.8 1.7 U 

1IJ-Dichloroethane 0.8 1.7 0.8 1.7 U 

cis-1.2-Dichloroethene 0.8 1.7 11.9 1.7 

Chloroform 0.8 1.7 0.8 1.7 U 

1.2-Dichloroethane 0.8 1.7 I 0.8 1.7 U 

1,1,11 -Trichloroethane 0.8 1.7 0.8 1.7 1 U 

Carbon tetrachloride 0.8 1.7 0.8 1.7 U 

Benzene 0.8 1.7 0.8 1.7 U 

1,2-Dichloropropane 0.8 1.7 0.8 1.7 U 

Trichloroethene 0.8 1.7 140 1.7 

cis-1,3-Dichloroprope;e 0.8 1.7 0.8 1.7 U 

trans-1,3-Dichloropropene 0.8 1.7 0.8 1.7 U 

1,1,2-Trichloroethane 0.8 1.7 0.8 1.7 U 

Toluene 0,8 1 7 0.8 1.7 U 

1,2-Dibromoethane 0.8 117 0.8 1.7 U 

Tetrachloroethene 0.8 1.7 0.8 1.7 U 

6hio-robenzene -0.8 1.7 0.8 1.7 U 

Ethylbenzene 0.8 1.7 0.8 1.7 U 

m.p-Xylenes 1.7 3.4 1.7 1.7 U 

Styrene 0.8 1.7 0.8 1.7 U 

o-Xylene b.8 1.7 0.8 1.7 U 

Tl,2,2-Tetrachloroethane 0.8 1.7 0.8 1.7 U 

1,3.5-Trimethylbehzene -6.8 1.7 0.8 1.7 I U 

1,2.4-Trimethylbenzene 0.8 1.7 0.8 1.7 U 

1,3-Dichlorobenzone 0.8 1.7 0.8 1.7 U 

1,4-Dichlorobenzene 1: 1.7 0.8 1.7 U 

1,2-Dichlorobenzene 08 1.7 0.8 1.7 U 

1,2,4-Tdchlorobenzone 0.8 1.7 0.8 1.7 U 

Hexachlorobutadiene 0.8 1.7 U 

Isurrogate I %REC I Control Limits I QuagiEl 

AFCEE FORM 0-2 -3- Rev. 10/99

AFCEE 

17 7 5 59 ORGANICS ANALYSES DATA SHEET 2 

RESULTS 

Analytical Method: TO-14 Preparatory Method: NA SDG N 3806 

LabName: CH2IVIHILLASL Contract: 156470.02.08.03 

Field Sample ID: 0003LF02GAC(INT) Lab Sample ID: 380602 Matrix: Air 


Date Received: 03/31/00 Date Prepared: 04/11/00 Date Analyzed: 04111100 17:27 


Analyte IVIDL RL Concentration Dilution Confirm Qualifier 

Dichlorodifluoramethane 0.5 1.1 0.6 1.1 F 

Chloromethane 0.5 1.1 0.6 1.1 F 

1,2-Dichloro.1,1,2,2-tetrafluoroethane 0.5 1.1 0.5 1.1 U 




Trichlorof luoromethane 0.5 1.1 1 0.5 1.1 U 

1.1-Dichloroethene 0.5 1.1 1 0.5 1.1 U 

Methylene chloride 0.5 1.1 0.8 1.1 F 

1,1,2-Trichloro-1,2,2-trifluoroethane 0.5 1.1 0.5 1.1 U 

1.1-Dichloroethane 0.5 1.1 0.5 1.1 U 

cis-1,2-Dichloroethene 0.5 1.1 3.8 1.1 

Chloroform 0.5 1.1 0.5 1.1 U 


1.1.1 -Trichloroethane 0.5 1.1 0.5 1.1 I U I 

Carbon tetrachloride 0.5 1.1 I 0.5 1.1 U 

Benzene 0.5 1.1 0.5 1.1 U 


Trichloroethene 0.5 1.1 0. 1.1 U 

cis-1,3-Dichloropropene 0.5 1.1 0.5 1.1 U 

trans-1.3-Dichloropropene 0.5 1.1 0.5 1.1 U 


Toluene 0.5 1.1 0.5 1.1 U 

1,2-Dibromoethane 0.5 1.1 0.5 1.1 U I 

Tetrachforoethene 0.5 1.1 I 0.5 1.1 U 

Chlorobenzene 0.5 1.1 0.5 1.1 U 


ml)-Xylenes 1.1 2.1 1.1 1.1 U 

Styrene 0.5 1.1 0.5 1.1 I U 

o-Xylene 0.5 1.1 0.5 1.1 U 

1,1,2,2-Tetrachloroethane 0.5 1.1 0.5 1.1 U 

1.3,5-Trimethylbenzene 0.5 1.1 0.5 1.1 U I 

1,2,4-Trimethylbenzene 0.5 1.1 0.5 1.1 U 

1,3-Dichlorobenzene 0.5 1.1 1 0.5 1.1 U 

1,4-Dichlorobenzene 0.5 1.1 0.5 1.1 U 


I= rhlorobenzene 0.5 1.1 0.5 1.1 U 

obutadiene 0.5 1.1 0.5 1.1 U 

Isurrogate I %REC I Control Limits Qualifi 

lBromofluorobenzene 91% 1 7 


AFCEE 1 7 7 5 6 

ORGANICS ANALYSES DATA SHEET 2 

RESULTS 


LabName: CH21VIHILLASL Contract: 156470.02.08.03 

Field Sample ID: 0003LF02GAC(OUT) Lab Sample ID: 380603 Matrix: Air 


Date Received: 03/31/00 Date Prepared: 04/13100 Date Analyzed: 04/13100 15:43 


alyte MDL RL lConcentration Dilution Confirm Qualifier 

ichlorodifluoromethane 0.5 1.0 0.6 1.0 F 

loromethane 0.5 1.0 0.6 1.0 F 

2-Dichloro.1.1,2.24etrafluoroothane 0.5 1.0 0.5 1.0 U 

nyl chloride 0.5 1.0 0.5 1.0 U 

momethane 0.5 1.0 0.5 1.0 U 

loroethane 0.5 1.0 0.5 1.0 U 


1.1-Dichloroethene 0.5 1.0 0.5 1.0 U 

Methylene chloride 0 1.0 0.5 1.0 U 

1,1,2-Trichloro-1,2.2-tdfluoroethane 0.5 1.0 0.5 1.0 U 

1,1-Dichloroethane -C-5 -10 0.5 1.0 U 

cis-1,2-Dichloroethene 0.5 1.0 0.5 1.0 U 

Chloroform 0.5 1.0 0.5 1.0 U 

1,2-Dichloroethane 0.5 1.0 0.5 1.0 I LI 

1.1. I -Trichloroothane 0.5 1.0 0.5 1 1.0 U 

Carbon tetrachloride 0.5 1.0 0.5 U 

Benzene 0.5 1.0 U 

1,2-DichlorODrooane 0.5 1.0 1.0 U 

Trichloroethene 0.5 1.0 0.5 1.0 U 

cis-1.3-Dichloropropene 0 5 1 0 0.5 1.0 U 

trans-1,3-Dichloropropene 0.5 1.0 U 

1. 1,2-Trichloroethane 0.5 1.0 0.5 1.0 U 

Toluene 0.5 1,13 0.5 1.0 U I 

T,2-DIbromoethane 0.5 1.0 0.5 1.0 U 




mp-Xylenes 1.0 2.0 1.0 1.0 U 

Styrene 0.5 1.0 0.5 1.0 I U 

o-Xylene 0.5 1.0 0.5 1.0 U 

1,1,2,2-Tatrachloroethane 0.5 1.0 0.5 1.0 U 

1.3.5-Trimethylbenzone 0.5 1.0 0.5 1.0 U 

1.2.4-Trimethylbenzene -65 1.0 0.5 1.0 U 

1.3-Dichlorobenzene --.5 1.0 0.5 1.0 U 

1.4-Dichlorobenzene 0.5 1.0 0.5 1.0 U 


1,2,4-Trichlorobenzene 0.5 1.0 0.5 1.0 U 

,Hexachlorobutadiene 1 0.5 11.0 0.5 1.0 ------- L- U__j 

urro ate _LREC Control Limits Qualifi 

lBromofluorobenzene 94% 7 -125 


I AFCEE 

1775 61 ORGANICS ANALYSES DATA SHEET 2 

RESULTS 



Field Sample ID: 0003WWlGAC(IN) Lab Sample ID: 380604 Matrix-. Air 


Date Received: 03/31/00 Date Prepared: 04113/00 Date Analyzed: 04/13/00 20:13 


Analyte MDL RL Concentration Dilution Confirm Oualifier 

Dichlorodifluoromethane 0.5 1.0 0.5 1.0 F 


1,2-Dichloro, 1, 1,2,2-tetrafluoroethane 0.5 1.0 0.5 1.0 U 

Vinyl chloride 0.5 1.0 1.1 1.0 

Bromornethane 0.5 1.0 0.5 1.0 U 



1.1-Dichloroethene % 0.5 1.0 0.5 1.0 U 

Methylene chloride 0.5 1.0 19.0 1.0 

1,1.2-Trichloro-1,2,2-tdfluoroethane 0.5 1.0 0.5 1.0 U 

1,1-Dichloroethane 0.5 1.0 0.5 1.0 U 

cis-1,2-Dichloroethene 0.5 1.0 16.4 1.0 

Chloroform 0.5 1.0 3.5 1.0 

1.2-Dichloroethane 0.5 1.0 0.5 1.0 I U 

1,1,1-Tr'ichloroethane 0.5 1.0 0.5 1.0 U 


Benzene 0.5 1.0 0.5 1.0 U 

1.2-Dichloropropane 0.5 1.0 0.5 1.0 U 

Trichloroethene 0.5 1.0 I 6.6 1.0 

cis-1.3-Dichloropropene 0.5 1.0 0.5 1.0 U 



Toluene 0.5 1.0, 0.9 1.0 F 

1.2-Dibromoethane 0.5 1.0 0.5 1.0 U 



Ethylbenzene 0.5 1.0 0. 1.0 U 

mP-Xylenes 1.0 2.0 1 1.0 1.0 U 

Stvrene 0.5 1.0 0.5 1.0 U 

o-Xylene 1.0 0 1.0 U 

1.1.2.2-Tetrachloroethane 0.5 1.0 0.5 1.0 U 

1.3.5-Trimethylbenzene 0.5 1.0 0.5 1.0 U 


1,3-Dichlorobenzene 0.5 1.0 0.5 1.0 



1.2.4-Trichlorobenzene 0.5 1.0 0.5 1.0 U 

Hexachlorobutadiene 0.5 1.0 0.5 1.0 U 

FSurroate %REC Controll-irnits Qualif 

lBromofluorobenzene 

AFCEE FORM 0-2 Rev. 10/99

AFCEE 1 7 75 6 


RESULTS 

Analocal Method: TO-14 Preparatory Method: NA SDG N 3806 

LabName: CH2MHILLASL - Contract: 156470.02.08.03 .- 

FieldSarnpIeID:0003WW1GAC(INT) - LabSampleID: 380605 Matrix: Air 


Date Received: 03/31/00 Date Prepared: 04/13/00 Date Analyzed: 04/13/00 18:14 


Analyte IVIDL- RL Concentration Dilution Confirm Qualifier 

Bichlorodifluoromethane 0.5 1.0 0.5 1.0 F 


1.2-Dichloro,1.1.2.2-tetrafluoroothane 0.5 1.0 1:,5 1.0 U 

Vinyl chloride 0.5 1.0 1:. F 




11,11-Dichloroethene 0.5 1.0 0.5 1.0 LI 


1.1'.2-Trichloro-1.2,2-tdfluoroethane 0.5 1.0 0.5 1.0 U 

1,11 -Dichloroethane -1.0 0.5 1.0 U 

cis-1,2-Dichloroethene 1.0 4.3 1.0 

Chloroform 0.5 1.0 0.7 1.0 F 


11,11,11 -Trichloroelhane 1.0 0.5 1.0 LI 

Carbon tetrachloride 6--5- 1- 0 0.5 1.0 U 

Benzene 0.5 1.0 0.5 1.0 U 


Trichloroethene 1.0 0.5 1.0 U 



1,1.2-Trichloroethane 0. 0.5 1.0 U 

Tofuene 0.5 1.0 0-5 11,0 U 

T2-Dibromoethane 0.5 1.0 0.5 1.0 U 

Tetrachloroethene 0.5 1.0 0.5 1.0 U I 



mp-Xylenes 1.0 2.0 I 1.0 1.0 U 

Styrene 0.5 1.0 0.5 1.0 U 

o-Xylene 0.5 1.0 0.5 1.0 U 

1.1,2,2-Tatrachloroethane 0.5 1.0 0.5 1.0 U 


1.2.4-Trimethylbenzone 0.5 1.0 0.5 1.0 U I 


1.4-Dichlorobenzene 6 5 1 0 0.5 1.0 

1,2-Dichlorobenzone 0.5 1.0 0.5 1.0 

1.2.4-Trichlorobenzene 1.0 0.5 1.0 

Hexachlorobutadiene --6.5 1.0 0.5 I 1.0 

ISurroaate I %REC I Control Limits I QualiEE 

izene 88 5-125 


AFCEE 

-7 7 5 6 3 ORGANICS ANALYSES DATA SHEET 2 

RESULTS 



Field Sample ID: 0003WW1 GAC(OUT) Lab Sample ID: 380606 Matrix: Air 


Date Received: 03/31/00 Date Prepared: 04/13/00 Date Analyzed: 04/13/00 17:12 



Dichlorodifluoromethane 1.3 2.5 1.3 2.5 U 

Chloromethane 1.3 2.5 1.3 2.5 U 

1,2-Dichloro.1.1.2,2:tetrafluoroethane 1.3 2.5 1.3 2.5 U 





1.1-Dichloroethene 1.3 2.5 1.3 2.5 U 


1.1,2-Trichloro-1,2,g-tfifluoroethane 1.3 2.5 1.3 2.5 U 

1.1-Dichloroethane 1.3 2.5 1.5 2.5 F 

cis-1,2-Dichloroethi-ne- 1.3 2.5 6.1 2.5 

Chloroform 1.3 2.5 1.3 2.5 U 

1.2-Dichloroethane 1.3 2.5 1.3 2.5 1 U 

1.1.1-Tdchloroathane 1.3 2.5 1 1.3 2.5 U 


Benzene 1.3 2.5 1,3 2.5 U 






Toluene 1.3 2.5 1.3 2.5 U 


Tetrachloroethene 1.3 2.5 I 1.3 2.5 U 



mp-Xylenes 2.5 5.0 2.5 2.5 U 

Styrene 1.3 2.5 1.3 2.5 U 

o-Xylene 1.3 2.5 1.3 2.5 1 U 






1.2 1.3 2.5 1.3 2.5 

1.2 1.3 2.5 1.3 2.5 

lHexachlorobutadiene 1.3 2.5 1.3 I 2.5 U 

ISurroqate I %REC Control Limits Qualifier 

113romofluorobenzene 95% 75-125 


AFCEE 

ORGANICS ANALYSES DATA SHEET 2 1 7 75 6 4 

RESULTS 



FieldSampleID:0003WWIGAC(OUT)DUP LabSampleID: 380606D Matrix: Air 


Date Received: 03131/00 Date Prepared: 04/13/00 Date Analyzed: 04/13/00 19:12 


alyte MDL RL Concentration Dilution Confirm Qualifier 

ichlorodifluoromethane 1.T 2.5 1.3 2.5 U 

loromethane 1.3 2.5 113 2.5 U 

2-Dichloro. 1. 1.2.2-tetraf luoroethane 1-3 -- i-.5 - 1.3 2.5 U 

nyl chloride 1.3 2.5 1.3 2.5 U 

romomethane 1.3 2.5 1.3 2.5 U 

loroethane 1.3 2.5 1.3 2.5 U 

Tdchlorofluoromethane 1.3 2.5 1.3 2.5 U 



1, 1.2-Trichloro-1,2.2-trifluoroethane 1.5 .5 1.3 U 

1,1-Dichloroethane 1.3 2.5 1.5 F 

cis-1.2-Dichloroethene 1.3 :F5- 5 8 2.5 

Chloroform 1.3 2.5 I 1.3 2.5 U 


1,1.1-Tdchloroethane 1.3 2.5 1.3 2.5 U 


Benzene 1.3 2.5 1.3 2.5 U 





1.1.2-Trichloroethane 1.3 2.5 1.3 2.5 1 U I 

Toluene- 1.3 2.5 1.3 2.5 U 

1,2-Dibromoethane 1.3 2.5 2.5 U 

Tetrachloroethene 1.3 2.5 -1.3 2.5 U 



mp-Xylenes 2.5 5.0 2.5 2.5 U 

Styrene 1.3 2.5 1.3 2.5 U 

o-Xylene 1.3 2.5 1.3 2.5 1 U 

1,1,2,2-Tetrachloroethane 1.3 2.5 -1.3 2.5 U 

.13.5-Trimethvlbenzene 1.3 2.5 1.3 2.5 U 

1,2,4-Tdmethylbenzene 1.3 2.5 1.3 2.5 U 

1,3-Dichlorobenzene i 1.3 2.5 1.3 2.5 U 


1,2-Dichlorobenzene 1.3 i.-5 1.3 2.5 U 

1,2,4-Trichlorobenzene 1.3 2.5 1.3 2.5 

Hexachlombutadiene 1.3 2.5 1.3 2.5 UU 

Isurrooate %REC Control Limits Qua] 

zene 


i AFCEE 


RESULTS 



FieIdSampIeID:0003WW1GAC(0UT)R1 LabSampleID: 380606R1 Matrix: Air 


Date Received: 03131/00 Date Prepared: 04/17/00 Date Analyzed: 04/17/00 21:37 

Concentration Units: 


57ichlorodifluoromethane 0.5 1.0 0.5 1.0 F 


1.2-Dichloro,1,1,2,2-tetrafluoroethane 0.5 1.0 0.5 1.0 U 

Vinyl chloride 0.5 1.0 1.2 1.6 



Tdchlorofluoromethane 0.5 1.0 0.5 1.0 U 

1.1-Dichlomethene 0.5 1.0 0.8 1.0 

M 0.5 1.0 63.0 1.0 

1,1.2-Trichloro-1.2,2-tdfluomethane 0.5 1.0 0.5 1.0 U 

1.1-Dichloroethane 0.5 1.0 1.5 1.0 

cis-1,2-Dichloroothene 0.5 1.0 6.2 1.0 

Chloroform 0.5 1.0 0.5 1.0 U 


1.1.1-Tdchloroethane 0.5 1.0 I 0.5 1.0 U 

Carbon tetrachloride 0.5 1.0 OW5 1.0 U 

Benzene 0.5 1.0 0.5 1.0 U 


Trichloroethene 0.5 1.0 0.5 1.0 F 



1.1,2-Tdchloroethane 0.5 1.0 0.5 1.0 U 

Toluene - 0Z 1.0-- 0.5 -1.0 U 


TetraGhloroethene 0.5 1.0 1 0.5 1.0 U 

Chlorobenzene 0.5 1.0 0.5 1.0 

Ethylbenzene 0.5 1.0 0.5 1.0 tujU 

mp-XyIenes 1.0 2.0 1.0 1.0 U 

Styrene 1.0 0.5 1.0 U 

o-Xylene 0.5 1.0 0.5 1.0 U 


1.3.5-Trimethylbenzene 0.5 1.0 0.5 1.0 U 



1.4-Dichlorobenzene 0. 1.0 .5 1.0 U 

1,2-Dichlorobenzene Z- 1.0 0.5 1.0 I U 

-Trichlorobenz .5 

1.2.4 ene 5 

i UU 

Isurrooate %REC Control Limits I Qualifier I 

113romofluorobenzene 96% 75-125 _j --------- I 


AFCEE 1 7 75 6 6 

ORGANICS ANALYSES DATA SHEET 3A 

INITIAL MULTIPOINT CALIBRATION-GCIMS ANALYSIS 

Analytical Method: TO-14 SDG No.: 3806 


Instrument ID: GC/MS - G Calibration Date(s): 04/10/00 

Initial Calibration ID: 0410TO14 Concentration Units: ppbv 

COMPOUND RRF1 RRF2 RRF3 RRF4 RRF5 RRF6 AVE RRF RSDTQ 

Dichlorodifluoromethane 1.539 1.515 1.657 1.494 1.434 1.379 1.503 6.3 

Chloromethane 0.699 0.621 0.766 0.624 0.610 0.627 0.658 9.4 

1,2-Dichloro.1.1.2,2-tetrafluorooth 0.744 0.634 0.629 0.637 0.594 0.628 0.644 7.9 

Vinyl chloride 0.767 0.742 0.523 0.650 0.647 0.657 0.664 13.0 

Bromomethane 0.616 0.607 I 0.743 0.605 I 0.588 0.592 I 0.625 9.4 

Chloroethane 0.414 0.400 0.480 0.407 0.390 0.382 0.412 8.6 

Trichlorof luoromethane 1.348 1.321 1.581 1.328 1.263 1.230 1.345 9.2 

11,11-Dichloroethene 1.120 1.132 1.312 1.122 1.111 1.084 1.147 7.2 1 

Methylene chloride 1.008 0.864 1.027 0.865 0.846 0.833 0.907 9.5 

1,1,2-Trichloro-1.2.2-trifluoroetha 1.086 1.080 1.257 1.083 1.039 0.980 1.088 8.5 

1,1-Dichloroethane 1.176 1.186 1.407 1.215 1.195 1.154 1.222 7.6 

cis-1.2-Dichloroethene 0.855 0.882. 1.073 0.931 0.918 1 0. 84 0.924 1 8.5 

Chloroform 1.086 1.099 1.331 1.136 1.121 1.079 1.142 8.3 

1,2-Dichloroathane 0.756 0.775 0.998 0.852 0.861 0.825 0.844 10.2 

1,1,1-Trichloroethane 0.629 0.685 0.799 0.707 0.676 0.653 0.691 8.5 

Carbon tetrachloride 0.582 0.622 0.735 0.669 0.638 0.611 0.643 8.3 I 

Benzene 1.644 1.657 1.992 1.741 1.757 1.668 1.743 7.5 

1.2-Dichloropropane 0.156 0.153 0.182 0.162 0.153 0.139 0.157 9.0 

Trichloroethene 0.142 0.139 0.164 0.149 0.144 0.134 1 0.145 7.2 

cis-1,3-Dichloropropene 0.245 0.261 0.326 0.293 0.293 0.271 0.281 10.2 

trans-1,3-Dichloropropene 0.153 0.184 0.237 1 0.220 0.220 0.208 0.204 14.9 

1,1.2-Trichloroethane 0.107 0.114 0.137 0.124 0.121 0.115 0.120 8.7 

Toluene 0.355 0.369 0.430 0.386 0.389 0.365 0.382 7.0 

1,2-Dibromoethane 0.131 0.155 0.191 0.185 0.184 0.173 0.170 13.3 

Tetrachloroethene 0.127 0.130 0.157 0.140 0.139 0.131 0.138 8.0 

Chlorobenzene 0.354 0.420 0.371 0.378 -0.363 0.371 7.2, 

-fft-hyIbWii;e 0.579 0.585 0.693 0.617 0.630 I 0.592 0.616 6.9 

m.o-XvIenes 0.431 0.457 I 0.543 0.478 0.469 0.417 0.466 9.4 

S!yrene 0.209 0.248 0.334 I 0.305 0.335 0.322 0.292 17.8 

o-Xylene 0.431 0.410 0.489 0.421 0.413 0.364 0.421 9.6 

1.1.2.2-Tetrachloroethane 0.235 0.271 0.332 0.296 0.292 0.255 0.280 12-1 

1,3,5-Tdmethylbenzene 0.292 0.323 0.378 0.346 0.350 0.334 0.337 8.5 

1,2.4-Tdmethylbenzene 0.259 0.305 0.363 0.342 0.377 0.364 0.335 13.4 

1,3-Dichlorobenzene 0.124 0.171 0.246 0.254 0.297 0.281 0.229 29.5 

1.4-Dichlorobanzene 0.243 0.246 0.263 0.269 0.300 1 0.315 1 0.273 10.6 

1,2-Dichlorobenzene 0.122 0.163 0.196 0.202 0.237 0.244 0.194 23 9 

1,2.4-Trichlorobenzene 0.074 0 073 0:070 0. 076 0.111 0.134 0.090 29.3 

1 Hexachlorobutacliene 0.125 0:103 0051 .090 --- 6.104 0.108 0.102 13.8 

romofluorobenzene 0.147 0.173 0.184 1 0.204 0.220 0.227 0.193 15.7 

Compound exceeded maximum %RSD value. 

AFCEE FORM O-3A Rev. 10/99

AFCEE 

7 7 5 6 7 ORGANICS ANALYSES DATA SHEET 4 

SECOND SOURCE CALIBRATION VERIFICATION 

Analytical Method: TO-1 4 SDG No.: 3806 

Lab Name: CI-12M HILL AS L Contract: 156470.02.08.03 

Instrument ID: GC/MS - G lnitia[Cali6rationfD: 0410TO14 

2ndSourceID: ICV-0410 Concentration Units: ppbv 

Analyte Expected Found %D Limits Qualifier 

Dichlorodifluoromethane 50 47.8 -4% 25 

Chloromethane 50 54.8 10% 25 

1,2-Dichlom,1,1,2,2-tetrafluoroethane 50 51.1 2% 25 

Vinyl chloride 50 56.6 13% 25 

Bromomethane 50 45.3 -9% 25 

Chloroethane 50 50.2 0% 25 

Trichlorofluoromethane 50 49.3 -1% 25 

1,1-Dichloroethene 50 48.6 -3% 25 

Methylene chloride 50 46.1 -8% 25 

1.1.2-Trichloro-1.2,2-tdfluamethane 50 48.2 -4% 25 

1.1-Dichloroethane 50 49.7 -1% 25 

cis-1,2-Dichloroethene 50 48.5 -3% 25 

Chloroform 50 48.6 -3% -25 

1,2-Dichloroethane 50 49.2 -2% 25 

1,1.1-Trichlomethane 50 1 47.5 -5% 25 

Carbon tetrachlorld 50 48.6 -3% -25 

Benzene 50 49.0 -2% 25 

1.2-Dichloropropane 50 50.2 0% 25 

Trichloroethene 50 49.0 -2% 25 

cis-1,3-Dichloropropene 50 38.8 -22% 25 

trans-1.3-Dichloropropene 50 38.1 -24% 25 

1.1,2-Trichlomethane 50 52.3 5% i 25 

Toluene 50 I 49.7 -1% 25 

1.2-DibromGethane 50 49.9 0% 25 

Tetrachloroethene 50 52.3 5% 25 

hlorobenzene 50 51.9- - 4%- -- 25-- 

Ethylbenzene 50 52.9 6% 25 

mp-Xylones 100 101.9 2% 25 

Styrene 50 57.4 15% 25 

o-Xylene 50 48.3 -3% 25 

1,1.2,2-Tetrachloroethane so 53.4 7% 25 

1,3.5-Trimethylbenzone 50 1 49.7 -11% 25 

1,2,4-Trimethylbenzene 50 51.1 2% 25 

1,3-Dichlorobenzene 50 49.2 -2% 5 

1.4-Dichlombenzene 50 44.1 -12% 25 

1,2-Dich(orobenzene 50 48.2 -4% 25 

1,2.4-Trichlorobenzene 50 38.2 -24% 25 

Hexachlorobutadiene 50 51.2 2% 25 

Isurrogate %REC I Control Limits Qualifi 

lBromofluorobenzene 99% 75-125 E 

AFCEE FORM 0-4 -12- Rev. 10199

AFCEE 1 7 75 6 

ORGANIC ANALYSES DATA SHEET 5A 

CALIBRATION VERIFICATION-GC/MS ANALYSIS 



Instrument ID: GC/MS - G InitialCalibrationID: 0410TO14 

Cal. Ver. ID: CV11_0411 

AVE CCV MAX 

COMPOUND RRF RRF %D %D Q 

Dichlorodifluoromethane 1.503 1.432 4.7 25 

Chloromethano 0.658 0.555 15.8 25 

1,2-Dichloro.1.1.2.2-tetrafluoroet 0.644 0.562 12.7 25 

Vinyl chloride 0.664 0.576 13.3 25 

Bromomethane 0.625 0.569 1 9.0 25 

Chloroethane 0.412 0.400 2.9 25 

Tdchlorofluoromethane 1.345 1.282 4.7 25 

1,1-Dichloroethene 1.147 1.093 4.7 25 

Methylene chloride 0.907 0.881 2.9 25 

1.1,2-Trichloro-1,2,2-triflu(iroetha- 1.088 1.063 2.3 25 

11,11-Dichloroethane 1.222 1.238 -1.3 25 

cis-1,2-Dichloroethene 0.924 0.964 -4.3 25 

Chloroform 1.142 1.188 -4.0 25 


1,1,1-Trichloroethane 0.691 0.715 -3.5 25 

Carbon tetrachloride 0.643 0.669 -4.0 25 

Benzene 1.743 1.787 -2.5 25 

1,2-Dichloropropane 0.157 0.169 -7.6 25 

Trichloroethene 0.145 0.154 -6.2 25 

cis-11,3-Dichloropropene 0.281 0.305 -8.5 25 

trans-1,3-Dichloropropene 0.204 0.228 1 -11.8 25 

1.1.2-Trichlorcethane 0.120 0.127 -5.8 25 

Toluene 0.382 0.398 -4.2 25 

j,2-Dibromoethane 0.170 0.192 -12.9 25 

Tetrachloroethene 0.138 0.142 -3.6 25 

Chlorobenzene 0.371 0.383 -3.2 25 

Ethylbenzene 0.616 0.639 -3.6 25 

mp-Xylenes 0.466 0.495 -6.2 25 

Styrene 0.292 0.332 -13.7 25 1 

o-Xylene 0.421 0.430 -2.1 25 

1.1.2.2-Tetrachloroethane 0.280 0.307 -9.6 25 

1.3.5-Trimethylbenzene 0.337 0.358 -6.2 25 

1,2,4-Trimethylbenzone 0.335 0.351 -4.8 25 

.3-Dichl.orobenzene 1 

0.229 0.265 -15.7 25 

1,4-Dichlorobenzene 0.273 0.283 -3.7 25 


0.090 -6.085 5.6 

1,2,4-Trichlorobenzene 5 

Hexachlorobutacliene 0.1021 0.096 5.9 25 

Bromofluorobenzene 0.1931 0.200 1 -3.6 25 

Compound exceeded maximum %D value. 

AFCEE FORM O-5A -13- Rev. 10/99

AFCEE 

17 7 5 6 9 ORGANIC ANALYSES DATA SHEET 5A 


AnalyticalMethod: TO-14 SDG No.: 3806 


Instrument ID: GC/MS - G Initia[CalibrationID: 0410TO14 

Cal. Ver. ID: CVI-0413 

AVE CCV MAX 

COMPOUND RRIF RRF %D %D Q 

Dichlorodif luoromethane 1.503 1.466 2.5 25 

Chloromethane 0.658 0.628 4.6 25 

1,2-Dichloro, 1.1.2,2-tetrafluoroet 0.644 0.607 5.7 25 


Bromomethane 0.625 0.592 5.3 25 1 

Chloroethane 0.412 0.403 2.2 25 

Tdchlorofluoromethane 1.345 1.355 -0.7 25 

1,1-Dichloroethene 1.147 1.138 0.8 25 


1,1,2-Trichloro-1,2,2-trffluoioetha 1.088 1.110 -2.0 25 

1,1-Dichloroothane 1.222 1.234 -1.0 25 


Chloroform 1.142 1.164 -1.9 25 



Carbon tetrachloride 0.643 0.722 1 -12.3 25 

Benzene 1.743 1.765 -1.3 25 

1,2-Dichloropropane 0.157 0.164 -4.5 25 



trans-1,3-Dichloropropene 0.204 0.222 -8.8 25 

1,1.2-Trichloroothane 0.120 0.127 -5.8 25 

Toluene 0.382 0.394 -3.1 25 

-12-gibromoethane 0.170- -0.188 .-- 10.6 25 

Tetrachloroethene 0.138 0.136 0.7 25 

Chlorobenzene 0.371 0.365 1.6 25 

Ethylbenzene 0.616 0.623 -1.1 25 

mp-Xylenes 0.466 0.485 -4.1 25 

Styrene 0.292 0.307 -5.1 25 

o-Xylene 0.421 0.432 -2.6 25 

1,1,2,2-Tetrachloroethane 0.280 0.298 -6.4 25 

1,3,5-Trimethylbenzene 0.337 0.346 -2.7 25 

1,2,4-Trimethylbenzene 0.335 0.344 -2.7 25 



1,2-Dichlorobenzene 0.194 0.192 1.0 25 

1,2,4-Tdchlorobenzene 0.090 0.078 13.3 25 

Hexachlorobutadiene 0.102 0.077 24 

Bromofluorobenzene -512 


AFCEE FORM O-5A -14- Rev. 10/99

AFCEE 1 7 75 7 0 





Instrument ID: GC/MS - G Initial Calibration ID: 0410TO14 

Cal. Ver. ID: CV1_0417 

AVE CCV MAX 

COMPOUND ARF RRF %D % D Q 

Dichlonadifluoromethane 1.503 1.429 4.9 25 


1.2-Dichloro,1,1,2,2-tetrafluoroet 0.644 0.536 16.8 25 


Bromomethane 0.625 0.579 7.4 25 

Chloroethane 0.412 0.412 0.0 25 

Trichlorofluoromethane 1.345 1.294 3.8 25 

1,1-Dichloroethene 1.147 1.155 -0.7 25 


1,1,2-Trichloro-1,2 2trifluometha 1.088 1.080 0.7 25 



Chloroform 1.142 1.154 -1.1 25 1 

1.2-Dichloroethane 0.844 0.860 1 -1.9 25 


Carbon tetrachloride 0.643 0.685 -6.5 25 

Benzene 1.743 1.829 -4.9 25 

1,2-Dichlorop 0.157 0.174 -10.8 25 



trans-1.3-Dichl 0.204 0.234 -14.7 25 1 

1.1,2-Trichloroethane 0.120 0.131 -9.2 25 

Toluene 0.382 0.413 1 -8.1 25 

2-Dibromoethane 0.170 0.194 -14.1 25 

Tetrachloroethene 0.138 0.150 -9.5 25 

Chlorobenzene 0.371 0.374 -0.8 25 

Ethylbenzene 0.618 0.643 -4.4 25 

mp-Xylenes 0.466 0.480 -3.0 25 

Styrene 0.292 0.296 -1.4 25 1 

o-Xylene 0.421 0.411 2.4 25 

1. 1,2,2-Tatrachloroothane 0.280 0.285 -1.8 25 

1,3,5-Trimethylbenzene 0.337 0.334 0.9 25 

1,2,4-Trimethylbenzene 0.336 0.335 0.0 25 

1.3-Dichlorobenzene 0.229 0.243 -5.7 25 



1.2,4-Tdchlorobenzene 0.090 0.088 :2 1 2: 

Hexachlorobutadiene 0.102 0.083 6 2 

Bromofluorob nzene 0.193 0.190 1.6 1 25 1 


AFCEE FORM O-5A Rev. 10/99

AFCEE 


17 7 5 7 1 BLANK 



Field Sample ID: B1 0410 Lab Sample ID: Bl-"10 Matrix: Air 


Date Received: NA Date Prepared: 04110100 Date Analyzed: 04/10/00 11:46 


Analyte IVIDL RL Concentration Dilution Confirm Qualifier 

Fichlorodifluoromethane 0.5 1.0 0.5 1.0 U 

Chloromethane ' 0.5 1.0 0.5 1.0 U 

1,2-Dichloro,1,1,2.2-tetrafluoroethane 0.5 1.0 0.5 1.0 U 






Methylene chloride 0.5 1.0 0.5 1.0 U 

1.1.2-Trichloro-1,2,2-tdfluoroethane 0.5 1.0 0.5 1.0 U 


cis-1,2-Dichloroethene 0.5 1.0 0.5 1.0 U 

Chloroform 0.5 1.0 0.5 1.0 U 

1,2-Dichloroethane 0.5 1.0 0.5 1.0 I U 

1.1.1 -Trichloroethane 0.5 1.0 0.5 1.0 U 


Benzene 0.5 1.0 I 0.5 1.0 U 





1,1.2-Trichloroethane 0.5 1.0 0.5 1.0 U 

Toluene 0.5 - 1,0 - 0.5 10 _U 

1,2-Dibromoethane 0.5 1.0 0.5 1.0 U 

Tatrachloroethene 0.5 1.0 1 0.5 1.0 U 



mP-Xylenes 1.0 2.0 1.0 1.0 U 

Styrene 0.5 1.0 0.5 1.0 I U 

O-Xylene 0.5 1.0 0.5 1.0 U 

1,1,2,2-Tetrachloroethane 0.5 1.0 0.5 1.0 U 


1,2,4-Trimethvlbenzene 0.5 1.0 I 0.5 1.0 U 

1.3-Dichlorobenzene 0.5_ 1.0 0.5 1.0 U 

1,4-Dichlorobenzene 0.5 1.0 U 

1,2-Dichlorobenzene 0.5 1.0 U 

1,2,4-Tdchlorobenzene 0.5 1.0 U 

Hexachlorobutadiene 0.5 1.0 

ISurrouate %REG Control Limits Qualifi 

lBromofluorobenzene 82% 75-125 

AFCEE FORM 0-6 -16- Rev. 10199

AFCEE 5 7 2 


BLANK 

Analytical Method: TO-1 4 Preparatory Method: NA SDG N 3806 

LabName: CH2MHILLASL Contract: 156470.02.08.03- 

Field Sample ID: Bl-0411 LabSamplaID: 811_W11 Matrix: Air 


Date Received: NA Date Prepared: 04/11/00 Date Analyzed: 04/11/00 15:12 





1,2- Dichloro,1.1,2,2-tetrafluoroethane 0.5 1.0 0.5 1.0 U 





1,11-Dichloroethene 41 0.5 1.0 0.5 1.0 U 


1.1,2-Trichloro-1.2,2-t(ifluoroethane 0.5 1.0 0.5 1.0 U 

1,1-Dichloroothane .0.5 1.0 0.5 1.0 U 

cis-1.2-Dichloroethene 0.5 1.0 0.5 1.0 U 

Chloroform 0.5 1.0 0.5 1.0 U 

1,2-Dichloroethane 0.5 1.0 1 0.5 1.0 I U 

1.1.1 -Trichloroethane 0.5 1.0 0.5 1.0 U 


Benzene 0.5 1.0 0.5 1.0 U 

1.2-Dichlompropane 0.5 1.0 0.5 1.0 U 

T.richloroethene 0.5 1.0 0.5 1.0 U 

Ts-11,3-Dichloropropene 0.5 1.0 0.5 1.0 U 

trans-1,3-Dichloropror)ene 0.5 1.0 0.5 1.0 U 

112-Trichloroethan 0.5 1.0 0.5 1.0 U 

Toluene 'i -1.0 0.5 1.0 I U 

1,2-Dibromoethane 0.5 1.0 0.5 1.0 U 




MP-Xylenes 1.0 2.0 1.0 1.0 U 

Styrene 0.5 1.0 0.5 1.0 U 

o-Xylene 0.5 1.0 0.5 1.0 U 

1.1,2,2-Tetrachloroethane 0.5 1.0 .0.5 1.0 I U 



1.3-Dichlorobanzene 0.5 1.0 0.5 1.0 U 

1.4-Dichlorobanzone 1.0 0.5 1.0 U 


11,24-Trjiocrh lorobdenzen 9 0.5 1.0 0.5 1.0 U 

!He ach obuta iene 1 0.5 1.0 0.5 1.0 U 

urroate I %REC Controll-imits Qual 



AFCEE 


BLANK 



Field Sample ID: B1-N13 Lab Sample ID: B1_0413 Matrix: Air 


Date Received: NA Date Prepared: 04/13100 Date Analyzed: 04/13/00 12:48 





1,2-Dichloro,1,1,2,2-tetrafluoroethane 0.5 1.0 0.5 1.0 U 




Tdchlorofluoromethane 0.5 1.0 0.5 1.0 I U 

1,1-Dichloroethene 4, 0.5 1.0 0.5 1.0 I U 


1,1 2-Trichloro-1,2,2-trifluoroethane 0.5 1.0 0.5 1.0 U 


cis-1,2-Dichloroethene 1.0 0.5 1.0 U 

Chloroform 0.5 1.0 0.5 1.0 U 


1.1,1-Trichloroethane 0.5 1.0 0.5 1.0 U 

Carbon tetrachloride 0.5 1.0 1 0.5 1.0 U 

Benzene 0.5 1.0 0.5 1.0 U 



cis-1,3-Dichloropropem 0.5 1.0 0.5 1.0 U 

trans-1,3-Dichloropror)ene 0.5 1.0 0.5 1.0 U 

1,1,2-Trichloroothane 0.5 1.0 0.5 1.0 U 

Toluene 0.5 1.0 0.5 1 .0, I - U 

1,2-Dibromoethane 0.5 1.0 I 0.5 1.0 U 




mD-Xvlenes 1.0 2.0 1.0 1.0 U 

Styrene 0.5 1.0 0.5 1.0 U 

o-Xylene 0.5 1.0 0.5 1.0 I U 

1,1,2,2-Tetmchloroethane 0.5 1.0 0.5 1.0 I U 





111:2'DiTch zene 0.5 1.0 0.5 1.0 U 

2.4_ ri = enzene 0.5 1.0 0.5 1 1.0 U 

IHexachlorobutadiene 0.5 1.0 0. U 

]Surrouate I %REC I Control-Limits I Qualifi 

lBromofluorobenzene 77% 1 75-125 1 

AFCEE FORM 0-6 Rev. 10199

AFCEE 

ORGANICS ANALYSES DATA SHEET 6 1 7 75 7.4 

BLANK 



Field Sample ID: B1 -0417 Lab Sample ID: Bl-0417 Matrix: Air 

% Solids NA Initial Calibration ID: 041 OTO 1 4 

Date Received: NA Date Prepared: 04/17100 Date Analyzed: 04/17/00 11:56 





1.2-Dichloro.1,1.2.2-tetrafluoroethane 0.5 1.0 0.5 1. U 

Vinyl chloride 1.0 0.5 1.0 U 


Chloroethane 0 5 0.5 1.0 U 

Trichlorofluoromethane 0.5 1 0.5 1.0 U 



1,1,2-Trichloro-1.2.2-tdfluoroethane 0.5 1.0 0.5 1.6-- U 


cis-1,2-Dichloroethn-e 0.5 -10 0.5 1.0 U 

Chloroform 0.5 1.0 0.5 1.0 U 

1. -Dichloroethane 0.5 1.0 0.5 1.0 U 

1.1.1-Tdchloroothane 0.5 1.0 0.5 1.0 U 

Carbon tetrachloride 0,5 1.0 0.5 1.0 U 

Benzene 0.5 1.0 0.5 1.0 U 

.12-Dichloropropane 0.5 1.0 0.5 1.0 U 



trans-1.3-Dichloropropene 

1,1.2-Tdchloroethane 

0.5 1.0 

-10 

0.5 

0.5 

1.0 

1.0 I 

U 

U 

TOILlens - - 0, 1.0 0 5 1.0 U 

1,2-Dibromoethane -1. 0 0.5 1.0 I U 

Tetrachlomethene 0.5 1.0 0.5 1.0 U 


Ethylbenzene 0.5 1 0 0.5 1.0 U 

m P-Xylenes 1.0 2:0 1.0 1.0 U 

Styrene 

o-Xylene 

0.5 

0.5 

1.0 

1.0 

0.5 

0.5 

1.0 

1.6 

U 

1.1.2.2-Tetrachloroothane 0.5 1.0 0.5 1.0 I U 




1.4-Dichlorobanzone 0.5 1.0 0.5 1.0 U 

1 2-Dich= 0ebnzene 

11 12.4_Tfl nzene 

0 --5 1 1.0 

0-5-L- 1 -o 

1 

0.5 

0.5 

1.0 

1.0 

U 

U 

IHexachlorobutadiene 0.5 1 1.0 1 0.5 1.0 U 

Fau:rro ate 


,REC 

76 

Control Li Itself Qualif 

75-125 1 E::] 


AFCEE 


LABORATORY CONTROL SAMPLE 



Lab Sample ID: BSlAO411 InitialCalibrationID: 0410TO14 


Anatyte Expected Found %R Limits Qualifier 

E7ichlorodifluoromethane 20 19.3 96 75 - 125 

Chloromethane 20 17.1 85 75 - 125 

1,2-Dichloro,1,1,2,2-tetFafiuoroethane 20 17.7 88 75 - 125 

Vinyl chloride 20 17.6 88 75 - 125 

Bromomethane 

Chloroethane 

20 

20 

19.4 

19.6 

97 

98 

75 - 125 

75 - 125 

TrIchlorofluoromethane 20 19.4 97 175 - 125 

1.1-Dichloroethene 

Methylene chloride 

20 

20 

19.4 

19.5 

97 

97 

75 - 125 

75 - 125 

1.1.2-Tdchloro-1,2,24rifluoroethane 20 19.8 99 75 - 125 

1.1-Dichloroethane 20 20.2 75 - 125 

cis-1,2-Dichloroethene 20 20.6 103 75 125 

Chloroform 

1.2-Dichloroethane 

20 

20 

21.0 

20a6 

105 

103 

75 - 125 

75 - 125 

1.1,1 -Trichloroethane 

Carbon tetrachloride 

20 

20 1 

20.9 

21.1 

105 

106 

72 - 125 I 

72 - 125 

Benzene 

1,2-Dichloropropane 

Trichloroethene 

20 

20 

20 

20.5 

21.2 

20.8 

102 

106 

104 

75 - 127 

75 - 125 

75 - 125 

cis-1,3-Dichloropropene 

trans-1,3-Dichloropropene 

1,1,2-Tdchloroethane 

20 

20 

20 

21.7 

22.3 

21.4 

109 

111 

107 

75 - 125 

75 - 125 

75 - 125 

Toluene 20 21.0 105 75 - 125 

1.2-Dibromoethane 20 I 22.8 114 74 - 125 

Tetrachloroethene 20 20.7 103 75 - 125 

Chlorobenzena 

Ethylbenzene 

20 

20 

20.6 

20.6 

103 

103 

75 - 125 

75 - 125 

M.13-XvIenes 40 42.3 106 75 - 125 

Styrene 20 22.9 114 i 75 - 135 

o-Xylene 20 20.3 101 175 - 137 

1, 1,2,2-Tetrachloroethane 20 22.1 110 175 - 125 

1,3,5-Trimethylbenzene 20 21.5 107 75 - 125 

1,2.4-Tdmethylbenzene 20 21.9 110 75 - 125 

1,3-Dichlorobenzene 

1,4-Dichlorobenzene 

20 

20 

22.9 

21.0 

115 

105 

75 - 

-125 

125 

75 

1.2-Dichlorobenzene 20 22.3 112 75 - 125 

1,2,4-Tdchlorobenzene 20 20.9 104 75 - 125 

Hexachlorobutadiene 20 18.6 __L 93 75 - 125 

ISurrooate %REC I Control Limits Qual 

lBromofluorobenzone 105% 75-125 


AFCEE 1 7 75 76 





Lab Sample ID: BS2AO413 Initial Calibration ID: 0410TO14 


Analyte Expected Found %R Limits Qualifier 

Dichlorodifluoromethane 20 21.0 105 75 - 125 

Chloromethane 20 19.6 98 - 125 

1,2-Dichloro.1.1,2,2-tetrafluoroethane 20 20.7 104 75 - 125 

Vinyl chloride 20 20.2 101 75 - 125 

gromornethane 20 19.6 98 75 - 125 

Chloroethane 20 20.1 101 75 - 125 

Trichlorofluoromethane '20 20.8 104 75 - 125 

11,11-Dichloroethene 20 20.5 102 75 - 125 

Methylene chloride 20 20.2 101 75 - 125 

1,1,2-Tribhloro-1.2,2-trifluoroethane 20 21.2 106 75 - 125 

1.1-Dichloroethane 20 21.2 106 75 - 125 

cis-1,2-Dichloroethene 20 21.3 106 75 - 125 

Chloroform 20 21.2 106 75 - 125 

.12-Dichloroethane 20 22.1 110 75 - 125 

1,11,11 -Trichloroethane 20 1 22.8 114 172 - 125 

Carbon tetrachloride 20 23.1 115 72 - 125 

Benzene 20 21.4 107 75 - 127 

1.2-Dichloropropane 20 21.7 109 75 - 125 

Trichloroethene 20 21.3 106 75 - 125 

cis-1,3-Dichloropropene 20 21.9 110 75 - 125 

trans-1,3-Dichloropropene 20 22.8 114 75 - 125 

1,1,2-Tdchloroethane 20 22.4 112 75 - 125 

Toluene 20 I 22.0 110 75 - 125 

.12-Dibromoethane 20 23.0 115 74 - 125 

Tetrachloroethene 20 20.8 104 75 - 125 

Chlorobenzene 20 21.0- 105 75 - 125 

Ethylbenzene 20 21.9 109 75 - 125 

rn.p-Xylenes 40 45.2 113 75 - 125 

Styrene 20 22.4 112 175 - 135 

o-XvIene 20 22.3 112 175 - 137 

1,1,2,2-Tetrachloroethane 20 1 23.1 116 75 - 125 

1.3,5-TrimethVibenzene 20 22.1 110 75 - 125 

1,2,4-Trimethylbenzene 20 22.8 114 75- 125 

1.3-Dichlorobenzone 20 23.9 120 75- 125 

1,4-Dichlorobenzene 20 21.5 108 75 - 125 

1,2-Dichlorobenzene 20 22.3 112 75- 125 

1.2.4-Tdchlorobenzene 20 20.8 104 75 - 125 

Hexachlorobutacliene 20 15.5 1 78 1 -125 

4u:rro ate %REC Control Limits Quall 

lBromofluorobenzene 110% 75-125 1 


AFCEE 




LabName: CH2MHILLASL Contract: .156470.02-08.03 

Lab Sample ID: BSIA0417 Initial Calibration ID: 0410TO14 


nalyte Expected Found %R Limits Qualifier 

ichlorodifluoromethane 20 20.2 101 175 - 125 

loromethane 20 20.9 105 75 - 125 

Dichloro, 1. 1.2.2-tetrafluoroethane 20 16.8 84 75 - 125 

nyl chloride 20 20.9 104 75 - 125 

ethane 20 22.5 112 75 - 125 

loroethane 20 23.6 118 75 - 125 

lorofluoromethane 20 22.4 112 75 - 125 

11,11-Dichloroethene 20 Z3.4 117 75 - 125 

Methylene chloride 20 23.3 117 75 - 125 

I'll 2-Trichloro-1.2,2-trifluoroetharle 20 23.5 117 175 - 125 

1,1-Dichloroethane % 20 24.2 121 75 - 125 

cis-1,2-Dichloroethene 20 24.6 123 75 - 125 

Chloroform 20 23.9 120 75 - 125 

1,2-Dichloroethane 20 1 23.8 119 7i - 125 

1.1.1-Trichloroethane 20 24.7 123 72 - 125 

Carbon tetrachloride 20 24.7 123 72 - 125 

Benzene 20 24.7 123 7i - 127 

1.2 Dichloropropane 20 22.9 114 75 - 125 

Trichloroethene 20 21.4 107 75 - 125 

cis-1,3-Dichloropropene 20 23.1 116 75 - 125 

trans-1,3-Dirhiorapropene 20 23.5 117 75 - 125 

1,1,2-Trichloroothane 20 I 22.6 113 75 - 125 

Toluene 20 21.9 110 75 - 125 

1.2-Dibromoothane 20 23.4 117 74 - 125 

Tetrachloroethene 20 22.1 110 T5 - 125 

hlorobenzene 20 20.9 105 75 - 125 

Ethylbenzene 20 21.5 108 75 - 125 

m.D-Xvienes 40 42.5 106 75 - 125 

Styrene 20 21.5 107 75 - 135 

o-Xylene 20 I 20.4 102 75 - 137 

1.1,2.2-Tetrachloroethane 20 21.6 108 75 - 125 

1.3.5-Trimethylbenzene 20 20.7 104 75 - 125 

1,2,4-Trimethylbenzene 20 21.0 105 75 - 125 




1,2;4 Triohlorobdrizene 20 18.4 92 75 - 125 

!He ah obuta iene 1 20 15.7 79 75 - 125 

Isurrogate %PIEC Control Limits Qualifi 

lBromofluorobenz 5-125 K 


AFCEE 1 7 75 7 8 


DUPLICATE SAMILE SUMMARY 

ArWytical Method: TO-14 AAB#: 3806 

Lab Native: CH2M[ Hill ASL Contract #: 156470.02.08.03 

Field Sample 11) 0003WWIGAC(OUT) Initial Calibration ID: 0410TO14 


Analyte Original Duplicate 

Smplc Result Sample Result %RPD Control Linfits Q 

Dichlorindifluoromethame 2.5 U 2.5 U NA do% 

Chlorcitnediane 2.5 U 2.5 U NA

7 7 5 7 9 

AFCEE 

ORGANIC ANALYSES DATA SHEET 9 

HOLDING TIMES 

Analytical Method: TO-14 AAB#: 3806 

LabNarne: CH2MHILLASL Contract#: 156470.02.08.03 

Field Sample ID Date 

Collected 

Date 

Received 

Date Max. 

