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2nd ASEAN Sago Symposium 2012, UNIMAS, Kota Samarahan ...

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2 nd <strong>ASEAN</strong> <strong>Sago</strong> <strong>Symposium</strong> <strong>2012</strong>, <strong>UNIMAS</strong>, <strong>Kota</strong> <strong>Samarahan</strong><br />

Advances in <strong>Sago</strong> Research and Development<br />

Poster 13<br />

Spectroscopic and Morphological Characterisation of Treated <strong>Sago</strong> Wastes as<br />

Biosorbents<br />

Siong Fong Sim 1,*, Nurul Aida Lu Mohd Irwn Lu 1, Terri Zhuan Ean Lee 1, Murtedza Mohamed 1<br />

1 Universiti Malaysia Sarawak, Faculty of Resource Science and Technology,<br />

94300 <strong>Kota</strong> <strong>Samarahan</strong>, Sarawak, Malaysia;<br />

*Email address of corresponding author: sfsim@frst.unimas.my<br />

<strong>Sago</strong> industry has undergone rapid development that has simultaneously generated massive<br />

amount of waste i.e., sago hampas. Lignocellulosic biomass has been known to be potential<br />

biosorbents nonetheless treatment is often necessary to improve the adsorption ability. In this<br />

paper, we treated sago hampas with citric acid, acetic acid, hydrothermal, NaOH, combination of<br />

HCl and NaOH and H2SO4 where the spectroscopic and morphological characteristics of the<br />

biomass were examined. Results showed that acetic acid, citric acid and hydrothermal<br />

treatment had not resulted in significant changes. Strong acid treatment however had caused<br />

severe hydrolysis with solubilisation of cellulose. NaOH treatment demonstrated exposure of<br />

cellulose suggesting effective removal of hemicelluloses and lignin. Among these treatment<br />

processes, NaOH treatment appeared to be potentially effective in improving the adsorption<br />

ability of sago hampas.<br />

Poster 14<br />

Production and Purification of <strong>Sago</strong> Sugar<br />

K.B. Bujang, N.J. Monib* & C. Nolasco-Hipolito<br />

Department of Molecular Biology, Faculty of Resource Science and Technology,<br />

Universiti Malaysia Sarawak, 94300 <strong>Kota</strong> <strong>Samarahan</strong>, Sarawak MALAYSIA.<br />

*Email address of corresponding author: jannahmonib@gmail.com<br />

<strong>Sago</strong> starch is an attractive alternative as a substrate for the production of sugar due to its<br />

economic and geographical considerations. In this study, sago starch was used for the<br />

production of glucose which is potentially viable as the new source of commercial sugar<br />

through enzymatic hydrolysis of sago starch into sugars (96% glucose), achieved after about 6<br />

hours. The objectives of this study are to develop effective filtration techniques to purify the<br />

Hydrolysed <strong>Sago</strong> Starch (HSS) to produce Purified <strong>Sago</strong> Sugar (PSS) using Powdered Activated<br />

Charcoal (PAC) and to observe the effects from augmentation of the purification scale.<br />

Purification of LSS at 152g/L glucose was performed on 5g PAC packed on glasswool in a glass<br />

tube (2.5cm diameter, and 2cm filtration height). Filtration by gravity at a flow-rate of<br />

130ml/hr gave the highest recovery of glucose at 73% (110.5g/L) compared to on 10g and 15g<br />

PAC, at 69% (89.8g/L) and 50% (75.4g/L), respectively. Efforts to enhance filtration of HSS was<br />

studied using a pump (flow-rate of 460ml/hr) demonstrated that purification under forced<br />

filtration yield a higher recovery (almost 90%, or 135.6g/L) compared to purification under<br />

gravity. Further analyses revealed that the recovery of glucose increased by over 70% (from<br />

101.3g/L to 153.7g/L) after 7 cycles upon filtration on the same batch of PAC. However, such<br />

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