Extracted Holding 

Time Held 

Ext. 

Date 

Analyzed 

Max. 

Holding 

Time Held Q 

Anal. 

Time Time 

01 0003LF02GAC(IN) 3/30/2000 3/31/2000 14 4/13/00 14 14 

020003LF02GAC(INT) 3/30/2000 3/31/2000 14 4/11/00 14 12 

03 0003LF02GAC(OUT) 3130/2000 3/31/2000 1 4 4/13100 1 4 1 4 

040003WWlGAC(IN) 3/30/2000 3/31/2000 1 4 4/13100 1 4 1 4 

'5100'0= 11 rGA (INT) 

06 

00 ACC(OUT) 

0610003WWlGAC(OUT)Rl 

13 30/2000000133/131/2000 

3/30/2 3 

J/ 

2000 i 

13/30/200013/31/20001 

'4 

14 

1 4 

1 

1 

4//1 

4 13100 

3/00 

I 

1 4/17/00 

14 

14 

1 4 

14 

14 

18 

AFCEE FORM 0-9 24- Rev. 10/99

AFCEE 1 7 75 8 0 

ORGANIC ANALYSES DATA SHEET 1 0 

VOLATILE ORGANIC INSTRUMENT PERFORMANCE CHECK (BFB) 

Analytical Method: TO-14 SDG No.3806 

Lab Name: CI-12M HILL ASL Contract: 156470.02.08.03 

Instrument ID: GC/MS - G BFBinjectionDate: 04/10/00 

SAS No.: 041 OT01 4 BFB Injection Time: 09!09 

Lab File ID: CV1 -041 0 

% RELATIVE 

m/a ION ABUNDANCE CRITERIA ABUNDANCE 

50 15.0 - 40.0% of mass 95 21.0 

75 30.0 - 60.0% of mass 95 50.4 

95 Base peak, 100% relative abundance 100.0 

96 5.0 - 9.0% of mass 95 7.1 

173 Less than 2.0% of mass 174 0.0 

174 50.0 - 1 00.0% of mass 95 64.8 

175 5.0 - 9.0% of mass 174 6.9 

176 95.0 - 1 0 1.0% of mass 174 96.1 

177 5.0 - 9.0% of mass 176 6.3 

THIS CHECK APPLIES TO THE FOLLOWING SAMPLES, MS, MSD, BLANKS, AND STANDARDS: 

EPA LAB LAB DATE TIME 

SAMPLE NO. SAMPLE ID FILE ID ANALYZED ANALYZED 

01 BI-0410 131 0410 131-0410.1) 04/10100 11:46 

02 1 PPBV SM LEVEL1 2 LEVEI-1 2.1) 04110100 18:18 

03 6 PPBV STD LEVEL2 LEVEL2.D_ 04/10/00 19:15 

04 10 PPBV STD LEVEL3 LEVEI-3.1) 04/10/00 20:01 

05 20 PPBV STD LEVELA LEVELAD 04110100 2015L1.14 

LEVEI-5.1) /i 6Foo I 21:41 

071 10OPPBVSTD LEVEL6 LEVEI-6.1) 04110100 22:31 

AFCEE FORM 10 Rev. 10/99

AFCEE 

77 5 8 1 ORGANIC ANALYSES DATA SHEET 10 




Instrument ID: GC/MS - G BFBInjectionDate: 04/11/00 

SAS No.: 041 OT01 4 BFBInjectionTime: 11:58 

Lab File ID: CV1_0411 

% RELATIVE 

m/e ION ABUNDANCE CRITERIA ABUNDANCE 

50 15.0 - 40.0% of mass 95 22.1 

75 30.0 - 60.0% of mass 95 48.8 

95 Base peak, 1 00% relative abundance 100.0 

96 5.0 - 9.0% of mass 95 6.8 


174 50.0 - 1 00.0% of mass 95 63.2 

175 5.0 - 9.0% of mass 174 7.1 

176 95.0 - 101.0% of mass 174 96.1 

177 5.0 - 9.0% of mass 176 6.5 




01 CV1-0411 CV1 0411 CV1 041 1.13 04/11/00 11:58 

02 BSIA0411 BSIA0411 BSIIA04111.1) 04/11/00 12:57 

03 B1-0411 BI 0411 B1 041111.1) 04/11/00 15:12 

04 0003LF02GAC(INT) 380602 380602.1) 04/11/00 17:27 

AFCEE FORM 10 Rev. 10199 

-26-

AFCEE 1 7 75 8 2 



Analytical Method7 TO-14 SDG No.3806 


Instrument ID: GC/MS - G BFB Injection Date: 04/13/00 

SAS No.: 0410TO14 BFB Injection Time: 08:20 


% RELATIVE 


50 15.0 - 40.0% of mass 95 23.3 

75 30.0 - 60.0% of mass 95 50.8 

95 Base peak, 1 00% relative abundance 100.0 

96 5.0 - 9.0% of mass 95 7.1 


174 50.0 - 1 00.0% of mass 95 55.9 

175 5.0 - 9.0% of mass 1 4 7.1 

176 95.0 - 101.0% of mass 174 98.6 

177 5.0 - 9.0% of mass 176 6.4 




01 CVI-0413 CV1 0413 CV1 0413.1) 04/13100 08:20 

02 SS2AD413 B82AO413 BS2AO413.D 04/13100 10:14 

03BI-0413 Bl-0413 B1-0413.D 04/13/00 12:48 

04 0003LF02GAC(IN) 380601 380601R.D 04/13100 13:42 

0 380603 380603R2.D 04/13/00 15:43 

0 GAC(OUT) 380606 380606R.D 04/13100 17:12 

0 GAC(INT) 380605 380605R2.D 04/13/00 18:14 

0 IGAC(OUT)DU 380606D 380606D.D 04/13/00 19:12 

0 GACQN) 380604 380604R.D 04/13/00 20:13 

1 7 CV1_0417 CV1 0417.1) 04/17/00 69:08 

AFCEEFORM10 Rev. 10/99 

2 7 -

7 7 5 8 3 AFCEE 





Instrument ID: GC/MS - G BFB Injection Date: 04/17/00 

SAS No.: 0410TO14 BFB Injection Time: 09:08 


% RELATIVE 


50 15.0 - 40.0% of mass 95 221 

75 30.0 - 60.0% of mass 95 49.7 

95 Base peak, 100% relative abundance 100.0 

96 5.0 - 9.0% of mass 95 6.6 


174 50.0 - 1 00.00/6 of mass 95 61.2 

175 5.0 - 9.00/0 of mass 174 7.5 

176 95.0 - 1 01.0% of mass 174 98.5 

177 5.0 - 9.0% of mass 176 6.6 

I 


LAB LAB DATE TIME 

SAMP SAMPLE ID FILE ID ANALYZED ANALYZED 

011 SSIA0417 BS1A0417.D 04/17/00 09:52 

02 B1 0417 RI nAI7 n nAll 7/nn 1 1 

03 

AFCEEFORM10 Rev. 10/99 

-28-

AFCEE 1 7 75 8 4 


VOLATILE INTERNAL STANDARD AREA AND FIT SUMMARY 

Analytical Method: TO-14 SDG N 3806 

LabName: CH2MHlLLASL Contract: 156470.02.08.03 

Instrument ID: GC/MS - G DateAnalyzed: 04/11/00 

Lab ID (Standard) CV1_0411 Time Analyzed: 11:58 

IS1 IS2 IS3 

AREA FIT AREA FIT AREA RT 

12 HOUR STD 317597 16.87 1273144 19.10 800833 23.34 

UPPER LIMIT 444636 16.37 1782402 18.60 1121166 22.84 

LOWER LIMIT 190558 17.37 763886 19.60 480500 23.84 

EPA SAMPLE 

NO. 

01 BSlAO411 318078 16.89 1291499 19.10 844161 23.34 

02B1-0411 309358 16.89 1236030 19.12 695999 23.34 

03 0003LF02GAC(INT) 316413 16.89 1274572 19.12 895272 23.34 

IS1 = Bromochloromethane 

IS? = 1,4-Difluorobenzene 

IS3 . Chlorobanzene-d5 

AREA UPPER LIMIT +40% of internal standard area 

AREA LOWER LIMIT - 40% of internal standard area 

FIT UPPER LIMIT +0.50 minutes of internal standard RT 

FIT LOWER LIMIT 0.50 minutes of internal standard RT 

Column to be used to flag values outside QC limit with an asterisk. 

Values outside of contract required QC limits 

AFCEE FORM 0-1 1 Rev. 10/99

AFCEE 

1 7 75 8 5 ORGANIC ANALYSES DATA SHEET 1 1 

VOLATILE INTERNAL STANDARD AREA AND FIT SUMMARY 


Lab Name: CI-12M HILL ASL Contract: 156470.02.08.03 

Instrument ID: GC/MS - G Date Analyzed: 04/13/00 

Lab ID (Standard) CVI-0413 Time Analyzed: 08:20 

IS1 IS2 IS3 

AREA FIT If AREA FIT 4 AREA If FIT 

12 HOUR STD 276521 16.92 1133759 19.13 756427 23.35 

UPPER LIMIT 387129 16.42 1587263 18.63 1058998 22.85 

LOWER LIMIT 165913 17.42 680255 19.63 453856 23.85 

EPA SAMPLE 

NO. 

01 SS2AU13 266047 16.90 1109295 19.13 741354 23.35 

02 B1_0413 269369 16.90 1104756 19.13 640083 23.35 

03 00OXF02GACON) 282569 16.90 1164045 19.13 846539 23.35 

04 wwLF02GAq0uT) 260839 16.92 1070502 19.13 752706 23.35 

05 0=WW1GAC(0Ur) 256231 16.91 1057020 19.13 772690 23.35 

06 0003WW1GAQ1Nn 259165 16.91 1047066 19.12 728070 23.34 

07 0003M1CAQ0UT)DUP 254389 16.92 1029774 19.13 741804 23.35 

080003WWlGAC(IN 258485 16.91 1052151 19.12 763772 23.34 


IS2 = 1,4-Difluorobenzene 

IS3 = Chlorobenzene-d5 



FIT UPPER LIMIT +0.50 minutes of internal standard FIT 

FIT LOWER LIMIT -0.50 minutes of internal standard FIT 

Column to be used to flag values outside QC limit with an asterisk. 


AFCEE FORM 0-1 I Rev. 10/99 

-30-

AFCEE 75 8 


VOLATILE INTERNAL STANDARD AREA AND AT SUMMARY 


Lab Name: CH2M HILL ASL Contract: -1 56470.02.08.03 

Instrument ID: GC/MS - G Date Analyzed: 04/17/00 

Lab ID (Standard) CV1-0417 Time Analyzed: 09:08 

IS1 IS2 IS3 

AREA AT AREA AT AREA AT 

12 HOUR STD 397981 16.91 1649571 19.14 1087745 23.36 

UPPER LIMIT 557173 16.41 2309399 18.64 152-2843 22.86 

LOWER LIMIT 238789 17.41 989743 19.64 652647 23.86 

EPA SAMPLE 

NO. 

ol BSIMW 339626 16.92 1600918 19.14 1045= - 

02 BI-0417 343867 16.92 1396637 19.13 800586 35 

03 00WWW1GAC(0UT)R1 384451 16.92 1597427 19.13 1108742 23.35 


IS2 = 1,4-Difluorobanzene 

IS3 = Chlorobenzene-d5 



RT UPPER LIMIT +0.50 minutes of internal standard AT 

AT LOWER LIMIT -0.50 minutes of internal standard AT 

Column to be used to flag values outside QC limit with an asterisk 


AFCEE FORM 0-1 1 -31- Rev. 10/99

1 7 7 5 8 7 

II 

CHAIN OF CUSTODY/SHIPPING DOCUMENTS 

-32-

CC) 

00 0 

Lr) 

r- 

C\) 

C11 

IL 

10 

.9-1c 

02 09C.90 

zt Domo. 

0 

Maui OF 

Soo 

t 

.tt 

-75 

1M -N f 

-SWR

Appendix Tab 

Appe'vid 1)( C- I 

Waf-cy- SMplc ,esu 1-, 

1 7 75 8 9

Columbia 

Analytical 

Mr. ServiceS INC. 

Mark Henry An Employee-Owned Company 

CH2M HILL/SPK 

9 South Washington St. 

Suite 400 

Spokane, WA 99204-0219 

Columbia Analytical Services Report 

Fairchild AFB WW1 Plume Investigation 

D0002702/D2702 

Submitted by: 

r 

A'&o 

Bryan Jones 

Project Manager/Client Services 

Enclosures 

xc: Ms. Artemis Antipas 

April 13, 2000 

1 7 75 9 0 

This report contains a total of 46 00001 

5090 Caterpillar Rood - Redding, CA 96003 - Telephone (530) 244-m7s'- Fox (530) 244-4109

91 TABLE OF CONTENTS 

CAS Lab Reference No.: D2702 

Level 2 

Cover Page ....................................................................................................................... I 

Table of Contents .............................................................................................................. 2 

AFCEE Data Qualifiers .................................................................................................... 3 

Sam ple Identification Cross-Reference ............................................................................ 4 

Page 

No. 

GC/M S V OLATILE O RGAN ICS .................................................................................... 5 

Case narrative .......................................................................................................... 6 

AFCEE Form 0-1 ................................................................................................... 7 

AFCEE Form 0-2 ................................................................................................... 8 

AFCEE Form 0-3 ................................................................................................. 14 

A FCEE Form 0-4 ................................................................................................. 20 

AFCEE Form 0-5 ................................................................................................. 22 

AFCEE Form 0-6 ...........................r ..................................................................... 28 

AFCEE Form 0-7 ................................................................................................. 32 

AFCEE Form 0-9 ................................................................................................. 36 

AFCEE Form 0-10 ............................................................................................... 37 

AFCEE Form 0-1 I ............................................................................................... 38 

AFCEE Appendix A .............................................................................................. 41 

AFCEE Appendix C .............................................................................................. 42 

M DL Form M ethod 8260 ...................................................................................... 44 

Chain of Custody D ocum entation ................................................................................... 45 

00002

AFCEE Data Qualifiers 1775 92 

Qualifiers Description 

i The analyte was positively identified, but the 

quantitation is an estimation. 

U The analyte was analyzed for, but not detected. 

The associated numerical value is at or below the 

MDL. 

F The analyte was positively identified but the 

associated numerical value is at or below the RIL. 

R The data are unusable due to deficiencies in the 

ability to analyze the sample and meet QC 

criteria. 

B The analyte was found in an associated blank, as 

well as in the sample. 

M A matrix effect was present. 

S To be applied to all field screening data. 

T Tentatively identified compound (using GUMS). 

00003

7 7 5 9 3 

Sample ID Cross-reference Table 

CAS Client Receive CotLect 

Lab Sample ID Sample ID Date Date Sample matrix Additional Description 

FS = Field Sample; LCS = Lab Control Sample; NON = Non-SampLe Type (Internal Admin) 

D2702000 NON EDATA 03/31/00 03/31/00 00:00 Administration EDATA 

D2702001 FS WW1WATER(IN) 03/31/00 03/30/00 09:15 Water 0003WWlWATER(IN) 

02702002 FS WlWATER(OLIT) 03/31/00 03130/00 09:10 Water 0003WWlWATER(OUT) 

The above tab sample ID's and cross reference information apply to samples as received by the Laboratory. Modifie 

to the tab sample ID my be added for internal tracking purposes. Any modified sample ID witt be reflected in the 

appropriate case narrative only. 

00004

I 

I 

GC/MS VOLATILE ORGANICS 

1 7 75 9 4 

00005

17 7 5 9 5 


Project: Fairchild AFB WWl PI 

I. RECEIPT 

CASE NARRATIVE 


No exceptions were encountered unless a Sample Receipt Exception Report 

is attached to the Chain-of-Custody included with this data package. 

II. HOLDING T311ES 

III. I-IETHOD 

A. Sample Preparation: All holding times were met. 

B. Sample Analysis: All holding times were met. 

Preparation: SW-846 5030B 

Cleanup: N/A 

Analysis: SW-846 8260B 

IV. PREPARATION 

Sample preparation proceeded normally. 

V. ANALYSIS 

A. Calibration: All acceptance criteria were met. 

B. Blanks: All acceptance criteria were met. 

C. Internal Standards: All acceptance criteria were met. 

D. Surrogates: All acceptance criteria were met. 

E. Spikes: All acceptance criteria were met. 

F. Samples: In order to report all target analytes within calibration 

range, sample 02702001 was reanalyzed on a diluted basis. Reporting 

limits have been adjusted accordingly. 

I certify that this data package is in compliance with the terms and conditions 

agreed to by the client and CAS, Inc., both technically and for completeness, 

except for the conditions noted above. Release of the data contained in this 

hardcopy data package has been authorized by the Laboratory Manager or 

designated person, as verified by the following signature. 

SIGNED: 7;- DATE: 7, 

Brian Moore 

Senior Chemist, GC/MS 

Columbia 5090 Caterpillar Road 00 06 

Analytical Services Redding, CA 96003-1412

AFCEE 

ORGANIC ANALYSES DATA PACKAGE 

Analytical Method: SW8260B AAB #: D2702 

Lab Name: CASILAB/RDD Contract #: F41624-94-D-8053 

Base/Command: FAIRCHILD AFB 3.0 Prime Contractor: CH2M HILL 

Project: FAIRCHILD AFB WWI PI 

Comments: 

See attached narrative 

Field Sample ID Lab Sample ID 

WWIWATER(IN) D2702001 

WWIWATER(rN)DL D270200IDL 

WIWATER(OUT) D2702002 

AFCEE FORM 0- 1 

1 7 7 5 9 6 AFCEE QAPP 

Version 3. 0 

March 1998 

RD"111 TcBS-09VP-SA.270DZ702--G 0 0 07

AFCEE A FCEE QAFP 

7 7 5 ORGANIC ANALYSES DATA SHEET 2 Version 3.0 

RESULTS March 1998 


Lab Name: CAS/LAB/R.DD Contract #: F41624-94-D-8053 

FieldSampleID: WWIWATER(IN) Lab Sample ID: D2702001 Matrix: Water 

% Solids: SampleDescription: 0003WWIWATER(FN) 

Date Received: 31 Mar 00 Date Prepared: Date Analyzed: 6 Apr 00 

Concentration Units (ug/L or mg(Kg dry weight): ug/L Sample Volume: 20.0 ML 

Analyte MDL RL Concentration Dilution Confirm 

1,1,1-TCA 0.12 0.8 0.12 1 U 

1, 1,2,2-Tetrachloroethane 0.12 0.4 0.12 1 U 

1, 1,2-TCA 0.11 1.0 0.11 I U 

II-DCA 0.12 0.4 0.12 1 U 

1, I -DCE 0.09 1.2 0.14 1 F 

1,2-DCA 0.13, 0.6 0.13, 1 U 

1,2-DCB 0.11 0.3 0.11 I U 

1,2-Dichloropropane 0.11 0.4 0.11 I U 

1,3-DCB 0.10 1.2 0.10 I U 

1,4-DCB 0.12 0.3 0.12 1 U 

Bromobenzene 0.13 0.3 0.13 1 U 

Bromodichloromethane 0.12 0.8 0.12 1 U 

Bromoform 0.09 1.2 0.09 1 1 

Bromomethane 0.16 1.1 0.16 1 

Carbon tetrachloride 0.10 2.1 0.14 1 F 

Chlorobenzene 0.11 0.4 0.11 I U 

Chloroethane 0.12 1.0 0.12 1 U 

Chloroform 0.11 0.3 8.14 1 

Chloromethane 0.07 1.3 0.071 1 U 

Cis-1,2-DCE 0.12 1.2 20.90 1 

Cis- 1,3-Dichloropropene 0.08 1.0 0.08 1 U 

Dibromochloromethane 0.09 0.5 0.09 1 U 

Dibromomethane 0.09 2.4 0.09 1 U 

Methylene chloride 0.13 0.3 0.Ij I U 

TCE 0.12 1.0 9.83 1 

Tetrachloroethene 0.12 1.4 0.12 1 1 U 

Trans-1,2-DCE 0.11 0.6 3.86 1 

Trans- 1,3-Dichloropropene 0.08 1.0 0.08 1 U 

Trichlorofluoromethane 0.11 0.8 0.11 I U 


Surrogate Recoveries am reported in Appenda O-A 

Comments: Internal Standards are reported in Appenda O-C 

AFCEEFORMO-2 Pagelof6 0 0 0 8

AFCEE 1 7 7 5 98 A FCEE Q9A PP 

ORGANIC ANALYSES DATA SHEET 2 Version 3. 0 



Lab Name: CAS/LAB/RDD Contract #: F41624-94-D-8053 

FieldSample[D: WWIWATER([N) Lab Sample ID: D2702001 Matrix: Water 

% Solids: SampleDescription: 0003WWIWATER(rN) 


Concentration Units (ug/L or mgfKg dry weight): sample Volume: 20.0 ML 


Surrogate Recovery Control Limits Qualifier 

Dibromofluoromethane 99 75-125 

Toluene-D8 97 75-125 

4-Bromofluorobenzene 102 75-125 

Internal Standard Qualifier 

Fluorobenzene 

Chlorobenzene-d5 

1,4-Dichlorobenzene-d4 

Surrogate Recowries are reported in Appendix O-A 

Comments: Internal Standards are reported in Appendix O-C 

AFCEEFORMO-2 Page2of`6 

RDD.00411, rC BS-4WJ71'T-Sif ooe0Z702-Q[ 0 0 9

AFCEE AFCEE QAPP 

1775 99 ORGANIC ANALYSES DATA SHEET 2 Version 3. 0 




FieldSampleID: WWIWATER(fN)DL LabSampleID: D270200IDL - Matrix: Water 

% Solids: SampleDescription: 0003WWIWATER(lN) 

Date Received: 31 Mar 00 Date Prepared: Date Analyzed: _LAaLQQ__ 

Concentration Units (ug/L or mg/Kg dry weight): ug/L Sample Volume: 20.0 ML 

Analyte MDL RL Concentration Dilution Confirml Qualiffier 

1,1,1-TCA 0.24 1.6 0.24 2 U 


1, 1,2-TCA 0.23 2.0 0.23 2 U 

II-DCA 0.249 0.80 0.249 2 U 

1,1-DCE 0.18 2.4 0.18 2 U 

1,2-DCA 0.26 1.2 0.26 2 U 

1,2-DCB 0.210 0.60 0.210 2 U 

1,2-Dichloropropane 0.221 0.80 0.221 2 U 

1,3-DCB 0.20 2.4 0.20 2 U 

1,4-DCB 0.245 0.60 0.245 2 U 



Brornoform 0.19 2.4 0.18 2 

Bromomedhane 0.32 2.2 0.32 2 U 

Carbon tetrachloride 0.21 4.2 0.21 2- U 

Chlorobenzene 0.223 0.80 0.223 2 U 


Chloroform 0.226 0.60 8.189 2 

Chloromethane 0.13 2.6 1 0.13 2 U 

Cis-1,2-DCE 0.25 2.4 20.50 2 

Cis-1,3-Dichloropropene 0.16 2.0 0.16 2 U 



Methylene chloride 0.261 0.60 0.261 2 U 

TCE 0.23 2.0 9.48 2 

Tetrachloroethene 024 2.8 1 0.24 2 U 

Trans-1,2-DCE 0.22 1.2 3.79 2 

Trans-1,3-Dichloropropene 0.17 2.0 0.17 2 U 

Trichlorofluoromethane 0.22 1.6 0.22 2 U 

Vinyl chloride 0.26 2.2 F 

Surrogate Recoveries are reported in Appendix O-A 

Comments: Internal Standards am reported in Appendix O-C 

AFCEEFORMO-2 Page3of6 

HS4i9j7PSrxR LRi0iiZ70210 0 0 1 0

AFCEE 1 7 7 5 1 0 0 AFCEEQAPP 



Analytical Method: SW8260B AAB D2702 


FieldSampleID: WWIWATER(FN)DL LabSamplelD: D270200IDL Matrix: Water 

% Solids: SampleDescription: 0003WWlWATER(IN) 


Concentration Units (ug1l, or mgfKg dry Weight): ug/L Sample Volume: 20.0 ML 



Dibromofluoromethane 89 75-12S 

Toluene-138 87 75-125 

4-Bromofluorobenzene 92 75-12S 


Fluorobenzene 




Comments: internal Standards are reported in Appendix O-C 

AFCEE FORM 0-2 Page 4 of 6 

,W11jV:&-w37PST-SR L>Q(002702-D2 60011

1 7 75 10 1 AFCEE AFCEE QAPP 

ORGANIC ANALYSES DATA SHEET 2 Version 3.0 



Lab Name: CAS/LAB/RDD Contract F41624-94-D-8053 

FieldSamplell): WtWATER(OUT) Lab Sample ID: D2702002 Matrix: Water 

% Solids: SampleDescription: 0003WWIWATER(OUT) 

Date Received: 3 1 Mar 00 Date Prepared: Date Analyzed: 

Concentration Units (ugfL or mgfKg dry weight): ug[L Sample Volume: 20.0 ML 

Analyte, MDL RL Concentration Dilution Confirml Qualifier 

1,1,1-TCA 0.12 0.8 0.12 1 U 


1, 1,2-TCA 0.11 1.0 0.11 I U 

1, I -DCA. 0.12 0.4 0.12 1 U 

1, I -DCE 0.09 1.2 0.09 1 U 

1,2-DCA 0.131 0.6 0.13 1 U 

1,2-DCB 0.11 0.3 0.11 I U 


I,3-DCB 0.10 1.2 0.10 I U 

I,4-DCB 0.12 0.3 0.12 1 U 


Bromodichloromethane 0.12 0.8- 0.121 1 

Bromoform 0.09 1.2 0.09 1 

Bromomethane 0.16 1.1 0.16 1 U 

Carbon tetrachloride 0.10 2.1 0.10 I U 



Chloroform 0.11 0.3 1 0.11 I U 


Cis-1,2-DCE 0.12 1.2 0.12 1 U 





TCE 0.12 1.0 0.12 1 U 

Tetrachloroethene 0.12 1.4 0.12 1 U 

Trans-1,2-DCE 0.11 0.6 0.11 I U 



Vinyl chloride 0.13 0.13 1 U 


Comments: Internal Standards are reported in Appendor O-C 

AFCEEF0R.MO-2 Page5of`6 xo4it.nssvvj7PST-5ND000M. 00012

AFCEE 1 7 7 5102 A FCEE (?A PP 





FieldSampleID: WIWATER(OUT) Lab Sample ID: D2702002 Matrix: Water 



Concentration Units (ug1l, or mglKg dry weight): ugfL Sample Volume: 20.0 ML 



Dibromofluorornethane 95 75-125 

Toluene-D8 96 75-125 



Fluorobenzene 




Comments: Infernal Standards are reportedn Appendix O-C 


00013

AFCEE QAPP 

17 7 5 10 3 AFCEE Version 3.0 

ORGANIC ANALYSES DATA SHEET 3 (Part 1) March 1998 

INITIAL MULTIPO[NT CALIBRATION.GC/MS 



Instrument ID: MS9 Date of Initial Calibration: 4 Apr 00 OC Colunm ID: DB-624 

Concentration Units (ug/L or mg/kg): UG/L 

Initial Calibration Sample 113s: VSTDG0.3 VSTDO05 VSTDO I 0 VSTDO15 VSTDO20 VSTDOOI 

Calibration File IDs: C000788 C000791 C000792 C000793 C000794 C0007910 

Analyte Std. RF I Std. RF SId RF SId. RF Std RF Std RF Std RF 

1 1 2 2 3 3 4 4 5 5 6 6 7 7 

1.1,1-TCA 5.000 0.438 10.00 0.449 15.00 0.461 20.00 0.482 0.500 0.537 

1,1,2,2-Tetrachlomethane- 0.300 0.562 5.000 0.424 MOO 0.448 15.00 0.459 20.00 0.477 

1,1,2-TCA 5.000 0.168 10.00 0.174 15.00 0.175 20.00 0.183 1.000 0.170 

II-DCA* 0.300 0.483 5.000 0.46 I 10.00 0.455 15.00 0.453 20.00 0.465 

II-DCE# 5.000 0.090 10.00 0.0871 15.001 0.091 20.001 0,0961 1.0001 0.093 1 1 

1,2-DCA 5.000 0.383 10.00 0.3881 15.001 0.387 20.00 0.397 0.500 0.494 

I,2-DCB 0.3001 1.5251 5.000 1.4571 10.001 1.452 15.00 1.440 20.00 1.461 

1,2-Dichloropmpane# 0.300 0.259 5.000 0.258 10.00 0.264 15M 0.267 20.00 0.280 

1,3-DCB 5.000 1.619 io.oo 6oo 15.00 1,560 20.00 1.572 1.000 L650 

1,4-DCB 0.300 1.804 5.000 1.593 10.00 1.596 15.00 1.574 20.00 1.612 

Bromobenzerie 0.300 0.958 5.000 0.894 10.00 0.885 15.00 0.876 20.00 0.890 

Bromodichloromethane 5.000 0.309 10.00 0.323 15.00 0.331 20.001 0.3481 0.5001 0.370 1 1 

Bromform. 5.000 0.105 10.00 0.118 15.00 0.126 20.001 0.1371 1.000 0.095 

Bromomethane 5.000 0.052 10.00 0.054 1540 0.062 20.00 0.062 1.000 0.046 

Carbon tetrachloride 5.000 0.336 10.00 0.350 15.001 0.361 20.00 0.377 1.000 0.309 

Chlombenzene- 0.300 1.143 5.000 1.054 10.001 1.056 15.00 1.045 20.00 1.067 

Chlomethane 5.000 0.089 10.00 0.081 15.001 0.088 20.00 0.087 1.000 0.089 

Chlomform# 0.300 0.472 MOO 0.448 10.001 0.453 15.00 0.456 20.00 0.470 

Chloromethane- 5.000 0.161 10.00 0.158 15.001 0.1631 20.00 0.176 1.000 0.151 

Cis-1,2-DCE 5.000 0.286 10 00 0.284 15.00 0.283 20.00 0.289 1.000 0.279 1 1 

Cis- 1.3-Dichloropropene 5.0001 0.2731 10.00 0.292 15-00 0.302 20.00 0.319 1.000 6.2-49 

Dibromochlorometharte 5.0001 0.2241 10.00 0.243 15M 0.252 20.00 0.268 0.500 0.260 

Dibromomethanc 

Methylene chloride - 5.000 0.1201 10.00 - ----- F-O..-1-35-[-5..000 

0300 

OA25 

0.111 

15.00 

0.00 

0.127 

0.105 

20.00 

15 00 

0.132 

0.111 

1.000 

20.00 

0.119 

0.114 

TCE 5.0001 0.3191 10.00 0,316 15.00 0311 20 00 0.325 1 MM 0 297 

SPCCS # CCCs 

Comments: 

AFCEE FORM 3 (Part 1) Page I of 2 

ADD-11 TC.8$-0937P-SR VOD:701 00014

17 7 5 10 4 AFCEE QAPP 

AFCEE Version 3. 0 


INITIAL MULTIPOINT CALIBRATION-GC/MS 



Instrument ID: MS9 Date of Initial Calibration: 4 Apr 00 GC Column ID: DB-624 


Initial Calibration Sample [Ds: VSTDOO.3 VSTDO05 VSTD0I0 VSTDO15 VSTDO20 VSTD00I 

Calibration File [Ds: C000788 C000791 C000792 C000793 C000794 C000790 

Analyte Std RF I Std RF SIA I RF Std I R.F Std R.F Std RF Std RF 

1 2 2 3 3 4 4 5 1 5 6 6 7 7 

Tenchloroethene 5.DOO 0.3601 10.00 0.357 15.001 0.351 20.00 0.359 1.000 0.361 

Trans-1,2-DCE 5.000 0.1071 10.00 0.106 15-00 0.108 20.00 0.113 0.500 0.142 

Trans-1,3-Dichlompropene 5.000 0.2831 10.00 0.308 15.00 0.320 20.00 0.343 1.000 0.258 

Trichlorofluoromethane 5.000 0.1651 10.00 0.152 15.00 0.161 20.00 0.166 0.500 0.204 

Vinyl chloride# 5.000 0.1601 10.00 0.150 15.00 0.1601 20.00 0.163 1.000 0.149 

Dibmmofluoromethant 5.000 0.2831 10.00 0.291 15.00 0.294 20.00 0.304 1.000 0.262 

Toluene-D8 5.GOO 1.4081 10.00 1.372 15.00 1.333 20.001 1.3481 1.000 1.268 1 

4-Bmmofluorobenzene 5.000 1.0021 10.00 O.M 15.00 0.969 20.00 0.9781 1.000 0.950 

SpCCS CCCS 

Comments: 

AFCEE FORM 3 (Part 1) Page 2 of 2 

ADD.411. rC BS37P-SR..170:-D.'702 00015

AFCEE QAPP 

75105 AFCEE Version 3.0 


INITIAL MULTIPOINT CALIBRATION-GCIMS 


Lab Name: CASILAB/RDD Contract #: F41624-94-D-8053 



Initial Calibration Sarnple [Ds: VSTDOO.3 VSTDO05 VSTDOIO VSTDO 1 5 VSTDO20 VSTDOOI 

Calibration File [Ds: C000788 C000791 C000792 C000793 C000794 C000790 

Analyte Curve Ave. % mean r COD Q 

Type RF RSD 0/6RSD 

1,1,1-TCA AVG 0.473 8.2 6.36 

1.1.2,2-Tetmchloroethane- AVG 0.474 11.1 6.36 

1,1,2-TCA AVG 0.174 3.3 6.36 

II-DCA* AVG 0.463 2.6 6.36 

II-DCE# AVG 0.0911 3.5 6.36 

1,2-DCA AVG 1 0.410 11.6 6.36 1 

1,2-DCB AVG 1.467 2.3 6.36 

1.2-Dichlompropme# AVG 0.266 3.3 6.36 

1,3-DCB AVG 1.600 2.3 6.36 

1,4-DCB AVG 1.636 5.8 6.36 

Brombenzene AVG 0.901 3.6 6.36 

Brontodichlorornethane AVG 0.336 7.0 6.36 

Brorra,fornn. AVG 1 0.1161 14.2 6.36 1 f i 

Brornornethane AVG 0.055 12.0 6.36 

Carbon tetrachloride AVG 0.347 7.5 6.36 

Chlorobenzent- AVG 1.073 3.7 636 

Chloroethane AVG 0.087 4.0 6.36 

Chlomfornn# AVG 0.460 2.3 6.36 

Chloromethane* AVG 0.162 5.8 636 

Cis-1,2-DCE AVG 1 0.2841 1.3 6.36 1 1 

Cis-1,3-Dichlompropene AVG 0.2871 9.6 6.36 

Dibrornochloronnethanc AVG 0.249 6.9 6.36 

Dibronnonnethane AVG 6.36 

Methylene chloride AVG 6.36 

TCE AVG 6.36 

SPCCs # CCCS 

Comments: 


RDD,IkMBS4917P- DW70Z-D:702-y 00016

1 7 7 5106 AFCEE QAFF 

Version 3.0 

AFCEE March 1998 

ORGANIC ANALYSES DATA SHEET 3 (Part 2) 






initial Calibration Sample IDs: VSTDOO.3 VSTDO05 VSTD010 VSTDO 1 5 VSTDO20 VSTD001 

Calibration File [Ds: C000788 C000791 C000792 C000793 C000794 CDO0790 


Type RF RSD %RSD 

Tetrachloroethcne AVG 0.358 1.1 6.36 

Trans-1,2-DCE --- ;-VG -0 115' 13.3 6.36 

Trans-1,3-Dichlompropene AVG 0.302 10.9 6.36 

Inchlorolluommethane -Tv-G -(I 7 o 11.8 6.36 

Vinyl chloride# TV-G 0-156 - 4 0 6.36 

Dibromofluoronacthane -- TV-G 0- 287 - 5 5 6.36 

Toluene-D8 AVG 1.346 3 9 (F3 6- 

SPCCs CCCS 

Comments: 

romfluorobenzene 0.978 2.0 6.36 


RDll.rc.Bs-o9j7pSr-S)ZDWZIOZ-D oOO17

AFCEE QAPP 

1775 107 AFCEE Version 3.0 

ORGANIC ANALYSES DATA SHEET 3A (Part 1) March 1998 

INITIAL MULTIPOfNT CALIBRATION-GC/MS 




Concentration Units (ugtL or mg/kg): UG/L 

Initial Calibration Sample IlDs: VSTDOO.3 VSTDO05 VSTD010 VSTDOi5 VSTDO20 VSTDG01 

Calibmtion File Ms: C000788 C000791 C000792 C000793 C000794 C000790 

Analyte Std RF Std RF S Std Std RF S RF 

RF Std RF Id 

I 1 2 2 Id RP 1 4 4 5 6 6 7 

1,1,2,2-Tetrachloroethane- 0.300 0.562 5.000 0.424 10.00 0.448 15.00 0.459 20.00 0.477 

II-DCA- 0.300 0.483 5.000 0.461 10.00 0.455 15.00 0.453 20.00 0.465 

II-DCE# 5.000 0.090 10.00 0.087 15.00 0.091 20.00 0.096 1.000 0.093 

1.2-Dichlonapropane# 0.300 0.259 5.000 0.258 10.00 0.264 15.00 0.267 20.00 0.280 

Bromoform* SA01 0.1051 10.00 0.1181 15.001 0.126 20.00 0.1371 1.0001 0.095 

Chlorobenzene* 0300 1.143 5.000 1.054 10.00 1.056 15.00 1.045 20.00 1.067 

Chlorofomi# 0.300 0.472 5.000 0.448 10.00 0.453 15.00 0.456 20.GO 0.470 

Chloromt:thane- 5.000 0.161 10.00 0.158 15.00 0.163 20.00 0.176 1.000 0.151 

Vinyl chloride# 5.000 0.160 10.00 0.150 15.00 0.160 20.00 0.163 1.000 0-149 

spCCs ft CCCs 

Comments: 

AFCEE FORM 3A (Part 1) Page I of I 

"&/j 0 0018

1 7 75108 A FcEE LqApp 



INITIAL MULTIPOrNT CALIBRATION-GCIMS 




Concentration Units (ug[L or mg/kg): UG/L 

Initial Calibotion sample 113s: VSTDOO.3 VSTDO05 VSTDOIO VSTDO 1 5 VSTDO20 VSTDOOI 

Calibration File 113s: C000788 C000791 C000792 C000793 C000794 C000790 



1.1,2,2-Tetrachlomethane* AVG 0.474 11.1 6.36 

1.1-DCA* AVG 0.463 26 6.36 

II-DCE# AVG O. 9-1 3 5 6.36 

1,2-Dichloropmpane# AVG 0. F6-6 3 3 6.36 

Brornoform. AVG 0.116 14.2 6.36 

Chlombenzene* AVG 1.073 3.7 6.36 

Chlomform# AVG 0.460 2.3 6.36 

Chloronnethane- AVG 0.162 5.8 6.36 

Vinyl chloride# AVG 0.156 4.0 6.36 

SPCCs CCCs 

Comments: 

AFCEE FORM 3A (Part 2) Page I of 1 

RDD-J 1. TC OS4937M-SR.jM-D270'- 

00019

AFCEE QAPP 

77 5 10 9 Version 3. 0 

March 1998 

AFCEE 





Instrument ID: MS9 Initial Calibration ID: C000795Q.D 

2nd Source ID: QCALTSTD Concentration Units (ugfl, or mg/kg): UG/L 

GIC Column ID: DB-624 

Comments: 

Analyte Expected Found %D Q 

1,1,1-TCA 10.0 9.32 -5.2 

1,1.2,2-Tetrachlomethane* 10.0 9 47 -5.5 

1,1,2-TCA 10.0 9.89 0.0 

II-DCA- 10.0 9.62 -3.8 

1.1-DCE# 10-0 9.74 -2.6 

1.2-DCA 10.0 9.301 -7.0 

1,2-DC13 10.0 9.83 -1.7 1 

1,2-Dichloropropane# 10.0 9.83 -1.7 

1,3-DCB 10.0 9.87 -1.3 

1,4-DCB 10.0 9.65 -3.5 

Brombenzene 10.0 9.73 -1.8 

Brornodichlorornethane 10.0 9.47 -3.9 

Brornof0m. 10.0 10.32 1.6 

Brornomethane 10.0 10.81 7.9 1 

Carbon tetrachloride 10.0 9.98 -0.2 

Chlombenzene- 10.0 9.63 -1.6 

Chloroethane 10.0 9.27 -6.5 

Chlorolbrin# 10.0 9.64 -3.6 

Chloromethane- 10.0 9.75 -2.3 

Cis-1,2-DCE 10.0 9.79 2.0 

Cis-1,21-Dichloropropene 10.0 10.08 1.8 I 

Dibrornochloromethane 10.0 9.78 -2.5 

Dibrommethane 10.0 9.82 0.1 

Methylene chloride 10.0 9.28 -7.3 

ITCE 10.0 9.84 -1.8 

SPCCs # CCCs 

AFCEE FORM 0-4 Page I of 2 

AD-11 x 8"37PÀ `702-DjY0020

AFCEE 






2nd Source ID: QCALTSTD Concentration Units (ug/L or mg/kg): UG/L 

GC Column ID: DB-624 

Comments: 

AFCEE QAPP 

7 75 1 1 0 Version 3.0 

Analyte Expected Found %D 

Tetmchloroethene 10.0 9.60 4.0 

Tmns-1,2-DCE 10.0 9.28 -7.1 

Trans-1,3-Dichloropropene 10.0 10.33 1.9 

Trichlorofluorornethane 10.0 8.85 -11.5 

Vinyl chloride# 10.0 9.26 -7.3 

Dibromfluoronnethane N/A N/A 0.0 

Tolucne-D8 N/A N/A 0.0 

4-Bromfluorobenzene N/A NIA 0.0 

SpCcs CCCs 


March 1998 

RDW4MTC.8S-MJ7PSr5R 2702-D27-1 a 0 0 2 -1

AFCEE QAPP 

177 5 1 1 1 Version 3.0 



CALIBRATION VERIFICATION-GCIMS ANALYSIS 




ICV ID: QCALTSTD CCV #1 ID: VSTD010 CCV #2 ID: 

ICV File ID: C000795Q.D CCV#IFiIeID: C000831.1) CCV #2 File ID: 


ICv CCv #1 CCV #2 

Analyte Expected Found %D or % drift Expected Found %D or % drift Found %D or % drift Q 

1,1,1-TCA 10.0 9.32 -5.2 10.0 9.28 -7.1 

1,1,2,2-Tetrwch1orocth&ne- 10.0 9.47 -5.5 10.0 10.81 8.0 

1,1,2-TCA 10.0 9.89 0.0 10.0 10.59 5.8 

1,1-DCA- 10.0 9.62 -3.8 10.0 10.03 0.3 

1,1-[)CE# 10.0 9.74 -2.6 10.0 8.65 -13.61 

1,2-DCA 10.0 9.301 .7.0 10.01 9.- -10 -8.9 

1,2-DCB 10.0 9.83 -1.7 10.01 9.88 -1.2 

1,2-Dichloropropane# 10.0 9.83 -1.7 10.0 10.31 3.2 

1,3-DCB 10.0 9.87 -1.3 10-0 9.89 -1.2 

1.4-DCB 10.0 9.65 -3.5 10.0 9.71 -2.9 

Brornobenzwe 10.0 9.73 -1.8 10.0 9.47 -5.3 

Bromodichlorornethane 10.0 9.47 -3.9 10.0 9.44 -5.7 1 

Brornoforrn* 10.0 10.32 1.6 10.0 9.67 .3.6 

Bromornethane 10.0 10.811 7.9 10.01 8.55 -15.5 

Carbon tetrachloride 10.0 9.98 -0.2 10.01 9 34 -6.5 

Chlorobenzene- 10.0 9.63 -1.6 10.0 9.95 -0.5 

Chloroethane 10.0 9.27 -6.5 10.0 8.80 -12.2 

Chlorofonn# 10.0 9.64 -3.6 10.0 9.75 1 -2.6 

Chloromethane- 10.0 9.75 -2.3 10.0 8.60 .14.0 1 

Cis-1,2-DCE 10,0 9.79 -2.0 10.0 10.25 2.6 

Cis- 1,3-Dichloropropene 10.0 10.081 1.8 10.0 10.75 7.4 

Dibrornochlorornethane 10.0 9.78 -2.51 10.0 9.27 -7 3 

Dibrornornethane I 10. 9.82 0.1 100 9.87 -1.5 

Methylene chloride 10.0 9.28 -73 8.46 -15.1 

ITCE I 10.0 9.84 -1.9 10.01 10.91 9.0 1 

SpCCs # CCCs 

Comments: 

AFCEEFORMO-5 Pagelof4 

RD411 oOO22

1 7 751 1 2 AFCEE QAPP 

Version 3.0 





Lab Name: CAS/LABIRDD Contract #: F41624-94-D-8053 


ICV ID: QCALTSTD CCv #1 ID: VSTD010 CCV #2 ID: 

ICV File ID: C000795Q.D CCV #1 File ID: C00083 I.D CCV #2 File ID: 


ICv Ccv #1 CCV #2 

Analyte Expected Found %Dordrift -ExPectedTFound %D or % drift Found %D or % drift Q 

Tetrachlomethene 

Trans-1,2-DCff joo 

I U.-o 

-9.2S 

9.60 4-0 

=7 - 

.1 

10.0 

- 

100 

9.45 

8.17 

-5.4 

-18.4 

Trans-1,3-Dichloropropene 10.0 10.33 1.9 - 10.0- 11.24 12.4 

Trichlorofluororrmthane M 0 0 8.85 -11.5 10.0 8.08 -19.2 

y] chloride# 10 0 9.26 .7-3 - 10 0 - 8 67 -13.0 

romfluoro=Fha-ne N7 NIAI 10.0 10.29 3.1 

uenc-D8 N/A N/Al 10.01 11.02 10.2 

romofluorobenzene N/A N/A 0.0 10.01 10.19 1.9 

SPCCS CCCs 

Comments: 


AD411 rC RS-M37P-SR 27OZ-D!70. 00023

AFCEE QAPP 

1775 1 1 3 Version 3. 0 



CALIBRATION VERIFICATION-GUMS ANALYSIS 




ICV ID: QCALTSTD CCV #1 ID: VSTD0l0 CCV #2 ID: 

ICV File ID: C000795Q.D CCV#l File ID: CG00852.1) CCV #2 File ID: 



Analyte Expected Found %D or % drift Expected Found %D or % drift Found %D or 3/oft Q 

1,1,1-TCA 10.0 9.32 -5.2 10.0 9.18 -8.1 

1,1,2,2-Tetrachloroethane- 10.0 9.47 -5.5 10.0 9.02 -9.7 

1,1,2-TCA 10.0 9.89 0.0 10.0 8.84 -11.5 

1,1-[)CA- 10.0 9.62 -3.8 10.0 9.40 -5.9 

II-DCE# 10.0 9.74 -2 6 10.0 9.31 -7.0 

1.2-DCA 10.0 9301 -7.0 10-01 8.69 -13.1 1 

1,2-DCB 10.0 9.83 -1.7 10.0 9.55 4.6 

1,2-Dichlompropane# 10.0 9.83 .1.7 10-0 9.26 -7.3 

1,3-DCB 10.0 9.87 -1.3 10.0 9.86 -1.5 

1,4-DCB 10.0 9.65 -3.5 10.0 9.59 -4.2 

Brombenzene 10.0 9.73 -1.8 10.0 9.33 -6.8 

Bromodichlorornethane 10.0 9.47 -3.9 10.0 8.80 -12.0 

Bromforrn. 10.0 10.32 1.6 10.0 8.63 -13.9 

Brornornethane 10.0 10.81 7.9 10.0 9.51 -4.7 

Carbon tetrachloride 10.0 9.98 -0.2 10.0 9.74 -2.5 

Chlorobcnzcne- 10.0 9.63 -1.6 10.0 9.65 -3.5 

Chloroethane 10 0 9.27 -6.5 10.0 9.53 -4.2 

Chloroform# 10.0 9 64 -3-6 10 0 9.46 -5.4 

Chlorornethane- 10.0 9.75 -2.3 10.0 9.97 -1.01 

Cis-1,2-DCE 10.0 9.79 1 -2.0 10.01 9,66 -3.4 

Cis-1,3-Dichloropmpene 10.0 10.08 1.8 10.0 9 95 -0-6 

Dibrornochlorornethane 10.0 9.78 -2.5 10.0 8.48 -15.3 

Dibromrnethane 10.0 9.82 0.1 10.0 9.05 -9.5 

Methylene chloride 10.0 9.28 -7.3 10.0 8.75 -12.5 

TCE 10.0 9.84 -1.8 10.0 9.12 -9.8 

* SPCCS # CCCS 

Comments: 


AD"411 W BSMJ7P,,-s8 .7o2-o- 0 0 0 2 4

AFCEE QAPP 

1 7 7 5 1 1 4 Version 3. 0 








ICV File ID: C000795Q.D CCV #1 File ID: C000852.D CCV #2 File ID: 

GC Colurrm ID: DB-624 

lCv CCv #1 CCV #2 

Analyte Expected Found %D or % drift Expected Found %D or % drift-' Found %D or % drift Q 

Tetrachlomethene 10.3 - 9.60 4.0 10.0 9.78 -2.1 

Trans-1,2-DCE 10.0 9.28 _7 T - 1 0 0 8.77 .12.4 

Tmns-1.3-Dichlompmpene ITO - 10 33 1.9 10.0 9.68 -3.1 

Trichlorofluoromthane 10.0 8.85 -11.5 10.0 9.14 -8.6 

ny C de# I 9.26 -7.3 10.0 9.68 -3.4 

uommethane N/A N/A 0.0 - 10.0 9.60 -3.9 

uenc. N/A NIA 0.0 10.0 9.50 -5.0 

mm uorobenzene N/A N/A 7 _0 - 1 0 0 9.48 -5.3 

SpCCs CCCs 

Comments: 


WM4112TC-aS-0937PST-SR D2702D270 00025

17 15 1 15 AFCEE QAPP 

Version 3. 0 





Lab Name: CASILAB/RDD Contract F41624-94-D-8053 


lCV ID: QCALTSTD CCV #1 ID: V'STD010 CCV #2 ID: 

ICV File ID: C000795Q.D CCV #1 File ID: C00083 I.D CCV #2 File ID: 


Analyte ICv 

-U7 Expected Found %D RF 

CCv #1 

Expected Found %D RF 

CCV #2 

Found %D 

1j,2,2-Tetmchloroethane* 0.448 10.0 9.47 -5.5 0.512 10.0 10.81 8.0 

II-DCA- 0.446 10.0 9.62 -3.8 0.465 10.0 10.03 0.3 

1,1-13CEN 0.089 10.0 9.74 -2.6 0.079 10.0 8.65 -13.6 

1,2-Dichlompmpane# 0.261 10.0 9.83 -1.7 0.274 10.0 10.31 3.2 

Brornoforrn* 0.118 10.0 10.32 1.6 0.112 10-0 9.67 -3.61 

Chlombenzene* 1.056 10.0 9.631 -1.6 1.0681 10.0 9.95 -0.5 

Chlorofonn# 0.4431 10.0 9.64 -3.6 0.448 10.0 9.75 -2.6 

Chlorornethane- 0.158 10.0 9.75 -2.3 0.139 10.0 8.60 -14.0 

Vinyl chloride# 0.145 10.0 9.26 -7.3 0.136 10.0 8.67 -13.0 

SpCCs CCCS 

Comments: 

AFCEE FORM O-5A Page I of 2 

RDD-00411 7r 85-037PST-SR D"2702-0026

AFCEE QAPP 

1 7 7 5 1 1 6 Version 3.0 







ICV ID: QCALTSTD CCV #1 ID: VSTDO10 CCV #2 ID: 

ICV File ID: C000795Q.D CCV#l File ID: C000852.1) CCV #2 File ID: 


Analyte ICv CCv #1 CCV #2 Q 

RF Expected Found %D RF Expected Found %D RF Found %D 

1,1.2,2-Tetmchloroethane- 0.448 10.0 9.47 .5.5 0.428 1(.0 9.02 -9.7 

1.1-DCA- 0.446 10.0 9.62 -3.8 0.436 10.0 9.40 -5.9 

II.DCE# 0.089 10.0 9.74 .2.6 0.085 10.0 9.31 -7.0 

1.2-Dichloropropanc# 0.261 10.0 9.83 -1.7 0.246 10.0 9.26 -7.3 

BT0M0f0M- 0.118 10.0 10.32 1.6 0.100 10.0 8.63 -13.9 

Chlombenzene* 1.056 10.0 9.63 -1.61 1.0351 10.0 9.651 -3.5 

Chlomforn# 

k1oro=thane- 

0.443 

0.158 

10.01 

10.0 

9. 

9.75 

-3.61 

-2.31 

0.4351 

0.1601 

10.0 

10.0 

9.46 

9.87 

-5.4 

-1.0 

nyl chloride# 0.145 10.0 9.26 -7.31 0.151 10.0 9.68 -3.4 

SpCCS CCCS 

Comments: 

AFCEE FORM O-5A Page 2 of 2 

RDD-11 W DSMWT-SR 2702-DIIG4)027


1-77 5 i 17 ORGANIC ANALYSES DATA SHEET 6 Version 3. 0 

BLANKS March 1998 


Lab Name: CAS[LAB/RDD Contract #: F41624-94-D-8053 

Concentration Units (ug/L or mgfkg): ug/L Method Blank ED: C0405WO2 

Lab Sample ID: C0405WO2 

Analyte MDL Method Blank RL Q 

1, 1, I -TCA 0.12 0.12 0.8 

1, 1,2,2-Tetrachloroethane 0.12 0.12 0.4 

1, 1,2-TCA 0.11 0.11 1.0 

II-DCA. 0.12 0.12 0.4 

II-DCF 0.09 0.09 1.2 

1,2-DCA 0.13 0.13 0.6 

1,2-DCB 0.11 I 0.11 0.3 

1,2-Dichloropropane 0.11 0.11 0.4 

I,3-DCB 0.10 0.10 1.2 

I,4-DCB 0.12 0.12 0.3 

Bromobenzene 0.13 0.13 0.3 

Bromodichloromethane 0.12 0.12 0.8 

Bromoform 0.09 0.09 1.2 

Bromomethane 0.16 1 0.16 1.1 

Carbon tetrachloride 0.10 0.10 2.1 

Chlorobenzene 0.11 0.11 0.4 

Chloroethane 0.12 0.12 1.0 

Chloroform 0.11 0.11 0.3 

Chloramethane 0.07 0.07 1.3 

Cis-1,2-DCE 0.12 0.12 1.2 

Cis- 1,3-Dichloropropene 0.08 0.08 1.0 

Dibromochloromethane 0.09 0.09 0.5 

Dibromornethane 0.09 0.09 2.4 

Mcthylene chloride 0.13 0.13 0.3 

TCE 0.12 0.39 1.0 

Tetrachloroethene 0.12 0.12 1.4 

Trans-1,2-DCE 0.11 0.11 0.6 

Trans- 1,3-Dichloropropene 0.08 0.08 1.0 

Trichlorofluoromethane 0.11 0.11 0.8 

Vinyl chloride 0.13 0.13 1.1 

Comments: 

AFCEE FORM 0-6 Page I of 4 RDMTC.,.IPsr-. .2.2-40 0 2 8



ORGANIC ANALYSES DATA SHEET 6 1 7 7 5 1 1 8 Version 3. 0 



Concentration Units (ug/L or mglkg): ug/L Method Blank ID: C0405WO2 

Lab Sample ID: C0405WO2 

Cornments: 

Analyte M1I)L Method Blank RL Q 



Toluene-138 106 75-125 

4-Bromofluorobenzene 114 75-i-25 

-------------------- 


Fluorobenzene 




RD&l 1 TC BS-102ZPSr-&q.2702-TT0029


7 7 5 1 1 9 ORGANIC ANALYSES DATA SHEET 6 Version 3.0 

BLANKS M4rch 1998 



Concentration Units (ug/L or mglkg): ug/L MethodBlankID: C0406WOI 

Lab Sample ID: C0406WOI 


1, 1, I -TCA 0.12 0.12 0.8 

1, 1,2,2-Tetrachloroe thane 0.12 0.12 0.4 

1, 1,2-TCA 0.11 0.11 1.0 

Il-DCA. 0.12 0.12 0.4 

II-DCE 0.09 0.09 1.2 

1,2-DCA 0.13 0.13 0.6 

1,2-DCB 0.11 0.11 0.3 


1,3-DCB 0.10 0.10 1.2 

1,4-DCB 0.12 0.12 0.3 



Brornofonn 0.09 0.09 1.2 

Iromornethane 0.16 0.16 1.1 





Chloromethane 0.07 0.07 1.3 

Cis-1,2-DCE 0.12 0.12 1.2 

Cis-1,3-Dichloropropene 0.08 0.08 1.0 

Dibromochloromethane 0.09 0.09 0.5 

Dibromomethane 0.09 0.09 2.4 

Methylene chloride 0.13 0.13 0.3 

TCE 0.12 0.12 1.0 


Trans-1,2-DCE 0.11 I 0.11 0.6 

Trans-1,3-Dichloropropene O08 0.08 1.0 


Vinyl chloride 0.13 0.13 

Comments: 


BWJIP-Sff.D"fyf) 0 j 0


AFCEE 1775120 AFCEE QAPP 




Concentration Units (ug/L or mgfkg): ug/L MethodBlankID: C0406WO1 

LabSampleID: C0406WOI 

Comments: 




Toluene-D8 96 75-125 


Fluorobenzene 

Chloroberizene-d5 




RD& II. IC. BS-09VP-SkD2702-D 010 0 3 1

AFCEE QAPP 

177519" 1 AFCEE Version 3.0 

ORGANIC ANALYSES DATA SHEET 7 March 1998 




LCS ID: C0405WO2LCS Concentration Units (ug/L or mg/kg): ug/L 

Date Extracted: Date Analyzed: 5 Apr 00 

Analyte Expected Found %R Control Limits Q 

1, 1, I -TCA 10.00 9.21 92 75-125 

1, 1,2,2-Tetrachloroethane 10.00 10.67 107 74-125 

1, 1,2-TCA 10.00 10.58 106 75-127 

II-DCA 10.00 9.94 99 72-125 

1,1-DCE 10.00 8.35 84 75-125 

1,2-DCA 10.00 9.23 92 68-127 

1,2-DCB 10.00 9.78 98 75-125 

1,2-Dichloropropane 10.00 10.30 103 70-125 

1,3-DCB 10.00 9.80 98 75-125 

1,4-DCB 10.00 9.65 96 75-125 

Bromobenzene 10.00 9.35 94 75-125 

Bromodichloromethane 10.001 9.40 941 75-125 

Bromoform 10.00 9.62 96 75-125 

Bromomethane 10.00 9.45 94 72-125 

Carbon tetrachloride 10.00 9.21 92 62-125 

Chlorobenzene 10.00 9.91 99 75-125 

Chloroethane 10.00 8.29 83 65-125 

Chloroform 10.00 9.71 97 74-125 

Chloromethane 10.00 8.47 85 75-125 

Cis- 1,2-DCE 10.00 10.20 102 75-125 

Cis- 1,3-Dichloropropene 10.00 10.70 107 74-125 

Dibromochloromethane 10.00 9.20 92 73-125 

Dibromomethane 10.00 9.97 100 69-127 

Methylene chloride 10.00 7.96 80 75-125 

TCE 10.00 10.56 106 71-125 

Tetrachloroethene 10.00 9.41 94 71-125 1 

Trans-1,2-DCE 10.00 7.88 79 75-125 

Trans- 1,3-Dichloropropene 10.00 11.03 110 66-125 

Trichlorofluoromethane 10.00 7.72 77 67-125 

1 Vinyl chloride 10.00 8.40 84 46-134 

Comments: 


L . 80937P-SR702-DZO 0032


AFCEE QAPP 

AFCEE 1 7 7 5 1 2 2 Version 3.0 




LCS ID: C0405WO2LCS Concentration Units (ug/L or mg/kg): ug/L 


Comments: 




Toluene-138 108 75-125 



Fluorobenzene 



AFCEEFOPN40-7 Page2of`4 

RD&ilXOS-0937PSr-SR.DW270l-D20 0 0

AFCEE QAPP 

7 5 2 3 AFCEE Version 3.0 





LCS ID: C0406WOlLCS Concentration Units (ug/L or mgfkg): ug/L 


Analyte Expected Found %R Control Limits 

1, 1, I -TCA 10.00 9.26 92 75-125 

1, 1,2,2-Tetrachloroefliane 10.00 9.68 97 74-125 

1, 1,2-TCA 10.00 9.32 93 75-127 

II-DCA 10.00 9.51 95 72-125 

1,1-DCE 10.00 9.11 9 1 75-125 

1,2-DCA 10.00 9.051 90 68-127 

1,2-DCB 10.00 9.64 96 75-125 


1,3-DCB 10.00 9.87 99 75-125 

I,4-DCB 10.00 9.62 96 75-125 

Bromobenzene 10.00 9.42 94 75-125 

Bromodichloromethane 10.00 9.14 91, 75-125 

Bromoform I 0,00 9,36 94 75-125 

Bromomethane 10.00 10.35 104 72-125 



Chloroethane 10.00 9.24 92 65-125 

Chloroform 10.00 9.53 95 74-125 


Cis-1,2-DCE 10.00 9.74 97 75-125 





TCE 10.00 9.11 9 1 71-125 

Tetrachloroethene 10.00 9.74, 97 71-125 

Trans-1,2-DCE 10.00 8.64 86 75-125 

Trans-1,3-Dichloropropene 10.00 10.18 102 66-125 


Vinyl chloride 10.00 9.48 95 46-134 

Comments: 


9DJ I TC 9"37P-Sft 2702-D, 

00034


AFCEE QAPP 

AFCEE 1 7 75 12 4 Version 3.0 




LCSID: C0406WOlLCS Concentration Units (ug[L or mg/kg): ug/L 


Comments: 




Toluene-138 94 75-125 



Fluorobenzene 



AFCEE-FORMO-7 Page4of4 

RD11 TCBS-W37P-SR.D2702-0.0035

AFCEE QAPP 

Version 3.0 

1775 1 2 5 March 1998 

AFCEE 


HOLDING TIMES 

Analytical Mediod: SW8260B AAB #: D2702 


lst Max. Ist 2nd Max. 2nd Max. Time Q 

Field Sample ID Date Date Date Holding Time Date Holding Time Date Holding Held 

Collected Received Prepared Time 1 Held Prepared Time 2 Held Analyzed Time A Anal. 

WWIWATER(IN) 3OMarGO 31Mar00 N/A N/A N/A N/A N/A N/A 6 Apr 00 1 4 7 

WWIWATER(IN)DL 30 Mar 00 3 i Mar 00 NIA NIA N/A N/A N/A N/A 6 Apr 00 14 7 

WIWATER(OUT) 30 Mar 00 31 Mar 00 N/A N/A NIA N/A N/A N/A 6 Apr 00 1 4 7 

Comments: 

AFCEE FORM 0-9 Page I of I 

2701

AFCEE 


INSTRUMENT ANALYSIS SEQUENCE LOG: 


Lab Name: CAS/LAB/PDD Contract F41624-94-D-8053 

Instrument ID #: MS9 

AFCEE QAPP 

Version 3.0 

1 7 7 5 1 2 6 March 1998 

Field Sample ID/Std. ID/ Laboratory Date Analysis Time Analysis Date Analysis Time Analysis 

Blank ID/QC Sample ID File ID Started Started Completed Completed 

VSTDOO.3 C000788 4 Apr 00 2235 4 Apr 00 2305 

VSTDOO.5 C000789 4 Apr 00 2307 4 Apr 00 2337 

VSTD001 C000790 4 Apr 00 2340 5 Apr 00 0010 

VSTDO05 C000791 5 Apr 00 0013 5 Apr 00 0043 

VSTD010 C000792 5 Apr 00 0045 5 Apr 00 0115 

VSTD015 C000793 5 Apr 00 0118 5 Apr 00 0[48 

VSTDO20 C000794 5 Apr 00 0150 5 Apr 00 0220 

--C-ALTSTD C000795Q 5 Apr 00 0223 5 Apr 00 0253 

VSTD010 C000831 5 Apr 00 2203 5 Apr 00 2233 

C0405WO2LCS C000832F 5 Apr 00 2236 5 Apr 00 2306 

C0405WO2 C000835F 6 Apr 00 0047 6 Apr 00 0117 

WWIWATER(IN) C000849 6 Apr 00 0824 6-Apr 00 0954 

WIWATER(OUT) C000850 6 Apr 00 0856 6 Apr 00 0926 

VSTD010 C000852 6 Apr 00 1000 6 Apr 00 1030 

C0406WOlLCS C000853 6 Apr 00 1033 6 Apr 00 1103 

C0406WO) C000854 6 Apr 00 1105 6 Apr 00 1135 

WWIWATER(IN)DL C000856 6 Apr 00 1211 6 Apr 00 IZ41 

Comments: 

AFCEEFORMO-10 Pagelofl 

RDD.11.rC8S-"J7PST-SR D"Z702-W 00037

AFCEE QAPP 

7 7 5 1 2 7 Version 3.0 

March 1998 

Analytical Method: SW8260B 

AFCEE 


INSTRUMENT PERFORMANCE CHECK 

(BFB or DFTPP) 


Instrument ID: MS9 Compound: BFB Injection Date/Time: 4 Apr 00 2204 

Mass Ion Abundance Criteria % Relative Abundance Q 

15% to 40% of mass 95 28.1 

30% to 60% of mass 95 45.4 

base peak, 100% relative abundance 100.0 

5% to 9% of mass 95 7.3 

-- r73- 0% to less than 2% of mass 174 0.0 (0.0) 

174 greater 50% of mass 95 60.0 

5% to 9% of mass 174 4.4 

--- Tlrc >95%, but


AFCEE 

ORGANIC ANALYSES DATA SHEET I 1 





AFCEE QAPP 

1 7 7 5 1 2 8 Version 3. 0 

March 1998 


= 15% to 40% of mass 95 271 

Irs- 30% to 60% of mass 95 45.2 


5% to 9% of mass 95 -77 

0% to less than 2% of mass 174 0.0 (0.0) 

TTT greater tha 50% of mass 95 50.6 

175 15% to 9% of mass 174 4A 

I /6 1 >95%, but

AFCEE QAPP 

7 7 5 1 2 9 Version 3.0 

March 1998 

AFCEE 

ORGANIC ANALYSES DATA SHEET I I 







15% to 40% of mass 95 2/.9 

73- 30% to 60% of mass 95 45.4 


5% to 9% of mass 95 7.1 

0% to less than 2% of mass 1 /4 0.0 (0.0) 

174 greater 50% of mass 95 58.2 

5% to 9% of mass 174 4.3 (7.5)1 

>95%, but

AFCEE 

ORGANICANALYSESDATASHEETAPPENDIXA, 

SURROGATE RESULTS 


Lab Name: CAS/LABIRDD Contract F41624-94-D-8053 

Matrix: Water 

AFCEE QAPP 

1 7 7 5 1 3 0 "'ers'on 3- 0 

March 1998 

Field/QC Sample ID Si S2 S3 S4 S5 S6 S7 S8 Q 

C0405WO2LCS 102 108 too 

-jO40SW02 9-7 -06 -4 

7VW-WATER(N) 99 97 02 

WATER(OUT) 9-5 9-6 -0 

CD406WOlLCS 97 94 94 

7-04-06W0 9-5 -96 1 -6 

-9W WATE I R(I N) L D 

89 87 92 

SI: Dibromofluoromethane 75-125 

S2: Toluene-D8 75-125 

S3: 4-Bromofluorobenzene 75-125 

Comments: 

AFCEE FORM APPENDIX A Page I of 1 90041 

fiDD-"'11:TC BS0937PST.M.770'.D'70.7-

AFCEE QAFP 

7 7 5 1 3 1 Version 3.0 

March 1998 

AFCEE 

ORGANIC ANALYSES DATA SHEET APPENDIX C 

INTERNAL STANDAP D AREA AND RT SUMMARY 

Analytical Method: SW8260 AAB #: D2702 


Instrument ID: MS9 Date Analyzed: 5 Apr 00 Time Analyzed: 0045 

IS1 IS2 IS3 

AREA TIME AREA TIME AREA TIME 

12 HOUR STANDARD 7206865 9.80 5527909 15-25 2208821 2D.20 

UPPER LIMIT 14413730 10.30 11055818 15.75 4417642 20.70 

LOWER LIMIT 3603433 9.30 1 2763955 14-75 1104411 19.70 

SAMPLE ID 

Www NNM= SN VEN 

C0405WO2LCS 7744464 9.80 5708031 15.25 2307357 20.20 

C0405W02 7899185 9.80 5632396 15.25 1813608 20 21 

WWIWATER(rN) 7038870 9.81 5305945 15.25 1975594 20.22 

WIWATER(OUT) 7147707 9.81 5385528 15.25 1991733 20.21 

[Si Fluombenzene IS4: 

IS2. Ch1ombcnzcnc-d5 IS5: 

IS3: 1,4-DichlombenzeneA4 TS6: 

Upper Limit = + 100% of Internal Standard Area Lower Limit 50% of Internal Standard Area 

Comments: Colurrm used to flag values outside of QC limits with an asteno 

AFCEE FORM APPENDIX C Page 1 00042 

RDD.l I: B09J'P- 270:-D'701.

AFCEE 

ORGANIC ANALYSES DATA SHEET-APPENDIX C 

INTERNAL STANDARD AREA AND RT SUMMARY 



Instrument ID: MS9 Date Analyzed: 5 Apr 00 Time Analyzed: 0045 

gg 

AFCEE QAPP 

1 7 75 1 3 2 Version J. 0 

March 1998 

I I IS2 IS3 


12 HOUR STANDARD 7206865 9.80 5527909 15.25 2208821 20.20 

UPPER LIMIT 14413730 10.30 11055818 15.75 4417642 20.70 

LOWER LIMIT 3603433 9.30 2763955 14.75 1 1104411 19.70 

SAMPLE ID W 

C0406WOlLCS 7552022 9.80 5852403 15.25 2393021 20.20 

CG406WO1 7266301 9.81 5253939 15.25 1523976 20.22 

WWIWATER(IN)DL 7151669 9.80 5412265 15.25 2005420 20.21 

IS 1: Fluorobenzene IS4: 

IS2: Chlorobenzene-d5 IS5 

IS3: 1,4-Dichlombenzene-& IS& 


Cornments: N Column used to flag values outside of QC limits with an asterisk 

AFCEE FORM APPENDIX C Page 2 AD"41 1: TC. 8&0937P-SR. 170'(,z 00 0 4 3

AFCEE QAPP 

I7 7 5 1 3 3 Version 3.0 

March 1998 

MDL STUDY REPORT FORM 

Lab Name: CAS/LAB/RDD Analytical Method: SW8260B Matrix: Water 

Instrument ID: MS9 

Concentration Units (ug/L or mglkg): ug/L 

Replicates 

Analyte Analysis 

Date 

A 

mt- 

Spiked 

2 3 4 

- 

8 

Std. 

Dev. 

MDL 

IJl-TCA 15 Feb 00 0 5 0 50805 0.47006 0.56691 -0.47939 0.56615 0.49381 0.56181 0.50235 0.040258 0.12 

1, 1,2,2-Tetrachloroethane 15 Feb 00 0.5 0.50076 0.47365 0.57071 0.50648 0.57414 0.50152 0,56576 0.50877 0.0388 16 0.12 

1,1,2-TCA 15 Feb 00 0.5 0.49954 0.47648 0.56015 0.49059 0.56412 0.50375 0.56984 0.49781 0.037751 0.11 

IJ-DCA 15 Feb 00 0.5 0.51209 0.47642 0.58227 0.49951 0.57906 0.51545 0.57774 0.51281 0.041546 0.12 

Ij-DCE 15 Feb 00 0.5 0.48708 0.46504 0.54421 0.46491 0.53013 0.52107 0.52707 0.49181 0.030715 0.092 

1,2-DCA 15 Feb 00 0.5 0.50115 0.46971 0-57129 j 0.48752 0.5739 1 0.49358 j 0.56547 0.48777 0.043536 0.13 

1,2-DCB 15 Feb 00 0.5 0.51014 0.47939 0.56174 0.48181 0.55904 0.49373 0.54022 0.48159 0.035077 0.11 

1.2-Dichloropropane 15 Feb w- 0.5 0.48061 0.43916 0.52244 0.45646 0.52712 0.46195 0.52559 0.44927 0.036894 0.11 

1,3-DCB 

1,4-DCB 

15 Feb 00 

15 Feb 00 

0.5 

0.5 

0.5284 

0.54216 

0.49139 

0.50077 

0.57429 

0.59577 

0.48467 

0.48779 

0.55519 

0.58291 

0.49848 

0.50536 

0.54547 

0 

.57226 

0.49806 0.033561 

40882 

.50171 FO- 

0.10 

0.12 

Brornobenzene 15 Feb 00 0.5 0.47931 0.45024 0.54781 0.43232 0.52507 0.44616 0.51529 0.44117 0.044217 

Brornodichlorornethane 15 Feb 00 0.5 0.47014 0.45894 0.54051 0.46605 0.545 (T4-6508 -0.54-606 0.47749 0.039867 

Brorrolionn 

Brornorrethane 

15 Feb 00 

15 Feb 00 

0.5 

0.5 

0.38882 

0.42913 

0.36948 

0.40958 

0.42191 

0.4844 

0.38641 

0.40985 

0.44139 

0.47258 

0.37414 

0.42706 

0.45035 

.57168 

0.40128 0.030465 

.4454 5.054-009 

0. 

0.16 

Carbon tetrachloride 15 Feb 00 0.5 0.49443 0.46165 0.53383 0.46568 0.54261 0.49861 0.55425 0.48867 0.034878 0.10 

Chlorobenzene 

Chloroethane 

15 Feb 00 

15 Feb 00 

0.5 

0.5 

0.52401 

0.49914 

0.48449 

0.41328 

0.55615 

0.4919 

0.48192 

0.5"97 

0.56967 

0.50221 

0.49742 

0.45582 

0.54062 

0.44524 

0.47083 0.037228 

41377 

.45443 FO- 

0.11 

0.12 

Chlorotom 15 Feb 00 0.5 0.52469 0.49842 0.58172 0.5239 0.59516 0.51179 0,59562 0.52689 0.037729 0.11 

Chlorornethane 15 Feb 00 0.5 0.39205 0.35387 0.40422 0.35314 0-40429 0.37499 0.4077 0.39284 0.0222 0.067 

Cis-1,2-E)CE 15 Feb 00 0.5 0 49962 0.46936 0.55274 0.46036 0.54009 0.46551 0.55087 0.46325 0.041449 0.12 

Cis-1,3-13ichloropropene 15 Feb 00 0.5 0.41869 0.38438 0.44062 0 38026 0.45133 0.40022 0.42558 0.39768 0M5939 0.0 

Dibrorroclflororrethane 

Dibrornomethane 

15 Feb 00 

15 Feb 00 

0.5 

0.5 

0.43639 

0.50205 

0-4113 

0.49746 

0.4882 

0.55247 

0.432 

0.50099 

0.49184 

0.55639 

0.43234 

0,49039 

0.4807 

0 

.57133 

0.43447 0.030950 

3IS20 

52091 rO- 

0.093 

0.094 

Methylene chloride 22 Feb 00 1 1.07334 1.15858 1.01863 1.09192 1.04873 1.0981 1.11256 1.11994 0.043509 0.13 

TCE 15 Feb 00 0.5 0.5098 0.47042 0.55059 0.45172 0.54825 0.48268 0.52994 0.46315 0.039166 0.12 

Tetrachloroethene 15 Feb 00 0.5 0 52512 0.48155 0.56546 0.47634 0.56179 0.49006 0.54119 0.46534 0.04 0.12 

Tnns-1,2-13CE IS Feb 00 0 5 0.49967 0.48961 0.54914 0.47705 0.55319 0.47868 .54996 0.47016 0.036155 0.11 

Trans-1,3-Dichloropropene 15 Feb 00 0 5 0 40739 037909 0.42935 0.38821 0.44193 0.3804 0.43236 0.37144 0 027732 0.083 

Trichlorotluoromethane 15 Feb 00 0 5 0.45817 0.41683 0.49789 0.44762 0.52664 0.46577 0.51415 3 0 H 

Vinyl chloride 15 Feb 00 0.5 0.37735 0.30439 0.36234 0.35263 0.3948 0.32427 0,36363 0.26343 0.042975 0.13 

MDL FORM Method SW8260 Page I of I 

RD&"411 M8WVP 2701-0,1-0004 4

CHAIN OF CUSTODY DOCUMENTATION 

1 7 

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Section Tab 

A rld 

1 7 7 5 1 3 6

I 

0 

ww-I 


Second Quarter 2000 Report 

I 

I 

'6I'A 


August 2000 

1 7 75 1 3 7

ww-1 


Second Quarter 2000 Report 

ww-1 


Preparedfor: 


Environmental Restoration Division (AFCEE/ERD) 



Prepared by: 

CH2M HILL 



August 2000 

1 7 75 1 3 8

I 

1 7 7 5 1 3 9 




146680.92.94 

MDH/BMF 

0

Notice 















NOTICE&PREFACE DOC 

146680 

1 7 7 5 1 4 0

Preface 

1 7 7 5 1 4 1 

This report presents findings obtained from the second quarter 2000 opfin-dzation, operation 



Mr. Jon Haliscak, Air Force Center for Environmental Excellence, Environmental Quality 

(AFCEE/EQ) is the Contracting Officer Representative. 

Approval: 

Mark Henry 


CH2M HILL 

IV NOTICE&PREFACE DOC 

146680

Contents 

Sections Page 

N otice ................................................................................................................................................. III 

Preface ................................................................................................................................................ IV 

List of Acronym s ............................................................................................................................. V II 

1.0 Introduction ........................................................................................................................ 1-1 

1.1 Authorization ............................................................................................................ 1-1 

1.2 Purpose and Objectives ............................................................................................ 1-1 

1.3 Background ................................................................................................................ 1-1 

2.0 Second Q uarter 2000 GTP O perations ........................................................................... 2-1 



2.1.2 Air Phase Analytical Results ........................................................................ 2-2 





2.3 TCE and DCE Rem ovals .......................................................................................... 2-3 

2.4 Plant Operations ....................................................................................................... 2-3 

2.4.1 Operational Param eters ................................................................................ 2-3 

2.4.2 H ours of Operation ....................................................................................... 2-3 


2.4.4 System Shutdow ns/ Alarm Conditions ...................................................... 2-4 

2.4.5 Site Events/ Repairs ....................................................................................... 2-4 

3.0 Recom m endations ............................................................................................................. 3-1 

3.1 W W -l Plant Optim ization ....................................................................................... 3-1 

4.0 References ........................................................................................................................... 4-1 

Appendices 




Tables 

2-1 WW-1 Liquid Phase Analytical Results, Second Quarter 2000 .................................... 2-2 

2-2 Approximate Flow Measurement Information at WW-1, Second Quarter 2000 ....... 2-3 

2-3 WW-1 System Shutdowns/ Alarms, Second Quarter 2000 ........................................... 24 

24 W W -1 Site Activities, Second Q uarter 2000 .................................................................... 2-5 

2-5 W W -1 Site Repairs, Second Q uarter 2000 ....................................................................... 2-5 

1 7 7 5 1 4 

2000 2ND QUARTER DOC V

List of Acronyms 





COC Contarrdnant of Concern 














pg/L micrograms per liter 

MDL Method Detection Lirrdt 



















ACRONYMS.DOC V11 

14980 

7 7 5 1 4 3



1 7 75 1 4 4 


February 1998) of Contract Number F41624-97-D-8019, issued by the Department of the Air 



the Fairchild Air Force Base runway. Fairchild AFB is located west of Spokane, Washington. 

1.2 Purpose and Objectives 

This report presents and summarizes data collected during the second quarter of 2000 for 

the optimization and long-term operation and maintenance (LTO) of the groundwater 

extraction and treatment system at the WW-1 site. 


The WW-l site consists of two interconnected industrial wastewater lagoons, a skimming 


stormwater and industrial wastewater generated on the base. TrichlOToethene (TCE) is the 






using air stripping and/or carbon adsorption for remediation of affected groundwater 





Associates. 

On March 1, 1997, CH2M HILL assumed primary responsibility for the optirnization, 




20DO 

2ND QUARTERDOG 

146680

2.0 Second Quarter 2000 GTP Operations 

This section presents and discusses data collected during LTO of the groundwater pumpand-treat 

system at WW-1 for the second quarter of 2000. 




Work Plan (CH2M HILL, March 1999b) and Sampling and Analysis Plan (SAP) 

(CH2M HILL, March 1999a). 


• Appendix A-1 Inspection/ Maintenance Forms 



• Appendix A-4 Incidental Water Treatment Forms 


• Appendix A-6 Event/ Repair Forms 







permitted standards. Performance monitoring is performed in compliance with the SAP 

(CH2M HILL, March 1999a) and includes quarterly water samples collected from the plant 

influent and plant effluent and annual air samples collected from the influent to the lead 

GAC unit, intermediate (influent into the lag GAC unit), and effluent from the lag GAC 

unit. 

The base submitted a request to Spokane County Air Pollution Control Authority 

(SCAPCA) during this quarter to reduce the frequency of air sampling from quarterly to 

annually. SCAPCA approved the request and made the appropriate modifications to 

NOC#679 (SCAPCA, June 2000). 


Influent and effluent water samples were collected on June 27, 2000, and analyzed for 

volatile organic compounds (VOCs) using EPA Method 8260, in accordance with the 

AFCEE Quality Assurance Project Plan (QAPP) version 3.0 (AFCEE, March 1998). In 

addition, matrix spike and matrix spike duplicate (MS/ MSD) and field duplicate samples 

were collected from the plant effluent in compliance with the SAP. Table 2-1 summarizes 

20DO 2ND OUARTER DOC 2.1 

1 7 7 5 1 4 5

1 7 7 5 1 4 6 WN-1 SECOND QUARTER 2OW REPORT 

the results for TCE, cis-1,2-dichloroethene (cis-DCE), and vinyl chloride (VC). Complete 

analytical data packages are included in Appendix C. 

TABLE 2.1 

WW-1 Liquid Phase Analytical Results, Second Quarter 2000 

TCE cis-DCE Vc 

Sample Location (pg/L) (pg/L) (pg/L) 

Plant Influent 2.94 4.39 0.13 U 


Qualifiers: 

U = The analyte was analyzed for,but was not detected. The associated numerical value is at or below the 

method detection limit (MIDL). 

Laboratory analytical results (data reports) for water samples collected during this quarter 

are presented in Appendix C. 


Air samples were not collected during this quarter. The next air sampling event will occur 

during the first quarter of 2001. 


The WW-1 GTP operated within regulatory compliance limits for the second quarter of 

2000. Trichloroethene was not detected in liquid discharge samples (the liquid discharge 

limit for TCE is 5-11g/L). 


2 .2.1 Flow Measurement System 







2.2.2 VolumeofWaterTreated 


total volume of water treated during the second quarter of 2000 was approximately 1.2 

million gallons. The average flow rate of extracted groundwater through the GTP during 

the quarter was approximately 10 gallons per minute (gpm). The total amount of 

groundwater treated at the WW-1 GTP from March 1, 1997, through the end of this quarter 

is approximately 20.6 million gallons. A more detailed description of the flows and readings 

are included in Appendix B as Tables B-1 and B-2. 

2-2 2000 2ND QUARTER.DOC

TABLE 2-2 

Flow Measurement Information at WW-1, Second Quarter 20008 

1 7 7 5 1 4 7 

WW-1 SECOND QUARTER M REPORT 

Period of EWjb Well Point Systeme Total Plant Discharge (P-5) 

Operation 

Total Total Total 

Volume Flow Rate Volume Flow Rate Volume Flow Rate 

(gallons) (gpM)d (gallons) (gpM)d (gallons) (gpM)d 

April 278,505 7.5 102,116 2.7 380,621 10.2 

May 330,760 7.4 106,505 2.4 437,265 9.8 

June 263,535 6.6 135,571 3.4 399,106 10.0 

Second Quarter 872,800 7.2 344,192 2.8 1,216,992 10.0 

aSee Appendix B (Flow Summary) for further details 

ÈW-1 Total Volume is corrected by subtracting the amount of re-circulation volume during routine cleaning. 

cWell Point System Flow Rate is not directly measured. It is assumed to be the difference between the Total Plant 

Discharge (P-5) and EW-1. 

dFlow Rate is calculated as a total monthly average by dividing the total flow by plant operating time. 


The estimated quantities of TCE and cis-DCE removed from the extracted groundwater 

during the second quarter of 2000 were calculated by multiplying quarterly concentrations 

by the total flow volume treated for the quarter. It is assumed that the air stripper had 100 


measured below the minimum detection limits in the plant discharge sample. The estimated 

quantities of TCE and cis-DCE removed were 0.03 pound and 0.04 pound, respectively. 




updated WW-1 Operations and Maintenance Manual (CH2M HILL, June 1998) and 

manufacturers' specifications. Second quarter.2000 readings are included in Appendix A. 


The WW-1 GTP operated for 2,030 hours during the second quarter of 2000. The GTP was 

shutdown for a total of 154 hours during the quarter as a result of several power failures. 


Approximately 45 gallons of incidental water were treated at the GTP. This water was 

generated by EA during their quarterly LTM sampling event. The Water Treatment 

Approval Form is included in Appendix A-4. 

2000 2ND QUARTER DOC 2-3

17 7 5 1 4 8 WW-1 SECOND QUARTER M REPORT 


A system shutdown is defined as any alarm or maintenance issue that results in plant down 

time of one hour or more. Table 2-3 summarizes the system shutdowns and alarms for this 

quarter. There was one Alarm response during the second quarter of 2000. The Alarm 

Response Form is provided in Appendix A-7. 

TABLE 2.3 

WW-1 System Shutdowns/Adarms, Second Quarter 2000 

Date Hours of Plant Shutdown Alarm Reason 

4/5/2000 3a No Power failure 


4/15/2000 4 Yes Power failure 


4126/2000 to 43a No Power failure 

4/27/2000 

4/28/2000 16a No Powerfailure 

6/11/2000 to 20a No Powerfailure 

6/12/2000 

6/1512000 to 32a No Power failure 

6/16/2000 


allours of Plant Shutdown are estimated. These estimates are based on a review of average daily flow rates and 

operator observations. 

2.4.5 Site EventS/Repairs 

Table 2-4 summarizes site activities for the second quarter. 

TABLE 2-4 

WN-1 Site Activities, Second Quarter 2000 


4/1212000 to Routine chlorinating and recirculating of EW-1 (36,359 gallons circulated) 

4/13/2000 

6/6/2000 Routine screen scrubbing of Well Point System 

6/9/2000 Treated 45 gallons of incidental water 

6/12/2000 to Routine chlorinating and re-circulating of EW-1 (33,321 gallons circulated) 

6/13/2000 

24 2DDO 2ND GUARTEP DOC

1 7 7 5 1 4 9 

WW-1 SECOND QUARTER 2000 REPORT 


Repair #16, which was initiated during the fourth quarter 1999, was completed. Repair #17 

was initiated during the first quarter of 2000 and is ongoing. Table 2-5 summarizes these 

repairs. The Event/ Repair Forms are provided in Appendix A. 

TABLE 2-5 

WW-1 Site Repairs, Second Quarter 2000 

Date 


10120/99 1 6 Completed Flow meter calibration. 

03/06/00 1 7 Ongoing Miscellaneous work items, including reconnaissance for WW-1 

source investigation, fire alarm system repair, and data validation to 

get historical treatment plant analytical data ready for ERPIMS. 

2000 2ND QUARTER DOC 2-5



The following are recommended to further optin-Lize WW-1 plant performance: 




• Modify the Well Point System to eliminate unnecessary valves, pipe, fittings, etc. to 


Both of these recommendations are temporarily on hold. Based on the outcome of the 

ongoing source investigation/potential soil removal action (upgradient of MW-102), these 

recommendations may not be necessary. Currently, source removal activities are scheduled 

for fourth quarter of 2000. Following the source removal activities, these recommendations 

will be revisited and reanalyzed for plant optimization effectiveness. 

1 7 7 5 150 

2DDO 2ND QUARTER.00C 3-1




CH2M HILL. Final Sampling and Analysis Plan Addendum for Groundivater Monitoring and 

Pump and Treat Systems Operation, Craig Road Landfill and VWA Sites, March 1999a. 

CH2M HILL. Final Work Plan for Pump and Treat Systems Operation, Craig Road Land/ill and 

M-1 Sites, March 1999b. 

CH2M HILL. Update to Roy F. Weston, Inc. January 1997, Fairchild AFB Groundimter 

Extraction and Treatment System WasteuYater Lagoons WW-I (AF Site VVP-03), Operations and 

Main tenance Manual, June 1998. 

Halliburton NUS (Halliburton NUS Environmental Corporation). Record of Decision for the 


Spokane County Air Pollution Control Authority (SCAPCA). Request and Approval for 

Modifications to the Sampling Frequency at WW-1, letter written to Bruce Oshita/ Fairchild 

AFB from Kelle Vigeland/SCAPCA, June 2000. 

URS Consultants, Inc. VVW-1 (A F Site VVT-03) Treatment System Addenda, April 1995. 



1 7 75 1 5 

2000 2ND QUARTER DOC 4 1

Appendix Tab 

"o;etic" X 

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1 7 75 1 5 2

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Appendix Tab 

Y- - CZ 

Pkf-vachokl we(1 Uo-(& Summaxic, 

1 7 7 51 5 9



1 7 75 1 6 0 


EW-1 EW-3 P-6 


Date Time Initia's (gpm) (gallons) (gpm) (gallon WPM) (gallons) 

0 bv& o-yoo && 7, 0 V00Y .77 

cylako 7, 'o -4,t,, z, j ell 2 1 0 Z et 17110, e 

e6dq '14'gz' A 4 //10 ' 14 / .1 21- .7 Z A) 

4A 7- 10,06 7 2 t W .27 1?7b y Y10 

f 6 1131bo efoo ell */ V, o 73?1 Z:i-pof- 7 Y71,IVI 

6 p 4 /., " f OD AL el, II(,A '16 .2,7 11,026 I/ b 

O 4 11-3 b 0 O'p -.,e* it - 16,-e I :Z v-1Z b 6 

0 4 lo/f., o7 (i 7, 1;? 7,1 9 q1 7,*k)7 

AL 7,3 2_! 7 P411 gr 

p -112 E 7 f fd3-g e) 

WW-I Flow kbster.)ds 06/02/2000 REVISED, FES i999

1 7 7 5 1 6 1 




Blower 



Date Time Initials W.C.) (inches w.c.) (inches w.c.) (inches w.c.) (inches w c.) (inches w.c.) I Temp. ff) 

Wolke, -04v I ,,o 12 _,q / O. 42 7. 0 7 5 

0 06 IP P-7,5rd .4 W,- bg L 2 - 0 0, j91 1 19 - 0 71- 67 O 

400el Y/v 1/1,49 /1), 0_ -11, i 7, o $6 

1 

lee, W 115, a I /Y,,o 04 7.10 10, 7,2 

141 /a C ] ;, a .11,ev 12-41Z O 7, 6 !j , d 7 6 

/. A A 0 1,7- O 'P, f) 1, 6 7,_ 4 12 7 2? 

24 _LL0_ ),7_4 O - 6 )I-/) /_ 0 4- 7,1111ok42-4 

Ay 4- 1w Az, I q_ j I X_ 6? /50, L94 Iii O 7, Q 0, 6 vrn 

d?14zjlo 025:"'o A Y I/ #. 0 .1.2 //1 9 a q 

01, 1; Ill. 0 1010 a, 0 17, 61 a, 0 1112 

Comments: 

A Z I/,/- 1A ed, W .7 kyl I Wp 7 

416 -5014 d.Adard a' L ky 0 a-4,2 ii /Al e6 j4- 2 

0 411,Z1,3 6 zCe", f IAII 

o &I, g(le 1) 

C/ 

WW-1 F Masterds iM9f98 REVISED. NOV 1995

is- 

0 

a. m 'S 

< !;Z x4 

1 7 7 1 6 2 0; 

6w 

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t 

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>, Cl) 

C 

V- 

LL 

0 

(L 

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m 

(L 

Cl) 

14 

rn

1 7 7 5 1 6 3 

WW-1 Routin Flow Measurem nts 


Extraction Wells Air Stripper Effluent Pull, 

,zoo 0 EW-1 EW-3 P-5 


Date Time Initials (gpm) (gallons) (gpm) (gallons) (gpm) (gallons) 

yflallolv 110JO '4 *,- "f. / '71,26 I, 'V 2 6 90-075 

also Wv 7, 7f H5 2 7 31' 

6IM/011 O' ?0,0 ,I & " 1 7, 7 0.0 'Y 3 1 .2 7 9.!r; Y10 9 

of)z0va vW1v 

Of&-&O C1 0 .700 

Algv 

ew 

7, 

7"-/ 

2r 4 f f'7,7 

4706 717 

7 7 It 77 Z !5' 

'f Jr/a/00 O ?Y o 7- d ILII Z I qC1;5',l` 

f/Ab /00 Z.-I 11) 30 3 7 I;lf,;7 

VM-1 Flow Master.xis 218/99 REVISED, FEB 1999



1 7 75 1 6 

Pre-Blower Post-Blower Primary GAC Vessel Lag 

Blower 

,7000 Vacuum Aur 

(inches Differential Air Differential Inlet Pressure Outlet Pressure Outlet Pressure ExitAir 

Date Time Initials w.c.) (inches w.c.) (inches w.c.) (inches w.c.) (inches w.c.) (inches w.c.) Temp (-F) 

5/0//#Z2 070 'A vz 147 e5 _/Y 4010 12"o J ,q 1#51 19 74 

7 4- 

6f Iev :4 15, 0 0, Ole 1,7, 6 0" a 151 0 I 7,1 

/Oa 09,00 10, M, q 0,06 /,? , ") 0,0 1010 74 

fz&v t2 qd") 'N If, () . I k1 do.bt 12- 0 6, 0 0110 7 6 

o ./I 1,0,6 j f - L6 6 70 

01041,9") goo, IL10 /0 0 

Comments: 

I 

I 

"W-1 Flow Master is 12r29198 RE\nSED. NOV 1998

in 

CDE (12) OE 

7 7 5 1 6 5 

W 2 

c 

< 

ul 

711 

4- (j) LL 0 

CO 

CL 

Cl) 

t: o C Q 

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LL 

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0 

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2 

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(D 

0. 

0 

ia



1 7 75 1 6 6 

Extraction Wells Air St 

0 

Flow 

EW-1 

Totalizer Flow Flow 

EW-3 

Totali 

Time Initials (gpm (gallons) 9pm) 

yk,-loo 

0 4vl 7, Z 

7 -I- 

oNYo 1,ew 1 7, 0- 1-1/11 7-51a I 

itiV11gloo I aw,,q Ie*) 1 7, H,75.; N 1 9' / F2 7,1> e 5 

14L411,11-tj O f4x Io,*, I 

I'd W// 7/44 v 2ffc/ LW */, I or, 

A-17V 7,;, 

15,7fll!5 I 1 

1qS I 7.7- 7- 

1 

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Ixy/1 I/Ov I'l 1?l I d Ifi *,-A I t'; / O -Z- I 2 7 14 6 717 -YA 

L4&11 O, / 

6 qlal'o I O -,q O 1-44 

2 171 9.Z-dA 

O 4v 41 7 7 Z, 

WWA Flow Masterxis 2111199 REVISED. FEB 1999

17 7516 7 WWA Routine Pump-and Treat System Monitoring 


re- r st- ower mary G sse 

r 

Vacuum r 

(inches ran a Air Di Inlet Pressure et ressure Outlet Pressure 

Date Time a W.C.) s W.C. (inches w.c (inches w.c.) s W.C. (inchesw.c) Temp.(OF) 

omments: 

1AW-1 FIOW MasterAs 12129198 

r 

'010 energy 

w J 

go 

REVISED. NOV 199

E 

a. S 

E E 

CO 

41E CL 

LL 

or 

EL 

CL 

E 

0. 0 1.41 

CL 

E 

x (D 

trip 

Ts 

1 7 75 1 6

Appendix Tab 

_AVKvdix- A-3 

Q(XKWIGVlet Da(-9-SUWvKCki-(fS 

1 7751 6 9

00 0 

CL .0 

FD MO MI 

-71 

-; 

0-0 

CZ 

MO e -§ " 11 l R) % 

0. a!9 z 

'40 

0 Em M- 

CL 

M 

Z= 

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0 ;E 

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ow 

CL A 

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r4, 

0 0 E LD 

r 

gg 

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tt= C. 

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Z 

CL (L 

0 

wo 

cm 

CW S 

1 7 75 1 72 

ow 

Em E 

Lm m a 

FL w 

CL 

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cm 

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0 

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------------talk 

0 tA, 

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';,k Ilk, tm 

Z- NJ 

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tA! 

-AS zkI 4-; 

's E I 

V4 v N, I Ilk. 

tz. z: zz Z: Z 

its 

NJ 

v N\, i 

Ilk

Appendix Tab 

APRvidix, A- .q 

Incideof-etl wova- rrcvhvvn PorM5 

1 7 75 1 7 4


BACKGROUND INFORMATION 


SOURCE (e..g, well pur.gin.g, etc,) We-tt otly"ni'ma 

LOCATION OF SOURCE monitorin.g well number, etc.) 

DATE OF GENERATION 

DATE OF SAMPLING de) 

DATE OF ANALYSIS (attach copy) 


APPROVAL BY 

(Fairchild Air Force Base) 

INDIVIDUAL TRANS EQUILG-WAIM 

NAME FAFB TITLE 


DATE TIME 


QUANTITY OF TRANSFER 111-r44'4 

INDIVIDUAL RECEI UN-Q 

fleerl jAled 

NAME SIGNATURE ORGAN. TITLE 

COMMENTS: 

1 7 75 1 7 5

Appendix Tab 

Appcr0i\1-,& IFo 

amplivn i;iDultrywvv&hoh Fovvls 

1 7 75 1 7 6

FAIRCHILD AFB 1 7 75 1 7 7 



SAMPLING DATE: 6-27-00 

SAMPLE TEAM MEMBERS: ?Vtr i 

SAMPLE MATRIX (circle one): Air( Groundwater Other. 

SAMPLE ID SAMPLETIME CONTAINERID PARAMETERS 

= WV/ WATE Id. 40 4-0-InI VoI95 4FCIr, r2-66 

"Wwi AM It 

w6wel OL,) 

LABORATORY: 1I!4L-Umg1,4 A'A" jZr7(f,,4e- -

Appendix Tab 

I 

Appe vic4 i Y- A- te, 

E;; V) / RCPj- (' v- Form 5 

1 7 7 5 1 7 8



Flow Meter Calibration 


Initial Date: October 20,1999 Completion Date: June 15,200 

Employee Responsible: Bob Worl Title: Treatment Plant QVerato 

Estimated Repair Cost: $1,200.00 Final Repair Cost: $1,592.0 

Est. CH2M HILL Level of Effort (LOE): 2 hrs Final CH2M HILL LOE: 19 hours 

Equipment Purchased: X Yes - No AS-Built Updated -Yes -No 

Nature of the Problem: Suspected flow meter error based on observed differences between 

EW-1 and P-5 discharges. 

Nature of Repair: Function and calibration check of an industrial flow transmitter unit on 

October 20,1999, by Equil2ment Technologv & Desien Inc. 

UACLIENT PROJECT DELIVERYX146680 FAIRCHILMCONTRACT8019 REPAIRSIM-1REPAIR 16.Doc 

1 7 751 7 9





Initial Date: March 6,2000 Completion Date: Ongoin 

Employee Responsible: Bob Worl Title: Treatment Plant 012erato 

Estimated Repair Cost: J2,M Final Repair Cost: Ongoin 

Est. CH2M HILL Level of Effort (LOE): 20 hrs Final CH2M HILL LOE: Ongoin 

Equipment Purchased: -Yes - No AS-Built Updated -Yes -No 

Nature of the Problem: Miscellaneous work items identified by CH2M HILL and 

miscellaneous small repairs completed at the direction/request of Fairchild AFB personnel. 


1. Reconnaissance for WW-1 source investigation 

2. FireAlarmSystemrepaironMarch22,2000,byGeneralFire 

3. Compilation of electronic data deliverable, data validation, preparation of 

ERPIMS submittal for treatment plant analytical data, and site survey to obtain state 

plane coordinates for treatment plant sampling locations. 

UACLIENT PROJECT DELIVERY1146680 - FAIRCHILOkCONTRACT8019 REPAIRSWIN-1 \REPAIR 17.Doc 

1 775i8o

Appendix Tab 

Awrdix A--* 

Alo-rvo espovi-56 Fov,-m5 

1 7 751 81

CH2M Hill -- Alarm Response Form 1 7 7 5 1 8 

WWI Site, Fairchild Air Force Base 

Date: &f,114E /&_e_ Time: ProjectNo.: 146680. 

RepairNumber: # (if applicable) Repair Needed: - Yes zY No 

Employee Responding: -(initial responder) LOE: -,,7- lrs 

Employee Responding: LOE: hrs 


Alarm 

Cause of Problem: 

Actions Taken: 41 49- ZY-4/h 2'Pa 2 74 Q 

INITIATE REPAIR: DATE' 

REPAIR COWLETED: DATE:

Appendix Tab 

?4rj I -Y- B 

POW -,)Vvl voav- 

1 7 75183

WWA Site Flow Summary (Table B-1) 


flow meter measures the flow coming from that well. The total flow discharged by the GTP, 


P-5 flow meter. The discharge from the plant (approximately 27 gpm) is intermittent and 

cycles as the air stripper effluent sump fills. There are no flow monitoring systems for the 

Well Point System, which includes EW-3, WP-1, WP-2, and WP-3. As a result, flow 

generated by the Well Point System is estimated by calculating the difference between the P- 

5 and EW-1 flow meter values. 

Average flow rates are also calculated for each system by dividing the daily flow volumes 

by the operating time in minutes for each month. 

As reported in Table B-1, the calculated average flow rate values for EW-1 on April 13, 2000, 

and June 13, 2000, are zero. This zero values are a result of re-circulating EW-1 during 

routine maintenance beginning on April 12,2000, and June 12,2000, respectively. During 

the maintenance of EW-1, the discharge line is connected in a circuit to flush chlorinated 

water through the system for about a 24-hour period. The flow meter for EW-1 registers the 

circulating flow, which creates a false influent flow reading at the GTP. The only flow into 

the GTP during this time is from the Well Point System. Consequently, the average 

calculated flow rate for P-5 is equal to the average calculated flow rate for the Well Point 

System. 

Also, as reported in Table B-1, calculated flow rates for the Well Point System had a steady 

decline from May 1, 2000, to May 26, 2000, with a rebound back to normal on June 1, 2000. 

The cause for this decline is unknown. The jet port vacuum readings did not shown any 

unusual trends during the month of May. The difference in flows from EW-1 and P-5 will be 

carefully monitored during the next quarter to help pinpoint the problem. 

2000 WWA Site Flow Summary (Table B-2) 


Point System, and P-5 through the second quarter of 2000. The flow rates are calculated by 




above. 

SPMPPENDIX 8 DOC 

7 75 1 8 4

Table B-1 

WWA Site Flow Summary, Second Quarter 2000 

EW-I Well Point System Total Plant Discharge (P-6) 


Flow Rate Flow Volume Average Flow Volume Average Flow Rate Average Flow 

Date Time (gpm) (gallons) Flow Rate (gallons) Flow Rate (gpm) Flow Rate Volume 

(gpm) (gpm) (gpm) (gallons) 

0410112000 850 7.2 13,397,200 7.3 4,299,825 2.7 27 9.9 19,419,744 

04/04/200C 11:00 7.2 13,428.525 7.0 4,311,355 2.6 27 9.6 19.462.599 

04/06/200 11.40 1 7.2 13,438,567 7.7 4,314,469 2.4 27 10.1 19,475,755 

04/07/2000 8:30 7.2 13,447,530 7.2 4,317,349 1 2.3 26 1 95 19,487,598 

04/10/2000 9:00 7.1 13,478,376 7.1 4,325,973 2.0 26 9.1 19,527,068 

04/'12/2000 9:00 7.1 13,498,756 7.1 4,330,247 1.5 26 8.6 19.551,722 

04/13/2000 8:00 8.3 13,535,115 0.0 4,297,776 2.8 27 2.8 19,555,610 

0411612000 7.00 7.9 13,563,099 7.8 4,303,721 1.7 27 9.4 19.589,539 

04119/2000 8.30 7.6 13,596,750 7.6 4,313,220 2 2 27 9.8 19,632.689 

04121/2000 8:30 8.5 13.621,302 8.5 4,323,971 3.7 27 12.3 19,667,992 

0412512000 9:00 1 8.1 13,669,367 8.3 4,346,120 3.8 26 12.1 19,738,206 

04/2712000 10:30 8.1 13,672,529 T9 4,347,560 1 3.6 26 11.4 19,742,808 

0412812000 12 30 81 13,677,443 8.0 4,349,890 3.8 26 11.7 19,750,052 

05/01/2000 10.30 8.1 13,712,064 8.2 4,365,582 3.7 26 '12.0 19,800,365 

05/05/2000 9:00 7.9 13,757,459 8.0 4,385,057 3.4 27 11 4 19,865,235 

05111/2000 9:00 7.7 13.824,633 7.8 4,406,056 24 27 10.2 19,953,408 

05/1212000 9:00 7.6 13,835,582 7.6 4,408,964 2.0 27 9.6 19,967,265 

05/1712000 9:00 7.4 13,890,039 7.6 4,419,263 1.4 26 9.0 1 20,032,021 

05123120001 8:30 1 7.0 13,952,333 72 4.424,299 0.6 27 7.8 20,099,351 

05/26/2000 8:00 7.1 13,982,303 7.0 4,424,511 0.0 27 7.0 20,129,533 

06/0112000 9:00 7.0 14,D42,824 70 4.472.087 5.5 27 12.4 20,237,630 

06/06/2000 7:50 7.3 14,091,235 6.8 4,485,346 1.9 26 8.6 20.299.300 

06/08/2000 8 00 6.8 14.110,516 6.7 4,493,009 27 27 9.3 20,326,244 

06/12/2000 9:00 7.1 14,140,072 1 6.4 4,507,549 3,1 27 9.5 20,370,340 

D6/13/2000 8:00 8.0 14,173,393 0.0 4,482,269 5.8 27 5.a 20,378,381 

06/16/2000 8:00 9.6 14,186,646 5.5 4,492,675 4.3 27 9.9 20,402,040 

06118/2000 11:00 8.1 14,205,832 7.0 4,5G4,649 4.3 1 27 11.3 20,433,200 

06/2012000 10:00 7.5 14,227,286 76 4.517.342 4.5 27 1 12.1 20,467.347 

06/ 3/2000 8.00 7.3 14,258.430 74 4,534,969 4.2 27 11 20,516,118 

0612712000 10:30 7 14,300,628 7.1 4,557,173 27 1": 20.580,520 

07/01/200 9:00 N 1 14,339,680 6.9 4,574,337 3.0 27 9.9 20,636,736 

Note: The zero values listed in the EW-1 column are a result of re-circulating EW-1 during routine maintenance. 

1 7 751 85 

SPIK/Appendix Table B-1.xIs 146680.92.94

Irst Quarter Summary 

Table B-2 

2000 WWA Site Flow Summary 

EW-1 Well Point m P-5 EW-1 Re-circ 


Operation (gallons) WPM) (gallons) (gpml (gpm) (gallons) 

January 285,962 6.4 123,182 2.8 409,144 9.2 0 

February 261,760 6.4 108,472 2.6 370,232 9.0 35,588 

March 326,917 7.4 146,449 3.3 473,366 10.7 0 

Ist Quarter 874,639 6.7 378,104 2.9 9.6 35-SRR 

EW-I Well Point m P- EW-1 Re-circ 

Period of TotalVolume FlowRate TotalVolume FlowRate TotalVolurne FlowRate Volume 


April 278,505 7.5 102,116 2.7 380,621 10.2 36,359 

May 330,760 7.4 106,505 2.4 437,265 9.8 0 

June 263,535 6.6 135,571 3.4 399,106 10.0 33,321 

2nd Quarter 872,800 7.2 344,192 2.8 1,216,992 -TO-.0 69,680 

SPKIFIow CaIrs.xIs 146680.92.94 

1 7 7 5 1 8 6

Appendix Tab 

ApK rd C4 6 

LT-0 A-Ho-lvhc&,( Oat-OL 

1 7 7 5 1 8 7

Appendix Tab 

Avef rid i x , C. - I 

wa(lc ampe gesu(4-, 

1 7 751 88

July 26. 2000 

Mr. Mark Henn, 

CH2M HILL/SPK 

9 South Washington St.. Suite 400 

Spokane, WA 99204-0219 

Dear Mr. Henry: 

Columbia 

Analytical 

ServiceS INC. 

An Employee-Owned Company 

RE: Analytical Data for Fairchild AFB 

Plant Monitoring 

Reference Numbers: D33) 16 

Enclosed is the amended report for the above mentioned reference number. Please refer 

to the attached amendment report for explanation. 

Columbia Analytical Services appreciates Your business and looks forward to serving your 

analytical needs again. If you should have any questions concerning the data, or if you need 

additional information, please call Client Serv ices at (530) 244-5227. 

Sincerely, 

41 

Bryan Jones 

Client Services/Project Manager 

Enclosures 


1 7 7 5 1 8 

5090 Caterpillar Road - Redding, CA 96003 * Telephone (530) 244-5227 Fox (530) 244-4109 

0 0 0

AMENDMENT REPORT 

Date: July 6, 2000 Client: CH2M Hill 

Reference No: D33.16 Project Name: Fairchild AFB 

Pkg. Level: I Completed by: Brian Moore 

Method(s): 8260 Approved by: 

Amendments completed and Reason(s): 

Reissue entire report using AFCEE Forms. 

Amendment Justification: 

0 Reporting error 

0 Calculation error 

0 Missing information/data 

0 Wrong information/data. 

0 Analytical problem/correction 

0 Sub-lab error 

0 Client change/request 

rx-I Other (define) Log-in error 

EDATA 0 Required El Not Required 

1 7 75 1 9


Level III 

TABLE OF CONTENTS 

Cover Page ....................................................................................................................... I 


A FCEE D ata Qualifiers .................................................................................................... 3 


1 7 75 1 9 I 

Page 

No. 

G C/M S V O LATILE O RG AN ICS .................................................................................... 5 

Case narrative ..................................... .................................................................... 6 

A FCEE Form 0 -1 ................................................................................................... 7 

A FCEE Form 0 -2 ................................................................................................... 8 

A FCEE Form 0 -3 ................................................................................................. 20 

A FCEE Form 0 -4 ................................................................................................. 26 

A FCEE Form 0 -5 ................................................................................................. 28 

A FCEE Form 0 -6 ................................................................................................. 31 

A FCEE Form 0 -7 ................................................................................................. 33 

A FCEE Form 0 -8 ................................................................................................. 35 

A FCEE Form 0 -9 ................................................................................................. 37 

A FCEE Form 0 -1 0 ............................................................................................... 38 

A FCEE Form 0 -1 I ............................................................................................... 39 

A FCEE A ppendix A .............................................................................................. 41 

A FCEE A ppendix C .............................................................................................. 42 

M D L Form M ethod 8260 ...................................................................................... 43 

Chain of Custody D ocum entation ................................................................................... 44 

0002

AFCEE Data Qualifiers 






MDL. 





criteria. 





T Tentatively identified compound (using GC/MS). 

1 7 75 1 9 2 

000 3

D 7 5 1 9 3 


CAS Client Receive Collect 

Lob Sample ID Sample ID Date Date Semple Matrix Additional Description 

FS = Field Sample; LCS = Lab Control Sample; MS = Matrix Spike; MSD Matrix Spike Duplicate; NON Non-Sampte 

Type (Internal Admin); TB = Trip Blank 

D3316000 NON EDATA 06128/00 06/28/00 00:00 Administration EDATA 

D3316001 FS WW1WATER(IN) 06/28/00 06/27/00 10:40 Water 0006WWlWATER(IN) 

D3316002 FS 1WATEROUT 06/28/00 06/27/00 10:30 Water 0006WWlWATER(OIJT) 

03316OD2MS MS 1WATEROUTMS 06/28/00 06/27/00 10:30 Water 0006WWIWATER(OtJT)MS 

D3316002MSD MSD IWATEROUTMSD 06/28/00 06/27/00 10:30 Water OOO6WWIWATER(OLJT)MSD 

D3316003 FS 0O6WW1WATER2 06/28/00 06/27/00 11:00 Water 0006WWIWATER2 

D3316004 TB TRIP BLANK 06/28/00 06/27/00 00:00 Water TRIP BLANK 

The above Lab sample ID-s and cross reference information apply to samples as received by the Laboratory. Modifiers 

to the !ab sample ID my be added for internal tracking purposes. Any modified sample ID wiH be reflected in th 

appropriate case narrative rely. 

0004

GUMS VOLATILE ORGANICS 

1 7 751 9 4. 

0005

CAS Lab Reference No.: D-,316 

prcDe--t: -airch-'d AFB rq! DX- 

I. RECEIPT 

CASE NARRATIVE 1 7751 95 


ExceDzcn -Reocr', 

is azracned Zo ':,a K 

-cav -n-1-:4=d -- is caa oacage. 

II. HOLDING TIMES 

III. METHOD 

A. Sample Preparat:--.,.: A-'! me. 

B. Sarcle Analvs-,s: hc-d-n- -=.es e-e 

Preoara---7.: 

Cleanup: N /A 

nalys-: SW-346 326--3 


Sample orepara-i,7: cr--ceedec ncrma-'.". 

V. ANALYSIS 

i accec--7.ce 'ne-. 

B. Blanks: All acceptance cr-,reria were mez. 


Surrogaes: All acceptance 2ri-er4a were 7.e:. 

E. Spikes: In the MS/MSD performed on D33160-,2, one or more compounds 

exceeded the recovery and/or RPD- crJteria. e associa'ed LCS met 

al acceola-ce criter4a. 

F. Samples: Sample analysis oroceeded normally. 






-23- 

SIGNED: DATE: 71, 7 /Wb 

Columbia 

,3r,,n Moor, 

Senior Chemist, GUMS 

5090 Caterpillar Road Phone 0006 

(530) 244-5227 

Analytical Sm ices Redding, CA 96003-14 12 Fax (530) 244-4109

AFCEE QAPP 

7 751 9 6 Version 3. 0 

March 1998 

AFCEE 



Lab Name: Columbia Analytical Services/Redding Contract 4: F41624-94-D-8019 


Project: FAIRCHILD AFB WWI PM 

Comments: 



WWIWATER(IN) D3316001 

IWATEROUT D3316002 

IWATEROUTMS D3316002MS 

IWATEROUTMSD D3316002MSD 

006WWIWATER2 D3316003 

TRIP BLANK D3316004 

AFCEE FORM 0-1 

RD&"724 X BIJMPS7-M JI&Dj"07


ORGANIC ANALYSES DATA SHEET 2 1 7 7 5 1 9 7 version 3. 0 

RESULTS I , March 1998 

Analytical Method: SW8260B AAB 9: D3316 


FieldSamplell): WWIWATER(IN) LabSamplell): D3316001 - Matrix: Water 

% Solids: SampleDescription: 0006WWIWATER(IN) 

Date Received: 28 Jun 00 Date Prepared: Date Analyzed: 29 Jun 00 



1, 1, I -TCA 0.12 0.8 0.12 1 U 

1, 1,2,2-Tetrachloroethane 0.12 0.4 OA2 I U 

1,1,2-TCA 0.11 1.0 0.11 I U 

Il-DCA 0.12 0.4 0.12 1 U 

Ij-DCE 0.09 1.2 0.09 1 U 

1,2-DCA 0.13 0.6 0.13. 1 U 

1,2-DCB 0.11 0.3 0.11 I U 


1,3-DCB 0.10 1.2 0.10 I U 

1,4-DCB 0.12 0.3 0.12 1 U 



Bromoform 0.09 1.2 0.09 1 1 1 U 

Bromornethane 0.16 1.1 0.16 1 U 




Chloroform 0.11 0.3 0.55 1 


Cis-1,2-DCE 0.12 1.2 4.39 1 1 





TCE 0.12 1.0 2.94 1 


Trans-1,2-DCE 0.11 0.6 1.97 1 1 



Vinyl chloride 0.13 1.1 0.13 1 U 




iaN0724 W BS-11WST41? 1Xx0J31d-DJ31A- 0008

AFCEE AFCEEQAPP 


1 7 75 1 9 8 RESULTS March 1998 


Lab Name: Columbia Analytical Services/Redding Contract #: F41624-94-D-8019 

Field Sample ID: WWIWATER(IN) Lab Sample ID: D3316001 Matrix: Water 

% Solids: SampleDescription: 0006WWIWATER(TN) 






Toluene-138 114 75-125 


Fluorobenzene 



Internal Standard Qualifler 



AFCEE FOKM 0-2 Page 2 of 12 

)ZD724 X BBWST-M D".131ii-D.1316-V 

0009


ORGANIC ANALYSES DATA SHEET 2 1 7 75 1 9 9 Version 3.0 




Field Sample ID: I WATEROUT Lab Sample ID: D3316002 - Matrix: Water 





1, 1, I -TCA 0.12 0.8 0.12 1 U 


1, 1,2-TCA 0.11 1.0 0.11 I U 

1, I -DCA 0.12 0.4 0.12 1 M 

lI-DCE 0.09 1.2 0.09 1 U 

1,2-DCA 0.13 0.6 0.13 1 U 

1,2-DCB 0.11 0.3 0.11 I U 


1,3-DCB 0.10 1.2 0.10 I U 

1,4-DCB 0.12 0.3 0.12 1 U 



Bromoform 0.09 1.2 0.09 1 U 





Chloroform 0.11 0.3 0.11 I U 


Cis-1,2-DCE 0.12 1.2 0.12 1 U 


Dibromochloromethane 0.09 0.5 0.09 1 1 U 

Dibrornomethane 0.09 2.4 0.09 1 1 U 

Mcthylene chloride 0.13 0.3 0.54 1 

TCE 0.12 1.0 0.12 1 U 


Trans-1,2-DCE 0.11 0.6 0.11 I U 







RDD724 TCBS-026PST JJ1&DJ.11&V 

0010



.1775Z00 RESULTS March 1998 



Field Sample ID: I WATEROUT Lab Sample ID: D3316002 Matrix: Water 



Concentration Units (ugfL or mgfKg dry weight): ug/L Sample Volume: 20.0 ML 

Analyte MDL RL Concentration Dilution Confirm Oualifier 



Toluene-D8 107 75-125 


Fluorobenzene 




Surrogate Recoveries are reported in Appenda O-A 


AFCEE FORM 0-2 Page 4 of 12 RD721 7CfiS-1J16PS7M.D0WJ31&DJJ1&y 0 0


ORGANIC ANALYSES DATA SHEET 2 1 77,5201 llersion.3.0 



Lab Name: Columbia Analytical Services/Redding Contract 9: F41624-94-D-80 1 9 

FieIdSampleID: IWATEROUTMS - LabSampleID: D3316002MS - Matrix: Water 

O/o Solids: SampleDescription: 0006WWIWATER(OUT)MS 




1,1,1-TCA 0.12 0.8 11.23 1 

1,1,2,2-Tetrachloroethane 0.12 0.4 12.42 1 

1, 1,2-TCA 0.11 1.0 11.45 1 

1, I -DCA 0.12 0.4 13.03 1 M 

II-DCE 0.09 1.2 11.56 1 

1,2-DCA 0.13 0.6 11.79 1 

1,2-DCB 0.11 0.3 11.141 1 

1,2-Dichloropropane 0.11 0.4 11.76 1 

1,3-DCB 0.10 1.2 11.22 1 

1,4-DCB 0.12 0.3 10.86 1 

Brornobenzene 0.13 0.3 10.68 1 

Bromodichlorornethane 0.12 0.8 11.26 1 

Brornoform 0.09 1.2 9.56 1 

Brornornethane 0.16 1.1 9.74 I I 

Carbon tetrachloride 0.10 2.1 11.12 1 

Chlorobenzene 0.11 0.4 11.11 I 

Chloroethane 0.12 1.0 12.48 1 

Chloroform 0.11 0.3 11.30 1 


Cis-1,2-DCE 0.12 1.2 11.42 1 

Cis-1,3-Dichloropropene 0.08 1.0 10.83 I I 

Dibromochloromethane 0.09 0.5 10.721 1 

Dibromomethane 0.09 2.4 10.95 1 


TCE 0.12 1.0 11.31 1 


Trans-1,2-DCE 0.11 0.6 11.59 1 

Trans-1,3-Dichloropropene 0.08 1.0 11.21 1 1 



F- i 


Comments: internal Standards are reported inAppendix O-C 

AFCEE FORM 0-2 Page 5 of 12 W724 TC-BS-132eSTS1? 33110331&1` 

0012


7 7 5 202 ORGANIC ANALYSES DATA SHEET 2 Version 3.0 




FieldSamplell): IWATEROUTMS _ LabSampleID: D3316002MS Matrix: Water 

% Solids SampleDescription: 0006WWIWATER(OUT)MS 






Toluene-138 120 75-125 


Fluorobenzene 

Chlorobenzcne-d5 



Surrogate Recowries are reported in Appenda 0-.4 



W724 WB1326PSTM&1)3311V 

001 3


ORGANIC ANALYSES DATA SHEET 2 1775203 version" 




FieldSampleID: IWATEROUTMSD_ LabSampIeID: D3316002MSD - Matrix: Water 

% Solids: SampleDescription: 0006WWIWATER(OUT)MSD 


Concentration Units (ug/L or mg/Kg dry weight): up/L Sample Volume: 20.0 ML 

Analyte MDL I RL Concentration Dilution Confirml Qualifier 

1, 1, I -TCA 0.12 1 0.8 11.08 1 

1, 1,2,2-Tetrachloroethane 0.121 0.4 11.93 1 

1,1,2-TCA 0.11 I 1.0 11.04 1 

II-DCA 0.121 0.4 12.48 1 1 M 

II-DCE 0.09 1 1.2 11.20 1 1 

1,2-DCA 0.131 0.6 I 11.421 1 

1,2-DCB 0.11 1 0.3 1 10.861 1 

1,2-Dichloropropane 0.11 1 0.4 1 11.341 1 

1,3-DCB 0.101 1.2 1 10.921 1 

1,4-DCB 0.121 0.3 1 10.581 1 1 1 

Bromobenzene 0.13 1 0.3 1 10.321 1 1 1 

Bromodichloromethane 0.121 0.8 1 11.011 I I I 

Bromoform 0.09 1 1.2 1 9.27 1 1 1 1 

Bromomethane 0.161 1.1 1 9.551 1 1 1 

Carbon tetrachloride 0.101 2.1 1 11.071 I I I 

Chlorobenzene 0.11 1 0.4 1 10.72 I 

Chloroethane 0.121 1.0 11.86 1 

Chloroform 0.11 0.3 10.90 1 


Cis-I,2-DCE 0.12 1.2 10.95 1 

Cis-1,3-Dichloropropene 0.08 1.0 10.65 1 

Dibromochloromethane 0.09 0.5 10.47, 1 

Dibromomethane 0.09 2.4 10.53 1 

Methylene chloride 0.13 1 0.3 11.09 1 

TCE 0.12 1 1.0 10.91 1 

Tetrachloroethene 0.12 1 1.4 9.13 1 

Trans-1,2-DCE 0.11 0.6 11.15 1 

Trans-1,3-Dichloropropene 0.08 1.0 11.18 1 

Trichlorofluorcimethane 0.11 0.8 11.32 1 



Comments: internal Standards are reported in Appendix O-C 


RDD724 TC SS-IJ26PST-SR D"JJ16-DJJ1'001 4



1775204 RESULTS March 1998 


Lab Name: Columbia Analytical ServicesfRedding Contract #: F41624-94-D-8019 

FieldSampleID: IWATEROUTMSD_ LabSampleID: D3316002MSD Matrix: Water 

% Solids: SampleDescription: 0006WWiWATER(OUT)MSD 

Date Received: 28 Jun 00- Date Prepared: Date Analyzed: 29 Jun 00 





Toluene-138 107 75-125 


Fluorobenzene 





Comments: Internal Standards are reported in Append" O-C 


ROD724 M BS-1326PST DAN73JI&DM60 015

1775205 AFCEE Wattt (aVj)AFCEEQAPP 





FieldSamplelD: 006WWIWATER2 _ LabSampleID: D3316003 - Matrix: Water 

% Solids: SampleDescription: 0006WWIWATER2 




1,1,1-TCA 0.12 0.8 0.12 1 U 


1, 1,2-TCA 0.11 1.0 0.11 I U 

II-DCA 0.12 0.4 0.12 1 U 

II-DCE 0.09 1.2 0.09 1 U 

1,2-DCA 0.13 0.6 0.13, 1 U 

1,2-DCB 0.11 0.3 0.11 I U 


1,3-DCB 0.10 1.2 0.10 I U 

1,4-DCB 0.12 0.3 0.12 1 U 



Bromoform 0.09 1.2 0.09 1 1 1 U 





Chloroform 0.11 0.3 0.11 I U 

Chloromethane 0.07 1.3 0.07, 1 U 

Cis-1,2-DCE 0.12 1.2 0.12 1 1 U 





TCE 0.12 1.0 0.12 1 U 


Trans-1,2-DCE 0.11 0.6 0.11 I U 



Vinyl chloride 0.13 1.1 0.13 I U 

Surrogate Recoveries are reported,. Appenda OA 

Comments: Internal Standards am reported in Appenda O-C 

77-1 

AFCEE FORM 0-2 Page 9 of 12 W724 M LJMPST3316-1)3310'0 1 6






FieldSampleID: 006WWIWATER2 _ LabSarnpleID: D3316003 - Matrix: Water 

% Solids: SampleDescription: 0006WWIWATER2 



Analyte MDL RL Concentration Dilution Con rm ualifier 


Dibrontofluoromethane 94 75-125 

Toluene-D8 107 75-125 


Fluorobenzene 




Surrogate Recoveries am reported in Appendix O-A 


AFCEEFORM[0-2 PageI0ofl2 ju)724 X 13MST D(XW3JJ&D331&0 017

AFCEE A FCEE QAPP 

ORGANIC ANALYSES DATA SHEET 2 1 7 7 5 207 Venion 3. 0 



Lab Name: Columbia Analytical Services/Redding Contract F41624-94-D-8019 

Field Sample ID: TRIP BLANK Lab Sample ID: D3316004 Matrix: Water 

% Solids: Sample Description: TRIP BLANK 


Concentration Units (ug/L or mg/Kg dry weight): up/L Sample Volume: 20.0 ML 


1,1,1-TCA 0.12 0.8 0.12 1 U 

1,1,2,2-Tetrachloroethane 0.12 0.4 0.12 1 U 

1, t,2-TCA 0.11 1.0 0.11 I U 

I,1-DCA 0.12 0.4 0.12 1 U 

Ij-DCE 0.09 1.2 0.09 I U 

1,2-DCA 0.13 0.6 0.131 1 1 U 

1,2-DCB 0.11 0.3 0.11 I U 


I,3-DCB 0.10 1.2 0.10 I U 

1,4-DCB 0.12 0.3 0.12 1 U 



Bromoform 0.09 1.2 0.09 1 1 1 U 





Chloroform 0.11 0.3 0.17 1 F 


Cis-1,2-DCE 0.12 1.2 0.12 1 1 U 





TCE 0.12 1.0 0.12 1 U 

Tetrachloroethene 0.12 1.4 0.12. 1 U 

Trans-1,2-DCE 0.11 0.6 0.11 I U 





Comments: internal Standards are reported in Appenda O-C 

AFCEE FORM 0-2 Page I I of 12 10724 Tca&132ST," 331&DJJJ VA






Field Sample ID: TRIP BLANK Lab Sample ID: D3316004 Matrix: Water 

% Solids: Sample Description: TRIP BLANK 


Concentration Units (ug/L or mg/Kg dry weight): ug[L Sample Volume: 20.0 ML 

I 



Dibrornofluoromethane 94 75-125 

Toluene-D8 107 75-125 


Fluorobenzene - 







M)724 M132STDWJJI&DJJI 0

1 7 7 5 209 AFCEEQAPP 

AFCEE Version 3.0 




Lab Name: Columbia Analytical Services/Redding - Contract 0: F41624-94-D-8019 

Instrument ID: MS9 Date of Initial Calibration: 14 Jun 00 GC Column ID: DB-624 


Initial Calibration Sample Ms: VSTDOO.3 VSTDOOS VSTDOIO VSTDO 1 5 VSTDO20 VSTDOOI VSTDOOS 

Calibration File IDs C001651 COO 1648 C001647 C001646 COO]645 C001649 COO1650 

Analyte Std RIF Std RF Std RF Std RIF Std RIF Std RF Std RF 

I 1 2 2 3 3 4 1 4 5 5 6 6 7 7 

1, 1, I -TCA 5.000 0,342 10.00 0.345 15 00 0.376 20.00 0.377 0.500 0.313 

1, 1,2,2 -Tetrachlormthane 0.300 0.556 5.000 0 526 10.00 0.516 15.00 0.536 20.00 0,487 

1,1,2-TCA 5.000 0.203 10.00 0.201 15.00 0.214 20.00 0.203 1.000 0.194 

1.1-DCA- 0,300 0.338 5 000 0.320 10.00 0 298 15.00 0.314 20.00 0.314 

],].DCEN 5,0001 0.1011 10.00 0.0971 15.00 0.102 20 00 0,109 1.0001 0.094 

1,2-DCA 5.000 0.315 10.00 0.3 16 15.00 0 339 20 00 0.335 0.500 0.288 

1,2-DCB 0 300 1,302 5.000 1.346 10.00 1.341 15 00 1.460 20.00 1.422 

1.2-Dichloropropane# 0.300 0 239 5 000 0.252 10 00 0,254 15.00 0 278 20.00 0.280 

AM 1,3.DCB 5.000 1 488 10.00 1520 15.00 1.684 20.00 1 706 1.000 1.332 

1,4-DCB 0.300 1 540 5.000 1.498 10.00 1.493 15.00 1 632 20 00 1.632 

Bromobenzene 0.300 0.671 5.000 0 736 10.00 0,751 15.00 0.840 20.00 0.813 

Bromodichloromethane 5.000 0,286, 10.00 0 288 15.00 0.316 20 001 0,318 0.500, 0.264 

Bromoform- 5.000 0.1221 10.00 0.128 15.00 0.138 20.00 0.132 I.Ooo 1 0.104 

Bromomethane 5.000 0 091 10.00 0.085 15.00 0.087 20.00 0.082 1.000 0.090 

Carbon tetrachloride 5.000 0.274 10.00 0.282 15.00 0.309 20.00 0.314 1.000 0.230 

Chlorobcnzene- 0.300 O948 5,000 0.959 10.00 0.947 15 00 1.024 20.00 1.020 

Chloroethwe 5.000 0.118 10.00 0.111 15.00 0.115 20.00 0.114 1.000 0.111, 

Chlorolontrig 0.300 0.460 5.000 0.416 10.00 0.412 15.00 0.445 20.00 0.447 1 

Chloromethane* 5.000 0,351 10.00 0.327 1 15.00, 0.354 20 00, 0.317, 1.000 0.315 

Cis-1,2-13CE 5.000, 0 254, 10.00 0.260 15.00 0.290 20.00 0.296 1.000 0.212 

Cis-1,31-Dichloropropene 1,000 2 2: 0.364 15.00 0.398 20.00 0.402 1.000 0.286 

Dibromochloromethane 5 000 230 0 0,237 15.00 0 256 20.00 0.248 0.500 0.202 

Dibromomethane --T-000 O. I io 10.00 _, 1-10 75-00- 0120 20 00 0120 1,000 0.101 

Methylene chloride 0.300 0.177 5.000 0,133 10.00 0.124 15.00 0.128 20.00 0 135 

ITCE 5.000 0 240 10.00 0.243 15.00 0.268 20.00 0.276 1.000 0.208 1 

SPCCs # CCCs 

Comments: 


RO 724 MB1326PSTJJMDJJI&V 0020

AFCEEQAPP 







Concentration Units (ug/L or mglkg): UG/L 

Initial Calibration Sample IDs VSTDO03 VSTDOOS VSTDOIO VSTDO15 VSTDO20 VSTDOOI VSTDO05 

Calibration File [Ds COO 1 651 COO1648 C001647 COO 1 646 C001645 COOI649 C001650 

Analyte Std RF Std RF Std RF Std RIF Std RF Std RF Std RF 

I 1 2 2 3 3 4 4 5 5 6 6 7 7 

Tetrachloroethcne 5.000 0.358 10 00 0.362 15.00 0.398 20.00 0 408 1 000 0.315 

Trans- 1,2-DCE 5.000 O 143 10.00 0.134 15.00 0.140 20.00 0 147 0 500 0.144 

Trns- 1,3-Dichloropropene 5.000 OAO6 10 00 0.418 15M (1448 20.00 0.429 1.000 0.343 

Trichiorofluoromethane 5.000 0.205 10 00 0.200 15.00 0.206 20.00 0.220 0 500 0.214 

Vinyl chloride# 5.0001 0.245 10.00 0.235 15.00 0.245 20.001 0.2291 1 0001 0.211 

Dibromofluoromethane 5.000 0.211 10.00 0.222 15.00 0.253 20.001 0.262 1.000 0.193 

Toluene-D8 5.000 L122 10 00 1.175 15.00 1.323 20.00 1.319 1.000 0.981 

4-Bromofluorobenzene 5 000 U86 10 00 0 725 15 00 0 843 20.00 0.838 1.000 0.624 

SPCCS # CCCs 

Comments: 


ItD 724 0021

AFCEEQAPP 

AFCEE 1775211 Version 3. 0 

ORGANIC ANALYSES DATA SHEET 3 (Pan 2) March 1998 



Lab Name: Columbia Analytical Services/Redding - Contract #: -F41624-94-D-8019 


Concentration Units (ug/L or mgfkg): UG/L 

Initial Calibration Sample [Ds VSTDO03 VSTDO05 VSTDOIO VSTDO15 VSTDO20 VSTDOOI VSTDOO 5 

Calibration File Ms: COO 1 651 C0016,48 COOI647 COO1646 C001645 C001649 C001650 


Type RIF RSD %RSD 

1, 1, I -TCA AVG 0.351 7 7 7.31 

1, 1,2,2-Tetrachlorocithane- AVG 0 524 4.9 7.31 

1, 1,2-TCA AVG 0.203 3.4 7.31 

lI-DCA- AVG 0.317 45 7.31 

[,I -DCE# AVG 0.101 6.0 7.31 1 1 

1,2-DCA AVG 0,319 6.3 7.31 

i,2-DCB AVG 1774 4.7 7.31 

1,2-Dichloropropanc# AVG 0.261 6 8 7.31 

I,3-DCB AVG 1.546 9.9 7 31 

I,4-DCB AVG 1.559 4.4 7.31 

Bromobenzene AVG I 0.762 1 8 8 7.31 

Bromodichloromethane AVG 0.294 7.7 7.31 1 1 1 

Bromolbrm- AVG 0.125 10.6 7.31 

Bromomethane AVG 0.087 4.2 7.31 

Carbon tetrachloride AVG 0.282 11.9 7.31 

Chlorobenzene- AVG 0.980 4.0 7 31 

Chloroethanc AVG 0.114 2.3 7.31 

Chlorofom# AVG 1 0.436 4.9 7.31 

Chloromethane- AVG 0.333 5.61 7.31 1 

Cis-1.2-13CE AVG 0.262 12.7 7.31 

Cis. 1,3-Dichloropropene AVG 0.360 13.0 7.31 

Dibromitchlommetharric AVG 0.235 9.9 7 31 

Dibromorricthane AVG 0.112 7.2 7.31 

Methylcnc chloride ILINIR 0,139 15.3 7.31 0.998 

TCE AVG 1 0.247, 10.9 7 31 

SPCCs 9 CCCS 

Comments: 


AD724-717 BS-1326PSr4fl M&DJJI&V 

0022

AFCEE QAPP 

17752 12 AFCEE Version 3.0 




Lab Name: Columbia Analytical Services/Redding - Contract #: -F4]624-94-D-8019 



Initial Calibration Sanple IDs VSTDOO.3 VSTDO05 VSTD010 VSTDO 1 5 VSTDO20 VSTD001 VSTDO05 

Calibration File IDs C001651 C001648 C001647 C001646 C001645 C001649 C001650 



Tietrachlorcedicne AVG 0.368 10.0 7.31 

Trans-1,2-DCE AVG 0.142 3.4 7.31 

Trms-1,3-Dichloropropene AVG 0.409 9.7 7.31 

Trichlorofluoromethme AVG 0.209 3 7 7.31 

Vinyl chloride# AVG 0.233 6.0 731 

Dibromofluoromethane AVG 0.228 12 7 7.31 

Toluene-D8 AVG 1 184 121 7.3 i 

4-Bromofluorobenzcne AVG 0,743 12 9 7.31 

SpCCs # CCCs 

Comments: 

AFCEEFORM3(Part2) Page2of2 

W724 M 1326PST JJI&DJJJ&V 

0 0 2

A FCEE QAPP 

AFCEE 7 5 2 1 3 Version 3.0 




Lab Name: Columbia Analytical Services/Redding - Contract 4: F41624-94-D-8019 



Initial Calibration Sample [Ds VSTDO03 VSTDO05 VSTD010 VSTD015 VSTDO20 VSTDOO I VSTDO05 

Calibration File [Ds C001651 C001648 C001647 C001646 C001645 C001649 C001650 

Analyte Std RF Std RIF Std RF Std RIF Std RIF Std RIF Std RF 

I 1 2 2 3 3 4 1 4 5 5 6 6 7 7 

1,1,2,2-Tetrachlorocthane- 0,300 0.556 5.000 0526 10.00 0.516 15.00 0.536 20.00 0.487 

1.1-DCA' 0.300 0 338 5.000 0.320 10.00 0 298 15.00 0.3 14 20.00 0.314 

1, I -DCE# 5,000 0.101 10.00 0.097 15.00 0.102 20.00 0 109 1.000 0.094 

1.2-Dichloropropanc# 0.300 0 239 5,000 0.252 10 00 0.254 15.00 0.278 20.00 0 280 

Bronnoform- 5.0001 0.1221 1000 0.1281 15.001 0.138 20.00 0.132 1.000 0.1041 1 1 

Chloroben=nc- 0.300 0.948 5 000 0.959 10.00 0 947 15.00 1.024 20.00 1.020 

Chiorofornrl 0.300 0.460 5,000 0.416 10.00 0,412 15.001 0.445 20 00 0,447 

Chloromethane- 5 000 0.35 1 10.00 0.327 15.00 0.354 20.00 0 317 1.000 0 315 

Vinyl chloride# 5 000 0.245 10.00 0.235 15.00 0.245 20.00 0.229 1.000 0 211 

SPCCs # CCCs 

Comments: 


724 TU BS.132WST 331&1)331&V 0024

AFCEEQAPP 








Initial Calibration Sarriple IDs. VSTDO03 VSTDO05 VSTD010 VSTDO15 VSTDO20 VSTDOOI VSTDO05 

Calibration File IDs C001651 C001648 C001647 C001646 C001645 C001649 C001650 



1,1,2,2-Tetrachlormthane* AVG 0.524 4.9 7.31 

II-C>CA* AVG 0.317 4.5 7.31 

1,1-DCEN AVG 0.101 6.0 7.31 

1,2-Dichloropropmeg AVG 0.261 6.8 7.31 

Brornotbrin- AVG 0.125 10.6 7.31 

Chlorobcnwne* AVG 0.980 4.0 7.31 

ChlorofonrriN AVG 0.436 4.9 7.31 

Chloromethane* AVG 0.333 5.6 7.31 

Vinyl chloridd AVG 0.233 6.0 7.31 

SPCCS 0 CCCs 

Comments: 


1 

RD724 M BS-IJ26PST-SA DM331&D331&V 

0025

AFCEE, 



Analytical Method SW8260B AAB 4: D3316 





Comments: 

AFCEE QAPP 

1 7 7 5 2 1 5 Version 3.0 

March 1998 


1, U -TCA 10.00 10 36 3.5 

1,1,2,2-Tetrachloroethane- 10.00 10.69 7.0 

1,1,2-TCA 10.00 10.70 6.9 

1.1-DCA- 10.00 10.89 8.9 

II-DCE# 10.00 10.66 6.4 

1,2-DCA 10.00 10.811 8.3 1 

1,2-DCB 10.00 10.44 4.4 

1.2-Dichloropropane# 10 00 10 60 5.9 

i,3.DCB 10.00 10.45 45 

1,4-DCB 10.00 10.21 21 

Bromobenzene 10.00 1 OA5 4.4 

Bromodichloromethane 10.0( 10.64 6.3 

Bronroforni- 10.00 10.541 5.6 1 

Brommethane 10.00 11.05 10.3 


Chlombenzene- 10.00 10.46 4.6 

Chlomethane 10.00 11.04 10.5 

Chlorofom# 10.00 10.24 2.3 

Chloromethane- 10.00 10.30 3.0 

Cis-1,2-DCE 10.00 10.841 8.2 

Cis-1,3-Dichlompropcne 10.00 11.01 10.0 

Dibrornochlorornethane 10.00 10.60 6.1 

Dibrointimthane 10.00 10 65 6.1 

1Methylene chloncle 10.00 10.75 7.5 

TCE 10.00 10.64 6.3 

SPCCs # CCCS 


RD"724 TCB1326P-M 331&WJI&V 

0026

AFCEE QAPP 

Version 3.0 

7 7 5 2 March 1998 

AFCEE 






2nd Source ID: QCALTSTD Concentration Units (ug/L or mglkg): UG/L 


Comments: 



Trans-1,2-DCE 10.00 10.73 7.3 

Tnins-1,3-Dichloropropene 10.00 10.93 9.3 

Ttichlorofluommethane 10.00 10.55 5.7 

Vinyl chloride# 10.00 10.64 6.4 

Dibronnofluoromethane N/A N/A 0.0 

Toluene-D8 N/A N/A 0.0 

4-Bronnolluorobenzene N/A N/A 0.0 

SpCcs CCCs 


ADD-"724 TC B1326P- 331&DM&V 

0027

AFCEE QAPP 

1 7 7 5 2 1 7 Version 3.0 








ICV File ID: C001652Q.D CCV #1 File ID: C001933.1) CCV #2 File ID: 




1.1,1-TCA 10.00 3.5 to 00 11.03 10.4 

1,1,2,2-Tetrachloroethane- 10.00 7.0 10.00 11.11 11.2 

1.1,2-TCA 10.00 10.70 6.9 10.00 10.59 5.9 

],]-DCA' 10 00 10.89 8.9 10.00 11.55 15.6 

1.1-DCE# 10.00 10.66 6.4 10.00 11.71 17.3 

2-DCA 10.00 10.81 8.3 10.001 10.991 9.8 

2-DCB 10.00 10.44 4 4 10.00 10 58 5.8 

2-Dichloropropancil 10.00 10.60 5.9 10.00 11.31 13.2 

3-DCB 10.00 10 45 4 5 10.00 10.79 7.9 

-DCB 10.00 10.21 2.1 10.00 10.41 4.1 

mobenzenc 10.00 10.45 4.4 looo 10.35 3.5 

modichloromthane 10.00 10.64 6.3 10.00 10.92 9.1 

Bronnofonr- 10.00 10.541 5.6 10.00 1 8.938 .10.4 

Bromomethane 10.00 11.05 10.3 Moo 9,711 -3.4 

Carbon tetrachloride 10.00 10.32 3.2 10.00 10.90 8.9 

Chlorobenzene- 10.00 10.46 4.6 10.00 10.56 5.5 

Chloroethanc 10.00 11.04 10.5 10.00 11.50 14.9 

Chloroforrn# 10.00 10.24 2.3 10.00 10.84 8.5 

Chloromethane- 10.00 10.30 3.0 10.00 9.032 -9.6 1 

Cis-1.2-13CE 10.00 10.841 8.2 10.001 10.82 8.2 

Cis- 1,3-Dichloropropene 10.00 11.01 1010 10.00 10.93 9.2 

Dibronniochloronnethane 10.00 10.60 6.1 10.00 10.16 1.4 

Dibrornomethane 10.00 10.65 6 1 10.00 10.27 2.5 

Methylene chloride I 10 00 10.75 7.5 10 00 1 LT 1 27 

SPCCS CCCs 

Comments: 

10 00 10.64 6.3 10.1010 11.10 10.8 


RD724 IC AS-1326PST-Dt D00i?JJ1&DJJ 

I& V 

0028

AFCEE QAPP 

Version 3.0 

7 7 5 2 1 8 AFCEE March 1998 





Instrument ID: MS9 InitialCalibrationID: C001652Q.D 

ICV ID: QCALTSTD CCV #I ID: VSTDO I 0 CCV #2 ID: 

ICV File ID: C001652Q.D CCV#lFileID: C001933.D CCV #2 File ID: 


ICV CCv #1 CCV #2 


Tetrachloroethene 10.00 10.25 2.4 10.00 9.387 -6.3 

Tmns-1.2-DCE 10.00 10.73 7.3 10.00 11.08 10.9 

Tmns-1,3-Dichlompropene 10.00 10.93 9.3 10.00 11.03 10.2 

Trichlomfluoromethane 10.00 10.55 5.7 10.00 11.36 13.4 

Vinyl chlondc# 10.00 10.64 6.4 10.00 10.86 8.6 

Dibromolluoroaxthane N/A N/Al 0.0 10.001 10.21 2.1 

Toluene-D8 N/A N/A 0.0 10.00 10.72 7.3 

4-Bromoiluorobenzene N/A N/A 0.0 10.00 9.569 4.4 

SpCCS # CCCS 

Cominents: 


"'724 '1326"" "J'033" 0 0 2 9

AFCEE QAPP 

1 7 7 5 2 1 9 Version 3.0 






Instrument ID: MS9 InitialCalibrationID: C001652Q.D 


ICV File ID: C001652Q.D CCV #I File ID: C001933.1) CCV #2 File ID: 


Analyte ICv CCv #1 CCV#2 Q 

RF Expected Found %D RF Expected Found %D -RF FouniTj %D 

1.1.2.2-Tetrachloroethane- 0.561 10 00 10.69 7.0 0.583 10.00 11.11 11.2 

II-DCA- 0.345 10.00 10.89 8.9 0.366 10.00 11.55 15.6 

1.1-[)CE# 0.107 10.00 10.66 6.4 0.118 10.00 11.71 17.3 

1.2-Dichlompropanc# 0.276 10.00 10.60 5.9 0.295 10.00 11.31 13.2 

Bronneifeimn- 0.132 10.00 10.54 5.6 0.112 10.00 8.938 .10 4 

Chlorobcnzene- 1.025 10.001 10.46 4.61 1.0341 10.00 10.561 5.5 

Chiorofornn# 0.446 10.00 10.24 2 31 0.4731 10.00 10.84 8.5 

Chloromethaneo 0.343 10.00 10.30 3.0 0.301 10.00 9.032 -9.6 

Vinyl chloride# 0,248 10 00 10 64 6.4 0.253 10 00 10.86 8 6 

SPCCS CCCS 

Comments: 

AFCEE FORM O-5A Page I of I 

0 0 3 0


AFCEE 1 7 7 5 2 20 AFCEEQAPP 




Concentration Units (ug/L or mgikg): ug/L Method Blank ID: _C0629W01 



1, 1, I -TCA 0.12 0.12 0.8 

1. 1.2,2-Tetrachloroethane 0.12 0.12 0.4 

1,1,2-TCA 0.11 0.11 1.0 

1. I -DCA 0.12 0.12 0.4 

II-DCE 0.09 0.09 1.2 

1,2-DCA 0.13 0.13 0.6 

I,2-DCB 0.11 0.11 0.3 


1,3-DCB 0.10 0.10 1.2 

1,4-DCB 0.12 0.12 0.3 


Bromodichloromethane Oq 12 0.12 0.8 

Bromol'orm 0.09 0.09 1.2 

Bromomethane 0.16 0.16 1.1 



Chloroethane 0.12 1 0.12 1.0 

Chloroform 0.11 I 0.11 0.3 

Chloromethane 0.07 1 0.07 1.3 

Cis-1,2-DCE 0.12 1 0.12 1.2 

Cis- 1,3-Dichloropropene 0.08 1 0.08 1.0 

Dibromochloromethane 0.09 1 0.09 0.5 

Dibromomethane 0.09 1 0.09 2.4 

MethvIene chloride 0.13 0.13 0.3 

TCE 0.12 0.12 1.0 


Trans- 1,2-DCE 0.11 0.11 0.6 




I---- I 

Comments: 


RDD724 IC BS-1326PST-AR DWJ31&DJ3J&V 

0031

7 7 5 2 2 1 AFCEE AFCEE QAPP 




Lab Name: Columbia Analytical Services/Redding Contract #: F41624-94-D-80 1 9 

Concentration Units (ug/L or mg(kg): ug/L MethodBlankID: C0629WOI 


Comments: 




Toluene-D8 108 75-125 


Fluorobenzene 

Chlorobenzene-dS 




724 MB132AT 331&DJJI&V 

0032


AFCEE QAPP 

AFCEE 1775222 Version 3.0 




LCSID: C0629WOlLCS Concentration Units (ug/L or mg/kg): ug[L 

Date Extracted: Date Analyzed: 29 Jun 00 

77- Analyte Expected Found %R Control Limits 

1, 1, I -TCA 10.00 1174 III 75-125 


1,1,2-TCA 10.00 11.19 112 75-127 

Ij-DCA 10.00 11.59 116 72-125 

1, I -DCE 10.00 11.06 III 75-125 

1,2-DCA 10.00 11.62 116j 68-127 

1,2-DCB 10.00 10.66 1071 75-125 


1,3-DCB 10.00 10.82 108 75-125 

1,4-DCB 10.00 10.55 106 75-125 

Bromobenzene 10.00 10.41 104 75-125 

Bromodichloromethane 10.00 1 1.2 l 1 12 75-125 

Bromoform 10.00 9.56 96 75-125 

Bromomethane 10.00 9.76 98 72-125 



Chloroethane - 

10.00 11.61 1161 65-125 

Chloroform 10.00 10.96 1101 74-125 


Cis- 1,2-DCE 10.00 10.92 109 75-125 

7tTI,3-Dichloropropene 10.00 11.39 114 74-125 

DibromochlOTOmethane 10.00 10.69 107 73-125 



TCE 10.00 11.01 1101 71-125 

Terrachloroethene 10.00 9.35 941 71-125 

Trans-1,2-DCE 10.00 10.96 1101 75-125 

Trans- 1,3-Dichloropropene 10.00 11.6! 117 66-125 

-Trichlorofluoromethane 10.00 10.97 -125 

Vinyl chloride 10.00 71-0-4 46-134 

Comments: 


RD&"7:4 M 813!6P- DW331&D331&V 

0033

AFCEE QAPP 

17 7 5 29" 3 AFCEE Version 3.0 





LCSID: C0629WOlLCS Concentration Units (ug/L or mg/kg): ug/L 

Date Extracted: Date Analyzed: 29 Jun 00 

Comments: 




Tolucne-D8 105 75-125 


Fluorobenzene 





RDD-724 

00 34


AFCEE 


MATRIX SPIKEIMATRIX SPIKE DUPLICATE SAMPLE 


Concentration Units (ug/L or mg(kg): ug/L %Solids: 

AFCEEQAPP 

1775224 Version 3.0 

March 1998 

Parent Field Sample ID: I WATEROUT MS ID: IWATEROUTMS MSD ID: I WATEROUTMSD 

Parent Spiked Duplicat 

Analyte Sample Spike Sample %R Spike %R %RPD Control Control Q 

Result Added Result Sample Limits Limits 

Result %RPD %R 

1. 1. I -TCA 10(o 11.23 1121 11.08 III 1 20 75-125 

1, 1.2,2-Tetrachloroethane 10.00 12.42, 1241 11.93 119 4 20 74-125 

1,1.2-TCA 10.00 11,451 114 11.04 110 4 20 75-127 

1,1-13CA 10.00 13.031 130 12.48 125 4 20 72-125 

[,I-DCE 10.00 11.561 116 11.20 112 3 20 75-125 

1,2-DCA 10.00 11.79 118 11.42 114 3 20 68-127 

1,2-DCB 10 00 1114 HI 10.86 109 2 20 75-125 

1.2-Dichloropropane 10 00 11.76 118 11.34 113 4 20 70-125 

-DCB 10.00 11.22 112 10,92, 109 3 20 1 75-125 

DCB 10.00 10 86 109 10.581 106 3 20 75-125 

mobenzene 10 00 10.68 107 10.32 103 3 20 75-125 

odichloromethane 10.00 11.261 113 11.01 110 2 20 75-125 

form 10.00 9.561 96 9.27 93 3 20 75-125 

metharic 10.00 9.741 97 9.55 96 2 20 72-125 

Carbon tetrachloride 10.00 11.121 III 11.07 III 01 20 62-125 

Chlomberczcne 10.00 11.111 111, 10.72 107 4 20 1 75-125 

Chloroahme 10.00 12.481 1251 11.86 119 5 20 1 65-125 

Chloroform 10 00 11.301 1131 10 90 109 4 20 74-125 

ChloromcLhanc 10.00 9 191 921 9.81 98 6 20 75-125 

Cis-1,2-E)CE 10.00 11.421 1141 10 95 110 4 20 75-125 

Cis-1.3-Dichloropropene I 10.00 10.83 1081 10.65 1061 2 20 74-125 

Dibromochloromethanc -10 00 10 72 107 10.47 1051 2 20 73-125 

Dibrornomethanc 10.00 10.95 105 4 20 69-127 

Methylene chloride 12.05 106 8 2 25 

TCE 109 41 20 1 71- 25 

Comments: 


724 MB.13MSTcJJM.DJ31& 100 35

AFCEE QAPP 

1775225 Version 3. 0 

March 1998 


AFCEE 


MATRIX SPIKE/MATRIX SPIKE DUPLICATE SAMPLE 


Concentration Units (ug/L or mg/kg): ugfL %Solids: 

Parent Field Sample ID: I WATEROUT MS ID: IWATEROUTMS MSD ID: I WATEROUTMSD 

Parent Spiked Duplicat 

Analyte Sample Spike Sample %R Spike %R %RPD Control Control Q 

Result Added Result Sample Limits Limits 

Result %RPD %R 

Tetrachloroethene 10.00 9.37 94 9.13 91 2 20 71-125 

Trms- 1,2-DCE 10.00 11.59 116 11.15 112 4 20 75-125 

Trms- 1,3-Dichloropropene 10 00 11.21 112 11.18 112 0 20 66-125 

Trichlorofluoromethme 10.00 11.81 118 11.32 113 4 20 67-125 

Vinyl chloride 10.00 11.63 116 11.38 114 2 20 46-134 

Corrunents: 


W724 n7 B112ST 331&D331&6 036 

Ank.

AFCEE 


HOLDING TIMES 



AFCEE QAPP 

.1775226 Version 3.0 

March 1998 

Ist Max. I St 2nd Max. 2nd Max. Time Q 


Collected Received Prepared Time I Held Prepared Time 2 Held Analyzed Time A Anal. 

WWIWATER(IN) 27 Jun 00 28 Jun 00 N/A N/A N/A N/A N/A N/A 29 Jun 00 14 2 

IWATEROUT 27 Jun 00 28 Jun 00 N/A N/A N/A N/A N/A N/A 29 Jun 00 14 2 

IWATEROUTMS 27 Jun 00 28 Jun 00 N/A N/A N/A N/A N/A N/A 29 Jun 00 14 2 

IWATEROUTMSD 27 Jun 00 28 Jun 00 N/A N/A N/A NIA N/A N/A 29 Jun 00 1 4 2 

006WWIWATER2 27 Jun OF 28 Jun 00 N/A N/A N/A NIA N/A N/A 29 Jun 00 1 4 2 

TRIP BLANK 27 Jun 00 28 Jun 00 N/A N/A NIA N/A N/A N/A 29 Jun 00 14 2 

Comments: 

AFCEE FORM 0-9 Page 1 of I 

RD&"724 TC BIJMP-SR W&DJ340 3 7

AFCEE QAPP 

Version 3.0 

1775227 March 1998 

AFCEE 


INSTRUMENT ANALYSIS SEQUENCE LOG 




Field Sample ID/Std ID/ Laboratory Date Analysis Time Analysis Date Analysis Time Analysis 


VSTDO20 C001645 14 Jun 00 1035 14 Jun 00 1105 

VSTDO15 C001646 14 Jun 00 1108 14 Jun 00 1138 

VSTDO I 0 C001647 14 Jun 00 1140 14 Jun 00 1210 

VSTDO05 C001648 14 Jun 00 1213 14 Jun 00 1243 

VSTD00I C001649 14 Jun 00 1245 14 Jun 00 1315 

VSTDOO.5 C001650 14 Jun 00 1318 14 Jun 00 1348 

VSTDOO 3 C001651 14 Jun 00 1351 14 Jun 00 1421 

QCALTSTD C001652Q 14 Jun 00 1423 14 Jun 00 1453 

VSTD010 C001933 29 Jun 00 0842 29 Jun 00 0912 

C0629WOlLCS C001934 29 Jun 00 0914 29 Jun 00 0944 

C0629WO1 C001939 29 Jun 00 1158 29 Jun 00 1228 

WWIWATER(IN) C001940 29 Jun 00 1231 29 Jun 00 13 

IWATEROUT C001941 29 Jun 00 1 1304 29 Jun 00 1334 

006WWIWATER2 C001942 29 Jun 00 1336 29 Jun 00 1406 

TRIP BLANK C001943 29 Jun 00 1409 29 Jun 00 1439 

IWATEROUTMS C001950 29 Jun 00 1758 29 Jun 00 1828 

[WATEROUTMSD C001951 29 Jun 00 1831 29 Jun 00 1901 

Comments: 


1 

RD&M72, 0038


AFCEE 





AFCEE QAPP 

1775228 Version 3. 0 

March 1998 

Instrument ID: MS9 Compound: BFI3 Injection Date/Time: 14 Jun 00 1004 


I 5% to 40% ot mass 95 24.1 

73- 30% to 60% of mass 95 49.1 

base peak, 100% relaotive abundance 100.0 

5% to 9% of mass 95 1.3 


--- T7T- 7o-m-ass 95 85.8 

T73- 5% to 9% of mass 174 6.0 (7.0) 

-- T76- >95%, but

AFCEE QAPP 

Version 3. 0 

1775229 March 1998 


AFCEE 




Lab Name: Columbia Analytical Scrvices/Redding Contract F41624-94-D-8019 

Instrument ID: MS9 Compound: BFB InjectionDate/Time: 29JunOO0811 


-- 37 15% to 40% of mass 95 24.1 

--- 73'- 30% to 60% of mass 95 52.8 

-- 9T base peak, 100% relative abundance --- raTu- 

5% to 9% of mass 95 7.4 


174 greater than 50% of mass 95 

--- T73- 5% to 9% of mass 1 /4 4.9 

-- 77- >95%, but

AFCEE 

ORGANIC ANALYSES DATA SHEET APPENDIX A 




Matrix: Water 

1 7 75 2 30 AFCEE QAPP 

Version 3.0 

March 1998 


C0629WO I LCS too 105 94 

C0629W01 99 108 104 

WWIWATER(IN) 100 114 107 

IWATEROUT 95 107 too 

WWIWATER2 94 107 too 

TRIP BLANK 94 107 99 

IWATEROUTNIS 116 1- 20 107 

-FWWATEROUTMSD to] 107 95 




Comments: 

AFCEE FORM APPENDIX A Page I of I 

NDD-"7Z4 n7BIJMPST-VM&&J)1600 4 1

AFCEE 


INTERNAL STANDARD AR-EA AND RT SUMMARY 



Instrument ID: MS9 Date Analyzed: 29 Jun 00 Time Analyzed: 0842 

TK 

1 7 7 5 2 3 AFCEE QAPP 

Version 3. 0 

March 1998 

ISI IS2 IS3 

A(#) TIME AREA TIME AREA TIME 

12 HOUR STANDARD 2716767 9.77 1899025 15.22 878719 20.18 

UPPER LIMIT 5433534 10.27 3798050 15.72 1757438 20.68 

LOWER LIMIT 

SAMPLE ID 

1358384 9.27 949513 14.72 

Cecil ia 

439360 19.68 

C0629WO I LCS 2700512 9.77 1874958 15.22 862209 20.18 

C0629WO] 2250022 9.78 1456149 15.23 560652 20.18 

WWIWATER(IN) 2666971 9.78 1706266 15.22 646362 20 18 

IWATEROUT 2601171 9 78 1680815 15.22 653594 20 18 

006WWIWATEP,2 2715869 9.78 1741798 15.22 664452 20.18 

TRIP BLANK 2805222 9.77 1779816 15.22 680312 20.18 

IWATEROUTMS 2395570 9 78 1692217 15.23 789962 20.18 

IWATEROUTMSD 2688502 9.78 1861134 15.22 854412 20.18 

Comments: 

IS1 Fluorobenzene IS4: 

IS2: Chlorobenzene-0 IS5: 

ISI 1,4-Dichlombenzene-& IS6, 


Column used to flag values outside of QC limits with an asterisk 

AFCEE FORM APPENDIX C Page I 

WW72',X.BIJ26P-M.337&D33]&VO042


AFCEE QAPP 

1775232 Version 3.0 

March 1998 

Lab Name: Columbia Analytical Services/Redding Analytical Method: SW8260B Matrix: Water 


Concentration Units (ug/L or mgfkg): ug/L 

Analyte Analysis Amt. Replicates Std. MDL 

Date Spiked 1 2 3 4 5 6 7 8 Dev. 

1,1,1-TCA 15 Fe 691 -0-4-773-9 -r5-6615 -(r4-9381 -0.56181 0,50235 0.040259'- 0.12 

1,1.2,2-TcuachiTmethanc-T5Fb-00 - o.5 0.50076 0.47365 0.57071 0.50648 -T5-7414 -T50-152 --r56-576 _T50-877 703-8-816 - 0 12 

1,1,2.TCA 15 Feb 06- - 0.5 -U.-4-9954 -T4-764S -(T.5-6015 -U 4 9-059 7-5-6412 -r5 0 3-7 5 -U-5-6984 (5.49781 0.037751 0.11 

[J-DCA 15 Feb UO- - 0 5 -T-51209 -T-4-7642 -U-5-8227 -U'4-9851 7-57906 7 5 1 5-45 0.57774 0.51281 10.041546 0 12 1 

[,I-DCE 15 Feb 00 0.5 0.48708 -7-46504 -T.-54421 0.52107 0.52707 0.49181 0.030715 0.092 

1,2-I)CA 15 Feb 00 - 0. 5 -T-50115 7-.46971 0.57129 0.48752 0,5739 0.49358 0,56547 -F4-8777 T043-536 0.13 

1.2-DCB 15 Feb 00 0.5 -T-51014 -T4-7939 0,56174 0.48181 0.55804 0.49373 0,54022 -T-4-8159 7035-077 0.11 

1.2-Dichloropropane 15 Feb 00 0.51 0.48061'-7-43916 7-5-2244 0.45646 0.52712 0.46IT5 -T5-2559 -F44927 0.036894 0.11 

1,3-I)CB 15 Feb 00 0.51 0.5284 0.49139 0.57429 0,48467 0.55519 0.49848 0.5T5-47 7-49806 0,033561 0.10 

1,4-DCB 15 Feb 00 0.5 0.54216 7-T58-577 -T48-779 -F5-8291 -T50-536 -T57-226 -TS-0171 0.040882 0.12 

UBro benienc 15 Feb 0.5 0.47931 0.450T4 -T.-54781 -T.4-3232 75-2507 -T.4-4616 -U.-51529 0 44i 17 0.04421 7 0 13 

22 - -T47 7-45-894 - 46 47749 .039867 0 12 

dichllorometbane 15 F b 00 0 5 0-14 -0 540-51 1 --60-5 0- 545 .-T46-508 75-4606 -T-- 

olorn' 15 Feb 00 .5 -T-38882 0.36948 0,42191 0.38641 0.44139 0.37414 0.450-3 -(T4o Tl2 8 T03-0465 0 091 

Flrroom.,mthane 15 Feb UOT - 0 5 7674-2 -9i 3 7674-o-qu -T4-844 -67-6 9 8-5 -6 4-72-5 8-U-4-2766 7-57-M -T4-454 -55-4669 -o i6 

Carbon lctnachl7ndc -T5 -Fcb00 - 0.5 -T.-49443 --(F.4-6165 733 3-83 -,6-.46568 7-54261 U.49861 U.55425 .48867 T034878 - 0.10 

Chlorobcnzene 15 Feb OU- - 0.5 0 5-2401 0 48449 0.55615 674-8192 -d.-5-6967 -6.-4-9742 -0.54062 -(T4 7 0-8 3 T-037228 0.11 

Chloroethane 15 Feb 00 0 5 0.49914 -T4-1328 -674-91-9 -r5-4497 7-50-221 0.45582 0.44524 0.45443 0.041377 0.12 

Chlorofom 15 Feb UO- - o 3 -o-5T4 6-9 -r4-9842 -6-5 8 -0 2 -U 5 2-3 9 0.58516 0.51179 0.59562 0.52689 jO.037729 0.11 

Chlorornethane 15 Feb UO-- - 0 5 -T-39205 7-3 5 3-8 7 -U-4-0422 -0-5314 -U4-0429 7-3-7499 O4077 0.39284 0.022203 0.067 

Cis-1,2.DCE 15 Feb UU- - 0 5 -6-499-62 -CF4-6-936 0.55274 0.46036 0.54009 0.46551 0.55087 0.46325 0.041"9 0.12 

Cis-1.3-Dichloropropene 15 Feb 00 - 0 5 -6'4-4-062 -C3-8026 7745-135 -7400-22 -U.-3-9768 702 5-939 0.078 

DibrornochloroirWjhane -T5 -Feboo - 0.5 -0.7436-39 -U.-41-13 -T.-4892 0- 432 0.49184 0.43234 0.4857- -r4-3"7 7030-950 - 0.093 

Dibrornornethanc 15 Feb 00 - 0.5 7.350-205 0.49746 0.55247 0 rO-O99 73-5639 --T.4-9039 735-2091 T031-520 0 094 

Methylene chloride 22 Feb 00 

1 1.0733 IT58-58 -T 018-63 -TO-9182 7-di-87-3 -7-09-81 7-1 12-56 -171-1-99-4 F0435-09 - 0 1 3 

TCE 15 Feb 00 0.5 0.5098 U-470-42 7-55-059 7-45-172 -F5-4825 -T48-268 -r52-994 -T46-315 U 0-3 91-6 6 0.12 

Tetrachloroethcne 15 Feb 00 0.5 0.52512 0.49M 0.56546 0.47634 0.56179 0.49006 0.54119 0.46534 0 04696- - 0.12 

Tnans-1,2-13CE I 5 Feb UO- - 0.5 -74-9967 0.48961 0.549141 0,47705 0.55319 0.47868 1 0.54996 0.47016 0.036155 0.11 

- - 7-- 0,42935 -T- .027732 0-083 

Tnins. 1,3-Dichloropropene 15 Feb 00 O 5 .40739 0.37909 0.38821 O."193 0.3804 0.43236 .37144 U- 

Trichlorofluorornethane -T5 -Fcb00 - 0 5 -CF4-5-817 -6 4-168-3 -CF4-9-789 -0 4-4762 0.52664 0.46577 0.51415 0.46605 U-036-448 - 0 11 

Vinyl chloride 15 Feb 00 - 0.5 7.33 77-3 5 -T.3-0439 -7-36234 -T-35263 -T.-3948 7-3-2427 -7-36363 -U-2-6343 Y042-975 - 0.13 

1k I 

MDL FORM Method SW8260 Page I of 1 

&DD-"724 004 3


1 7 7.52 3 3 

00 44

.0 

in 

U) 

1775234 

u 7 

m 

< 

Z z 

0 

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Af&A 

1 

5090 Caterpillar Road 

Reddina, CA 96003 

Project/Clien 

otumb' 1775235 

COOLER RECEIPT FOR-NI 

Cooler received on -6-2 0 and opened on by 

1. -4/24 . 

Shipped via: Airbill 

Work Order DOO 

2. Coolers screened by: !Date: 

AccefZNe Reject 

3. Were custody seals on outside of cooler? 

If ves, hov N A 

4. Were seals intact and signature & date correct! 

Temperature of co(ler(s) upon receipt: 

Temperature Blajik: 

6. Type of packing material present: 

i Ie-1 

T'S N( N A 

7. Were custody papers properly filled out (ink, signed, etc.). ' NO N/A 

8. Did containers arrive in good condition (unbroken)'? YES' N 0 N/A 

9. Were all bottle labels complete (i.e. analysis, preservation, etc.).' IE S N 0 N/A 

10. Did all bottle labels and tags agree with custody papers? N. 0 1,/A 

IL Were the correct types of bottles used for the tests indicated? 

12. Were all of the preserved bottles received at the lab with the appropriate 

NO N/A 

preservative? pH: 4f 2 -4-Z11-- NO N/A 

13. Were VOA vials checked for absence of air bubbles? If present, note below. N/A 

14. Samples transferred to the freezer: Date: Time: 

Explain any discrepancies: 

00 4 6

Section Tab 

,rl QuaH-ev- 

1775236

ww_1 


Third Quarter 2000 Report 

iI 


December 2000 

1775237

ww-1 


Third Quarter 2000 Report 

ww-1 


Preparedfor: 


Environmental Quality (AFCEE/EQ) 


AFCEE Contract Number F41624 97 D 8019, Delivery Order 129 

Prepared by: 

CH2M HILL 



December 2000 

1775238

1 

i 

1775239 




156470.02.92.94 

MDH/BMF

Notice 

1775240 



Program (IRP). The limited objei tives of this report and the ongoing nature of the IRP, 





recommendations, or other views expressed herein, which are those of the contractor offly, 





Non-Goverrunent agencies may purchase copies of this document from National Technical 


NOTICE&PREFACE DOC 

156470 02 92 94

Preface 

1 7 7 5 2 4 

This report presents findings obtained from the third quarter 2000 optimization, operation 




(AFCEE/ EQ) is the Contracting Officer Representative. 

Approval: 

1;ye"k 

Mark Henry 


CH2M HILL 

IV NOTIMPREFACE DOC 

156470 02 92 94

Contents 

1775242 

Sections Page 

N otice ................................................................................................................................................. III 

Preface ................................................................................................................................................ IV 

List of Acronym s ............................................................................................................................. V II 

1.0 Introduction ........................................................................................................................ 1-1 

1.1 Authorization ............................................................................................................ 1-1 

1.2 Purpose and O bjectives ............................................................................................ 1-1 

1.3 Background ................................................................................................................ 1-1 

2.0 Third Q uarter 2000 G TP O perations .............................................................................. 2-1 



2.1.2 Air Phase Analytical Results ........................................................................ 2-2 





2.3 TCE and cis-DCE Rem ovals ..................................................................................... 2-3 

2.4 Plant O perations ....................................................................................................... 2-3 

2.4.1 O perational Param eters ................................................................................ 2-3 

2.4.2 H ours of O peration ....................................................................................... 2-3 


2.4.4 Site Events/ Repairs ....................................................................................... 2-4 

2.4.5 System Shutdow ns/ A larm Conditions ...................................................... 2-4 

3.0 Recom m endations ............................................................................................................. 3-1 

3.1 W W -1 Plant O ptin-dzation ....................................................................................... 3-1 

4.0 References ........................................................................................................................... 4-1 

Appendices 



C LTO Analytical Data WW-1 System Shutdowns/ Alarms, Third Quarter 2000 

Tables 

2-1 WW-1 Liquid Phase Analytical Results, Third Quarter 2000 ....................................... 2-2 

2-2 Flow Measurement Information at WW-1, Third Quarter 2000 .................................. 2-3 

2-3 W W -1 Site Activities, Third Q uarter 2000 ....................................................................... 24 

2-4 W W -1 Site Repairs, Third Q uarter 2000 .......................................................................... 2-4 

2-5 System Shutdow ns/ Alarm s, Third Q uarter 2000 .......................................................... 2-5 

20DO 3RO QUARTER DOC V

List of Acronyms 





COC Contarrdnant of Concern 














Vg/L n-dcrograms per liter 

MDL Method Detection Lirrdt 











RL Reporting Limit 









1775243 

ACRONYMS DOC Vil 

156470 02 92 94



1775244 


March 2000) of Contract Number F41624-97-D-8019, issued by the Department of the Air 



the Fairchild AFB runway. Fairchild AFB is located west of Spokane, Washington. 

1.2 Purpose and Objectives 

This report presents and summarizes data collected during the third quarter of 2000 for the 

optimization and long-term operation and maintenance (LTO) of the groundwater 

extraction and treatment system at the WW-1 site. 


The WW-1 site consists of two interconnected industrial wastewater lagoons, a skimming 


stormwater and industrial wastewater generated on the base. Trichloroethene (TCE) is the 



lagoons and residual TCE in the stormwater sewer system from flightline oil/ water 




(Halliburton, June 1993). Construction of a purnp-and-treat system, consisting of two 




Associates. 





2000 3RD QUARTER DOC 1-1 

156470 02.92 94

2.0 Third Quarter 2000 GTP Operations 

This section presents and discusses data collected during LTO of the groundwater purnpand-treat 

system at WW-1 for the third quarter of 2000. 




Work Plan (CH2M HILL, September 2000c), Sampling and Analysis Plan [(SAP), 

CH2M HILL, September 2000a], and the Quality Assurance Project Plan [(QAPP), CH2M 

HILL, September 2000b]. 


Appendix A-1 Inspection/Maintenance Forms 

Appendix A-2 Extraction Wells Data Summaries 

Appendix A-3 Operational Data Summaries 

Appendix A-4 Incidental Water Treatment Forms 

Appendix A-5 Sampling Documentation Forms 

Appendix A-6 Event/ Repair Forms 

Appendix A-7 Alarm Response Forms 







and QAPP. This monitoring includes quarterly water samples collected from the plant 

influent and plant effluent and air samples collected annually from the influent to the lead 


unit. 


1775245 

Influent and effluent water samples were collected on September 27, 2000, and analyzed for 

volatile organic compounds (VOCs) using EPA Method 8260 as specified by the SAP and in 

accordance with the QAPP. Table 2-1 summarizes the results for TCE, cis-1,2-dichloroethene 

(cis-DCE), and vinyl chloride (VC). Complete analytical data packages are included in 

Appendix C. 

20DO 3RD QUARTER DOC 2-1

1775246 WW-1 THIRD QUARTER 2I)DO REPORT 

TABLE 2-1 

WW-1 Liquid Phase Analytical Results, Third Quarter 2000 

TCE cis-DICE VIC 

Sample Location (pg/L) (jag/L) (pg/L) 

Plant Influent 5.00 15.7 0.37 F 


Qualifiers: 

F = The analyte was positively identified but the associated numerical value is at or below the RL. 

U = The analyte was not detected. The associated numerical value is the lower IVIDL. 





The WW-1 GTP operated within regulatory compliance limits for the third quarter of 2000. 

TICE was not detected in liquid discharge samples; the liquid discharge limit for TCE is 

5pg/L. 









2.2.2 Volume of Water Treated 


total volume of water treated during the third quarter of 2000 was approximately 1.1 


the quarter was 8.4 gallons per minute (gpm). The total amount of groundwater treated at 

the WW-1 GTP from March 1, 1997, through the end of this quarter is approximately 21.7 

n-dllion gallons. A more detailed description of the flows and readings are included in 

Appendix B as Tables B-1 and B-2. 

2-2 2DOO 3RD OUARTER DOC

TABLE 2-2 

Flow Measurement Information at WW-1, Third Quarter 2000a 

WN-1 THIRD OUARTER2000 REPORT 

EW-1 b Well Point Systemc Total Plant Discharge (P-5) 


Period of Volume Flow Rate Volume Flow Rate Volume Flow Rate 

Operation (gallons) (gpM)d (gallons) (gpM)d (gallons) (gpM)d 

July 273,189 6.1 126,902 2.8 400,091 9.0 

August 265,915 6.2 112,050 2.6 377,965 8.7 

September 194,520 5.1 92,992 2.4 287,512 7.6 

Third Quarter 733,623 5.8 331,944 2.6 1,065,567 8.4 

OSee Appendix B (Flow Summary) for details. 

bEW-1 Total Volume is corrected by subtracting the amount of re-circulation volume during routine cleaning. 

'Well Point System Flow Rate is not directly measured. It is assumed to be the difference between the Total Plant 

Discharge (P-5) and EW-1 Total Volumes. 

'Flow Rate is calculated as a total monthly average by dividing the total flow by plant operating time. 

2.3 TCE and cis-DICE Removals 


during the third quarter of 2000 were calculated by multiplying quarterly concentrations by 

the total flow volume treated for the quarter. It is assumed that the air stripper had 100 


measured below the lower MDLs in the plant discharge sample. The estimated quantities of 

TICE and cis-DCE removed were 0.04 pound and 0.14 pound, respectively. 




updated WW-1 Operations and Maintenance Manual (CH2M HILL, June 1998) and 

manufacturers' specifications. Third quarter 2000 readings are included in Appendix A. 


The WW-1 GTP operated for 2,091 hours during the third quarter of 2000. The GTP was 

shutdown for a total of 118 hours during the quarter as a result of several power failures. 


Approximately 785 gallons of incidental water were treated at the GTP this quarter. The 

water was generated by URS/ Dames & Moore from the SD-37 RI/ FS project and by EA 

1775247 

2000 3RD QUARTER DOC 2.3

1775248 

WN-1 THIRD QUARTER 2000 REPORT 

from their third quarter LTM sampling event. The Water Treatment Approval Forms are 

included in Appendix A-4. 

2.4.4 Site Events/Repairs 

Table 2-3 summarizes site activities for the third quarter. 

TABLE 2-3 

WW-1 Site Activities, Third Quarter 2000 


7/17/2000 Chlorinating and cleaning EW-1 without recirculation 

7/27/2000 Attempted routine cleaning of EW-1 with re-circulation but discontinued after 4 hours 

(5,809 gallons circulated) due to EW-1 pump and motor failure--caused a Low Flow 

Alarm 


8/23/2000 

9/6/2000 Treated approximately 675 gallons of LIRS/Dames & Moore purge water from the SID- 

37 RI/FS project 

9/1412000 Routine cleaning of the Well Point System-Well Point System shutdown for 4 hours 

9/18/2000 Treated approximately 1 1 0 gallons of purge water from EA's quarterly LTM sampling 

9/27/2000 Quarterly sampling of GTP water influent and effluent. 


9/28/2000 


Repair #17 was initiated during first quarter 2000 and completed during this quarter. Table 

2-4 summarizes this repair. The Event/ Repair Form is provided in Appendix A-6. 

TABLE24 

NW-1 Site Repairs, Third Quarter 2000 

Date 


03/6/2000 17 Completed Miscellaneous work items, including reconnaissance for WIN-1 

source investigation, fire alarm system repair, data validation to get 

historical treatment plant analytical data ready for ERPIMS, survey 

of LTO sampling locations, and EW-11 pump and motor 

replacement. 




2-4 2000 3RD QUARTER DOC

1775249 

WW-1 THIRD QUARTER 20DO REPORT 

quarter. There were three alarm responses during the third quarter of 2000. The Alarm 

Response Forms are provided in Appendix A-7. 

TABLE 2.5 

WW-1 System Shutdowns/Alarms, Third Quarter 2000 

Date Hours of Plant Shutdown' Alarm Reason 

7/27/2000 6 Yes Low Flow Alarm-The pump and motor 

on EW-1 failed and required replacement 

7/31/2000 1 Yes Air stripper failed and required system restart 


8/21/2000 1 8 No Power failure 

8/27/2000 3 Yes Power failure 

9/18/2000 to 22 No Power failure 

9119/2000 

9/28/2000 to 65 No Power failure 

10/1/2000 

OlHours of Plant Shutdown are estimated. These estimates are based on a review of average daily flow rates and 


The 108 hours of plant shutdown this quarter (or 92 percent of the total shutdown time) are 

from unalarmed power failures as a result of minor power outages. These outages were 

long enough to cause GTP motor shutdown, but not long enough to trip the auto-dialer 

alarm system. Inland Power & Light, the electricity purveyor in the area, has been notified 

of these electricity "blurbs" on several occasions and has not made any effort in resolving 

the problem. CH2M HILL will make necessary adjustments to the alarm system during the 

fourth quarter in hopes of detecting these minor power failures, thereby minimizing the 

plant shutdown time. 

2000 3RD QUARTER OOC 2-5


3.1 WW-I Plant Optimization 

The following are recommended to further optimize WW-1 plant performance: 

1775250 






Both of these recommendations are temporarily on hold. The source removal activity 

(upgradient of MW-102) was conducted in October 2000; approximately 200 cubic yards of 

contaminated soil and about 35 buried drums were removed. Of the 35 drums, 

approximately 25 drums contained liquids and/or sludge. 

2000 3RD QUARTER DOC 3-1




CH2M HILL. Draft Field Sampling Plans, Groundwater Monitoring and Pump-and-Treat Systems 

Operation, Craig Road Landfill and I/VW-1 Sites, Fairchild Air Force Base, September 2000a. 

CH2M HILL. Draft Quality Assurance Project Plan for tlw Pump-and-Treat Systems Operation, 

Craig Road Landfill and INW-1 Sites, Fairclidd Air Force Base, September 2000b. 

CH2M HILL. Draft Work Plait Addendumfor Punip-and-Treat Systems Operation, Craig Road 

Landfill VVW-1 Sites, Fairdrild Air Force Base, September 2000c. 

CH2M HILL. Update to Roy F. Weston, Inc. January 1997, Fairchild AFB Ground7vater 

Extraction and Treatment System WasteWater Lagoons VVW-1 (AF Site INP-03), Operations and 

Maintenance Mari ual, June 1998. 

Halliburton NUS (Halliburton NUS Environmental Corporation). Record of Decision for tlw 





URS Consultants, Inc. 1,VW-1 (AF Site WP-03) Treatment System Addenda, April 1995. 



1 7 75 2 5 

200D 3RD QUARTER DOC 4-1

Appendix Tab 

2.4 vid I /A 

Orxro,Oviz; anJ 0,m-n+rvionce Fbrwis 

1775252

APPENDIX A-1 

Inspection/Maintenance Forms 

1775253

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APPENDix A-2 

Extraction Wells Data Summaries 

I 

I 

1775259



1775260 


EW-1 EW-3 P-5 



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OVL'F160 'Jg 70 4j .f Li 1-/ 7 

WW-1 FlowMaster)ds 06/02/2000 REVISED, FEB 1999

1 7 7 5 2 6 1 



Pre-Blower Post-Blower Primary GAC Vessel Lag GAC Vesse 

Blower 


(inches Differential Air Differential Inlet Pressure Outlet Pressure Outlet Pressure Ex r 

Date Time Initials w.c.) i(inchesw.c.) (inchesw.c.) (inches w.c.) (inches w.c.) (inches w.c.) Temp. (OF) 

Qq1*Z&d 66,0"i 5, Id 0, /5 SY 

LI ff I 

f//; /0' 99 Ma -44V ZY, 0 0, Z b,04 Z_ f _0 e), 0 

0 fj/'//o 0 0 7YO .4V&,-. /%=,I 0, 0,,9 ll "I'll 

-lo .4 #,,-I /,q, 49 01 /I .,06 

4f104 02r"gr 'I" /,Y 0 0, 1.'7- 0,0 4- 121 7.f 

o Ylvkz, e ffoa iq o o. / -z 0,04 /1X - le V_ .9 e,_ a 

oz 'P, 17, !I, 0 1, Az 10 0- v_ 0 

9-?/; 710 00fq 0, /3, 1,-Z 0,0 -2 I-) 010 

e I&A I Al, d 6,1 7 0, /j e 0 0 9 fy 

Comments: 

/0 0 7.f p./. 

6 I/jf/v ewa 5wr W,0 7- 

W/ 

'PL.0 

0 IAI 

V6W-1 F Masler)d. 12/29/96 REVISED. NOV 1998

Sul v 

4) N6 

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0 t4 

LL 

CO .

1775263 

WW-I Routine Flow Measurements 


Extraction Wells Air Stripper Effluent Pu 

plo 0 EW-1 EW-3 P-5 


Date Time Initia (gallons) (gpm) (gallons) (gpm) (gallons) 

'00/0,00C, 69,00 7, 9 Y 2 ?- ?Z f / 79 I-j 

59AMy '01"Oe, Of &,- I 9191f ;Z 9 ) ',Vs, 90 

0/l/ /O O OV/ f Ay' I 7/4 20 3' 77 

,4,70 3 7 -/,; 7 2 7 

e 9.1 0 AV 7- 7,71 / / 2 7 1-27eja!5r-l 

// " Bell LA IUlbq7 09ce-du Y 7 ZqN 21,15 

4; if 2-6"7 6?7 f&e, .2 (, 

ga&& fy /,f .2 7, 7 EJ11 ? t./ / - --7 Z 7 

du; 716V 18, 0 5. -29 7;.7. 0 77 76;1 7/ 

00AW90 6,900 5 7 7 ;mAJ 7 

WW-1 Flow MasterAs 06MMOOO RDASED. FEB 1990

1775264 



I Pre-Blower Post-Blower Primary GAC Vessel Lag GAC Vessel 

Blower 



Date Time Initials w.c.) (inches w.c.) (inches w.c.) (inches w.c.) (inches w.c.) (inches w.c.) Temp. (OF) 

/n/00 P IV 

Ahi/l/e/i 

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AV,, 1q, 1) 4 /.XI e.;, 0- 0 4511/3 55 

d 4, Or 0 

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V, z, 

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IS2, 

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9,00149 0)3 0 v Ww,, 0, 0 917 

Comments: 

j5UL) )IMAA11" ee-, 1,614 7 

-i F Malt.,.,i. 12129198 RE"SED. NOV 1998

Cl) 

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1775266 


EW-1 EW-3 P-S 



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21310z ,O'oo -LA_ (e - (O 35 9.57 7 2-7 (p (D 4 6 +7 

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1775267 




;400 

Bloweru 

Vacuum Ai 


Date Time Initials W.C.) (inches w c.) (inches w.c.) (inches w.c.) (inches w.c) (inches w C) Temp ff) 

17101100 ofov #t,- .13 610 /;, 0 5, 0 

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wvv-1 F Maste, As 12J29t9B R"SED. NOV 1998 

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1775268

-l/ 

APPENDix A-3 

Operational Data Summaries 

I 

1775269

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APPENDix A-4 

Incidental Water Treatment Forms 

1775274

FAIRCHILD AFB WW-1 1775275 


INFORMATION 

SOURCE (e.g,, etc.) FT-(, Li J- 154v -1. P'S-) ) 5'6-3z 

LOCATIONOFSOURCE(e.g.,moiiitoriiig\Nellnuiiiber,etc.) s4p, lf.%IeA aGrf, 

DATEOFGENERATION qlIZID, 

DATEOFSAMPLING 5ame, cts 



APPROVAL BY 

(Fairchild Airforce Base) 

INbIVI6UA TR149i6ilild WATE 

C-A 5 4-rs f--u- 

NAME SIGNATURE irlkr TITLE 


DATE aIIgZgv TIME la,70 

ACCEPTING TANK T--tuT- T-401 

QUANTITY OF TRANSFER I IQ 

INDIVIDUAL RECFJVING WATER 

NAME' SIGNATURE ORGAN. TITLE 

COMMENTS:


1775276 


SOURCE (e.g., well purging, etc.) 


LOCATION OF SOURCE (e.g., monitorina well number, etc.) 

MO? //'eV Mr WCA 

DATE OF GENERATION 2 -3 eAl -r 74- 




APPROVAL BY- 

(Fairchild Air.Force Base) 

INDIVIDtAL TRANSPQRTIN! 

NAME SIMATURE FAFB TITLY 


DATE TIME 

ACCEPTING TANK T-tol- T-1-ff - 

QUANTITY OF TRANSFER 465,- 

INDIVIDUAL RECEIVING WATER 

40h.e'rf Work -4') III-r/ light 


COMMENTS: 

0 (42-

X 

i\ 

A"ENDix A-5 

I/ Sampling Documentation Forms 

-1 

1775277

FAIRCHILD AFB 



SAMPLING DATE: 2--1 -0 0 

SAMPLETEAMMEMBERS: 

SAMPLE MATRIX (circle on roundwater Other. 


of:10 VPA Yj A Lwq 

VI vi I - F- ID 0 F-, O'D 

LABORATORY: 00(-QtA,%%P,. 

COMMENTS: Q Ir4R-oE,,)T- 

lf-m 

COMPLETED BY 

(sagno/6 /(d a I e/ 

177527B

"PENDix A-6 

Event/Repair Forms 

1775279

Ww-1, Fairchild Air Force Base 



Project No.: 146680.96.94 Repair Number: #17 

Initial Date: March 6,2000 Completion Date: Sel2tember 30, 2000 

Employee Responsible: Bob Worl Title: Treatment Plant Operato 

Estimated Repair Cost: J2,M Final Repair Cost: J6,121 

Est. CH2M HILL Level of Effort (LOE): 20 hrs Final CH2M HILL LCIE: 33 hrs 

Equipment Purchased: -Yes X No AS-BuiltUpdated-Yes X No 

Nature of the Problem: Miscellaneous small reRairs and work items for unforeseen reRair 

and repairs completed at the direction/request of Fairchild AFB staff. 

Nature of Repairs: 

1. Reconnaissance for WW-1 source investigation 

2. Fire Alarm System repair on March 22, 2000, by General Fire 

3. Compilation of electronic data deliverable, data validation, preparation of 

ERPIMS submittal for treatment plant analytical data, and site survey to obtain 

state plane coordinates for treatment plant sampling locations 

1775280 

4. Replaced pump and motor on EW-1 using spare parts on July 27, 2000, by CH2M 

HILL staff 

UACLIENT PROJECT DELIVERA146680 -FAIRCHILMONTRACT8019 REPAIRSMW-tREPAIR ITDOC

A"ENDw A-7 

I/ Alarm Response Forms 

1 7 75281

CH2M Hill -- Alarm Response Form 1775282 

WW1 Site, Fairchild Air Force Base 

Date: /)5/JZ/z-va Time: 1;24an ProjectNo.: 146680.7Z.-I) 

Repair Number: (if applicable) Repair Needed: Yes X No 

Employee Responding: ,X4W' (initial responder) LOE: - 2. hrs 



Alarm: 462z, e9az.,";p 

Cause of Problem: eoge 

ActionsTakem-A.-o1-z"y 

INMATE REPAIR DATE, 

REPAIR CPLETED DAPE:

1775283 CH2M Hill Alarm Response Form 


Date: aZlil lel, Time: C9 Project No.: 146680. 

Repair Number: (ifapplicable)RepairNeeded:- YesX No 

Employee Responding: :d #.e,- (initial responder) LOE: hrs 



Alarm: 

,7e79 

Cause of Problem: efA,&e4,a 

Actions Taken: 

INITLATE REPAR DATE 

REPAIRCOMETED DATE

CH2M Hill -- Alarm Response Form 1775284 


Date: OZIAZ Time: 1,zqa ProjectNo.: 146680.z,-zz 

Repair Number: # (if applicable) Repair Needed: *Yes No 

Employee Responding: ,Of (initial responder) LOE: hrs 



Alarm 


Actions Taken: 

INITIATE 

REPAIR d,41,01 #V..It/ DATE 

REPAIRCOMPLETED: DATE' Glze!4,w

Appendix Tab 

kpeodl\ 13 

Row umvvtm- 

1775285

1775286 

WW-I Site Flow Summary (Table B-1) 


flow meter measures the flow con-dng from that well. The total flow discharged by the GTP, 


P-5 flow meter. The discharge from the plant (approximately 27 gpm) is intern-dttent and 


Well Point System, which includes EW-3, WP-I, WP-2, and WP-3. As a result, flow 


5 and EW-1 flow meter values. Average flow rates are also calculated for each system by 

dividing the daily flow volumes by the operating time in minutes for each month. 

EW-1 Routine Maintenance 

During routine maintenance of EW-1, the discharge line is connected in a circuit to flush 

chlorinated water through the system for about a 24-hour period. The flow meter for EW-1 

registers the circulating flow, which creates a false influent flow reading at the GTP. The 

only flow into the GTP during this time is from the Well Point System. Consequently, the 

average calculated flow rate for P-5 is equal to the average calculated flow rate for the Well 

Point System during this time period. 

As reported in Table B-1, the calculated average flow rate values for EW-1 on August 23, 

2000, and September 28, 2000, are zero. These zero values are a result of re-circulating EW-1 

during routine maintenance beginning on August 22, 2000, and September 27, 2000, 

respectively. EW-1 also was re-circulated on July 27,2000; however, the re-circulation was 

discontinued after only 4 hours due to EW-1 pump and motor failures, which caused a low 

flow alarm at the GTP. As a result of the short maintenance period for EW-1 in July, the 

values reported in Table B-1 for July 28, 2000, are not corrected. 

2000 WW-1 Site Flow Summary (Table B-2) 


Point System, and P-5 through the third quarter of 2000. The flow rates are calculated by 




above. 

SPMPPENDIX 8 DOC

Table B-1 

WW-1 Site Flow Summary, Third Quarter 2000 

1775287 

EW-1 Well Point System Total Plant Discharge (P-5) 


Flow Rate Flow Volum stage Flow Volume Average Flow Rate Average Flow 

Date Time Flow Rate Flow Rate Flow Rate Volume 

Wpm) (gallons) (gallons) IgPm) Wpm) WPM) (gallons) 

1-Jul-00 9:00 6.8 14,339,680 6 9 4,574,337 3.0 27 9.9 20,636,736 

3-Jul-00 10 00 6.6 14,359,577 - 6 8 4,582,551 2.8 27 9.6 20,664,847 

7-Jul-00 8:00 I 6.5 14,396,656 1 6 6 4,593,059 1.9 27 8.4 20,712,434 

12-Jul.00 14:00 6 4 14,445.225 6.4 4,604.128 1 1.5 27 7 9 20,772,072 

14-Jul-00 10:00 5.8 14.462,093 6.4 4,614,509 3.9 27 10.3 20,799,321 

1 8-Jul-00 8:30 5.8 14,487,797 4.5 4,636,661 3 9 27 8.4 20,847,177 

21-Jul-00 8:00 5.3 14,511,528 5.5 4,650,855 3.3 27 8.8 20,885,102 

24-Jul-00, 8:30 6.9 14,534.566 53 4,667,227 3.8 27 9.1 20,924.512 

27-Jul-00 8 30 6.8 14,564,662 7.0 4,679,729 2.9 27 9.9 20,967,110 

28-Jul-00 6:00 7.6 14,576,759 9.46 4,678.730 -0.8 27 8.6 20,978,208 

31 -Jul-00 6:00 1 7.5 14,608,029 1 7.3 4,691,111 2.9 1 27 10.2 21,021,859 

2-Aug-00 8 00 7.0 14,629,326 7.1 4,699,749 2.9 27 10.0 21,051,794 

B-Aug-00 9:00 6.6 14,688,533 6.8 4,723,636 2 7 28 9.6 21,134,888 

11-Aug-00 9:45 6.4 14.716.905 6.5 4,735,405 2.7 27 9.2 21,175,029 

14-Aug-00 8:30 6 3 14,743,799 6.3 4,746.320 2.6 27 8.9 21,212,838 

17-Aug-00 9.30 6.2 14,771,112 6.5 4,757,228 2.6 27 9.1 21,251,059 

21-Aug-00 11,00 6.4 14,801,697 6 4 4,769,269 2 5 27 8.9 21,293,685 

22-Aug-00 8.15 6.4 14,809,741 6.3 4,772,242 1 2 3 26 8.6 21,304,702 

23-Aug-00 8:15 1 6.4 14,849,694 1 0.0 4,737,777 3.8 27 3.8 21,310J90- 

27-Aug-00 6 30 5.9 14,887,220 6.9 4,752,232 2.6 27 9.5 21,362,171 

30-Aug-00 8 00 5.6 14,908,353 4.8 4.760,975 2.0 27 6.8 21.392.047 

I-Sep-00 8.00 5 5 14,924,545 5.6 4.767,527 2.3 27 7.9 21,414,791 

5-Sep-00 9:00 5.5 14,956,267 5.5 4,780,591 2.2 27 7.7 21.459,577 

6-Sep-00 9:00 5.5 14,964.038 5 4 4,783,818 2.2 27 7.6 21,470,575 

12-Sep-00 9:00 5.3 15,010,470 5 4 4,803,032 22 27 7.6 21,536,221 

14-Sep-00 7:30 5 3 15,025,192 5.3 4,809,107 2.2 27 7.5 21,557,018 

18-Sep-00 10:30 1 5 1 15.056.265 1 5.6 4,823.160 2.5 1 27 8.2 21.602,144 

19-Sep-00 8.45 5.3 15,058,419 5.0 4,824,344 2.7 27 7.7 21,605,482 

21-Sep-00 8 00 5.0 15,072,983 5.1 4,831.326 2.5 26 7.6 21,627,028 

26-Sep-00 9.30 5.1 15,109,718 5.0 4,849,995 2.6 26 7.6 21,682,432 

27-Sep-00 8:45 5.0 15,116,589 4.9 4,853,726 2.7 26 7 6 21,693,034 

28-Sep-00 8:30 6.3 15,155,047 - 0 ::26 098 3.8 26 3.8 21.698,451 - 

I-Oct-00 10 00 5.8 15,157,523 419 27474 2.7 26 1 7.6 21,702,303 

Notes: 

'The zero values listed in the EW-1 column are a result of re-circulating EW-1 during routine maintenance The associated measured flow rate 

values are measured readings collected prior to starting EW-1 recirculation. 

turing the routine re-circulation of EW-1 on July 27th, the pump and motor on EW-I broke do" after approximately 4 hours of re-arculation, 

Icausinq a low flow alarm at the GTP. 

SPIK/Appendix Table B-1 xls i56470.02.92.94

1775288 

[#0#(0(f it: -6u-ar-te r-S--u q- prig-ar-- 

Table B-2 

2000 WW-1 Site Flow Summary 

EW-1 Well Point ystem P-6 EW-11 Re-circ 


Operation (gallons) (gpm) (gallons) (gpm) (gallons (gpm) (gallons) 

January 285,962 6.4 123,182 2.8 409,144 9.2 0 

February 261,760 6.4 108,472 2.6 370,232 9.0 35,588 

March 326,917 7.4 146,449 3.3 473,366 10.7 0 

Ist Quarter 874,639 6.7 378,1 D4 2.9 9.6 35.588 

F2V06-Se QuarWr SUT'91afy 

EW-1 Well Point m P-5 EW-1 Re-circ 



April 278,505 7.5 102,116 2.7 380,621 10.2 36,359 

May 330,760 7.4 106,505 2.4 437,265 9.8 0 

June 263,535 6.6 135,571 3.4 399,106 10.0 33,321 

2nd Quarter 872,800 7.2 3",192 2.8 1,216,992 10.0 69,680 

[2_CD0Tfilrcl[Qu rterSummary_ 

EW-1 Well Point M P-5 EW-1 Re-circ 



July 273,189 6.1 126,902 2.8 400,091 9 0 5,809 

August 265,915 6.2 112,050 2.6 377,965 8.7 39,953 

September 194,520 5.1 92,992 2.4 287,512 7.6 38,458 

3rd Quarter 733,623 5.8 331,944 2.6 1,065,567 8.4 84,220 

SPKIFIow CalmAs 156470M.gZ94

Appendix Tab 

LTO An &.1 

Arppevjjl ( 

co"I pafv, 

1775289

I/ 

1 

APPENDIX C-1 

Water Sample Results 

I 

1775290

Columbia 

Analytical 

INC- 

ServiceS 

Mr. Mark Henry An Employee-Owned Company 

CH21M HILL/SPK 


Suite 400 

Spokane, WA 99204-0219 


Fairchild AFB WW1 Plant Monitoring 

D0003785/D3785 

Submitted by: 

414W AW 

Bryan Jones 


Enclosures 


October 13, 2000 

This report contains a total of 37 pages. 

1 7 752 9 

5090 Caterpillar Road - Redding, CA 96003 - Telephone (530) 244-5227 Fox (530) 244-410§' 0


Level III 

TABLE OF CONTENTS 1775292 

Cover Page ....................................................................................................................... I 


A FCEE Data Q ualifiers .................................................................................................... 4 


Page 

No. 

G C/M S VO LA TILE O RGA N ICS .................................................................................... 6 


A FCEE Form 0 -1 ................................................................................................... 8 

A FCEE Form 0 -2 ................................................................................................... 9 

A FCEE Form 0 - I ................................................................................................. I 3 

A FCEE Form 0 -4 ................................................................................................. 19 

A FCEE Form 0 -5 ................................................................................................. 21 

A FCEE Form 0 -6 ................................................................................................. 24 

A FCEE Form 0 -7 ................................................................................................. 26 

A FCEE Form 0 -9 ................................................................................................. 28 

A FCEE Form 0 - IO ............................................................................................... 29 

A FCEE Form 0 -1 I ............................................................................................... 30 

A FCEE A ppendix A .............................................................................................. 32 

A FCEE A ppendix C .............................................................................................. 3) 3) 


Chain of Custody Docum entation ................................................................................... 35 

C 2

Intentional Blank 

1775293 

0 u , 3

AFCEE Data Qualifiers 






MDL. 





criteria. 





T Tentatively identified compound (using GC/MS). 

1775294 

0 O 0 4



Lab Sample ID Sample ID Date Date Sample Matrix Additional Description 

FS = Field Sample; LCS = Lab Control Sample; NON = Non-Sampte Type (Internet Acknin) 

D3785000 NON EDATA 09/28/00 09/28/00 00:00 Administration EDATA 

D3785001 FS 09WWIIP01INF 09/28/00 09/27/00 09:10 Water 0009WWI-IP-01-INF 

D3785002 FS 09WWIEPOIEFF 09/28/00 09/27/00 09:00 Water 0009WWi-EP-Oi-EFF 

1775295 

The above tab sample ID-s and cross reference information apply to samples as received by the Laboratory. Modifiers 

to the tab sampte ID my be added for internal tracking purposes. Any modified sample ID wilt be reflected in the 


0 5

i 


1775296 

C. 0 0 6


Project: Fairchild AFB WWI PM 

I. RECEIPT 


GC/MS VOLATILE ORGANICS 1775297 



II. HOLDING TI14ES 



III. METHOD 


Cleanup: N/A 




V. ANALYSIS 






F. Samples: All acceptance criteria were met. 




harchcopy data package has been authorized by the Laboratory Manager or 


SIGNED: DATE: to 

Brian Moore 

Senior Chemist, GC/MS 

5090 Caterpillar Road Phone (530)24 Q7 

Columbia go 

Analytical Semces Redding. CA 96003-1412 Fax (530)24V4 7

AFCEE QAPP 

Version 3. 0 

1775298 March 1998 

AFCEE 



Lab Name: Columbia Analytical Services/Redding Contract#: F41624-94-D-8019 



Comments- 



09WWIIPOIINF D3785001 

-T9 WW -IEP0 I EF -53785002 

AFCEE FORM 0-1 0008 

RDD W1011 %Z B5.1111PST4R D"1183 DUS1.1

AFCEE A FCEE QA PP 

ORGANIC ANALYSES DATA SHEET 2 Versioli 3. 0 

RESULTS 1775299 March 1998 

Analytical Method SW8260B AAB H: D37U 


FieldSampleID: 09WWIIPOIINF LabSampIeID: D3785001 Matrix- Water 

% Solids: SampleDescription: 0009WWI-IP-01-INF 

Date Received: DatePrepared: .. DateAnalyzed: 9Oct00 

ConcentrationUnits(ug/Lormg/Kgdryweight): Sample Volume: 25.0 ML 


1,1,1-TCA 0.13 1 U 

1,1,2,2-Tetrachloroethane 0.13 

1, 1,2-TCA 0.12 

lI-DCA 0.14 

I I-DCE 0.13 

1,2-DCA 0.13 

I,2-DCB 0.12 

1,2-Dichloropropane 0.12 U 

1,3-DCB 0.13 U 

1,4-DCB 0.13 U 

Bromobenzene 0.12 U 

Bromodichloromethane 0.13 U 

Brornoform 0.12 U 

Bromomethane 0.26 1.1 0 

Carbon tetrachloride 0.14 

Chlorobenzene 0.12 0.1 

Chloroethane 0.1 

Chloroform 0.13 1. 

Chloromethane 0.14 0.4 

Cis-1,2-DCE 0.13 1 

Ci 0.10 U 

Dibromochloromethane 0.11 U 

Dibromomethane 0.14 U 

Methylene chloride 0.14 

TCE 0.15 


Tr 0.15 0.6 

Trans- 1,3-Dichloroprope 0.10 10 U 

Trichlorofluoromethane 0.14 0.8 U F 

Surrogate Recowries or, reported in Appendix O-A 

Comments: internal Standards are reported in Appendix 0-C 

AFCEE FORM 0-2 Page I of 4

AFCEE A FCEE QAPP 

1775300 ORGANIC ANALYSES DATA SHEET 2 Version 3.0 




FieldSampleID: 09WWIIPOIINF LabSampleID: D3785001 Matrix: Water 

% Solids: SampleDescription: 0009WWI-[P-01-INF 

Date Received: Date Prepared: Date Analyzed: 9 Oct 00 

Concentration Units (ug/L or mg/Kg dry weight): I... Sample Vo ume: 

_qgL 1 25.0 ML 


Surrogate Recovery Control Limits Qualifler 


Toluene-D8 94 75-125 


Fluorobenzene 


1.4-Dichlorobenzene-d4 


Su"ogate Recoveries are reported in Appendix O-A 


AFCEE FORM 0-2 Page 2 of 4 HIM-1)(1/11/1 X7 R1-J531PQ-V1? 11.113115-11JG-( 0


ORGANIC ANALYSES DATA SHEET 2 1 775301 Version 3.0 


Analytical Method- SW8260B AAB,#: D3785 


Field Sample ID: 09WWIEPOIEFF _ Lab Sample ID: D3785002 - Matrix: Water 

% Solids: SampleDescription: 0009WWI-EP-01-EFF 

Date Received: DatePrepared: DateAnalyzed: 9OCtOO 

ConcentrationUnits(ug/Lormg/Kgdryweight): _jj&Lj... SampleVolume: 25.0 ML 

Analvte MDL RL I Concentration I Dilution Confirin Qualifier 

1,1,1-TCA 0.13 0.81 - 0.131 1 U 

I'l, 2-Tetrachloroethane 0.13 0.4F 0.131 I I U 

1,1,2-TCA 0.121 1.0 0.12 1 I U 

],I-DCA 0.14 0.4 0.14 1 I U 

II-DCE 0.13 1.2 0.131 1 U 

1,2-DCA 0.13 0.61 0.131 1 1 1 U 

0.121 0.12 

1,2-DCB 03 1 I I I 

1,2-Dichloropropane 0.121 0.41 0.12 1 I U 

I,3-DCB 0.13 1.2 0.13 I 

I,4-DCB 0.13 0.3 0.13 I 

Bromobenzene 0.1+2 0.3 0.12 I 

Brornodichloromethane 0.13 0.8 0.13 1 

Bromoform 1 0.12 -1 

Bromomethane 0.26 LI 0.26 1 

Carbon tetrachloride 0.14 21 0.14 1 

Chlorobenzene 0.12 0.4 0.12. I U 

Chloroethane 0.181 1.01 0.18 I U 

Chloroform 0.13 0.3 0.13 1 U 

Chloromethane 0.14 1.3 0.50 I F 

Cis-1,2-DCE 0.13 1.2 0.13 I U 

Cis-1,3-Dichloropropene 0.10 1.0 0.10 I U 

0.5 0.11 U 

Dibromochloromethane 0.11 

Dibromomethane 0.14 2.4 -- 0.14. 1 U 

Methylene chloride 0.14 0.3 0.391 I 

TCE 0.15 1.0 0.151 1 U 

Tetrachloroethene 0.12 1.4 0.12 1 1 U 

Trans-1,2-DCE 0.15 0.6 0.151 1 U 

Trans- 1,3-Dichloroprope 0.10 I.OF- - uol I I U 

Trichlorofluoromethane 0.8 0.14 1 1 1 -- U 

Vinyl chloride 0.13 1.1 0.131 1 1 1 U I 

Surrogate Recoveries are reported in Appendix 0-A 


AFCEE FORM 0-2 Page 3 of 4 )UM-0011,11 %7 H.%-Ii3ii-Si-NU 1111"(0715-11lao 1 1




Analytical Method. SW8260B AAB #: D3785 

Lab Name: Columbia ding 

Analytical Services/Red j, Contract #: F41624-94-D-8019 

FieldSampleID: 09WWIEPOIEFF _ LabSarnpIcID: D3785002 - Matrix: Water 

% Solids: Sample Description- 0009WWI-EP-01-EFF 

Date Received: 28 Sep 00 Date Prepared: Date Analyzed. 9 Oct 00 

Concentration Units (ug/L or mg/Kg dry weight): _qLL.. Sample Volume: 25.0 ML 




Toluene-D8 97 75-125 

4-Bromotluorobenzene 102 75-125 

Fluorobenzene 




Surrogaie Recowries are eported in Appendix O-A 

Comments: Internal Siandards are repoied ,, Appendix 0-C 

AFCEEFORMO-2 Page4of4

AFCEEQAPP 


ORGANIC ANALYSES DATA SHEET 3 (Part 1) Afarch 1998 

INITIAL MULTIPCINT CALIBRATION-GC/MS 


Lab Name: Columbia Analvtical Services/Reddinp Contract F41624-94-D-8019 

Instrument ID: MSK Date of Initial Calibration: 9 Oct 00 GC Column ID: RTX-624 


Initial Calibration Sample lDs VSTDO03 VSTDO05 VSTDO I 0 VSTDO15 VSTDO20 VSTDOOI VSTDO05 

Calibration File IDs. K004115 K004118 K004119 K004120 K004121 K004117 K004116 

Analyte Std RF Std RF Std RF Std RF Std RF Std RF Std RF 

I 1 2 2 3 3 4 1 4 5 5 6 6 7 7 

1, 1, I -TCA 5 000 0 3 87 10 00 0 367 15.00 0 347 20 00 0 363 0,500 0.390 

1, 1,2,2-Tetrachloroethane- 0.300 0.340 5,000 0 372 10.00 0.367 15.00 0,355 20.00 0 385 

1,1,2-TCA 5.000 0.197 10.00 0.184 15 00 0.177 20.00 0.193 1.000 0.184 

1.1-DCA* 0 300 0 378 5.000 0 398 10.00 0 377 15.00 0.357 20.00 0 3 72 

II-DCE# 5 000 1 0.1371 10.00 01421 15 00 0,135 20.00 0 145 1 000 0.148 1 

1,2-DCA 5,000 0 251 10 00 0,241 15.00 0 218 2000 0 220 0.500 0.242 

1,2-DCB 0300 1.090 5 000 1 181 10.00 1.195 15.00 1.166 20 00 1 285 

1,2.Dichloropropane# 0 300 OA81 5,000 0,198 10 00 0 200 15 00 OA87 20.00 0.204 

1,3-DCB 5,000 1 383 10 00 1.370 15.00 1 347 20 00 1 483 1 000 1 381 1 

1,4-DCB 0.300 1 368 5 000 1361 10.00 1 383 1 5 00 1 299 20 00 1 454 

Bromobenzene 0 300 0,645 5.000 0 736 10 00 0.747 15.001 0.729 NM 0 809 1 

Bromodichloromethane 5 000 0.322, 10.00 0 304 15.00, 0.290 20.00 0.301, 0 500 0 294 1 

Bronnoform- 5 000 0 188 10 00 0.191 15 00 0 184 20,00 0.207 1.000 0 160 

Bromomethane 5.000 0 126 10 00 0129 15.00 0 118 20 00 0 119 1 000 0136 

Carbon tetrachloride 5.000 0 302 10 00 0,293 15.00 0 276 20 00 0 294 1 000 0302 

Chlorobenzene- 0 300 0 910 5,000 0,956 10 00 0.948 15.00 0.924 20.00 1014 1 

Chloroethane 5 000 0.100 10 00 0 099 15 00 0.090 20 00 0 091 1.000 0103 

Chloroform# 5.000 0 480 10.00 0.459 15 00 0 424 20.00 0.444 0 500 0 471 

Chloromethane- 5.000 0 229 110 00, 0 250, 15.00 0 225 20 00 I 0 232 1,000 0,240 1 

Cis-1,2.DCE 5,000 0.262 10.00 0,255 15.00 0 247 20 00 0.258 1.000 

Cis-1,3-I)ichloropropcne 5,000 0.328 10 00 0,329 15.00 0315 20 00 0 334 1.000 0.280 

Dibromochloromethane 5 000 0 296 10 00 0 300 15 00 0 289 20.00 0 321 0 500 0 262 1 

Dibromomelhant 5 000 0121 10 00 0 115 15.00 0 112 20 00 0.115 1 000 0.112 

Methylere, chloride 0.300 0 204 5.000 0 i55 10 00 0.1471 15.00 0 133 20 00 0 144 

ITCE 5 000 0 256 10.00 0 252 15 00, 0,240 120.00 0 255, 1.000 0 258 

SPCCs # CCCS 

Comments: 

AFCEE FORM 3 (Parl 1) Page I of 2 

RMI-11"I'M A7 BY-15311-S1,W1 111111037A3.11) 4910 1 3

AFCEEQAPP 

Version 3.0 

1775304 AFCEE March 1998 


INITIAL MULTIPOINT CALIBR-ATION-GC/MS 

Analytical Method: SW8260B AAB #. D3785 

Lab Name. Columbia Analytical Services/Redding, - Contract #: F41624-94-D-8019 


Concentration Units (ug/L or mgikg): UG/L 

Initial Calibration Sample IDs: VSTDOO.3 VSTD005 VSTDO I 0 VSTDO15 VSTDO20 VSTD001 VSTDO05 

Calibration File IDs: K004115 K004118 K004119 K004120 K004121 K004117 K004116 

Analyte Std RF I Stcl RF Stcl RF Std I RF Stcl RF I Stcl RF Stcl RF 

I 1 2 2 3 3 4 4 5 5 6 6 7 7 

Tetrachloroethene 5 000 0 4561 M00 0.43 7 15 00 0.436 20 00 1 0.491 1.000 0 427 

Trans-1,2-DCE 5 000 0,1671 10 00 0 163 15.00 OA57 20.001 0.166 O500 0 173 

Trws-1,3-Dichloropropene 5 000 0 372 10 00 0 382 15.00 0,371 20 00 0.405 1.000 0316 

Trichlorofluoromethane 5000 0304 10 00 0192 15 00 0,270 20.00 0 275 0,500 0.305 

Vinyl chlonde# 5.000 0 203 110.001 0.217 15 00 0.198 20 00 0.209 1.000 0 205 

Dibromofluoromethane 5 000 0 287 110 00 0 274 15 00 1 0.264 20 00 0.274 1 000 0.278 

Toluene-DS 5 000 1 224 110 00 1.232 15.001 1,185 20 00 1 315 1 000 1 145 

4-Bromofluorobenzene 5 000 0 807 M00 0 832 15 00 1 O826 20 00 0896 1.000 0 752 

SPCCs CCCs 

Comments: 


j, 4

AFCEEQAPP 


ORGANIC ANALYSES DATA SHEET 3 (Part 2) Afareh 1998 






Initial Calibration Sample ]Ds VSTDO03 VSTDO05 VSTD0l0 VSTDO15 VSTDO20 VSTD001 VSTDOOS 

Calibration File lDs. K004115 K004118 K004119 K004120 K004121 K004117 K004116 



1,1,[-TCA AVG 0 371 4.8 5.46 

1,1,2,2-Tetrachloroethane- AVG 0.364 4 7 5 46 

1,1,2JCA AVG 0.187 4.3 5 46 

1, I -DCA- AVG 0.376 3.9 5 46 

1.1-DCE# AVG 0 141 3.91 5.46 

1,2-DCA AVG 0.234 6 1 5 46 

1,2-DCB AVG 1 183 5.9 5.46 

1,2-Dichloropropanc# AVG 0 194 4 9 5.46 

1,3-DCB AVG 1.393 3 8 5 46 

1,4-DCB AVG 1 373 4.0 5.46 

Bromobenzcne AVG 0.733 8 0 5 46 

Bromodichloromethane AVG 0.302 4 1 1 5 46 

Bromoform- AVG I 0 186 9 1 5.46 1 1 1 

Brornomethane AVG 0,126 5.6 5 46 

Carbon tetrachloride AVG 0,293 3 7 5 46 

Chlorobenzene- AVG 0 950 4 2 5 46 

Chloroethane AVG 0 097 6 0 5.46 

Chloroform# AVG 0 456 4.9 5.46 

Chloromethane- AVG 0 235 4.2 5.46 

Cis-1,2-DCE AVG 1 0.253 3 0 1 5A6 

Cis-13-Dichloromopene AVG 0 317 70 5 46 

Dibromochloromethane AVG 0.294 3 5 46 

Dibromomethane AVG 0 115 3 2 

Methylene chloride AVG 0.15 7 17 5 

TCE AVG 0 252 2.9 

SPCCS N CCCs 

Comments: 

AFCEE FORM 3 (Part 2) Page I of 2

AFCEEQAPP 


1775306 ORGANIC ANALYSES DATA SHEET 3 (Part 2) March 1998 

INITIAL MULTIPOINT CALIBRATIONI-GC/MS 





Initial Calibration Sample [Ds VSTDO03 VSTDO05 VSTD010 VSTDO15 VSTDO20 VSTDOOI VSTDO05 

Calibration File [Ds. K004115 K004118 K004119 K004120 K004121 K004117 K004116 



Teirachloroethene AVG 0 449 56 5.46 

Trans-1,2-13CE AVG 0.165 3 5 5 46 

Trans-1,3-Dichloropropene AVG 0369 8 8 5 46 

Trichlorofluoromethane AVG 0 289 5.5 5 46 

Vinyl chlorideO AVG 0 206 3.41 5 46 

Dibromofluoromethanc AVG 0 275 2 9 5 46 

Toluene-D8 AVG 1.220 5.2 5 46 

4-Bromofluorobenzene AVG 0 823 6 3 5.46 

SPCCs # CCCs 

Comments: 

AFCEEFORM3(Part2) Page2of2

A FCEE QA PP 

AFCEE 1775307 Versioit 3. 0 






Concentration Units (ug/L or mg/kO. UG/L 

Initial Calibration Sample II)s VSTDO03 VSTDO05 VSTDO I 0 VSTDO 1 5 VSTDO20 VSTD001 VSTDO05 

Calibration File IDs, K004115 K004118 K004119 K004120 K004 I 21 K004117 K004116 

Analyte Stcl RF Stdl RF Std RIF Stcl RF Stcl RF Std RF Std RF 

I 1 2 2 3 3 4 4 5 5 6 6 7 7 

1, 1,2,2-Tetrachloroethane- 0 300 0 340 5 000 0 372 10.00 0.367 15.00 0 355 20 00 0 385 

II-DCA' 0.300 0.378 5 000 0 398 10.00 0.3 77 15.00 0.3 57 20.00 0.372 

II-DCE# 5 000 0,137 10.00 0,142 15.00 0 135 20.00 0145 1 000 0 148 

1,2-Dichloropropane# 0.300 0 181 5 000 0 198 10.00 0,200 15.00 0.187 20.00 0.204 

Bronroform. 5 000 I 0 1881 10.00 0 1911 15 00 0 184 20001 0.207 1.0001 0.160 

Chlorobenzene- 0.300 0.910 5.000 0 956 10 00 0 949 15 00 0 924 20.00 1.014 

Chlorofom# 5M0 0 480 10.00 0.459 15.00 0.424 20.00 0 444 0 500 0 471 1 1 

Chloromethane- S 000 0 229 10.00 0.250 15M 0 225 20M 0 232 1 000 0 240 

Vinyl chloride# 5 000 0 203 10 00 0.217 15.00 0 198 20 00 0109 1 MO 0 205 

SPCCS CCCs 

Comments: 


Rj)I)-0II Ill II A7 H153 1/'.% /-.V? IM6113 785-1)j M3- I' 

0017

A FCEE QA PP 

1775308 AFCEE Version 3. 0 


INITIAL MULTIPOFNT CALIBRATION-GC/MS 





Initial Calibration Sample IDs VSTDO03 VSTDO05 VSTD010 VSTD015 VSTDO20 VSTD001 VSTD00i 

Calibration File lDs K004115 K004118 K004119 K004120 K004121 K004117 K004116 



1,1,2,2-Tetrachlorrotthane* AVG 0.364 4 7 5 46 

1, I -DCA- AVG 0 376 3.9 5A6 

1, I -DCE4 AVG 0 141 3.9 5.46 

1,2-Dichloropropaneg AVG 0.194 4 9 5 46 

Bromof0mn* AVG 0.186 9 1 5 46 

Chlorobenzene- AVG 0.950 4 2 5.46 

Chlorofornng AVG 0 456 4.9 5 46 

Chloromethane* AVG 0.235 4 2 5 46 

Vinyl chloride# AVG 0 206 3 4 5 46 

SpCCS # CCCS 

Comments: 


I 

A7 HI 15311'11 III 11.11,13-13-1137,Ij '01518

AFCEE 





Instrument ID: MSK Initial Calibration ID: K004124Q.D 


GC Column ID: RTX-624 

Comments: 

AFCEEQAPP 

1775309 Version 3.0 

March 1998 


1,1,1-TCA 10 00 9 507 -4 8 

1, 1,2,2 Jetrach I oroethan e 10 00 10 64 6 3 

1,1,2-TCA 10 00 9,651 -33 

1,1 -DCA* 10.00 10.60 5.9 

1, I -DCE4 i 0.00 10 40 3 9 

1,2-DCA 10 00 9,4151 -5 7 

1,2-DCB 10.00 10 29 2.9 

1,2-Dichloropropanc# 10 00 10.21 2O 

1,3-DCB Moo 10 09 0 ( 

1,4-DCB Moo 9 885 -1.2 

Bronnobenzene 10.00 10.38 3 8 

Bromodichloromethane I OM 9 734 -2 8 

Bronnoforrn- 10.00 M01 -0.0 

Bronnornoliane 10.0( 10.701 6 7 

Carbon tetrachloride 10.00 9 731 -2 6 

Chlorobenzene- 10.00 9 909 -0 9 

ChlMethane 10 00 10 03 0.4 

Chlorofom# 10.00 9 646 -3.4 

Chloromethane- 10 00 11 50 1 51 

Cis 1,2.DCE 10 00 10 2 3 2 3 

Cis- 1,3-DichlOrOPTOpene 10 00 10 581 5 9 

Dibromochloromethane 10 00 9.809 -1.8 

Dibroniomethane 10 00 9.821 .1 9 

Methylene chloride 10 00 9.055 -9 3 

TCE to 00 9 869 -1.3 

SPCCS # CCCs 


RDD001011 A7 SS4531PST-AR

AFCEE QAPP 

177 5 3 1 0 Version 3.0 

March 1998 

AFCEE 








Comments: 


Tetmchloroethene 10.00 9 894 -1.0 

Trans-1,2-DCE 10.00 9622 -3 7 

Trans-1,3-Dichloropropene 10.00 10.35 3 4 

Tnchlorofluoromethane 10 00 i 0.08 0.9 

Vinyl chloride# 10 00 10 72 7 0 

Dibromofluoromethane N/A N/A 00 

Toluene-D8 N/A N/A 0 0 

4-Bromofluorobenzene N/A N/A 0 0 

SPCCS CCCs 


RDD 01011 A7BS4131PST-SR DJ ,,,r

AFCEE QAPP 

1 7 7 5 3 1 1 Version 3. 0 








ICV File ID: K004124Q.D CCV #1 File ID: K004123.1) CCV #2 File ID: 



Analyte F-Expected I Found I %D or % drift Expected I Found I %D or % drift Found ID or % drift Q 

1.1,i-TCA 10 001 9.5071 -4.81 10 001 10.041 0 3 1 1 

1,1,2,2Tctrachloroelhanc- 10.001 10 641 6 3 1 10.001 10.921 9.3 1 1 

1,1,2-TCA 10,001 9,6511 -3.31 10.001 10 331 3.1 

1.1-DCA' 10.001 10,601 5.9 10.001 10.181 1.9 

II-DCE# I 001 10,401 3.9 10.001 9.9791 -0.3 

1,2-DCA 10 001 9 4151 .5.7 10 001 9 8671 .1.4 

1.2-DCB 10.001 10 291 2.9 10(01 10 491 4 9 

1,2-Dichloropropane# I .001 10,211 2.0 10,001 10.151 1.51 1 

1,3-DCB 10 001 10 091 0.9 10 001 10 231 2 

1,4-DCB loool 9.8851 -1 2 to 00 10.141 1 

Bromobenzene 10.001 10.381 3.8 10.00 10.741 7.5 

Bromodichloromethane 10.001 9,7341 -2.8 10.00 10.091 0.9 

Bronnoforrin- 10 001 10 oil 0 0 10 00 10 381 3 8 

Bronnornethane 10.001 10.701 6.7 1 10 00 10.351 3. 

Carbon tetrachloride 10,001 9 7311 -2.61 10.001 9,7891 -2.2I 

Chlorobenzen'. 10.001 9.9091 -0 9 10.001 9 973 421 

Chloroethane 10.001 10.031 0 4 10.001 9 860 -1.6 

ChlorofionrnH 10 001 9.6461 -3.4 10 001 9,806 -1.9 

Chloromethane' 10.001 11.501 M2 mool 10,41 4 1 

Cis-1.2-DCE 10.001 10.231 23 10 o(l 10 33 3 5 

Cis-1,21-Dichloropropere 10 001 10 581 5.9 10,001 10.34 3.4 

Dibronnochloronnelhane 10.001 9,8091 -1.8 i0.001 10 28 2 9 

Dibromomethane 10.001 9.8211 -1 9 10 00 10 21 2 5 

Methylene chloride lo 001 9 0551 -9.3 10 00 9,209 -8 I 

TCE 10 001 9 8691 -1.3 10 00 9.878 -1.3 

SPCCS CCCs 

Comments: 


RDD-001011 A2 BS 1531PST SRD"3785.0378B021

AFCEE QAPP 

177 5 3 1 2 Version 3.0 







ICV ID: QCALTSTD CCV #1 ID: VSTD010 CCV #2 ID. 

ICV File ID: K004124Q.D CCV #1 File ID: K004123.13 CCV #2 File ID: 


ICv Ccv #1 CCV #2 


Tetrichloroethene 10.00 9.894 -1.0 10.00 1010 10 

Trins-1,2-DCE 10.00 9 622 -17 10 00 10.08 0 5 

Trans-1,3-Dichloropropene 10 00 10 35 3 4 10.00 10.24 23 

Trichlorofluoromethane 10 00 10.08 09 1 10 00 9 908 -0 8 

Vinyl chloride# 10.00 7.0 10.00 10.04 0 2 

Dibromofluoromethane N/A N/A 0 0 10.00 9.8601 -1.3 

Toluene-D8 N/A N/A 0 0 10 00 9 554 44 

4-Brornofluorobenzene N/A N/A 0.0 10.00 10.16 In 

SpCcs CCCs 

Comments: 


ID Q 2 2 

RDD-M011 VZ BS-1131PSYSR DWOU85-D3,81-1

AFCEE OAPP 

1 7 7 5 3 1 3 Version 3. 0 








ICV File ID: K004124Q.D CCV #I File ID: K004123.1) CCV #2 File ID: 


Analyte ICv CCv #1 CCV #2 Q 

RF Expected Found %D RF Expected Found %D RF Found %D 

1,1,2,2-Tcuachloroethane- 0.387 10.00 10.64 6.3 0.398 10.00 10.92 93 

II-DCA- 0 399 10M 10 60 5.9 0 384 10.0( 1018 1.9 

),I-DCE# 0.147 10.00 10 40 3.9 0.141 10 00 9.979 -0.3 

1.2-Dichloropropane# 0.198 10.00 10.21 2 0 0.197 10.00 1015 1.5 

Bromofomi- 0.186 10.00 10.01 -0.0 0 193 10.00 10 38 38 

Chlorobenzene- 0.942 10 00 1 9 909 -0.91 0.948 1 10.00 9.9731 -0 2 1 

Chlorofonn# 0.440 10 00 9 646 -3 4 0.447 10.00 9M6 -1.9 

Chloromethane- 0 271 10.00 11 50 152 0 245 10.00 10.41 41 

Vinyl chlOTidC# 0.22 1 10.00 10.72 7 0 0 207 10.00 10 04 0.2 

SpCCS CCCs 

Comments: 


RDD-W10)1.k7 flS.1331PST4R D"1785 D?785 021 3


17753 14 ORGANIC ANALYSES DATA SHEET 6 Version 3.0 


Analytical Method: SW8260B AAB ft: D3785 


Concentration Units (ug/L or mg/kg): uv,/L MethodBlarkID: K1009WO1 

LabSampleID: KI009W01 


1,1,1-TCA 0.13 0.13 0.8 


1,1,2-TCA 0.12 0.12 1.0 

II-DCA 0.14 0.14 0.4 

LI-DCE 0.13 0.113 1.2 

1,2-DCA 0.13 k 1 13 0.6 

I,2-DCB 0.12 1 0.12 0.3 

1,2-Dichloropropane 0.12 1 0.12 0.4 

1,3-DCB 0.13 1 0.13 1.2 

I,4-DCB 0.13 1 0.13 0.3 1 



Bromofortri 0.12 0.12 1.2 

Brornomethane 0.26 0.26 1.1 



Chloroethane 0.18 I 0.18 1.0 

Chloroform 0.13 1 0.13 0.1 

Chloromethane 0.14 0.14 

Cis-1,2-DCE 0.13 0.13 1.2 

Cis-1,3-Dichioropropene 0.10 0.10 1.0 

DibromochloromethLn.e . . 0.11 0.5 


MethVlene chloride 0.14 0.14 0.3 

TCE 0 15 0.15 1.0 

Tetrachloroethene 0.12 I 0412 1.4 

Trans-1,2-DCE 0.15 1 0.15 046 




Comments. 

AFCEE FORM 0-6 Page I of 2 RDD-11(11111IA7B 1331P11-SH OW1113


AFCEE 1 775 3 1 5 AFCEEQAPP 




Concentration Units (ug/L or mgfkg): ug/L MethodBlankID: KI009W01 

LabSampleID: K1009WOI 

Comments: 




Toluene-138 96 75-125 


Fluorobenzene 





A7 HS

A FCEE QAPP 

'17 53 16 AFCEE Version 3.0 





LCSID: K1009WOlLCS Concentration Units (ug/L or mg/kg): ug/L 

Date Extracted: Date Analyzed: 9 Oct 00 


1, 1, I -TCA 10.00 9.51 9 5 75-125 


1,1,2-TCA 10.00 9.65 96 75-127 

1, I -DCA 10.00 10.60 106 72-125 

1, I -DCE 10.00 10.40 104 75-125 

1,2-DCA 10.00 9.42 941 68-127 

1,2-DCB 10.00 10.29 103 75-125 1 


1,3-DCB 10.00 10.09 101 75-125 

1,4-DCB 10.00 9.89 99 75-125 

Bromobenzene 10.00 10.38 104 75-125 

Bromodichloromethane 10.00, 9.73 97 75-125 

Bromoforin 10.00 10.01 1001 75-125 

Bromomethane 10.00 10.70 107 72-125 1 



Chloroethane 10.00 10.03 100 65-125 

Chloroform 10.00 9.65 96 74-125 

Chloromethane 10.00 11 50 115 75-125 

Cis-1,2-DCE 10.00 10.23 1021 75-125 

Cis-1,3-Dichloropropene 10.00 10.58 106 74-125 1 

-Fibromochloromethane 10.00 9.81 98 73-125 



TCE 10.00, 9.87 99 71-125 

Tetrachloroethene 10.00 9.89 99 71-125 

Trans-1,2-DCE 10.00 9.62 961 75-125 

-Trans- 1,3-Dichloropropene 10.00 10.35 104 66-125 

-Trichlorofluoromethane 10.00 10.08 101 67-125 


Comments: 

AFCEEFOPMO-7 Pagelol`2 RDD 00/011 ES-, 5 UPST SRD"aQ,46


7 7 5 3 1 7 AFCEE QAPP 





LCSID: K1009WOlLCS Concentration Units (ug/L or mg/kg): ug/L 

Date Extracted: Date Analyzed: 9 Oct 00 

Comments: 




Toluene-DS 95 75-125 


Fluorobenzene 




AFCEE FORM 0-7 Page 2 of 2 kz Bs par sH D,,w I 

RDD W101 I 3 ,',,7

AFCEE QAPP 

17 7 5 3 1 8 Version 3. 0 

March 1998 

AFCEE 


HOLDING TIMES 



Ist Max. Ist 2nd Max, 2nd Max. Time Q 



09WWIIPOIINF 27 Sep 00 28 Sep 00 N/A N/A N/A N/A N/A N/A 9 Oct 00 1 4 1 2 

09WWIEPOIEFF 27 Sep 00 28 Sep 00 N/A N/A N/A N/A N/A N/A 9 Oct 00 14 1 2 

Comments 


RDD 001011 %T BS MiPST-SR D"37fyolfj 28

AFCEE 





Instrument ID #: MSK 

177531 9 A FCEE QAPP 

Version 3.0 

March 1998 



VSTD003 K004115 9 Oct 00 0958 9 Oct 00 1028 

VSTDOO.5 K004116 9 Oct 00 1029 9 Oct 00 1059 

VSTD001 K0041 i 7 9 Oct 00 1100 9 Oct 00 1130 

VSTDO05 K004118 9 Oct 07 1131 9 Oct 00 1201 

VSTD010 K004119 9 Oct 00 1202 9 Oct 00 1232 

VSTDO15 K004120 9 Oct 00 1233 9 Oct 00 1 303 

VSTDO20 K004121 9 Oct 00 1304 9 Oct 00 1 334 

VSTD010 K004123 9 Oct 00 1406 9 Oct 00 1 1436_ 

K1009WOlLCS K004124 9 Oct 00 1508 9 Oct 00 I 1 538 

QCALTSTO K004124Q 9 Oct 00 1508 9 Oct 00 1539 

K I 009WO I K004127 9 Oct 00 1642 9 Oct 00 1712 

09WWIIPOIINF K004132 9 Oct 00 1917 9 Oct 00 1947 

09WWIEPOIEFF K004133 9 Oct 00 1948 9 Oct 00 2018 

Comments: 


RDD.01011 A7 HS-153) PST SRD0003785-DPA5. V 

0 0- 2

AFCEE QAPP 

Version 3. 0 

7 5 31-1 0 March 1998 


AFCEE 





Instrument ID: MSK Compound: BFB Injection Date/Time: 9 Oct 00 0928 

Mass I Ion Abundance Criteria % Relative Abundance Q 

:)U II 5% to 40% of mass 95 - - - - T97-- 

75 130% to 60% ot mass 95 43.7 

9-) 1 base peak, I 00% relative abundance 

96 5% to 9% of mass 95 

173 0% to less than 2% of mass 174 0.0 ROT 

-- 772F 87.9-- 

T73- 5% to 9% of mass 17 6.2 -- (To) 

176- >95%, but


AFCEE 





Instrument ID: MSK Compound: BFB Injection Date/Time: 9 Oct 00 1334 

AFCEEQAPP 

1 7 7 5 3 2 1 Version 3.0 


15% to 40% of mass 95 16.5 

30% to 60% of mass 95 39.6 

base peak, I 00% relative abundance 100.0 

PT 5% to 9% of mass 95 7.3 

0% to less than 2% of mass 1/4 _UU- 77 

174 greater than 50% of mass 95 98.1 

5% to 9% of mass 174 7.2 

>95%, but

AFCEE QAPP 

Version 3.0 

17 7 3 2 2 March 1998 

AFCEE 



Analvtical Method: SW8260B AAB #: D3785 


Matrix: Water 


K1009W01 LCS 92 95 98 

K1009WO] 104 96 102 

09\k1W11P011NF 104 94 104 

09'AIWIEPOIEFF 105 97 102 




Comments: 

AFCEE FORM APPENDIX A Page I of 1 003 

RDD M011 A7 BS1531PST SR D3781 D1181 "

AFCEE 


INTERNAL STANDARD AREA AND RT SUMMARY 



Instrument ID: MSK Date Analyzed: 9 Oct 00 Time Analyzed: 1202 

1 77 5 3 2 3 AFCLEE QAPP 

Version 3.0 

March 1998 

ISI IS2 IS3 


12 HOUR STANDARD 2871466 10.09 1938204 14 59 1226751 18 50 

UPPER LIMIT 5742932 10.59 3876408 is 09 2453502 1 9 00 

LOWER LIMIT 1435733 9.59 969102 14.09 613376 18 00 

SAMPLE ID 

K1009WO1 LCS 3056933 10 09 2055545 14.61 1216922 18.50 

K1009WO1 2711959 10 to 1773089 14 61 996318 19 51 

09WWIIPOIINF 2383823 10.10 1546023 14.60 873154 18 51 

09WWIEPOIEFF 2336379 10.10 1492527 14.61 876192 18 51 

Comments: 

IS[: Fluorobenzene IS4. 

IS2: Chlorobenzene-0 IS5 

IS3. 1,4-Dichiorobenzene-d,4 IS6: 



AFCEE FORM APPENDIX C Page I RDD-001011 A7 BS.] 511PST-SR DWO 0, )' .3 

3 78N

AFCEE QAPP 

Version 3.0 

1775324 March 1998 



Instrument ID: MSK 


Replicates Sid. MDL 

Analyte Analysis Amt. 1 2 3 4 5 6 7 8 

Date Spiked Dev. 

1,1,1-TCA 2F bOO 0.5 .40463 0A0738 0.34647 0.4Of57 0 41963 0 40764 0.32694 0.46995 0 044056 01 3 

1.1,2,2-Tetrachloroethane 3Feb 00 M 0.4287 03923 0 4394 0 4205 0 387 (T5-057 -F3-837 -- 5-47-33 0 043406 01 3 

1,1,2-TCA 3Feb 00 0 5 0.4324 0 4046 0.437 0.4209 0.384 0.4754 6 3 7-67 OA91 8 0 678 01 2 

1,1-DCA 2Feb 00 0 5 0 40802 0 41801 -T3 64-2 2 -0 42238 0 43003 0 43854 0.35778 0 50298 0 045395 01 4 

2Feb 00 0.51 0.40625 0.41601 0.35324 0 0.48759 0 044055 

II-DCE 40759 .41898 41049 0 3439 1 3 

1,2-DCA 3 Feb 00 O51 0A593 j 0 4406 0 4635 j 0.4469 0,4162 0.5397 0 4232 0 5198 0.044166 o7-3 

1,2-DCB 2 Feb 00 0 51 0,418351 0 40355 0.35625 0.40057 0.41546 0 40351 0.33258 0 4651 0 040170 01 2 

1,2-Dichloropropane 3Feb 00 0 5 0 4246 0,404 0 4177 0 4075 0 3835 0.4814 0.3702 0,484 U041-569 01 1 

1,3-DCB 2Feb 00 0.5 0 42362 0 42052 0.36177 T404-96 -T42 6-3 7 0 41317 0.33179 0 47629 O043718 01 3 

1,4-DCB 2Feb 00 0-44079 -0-4 3 2-93 -T-42071 -6 4 3-716 0 42872 0.34914 0 49397 0 044283 01 3 

Bromobenzene 2 Feb 00 -F3-8513 -T-38369 --0-3 67-66 0- 3 8 5 -T37-208 -T30-002 -7428-61 -ff-03-8489 01 1 

Bromodichloromethane 2Feb 00 -T3-961 10-41 5-9 3 -C74-092 -T43-127 7742-2-22 -7-34-43 -T4-8499 --042-963 01 1 

Brornoforni 

Bromornethane 

3Feb 00 

-T-Feb00 - 

--73 6-7 7-0-3-24-2 -(T-3692 0- 3 4 8 -7-3-1-7-6 0- 4 23 5 

0 5 -70-5 0 5203 0.4035 0.3693 0.4807 O5786 

659 

0 3 1 3 1 

0 4089 

0 406 10 0409 

0.5902 0. 87245 NWO 

Carbon tetrachloride 2Feb 00 0 5 0.380231 038243 0 334781 0.38446 0 39713 0.39292 0.30648 0 46023 0 045313 0 14 

Chlorobenzene 2Feb 00 0 5 0.41247 0 41499 0 354971 0A0077 0.41516 0 41 276 0 34022 0 46588 0.039056 01 

Chioroethane -TF-eb00 - 0 5 373 0 33521 0.2537 0.31306 0 33057 0 353 19 0 26448 0 44655 U 0-59409 01 8 

Chlorofonn 2 Feb 00 0 5 0,42723 0.37362 42577 072-377 -T4-3436 -7500-44 U-0-43771 013 

Chloromethane -TF-eb00 - 0 5 10 30927 0 38209 0.38095 0,38928 0.32183 -d-4-6118 T046-447 014 

Cis-1,2-DCE -TF-eb00 - 0 5 0.40316 0.396!fl-0.31786 0.45403 0 042200 OA3 

Cis-1,3-Dichloropropene 2 eb 00 0 5 0 31512 0.35353 0 36218 0.360931 0.28787 0 4037 0.034491 0 10 

Dibromchloromethane 

Dibromornethane 

3Feb 00 

3Feb 00 

0 5 

0 51 

0 3828 

0 3983 

0.3593 

0 3916 

0.4008 

0.421 

-0- 3 7-21 - 

O 3778 

0.348 

.3669 

0 4334 

0.4835 

0.3444 

3571 

0 

0,4409 0.036966 

0.4672 

046181 

0 11 

0.14 

Methylene chloride 3Feb 00 0.51 0.4436 T4 3-9 7 -U-46-46 -6-42-12 -- (T5-479 --4-29-5 -T5-224 0,046710 0A4 

TCE 2 Feb 00 0 5 0 426 0 41809 0.37995 OA172 0 44338 0.42658 T3 6-5 9 0-.5 3 6-5 5Ti 0 5 1-2 5 8- 0 1 5 

Tetrachloroethene 

Trans-1,2-DC 

Trans- 1,3-Dichloropropene 

Tri chlorc, fl uoromethane 

2Feb 00 

2 Feb 00 

2Feb 00 

-YF-eb00 

0.39769 0 39986 

--6-420 - -44 

77 0 125 

0.5 

0.36481 0.35800 

-0.37915 0 38799 

0 44 0 38479 (5-404-4 -(T3-(o(2 -j'3 -l( 2 8 77 -3o 5 70 039642 

0 3683 0 42235 0 44764 0 44792 37594 52457 0 048647 

0,36109 0.29816 

.3126 0.36063 0 3617 0 41225 0 034869 

0.33905 -(T3 9 4-7 4 -6-4-o-46( 0 40428 

0 32474 0A8353 0 048089 

01 2 

01 5 

oI 5 

01 4 

Vinyl chloride 2 Feb 00 I 0 5 0 34676 0.35315 0 29695 0 35651 0.35156 0 35847 0.2824 0 42503 0 043167 01 3 

MDL FORM Method SW8260 Page I of I 

RDD001011 XZ BS-1511 PST SR 03781 070,3 4 

I


1 7 75 3 2 5 

0035

C\l 

m 

77 

U 

0 

Q a:< 

LI) 

Q3 

m 0 

0 

mC

Columbia 

AnalyticaE 

Service 1 'i 



Redding, CA 96003 

COOLER RECEIPT FORTNII 

1,J 1) L 7,D 1-=AXJ 

Project/Client WorkOrderDOO -37S',T- 

1. Cooler(s) received on: Shipped via: x 

Shipping Bill 4 (s): 4JOZ ;340-5- 7,-5-7(. 

1 77532 7 

Cooler(s) screened by: vt! e e Rejected 

3. Custody seals on outside of cooler. S NO N'A 

If ves. where'? Front Rear Lt Side Rt Side 

Seals intact. f!5 NO 

i1). Sample ?rocessing"Tazoinu b%: 

4 Coolersl Temperatur., ------I 

Temp. B)ank!if present.) 

5. Type of packing material present: 

C00LFR/S-k),rPLE PROCFSSP;G 

7 . Custody papers property filled out (ink, signed. dated, released. etc.)? YES NO 

S. Containers arrived in good condition (unbroken, leakina, etc.)? -tt O 

9. Container labels complete (i.e. 2nalvsis, preservation, date/time, etc.)? *S::, 0 

10. Container labels and tags agree with custody papers' Cis 0 

II. Correct types of containers used for the tests indicateV NSS N, 0 

a.) Adequate sample received? If not, note on Exception Report. C68 -N O 

12. Preserved containers received with the appropriate preservative? NO N/A 

pH: .t -2- (o r) -Sea-piLlog, 

13. VOA vials checked for -absence of air bubbles'! N/A 

If present, note on the Exception Report. Unacceptable 


See Exception Report for discrepancies.

Section Tab 

q +0 aow+r r Pm vlooL 

1775328

ww-1 



Fourth Quarter and Annual 2000 Report 

1 

j 

cl;%' 

L 1,' I 

July 2001 

1 775 3 2- 9

ww-1 



Fourth Quarter and Annual 2000 Report 

Preparedfor: 


Environmental Quality (AFCEE/EQT) 



Prepared by: 

CH2M HILL 



July 2001 

1775330

(07N01N),W.h11=.M2, 

1 7 75 3 3 1 

Fo" Approved 

REPORT DOCUMENTATION PAGE OMB No. 0704-0188 

Vl .. "il Zh., W W"iltWdl. l 

1. AGENCY USE ONLY (Leave blank) 2. REPORT DATE 3. REPORT TYPE AND DATES COVERED 

I July 2001 Final 

4. TITLE AND SUBTITLE 5. FUNDING NUMBERS 

WW-1, 2000 Fourth Quarter and Annual Report, Long-Term Operation and F41624-97-D-8019 

Maintenance -Fairchild Air Force Base, Washington Delivery Order 129 

6. AUTHOR(S) 

Mark Henry 

7. PERFORMINGORGANiZATIONNAME(S)ANDADDRESS(ES) 8. PERFORMING 

ORGANIZATION REPORT 

CH2M HILL NUMBER 

9 South Washington Street, Suite 400 

Spokane, Washington 99201-3709 N/A 

9. SPONSORINGIMONITORINGAGENCYNAME(S)ANDADDRESS(ES) 10. 

SPONSORI 

Air Force Center for Environmental Excellence NG/MONITORING 

HQ AFCEE/ERD AGENCY REPORT 

3207 North Road (Bldg. 532) NUMBER 

Brooks Air Force Base, Texas 78235-5363 N/A 

11. SUPPLEMENTARY NOTES 

12a. DISTRIBUTION/AVAILABILITY STATEMENT 12b. DISTRIBUTION CODE 

AMC, Scott Air Force Base, Illinois 

HQ AFCEE/ERD, Brooks Air Force Base, Texas 

92 CES/CEV, Fairchild Air Force Base, Washington 

Washington Department of Ecology, Lacey, Washington 

13. ABSTRACT (Maximum 200 words) 

The purpose of this report is to present, summarize, and evaluate data collected during 2000 as part of the optimization and 

long-term operation and maintenance of the groundwater extraction and treatment system at the WW- I site. 

14. SUBJECTTERMS 15. NUMBER OF PAGES 

- Fairchild Air Force Base, WW-1 

- Long-Term Operation and Maintenance 

- 2000 Fourth Quarter and Annual Report 

16. PRICE CODE 

17. SECURITY 18. SECURITY CLASSIFICATION 19. SECURITY CLASSIFICATION 20. LIMITATION OF 

CLASSIFICATION OF THIS PAGE OF ABSTRACT ABSTRACT 

OF REPORT Unclassified Unclassified 

Lnclassified 

NSN 7540-01-280-5500 Standard Form 298 (rev. 2-89) 

Prescribed by ANSI Sid 239-18 

REPORT DOCUMENTATION PAGEDOC

Notice 

1775332 




along with the evolving knowledge of site conditions and Chemical effects on the 











NOTICE&PREFACE DOC III 

156470 02.92.94

1775333 

Preface 

This report presents findings obtained from the first quarter 2001 optimization, operation 




(AFCEE/ EQ) is the Contracting Officer Representative. 

Approval: 

I 

Mark Henry 

CH2M HILL 


IV NOTICEPREFACE DOG 

156470 OZ92 94

Contents 

1775334 

Section Page 

Report D ocum entation Page ... ................................................................................................. II 

N otice ... ....................................................................................................................................... III 

Preface .......................................................................................................................................... IV 

Table of Contents ........................................................................................................................ V 

1.0 Introduction ......................................................................................................................... 1-1 

1.1 Authorization .......................................................................................................... 1-1 

1.2 Purpose and Objectives ......................................................................................... 1-1 

1.3 Background ............................................................................................................. 1-1 

2.0 Fourth Quarter 2000 LTO .................................................................................................. 1-1 

2.1 Perform ance M onitoring ....................................................................................... 2-1 

2.1.1 Liquid Phase Analytical Results ........................................................... 2-1 

2.1.2 Air Phase Analytical Results ................................................................. 2-2 

2.1.3 Regulatory Com pliance ......................................................................... 2-2 

2.2 Volum e of W ater Treated ...................................................................................... 2-2 

2.2.1 Flow M easurem ent System ................................................................... 2-2 

2.2.2 Volum e of W ater Treated ...................................................................... 2-2 

2.3 TCE and cis-DCE Rem ovals .................................................................................. 2-3 

2.4 Treatm ent Plant Operations .................................................................................. 2-3 

2.4.1 Operational Param eters ......................................................................... 2-3 

2.4.2 Hours of Operation ................................................................................ 2-3 

2.4.3 Incidental W ater Treatm ent .................................................................. 2-4 

2.4.4 Site Activities and Repairs ..................................................................... 2-4 

2.4.5 System Shutdow ns/ Alarm Conditions ............................................... 2-5 

3.0 2000 Annual W W -1 GTP O perations .............................................................................. 3-1 

3.1 Perform ance M onitoring ........................................................................................ 3-1 

3.1.1 Liquid Phase Results .............................................................................. 3-1 

3.1.2 Air Phase Results .................................................................................... 3-1 

3.1.3 Com pliance w ith Discharge Requirem ents ........................................ 3-1 

3.2 Volum e of W ater Treated ...................................................................................... 3-2 

3.3 Contan-dnant Rem oval .......................................................................................... 3-2 

3.4 Operational Param eters ........................................................................................ 3-2 

4.0 Recom m endations .............................................................................................................. 4-1 

4.1 W W -1 Plant Optirnization .................................................................................... 4-1 

5.0 References ............................................................................................................................ 5-1 

Appendix 




2000 WWI ANNUALDOC V 

1%470,02.92.94

753 " 5 

dolntehts, Continued 

Figure 

3-1 WW-1 Historic Monthly Treatment Volumes ................................................................. 3-3 

Table Page 

2-1 WW-1 Liquid Phase Analytical Results, Fourth Quarter 2000 ..................................... 2-2 

2-2 Flow Measurement Information at WW-1, Fourth Quarter 2000 ................................. 2-3 

2-3 WW-1 Site Activities, Fourth Quarter 2000 ..................................................................... 24 

2-4 Site Events/ Repairs Summary, Fourth Quarter 2000 .................................................... 2-5 

2-5 WW-1 System Shutdowns/ Alarms, Fourth Quarter 2000 ............................................ 2-5 

3-1 2000 WW-1 Liquid-Phase Analytical Results .................................................................. 3-1 

3-2 2000 Flow Sununary Data .................................................................................................. 3-5 

A 2000 WWI ANNUALDOC 

1%470 02 92.94



1 7753346 


March 2000) of Contract Number F41624-97-D-8019, issued by the Department of the Air 



the Fairchild AFB runway. Fairchild AFB is located west of Spokane, Washington. 

1.2 PurposeandO active 

The purpose of this report is to present, summarize, and evaluate data collected during 2000 

as part of the optimization and long-term operation (LTO) of the groundwater extraction 

and treatment system at the WW-1 site. 


The WW-1 site consists of two interconnected industrial wastewater lagoons, a skimn-dng 


stormwater and industrial wastewater generated on the base. Trichloroethene (TCE) is the 











Associates. 





200OWW1 ANNUALDOC 1-1 

156470.02.92.94

2.0 Fourth Quarter 2000 LTO 

1 77533 7 

This section presents and discusses data collected during LTO of the groundwater pumpand-treat 

system at WIN-1 for the fourth quarter of 2000. 




WW-I Operations and Maintenance Manual [(O&M Manual), CH2M HILL, June 19981 Work 

Plan (CH2M HILL, September 2000c), Sampling and Analysis Plan [(SAP), CH2M HILL, 

September 2000a], and the Quality Assurance Project Plan [(QAPP), CH2M HILL, 

September 2000b]. 


• Appendix A-1 Inspection/ Maintenance Forms 



• Appendix A4 Incidental Water Treatment Forms 


• Appendix A-6 Event/ Repair Forms 








and QAPP. This monitoring includes quarterly water samples collected from the plant 

influent and plant effluent and air samples collected annually from the influent to the lead 


unit. 


Influent and effluent water samples were collected on December 18, 2000, and analyzed for 

volatile organic compounds (VGCs) using EPA Method 8260 as specified by the SAP and in 

accordance with the QAPP. Table 2-1 summarizes the results for TCE, cis-1,2-dichloroethene 

(cis-DCE), and vinyl chloride (VC). Complete analytical data packages are included in 

Appendix C. 

2000 WWI ANNUALDOC 2-1 

156470.02.92 94

1 7 7 5 3 8 

DRAFT WVV-1 2M FOURTH QUARTER AND ANNUAL REPORT 

LONGTERM OPERATION AND MAINTENANCE 

TABLE 2-1 

WW-1 Liquid Phase Analytical Results, Fourth Quarter 2000 

TICE cis-DICE Vc 

Sample Location (jLg/L) (pg/L) (jug/L) 

Plant Influent 3.33 8.62 0.24 U 


Qualifiers: 

U = The analyte was not detected. The associated numerical value is at or below the IVIDL. 





The WW-1 GTP operated within regulatory compliance limits for the fourth quarter of 2000. 

TCE was not detected in liquid discharge samples; the liquid discharge limit for TCE is 

5 log/ L. 




meter measures flow coming from that well only. Flow meter (P-5) measures the combined 



WP-1, WP-2, and WP-3. Because of this, flow from the Well Point System is estimated by 

assurrdng it to equal the difference in flow between total plant discharge and EW-1. 

2.2.2 Volume of Water Treated 


total volume of water treated during the fourth quarter of 2000 was approximately 0.79 


the quarter was 6.2 gallons per minute (gpm). The total amount of groundwater treated at 

the WW-1 GTP from March 1, 1997, through the end of this quarter is approximately'27.5 

million gallons. A more detailed description of the flows and readings are included in 

Appendix B as Tables B-1 and B-2. 

2-2 2000 WVV1 

ANNUAL DOC 

156470 02.92 94

TABLE 2-2 

Flow Measurement Information at WINA Fourth Quarter 2000a 

1 7 7'5 3 M 

DRAFT WW-I 2000 FOURTH QUARTER AND ANNUAL REPORT 

LONG-TERM OPERATION AND MAINTENANCE 

EW-1b Well Point SystemO Total Plant Discharge (P-5) 


Period of Volume Flow Rate Volume Flow Rate Volume Flow Rate 

Operation (gallons) (gpM)d (gallons) (gpM)d (gallons) (gpM)d 

October 220,415 5.1 102,187 2.4 322,602 7.5 

November 175,219 4.4 80,953 1.8 256,172 6.2 

December 138,922 4.5 76,746 0.6 215,668 5.0 

Fourth Quarter 534,556 4.6 259,886 1.6 1 794,442 6.2 

asee Appendix B (Flow Summary) for details. 

bEW-1 Total Volume is corrected by subtracting the amount of recirculation volume during routine cleaning. 

Vell Point System Flow Rate is not directly measured. It is assumed to be the difference between the Total Plant 

Discharge (P-5) and EW-1 Total Volumes. 




during the fourth quarter of 2000 were calculated by multiplying quarterly concentrations 

by the total flow volume treated for the quarter. It is assumed that the air stripper had 100 


measured below the lower MDLs in the plant discharge sample. The estimated quantities of 

TCE and cis-DCE removed were 0.02 pound and 0.06 pound, respectively. 

2.4 Treatment Plant Operations 



updated WW-I Operations and Maintenance Manual (CH2M HILL, June 1998) and 

manufacturers' specifications. Fourth quarter 2000 readings are included in Appendix A. 


The WW-1 GTP operated for approximately 2,127 hours during the fourth quarter of 2000. 

The GTP was shutdown for an estimated 81 hours during the quarter as a result of several 

power failures. EW-1 was subjected to longer period of shutdown this quarter due to low 

flow alarms. It is estimated that EW-1 was shutdown for a total of 289 hours. 


1%470 029294

V 75 31 0 

DRAFT WW-1 2000 FOURTH QUARTER AND ANNUAL REPORT 

LONG TERM OPERATION AND MAINTENANCE 


Approximately 345 gallons of incidental water were treated at the GTP this quarter. The 

water was generated by URS from the SD-37 RI/ FS project (approximately 200 gallons), by 

Montgomery Watson from their fourth quarter LTM sampling event (approximately 75 

gallons), and by CH2M HILL from the WW-1 source investigation (approximately 70 

gallons). The Water Treatment Approval Forms are included in Appendix A-4. 

2.4.4 Site Activities and Repairs 

Site Events 

Table 2-3 summarizes site activities for the fourth quarter. 

TABLE 2-3 

WN-1 Site Activities, Fourth Quarter 2000 


10/16 WWA source investigation activities (described below) 

11/14 Turned heat tape on for EW-1 and Well Point System 

1218 Treated approximately 180 gallons of LIRS purge water from the SD-37 RI/FS project 

12/12 Routine cleaning of the Well Point System wells 

12/18 Quarterly compliance sampling of the WW-1 GTP liquid influent and effluent 

12119 Treated approximately 75 gallons of purge water from Montgomery Watson's quarterly LTM 

sampling, and treated approximately 70 gallons of liquids from CH2M HILL's WWA source 

investigation work. 

12121 Treated approximately 20 gallons of LIRS purge water from the SD-37 RI/FS project 

Source Investigation Activities. LTM data reviewed for a recent 5-year review of the WW-1 

site and annual trend analysis indicated that the source of the TCE contamination in the 

groundwater at WW-1 likely is contaminated soil that seasonally becomes saturated. In June 

2000, EA/ Montgomery Watson performed depth-specific soil and groundwater sampling in 

the immediate vicinity of MW-102. Results presented in their summary report (EA, July 

2000) further indicated that the likely source of the TCE contamination was located west of 

MW-102. The source was believed to be a thin layer of soil (approximately 1 to 4 feet thick) 

occurring at a depth of 6 to 10 feet below ground surface (bgs). 

Based on these results, CH2M HILL initiated source removal activities on October 16, 2000. 

The proposed removal action included excavating and land-farming an estimated 100 cubic 

yards of TCE-contaminated soil. The clean, overburden soil was to be placed back in the 

excavation area and re-graded. However, during the soil removal, a cluster of 35 buried 

drums were discovered at depths of 10-14 feet bgs. The drums contained an estimated 750 

gallons of liquid wastes. Because of the additional area that the drum cluster occupied, 225 

cubic yards of TCE- and TPH-contaminated soils were removed and stockpiled for landfarming. 

Additional details of this removal action are presented in a summary technical 

memorandum (CH2M HILL, February 2001). 

2-4 200OWW1 ANNUALDOC 

156470.02.9294

1 7 75 3 4 

DRAFT WN-1 2000 FOURTH QUARTER AND ANNUAL REPORT 

UONC-TERM OPERATION AND MAINTENANCE 

Site Repairs 


Repairs after October 8, 2000, when D.O. 129 was initiated for LTO, will be tracked as 

2000/ 2001 Repairs. One repair was initiated under 2000/ 2001 Repairs during the fourth 

quarter and is summarized in Table 2-4. The Event/ Repair Form is provided in Appendix 

A-6. 

TABLE 24 

Site Events/Repairs Summary, Fourth Quarter 2000 

Repair Nature of Problem Nature of Repair 

2000/2001 Miscellaneous tasks and repairs that were Initiated to resolve EW-1 'low flow' alarms 

Repairs not specifically identified in the scope of caused by unseasonably low extraction rates. 

work. 




quarter. There were two plant alarm responses during the fourth quarter of 2000. There 

were several other alarm responses due to EW-1 "low flow" alarms. The estimated 

durations for the EW-1 alarm responses also are listed in Table 2-5. The Alarm Response 

Forms are provided in Appendix A-7. 

TABLE 2-5 

WW-1 System Shutdowns/Alarms, Fourth Quarter 2000 

Date Hours of Plant Alarm Reason 

Shutdown' 


10/23 1 5 No Power failure 

11/1 - 11/6 24 No Power failure 

11/8 -11/10 0b Yes EW-1 low flow alarm-24 hours offline 

11/27 - 11/30 23 No Power failure 

11128 ob Yes EW-1 low flow alarm- I hour offline 

11/30 3 Yes Power failure 

12/13 ob Yes EW-1 low flow alarm-2 hours offline 

12/19 - 12/20 ob Yes EW-1 low flow alarm-1 3 hours offline 

12/20 3 Yes Air stripper failed because of ice buildup 

on intake and required system re-start 

12121 3 No Power failure 


156470.02 92 94

. 1775342 

DRAFTWW-I 20DO FOURTH QUARTER AND ANNUAL REPORT 


TABLE 2-5 

WW-1 System ShutdownsAarms, Fourth Quarter 2000 

Date Hours of Plant Alarm Reason 

Shutdowna 

12/22 - 12/23 0 b Yes EW-1 low flow alaffn-34 hours offline 

12/24 - 12128 ob Yes EW-1 low flow alarm--83 hours offline 

12/28 - 12/31 0 b Yes EW-1 low flow alarm-67 hours offline 

Total Shutdown 81 

Hours 

'Hours of Plant Shutdown are estimated. These estimates are based on a review of average daily flow rates and 


b Unseasonably low flows from EW-1 shutdown the well and Caused a low flow alarm in the plant; however, the 

plant continued to operate with influent from the Well Point System. 

Seventy-five hours (or 96 percent of the estimated total shutdown time) of total plant 

shutdown this quarter resulted from short-term power failures that did not trigger an 

alarm. These outages were long enough to cause GTP motor shutdown, but not long 

enough to trip the auto-dialer alarm system. h-dand Power & Light, the electricity supplier 

in the area, has been notified of these electricity 'blurbs" on several occasions, and they 

have not made any effort to resolve the problem. 

EW-1 was offline for more than 293 hours this quarter as a result of "low flow" alarms. The 

cause of the alarms is unseasonably low flow extraction rates from the well. The alarm 

mechanism for EW-1 will be adjusted during first quarter 2001 so that lower flow rates can 

be continuously extracted without triggering an alarm. 

2-6 2000 1AW1 

ANNUALDOC 

156470.0Z92 94

3.0 2000 Annual WW-1 GTP Operations 


Performance monitoring at the WW-1 GTP consisted of water sampling quarterly and air 

sampling annually. This sampling was designed to ensure compliance with discharge 

requirements and to assess the overall performance of the GTP. All sampling was 

conducted as specified by the site O&M Manual and SAP, in accordance with the QAPP. 

1775343 

3.1.1 Liquid Phase Results 

Liquid influent and effluent samples were collected quarterly during 2000. The results for 

TCE and cis-DCE are summarized in Table 3-1. Additional analytes were detected; complete 

analytical data packages are located in Appendix C of each quarterly report. 

TABLE 3-1 

2000 WW-1 Liquid-Phase Analytical Results 

Plant Influent Plant Effluent 

TCE cis-I)CE TCE cis.DCE 

Quarter (p91L) WIL) (pg/L) (p91L) 

First 9.8 20.5 0.12 U 0.12 U 

Second 2.9 4.4 0.12 U 0.12 U 

Third 5.0 15.7 0.15 U 0.13 U 

Fourth 3.3 8.6 1 0.25 U 0.22 U 

Qualifier: 

U = The analyte was not detected. The associated numerical value is at or below the lower IVIDL. 

3.1.2 Air Phase Results 

The base submitted a request to the Spokane County Air Pollution Control Authority 

(SCAPCA) during the second quarter to reduce the frequency of air sampling from 

quarterly to annually at the WW-1 GTP. SCAPCA approved the request and made the 

appropriate modifications to NOC#679 (SCAPCA, June 2000). Consequently, the WW-1 

GTP air stream monitoring for 2000 was limited to one sampling event, which was 

conducted during the first quarter. The next air sampling event will occur during the first 

quarter of 2001. The results of the 2000 air sampling event are provided in the first quarter 

report (CH2M HILL, June 2000). 

3.1.3 Compliance with Discharge Requirements 

The WW-1 GTP was in compliance with liquid and air discharge requirements throughout 

2000 operations. 

20DO 

WWI ANNUALDOC 3-1 

156470.02.92.94

1775344 

DRAFT WI 2000 FOURTH QUARTER AND ANNUAL REPORT 

LONGTERM OPERATION AND WINTENANCE 


Table 3-2 provides estimated monthly volumes of water treated at the WW-1 GTP during 

2000. Table B-2 in Appendix B provides additional details of the fourth quarter 2000 GTP 

flows. In total, approximately 4.3 million gallons of water were treated during 2000. 

Figure 3-1 shows the monthly volume of water treated at the GTP since March 1997. From 

the first month after the Well Point System was completed (January 1998), the volume of 

water treated by the GTP has steadily declined. As previously mentioned, EW-1 (generally 

the largest water contributor) was offline for more than 223 hours due to shutdowns caused 

by low extraction rates ("low flow' alarms) during the fourth quarter. Henceforth, the 

overall GTP treatment volume was much lower than what has been seen in the past, 

excluding the December 1997 shutdown of the GTP for the Well Point System installation. 

3.3 Contaminant Removal 

The estimated quantities of TCE and cis-DCE removed during 2000 operations are 

0.19 pound and 0.46 pound, respectively. Since March 1, 1997, the GTP has removed 

approximately 0.95 pound of TCE and 1.6 pounds of cis-DICE. 

3.4 Operational Parameters 

The WW-1 GTP continued in 24-hour operation mode during 2000 except an estimated 

376 hours due to power outages and periodic maintenance and repairs. 

3-2 2000 WWI ANNUALDOG 

156470.02 9194

Insert Figure 3-1 

I 

1775345 

DRAFT WW-1 2000 FOURTH QUARTER AND ANNUAL REPORT 


2000'AWI ANNUAL DOC 3-3 

156470 02.92 94

1 7753A. G 

DRAFT M-I 2000 FOURTH QUARTER AND ANNUAL REPORT 


Blank page 

3-4 2000 Ml ANNUALDOC 

156470 02.92.94

TABLE 3-2 

2000 Flow Summary Dataa 

1775347 

DRAFr WW-I 20DO FOURTH QUARTER AND ANNUAL REPORT 


EW-11' Well Point System' Plant Discharge (13-5) 

Period of Total Total Total 

Operation Volume Flow Rate Volume Flow Rate Volume Flow Rate 

(gallons) (gpM)d (gallons) (gpM)d (gallons) (gpM)d 

January 285,962 6.4 123,182 2.8 409,144 9.2 

February 261,760 6.4 108,472 2.6 370,232 9.0 

March 326,917 7.4 146,449 3.3 473,366 10.7 

First Quarter 874,639 6.7 378,104 2.9 1,252,742 9.6 

April 278,505 7.5 102,116 2.7 380,621 10.2 

May 330,760 7.4 106,505 2.4 437,265 9.8 

June 263,535 6.6 135,571 3.4 399,106 10.0 

Second Quarter 872,800 7.2 344,192 2.8 1,216,992 10.0 

July 273,189 6.1 126,902 2.8 400,09i 9.0 

August 265,915 6.2 112,050 2.6 377,965 8.7 

September 194,520 5.1 92,992 2.4 287,512 7.6 

Third Quarter 733,623 5.8 331,944 2.6 1,065,567 8.4 

October 220,415 5.1 102,187 2.4 322,602 7.5 

November 175,219 4.4 80,953 1.8 256,172 6.2 

December 138,922 4.5 76,746 0.6 215,668 5.0 

Fourth Quarter 534,556 4.6 259,886 1.6 794,"2 6.2 

2000 3,015,618 6.1 1,314,126 2.5 4,329,743 8.6 

OSee Appendix B (Flow Summary) of the respective quarterly reports for details. 

bEW-1 Total Volume is corrected by subtracting the amount of re-circulation volume during routine cleaning. 

cWell Point System Flow Rate is not directly measured. It is assumed to be the difference between the Total 

Plant Discharge (P-5) and EW-1 Total Volumes. 


2000 WWI ANNUAL DOC 3.5 

156470.02.92.94



The following are recommended to further optin-dze WW-1 plant performance: 

1775348 

• Evaluate extraction rates to detern-dne if declining flows are resulting from regional or 





Both of these recommendations are temporarily on hold to evaluate their cost/benefit in 

view of source removal activities conducted upgradient of MW-102 in October 2000. During 

these activities, approximately 225 cubic yards of TCE- and TPH-contan-dnated soils were 

excavated. The contaminated soils currently are being land-farmed adjacent to the removal 

area. In addition to contaminated soils, 35 buried drums were discovered during the source 

removal activity. Twenty-six of the 35 drums contained an estimated 750 gallons (total) of 

liquid wastes, and have since been incinerated. 

2000 WW1 ANNUALDOC 4-1 

156470 02 92.94


Air Force Center for Envirom-nental Excellence (AFCEE). AFCEE Quality Analysis Project 


CH2M HILL. Summary Status Report #1 for Source Investigation Activities Conducted at the 

VVW-1 Site, February 2001. 

CH2M HILL. Draft Field Sampling Plans, Groundwater Monitoring and Pump-and-Treat Systems 

Operation, Craig Road Landfill and PM-] Sites, Fairchild Air Force Base, September 2000a. 

CH2M HILL. Draft Quality Assurance Project Plan for the Pump-and-Treat Systems Operation, 

Craig Road Landfill and VVW-1 Sites, Fairchild Air Force Base, September 2000b. 

CH2M HILL. Draft Work Plan Addendum for Pump-and-Treat Systems Operation, Craig Road 

Landfill VVW-I Sites, Fairchild Air Force Base, September 2000c. 

CH2M HILL. VVW-1 Optimization, Operations, and Maintenance, Third Quarter 2000 Report, 

December 2000. 

CH2M HILL. VVW-1 Optimization, Operations, and Maintenance, Second Quarter 2000 Report, 

August 2000. 

CH2M HILL. VVW-I Optimization, Operations, and Maintenance, First Quarter 2000 Report, 

June 2000. 

CH2M HILL. Update to Roy F. Weston, Inc. January 1997, Fairchild AFB Groundwater 

Extraction and Treatment System Waste7vater Lagoons VM-1 (AF Site VVP-03), Operations and 

Maintenance Manual, June 1998. 

EA. Plume Definition in Support of Monitoring Well Optimization, July 2000. 

Halliburton NUS (Halliburton NUS Environmental Corporation). Record of Decision for the 





URS Consultants, Inc. AM-I (AF Site KIP-03) Treatment System Addenda, April 1995. 



200D WWI ANNUAL DOC 

156470 02 9Z94 

1775349

Appendix Tab 

Livid i y .A . 

cpev-d'Oyls aKc( "Okla6laoc'e 6vm,-, 

1775350

AXPENDIX A-1 

Inspection/Maintenance Forms 

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w J" C> 

-0 c w lui 2 12 LL 

MO 0 m a co0 

4, U) E

05 

1775355 

LL 0 

< * 0- 

2, _0 

co 0 

LL 

E 

=5 

U) 

2 

0 

0 

CL 

co a :6 

0 

-5 

-N, Zz 

CO 

49 0 EL 

E CL = 

LD 'T LI) 

ID U3 4) 

o 8 

UJ 3: C, LM m 0 m 

CL c zLu 

LLI , 2 C 

19 .. I = C, 

M zM 4) 

c r=

co 

LL 

< 

Z3 

0 

Co 

C 

E 

0 

co 

EL 

U E T4 

CU E1 

LL u) v4 

(D 

Co 

(D 4z -rj CZ 4z, 

>1 

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0 

D 

qzzs 

cm 

E 0 0 

EL 

0 

M 

Or 

0 CD 

0 

C 

w 

S 

0 E Z 

0 t- w M 

0 ,Sm 

_j 

a .1 , m 

LLI 

z 



t2 

0 

M CL < 

a o 

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M -z; Z 

iLu E LD 0 26 ul W ga Oa 

IL E U 

0 O 

:i 

LL 

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w 

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0 0 

w 

a- :ME M FL M 5 m 0 

1775356

APPENDix A-2 0 

I/ Extraction Wells Data Summaries 

I 

I 

I 

I 

I 

1775357

WW-1 Routine Flow Measur ments 


1775358 


;2LV 0 EW-1 EW-3 P-6 



421,2tygg oilo a yz!j 5 Voo fr IAIq(, 7 

/Z/,060 Al, 3v Y f O 

IV1,14'a Lima -Y v .1 1.2 / 0 If WY W6/ 1; -1,1 7 4, 

OT-10-11AIJ5.A0 

Al. Iq 

1,4 k4,1 V, -Z 65n.;? 6 Z 

I; //? /40 a Pe O 4, 4106 3 1 1 E17 '74fzlzl;lf,5 

let af 

,O fO o e 4r- 4 14 YV If /,I 7,4' 

IA12;lob 

4 lb-0 

)10 I.-ow er j/., ;Z tilf 34- 

Z711, /-/f W 

L4& 7,ff '7 2- 71 & I 

)XIL71ge, ;Z zf,71, 

alNap 2;2-0 

-1/1,0 (J533 a -.0 11, A/"!; 3 7 ,Y,,? 

WW-1 FfowMas(.)ds OSADMOOO REVISED. FES 1999 

7 v

1 77 5 35 9 



Pre-Blower Post-Blower Primary G Vessel Lag GAC Vesst 

Blower Air 

Vacuum Differential Air Differential Inlet Pressure Outlet Pressure Outlet Pressure E) r 

Date Time Initials (inches w.c. (inches w.c.) has w.c.) (inches w.c.) (inches w.c.) I Temp. 

'9' 49 7Z 

t;140010,3 I 010,0 7 4Z, j 3- 0 01 115 74 

Low, , etv 11' 0 '/v '0 6 t'l_ 0 0- a 6 j 7 

1'71111j 114,1 & 'l 4t, H. 0 d, b (I Z) 7,1 

/.Z// (;6'2P 1) 7 

U/JZ L6 5- Z/ 

or's 0 JO 0 0- 0 [7 6* 

1.712,zle'a Step edv" /11,0 /Y Olaf 0 10, 0 0, 0 74 

a2ul."o ofz"p 4 V- /Y 0 0,0 4 0, 6 7,1 

vb!'7/00 0 qr,'q .4 1q, '9 0 I: 0,0 ;7.4 

Comments: 

a W61 

U e3 

".Amiga 

W W 4z a 

ov,*,o /"//f 70 

Af 0 _7 _f 

sky/ 

WW-1 Flo. master x1s 08/10/2000 REVISED, NOV 1998 

'_ej

1775360 

0 

> 

Ccc 

ir 

w 

A4 

4) V-1 %Ilk 4, 

cc it, 

E 0CL 

0 

Ucn 

d 

0v4 

LL 

> CL 

t: 0 

0 9L 

0 

I.Q 

-5ET 

0. 12 1 r fICZ 

a: Q_ -,SIN 

mn 

A 

E 

F- 

0 z

17 75 3 6 1 

WW-1 Routine Flow Measur ments 



2 EW-1 EW-3 P-5 


Date Time Initials (gpm) (gallons) (gallons) (gpm) (gallons) I 

/I//P//Od lq'Oe' -1 V i-1,7 377?Ur 2 79,q?3 

IM1041a" O!?yzq 4k'- - - 

WoZloo .7,oo -.4 -Y- 7 

Ilki?/po Ydo -4 6:2 75 ;2 4 

IllpflAkimo k Y 7 III 04.2 7 9WI f YZ Zy 2- 

1 if 1 bme -4 UC- AO 2 7 7 3 8 W I Y d-2 7-7- 

7 

k 

,;'dp Pilo 1.1 914 

111,5J6 goo 'A#/, I/ ;5l 4 

1;Z71041 7- 

/2. 741 v /= 2- 

7 F&z g&7- 

#4Y1 5 '2 

WW-1 Flow MasterAs 06/0212000 REVISED. FEB 1999




1 775 62 

2L10 o Air 

rential Air Differential Inlet Pressure Outlet Pressure Outlet Pressure Exit Air 

Date Time Initials a W.C.) (inches w.c.) (inches w.c.) (inches w c.) (inches w.c.) Temp. ff) 

0 Ida 10,11 0, 0 _1112 76' 

0 0 6,11 0 _,0 7/7 

0,17- 77 

/6 a 0 '44" /Y 0 I 91dc f.2- 0 -6,6 0, 40 I 77 

,0 ?Oa 'H, 0 ly 0"a 4 /17, ey 2), 0 6-,6 7 7 0 

I/& /0 a I ?Oa 0 Io, 0 )2--Ia 0,0 "l, 0 7,7 

/V 

IZA-VoD 1/) a of d.lq 6"01 /,7 b, 41 7 

2LO12 0 77 

Comments: 

///a e A 

Wdo 17 ai awl 

I/A 5Y/0 

/1 t 

L -/I r-)Lo ej 

adds 

4ftLf nz vwxe- WI 

I F M..t, A I V29/98 REVISED. NOV 199B

12 

1775363 

.2 

CO 

N\ 

CL in 

2 0 0 

E 

o 0 

LL 

(CL) 

N4 \4N 

TA 

co t: 

< 0 

E (L 

OM 

Xz 

'CA 

czs

WW-1 Routine Flow Measurern nts 


1775364 


EW-1 EW-3 P-5 

Flow Totalizer Flow Flow otalizer Flow Flow Totalizer allow 

Date Time Initials (gpm) (gall n gpM (gallons) (gpm) (gallons) I 

/0/ff//,qO 1,900 A f ( / j 7,.23 .7 kife 9 , / 

101016e, 4900 o-l 5- q L 7 1 2- 2- 7 'OVI& 3.2 

iv Zq /ov I e) ioe, et--] -3 -17 f 1.2 q 917 

fi 

d A 2e, 74 1.2- LI 

k1, , ;? -YO;2,2,1 - 2 4 

44 V, V 31Y 7kl 'I Ao-4-t 2 4' 

1,91;)lz Zv 3 a A 4e -V, 6 3 -/,; V 3 5 I 72 7 

/s/56/00 030 7 34M o .2f 7-7 70r 

WW-1 Flow MasterAs 06102r2OOO REVISED. FEB 1999

1775365 




0 Blower 



Date Time Initials w C.) (incheswc) (inchesw.c.) (inches w.c) (inches w c.) (inches w c.) Temp. ff) 

j4ealoo jozo 44W ) Y_' P ).Z I 10 15,0 'P' * 

/0,6 1/0 0 Om ) A ki, L) 2 "i L12 16 

Lhg6v jlk o 0 

Ill lb I 61 q 6'q I'l b 

11202,&vv e) ve, & '4 t- )I'a e)'06 1 2 0 'I 

1C)II7100 O'P 0 / 111, t) 6 /' ) I D - 

I 0 /.Xv),o Io 4 o 11 'Yv I 1-1, v 

16 lzrlp 0 I Al"5 0 0 0, 9; 'e' Z) 

ft, bov 0 LI 7 6,_ a e') 7 

7Y 

Comments: 

ja 11 7 &v 4U X.Az 

Lq 

vvVv.1 Fiow master.xis 12129t98 REVISED, NOV 1998

CL 

CD 

En 

0 

r 

0 0 

C, 4 

r4, 

> 'cl 

0 

0 0. lk 

,5 E 

cr 

c 

T'A 

CL 

E 

4z 

Tle 

%Z 

IN 1775366 0z 

ers 

qz 

rA VA 

w 

(n 

> 

w 

we

APPENM A-3 

Operational Data Summaries 

1 1775367

E 

E 

> E 

U--) Till 

EL Xv 0, 

-U) us fi 70 

co 

CL 

m ca 

CL 

0 CL 

< 

(50 

a. 

%C) 

Iz m 

.2 

7i 

la 12 .2 

al ou 

0 

CL % 

Om M, CE 

12 0 0 .2! 

CW 

Ae 2 

1775368 

21 E Eo .2 

m t -- ML Om 02 

0 E 

.9 m 2' 0 Ea i7L 

MO -M 

0 

0 m cc Z 0 Omm 

> 0 4 z 

20 

0 cc 

0

1775369 I!E 

Lo 

0 

> 

E tt\ 

IR, 0 E 

0 E2 

0 0 C < 

0 0 

lzz NN 

v x C>; 

CL 0 C w 

m au > 

0 

0. too, 

0 

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76 

C 

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0 

0 '74- -zt- 

0 

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tL (L 

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Eo 2 

0 0 - 0 mCE 

cs Z Z) E C 

Z 

CL EL fi 

75 

0 

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0 

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E I'm E 

05 4, ilk. 0 a 

W E 

o m Ma. .- 0 '01 

13 

Z 

0 

IX 

r2 Z, 0 

B 

E 

3. 

E 0 

Lm m m 

2

t2 

> 

0 

Ln w 4 

a. IL 

E m 

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0 

12 M 

e 14 v4 

EL e tp a e 

CL 

4) CL 

IL 14% 

0 

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CL 

v la 

15 co 0 c 

co T :z c 

a 76 0 m 

o CL 

Iz 

tr 

E Z 

CL 

0 CL tA

1 7 7 5,3 7 1 

0 C 

U) 

c Ztt\P_ 

0 'i Id 

%_ zt-, I I 

LL 

ri 

tz 

ZI, 

0! C! v_i 0 

i zA 

0, Tv 

Vk 

04, t41 k! 

TA. 

elk 

ZI all 

rA, 

740 

VA 

4I 'Ai 

k, 

til 

4, 

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nar_ 

elk OK 

zr-; t, ;k: 

rA 

7z,

APPENDLX A-4 I 

Incidental Water Treatment Forms 

I 

I 

I 

I 

1775372

FAIRCHILD AFB WW-1 


WATER TREATMENT APPROVAL FORM 1775373 

SOURCE (e.g., well purging, etc.)Z'e-kh cv-m's 0-- vow-1 i e% f) P, vy--v 

LOCATIONOFSOURCE(e.g.,moiiitoringN%,ellnumber,etc.) WW-1 stivra, 

".1 "'s tL Z9 31 

DATE OF GENERATION johtl 0 cz 

DATEOFSAMPLTNG coo 

DATE OF ANALYSIS Wallach copy) 

DATE OF APPROVAL TO DISCHARGE Z 1510 

APPROVAL BY z 

(Fairchild Air.Force Base) 

IN-MVIDUAL TkNgPORTIYG WA-T-E- 

14 7/ 

NAMP, SIGNATURE FAFB 017ITLE 


DATE Ia II f Z., 0 TIME 6 fj,l 


QUANTITY OF TRANSFER 19e 


way e-14 m )./I,// 


COMMENTS: 

Lt

1775374 Anatek Labs, Inc. 

1282 Alturas Drive - Moscow, ID 83843 - (208) 683-2839 - Fax (208) 862-9246 - email moscow(aanatektabs corn 

504 E Sprague Ste. 0 - Spokane WA 99202 - (509) 838-3999 - Fax (509) 838-4433 - email spokaneanateklabs corn 

CH2M HILL-SPOKANE Sample Name: 112 DR 8 

MARK HENRY Sampling Date: 11/2/2000 

Sampling Time 11:00 

9 S WASHINGTON STE 400 Date Received 1113/2000 

SPOKANE WA 99201 

Certificate of Analysis 

EPA Method 82601624 GCIMS Volatile Organics 

lAnalyte Result I Units POL 

dichlorodifluoromethane, 0 001 

ND mQ/L 0,001 i 

ivinvi chloride 

chlorcethane: 

0,295 

ND 

IL 0 001 

-0661 

I 

trichlorofluoromethane ND Mall- 0 001 

Acetone: 0 030 Moll. 0.005 

methylene chloride: 0.003 mg/L 0001 

trans-1,2-dichloroethene: 0.006 rij 0 001 

II-Dichloroethene: 0 004 mg/L 0 001 

1,1-dichlofoethane: NO MCVL 0.001 

2,2-dichloropropane 0 (01 

cis-1,2-dichloroethene 0.001 I 

bromochloromethane, ND 1 mg/L 0.001 

chloroform ND Mg/L 1 0.001 

1,1,1-trichloroethane: QlL 0.001 

Methyl ethyl ketone: ND N/L 0.005 

carbon tetrachloride: 0 0-0 1--I 

1.1-dichloropropene: ND ma/L 0.001 

benzene: 0.002 0 001 

1,2-dichloroethane. ND 0 001 

trichloroethene: 0.108 Mg/L 0,001 

).2- jchloro ropqw_ ND, _mglL OM 

dilbromorrethane ND_____ mg[L -uoi 

,bir.o.mod"Ch'Oromelhane 

I 34chloopopene: 

ND 

ND 

mg/L 

Mg/L 

0 001 

0.001 

Methylisobut,d ketone 

LtojUen_e____ ___-- - 

0.029 

0016 

ri 

L 

05 

0 0(i 

ene ND mg/L 0.001 

tetrachlorcietheri 

ND 

ND 

mg/L 

m IL 

0 001 

0 001 

_3-dichloropropaw . mg/L 0.001 

dibromochloromethane: 

2-Hexanone: 

ND 

ND 

Mg 

0.005 

12-dibrorroethane: 

chlorobenzene: 

N D mg 

0.001 

1. 1,1,2.tetrachlormthane ND Mg/L 0.00-1 

m+p-xy1ene 

10 

styrene 

ibromoform: 

1,1,2,21etrachloroethana 

0 004 

ND 

0,343 

NO 

NO 

Mg/l. 

Mg/L Mgt 

mg[L 

mg/L 

1 ___mgIL 

0 001 

0 

001 

d061 

001 

0 00 

0 00 I 

Lab 

Ma 

trix 

Analyst 

Analysis Date 

29740-06 

WASTE WATER 

HY 

1111112000 

1 2 3-trichloroploparte ND Tl 0.00 

1 -dichlorobenzzene___- 3 

1,4-dichlorobenzene. 

-ND- 

ND 

mg/L-mg/L 

Surrogate Standard 

1,2-Dichloroethane-d4 %R 

% Recovery J 

100 1 j 

.2-dichlorobenzen(L I 

hexachloTobutadiene 

naphthlew 

ND - 

N D 

-M 

Chlofolierizene-6 %R 

Tciuene-d[B %R 

99 2 

100 1 

MTBE. ND M 1 0 001 

NE) Not Detected POL Practical Quantilalion Limit Project WW-ISOILTREATMENT FPA 8260 Reoofl Pace 2 of 4

Anatek Labs, Inc. 177537r) 

1282 Alturas Drive - Moscow, iD 83843 - (208) 883-2839 - Fax (208) 882-9246 - email moscowanateklabs.com 

504 E Sprague Ste, 0 - Spokane WA 99202 - (509) 838-3999 Fax (509) 838-4433 - email spokaneanateklabs com 

CH2M HILL-SPOKANE Sample Name: 112 DR 29 

MARK HENRY Sampling Date 11/2/2000 

Sampling Time: 12:00 

9 S WASHINGTON STE 400 Date Received: 11/3/2000 

SPOKANE WA 99201 

Certificate of Analysis 

EPA Method 82601624 SCIMS Volatile Organics 

AnaW 

dichlorodifluoromethane: 

Result 

NO 

Units 

mg/Ak 

OL 

0.140 1 

chloromethane: ND M 0.140 

vinyjqhlofide ND 0.140 

dkroethane: ND 0 40 

tdchlorofluoromethane: t'Lo 

Acetone: 

nlety I 

ND 

ND 

malka 

mwkq_ 

0.700 

0 140 

trans. 1,2-dichloreethene: ND 0.140 

1,1.Dichloroethene N D MCA 0.140 

1.1-dichloroethane: ND molk 0.140 

2,2-dichloropropane: 11199- 0.140 

C.isl djchloroetlhene' ND - 

bromochloromethane: ND 0.140 

chloroform: NO ma/ka 4- 0.140 

11,1-tirtiloreethane: ND malk 0 

Methyl ethyl ketone: ND MCAO 

carbon tetrachloride: ND me/ko 0.140 

1,1-dichlor PL0pqnE- ___._ ND mo/ko I 0 140 

benzene: ND ma/ko 1141 

1,2.dichloroethane: ND _L mg/kg 

trichloroethene: NO 0.140 

1,?-Jichlcropropwe. 

idibromomethane, 

ND 

ND 

MgLkg 0140 

--!PgLkg ----- -- 0,140 

bromodichloromethane ND rn N 0 140 

ND _MAq .140 

molkg_ 0.700 

toluene. D imgLkg 0.140 

4ELS-.13-d!clnpjopwe._ -ND- - -1 -mgg -1- -0.140 

1.1 2-trichloroethane, ND --MLkg - 0.140 

tetrachloroethene: -ND--__ mg/kg_ 0.140 1 

L34 -- - ND mq/kg__ 0.140 1 

dibromochloromethane: ND mcAQ 0.140 

2-Hexanone: NO MCAQ 0.700 

1,2-dibromoethane: -ND irftg 0.140 

chlorobenzene: -D /kg 0.140 

1,1,j,?-_tetratIorWhanq ND 140 

qLhylbenzew ND- pgfkg 0.140 

m+ .... P_'xy lene: ND mg/kg 0,140 Lab 29740-07 

L(Lxytrle- 

:styrene, ND 

_Tglkg 

mglkg 

0.140 

0.140 

Matrix. OL 

W 

ibromolorm ND mglkg 0 14-0 Analyst 

1. 1,2,Mteracliloroethane: N D m 0.140 Analysis Date. 11/13/2000 

t2 3 trichloropLopane ND g. 

.ILdichlorolbenzerie. 0.140 1 urrogate % Recovery 

1 .4dichlorobimpene 

.IZ-_dichlorobenLene: -ND 

--- ng/kg 

_m g/kg 

11.2-Dichlo 

or tie % 

98.9 

100.2 

hexachlortilbutadiene: ND mgg 0 140 Tol 

jaiplthalene- i N-D mg/kg 0.140 

IVITBE ND mg/kg 0.140 

ND Not Detected POL Practical Quantilation Limit Proiect WW-1 SOIL TREATMENT EPA 8260 Reriort Pace 3 of 4


1775376 


SOURCE (e.g., well purging, etc.) soetl 


LOCATION OF SOURCE (e.q., monitoring well number, etc.) 

DATEOFGENERATION 17-6-00717-77-OC4 

DATEOFSAMPLING t-30 .00 

DATE3DF ANALYSIS (attach copy) 1112-pi 

DATE OF APPROVAL TO DISCHARGE 2 4c 

APPROVAL BY 


NDIVIDUAL TRANSPORTING WATER 

NAME SIGNATURE -EA TITLE 

TRANSFER INFORMATION ^-- d 

DATE 7 - -(- rX) 1,5- TIME 




If'Lef, VI 

NAME SIG ORGAN. TITLE 

COMMENTS:

FAIRCHILD AFB =nub 

5f7Ze 

SOURCE (e.g., well purging, etc.) LA)4C,(( 


FT' 1 Z 09 11 

LOCATION OF SOURCE (e..g., monitoring well number, etc.) I 

DATEOFGENERATION 


DATE OF ANALYSIS (attach copy) HISV'-tc-a.( uJ 


APPROVAL BY 


INDIVIDUAL TRANSP G IL I.- 

M, k IT< 

NAME SIGNATURE TITLE 

AA.P 


DATE 1,Z1Zf106 TIME 0 90 19 



INDIVIDUAL RECEIVINGHATER 

r-- Alirtl 1:- b it 

NAME SIGNATURE TITLE 

COMMENTS: 

1775377

-l/ 

APPENDIX A-5 

Sampling Documentation Forms 

1I 

I 

I . 

I 

I -I- 

I 

1775378

FAIRCHILD AFB 1775379 



SAMPLING DATE: F Z-Duo 

SAMPLE TEAM MEMBERS: -- 

fd,(L pp. 

SAMPLEMATRIX(circleone)-. A,,(4Grounclwater Other. 


o!))2-4lvol itA D 63: c 6)1- - PL- 

-lnv-u-w\ f 90 irf TTO ' g Lo it 

LABORATORY: wmalk 11;#ZUICIE5 

COMMENT 

Vince plw,\- 

Com Jz-/ F-OD 

(date)

AppiNDLx A-6 

Event/Repair Forms 

I 

.i 

1775380 

I



Miscellaneous Small Repairs and Work Items 

Project No.: 156470.02.94.90 Repair ID: 2000/2001 Repair 

Initial Date: October 8, 2000 Completion Date: Ongoin 

Employee Responsible: Bob Worl Title: Treatment Plant ORerator 

Estimated Repair Cost: $5,000 Final Repair Cost: Ongoin 

Est. CH2M HILL Level of Effort (LOE): 20 hrs Final CH2M HILL LOE: Ongoing 

Equipment Purchased: -Yes -No AS-Built Updated -Yes - No 

1 7 75 3 81 

Nature of the Problem: Miscellaneous small repairs and work items for unforeseen repairs, 

and repairs completed at the direction/request of Fairchild AFB staff. This repair was 

opened on October 8, 2000 under DO 129. 

Nature of Repairs: 

1. Repair initiated in December to resolve EW-1 "low flow" alarms caused by 

seasonally low extraction rates. The modification/ repair to the EW-1 alarm 

system will be completed during first quarter 2001. 

LIACILIENT PROJECT DELIVERY\156470 -FAIRCHILD )C129\REPAIRS\WW1WW1 2000_20001 REPAIRS.DOC

-I/ 

APPENDix A-7 

. Alarm Response Forms 

I 

1775382 

I

CH2M Hill - Alarm Response Form 

WW-1 Site, Fairchild AFB 

Date: _dSfFF SY,04 Time: Project No.: 156470 

Repair Number: # (if applicable) Repair Needed: -Yes No 

Employee Responding: (initial responder) LOE: hrs 

Employee Responding: LCIE: hrs 


Alarm: I EW-1 UQ FLOW i0agAt 

IW, 


Actions Taken: &XAbUx6Pw "PM MR R 

1775383

1775384 


WWA Site, Fairchild AFB 

Date: Time: Project No.: 156470 

Repair Number: #. . (if applicable) Repair Needed: -Yes No 

Employee Responding: AO A/ (initial responder) LCIE: hrs 



Alarm: A I lr -,-iiz I PM)Z, 

Cause of Problem: ICf, &JIW-U9 QAf FUWM IMIAYF, 

Actions Taken: . iFF ic-F_ AiJO /,5-si*zmC>


WW-I Site, Fairchild AFB 

Date: Time: 000: 00 Project No.: 156470 

Repair Number: (if applicable) Repair Needed: -YesANo 

Employee Responding: (initial responder) LOE: hrs 



Alarm: Aujoe wftF- Atp- sff4AP6JP_ 

Cause of Problem: t9mrk 

ActionsTaken: ;k"OWI-AD690 AURM Aw- 

OW4 

1775385

Appendix Tab 

ApZvidk,'r r-3 

Row 5Arorytav 

1775386

WW-1 Site Flow Summary (Table B-1) 

1775387 


flow meter measures the flow con-dng from that well. The total flow discharged by the GTP, 

wl-dch is a combination of flow from EW-1 and the Well Point System, is measured by the 

P-5 flow meter. The discharge from the plant (approximately 27 gpm) is intermittent and 


Well Point System, which includes EW-3, WP-J, WP-2, and WP-3. As a result, flow 


5 and EW-1 flow meter values. Average flow rates are also calculated for each system by 

dividing the daily flow volumes by the operating time in minutes for each month. 

EW-1 Routine Maintenance 

During routine maintenance of EW-1, the discharge line is connected in a circuit to flush 

chlorinated water through the system for about a 24-hour period. The flow meter for EW-1 

registers the circulating flow, which creates a false influent flow reading at the GTP. The 

only flow into the GTP during this time is from the Well Point System. Consequently, the 

average calculated flow rate for P-5 is equal to the average calculated flow rate for the Well 

Point System during this time period. 

There were no routine EW-1 maintenance activities during the fourth quarter due to heavy 

snow loads and related access issues to the wellhead. Routine maintenance will resume next 

quarter when the snow depth subsides. 

2000 WW-1 Site Flow Summary (Table B-2) 


Point System, and P-5 through the third quarter of 2000. The flow rates are calculated by 




above. 

The Well Point System's average flow rate for December is significantly influenced (biased) 

by the frequent EW-1 low flow alarms and subsequent EW-1 shutdowns. It is estimated that 

EW-1 was offline for a total of 200+ hours during December as a result of low flow alarms 

and manual shutdowns for well recharging. This issue of EW-1 shutting down during 

unseasonably low flows (less than 4 gpm) will be resolved during first quarter 2001. 

SPKAPPENDIX B DOC

1775388 

Table B-I 

WW-I Site Flow Summary, Fourth Quarter 2000 

EW-1 Well Point System Total Plant Discharge (P-5) 

(measured calculated) (calculated) (calculated) (measured) (calculated) (measured) 

Date Time 

Average 

Flow Ral 'measu:nn Flow Volume 

ate Flow Vo e Flow Rate 

Average 

' 

Flow Rate 

Flow Rate 

Ave age 

'R 

Flo ate 

Flow 

Volume 

(gpm) (gallons) (gPm) (gallons) (gpm) (gpm) (gpm) (gallons) 

01-Oct-00 10:00 5.8 15,157,523 4.9 4,822,061 2.7 26 76 21,456,831 

03-Oct-00 9:00 5.4 15.173,422 5.6 4,828,963 2.4 26 8.1 21,479,632 

06-00-00 9:00 53 15,196,351 5.3 4,838,895 2.3 26 7.6 21,512,493 

IO-Oct-00 9:00 5 1 15,226,234 5.2 4,851,937 2.3 26 7.5 21,555,418 

13-Oct-00 9.00 5.1 15,248,124 5.1 4,862.012 2.3 26 7.4 21,587,383 

17-Oct-00 9:00 5.0 15,276,766 5.0 4,875,228 2.3 26 7.3 21,629,241 

20-Oct-00 10:00 4.8 15,298,220 4.9 4,884,928 2.2 26 7.1 21,660.395 

23-Oct-00 6:30 4.8 15,313,744 4.8 4,892.868 25 25 7.3 21,683,859 

27-Oct-00 10:30 4.8 15,342,435 4.8 4,907,639 2.5 26 7.2 21,727,321 

30-Oct-00 9:30 4.7 15,363,060 4.8 4,917,371 2.3 26 7.1 21,757,678 

01 -Nov-00 14:00 47 15,377,938 4.7 4,924,248 2.2 26 6.9 21.779,433 

06-Nov-00 9,30 4.7 15,403,616 4 7 4,936,198 2.2 26 6.9 21,817,061 

07-Nov-00 9.00 4.7 15,410,295 4.7 4,939,471 2 3 26 7 1 21,827,013 

08-Nov-00 14:00 4.7 15,418,275 4.6 4,943,475 2.3 26 6.9 21,838.997 

14-Nov-00 9:00 4.7 15,449,938 4.6 4,962.222 2.2 25 6.0 21,889,407 

16-Nov-00 9:00 4.6 15,463,141 4.6 4,967,867 2.0 26 6.5 21,908.255 

21-Nov-00 9 30 4.5 15,496,153 4.6 4,981,636 1.9 26 6.5 21,955,036 

25-Nov-00 9:00 4.4 15,521.661 4.5 4,991,734 1.8 26 6.2 21,990,642 

27-Nov-00 10:00 4.4 15,528,662 4.5 4,994,552 1.8 26 6.3 22,000.461 

29-Nov-00 10:30 4.5 15,541,614 4.5 5,000,504 2.0 26 6.5 22,019,365 

30-Nov-00 9:30 4.5 15,546,873 4 4 5,002,732 1.9 26 6.2 22,026,852 

04-Dec-00 9.30 4.4 15,572,008 4.4 5,012,607 1.7 26 6.1 22,061,862 

08-Dec-00 8:00 4.3 15,596,451 4.3 5,021,762 1.6 26 5.9 22,095,460 

12-Dec-00 8 00 4 2 15,620,B44 4.2 5,030,303 1.5 25 5.7 22.128,394 

13-Dec-00 15:30 4.4 15,628,441 4.2 5.032,572 1.2 26 5 2 22,138,260 

18-Dec-00 8:00 4.2 15,657,126 4 2 5.041,818 1 4 26 5.6 22,176,191 

19-Dec-00 8:20 4.2 15,660,039 4.2 5.044,504 1 8 25 3 8 22,181,790 

22-Dec-00 8 30 4.2 15,669,556 4.2 5,052,448 1.8 25 4 0 22,199,251 

26-Dec-00 9 00 4.5 15,674,557 4.2 5,065,297 2 2 26 3 1 22,217,101 

27-Dec-00 11:30 4.3 15,680,239 4.2 5,067,818 1 6 26 5 2 22,225,304 

28-Dec-00 12:00 4.4 15,685,314 4.2 5,069,641 1 4 26 5.1 22,232.202 

01-Jan-01 10:00 4.6 15,692,079 42 5,081.947 22 26 3.4 22,251,273 

SPK/Appendix Table B-1 xIs 156470.02 92.94

I i 1 

Appendix Tab 

vKvlalv, a 

L-FO /Ma(V-hco-/( 06& 

1775389

APPENDIX C-1 

Water Sample Results 

I 

I 

I 

1775390

Ar'6'Colurnbia 

Analytical 

INC. 

Mr. Mark Henry ServiceS 

CH2M HILL/SPK An Eniploy-Owned Company 


Suite 400 

Spokane, WA 99204-0219 

Submitted by- 


Fairchild AFE WWl Plant Monitoring 

D0004343/D4343 

4L' 

Bryan Jones 


Enclosures 


January 8, 2001 

This report contains a total of 37 pages. 

1 7 7 5 3 9 

5090 Caterpillar Road - Redding. CA 96003 - Telephone (530) 244-5227 Fax (530) 244-4109

1775392 


Level III 

TABLE OF CONTENTS 

Cover Page ....................................................................................................................... I 


AFCEE Data Qualifiers .................................................................................................... 3 


GC/M S V OLA TILE ORGAN ICS .................................................................................... 5 


A FCEE Form 0 -1 ................................................................................................... 7 

AFCEE Form 0 -2 ................................................................................................... 8 

AFCEE Form 0-3 ................................................................................................. 12 

A FCEE Form 0-4 ................................................................................................. 1 8 

A FCEE Form 0-5 ................................................................................................. 20 

A FCEE Form 0-6 ................................................................................................. 23 

A FCEE Form 0-7 ................................................................................................. 25 

AFCEE Form 0-9 ................................................................................................. 27 

A FCEE Form 0- IO ............................................................................................... 28 

AFCEE Form 0-1 I ............................................................................................... 29 

A FCEE Appendix A .............................................................................................. 3 1 

A FCEE Appendix C .............................................................................................. 32 


Chain of Custody Docum entation ................................................................................... 34 

Page 

No. 

0 0 02

1775393 

AFCEE Data Qualifiers - 






MDL. 


associated numerical value is at or below the RL. 



criteria. 





T Tentatively identified compound (using GC/MS).

1775394 

SampLe ID Cross-reference TabLe 


Lab Sample ID Sample ID Date Date Sample Matrix Additional Description 

FS = Field Sample; LCS = Lab Control SampLe; NON = Non-Sampte Type (Internal Admin) 

D4343000 NON EDATA 12/19/00 12/19/00 00:00 Ackninistration EDATA 

D4343001 FS 12WW11PO11NF 12/19/00 12/18/00 08:30 Water 0012WW11POIINF 

D4343002 FS 12WW1EP01EFF 12/19/00 12/18/00 08:20 Water 0012WWIEPOlEFF 

The above Lab sampLe ID's and cross reference information apply to samples as received by the Laboratory. Modifiers 

to the tab sample ID may be added for internal tracking purposes. Any modified sample 10 will be reflected in the 


00 0 4

GCIMS VOLATILE ORGANICS 

1775395 

0005


1775396 GC/MS VOLATILE ORGANICS 


Project: Fairchild AFB WWl PM 

I. RECEIPT 



II. HOLDING TIMES 

III. I-IETHOD 




Cleanup: N/A 




V. ANALYSIS 



C. Internal Standards; All acceptance criteria were met. 



F. Samples: Sample analysis proceeded normally. 





designated Ir rson, as verified by the following signature. 

SIGNED: &Gb A C"L. UOO A DATE: 

Tracy ChiWders 

Chemist, GUMS 

Col.mbia 5090 Caterpillar Road Phme-(53 6 

Analytical Scices Reddmg, CA 96003-1412 F.. (530) 2444)09

AFCEE 






Comments: 



12WWIIPOIINF D4343001 

12WWIEPOIEFF D4343002 

AFCEEQAPP 

1775397 Version 3. 0 

Afarch 1998 

AFCEE FORM 0-1 000 9 

RDD-010103 IC SS 1136PS7 SM W343 DIW-F


1775398 ORGANIC ANALYSES DATA SHEET 2 Version 3.0 


Analytical Method: SW8260B AAB 9: D434j - 


Field Sample ID: 12WWIIPOIINF Lab Sample ID: D4343001 - Matrix: Water 

% Solids: SampleDescription: 0012WWIIPOIINF 

Date Received: 19 Dec 00 Date Prepared: Date Analyzed: 27 Dec 00 


Analyte MDL RL Concentration Dilution Confirm Quaiiner 

1, 1, I -TCA 0-22 0.8 0.22 1 U 


1, 1,2-TCA 0.26 1.0 0.26 1 U 

II-DCA 0.07 0.4 0.07 1 U 

1, I -DCE 0.25 1.2 0.25 I U 

1,2-DCA 0.27 0.6 0-27 1 U 

I,2-DCB 0.08 0.31 0.12 1 F 


1,3-DCB 0.25 1.2 0.25 1 U 

1,4-DCB 0.08 0.3 0.08 1 U 

Bromobenzene 0.11 0.3 0.11 I U 


Bromoform 0.14 1.2 0.14 1 U 


Carbon tetrachloride 0.22 2.1 0.22 1 



Chloroform 0.09 0.3 0.48 1 


Cis-1,2-DCE 0.22 1.2 8.62 1 

Cis-1,3-Dichloropropene 0.16 1.0 0.16 1 1 U 




TCE 0.25 1.0 3.33 1 


Trans- 1,2-DCE 0.23 0.6 1.69 1 



Vinyl chloride 0.24 1.1 0.24 I U 



AFCEE FORM 0-2 Page I of 4 RDD-v lo I Is 7T' BV-1 I J6P S 1411 1.114313-1,030 0 8

AFCEE 

ORGANIC ANALYSES DATA SHEET 2 1 7 75 3 99 AFCEEQAPP 

RESULTS Version 3.0 

March 1998 



Field Sample ID: 12WWIIPOIINF Lab Sample ID: D4343001 Matrix: Water 

% Solids: SampleDescription: 0012WWIIPOIINF 


Concentration Units (ug/L or mg/Kg dry weight): u.F/L Sample Volume: 20.0 ML 




Toluene-D8 113 75-125 


Fluorobenzene 


Chlorobcnzene-d5 


S111,0gare Recoee,,s are reported in App,,d,, O-A 

Comments: Internal Standards are reported in Appendix OC 

AFCEE FORM 0-2 Page 2 of 4 0 9




Analytical Method: SW8260B AAB t: D43,13 - 

Lab Name: Columbia Analytical Services/Reddiniz Contract #: F41624-94-D-8019 

Field Sample ID: 12WWIEPOIEFF _ LabSamplell): D4343002 - Matrix: Water 

% Solids: SampleDescription: 0012WWIEPOIEFF 




1, 1, I -TCA 0.22 0.8 0.22 1 U 


1, 1,2-TCA 0.26 1.0 0.26 1 U 

1, I -DCA 0.07 0.4 0.07 1 U 

1, I -DCE 0.25 1.2 0.25 1 U 

1,2-DCA 0.27 0.6 0.27 1 U 

1,2-DCB 0.08 0.3 0.08 I U 


I,3-DCB 0.25 1.2 0.25 1 U 

1,4-DCB 0.08 0.3 0.08 1 U 

Bromobenzene 0.11 0.3 0.11 I U 

Bromodichloromethane 0.23 0.8 1 0.23 1 U 

Bromoform 0.14 1.2 0.14 1 U 

Bromomethane 0.33 1.1 0.33 1 

Carbon tetrachloride 0.22 2.1 0.22 1 U 



Chloroform 0.09 0.3 0.09 1 U 


Cis-1,2-DCE 0.22 1.2 0.22 1 U 

Cis-1,3-Dichloropropene 0.16 1.0 0.16 1 1 U 

Dibrornochloromethane 0.19 0.5 0.19 1 U 



TCE 0.25 1.0 0.25 1 U 


Trans-1,2-DCE 0.23 0.6 0.23 1 U 






AFCEE FORM 0-2 Page 3 of 4 IM11-111111113 R' BA-1136PSI-AR 11.1014313-110"fi; I 0

AFCEE 1 77 540 1 A FCEE QA PP 


RESULTS Afarch 1998 


Lab Name: Columbia Analytical Services/Redding Contract : F41624-94-D-8019 

Field Sample ID: 12WWIEPOIEFF _ LabSamplelD: D4343002 - Matrix: Water 

% Solids: SampleDescription: 0012WWIEPOIEFF 






Toluene-D8 107 75-125 


Fluorobenzene 




S,,,,,g.t, Recow,,es are reported in Appendix O-A 



ia)D-11101113

AFCEEQAPP 





Lab Name: Columbia Analytical Services/Redding - Contract #: -F41624-94-D-8019 

Instrument ID: MS3 Date of Initial Calibration: 29 Nov 00 GC Column ID: DB-624 


Initial Calibration Sainple ]Ds: VSTDOO.3 VSTDO05 VSTDOJO VSTD015 VSTDO20 VSTDOOI VSTDOO.5 

Calibration File ]Ds J003779 J003776 J003775 J003774 J003773 J003777 J003778 

Analyte Std RF Std RF Std RF Std RF Std RF Std RF Std RF 

I 1 2 2 3 3 4 1 4 5 5 6 6 7 7 

1,1,1-TCA 5 000 0.344 10 00 0.324 15 00 0.328 20.00 0.322 0.500 0 293 

1,1,2,2-Tetrachloroethanc- 0 300 0.435 5.000 O606 10 00 0 568 15.00 O556 20.00 0 563 

1,1,2-TCA 5 000 0 213 M00 0.207 15M 0 207 20.00 0.216 1 000 0 213 

[,I-DCA* 0.300 0 340 5 000 0.431 10 00 0.410 15.00 0 431 20 00 0.428 

[,I-DCE4 5.000 0 178 M00 0 1661 15.001 0.178 20 00 0 165 L000 0.143 

I,2-DCA 5 000 0 265 10 00 0 250 15.00 0.250 20.00 0,242 0 500 0.249 

1,2-DCB 0 300 1.440 5.000 1 473 10.00 1 355 15.00, 1.382 MOO 1 360 

1,2-Dichloroprop=e# 0.300 0.283 5 000 0.344 10.00 0 323 15.00 0330 20 00 0.327 

I,3-DCB 5.000 1 690 10.00 1.545 15.00 1.581 20.00 1 552 1.627 

I,4.DCB 0 300 1 611 5 000 1.635 10.00 1.565 15 00 1.561 1.529 

Btornobenzene 0.300 0 626 5 000 U18 10.00 0.697 15.00 0 702 20M 0 693 

Bromodichloromethane 5.0001 0 3231 10 00 0 306, 15.00, 0.317 20.00 0.3011 0.500 0.287 

Brornoforna- 5.000 0.112 10.00 0.120 15.00 0 121 20.00 0.1201 1.0001 0.081 

Broniontethane 5.000 0.110 10 00 0.114 15.00 0.122 20.00 0 118 1.0001 0.089 

Carbon tetrachloride 5 000 0.266 10.00 0.255 15.00 0.256 20.00 0.249 1 0001 0.235 

Chlorobenzene- 0 300 0 991 5 000 1.060 10.00 1 007 15.00 I.G40 20.001 1,031 

Chloroethane 5,000 0.167 10 00 0 156 15.00 0 174 20.00 0.158 1.000 0.138 

Chlorofornig 0.300 0 406 5.000 0,423 10 00 0.397 15M 0,406 20.00 0.408 

Chloromethane- 5.000 1 0 300, 10 00 0.263 I 15 00, 0.291 20.00 0.274 1,000 0 265 

Cis-1,2-DCE 5.000 0.263 10 00 0 252 15 00 0.255 20.00 0.262 1.000 0.241 

Cis-1,3-Dichloropropene 5MO 0.430 10.00 0A23 15.00 0.433 20 00 0 423 1 000 0 403 

Dibromochloromethme 5 000 0141 10.00 0 240 15.00 0.247 0.176 

Dibromornethane 5 000 OA25 M00 0.119 15 00 0.121 20.00 0.117 1 00 I0 I04 

Methylene chloride 0,300 0 218 5 000 0 210 10.00 0,195 15.00 0 207 0 200 

TCE 5.000 0 286 1 0 00 I0 272 15M 0,283 20.00 0 276 0 2901 1 1 

* SPCCS # CCCs 

Comments: 


RIM-111113 1N)W'4343-D434(y 0

AFCEEQAPP 

AFCEE 1775403 Version 3.0 







Initial Calibration Sample IDs: VSTDOO.3 VSTDO05 VSTID010 VSTDO 1 5 VSTDO20 VSTDOO I VSTD00 i 

Calibration File IDs: J003779 J003776 J003775 J003774 J003773 J003777 J003778 

Analyte Std RF Std RF Std RF Std RF Stcl RF Std RF Std RF 

I 1 2 2 3 3 4 4 5 5 6 6 7 7 

Tctrachloroethenc 5,000 0.380 10.00 0.361 15 00 0 364 20 00 0368 1.000 0.359 

Trans-1,2-DCE 5.000 0.226 10 00 0.209 15.00 0.222 20 00 0 218 0.500 0.182 

Trans-1,3-Dichloropropene 5.000 0 412 10.00 0.409 15.00 0 413 20.00 OA33 1 000 0.378 

Trichlorofluoromethmc 5,000 0.257 10.00 0.240 15 00 0163 20.00 0 235 0.500 0.179 

Vinyl chloride# 5.000 1 0,2751 10.00 0,2581 15,001 0.286 20.001 0 264 1.0001 0.202 

Dibromofluorometbane 5 000 0.236 10 00 0.224 15 00 0,232 20.00 0 227 1.000 0.180 

Toluene-D8 5 000 1.142 10.00 1 104 15.00 1 136 20 00 1 212 1 000 0.944 

4-Bromofluorobenzene 5.000 0.695 10.00 0,694 15.00 0 696 20.00 0 686 1,000 0.597 

SPCCs CCCS 

Comments: 


IWD-11111113 R r

1775404 A FCEE QA PP 


ORGANIC ANALYSES DATA SHEET 3 (Part 2) Alarch 1998 






Initial Calibration Sample IDs. VSTDOO.3 VSTDO05 VSTDO I 0 VSTDO15 VSTDO20 VSTD001 VSTDOO 

Calibration File [Ds J003779 J003776 J003775 J003774 J003773 J003777 J003778 



1,1,1-TCA AVG 0 322 5.7 6.48 

1, 1,2,2-Tetrachloroethne* AVG 0.546 IL9 6 48 

1, 1,2-TCA AVG 0 211 1 9 6 48 

I,]-DCA* AVG 0A08 9 6 6.48 

I,]-DCE4 AVG OA66 861 6 48 1 

1,2-DCA AVG 1 0.251 3 3 6 48 

1,2-DCB AVG 1 402 37 6.48 

1,2-Dichloroproparre# AVG 0.321 7.1 6A8 

I,3-DCB AVG 1 599 3.8 6A8 

I,4-DCB AVG 1580 2.7 6 48 

Brormbenzene AVG 0 687 5.2 6.48 

Bromodichloromethane AVG 0307 4.61 6.48 1 

Bromoform* AVG 0. I I 1 15.5 6A8 

Bromomethane AVG 0 III IL7 6A8 

Carbon tetrachloride AVG 0.252 4.5 6 48 

Chlorobenzene* AVG 1.026 2 7 6.48 

Chlomethane AVG 0,159 8.4 6 48 

Chloroform# AVG 0.408 2.3 6 48 

Chloromethane- AVG 0 279 5.8 6 48 1 

Cis-1,2-DCE AVG 0 255 3.5 6.48 

Cis-1,3-Dichloropropene AVG 0 422 2.8 6 48 

Dibromochloromethane AVG 0129 13.1 6 48 

Dibromomethane AVG 0.117 6 7 6A8 

Methylene chloride AVG 0.206 4 4 6 48 

TCE AVG 0 281 2.6 6A9 

SPCCS # CCCs 

Comments: 


HIJIX0101113 W BA-1 13APS 1-.We 1)(MV4313-1143434' 

001 4

1775405 AFCEEQAPP 

Version 3. 0 







Concentration Units (ug/L or mgfkg): UG/L 

Initial Calibration Sample IDs VSTDOO.3 VSTDO05 VSTDOIO VSTDO 1 5 VSTDO20 VSTDOO I VSTDOO 5 

Calibration File IDs J003779 J003776 J003775 J003774 J003773 J003777 J003778 



Tctrachloroethene AVG 0 366 2.3 6.48 

Trans-1,2-DCE AVG 0 211 8.2 6.48 

-Trans-1,3-Dichloropropene AVG 0 409 4.9 6.48 

Trichlorofluoromethane AVG 0.235 14.1 6.48 

-Vinyl chloride# AVG 0.257 12.7 6.48 1 

Dibromofluoromethane AVG 0.220 10 4 6 48 

Toluene-D8 AVG 1.108 9.0 6 48 

4-Bromofluorobenzene AVG 0,674 6 4 6A8 

SPCCs 4 CCCs 

Comments: 

AFCEEFORM'3(Part2) Pa.gc2ol`2 

001 5

AFCEEQAPP 

1775406 AFCEE Version 3.0 




Lab Name: Columbia Analvtical Services[Redding Contract #: F41624-94-D-8019 



initial Calibration Sample [Ds VSTDO03 VSTDO05 VSTD010 VSTD015 VSTDO20 VSTD001 VSTDO05 

Calibration File IDs J003779 J003776 J003775 J003774 J003773 J003777 J003778 

Analyte Std RE Std RE Std RE Std RE Std RF Std RF Std RF 

I 1 2 2 3 3 4 4 5 5 6 6 7 7 

1, 1,2,2-Teirachloroethane- 0 300 0.435 5.000 0.606 10 00 0.568 15.00 0 556 20 001 0 563 

ll-DCA- 0.300 0 340 5.000 0.431 10 00 0.410 15 00 0 431 20.001 0.428 

II-DCE# 5 000 0.178 10.00 0.166 15 00 OA78 20.00 0.165 1 000 1 0.143 

1,2-Dichloropropme# 0.300 0.283 5 000 0.344 10 00 0.323 15.00 0.330 20.001 0.327 

Bromoform* SMO 1 0.1121 M00 0,1201 15.001 0 121 20.00 0,120 1 0oo I 0 081 I 

Chlombenzene* 0.300 0.991 5.000 1.060 10.00 1.007 15.00 1 040 20,001 1,031 

Chloroforrml 0 300 0.406 5.000 0.423 10.00 0.397 15 00 0 406 20.001 0 408 

Chioromethane* 5.000 0.300 10 00 0.263 15.00 0.291 20.00 0.274 1.000 0 265 

Vinyl chloridd 5M0 0.275 10.00 0 258 15M 0 286 NM 0,264 1 000 0 202 

SPCCS CCCs 

Comments: 

AFCEE FORM JA (Part 1) Page I of 1 

ROD-1110103 R HS-1131,"11-111 11111111313-11130io

1775407 A FCEE QA PP 



INITIAL MULTIPOINT CALIBRATICN-GC/MS 





Initial Calibration Sample [Ds: VSTD00,3 VSTDO05 VSTID010 VSTD015 VSTDO20 VSTD00l VSTDO05 

Calibration File ]Ds: J003779 J003776 J003775 J003774 J003773 J003777 J003778 



1,1,2,2-Tetrachlormthane- AVG 0.546 11.9 6 48 

lI-DCA* AVG 0 408 9 6 6 48 

-[,I-DCE# AVG 0.166 8.6 6 48 

-1,2-Dichloroprop=c# AVG 0.321 7.1 6 48 

Bromofom* AVG 0.111 15.5 6.48 

Chlorobenzene* AVG 1.026 2.7 6.48 

Chloroform# AVG 0.408 2.3 6.48 

Chloromethane- AVG 0 279 5 8 6 48 

Vinyl chloride# AVG 0.257 12 7 6.48 

SPCCs CCCs 

Comments: 


1 7

AFCEE QAPP 

1775408 Version 3.0 

March 1998 

AFCEE 




Lab Name: Columbia Analytical Services[Redding Contract #: F41624-94-D-8019 

Instrument ID: MS3 Initial Calibration ID: 3003780.13 



Comments: 


1. 1, I -TCA 10 00 10 60 6.0 

1,12,2-Tetrachloroethane- 10 00 10.33 3.3 

1,1,2-TCA 10.00 9.704 -10 

ll-DCA- 10.00 10.26 2.6 

II-DCE# 10.0( 10.41 4.1 

1,2-DCA 10.00 10.29 2.9 

1,2-DCB 10 00 10.011 00 I 

1,2-Dichloropropane# 10.00 M53 5.3 

1,3-DCB 10.00 10 09 0 9 

1,4-DCB 10.00 1012 1.2 

Brombenzene 10.00 10.40 4.0 

Bromodichloromethane 10.0( 10 41 4.1 

Bronnoforrn- 10.00 10.38 18 

Bronnornethane 10.00 10.731 7.3 1 

Carbon tetrachloride I OM 10 49 4.8 

Chlorobenzene- 10 00 10.33 3.3 


Chloroforin# I OM M22 2.2 

Chloromethane- I OM 10 56 5.6 

Cis-1,2-DCE 10.00 10.52 5.2 

Cis-1.3-Dichlompropene 10 00 10.451 4.5 1 

Dibromochloromethane 10.00 10.29 M 

Dibronnornethane 10.00 10.43 -4-3 

Methylene chloride 10.00 1 O07 0 7 

TCE 10 00 10.36 3.6 

SPCCs # CCCs 


RDD-010101 TC BS 1136PST-SR 11311.fllo'j 8

AFCEE 





Instrument ID: MS3 Initial Calibration ID: J003780.1) 



Comments: 

09 AFCEE QAPP 

17754 Version 3.0 



Trans-1,2-DCE 10 00 10.47 4.7 

Trans-13-Dichloropropene 10.00 1013 1 3 

Trichlorofluoromethane 10.00 10 88 88 

Vinyl chloride# 10.00 10.87 8 7 

Dibromotluoromethane N/A NIA 0.0 

Toluene-D8 N/A N/A 00 

4-13romofluorobenzene N/A N/A 0 0 

SPCCS 4 CCCS 


March 1998 

RDD01010J TC.BS-1136PST-SR DW0114J-D4q- 

U

AFCEE QAPP 

1775410 Version 3.0 






Instrument ID: MS3 Initial Calibration ID: J003780.D 


ICV File ID: J003780.D CCV #I File ID: J004155.D CCV #2 File ID: 

GC Colunm ID: DB-624 



1, 1, I -TCA 10.00 10.60 6 0 10 00 10.12 12 

1, 1,2,2-Tetrachloroethane* 10.00 10.33 3.3 lo.Go t OA9 4 9 

1,1,2-TCA 10 00 9.704 -3 0 Moo 10.37 3.7 

II-DCA- 10 00 10.26 2.6 Moo 10.62 6.2 

II-DCE# 10.00 10.41 4 1 10 00 10 01 0 1 

1,2-DCA 10 00 10.291 2.9 10.001 11.65 165 

1,2-DCB 10.00 Mot 0 0 10.00 9.753 -2.5 

1,2-Dichloropropane# 10.00 10.53 5.3 10 00 Mob 0.6 

1,3-DCB 10.00 10 09 0 9 10 00 9.807 _L9 

1,4-DCB 10.00 10.12 1.2 10 00 9.842 -Lb 

Bronnobenzene 10.00 10A0 4.0 10.00 10 14 1.4 

Bronitadichloronnetbane 10.00 10.41 4.1 10.00 9.862 -1.4 

Bromfornt- 10.00 10.38 1 3.8 10 00 9.353 -6.5 

Brornonnethane 10 00 10.73 7.3 10 00 8.032 -19.7 

Carbon tetrachloride 10.00 10.49 4.8 10.00 10 03 0.3 

Chlorobenzene- 10.00 10.33 3.3 Moo 9.861 -1 4 

Chloroethane 10.00 10.36 3.6 10.00 9.511 4.9 

Chlorolbarn4 10.00 1 012 2.2 10 00 10.11 1.1 

Chloromethane- lo.Go 10 56 5 6 10 00 9.621 -3.8 1 

Cis-1,2-DCE 10.00 10.52 1 5.2 10.00 1 9.950 -0 5 

Cis- 1,3-Dichloropropene to 00 10.45 4.5 10.00 9134 -7.6 

Dibromochlommethane 10.00 10.29 2.8 10 00 M66 6.6 

Dibronnornethane lo 00 10.43 4 3 10 00 10 15 L5 

Wthylene chlonde 10.00 10.07 0.7 10.00 10 35 3.5 

TCE 10.00 10.36 3 6 10 00 1 OM 0.2 

* SPCCs # CCCS 

Comments: 


RDD 010104 TC BS 0841PST-SR DM434 I-D,0,0 12 0

AFCEE QAPP 

1 7 7 5 4 1 Version 3.0 






Instrument ID: MS3 Initial Calibration ID: J003780.1) 

ICV ID: QCALTSTD CCV #I ID: VSTDO I 0 CCV #2 ID: 

ICV File ID: J003780.1) CCV #1 File ID: J004155.1) CCV #2 File ID: 


Icv CCv #1 CCV #2 


Tetractiloroethene 10.00 10.03 0 3 10.00 9 704 -3.0 

Trans-1,2-DCE 10.00 10.47 4.7 10.00 10 25 2 5 

Trans-1,3-Dichloropropene 10 00 1013 1.3 10.00 9.652 -3 5 

Trichlorofluoromethane 10.00 10.88 8 8 10.00 10.26 2.6 

inyl chloride# 10.00 10.87 8.7 10 00 9.392 -61 

ibromofluoromthanc N/Al NIA 0.0 10.00 11 061 10.6 

luene-D8 N/A N/A 00 10.00 10.85 8.5 

-Bromonuorobenzene N/A N/A 0.0 10 00 10.32 3.2 

SPCCs # CCCs 

Comments: 

AFCEEFOPMC-5 Pagc2of`2 

RDD-01 0104 TC BS-0841PST-SR DOW'.14 0, 0- 2

17 -7 

AFCEE QAPP 

54 1 2 Version 3. 0 






Instrument ID: MS3 Initial Calibration ID: J003780.13 

ICV ID: QCALTSTD CCV #1 ID: VSTDO I 0 CCV #2 ID: 

ICV File ID: J003780.1) CCV #I File ID: J004155.1) CCV #2 File ID: 


Analyte ICv CCv#I CCV #2 Q 

-T-l Expected Found %D RF Expected Found %D RF Found %D 

1,1,2.2-Tevachloroethane- 0.564 10.00 1033 3.3 0.572 10.00 10.49 4.9 

1,1-[)CA* 0 419 10.00 10.26 2.6 0.433 MOO 10.62 6.2 

1.1-DCE# 0.173 10.00 10 41 4.1 0.166 10.00 10.01 0.1 

1,2-Dichloropropane# 0.338 10.00 10.53 53 0.323 10.00 10.06 0 6 

Brornotorin- 0.115 10.00 10.38 18 0AG4 10.00 9.353 -6.5 

Chlorobenzene- 1.060 10.00 10.331 3 3 1.0121 10.00 9.861 I -1.4 

Chlorofornn# 0.4171 10.00 10.22 2 2 0 412 10.00 10.11 1.11 I 

Chloromethane- 0.294 10.(O 10.56 5.6 0.268 10.00 9.621 -3.8 

Vinyl chloride# 0.279 10.00 10.87 8.7 0.241 10.0( 9.392 -6 1 

SpCCS CCCS 

Comments: 


RDD-010104 TC BS 0811PYr SR 131J-D YY0 2


AFCEE 7 7 5 4 1 3 AFCEEQAPP 


BLANKS Alarch 1998 


Concentration Units (ug/L or mg1kg): ug/L MethodBlankID: J1227WO] 

LabSampleID: J1227WO] 


1,1,1-TCA 0.22 0.22 0.8 


1, 1,2-TCA 0.26 0.26 1 0 

1, I -DCA 0.07 0.07 0.4 

1, I -QCE 0.25 0.25 1.2 

1,2-DCA 0.27 0.27 0.6 

1,2-DCB 0.08 1 0.08 0.3 


1,3-DCB 0.25 0.25 1.2 

I,4-DCB 0.08 0.08 0.3 



Bromoform 0.14 0.14 1.2 1 

Brornomethane 0.33 I 0.33 1.1 





Chloromethane 0.17 0.17 1.3 

Cis-1,2-DCE 0.22 0.22 1.2 1 

Cis- 1,3-Dichloropropene 0.16 I 0.16 1.0 

Dibromochloromethane O. I 9 0.19 0.5 


Methylene chloride 0.13 0.13 0.3 

TCE 0.25 0.25 1.0 


Trans-1,2-DCE 0.23 0.23 0.6 1 

Trans- 1.3-DichloroDrovene 0.20 0.20 1.0 

Trichlorofluoromethane 0.36 I 0.36 0.8 


Comments: 


2 3

1775114 AFCEE AFCEEQAPP 




Lab Name: Columbia Analytical Services/Reddin2 Contract F41624-94-D-8019 

Concentration Units (ug/L or mg/kg): ug/L MethodB]ankID: JI227W01 

LabSampIeID: J1227WOI 

Comments: 

Analyte MDL Method Blank RL 



Toluene-D8 103 75-125 


Fluorobenzene 





24


AFCEE QAPP 

AFCEE 17754 15 Version 3. 0 




LCSID: J1227WOlLCS Concentration Units (ug[L or mgfkg): ug/l. 

Date Extracted: Date Analyzed: 27 Dee 00 


1, 1, I -TCA 10.00 10.12 101 75-125 


1,1,2-TCA 10.00 9.72 97 75-127 

II-DCA 1000 10.45 104 72-125 

1,1-DCE 10.00 9.98 100 75-125 

1,2-DCA 10.00 11.17 1121 68-127 

1,2-DCB 10.00 9.57 96 75-125 


I,3-DCB 10.00 9.72 97 75-125 

1,4-DCB 10.00 9.68 97 75-125 

Bromobenzene 10.00 10.22 102 75-125 

Bromodichloromethane 10.00 9.66 96 75-125 

Bronnoform 10.00 8.9-1 881 75-125 

Bronnomethane 10.00 8.08 8 1 72 -125 



Chloroethane 10.00 9.24 92 65-125 

Chloroform 10.00 9.98 100 74-125 


Cis-1,2-DCE 10.00 9.96 100 75-125 



Dibromornethane 10.00 9.83 98 69-127 


TCE 10.00 9.97 100 71-125 

Tetrachloroethene 10.00 9.73 97, 71-125 

Trans-1,2-DCE 10.00 9.92 99 75-125 

Trans-1,3-Dichloropropene 10.00 9.50 95 66-125 



Comments: 


RDD-010103 7K BV-11 6PST-Sfl

AFCEE QAPP 

17 -7 54 1 6 AFCEE Version 3.0 





LCSID: J1227WOlLCS Concentration Units (ug/L or mg/kg): ug/L 

Date Extracted: Date Analyzed: 27 Dec 00 

Comments: 




Toluene-138 106 75-125 


Fluorobenzene 





RDD-010103 BS IIJ6PST-SR -ITO-2

AFCEE 


HOLDING TIMES 



AFCEE QAPP 

1 7 75 4 1 7 V,,.,i,,, 3. 0 

March 1998 

Ist Max. lst 2nd Max. 2nd Max. Time Q 



12WWIIPOIINF 18 Dec 00 19 Dec 00 NIA N/A N/A N/A N/A N/A 27 Dec 00 i4 9 

12WWIEPOIEFF 18 Dec 00 19 Dec 00 N/A N/A N/A N/A N/A N/A 27 Dec 00 1 4 9 

Comments: 


RDD010 IO TC BS-11 16PST SR DOW4343-0430 '027

AFCEE QAPP 

17 7 5 Version 3.0 

March 1998 

AFCEE 








VSTDO20 J003773 29 Nov 00 1002 29 Nov 00 1032 

VSTD015 1003774 29 Nov 00 1040 29 Nov 00 1110 

VSTD010 J003775 29 Nov 00 1119 29 Nov 00 1149 

VSTDO05 J003776 29 Nov 00 1155 29 Nov 00 1225 

VSTD001 J003777 29 Nov 00 1237 29 Nov 00 1307 

VSTDOO 5 J003778 29 Nov 00 1 1318 29 Nov 00 1348 

VSTDOO.3 J003779 29 Nov 00 1358 29 Nov 00 1428 

QCALTSTD J003780 29 Nov 00 1434 29 Nov 00 150 

VSTD010 J004155 27 Dee 00 0854 27 Dec 00 0924 

J I 227WO1 LCS J004156F 27 Dec 00 0937 27 Dee 00 1007 

JJ227W01 J004158F 27 Dec 00 1054 27 Dec 00 112 

12WWIIPOIINF J004160 27 Dec 00 1206 27 Dec 00 123 

12WWIEPOIEFF J004161 27 Dec 00 1 1243 27 Dec 00 1313 

Comments: 

AFCEEFOPMO-10 Pagelofl 

DD010103 TC.BS 1136PST-SR 343-D4343. 0028


AFCEE 





1 7 7 5 419 AFCEEQAPP 

Version 3. 0 

March 1998 

Instrument ID: MS3 Compound: BFB Injection Date/Time: 29 Nov 00 0929 


-- = 15% to 40% of mass 95 19.) 

--- 73- 30% to 60% of mass 95 43.9 

base peak, I 00% relative abundance 100.0 

---- 9T 5% to 9% of mass 95 7.0 

--- r7T- 0% to less than 2% of mass 174 0.3 (0.5) 

-- 77- greater than 50% of ass 95 58.4 1 1 

775- 5% to 9% of mass 174 4.0 

T77 >95%, but

AFCEE QAPP 

Version 3.0 

1775 120 March 1998 


AFCEE 



(BFI3 or DFTPP) 


Instrument ID: MS3 Compound: BFB Injection Date/Time: 27 Dec 00 0742 


15% to 40% of mass 95 23.2 

30% to 60% of mass 95 46.2 

--- 9T base peak, I 00% relative abundance 100.0 

5% to 9% of mass 95 6.8 

0% to less than 2% of mass 174 0.4 (0.7) 

174 greater than 50% of mass 9 9.1 

---- = 5% to 9% of mass 174 4.7 

-- r7- >95%, but

AFCEE 




Lab Name: Columbia Analytical ServicestRedding Contract F41624-94-D-8019 

Matrix: Water 

AFCEE QAPP 

1 7 75 4 2 1 Version 3.0 

March 1998 

Field/QC Sample ID Si S2 S3 S4 S5 S6 S7 Ss Q 

31227WOi LCS 104 106 99 

J1227WO1 100 103 too 

12WWIIPOIINF 107 113 104 

12WWIEPOiEFF 103 107 103 




Comments: 

AFCEE FORM APPENDIX A Page I of I 

RDO01010 I TC BS- I I 16PSTSR De., 3, 3.,,QQ 3

AFCEE QAPP 

77 5 4 2 2 Version 3. 0 

Comments: 

AFCEE 


INTERNAL STANDARD AP EA AND RT SUMMARY 



Instrument ID: MS3 Date Analyzed: 29 Nov 00 TimeAnalyzed: 1119 

IS1 IS2 IS3 

March 1998 


12 HOUR STANDARD 9238962 11.10 7456065 16 37 3799250 20.6i 

UPPER LIMIT 18477924 11.60 14912130 16 87 7598500 2111 

LOWER LIMIT 4619481 10 60 3728033 1587 1899625 20 11 

SAMPLE ID 

J1227WOlLCS 9365008 11 07 7058600 1635 3502326 20.59 

J1227W01 9808603 11.08 6638839 16.35 3160289 20J9 

12WWIIPOIINF 8391023 11 08 6330382 16 35 3025659 2059 

12WWIEPOIEFF 7363498 1110 5577735 16 34 2596376 20.58 

Isi. Fluorobenzene IS4. 

IS2 Chlorobenzene-0 Iss. 

IS3 1,4-Dichlorobenzene-d,l IS6. 


AFCEE FORM APPENDIX C Page I 


% 

RDD-010103 TCBS-1136PSr SR 3


AFCEE QAPP 

1775423 Version 3.0 

March 1998 




Replicates 

Analyte Analysis Amt. 2 3 4 5 6 7 -8 Sid, MDL 

Date Spiked Dev. 

lt,]-TCA 25 Feb 00 1 0.88469 0.88725 0.97684 0.80569 0.9372 0 77978 0.97456 0.83774 0 074429 0.22 

1,1 2,2-Tetmchloroethane 9 Mar 00 0.5 0 53 159 0,57404 0.53554 0.61526 0.45347 0.55417 0.56525 0,46692 0.054128 0 16 

1.1,2-TCA 25 Feb 00 1 0.99872 0.99277 1.16447 0.90669 1.02697 0.90679 1 0724 0.94141 0.087739 0 20 

1.1-DCA 8 Mar 00 0.5 0 44039 OA147 0 45278 0 43842 0 42784 0 45029 0 47477 0A0478 0 022287 0 067 

ll-DCE 25 Feb 00 1 0.87687 0.78089 0.92138 0.80206 0.98724 0.76978 0 97333 0,90002 O084750 0.25 

1,2-DCA 25 Feb 00 1 1.07865 1.05575 1 21429 1 01652 1 22753 1 0.97848 1 134 1.04165 0.090777 0.27 

1,2-DCB 8 Mar 00 0.5 0.49953 0.48294 0.50262 0.54225 0.47071 0.52307 0.54878 0.50655 0 027163 0 091 

1.2-Dichloropropane 8 Mar 00 0.5 0.45864 0.44212 0.48203 0.52411 0.42729 0.47337 0.4826 0 47766 0 029336 0.088 

1.3-DCB 25 Feb 00 1 1.05451 0.99461 1 13016 0.90109 1 10332 0.93071 1.09727 1.0012 0 083666 0.25 

1,4-DCB 8 Mar 00 0.5 0.50929 0.49177 0.51711 0.52441 0 48687 0.54908 0.55829 0.489 0 027160 0 081 

Bromobenzene 8 Mar 00 0.5 0.45798 0A325 0.43584 0.51724 0.40684 0 45223 0 49751 0 45593 0.035574 0.11 

jBi-orricidc1loronnethane 25 Feb 00 1 0.9867 0.89716 1 02541 0,80702 0.95008 0.8i 971 0.93701 0.81305 0 077397 0 23 

Br"ofo. 25 Feb 00 I 0 7046 0.69077 0 71221 0 59043 0 67653 0 60831 0 70141 0.64763 0 046259 0 14 

Bronnornethane 25 Feb 00 I 0 96761 0.88975 1.16915 0,85572 1.0619 0.85361 0.98442 0.9092 0.109151 0.33 

Carbon tetrachloride 25 Feb 00 1 0.84794 0 81588 0.8754 0.69174 0.89453 0.71818 0.84754 0,78052 0.073273 U2 

Chiorobenzene 8 Mar 00 0.5 0 50987 0.48705 0.5264 0.56648 0.47604 0.5291 0.53529 0.51288 0 028419 0 085 

Chloroethane 25 Feb 00 1 0.77665 0.83743 0.87068 0.72694 0.94065 0 70655 0 97641 0.91748 0.) 00113 0 30 

Chlorofortri 8 Mar 00 0 5 0 49321 0A5903 0,47718 0.51568 0.43933 0.51028 0.51252 0.45274 0 029801 0 089 

Chloromethane 25 Feb 00 I 0 76556 0.74161 0.74714 0 65696 0,7544 0.60591 0.71627 0.74913 0.056378 0.17 

Cis-1,2-DCE 25 Feb 00 1 O96171 0 94798 1,07969 0,87766 1.06163 0.91503 1.04368 0.9944 0.072407 0.22 

Cis-1,3-Dichloropropene 25 Feb 00 1 O92532 0.88503 0.95517 0.86814 0.951 72 0.80579 0.9287 0.84866 0.053197 0 16 

Dibromochloromethane 25 Feb 00 1 0,82914 0.80634 0.83639 0 7177 0 84986 0 70584 0.85614 0.73033 0 062976 0 19 

Dibromomethane 25 Feb 00 1 1.0262 0 96732 1 1575 0,89892 1 11464 0,89382 1.0017 0.88896 0.102262 0 31 

Methylene chloride 8 Mar 00 0 5 0 50932 0 51772 0.54275 0.57128 0.50001 0.56598 0 59942 O61424 0.042210 0 13 

TCE 25 Feb 00 I 0 97017 0.99215 1.06629 0.8312 1 01458 O86373 1.04878 0 95648 0 083377 0 25 

Tetrachloroethene 25 Feb 00 i 0.9867 0.97957 1 09232 0,88683 1.07993 0,88401 1.0772 0.95599 0.083880 0 25 

Traris-1,2-DCE 25 Feb 00 i O94823 0 92685 1 02878 0.80794 0,97958 0 80797 0 94676 0 90621 0 077674 0 23 

Truns-1,21-Dichloropropene 25 Feb 00 I 0 85659 0,84435 0.90409 0 79831 0.9271 0.72072 1 0.87954 0.82644 0.066036 0.20 

Trichlorofluoromethane 25 Feb 00 1 0.84445 0.56244 0 87558 0.71011 0.0528 0.57086 0.82408 0.737(6 0.120995 0 36 

Vinyl chloride 25 Feb 00 1 0.74226 0.7417 0 78014 066757 0.77776 0,56723 0,82259 0,72788 0.079309 0.24 

MDL FORM Method SW8260 Page I of I 0 0 3 3 

RDD010103 TCBS41i6PSTSRDW04343-D4311-1'

1775424 


00.14

Z Z 

i2 

i; 0 

0 1.z 

Ln tP 9 

C\j 01 

Ln 0 

E 7-: 

0 CC 0 

U) 

U. CA- 

0 L zwmw 

< 

U 

0< 0 uoz< 

CO 0 

R

1775426 

Columbia 

Analytical 

ServiceS inc, 




COOLER RECEIPT FORM 

Project/Client VA,11ZCH I L.Z> WorkOrdei-D0004-345 

1. Cooler(s)/Sample(s)receivedon: I-Aliq)co Shippedvia: 'Pp r--x 

Shippingllill#(s): 

2. Cooler(s) screened by: Rejected 

3. Custody seals on outside of cooler. NO NIA 

If yes, where? Front I Rear__L_ Lt Side- Rt Side 

Seals intact. (YES NO 

4. Sample Processing/Tagaing. by: 

5. Cooler(s)/Sample(s) Temp.'s 

(or) 

Temp. Blank (if present) C 

COOLER/SAME PROCESSING 

6. Type of packing material presentz -:3mg &2g& 3"Ma j "ex 

7. Custody papers properly filled out (ink, signed, dated, released, etc.)? NO 

8. Containers arrived in good condition (unbroken, leaking, etc.)? Jt7M NO 

9. Container labels complete (i.e. analysis, preservation, date/time, etc.)? 4iDS NO 

10. Container labels and tags agree with custody papers? NO 

II. Correct types of containers used for the tests indicated? NO 

a-) Adequate sample received? If not, note on Exception Report. 7(4R NO 

12. Preserved containers received with the appropriate preservative? NO Ni/A 

pH: Z 2. (or) S-e e p g 

13. VOA vials checked for absence of air bubbles? N/A 



See Exception Report for discrepancies. 

0036

Columbia 1775427 

Analytical 

ServiceSinc 




COOLER RECEIPT FORM 

Project/Client- VA.1 RCH I L-r-> Work Order DOOC4345 

1. Cooter(s)/Sample(s)receivedon: j-Z1l9)00 Shippedvia: :kp r--x 

Shipping Bill # (s): 8 15 5S+ ie.,rc)44 

2. Cooler(s) screened by: Rejected 

3. Custody seats on outside of cooler. NO N/A 

If yes, where? Front I Rear__I_ Lt Side- Rt Side 

Seals intact. R NO 

4. Sample Processing/Tagmna by: 

5. Cooler(s)/Sample(s) Temp- Is 

(or) 

Temp. Blank (if present) 'f7Z C 

COOLER/SAME PROCESSING 

6. Type of packing material presena6e t 

7. Custody papers properly filled out (ink, signed, dated, released, etc.)? NO 

8. Containers arrived in good condition (unbroken, leaking, etc.)? afD NO 

9. Container labels complete (i.e. analysis, preservation, date/time, etc.)? 4% NO 

10. Container labels and tags agree with custody papers? (ff-B NO 

II. Correct types of containers used for the tests indicated? NO 

a.) Adequate sample received? If not, note on Exception Report. NO 

12. Preserved containers received with the appropriate preservative? NO N/A 

pH: Za 14 C,(- (or) Sè-ep .. ' 

13. VOA vials checked for absence of air bubbles? Is N/A 


14. Samples transferred to the freezer: Date: Time: (2! 

See Exception Report for discrepancies. 3 7

I - 

FINAL PAGE 

ADMINISTRATIVE RECORD 

FINAL PAGE 

1 775,1"90o 

M 

I

7 - Air Mobility Command Administrative Record

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